#------------------------------------------------------------------------------
#$Date: 2016-03-22 12:50:11 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178965 $
#$URL: svn://www.crystallography.net/cod/cif/4/11/94/4119448.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4119448
loop_
_publ_author_name
'Polly L. Arnold'
'Emmalina Hollis'
'Gary S. Nichol'
'Jason B. Love'
'Jean-Christophe Griveau'
'Roberto Caciuffo'
'Nicola Magnani'
'Laurent Maron'
'Ludovic Castro'
'Ahmed Yahia'
'Samuel O. Odoh'
'Georg Schreckenbach'
_publ_section_title
;
 Oxo-Functionalization and Reduction of the Uranyl Ion through
 Lanthanide-Element Bond Homolysis: Synthetic, Structural, and Bonding
 Analysis of a Series of Singly Reduced Uranyl-Rare Earth 5f1-4fn
 Complexes
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3841
_journal_page_last               3854
_journal_paper_doi               10.1021/ja308993g
_journal_volume                  135
_journal_year                    2013
_chemical_formula_moiety         'C109 H105 Eu2 N21 O4 U2'
_chemical_formula_sum            'C109 H105 Eu2 N21 O4 U2'
_chemical_formula_weight         2553.12
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.125(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.4550(5)
_cell_length_b                   27.5854(7)
_cell_length_c                   23.1120(6)
_cell_measurement_reflns_used    19474
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.1746
_cell_measurement_theta_min      2.8834
_cell_volume                     9970.4(5)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_molecular_graphics    'ORTEP (Farrugia, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.977
_diffrn_measurement_device_type  'Xcalibur, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0501
_diffrn_reflns_av_sigmaI/netI    0.1335
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       35
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            76695
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.89
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.544
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.75285
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.701
_exptl_crystal_description       plate
_exptl_crystal_F_000             4992
_exptl_crystal_size_max          0.255
_exptl_crystal_size_mid          0.137
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.196
_refine_diff_density_min         -1.380
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.745
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1314
_refine_ls_number_reflns         22366
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      0.745
_refine_ls_R_factor_all          0.0707
_refine_ls_R_factor_gt           0.0298
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0125P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0424
_refine_ls_wR_factor_ref         0.0444
_reflns_number_gt                12649
_reflns_number_total             22366
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ja308993g_si_011.cif
_cod_data_source_block           p10088
_cod_database_code               4119448
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7181(3) 0.00266(15) 0.93725(18) 0.0253(11) Uani 1 1 d . . .
H1 H 0.7741 0.0143 0.9416 0.030 Uiso 1 1 calc R . .
C2 C 0.6828(3) -0.03427(15) 0.89386(18) 0.0234(11) Uani 1 1 d . . .
C3 C 0.7156(3) -0.06006(16) 0.85491(19) 0.0321(12) Uani 1 1 d . . .
H3 H 0.7722 -0.0582 0.8525 0.039 Uiso 1 1 calc R . .
C4 C 0.6501(3) -0.08917(15) 0.82006(19) 0.0324(12) Uani 1 1 d . . .
H4 H 0.6531 -0.1111 0.7891 0.039 Uiso 1 1 calc R . .
C5 C 0.5789(3) -0.08034(15) 0.83878(19) 0.0275(11) Uani 1 1 d . . .
C6 C 0.4892(3) -0.10238(16) 0.81522(19) 0.0302(12) Uani 1 1 d . . .
C7 C 0.4722(3) -0.13127(15) 0.86709(19) 0.0369(12) Uani 1 1 d . . .
H7A H 0.5147 -0.1572 0.8802 0.055 Uiso 1 1 calc R . .
H7B H 0.4148 -0.1455 0.8527 0.055 Uiso 1 1 calc R . .
H7C H 0.4762 -0.1096 0.9015 0.055 Uiso 1 1 calc R . .
C8 C 0.4838(3) -0.13702(16) 0.76244(19) 0.0449(14) Uani 1 1 d . . .
H8A H 0.4990 -0.1196 0.7303 0.067 Uiso 1 1 calc R . .
H8B H 0.4253 -0.1495 0.7462 0.067 Uiso 1 1 calc R . .
H8C H 0.5235 -0.1641 0.7770 0.067 Uiso 1 1 calc R . .
C9 C 0.4251(3) -0.06209(16) 0.79503(18) 0.0255(11) Uani 1 1 d . . .
C10 C 0.3669(3) -0.05335(18) 0.73694(19) 0.0367(12) Uani 1 1 d . . .
H10 H 0.3597 -0.0727 0.7017 0.044 Uiso 1 1 calc R . .
C11 C 0.3222(3) -0.01158(17) 0.74033(18) 0.0364(12) Uani 1 1 d . . .
H11 H 0.2789 0.0032 0.7080 0.044 Uiso 1 1 calc R . .
C12 C 0.3532(3) 0.00485(16) 0.80110(18) 0.0260(11) Uani 1 1 d . . .
C13 C 0.3326(3) 0.04628(16) 0.82849(19) 0.0311(12) Uani 1 1 d . . .
H13 H 0.2908 0.0682 0.8048 0.037 Uiso 1 1 calc R . .
C14 C 0.3574(2) 0.10300(16) 0.90702(19) 0.0258(11) Uani 1 1 d . . .
C15 C 0.3329(2) 0.10839(16) 0.95968(19) 0.0307(12) Uani 1 1 d . . .
H15 H 0.3251 0.0801 0.9808 0.037 Uiso 1 1 calc R . .
C16 C 0.3198(3) 0.15327(18) 0.9819(2) 0.0369(13) Uani 1 1 d . . .
C17 C 0.2911(3) 0.15755(17) 1.0370(2) 0.0521(15) Uani 1 1 d . . .
H17A H 0.3302 0.1790 1.0668 0.078 Uiso 1 1 calc R . .
H17B H 0.2911 0.1254 1.0551 0.078 Uiso 1 1 calc R . .
H17C H 0.2332 0.1711 1.0254 0.078 Uiso 1 1 calc R . .
C18 C 0.3239(4) 0.24461(18) 0.9753(3) 0.087(2) Uani 1 1 d . . .
H18A H 0.2700 0.2469 0.9849 0.131 Uiso 1 1 calc R . .
H18B H 0.3242 0.2687 0.9443 0.131 Uiso 1 1 calc R . .
H18C H 0.3719 0.2507 1.0122 0.131 Uiso 1 1 calc R . .
C19 C 0.3322(3) 0.19465(18) 0.9517(2) 0.0477(14) Uani 1 1 d . . .
C20 C 0.3579(3) 0.18942(17) 0.9002(2) 0.0403(13) Uani 1 1 d . . .
H20 H 0.3674 0.2179 0.8801 0.048 Uiso 1 1 calc R . .
C21 C 0.3705(3) 0.14460(17) 0.8765(2) 0.0302(12) Uani 1 1 d . . .
C22 C 0.3677(3) 0.16857(16) 0.7796(2) 0.0367(13) Uani 1 1 d . . .
H22 H 0.3106 0.1788 0.7740 0.044 Uiso 1 1 calc R . .
C23 C 0.4065(3) 0.18079(18) 0.7351(2) 0.0436(14) Uani 1 1 d . . .
C24 C 0.3714(4) 0.1989(2) 0.6760(2) 0.078(2) Uani 1 1 d . . .
H24 H 0.3129 0.2064 0.6565 0.093 Uiso 1 1 calc R . .
C25 C 0.4362(4) 0.2040(2) 0.6518(3) 0.085(2) Uani 1 1 d . . .
H25 H 0.4317 0.2149 0.6119 0.103 Uiso 1 1 calc R . .
C26 C 0.5106(4) 0.19003(18) 0.6968(2) 0.0509(15) Uani 1 1 d . . .
C27 C 0.5999(4) 0.18919(19) 0.6897(2) 0.0515(15) Uani 1 1 d . . .
C28 C 0.6123(4) 0.2359(2) 0.6587(3) 0.106(3) Uani 1 1 d . . .
H28A H 0.5636 0.2408 0.6219 0.159 Uiso 1 1 calc R . .
H28B H 0.6650 0.2338 0.6477 0.159 Uiso 1 1 calc R . .
H28C H 0.6162 0.2632 0.6866 0.159 Uiso 1 1 calc R . .
C29 C 0.6058(3) 0.1468(2) 0.6484(2) 0.0709(19) Uani 1 1 d . . .
H29A H 0.6018 0.1162 0.6688 0.106 Uiso 1 1 calc R . .
H29B H 0.6605 0.1483 0.6399 0.106 Uiso 1 1 calc R . .
H29C H 0.5587 0.1489 0.6101 0.106 Uiso 1 1 calc R . .
C30 C 0.6724(3) 0.18438(18) 0.7496(2) 0.0428(14) Uani 1 1 d . . .
C31 C 0.7505(4) 0.2065(2) 0.7630(2) 0.074(2) Uani 1 1 d . . .
H31 H 0.7684 0.2291 0.7384 0.089 Uiso 1 1 calc R . .
C32 C 0.7989(4) 0.1887(2) 0.8203(2) 0.077(2) Uani 1 1 d . . .
H32 H 0.8561 0.1974 0.8421 0.093 Uiso 1 1 calc R . .
C33 C 0.7485(3) 0.15654(17) 0.8391(2) 0.0372(13) Uani 1 1 d . . .
C34 C 0.7644(3) 0.13657(16) 0.8979(2) 0.0350(12) Uani 1 1 d . . .
H34 H 0.8196 0.1408 0.9265 0.042 Uiso 1 1 calc R . .
C35 C 0.7272(2) 0.10616(16) 0.97933(19) 0.0250(11) Uani 1 1 d . . .
C36 C 0.7582(2) 0.14562(16) 1.01819(19) 0.0298(12) Uani 1 1 d . . .
H36 H 0.7699 0.1750 1.0008 0.036 Uiso 1 1 calc R . .
C37 C 0.7728(3) 0.14414(16) 1.08062(19) 0.0284(11) Uani 1 1 d . . .
C38 C 0.8059(3) 0.18834(16) 1.11928(18) 0.0441(14) Uani 1 1 d . . .
H38A H 0.7704 0.1946 1.1455 0.066 Uiso 1 1 calc R . .
H38B H 0.8038 0.2164 1.0929 0.066 Uiso 1 1 calc R . .
H38C H 0.8651 0.1827 1.1446 0.066 Uiso 1 1 calc R . .
C39 C 0.7670(3) 0.09838(16) 1.17323(17) 0.0398(13) Uani 1 1 d . . .
H39A H 0.8239 0.1108 1.1957 0.060 Uiso 1 1 calc R . .
H39B H 0.7623 0.0645 1.1846 0.060 Uiso 1 1 calc R . .
H39C H 0.7234 0.1178 1.1832 0.060 Uiso 1 1 calc R . .
C40 C 0.7541(2) 0.10142(17) 1.10640(18) 0.0262(11) Uani 1 1 d . . .
C41 C 0.7233(2) 0.06235(16) 1.06824(18) 0.0274(11) Uani 1 1 d . . .
H41 H 0.7107 0.0333 1.0858 0.033 Uiso 1 1 calc R . .
C42 C 0.7097(2) 0.06305(15) 1.00581(18) 0.0217(10) Uani 1 1 d . . .
C43 C 0.5636(3) 0.1874(2) 0.9569(2) 0.0508(15) Uani 1 1 d . . .
H43 H 0.5452 0.1568 0.9669 0.061 Uiso 1 1 calc R . .
C44 C 0.5761(4) 0.2246(3) 0.9994(3) 0.079(2) Uani 1 1 d . . .
H44 H 0.5678 0.2197 1.0379 0.095 Uiso 1 1 calc R . .
C45 C 0.6007(5) 0.2681(3) 0.9832(4) 0.104(3) Uani 1 1 d . . .
H45 H 0.6088 0.2948 1.0104 0.125 Uiso 1 1 calc R . .
C46 C 0.6138(4) 0.2740(2) 0.9285(4) 0.087(2) Uani 1 1 d . . .
H46 H 0.6330 0.3041 0.9178 0.105 Uiso 1 1 calc R . .
C47 C 0.5987(3) 0.2356(2) 0.8891(3) 0.0533(16) Uani 1 1 d . . .
H47 H 0.6047 0.2402 0.8499 0.064 Uiso 1 1 calc R . .
C48 C 0.5634(3) 0.02107(17) 0.7472(2) 0.0363(13) Uani 1 1 d . . .
H48 H 0.6039 0.0137 0.7855 0.044 Uiso 1 1 calc R . .
C49 C 0.5580(3) -0.00993(17) 0.7002(2) 0.0397(13) Uani 1 1 d . . .
H49 H 0.5949 -0.0372 0.7056 0.048 Uiso 1 1 calc R . .
C50 C 0.4976(3) -0.00061(18) 0.6446(2) 0.0430(14) Uani 1 1 d . . .
H50 H 0.4924 -0.0212 0.6107 0.052 Uiso 1 1 calc R . .
C51 C 0.4457(3) 0.03874(19) 0.6394(2) 0.0450(14) Uani 1 1 d . . .
H51 H 0.4023 0.0455 0.6022 0.054 Uiso 1 1 calc R . .
C52 C 0.4572(3) 0.06861(18) 0.6892(2) 0.0496(15) Uani 1 1 d . . .
H52 H 0.4213 0.0962 0.6848 0.059 Uiso 1 1 calc R . .
C101 C 0.7992(3) 0.89255(16) 0.46788(18) 0.0268(11) Uani 1 1 d . . .
H101 H 0.7406 0.8847 0.4601 0.032 Uiso 1 1 calc R . .
C102 C 0.8577(3) 0.85562(16) 0.46663(18) 0.0267(11) Uani 1 1 d . . .
C103 C 0.8440(3) 0.80625(16) 0.45355(19) 0.0357(13) Uani 1 1 d . . .
H103 H 0.7908 0.7897 0.4427 0.043 Uiso 1 1 calc R . .
C104 C 0.9228(3) 0.78655(16) 0.45947(19) 0.0347(12) Uani 1 1 d . . .
H104 H 0.9341 0.7536 0.4530 0.042 Uiso 1 1 calc R . .
C105 C 0.9833(3) 0.82354(15) 0.47662(19) 0.0274(11) Uani 1 1 d . . .
C106 C 1.0800(3) 0.82121(15) 0.4915(2) 0.0315(12) Uani 1 1 d . . .
C107 C 1.1077(3) 0.85226(16) 0.44568(19) 0.0373(13) Uani 1 1 d . . .
H10A H 1.0913 0.8861 0.4487 0.056 Uiso 1 1 calc R . .
H10B H 1.0796 0.8403 0.4043 0.056 Uiso 1 1 calc R . .
H10C H 1.1699 0.8502 0.4547 0.056 Uiso 1 1 calc R . .
C108 C 1.1073(3) 0.76830(16) 0.4861(2) 0.0540(16) Uani 1 1 d . . .
H10D H 1.1693 0.7669 0.4944 0.081 Uiso 1 1 calc R . .
H10E H 1.0786 0.7563 0.4449 0.081 Uiso 1 1 calc R . .
H10F H 1.0911 0.7481 0.5157 0.081 Uiso 1 1 calc R . .
C109 C 1.1222(3) 0.83983(15) 0.5558(2) 0.0254(11) Uani 1 1 d . . .
C110 C 1.1797(3) 0.81542(16) 0.6058(2) 0.0357(13) Uani 1 1 d . . .
H110 H 1.2020 0.7836 0.6058 0.043 Uiso 1 1 calc R . .
C111 C 1.1971(3) 0.84687(16) 0.6544(2) 0.0307(12) Uani 1 1 d . . .
H111 H 1.2345 0.8412 0.6944 0.037 Uiso 1 1 calc R . .
C112 C 1.1494(3) 0.88847(15) 0.63383(19) 0.0224(11) Uani 1 1 d . . .
C113 C 1.1421(3) 0.93176(16) 0.66418(18) 0.0276(12) Uani 1 1 d . . .
H113 H 1.1716 0.9343 0.7065 0.033 Uiso 1 1 calc R . .
C114 C 1.0833(2) 1.00761(16) 0.67377(18) 0.0223(10) Uani 1 1 d . . .
C115 C 1.1082(2) 1.05350(16) 0.66263(18) 0.0272(11) Uani 1 1 d . . .
H115 H 1.1314 1.0579 0.6301 0.033 Uiso 1 1 calc R . .
C116 C 1.1006(3) 1.09337(17) 0.6969(2) 0.0352(12) Uani 1 1 d . . .
C117 C 1.1304(3) 1.14225(16) 0.6835(2) 0.0544(16) Uani 1 1 d . . .
H11A H 1.0809 1.1635 0.6669 0.082 Uiso 1 1 calc R . .
H11B H 1.1615 1.1388 0.6538 0.082 Uiso 1 1 calc R . .
H11C H 1.1684 1.1564 0.7212 0.082 Uiso 1 1 calc R . .
C118 C 1.0533(4) 1.12942(17) 0.7824(2) 0.0744(19) Uani 1 1 d . . .
H11D H 1.1092 1.1427 0.8054 0.112 Uiso 1 1 calc R . .
H11E H 1.0236 1.1182 0.8107 0.112 Uiso 1 1 calc R . .
H11F H 1.0191 1.1547 0.7559 0.112 Uiso 1 1 calc R . .
C119 C 1.0654(3) 1.08696(17) 0.7436(2) 0.0429(14) Uani 1 1 d . . .
C120 C 1.0395(3) 1.04105(17) 0.75377(19) 0.0392(13) Uani 1 1 d . . .
H120 H 1.0150 1.0371 0.7857 0.047 Uiso 1 1 calc R . .
C121 C 1.0468(3) 0.99985(16) 0.72026(18) 0.0278(11) Uani 1 1 d . . .
C122 C 1.0296(3) 0.94319(17) 0.7889(2) 0.0348(12) Uani 1 1 d . . .
H122 H 1.0730 0.9605 0.8185 0.042 Uiso 1 1 calc R . .
C123 C 0.9861(3) 0.90556(19) 0.8090(2) 0.0398(13) Uani 1 1 d . A .
C124 C 0.9988(4) 0.8889(2) 0.8678(2) 0.0724(19) Uani 1 1 d . . .
H124 H 1.0418 0.8990 0.9037 0.087 Uiso 1 1 calc R . .
C125 C 0.9365(4) 0.8546(2) 0.8636(3) 0.081(2) Uani 1 1 d . . .
H125 H 0.9282 0.8370 0.8966 0.098 Uiso 1 1 calc R . .
C126 C 0.8884(3) 0.85003(19) 0.8033(2) 0.0447(15) Uani 1 1 d . . .
C127 C 0.8178(3) 0.8135(2) 0.7759(3) 0.0536(16) Uani 1 1 d . . .
C128 C 0.8590(3) 0.76766(18) 0.7578(3) 0.093(2) Uani 1 1 d . . .
H12A H 0.8146 0.7434 0.7404 0.140 Uiso 1 1 calc R . .
H12B H 0.9014 0.7542 0.7939 0.140 Uiso 1 1 calc R . .
H12C H 0.8871 0.7765 0.7276 0.140 Uiso 1 1 calc R . .
C129 C 0.7768(3) 0.7982(2) 0.8246(2) 0.087(2) Uani 1 1 d . . .
H12D H 0.7504 0.8266 0.8371 0.130 Uiso 1 1 calc R . .
H12E H 0.8209 0.7849 0.8600 0.130 Uiso 1 1 calc R . .
H12F H 0.7330 0.7735 0.8077 0.130 Uiso 1 1 calc R . .
C130 C 0.7472(3) 0.83140(16) 0.7192(2) 0.0396(13) Uani 1 1 d . . .
C131 C 0.6616(3) 0.81558(17) 0.6989(2) 0.0491(15) Uani 1 1 d . . .
H131 H 0.6358 0.7933 0.7192 0.059 Uiso 1 1 calc R . .
C132 C 0.6224(3) 0.83809(17) 0.6447(2) 0.0430(14) Uani 1 1 d . . .
H132 H 0.5643 0.8347 0.6204 0.052 Uiso 1 1 calc R . .
C133 C 0.6843(3) 0.86716(16) 0.6317(2) 0.0324(12) Uani 1 1 d . A .
C134 C 0.6771(3) 0.89829(15) 0.5833(2) 0.0313(12) Uani 1 1 d . . .
H134 H 0.6221 0.9029 0.5545 0.038 Uiso 1 1 calc R . .
C135 C 0.7218(3) 0.96192(16) 0.53375(19) 0.0246(11) Uani 1 1 d . . .
C136 C 0.6634(2) 0.99649(16) 0.53961(17) 0.0273(11) Uani 1 1 d . . .
H136 H 0.6336 0.9906 0.5681 0.033 Uiso 1 1 calc R . .
C137 C 0.6462(3) 1.03882(16) 0.50651(18) 0.0250(11) Uani 1 1 d . . .
C138 C 0.5819(3) 1.07425(16) 0.51510(19) 0.0391(13) Uani 1 1 d . . .
H13A H 0.5502 1.0594 0.5401 0.059 Uiso 1 1 calc R . .
H13B H 0.5420 1.0831 0.4753 0.059 Uiso 1 1 calc R . .
H13C H 0.6114 1.1034 0.5355 0.059 Uiso 1 1 calc R . .
C139 C 0.6785(3) 1.09512(15) 0.43101(19) 0.0356(12) Uani 1 1 d . . .
H13D H 0.7158 1.0959 0.4053 0.053 Uiso 1 1 calc R . .
H13E H 0.6921 1.1225 0.4595 0.053 Uiso 1 1 calc R . .
H13F H 0.6187 1.0974 0.4054 0.053 Uiso 1 1 calc R . .
C140 C 0.6919(2) 1.04852(16) 0.46608(18) 0.0237(11) Uani 1 1 d . . .
C141 C 0.7504(2) 1.01461(16) 0.45972(17) 0.0237(11) Uani 1 1 d . . .
H141 H 0.7820 1.0214 0.4325 0.028 Uiso 1 1 calc R . .
C142 C 0.7650(2) 0.97118(16) 0.49117(18) 0.0229(11) Uani 1 1 d . . .
C143 C 0.8386(3) 1.0306(2) 0.6579(2) 0.0421(14) Uani 1 1 d . . .
H143 H 0.8574 1.0278 0.6231 0.051 Uiso 1 1 calc R . .
C144 C 0.8224(3) 1.07619(19) 0.6764(2) 0.0521(15) Uani 1 1 d . . .
H144 H 0.8285 1.1041 0.6541 0.063 Uiso 1 1 calc R . .
C145 C 0.7974(3) 1.0804(2) 0.7274(3) 0.0639(18) Uani 1 1 d . . .
H145 H 0.7870 1.1115 0.7415 0.077 Uiso 1 1 calc R . .
C146 C 0.7875(3) 1.0393(2) 0.7579(3) 0.0681(18) Uani 1 1 d . . .
H146 H 0.7704 1.0414 0.7935 0.082 Uiso 1 1 calc R . .
C147 C 0.8029(3) 0.9949(2) 0.7359(2) 0.0503(15) Uani 1 1 d . . .
H147 H 0.7945 0.9665 0.7567 0.060 Uiso 1 1 calc R . .
C200 C 0.8904(5) 0.9320(5) 0.0387(4) 0.146(4) Uani 1 1 d . . .
H200 H 0.8301 0.9284 0.0234 0.175 Uiso 1 1 calc R . .
C201 C 0.9430(8) 0.8932(4) 0.0379(5) 0.179(5) Uani 1 1 d . . .
H201 H 0.9179 0.8635 0.0202 0.215 Uiso 1 1 calc R . .
C202 C 1.0178(6) 0.8957(4) 0.0582(5) 0.158(5) Uani 1 1 d . . .
H202 H 1.0515 0.8673 0.0605 0.190 Uiso 1 1 calc R . .
C203 C 1.0542(6) 0.9359(5) 0.0773(5) 0.181(5) Uani 1 1 d . . .
H203 H 1.1148 0.9368 0.0884 0.217 Uiso 1 1 calc R . .
C204 C 1.0151(6) 0.9762(3) 0.0828(3) 0.118(3) Uani 1 1 d . . .
H204 H 1.0467 1.0042 0.1004 0.141 Uiso 1 1 calc R . .
N1 N 0.6758(2) 0.02113(12) 0.97140(14) 0.0231(9) Uani 1 1 d . . .
N2 N 0.5976(2) -0.04655(12) 0.88411(14) 0.0251(9) Uani 1 1 d . . .
N3 N 0.4166(2) -0.02731(13) 0.83403(14) 0.0265(9) Uani 1 1 d . . .
N4 N 0.3700(2) 0.05548(13) 0.88650(15) 0.0263(9) Uani 1 1 d . . .
N5 N 0.4072(2) 0.14379(12) 0.82819(16) 0.0289(9) Uani 1 1 d . . .
N6 N 0.4929(3) 0.17491(12) 0.74709(16) 0.0349(10) Uani 1 1 d . . .
N7 N 0.6695(2) 0.15297(12) 0.79467(16) 0.0307(10) Uani 1 1 d . . .
N8 N 0.7078(2) 0.11269(12) 0.91496(15) 0.0246(9) Uani 1 1 d . . .
N9 N 0.5760(2) 0.19217(15) 0.90335(18) 0.0381(11) Uani 1 1 d . . .
N10 N 0.5162(2) 0.06100(14) 0.74359(15) 0.0324(10) Uani 1 1 d . . .
N101 N 0.8241(2) 0.93731(13) 0.47947(14) 0.0243(9) Uani 1 1 d . . .
N102 N 0.9439(2) 0.86601(12) 0.48093(14) 0.0216(8) Uani 1 1 d . . .
N103 N 1.1041(2) 0.88418(12) 0.57291(15) 0.0223(9) Uani 1 1 d . . .
N104 N 1.0965(2) 0.96854(13) 0.63647(14) 0.0228(9) Uani 1 1 d . . .
N105 N 1.0130(2) 0.95532(12) 0.73158(15) 0.0268(9) Uani 1 1 d . A .
N106 N 0.9189(2) 0.88136(14) 0.76933(16) 0.0366(10) Uani 1 1 d . A .
N107 N 0.7612(2) 0.86266(13) 0.67821(19) 0.0392(11) Uani 1 1 d . A .
N108 N 0.7413(2) 0.92151(13) 0.57498(15) 0.0278(9) Uani 1 1 d . A .
N109 N 0.8287(2) 0.98974(14) 0.68719(17) 0.0368(10) Uani 1 1 d . A .
N200 N 0.9261(6) 0.9769(4) 0.0623(3) 0.158(3) Uani 1 1 d . . .
O1 O 0.53676(16) 0.05931(9) 0.88375(11) 0.0263(7) Uani 1 1 d . . .
O2 O 0.48850(15) -0.04322(8) 0.98015(10) 0.0196(7) Uani 1 1 d . . .
O3 O 0.93897(16) 0.92609(10) 0.59321(12) 0.0297(7) Uani 1 1 d . A .
O4 O 1.03776(15) 0.97134(9) 0.47414(11) 0.0205(7) Uani 1 1 d . . .
Eu1 Eu 0.558989(14) 0.121863(8) 0.831568(10) 0.02609(6) Uani 1 1 d . . .
Eu2 Eu 0.879455(14) 0.908600(8) 0.665166(10) 0.02888(6) Uani 1 1 d . . .
U1 U 0.512113(10) 0.006673(6) 0.928907(7) 0.02119(4) Uani 1 1 d . . .
U2 U 0.989028(10) 0.944799(6) 0.533147(7) 0.01921(4) Uani 1 1 d . . .
N110 N 0.9073(10) 0.8231(5) 0.6359(7) 0.043(4) Uani 0.481(7) 1 d PU A 1
C148 C 0.8502(7) 0.7873(4) 0.6176(5) 0.045(4) Uani 0.481(7) 1 d P A 1
H148 H 0.7914 0.7952 0.6085 0.054 Uiso 0.481(7) 1 calc PR A 1
C149 C 0.8711(9) 0.7406(4) 0.6112(5) 0.047(4) Uani 0.481(7) 1 d P A 1
H149 H 0.8285 0.7161 0.6022 0.057 Uiso 0.481(7) 1 calc PR A 1
C150 C 0.9530(17) 0.7293(8) 0.6177(13) 0.057(6) Uani 0.481(7) 1 d P A 1
H150 H 0.9690 0.6972 0.6110 0.069 Uiso 0.481(7) 1 calc PR A 1
C152 C 0.9875(11) 0.8126(7) 0.6435(11) 0.058(5) Uani 0.481(7) 1 d PU A 1
H152 H 1.0300 0.8372 0.6555 0.069 Uiso 0.481(7) 1 calc PR A 1
C151 C 1.0109(15) 0.7647(7) 0.6340(16) 0.073(7) Uani 0.481(7) 1 d P A 1
H151 H 1.0693 0.7575 0.6393 0.088 Uiso 0.481(7) 1 calc PR A 1
N111 N 0.9591(11) 0.8309(4) 0.6601(6) 0.043(3) Uani 0.519(7) 1 d PU A 2
C153 C 0.9294(14) 0.8039(6) 0.6117(6) 0.054(4) Uani 0.519(7) 1 d P A 2
H153 H 0.8914 0.8191 0.5768 0.065 Uiso 0.519(7) 1 calc PR A 2
C154 C 0.947(2) 0.7561(9) 0.6058(10) 0.073(7) Uani 0.519(7) 1 d P A 2
H154 H 0.9199 0.7382 0.5699 0.088 Uiso 0.519(7) 1 calc PR A 2
C156 C 1.0430(6) 0.7643(4) 0.7056(6) 0.054(4) Uani 0.519(7) 1 d P A 2
H156 H 1.0862 0.7517 0.7398 0.064 Uiso 0.519(7) 1 calc PR A 2
C155 C 1.0071(16) 0.7355(8) 0.6556(9) 0.065(5) Uani 0.519(7) 1 d P A 2
H155 H 1.0229 0.7024 0.6552 0.078 Uiso 0.519(7) 1 calc PR A 2
C157 C 1.0164(6) 0.8109(4) 0.7056(5) 0.043(3) Uani 0.519(7) 1 d P A 2
H157 H 1.0411 0.8299 0.7410 0.052 Uiso 0.519(7) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 121.8(4) . .
N1 C1 H1 119.1 . .
C2 C1 H1 119.1 . .
C3 C2 N2 110.4(4) . .
C3 C2 C1 132.2(4) . .
N2 C2 C1 117.4(4) . .
C2 C3 C4 106.6(4) . .
C2 C3 H3 126.7 . .
C4 C3 H3 126.7 . .
C3 C4 C5 107.3(4) . .
C3 C4 H4 126.4 . .
C5 C4 H4 126.4 . .
N2 C5 C4 110.4(4) . .
N2 C5 C6 120.5(4) . .
C4 C5 C6 129.2(4) . .
C9 C6 C8 110.6(4) . .
C9 C6 C5 108.8(4) . .
C8 C6 C5 110.1(3) . .
C9 C6 C7 110.1(3) . .
C8 C6 C7 108.6(4) . .
C5 C6 C7 108.6(3) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
N3 C9 C10 109.5(4) . .
N3 C9 C6 121.7(4) . .
C10 C9 C6 128.8(4) . .
C11 C10 C9 107.8(4) . .
C11 C10 H10 126.1 . .
C9 C10 H10 126.1 . .
C10 C11 C12 106.9(4) . .
C10 C11 H11 126.6 . .
C12 C11 H11 126.6 . .
C13 C12 N3 121.1(4) . .
C13 C12 C11 130.5(4) . .
N3 C12 C11 108.3(4) . .
N4 C13 C12 121.1(4) . .
N4 C13 H13 119.4 . .
C12 C13 H13 119.4 . .
C21 C14 C15 118.7(4) . .
C21 C14 N4 121.6(4) . .
C15 C14 N4 119.7(4) . .
C16 C15 C14 122.5(4) . .
C16 C15 H15 118.8 . .
C14 C15 H15 118.8 . .
C15 C16 C19 119.0(5) . .
C15 C16 C17 121.0(4) . .
C19 C16 C17 120.0(4) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C19 C18 H18A 109.5 . .
C19 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C19 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C16 C19 C20 118.6(5) . .
C16 C19 C18 121.7(5) . .
C20 C19 C18 119.6(5) . .
C19 C20 C21 123.4(5) . .
C19 C20 H20 118.3 . .
C21 C20 H20 118.3 . .
C20 C21 C14 117.7(4) . .
C20 C21 N5 118.2(4) . .
C14 C21 N5 123.5(4) . .
N5 C22 C23 122.5(4) . .
N5 C22 Eu1 46.4(2) . .
C23 C22 Eu1 76.0(3) . .
N5 C22 H22 118.8 . .
C23 C22 H22 118.8 . .
Eu1 C22 H22 165.2 . .
N6 C23 C24 109.1(5) . .
N6 C23 C22 120.1(4) . .
C24 C23 C22 130.8(5) . .
N6 C23 Eu1 42.8(2) . .
C24 C23 Eu1 148.2(4) . .
C22 C23 Eu1 78.9(3) . .
C25 C24 C23 107.5(5) . .
C25 C24 H24 126.3 . .
C23 C24 H24 126.3 . .
C24 C25 C26 106.5(5) . .
C24 C25 H25 126.7 . .
C26 C25 H25 126.7 . .
N6 C26 C25 110.7(5) . .
N6 C26 C27 124.0(5) . .
C25 C26 C27 125.2(5) . .
C28 C27 C30 108.7(5) . .
C28 C27 C26 108.2(4) . .
C30 C27 C26 114.2(4) . .
C28 C27 C29 108.1(4) . .
C30 C27 C29 108.5(4) . .
C26 C27 C29 109.1(4) . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
N7 C30 C31 111.3(5) . .
N7 C30 C27 123.0(5) . .
C31 C30 C27 125.4(5) . .
C30 C31 C32 105.9(5) . .
C30 C31 H31 127.0 . .
C32 C31 H31 127.0 . .
C33 C32 C31 107.6(5) . .
C33 C32 H32 126.2 . .
C31 C32 H32 126.2 . .
C32 C33 N7 109.3(4) . .
C32 C33 C34 127.4(5) . .
N7 C33 C34 122.3(4) . .
C32 C33 Eu1 147.8(4) . .
N7 C33 Eu1 43.0(2) . .
C34 C33 Eu1 79.8(3) . .
N8 C34 C33 123.7(4) . .
N8 C34 H34 118.2 . .
C33 C34 H34 118.2 . .
C36 C35 C42 117.4(4) . .
C36 C35 N8 119.1(4) . .
C42 C35 N8 123.2(4) . .
C37 C36 C35 123.6(4) . .
C37 C36 H36 118.2 . .
C35 C36 H36 118.2 . .
C36 C37 C40 118.6(4) . .
C36 C37 C38 120.4(4) . .
C40 C37 C38 121.0(4) . .
C37 C38 H38A 109.5 . .
C37 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
C37 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C40 C39 H39A 109.5 . .
C40 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C40 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
C41 C40 C37 118.0(4) . .
C41 C40 C39 121.4(4) . .
C37 C40 C39 120.6(4) . .
C40 C41 C42 124.0(4) . .
C40 C41 H41 118.0 . .
C42 C41 H41 118.0 . .
C41 C42 C35 118.3(4) . .
C41 C42 N1 118.7(4) . .
C35 C42 N1 123.0(4) . .
N9 C43 C44 123.9(6) . .
N9 C43 H43 118.1 . .
C44 C43 H43 118.1 . .
C45 C44 C43 116.6(7) . .
C45 C44 H44 121.7 . .
C43 C44 H44 121.7 . .
C46 C45 C44 120.7(7) . .
C46 C45 H45 119.7 . .
C44 C45 H45 119.7 . .
C45 C46 C47 118.7(7) . .
C45 C46 H46 120.7 . .
C47 C46 H46 120.7 . .
N9 C47 C46 122.7(6) . .
N9 C47 H47 118.7 . .
C46 C47 H47 118.7 . .
N10 C48 C49 125.2(4) . .
N10 C48 H48 117.4 . .
C49 C48 H48 117.4 . .
C48 C49 C50 118.2(5) . .
C48 C49 H49 120.9 . .
C50 C49 H49 120.9 . .
C51 C50 C49 118.6(5) . .
C51 C50 H50 120.7 . .
C49 C50 H50 120.7 . .
C50 C51 C52 118.9(5) . .
C50 C51 H51 120.6 . .
C52 C51 H51 120.6 . .
N10 C52 C51 123.9(5) . .
N10 C52 H52 118.0 . .
C51 C52 H52 118.0 . .
N101 C101 C102 121.1(4) . .
N101 C101 H101 119.4 . .
C102 C101 H101 119.4 . .
N102 C102 C103 109.8(4) . .
N102 C102 C101 120.1(4) . .
C103 C102 C101 130.1(4) . .
C104 C103 C102 106.2(4) . .
C104 C103 H103 126.9 . .
C102 C103 H103 126.9 . .
C103 C104 C105 107.9(4) . .
C103 C104 H104 126.0 . .
C105 C104 H104 126.0 . .
N102 C105 C104 109.7(4) . .
N102 C105 C106 120.6(4) . .
C104 C105 C106 129.6(4) . .
C109 C106 C105 109.5(4) . .
C109 C106 C107 110.0(4) . .
C105 C106 C107 109.5(4) . .
C109 C106 C108 110.1(4) . .
C105 C106 C108 109.4(4) . .
C107 C106 C108 108.4(4) . .
C106 C107 H10A 109.5 . .
C106 C107 H10B 109.5 . .
H10A C107 H10B 109.5 . .
C106 C107 H10C 109.5 . .
H10A C107 H10C 109.5 . .
H10B C107 H10C 109.5 . .
C106 C108 H10D 109.5 . .
C106 C108 H10E 109.5 . .
H10D C108 H10E 109.5 . .
C106 C108 H10F 109.5 . .
H10D C108 H10F 109.5 . .
H10E C108 H10F 109.5 . .
N103 C109 C110 110.2(4) . .
N103 C109 C106 121.2(4) . .
C110 C109 C106 128.5(4) . .
C111 C110 C109 106.4(4) . .
C111 C110 H110 126.8 . .
C109 C110 H110 126.8 . .
C110 C111 C112 106.8(4) . .
C110 C111 H111 126.6 . .
C112 C111 H111 126.6 . .
N103 C112 C111 110.3(4) . .
N103 C112 C113 118.6(4) . .
C111 C112 C113 131.0(4) . .
N104 C113 C112 122.6(4) . .
N104 C113 H113 118.7 . .
C112 C113 H113 118.7 . .
C115 C114 C121 120.4(4) . .
C115 C114 N104 117.8(4) . .
C121 C114 N104 121.7(4) . .
C114 C115 C116 122.6(4) . .
C114 C115 H115 118.7 . .
C116 C115 H115 118.7 . .
C115 C116 C119 118.6(4) . .
C115 C116 C117 120.2(4) . .
C119 C116 C117 121.2(4) . .
C116 C117 H11A 109.5 . .
C116 C117 H11B 109.5 . .
H11A C117 H11B 109.5 . .
C116 C117 H11C 109.5 . .
H11A C117 H11C 109.5 . .
H11B C117 H11C 109.5 . .
C119 C118 H11D 109.5 . .
C119 C118 H11E 109.5 . .
H11D C118 H11E 109.5 . .
C119 C118 H11F 109.5 . .
H11D C118 H11F 109.5 . .
H11E C118 H11F 109.5 . .
C120 C119 C116 118.5(4) . .
C120 C119 C118 120.0(5) . .
C116 C119 C118 121.5(5) . .
C119 C120 C121 124.4(4) . .
C119 C120 H120 117.8 . .
C121 C120 H120 117.8 . .
C114 C121 C120 115.5(4) . .
C114 C121 N105 124.4(4) . .
C120 C121 N105 119.9(4) . .
N105 C122 C123 123.4(4) . .
N105 C122 H122 118.3 . .
C123 C122 H122 118.3 . .
N106 C123 C124 109.8(5) . .
N106 C123 C122 121.4(4) . .
C124 C123 C122 128.8(5) . .
N106 C123 Eu2 42.2(2) . .
C124 C123 Eu2 151.8(4) . .
C122 C123 Eu2 79.2(3) . .
C125 C124 C123 106.1(5) . .
C125 C124 H124 127.0 . .
C123 C124 H124 127.0 . .
C124 C125 C126 108.4(5) . .
C124 C125 H125 125.8 . .
C126 C125 H125 125.8 . .
N106 C126 C125 108.9(5) . .
N106 C126 C127 123.5(5) . .
C125 C126 C127 127.3(5) . .
C126 C127 C130 114.7(4) . .
C126 C127 C129 109.2(5) . .
C130 C127 C129 109.0(4) . .
C126 C127 C128 108.1(4) . .
C130 C127 C128 108.0(5) . .
C129 C127 C128 107.6(4) . .
C127 C128 H12A 109.5 . .
C127 C128 H12B 109.5 . .
H12A C128 H12B 109.5 . .
C127 C128 H12C 109.5 . .
H12A C128 H12C 109.5 . .
H12B C128 H12C 109.5 . .
C127 C129 H12D 109.5 . .
C127 C129 H12E 109.5 . .
H12D C129 H12E 109.5 . .
C127 C129 H12F 109.5 . .
H12D C129 H12F 109.5 . .
H12E C129 H12F 109.5 . .
N107 C130 C131 109.6(5) . .
N107 C130 C127 123.7(5) . .
C131 C130 C127 126.5(5) . .
C132 C131 C130 107.6(5) . .
C132 C131 H131 126.2 . .
C130 C131 H131 126.2 . .
C131 C132 C133 106.8(5) . .
C131 C132 H132 126.6 . .
C133 C132 H132 126.6 . .
C134 C133 N107 120.6(4) . .
C134 C133 C132 130.0(5) . .
N107 C133 C132 109.4(4) . .
C134 C133 Eu2 78.7(3) . .
N107 C133 Eu2 41.9(2) . .
C132 C133 Eu2 151.3(4) . .
N108 C134 C133 123.7(4) . .
N108 C134 H134 118.1 . .
C133 C134 H134 118.1 . .
C136 C135 C142 117.3(4) . .
C136 C135 N108 119.1(4) . .
C142 C135 N108 123.3(4) . .
C137 C136 C135 123.8(4) . .
C137 C136 H136 118.1 . .
C135 C136 H136 118.1 . .
C136 C137 C140 118.4(4) . .
C136 C137 C138 120.7(4) . .
C140 C137 C138 120.9(4) . .
C137 C138 H13A 109.5 . .
C137 C138 H13B 109.5 . .
H13A C138 H13B 109.5 . .
C137 C138 H13C 109.5 . .
H13A C138 H13C 109.5 . .
H13B C138 H13C 109.5 . .
C140 C139 H13D 109.5 . .
C140 C139 H13E 109.5 . .
H13D C139 H13E 109.5 . .
C140 C139 H13F 109.5 . .
H13D C139 H13F 109.5 . .
H13E C139 H13F 109.5 . .
C141 C140 C137 118.7(4) . .
C141 C140 C139 120.9(4) . .
C137 C140 C139 120.5(4) . .
C140 C141 C142 122.9(4) . .
C140 C141 H141 118.6 . .
C142 C141 H141 118.6 . .
C141 C142 C135 118.9(4) . .
C141 C142 N101 118.8(4) . .
C135 C142 N101 122.3(4) . .
N109 C143 C144 122.7(5) . .
N109 C143 H143 118.6 . .
C144 C143 H143 118.6 . .
C145 C144 C143 118.8(5) . .
C145 C144 H144 120.6 . .
C143 C144 H144 120.6 . .
C144 C145 C146 119.2(5) . .
C144 C145 H145 120.4 . .
C146 C145 H145 120.4 . .
C145 C146 C147 118.7(5) . .
C145 C146 H146 120.6 . .
C147 C146 H146 120.6 . .
N109 C147 C146 123.4(5) . .
N109 C147 H147 118.3 . .
C146 C147 H147 118.3 . .
C201 C200 N200 120.1(9) . .
C201 C200 H200 120.0 . .
N200 C200 H200 120.0 . .
C202 C201 C200 122.2(12) . .
C202 C201 H201 118.9 . .
C200 C201 H201 118.9 . .
C201 C202 C203 120.6(11) . .
C201 C202 H202 119.7 . .
C203 C202 H202 119.7 . .
C202 C203 C204 125.5(10) . .
C202 C203 H203 117.2 . .
C204 C203 H203 117.2 . .
C203 C204 N200 118.4(9) . .
C203 C204 H204 120.8 . .
N200 C204 H204 120.8 . .
C1 N1 C42 117.8(4) . .
C1 N1 U1 113.4(3) . .
C42 N1 U1 121.3(2) . .
C5 N2 C2 105.4(3) . .
C5 N2 U1 134.9(3) . .
C2 N2 U1 117.6(3) . .
C9 N3 C12 107.5(3) . .
C9 N3 U1 134.2(3) . .
C12 N3 U1 113.9(3) . .
C13 N4 C14 116.4(4) . .
C13 N4 U1 111.3(3) . .
C14 N4 U1 123.6(2) . .
C22 N5 C21 116.6(4) . .
C22 N5 Eu1 111.9(3) . .
C21 N5 Eu1 129.1(3) . .
C26 N6 C23 106.2(4) . .
C26 N6 Eu1 136.1(3) . .
C23 N6 Eu1 114.4(3) . .
C30 N7 C33 105.9(4) . .
C30 N7 Eu1 135.1(3) . .
C33 N7 Eu1 113.7(3) . .
C34 N8 C35 115.5(4) . .
C34 N8 Eu1 108.8(3) . .
C35 N8 Eu1 129.3(3) . .
C43 N9 C47 117.4(5) . .
C43 N9 Eu1 121.6(4) . .
C47 N9 Eu1 121.0(3) . .
C48 N10 C52 115.1(4) . .
C48 N10 Eu1 118.8(3) . .
C52 N10 Eu1 125.4(3) . .
C101 N101 C142 117.9(4) . .
C101 N101 U2 112.7(3) . .
C142 N101 U2 121.6(2) . .
C105 N102 C102 106.3(4) . .
C105 N102 U2 135.5(3) . .
C102 N102 U2 115.3(3) . .
C109 N103 C112 106.2(3) . .
C109 N103 U2 135.8(3) . .
C112 N103 U2 115.4(3) . .
C113 N104 C114 117.4(3) . .
C113 N104 U2 112.4(3) . .
C114 N104 U2 123.9(2) . .
C122 N105 C121 116.2(4) . .
C122 N105 Eu2 110.1(3) . .
C121 N105 Eu2 129.4(3) . .
C126 N106 C123 106.8(4) . .
C126 N106 Eu2 137.7(4) . .
C123 N106 Eu2 115.3(3) . .
C130 N107 C133 106.6(4) . .
C130 N107 Eu2 137.7(3) . .
C133 N107 Eu2 115.6(3) . .
C134 N108 C135 117.1(4) . .
C134 N108 Eu2 111.3(3) . .
C135 N108 Eu2 126.9(3) . .
C147 N109 C143 117.1(4) . .
C147 N109 Eu2 119.0(4) . .
C143 N109 Eu2 123.1(3) . .
C204 N200 C200 112.7(8) . .
U1 O1 Eu1 177.04(14) . .
U1 O2 U1 107.60(10) . 3_657
U2 O3 Eu2 176.68(15) . .
U2 O4 U2 108.31(10) . 3_776
O1 Eu1 N7 138.61(11) . .
O1 Eu1 N6 144.07(11) . .
N7 Eu1 N6 72.28(13) . .
O1 Eu1 N9 104.30(12) . .
N7 Eu1 N9 91.01(12) . .
N6 Eu1 N9 89.76(12) . .
O1 Eu1 N5 82.78(10) . .
N7 Eu1 N5 138.59(12) . .
N6 Eu1 N5 68.91(13) . .
N9 Eu1 N5 75.15(11) . .
O1 Eu1 N10 82.50(10) . .
N7 Eu1 N10 90.21(11) . .
N6 Eu1 N10 79.15(12) . .
N9 Eu1 N10 167.89(12) . .
N5 Eu1 N10 96.13(11) . .
O1 Eu1 N8 78.30(10) . .
N7 Eu1 N8 69.91(12) . .
N6 Eu1 N8 137.62(12) . .
N9 Eu1 N8 72.62(11) . .
N5 Eu1 N8 136.87(11) . .
N10 Eu1 N8 119.00(11) . .
O1 Eu1 C33 121.84(11) . .
N7 Eu1 C33 23.26(11) . .
N6 Eu1 C33 92.81(13) . .
N9 Eu1 C33 80.05(12) . .
N5 Eu1 C33 148.92(11) . .
N10 Eu1 C33 105.10(11) . .
N8 Eu1 C33 47.06(11) . .
O1 Eu1 C23 123.18(12) . .
N7 Eu1 C23 94.99(13) . .
N6 Eu1 C23 22.73(12) . .
N9 Eu1 C23 88.29(12) . .
N5 Eu1 C23 46.80(12) . .
N10 Eu1 C23 79.60(12) . .
N8 Eu1 C23 154.94(12) . .
C33 Eu1 C23 114.83(13) . .
O1 Eu1 C22 101.85(11) . .
N7 Eu1 C22 118.68(12) . .
N6 Eu1 C22 47.34(12) . .
N9 Eu1 C22 80.48(11) . .
N5 Eu1 C22 21.72(11) . .
N10 Eu1 C22 88.37(11) . .
N8 Eu1 C22 152.10(10) . .
C33 Eu1 C22 135.29(12) . .
C23 Eu1 C22 25.08(10) . .
O1 Eu1 U1 1.37(7) . .
N7 Eu1 U1 139.98(9) . .
N6 Eu1 U1 143.09(10) . .
N9 Eu1 U1 103.73(10) . .
N5 Eu1 U1 81.42(8) . .
N10 Eu1 U1 82.85(8) . .
N8 Eu1 U1 79.25(8) . .
C33 Eu1 U1 123.06(9) . .
C23 Eu1 U1 122.02(10) . .
C22 Eu1 U1 100.55(9) . .
O3 Eu2 N106 140.19(11) . .
O3 Eu2 N107 139.78(12) . .
N106 Eu2 N107 71.90(14) . .
O3 Eu2 N109 102.15(12) . .
N106 Eu2 N109 94.53(12) . .
N107 Eu2 N109 96.39(12) . .
O3 Eu2 N111 78.2(3) . .
N106 Eu2 N111 78.5(3) . .
N107 Eu2 N111 90.6(3) . .
N109 Eu2 N111 168.1(4) . .
O3 Eu2 N110 81.1(3) . .
N106 Eu2 N110 87.8(3) . .
N107 Eu2 N110 76.4(3) . .
N109 Eu2 N110 171.4(4) . .
N111 Eu2 N110 20.2(3) . .
O3 Eu2 N108 81.31(10) . .
N106 Eu2 N108 138.07(12) . .
N107 Eu2 N108 68.48(12) . .
N109 Eu2 N108 76.99(11) . .
N111 Eu2 N108 114.6(4) . .
N110 Eu2 N108 95.7(4) . .
O3 Eu2 N105 81.16(10) . .
N106 Eu2 N105 69.45(12) . .
N107 Eu2 N105 138.75(12) . .
N109 Eu2 N105 73.12(11) . .
N111 Eu2 N105 95.3(4) . .
N110 Eu2 N105 115.4(4) . .
N108 Eu2 N105 141.04(11) . .
O3 Eu2 C123 123.20(11) . .
N106 Eu2 C123 22.47(12) . .
N107 Eu2 C123 93.34(14) . .
N109 Eu2 C123 85.56(12) . .
N111 Eu2 C123 84.4(3) . .
N110 Eu2 C123 99.5(4) . .
N108 Eu2 C123 152.81(11) . .
N105 Eu2 C123 47.03(12) . .
O3 Eu2 C133 121.80(11) . .
N106 Eu2 C133 93.81(13) . .
N107 Eu2 C133 22.51(11) . .
N109 Eu2 C133 89.73(11) . .
N111 Eu2 C133 100.2(4) . .
N110 Eu2 C133 81.8(4) . .
N108 Eu2 C133 45.97(11) . .
N105 Eu2 C133 154.40(11) . .
C123 Eu2 C133 114.32(13) . .
O3 Eu2 U2 1.53(7) . .
N106 Eu2 U2 140.46(9) . .
N107 Eu2 U2 140.68(10) . .
N109 Eu2 U2 100.65(10) . .
N111 Eu2 U2 79.6(2) . .
N110 Eu2 U2 82.6(3) . .
N108 Eu2 U2 81.21(8) . .
N105 Eu2 U2 80.38(7) . .
C123 Eu2 U2 122.95(9) . .
C133 Eu2 U2 122.28(8) . .
O1 U1 O2 175.42(10) . .
O1 U1 O2 103.04(10) . 3_657
O2 U1 O2 72.40(10) . 3_657
O1 U1 N3 89.30(11) . .
O2 U1 N3 94.63(10) . .
O2 U1 N3 142.13(10) 3_657 .
O1 U1 N2 88.70(11) . .
O2 U1 N2 94.75(10) . .
O2 U1 N2 142.75(9) 3_657 .
N3 U1 N2 71.84(11) . .
O1 U1 N1 73.58(10) . .
O2 U1 N1 105.09(10) . .
O2 U1 N1 83.54(9) 3_657 .
N3 U1 N1 134.28(11) . .
N2 U1 N1 65.85(11) . .
O1 U1 N4 73.72(10) . .
O2 U1 N4 105.66(10) . .
O2 U1 N4 82.01(9) 3_657 .
N3 U1 N4 67.14(11) . .
N2 U1 N4 135.15(10) . .
N1 U1 N4 139.99(11) . .
O1 U1 U1 135.30(8) . 3_657
O2 U1 U1 40.14(7) . 3_657
O2 U1 U1 32.26(6) 3_657 3_657
N3 U1 U1 125.39(8) . 3_657
N2 U1 U1 125.78(7) . 3_657
N1 U1 U1 94.00(7) . 3_657
N4 U1 U1 93.28(7) . 3_657
O1 U1 Eu1 1.59(8) . .
O2 U1 Eu1 174.64(7) . .
O2 U1 Eu1 102.33(6) 3_657 .
N3 U1 Eu1 89.04(8) . .
N2 U1 Eu1 90.10(8) . .
N1 U1 Eu1 74.84(7) . .
N4 U1 Eu1 72.18(7) . .
U1 U1 Eu1 134.581(8) 3_657 .
O3 U2 O4 173.51(11) . .
O3 U2 O4 101.89(10) . 3_776
O4 U2 O4 71.69(10) . 3_776
O3 U2 N103 90.03(11) . .
O4 U2 N103 94.63(10) . .
O4 U2 N103 142.65(10) 3_776 .
O3 U2 N102 89.16(11) . .
O4 U2 N102 96.64(10) . .
O4 U2 N102 143.59(10) 3_776 .
N103 U2 N102 70.63(11) . .
O3 U2 N104 73.70(10) . .
O4 U2 N104 104.04(10) . .
O4 U2 N104 82.85(10) 3_776 .
N103 U2 N104 66.59(11) . .
N102 U2 N104 133.48(11) . .
O3 U2 N101 72.69(11) . .
O4 U2 N101 107.02(10) . .
O4 U2 N101 84.27(10) 3_776 .
N103 U2 N101 133.01(11) . .
N102 U2 N101 65.90(11) . .
N104 U2 N101 140.46(10) . .
O3 U2 U2 133.65(8) . 3_776
O4 U2 U2 39.93(7) . 3_776
O4 U2 U2 31.76(6) 3_776 3_776
N103 U2 U2 125.60(7) . 3_776
N102 U2 U2 127.46(7) . 3_776
N104 U2 U2 92.89(8) . 3_776
N101 U2 U2 95.44(8) . 3_776
O3 U2 Eu2 1.80(8) . .
O4 U2 Eu2 171.72(7) . .
O4 U2 Eu2 100.14(6) 3_776 .
N103 U2 Eu2 91.24(7) . .
N102 U2 Eu2 90.81(7) . .
N104 U2 Eu2 72.99(7) . .
N101 U2 Eu2 72.77(7) . .
U2 U2 Eu2 131.887(8) 3_776 .
C152 N110 C148 117.3(17) . .
C152 N110 Eu2 115.4(17) . .
C148 N110 Eu2 127.2(9) . .
N110 C148 C149 124.0(11) . .
N110 C148 H148 118.0 . .
C149 C148 H148 118.0 . .
C150 C149 C148 119.3(15) . .
C150 C149 H149 120.3 . .
C148 C149 H149 120.3 . .
C151 C150 C149 118(2) . .
C151 C150 H150 121.2 . .
C149 C150 H150 121.2 . .
N110 C152 C151 120(2) . .
N110 C152 H152 120.1 . .
C151 C152 H152 120.1 . .
C150 C151 C152 122(2) . .
C150 C151 H151 119.2 . .
C152 C151 H151 119.2 . .
C157 N111 C153 115.8(15) . .
C157 N111 Eu2 125.3(9) . .
C153 N111 Eu2 117.5(16) . .
N111 C153 C154 127.1(18) . .
N111 C153 H153 116.5 . .
C154 C153 H153 116.5 . .
C153 C154 C155 116(2) . .
C153 C154 H154 122.2 . .
C155 C154 H154 122.2 . .
C157 C156 C155 119.5(12) . .
C157 C156 H156 120.2 . .
C155 C156 H156 120.2 . .
C156 C155 C154 118(2) . .
C156 C155 H155 121.0 . .
C154 C155 H155 121.0 . .
N111 C157 C156 123.7(11) . .
N111 C157 H157 118.1 . .
C156 C157 H157 118.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.308(5) .
C1 C2 1.421(5) .
C1 H1 0.9500 .
C2 C3 1.383(5) .
C2 N2 1.390(5) .
C3 C4 1.385(5) .
C3 H3 0.9500 .
C4 C5 1.390(5) .
C4 H4 0.9500 .
C5 N2 1.364(5) .
C5 C6 1.531(5) .
C6 C9 1.504(6) .
C6 C8 1.530(5) .
C6 C7 1.536(5) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 N3 1.353(5) .
C9 C10 1.406(5) .
C10 C11 1.383(6) .
C10 H10 0.9500 .
C11 C12 1.412(5) .
C11 H11 0.9500 .
C12 C13 1.398(5) .
C12 N3 1.401(5) .
C13 N4 1.314(4) .
C13 H13 0.9500 .
C14 C21 1.398(6) .
C14 C15 1.404(5) .
C14 N4 1.431(5) .
C15 C16 1.383(6) .
C15 H15 0.9500 .
C16 C19 1.387(6) .
C16 C17 1.495(5) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 C19 1.505(6) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C20 1.388(6) .
C20 C21 1.393(5) .
C20 H20 0.9500 .
C21 N5 1.426(5) .
C22 N5 1.302(5) .
C22 C23 1.410(6) .
C22 Eu1 3.264(4) .
C22 H22 0.9500 .
C23 N6 1.370(5) .
C23 C24 1.399(6) .
C23 Eu1 3.229(5) .
C24 C25 1.358(7) .
C24 H24 0.9500 .
C25 C26 1.391(6) .
C25 H25 0.9500 .
C26 N6 1.351(5) .
C26 C27 1.528(7) .
C27 C28 1.517(6) .
C27 C30 1.526(6) .
C27 C29 1.531(6) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 N7 1.366(5) .
C30 C31 1.369(6) .
C31 C32 1.405(7) .
C31 H31 0.9500 .
C32 C33 1.374(6) .
C32 H32 0.9500 .
C33 N7 1.386(5) .
C33 C34 1.412(6) .
C33 Eu1 3.214(5) .
C34 N8 1.299(5) .
C34 H34 0.9500 .
C35 C36 1.402(5) .
C35 C42 1.407(5) .
C35 N8 1.433(5) .
C36 C37 1.388(5) .
C36 H36 0.9500 .
C37 C40 1.398(5) .
C37 C38 1.509(5) .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 C40 1.494(5) .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 C41 1.385(5) .
C41 C42 1.390(5) .
C41 H41 0.9500 .
C42 N1 1.416(5) .
C43 N9 1.322(5) .
C43 C44 1.390(7) .
C43 H43 0.9500 .
C44 C45 1.357(8) .
C44 H44 0.9500 .
C45 C46 1.357(8) .
C45 H45 0.9500 .
C46 C47 1.369(7) .
C46 H46 0.9500 .
C47 N9 1.326(6) .
C47 H47 0.9500 .
C48 N10 1.335(5) .
C48 C49 1.363(5) .
C48 H48 0.9500 .
C49 C50 1.383(5) .
C49 H49 0.9500 .
C50 C51 1.363(6) .
C50 H50 0.9500 .
C51 C52 1.379(6) .
C51 H51 0.9500 .
C52 N10 1.344(5) .
C52 H52 0.9500 .
C101 N101 1.302(5) .
C101 C102 1.408(5) .
C101 H101 0.9500 .
C102 N102 1.383(5) .
C102 C103 1.398(5) .
C103 C104 1.374(5) .
C103 H103 0.9500 .
C104 C105 1.394(5) .
C104 H104 0.9500 .
C105 N102 1.358(5) .
C105 C106 1.521(6) .
C106 C109 1.520(5) .
C106 C107 1.537(5) .
C106 C108 1.543(5) .
C107 H10A 0.9800 .
C107 H10B 0.9800 .
C107 H10C 0.9800 .
C108 H10D 0.9800 .
C108 H10E 0.9800 .
C108 H10F 0.9800 .
C109 N103 1.348(5) .
C109 C110 1.416(5) .
C110 C111 1.378(5) .
C110 H110 0.9500 .
C111 C112 1.388(5) .
C111 H111 0.9500 .
C112 N103 1.378(5) .
C112 C113 1.408(5) .
C113 N104 1.305(5) .
C113 H113 0.9500 .
C114 C115 1.379(5) .
C114 C121 1.400(5) .
C114 N104 1.438(5) .
C115 C116 1.383(5) .
C115 H115 0.9500 .
C116 C119 1.385(6) .
C116 C117 1.500(6) .
C117 H11A 0.9800 .
C117 H11B 0.9800 .
C117 H11C 0.9800 .
C118 C119 1.526(6) .
C118 H11D 0.9800 .
C118 H11E 0.9800 .
C118 H11F 0.9800 .
C119 C120 1.380(6) .
C120 C121 1.402(5) .
C120 H120 0.9500 .
C121 N105 1.407(5) .
C122 N105 1.310(5) .
C122 C123 1.419(6) .
C122 H122 0.9500 .
C123 N106 1.370(5) .
C123 C124 1.387(6) .
C123 Eu2 3.242(5) .
C124 C125 1.375(7) .
C124 H124 0.9500 .
C125 C126 1.378(7) .
C125 H125 0.9500 .
C126 N106 1.364(5) .
C126 C127 1.519(7) .
C127 C130 1.538(6) .
C127 C129 1.539(6) .
C127 C128 1.552(6) .
C128 H12A 0.9800 .
C128 H12B 0.9800 .
C128 H12C 0.9800 .
C129 H12D 0.9800 .
C129 H12E 0.9800 .
C129 H12F 0.9800 .
C130 N107 1.352(5) .
C130 C131 1.408(6) .
C131 C132 1.367(6) .
C131 H131 0.9500 .
C132 C133 1.399(6) .
C132 H132 0.9500 .
C133 C134 1.387(6) .
C133 N107 1.388(5) .
C133 Eu2 3.267(5) .
C134 N108 1.301(5) .
C134 H134 0.9500 .
C135 C136 1.390(5) .
C135 C142 1.404(5) .
C135 N108 1.436(5) .
C136 C137 1.376(5) .
C136 H136 0.9500 .
C137 C140 1.395(5) .
C137 C138 1.499(5) .
C138 H13A 0.9800 .
C138 H13B 0.9800 .
C138 H13C 0.9800 .
C139 C140 1.499(5) .
C139 H13D 0.9800 .
C139 H13E 0.9800 .
C139 H13F 0.9800 .
C140 C141 1.382(5) .
C141 C142 1.383(5) .
C141 H141 0.9500 .
C142 N101 1.434(5) .
C143 N109 1.350(5) .
C143 C144 1.381(6) .
C143 H143 0.9500 .
C144 C145 1.369(6) .
C144 H144 0.9500 .
C145 C146 1.371(7) .
C145 H145 0.9500 .
C146 C147 1.380(7) .
C146 H146 0.9500 .
C147 N109 1.330(5) .
C147 H147 0.9500 .
C200 C201 1.380(12) .
C200 N200 1.406(10) .
C200 H200 0.9500 .
C201 C202 1.175(10) .
C201 H201 0.9500 .
C202 C203 1.273(10) .
C202 H202 0.9500 .
C203 C204 1.310(9) .
C203 H203 0.9500 .
C204 N200 1.392(8) .
C204 H204 0.9500 .
N1 U1 2.594(3) .
N2 U1 2.473(3) .
N3 U1 2.452(3) .
N4 U1 2.611(3) .
N5 Eu1 2.548(3) .
N6 Eu1 2.411(3) .
N7 Eu1 2.395(3) .
N8 Eu1 2.615(3) .
N9 Eu1 2.511(4) .
N10 Eu1 2.561(3) .
N101 U2 2.618(3) .
N102 U2 2.485(3) .
N103 U2 2.478(3) .
N104 U2 2.575(3) .
N105 Eu2 2.597(3) .
N106 Eu2 2.410(3) .
N107 Eu2 2.418(3) .
N108 Eu2 2.587(3) .
N109 Eu2 2.496(4) .
O1 U1 1.904(2) .
O1 Eu1 2.200(2) .
O2 U1 1.932(2) .
O2 U1 2.334(2) 3_657
O3 U2 1.893(3) .
O3 Eu2 2.230(3) .
O4 U2 1.928(2) .
O4 U2 2.351(2) 3_776
Eu1 U1 4.1027(3) .
Eu2 N111 2.534(14) .
Eu2 N110 2.535(15) .
Eu2 U2 4.1208(3) .
U1 O2 2.334(2) 3_657
U1 U1 3.4509(3) 3_657
U2 O4 2.351(2) 3_776
U2 U2 3.4781(3) 3_776
N110 C152 1.31(2) .
N110 C148 1.337(19) .
C148 C149 1.353(14) .
C148 H148 0.9500 .
C149 C150 1.34(3) .
C149 H149 0.9500 .
C150 C151 1.33(4) .
C150 H150 0.9500 .
C152 C151 1.41(2) .
C152 H152 0.9500 .
C151 H151 0.9500 .
N111 C157 1.297(17) .
N111 C153 1.31(2) .
C153 C154 1.36(3) .
C153 H153 0.9500 .
C154 C155 1.38(3) .
C154 H154 0.9500 .
C156 C157 1.358(13) .
C156 C155 1.38(3) .
C156 H156 0.9500 .
C155 H155 0.9500 .
C157 H157 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 -177.4(4) . .
N1 C1 C2 N2 6.9(6) . .
N2 C2 C3 C4 -0.1(5) . .
C1 C2 C3 C4 -176.0(4) . .
C2 C3 C4 C5 0.0(5) . .
C3 C4 C5 N2 0.2(5) . .
C3 C4 C5 C6 179.5(4) . .
N2 C5 C6 C9 55.6(5) . .
C4 C5 C6 C9 -123.7(5) . .
N2 C5 C6 C8 177.0(4) . .
C4 C5 C6 C8 -2.3(6) . .
N2 C5 C6 C7 -64.3(5) . .
C4 C5 C6 C7 116.4(5) . .
C8 C6 C9 N3 178.8(4) . .
C5 C6 C9 N3 -60.2(5) . .
C7 C6 C9 N3 58.8(5) . .
C8 C6 C9 C10 -1.5(6) . .
C5 C6 C9 C10 119.5(5) . .
C7 C6 C9 C10 -121.6(5) . .
N3 C9 C10 C11 0.7(5) . .
C6 C9 C10 C11 -179.0(4) . .
C9 C10 C11 C12 -0.4(5) . .
C10 C11 C12 C13 177.0(4) . .
C10 C11 C12 N3 0.0(5) . .
N3 C12 C13 N4 -2.4(6) . .
C11 C12 C13 N4 -179.1(4) . .
C21 C14 C15 C16 1.2(6) . .
N4 C14 C15 C16 179.9(4) . .
C14 C15 C16 C19 -0.9(7) . .
C14 C15 C16 C17 178.1(4) . .
C15 C16 C19 C20 -0.3(7) . .
C17 C16 C19 C20 -179.3(4) . .
C15 C16 C19 C18 -176.5(5) . .
C17 C16 C19 C18 4.5(8) . .
C16 C19 C20 C21 1.2(7) . .
C18 C19 C20 C21 177.5(5) . .
C19 C20 C21 C14 -0.9(7) . .
C19 C20 C21 N5 -172.2(4) . .
C15 C14 C21 C20 -0.3(6) . .
N4 C14 C21 C20 -179.0(4) . .
C15 C14 C21 N5 170.5(4) . .
N4 C14 C21 N5 -8.2(6) . .
N5 C22 C23 N6 -12.5(7) . .
Eu1 C22 C23 N6 -12.2(4) . .
N5 C22 C23 C24 166.9(5) . .
Eu1 C22 C23 C24 167.2(6) . .
N5 C22 C23 Eu1 -0.3(4) . .
N6 C23 C24 C25 0.2(7) . .
C22 C23 C24 C25 -179.3(6) . .
Eu1 C23 C24 C25 -23.6(11) . .
C23 C24 C25 C26 -1.4(7) . .
C24 C25 C26 N6 2.2(7) . .
C24 C25 C26 C27 179.2(5) . .
N6 C26 C27 C28 -138.6(5) . .
C25 C26 C27 C28 44.8(7) . .
N6 C26 C27 C30 -17.4(7) . .
C25 C26 C27 C30 165.9(5) . .
N6 C26 C27 C29 104.1(6) . .
C25 C26 C27 C29 -72.5(7) . .
C28 C27 C30 N7 164.2(5) . .
C26 C27 C30 N7 43.3(6) . .
C29 C27 C30 N7 -78.5(6) . .
C28 C27 C30 C31 -22.9(7) . .
C26 C27 C30 C31 -143.7(5) . .
C29 C27 C30 C31 94.4(6) . .
N7 C30 C31 C32 -1.4(6) . .
C27 C30 C31 C32 -175.1(5) . .
C30 C31 C32 C33 0.4(7) . .
C31 C32 C33 N7 0.7(7) . .
C31 C32 C33 C34 -167.7(5) . .
C31 C32 C33 Eu1 -25.5(9) . .
C32 C33 C34 N8 168.3(5) . .
N7 C33 C34 N8 1.2(7) . .
Eu1 C33 C34 N8 7.7(4) . .
C42 C35 C36 C37 0.4(6) . .
N8 C35 C36 C37 175.0(4) . .
C35 C36 C37 C40 -1.4(6) . .
C35 C36 C37 C38 -179.6(4) . .
C36 C37 C40 C41 1.2(6) . .
C38 C37 C40 C41 179.5(4) . .
C36 C37 C40 C39 -178.8(4) . .
C38 C37 C40 C39 -0.5(6) . .
C37 C40 C41 C42 -0.2(6) . .
C39 C40 C41 C42 179.8(4) . .
C40 C41 C42 C35 -0.8(6) . .
C40 C41 C42 N1 -178.4(4) . .
C36 C35 C42 C41 0.7(6) . .
N8 C35 C42 C41 -173.7(4) . .
C36 C35 C42 N1 178.1(4) . .
N8 C35 C42 N1 3.8(6) . .
N9 C43 C44 C45 1.4(9) . .
C43 C44 C45 C46 -1.3(11) . .
C44 C45 C46 C47 2.4(11) . .
C45 C46 C47 N9 -3.6(10) . .
N10 C48 C49 C50 -2.0(7) . .
C48 C49 C50 C51 -0.7(7) . .
C49 C50 C51 C52 2.1(7) . .
C50 C51 C52 N10 -1.1(8) . .
N101 C101 C102 N102 3.4(6) . .
N101 C101 C102 C103 -177.9(4) . .
N102 C102 C103 C104 -0.5(5) . .
C101 C102 C103 C104 -179.4(4) . .
C102 C103 C104 C105 0.7(5) . .
C103 C104 C105 N102 -0.6(5) . .
C103 C104 C105 C106 177.4(4) . .
N102 C105 C106 C109 56.3(5) . .
C104 C105 C106 C109 -121.6(5) . .
N102 C105 C106 C107 -64.4(5) . .
C104 C105 C106 C107 117.7(5) . .
N102 C105 C106 C108 176.9(4) . .
C104 C105 C106 C108 -0.9(6) . .
C105 C106 C109 N103 -55.5(5) . .
C107 C106 C109 N103 64.9(5) . .
C108 C106 C109 N103 -175.8(4) . .
C105 C106 C109 C110 121.4(5) . .
C107 C106 C109 C110 -118.2(5) . .
C108 C106 C109 C110 1.1(6) . .
N103 C109 C110 C111 -0.6(5) . .
C106 C109 C110 C111 -177.8(4) . .
C109 C110 C111 C112 1.2(5) . .
C110 C111 C112 N103 -1.4(5) . .
C110 C111 C112 C113 179.5(4) . .
N103 C112 C113 N104 -2.3(6) . .
C111 C112 C113 N104 176.7(4) . .
C121 C114 C115 C116 1.6(6) . .
N104 C114 C115 C116 -178.1(4) . .
C114 C115 C116 C119 -1.1(7) . .
C114 C115 C116 C117 178.7(4) . .
C115 C116 C119 C120 0.0(7) . .
C117 C116 C119 C120 -179.8(4) . .
C115 C116 C119 C118 -178.6(4) . .
C117 C116 C119 C118 1.6(7) . .
C116 C119 C120 C121 0.5(7) . .
C118 C119 C120 C121 179.2(4) . .
C115 C114 C121 C120 -1.0(6) . .
N104 C114 C121 C120 178.7(3) . .
C115 C114 C121 N105 174.3(4) . .
N104 C114 C121 N105 -6.0(6) . .
C119 C120 C121 C114 0.0(7) . .
C119 C120 C121 N105 -175.6(4) . .
N105 C122 C123 N106 -4.5(7) . .
N105 C122 C123 C124 178.7(5) . .
N105 C122 C123 Eu2 -5.4(4) . .
N106 C123 C124 C125 -1.4(6) . .
C122 C123 C124 C125 175.7(5) . .
Eu2 C123 C124 C125 4.3(10) . .
C123 C124 C125 C126 1.2(7) . .
C124 C125 C126 N106 -0.6(7) . .
C124 C125 C126 C127 174.0(5) . .
N106 C126 C127 C130 -36.4(7) . .
C125 C126 C127 C130 149.7(5) . .
N106 C126 C127 C129 -159.1(4) . .
C125 C126 C127 C129 27.1(7) . .
N106 C126 C127 C128 84.1(6) . .
C125 C126 C127 C128 -89.8(6) . .
C126 C127 C130 N107 32.4(7) . .
C129 C127 C130 N107 155.2(5) . .
C128 C127 C130 N107 -88.2(6) . .
C126 C127 C130 C131 -153.2(4) . .
C129 C127 C130 C131 -30.4(7) . .
C128 C127 C130 C131 86.3(6) . .
N107 C130 C131 C132 -0.6(5) . .
C127 C130 C131 C132 -175.7(5) . .
C130 C131 C132 C133 0.6(5) . .
C131 C132 C133 C134 -178.0(5) . .
C131 C132 C133 N107 -0.3(5) . .
C131 C132 C133 Eu2 1.2(9) . .
N107 C133 C134 N108 6.3(7) . .
C132 C133 C134 N108 -176.2(4) . .
Eu2 C133 C134 N108 4.1(4) . .
C142 C135 C136 C137 -0.3(6) . .
N108 C135 C136 C137 173.5(4) . .
C135 C136 C137 C140 -2.1(6) . .
C135 C136 C137 C138 179.6(4) . .
C136 C137 C140 C141 1.9(6) . .
C138 C137 C140 C141 -179.8(4) . .
C136 C137 C140 C139 -177.3(4) . .
C138 C137 C140 C139 1.0(6) . .
C137 C140 C141 C142 0.8(6) . .
C139 C140 C141 C142 179.9(4) . .
C140 C141 C142 C135 -3.3(6) . .
C140 C141 C142 N101 177.2(3) . .
C136 C135 C142 C141 3.0(6) . .
N108 C135 C142 C141 -170.6(4) . .
C136 C135 C142 N101 -177.5(3) . .
N108 C135 C142 N101 8.9(6) . .
N109 C143 C144 C145 1.7(8) . .
C143 C144 C145 C146 -1.3(8) . .
C144 C145 C146 C147 -0.2(9) . .
C145 C146 C147 N109 1.5(8) . .
N200 C200 C201 C202 3(2) . .
C200 C201 C202 C203 -6(2) . .
C201 C202 C203 C204 8(2) . .
C202 C203 C204 N200 -5.0(19) . .
C2 C1 N1 C42 -169.6(4) . .
C2 C1 N1 U1 -19.4(5) . .
C41 C42 N1 C1 -125.8(4) . .
C35 C42 N1 C1 56.8(5) . .
C41 C42 N1 U1 86.5(4) . .
C35 C42 N1 U1 -90.9(4) . .
C4 C5 N2 C2 -0.2(5) . .
C6 C5 N2 C2 -179.6(4) . .
C4 C5 N2 U1 162.3(3) . .
C6 C5 N2 U1 -17.1(6) . .
C3 C2 N2 C5 0.2(5) . .
C1 C2 N2 C5 176.8(4) . .
C3 C2 N2 U1 -165.9(3) . .
C1 C2 N2 U1 10.7(5) . .
C10 C9 N3 C12 -0.7(5) . .
C6 C9 N3 C12 179.0(4) . .
C10 C9 N3 U1 -154.9(3) . .
C6 C9 N3 U1 24.9(6) . .
C13 C12 N3 C9 -176.9(4) . .
C11 C12 N3 C9 0.4(5) . .
C13 C12 N3 U1 -16.9(5) . .
C11 C12 N3 U1 160.4(3) . .
C12 C13 N4 C14 167.8(4) . .
C12 C13 N4 U1 18.8(5) . .
C21 C14 N4 C13 -49.8(5) . .
C15 C14 N4 C13 131.4(4) . .
C21 C14 N4 U1 95.0(4) . .
C15 C14 N4 U1 -83.7(4) . .
C23 C22 N5 C21 164.2(4) . .
Eu1 C22 N5 C21 163.8(5) . .
C23 C22 N5 Eu1 0.4(6) . .
C20 C21 N5 C22 -56.6(6) . .
C14 C21 N5 C22 132.6(4) . .
C20 C21 N5 Eu1 103.9(4) . .
C14 C21 N5 Eu1 -66.9(5) . .
C25 C26 N6 C23 -2.1(6) . .
C27 C26 N6 C23 -179.1(5) . .
C25 C26 N6 Eu1 155.2(4) . .
C27 C26 N6 Eu1 -21.8(8) . .
C24 C23 N6 C26 1.1(6) . .
C22 C23 N6 C26 -179.3(4) . .
Eu1 C23 N6 C26 162.9(5) . .
C24 C23 N6 Eu1 -161.8(3) . .
C22 C23 N6 Eu1 17.8(6) . .
C31 C30 N7 C33 1.9(5) . .
C27 C30 N7 C33 175.7(4) . .
C31 C30 N7 Eu1 153.1(4) . .
C27 C30 N7 Eu1 -33.1(7) . .
C32 C33 N7 C30 -1.6(6) . .
C34 C33 N7 C30 167.6(4) . .
Eu1 C33 N7 C30 158.2(4) . .
C32 C33 N7 Eu1 -159.8(4) . .
C34 C33 N7 Eu1 9.4(6) . .
C33 C34 N8 C35 -164.4(4) . .
C33 C34 N8 Eu1 -9.9(5) . .
C36 C35 N8 C34 44.6(5) . .
C42 C35 N8 C34 -141.1(4) . .
C36 C35 N8 Eu1 -103.7(4) . .
C42 C35 N8 Eu1 70.6(5) . .
C44 C43 N9 C47 -2.5(7) . .
C44 C43 N9 Eu1 176.9(4) . .
C46 C47 N9 C43 3.5(8) . .
C46 C47 N9 Eu1 -175.8(4) . .
C49 C48 N10 C52 3.0(7) . .
C49 C48 N10 Eu1 -167.7(3) . .
C51 C52 N10 C48 -1.3(7) . .
C51 C52 N10 Eu1 168.6(4) . .
C102 C101 N101 C142 -168.6(4) . .
C102 C101 N101 U2 -18.9(5) . .
C141 C142 N101 C101 -129.8(4) . .
C135 C142 N101 C101 50.7(5) . .
C141 C142 N101 U2 83.3(4) . .
C135 C142 N101 U2 -96.2(4) . .
C104 C105 N102 C102 0.3(5) . .
C106 C105 N102 C102 -178.0(4) . .
C104 C105 N102 U2 159.2(3) . .
C106 C105 N102 U2 -19.1(6) . .
C103 C102 N102 C105 0.1(5) . .
C101 C102 N102 C105 179.1(4) . .
C103 C102 N102 U2 -163.6(3) . .
C101 C102 N102 U2 15.3(5) . .
C110 C109 N103 C112 -0.3(5) . .
C106 C109 N103 C112 177.1(4) . .
C110 C109 N103 U2 -160.3(3) . .
C106 C109 N103 U2 17.1(6) . .
C111 C112 N103 C109 1.1(5) . .
C113 C112 N103 C109 -179.7(4) . .
C111 C112 N103 U2 165.8(3) . .
C113 C112 N103 U2 -15.0(5) . .
C112 C113 N104 C114 170.6(4) . .
C112 C113 N104 U2 17.3(5) . .
C115 C114 N104 C113 123.3(4) . .
C121 C114 N104 C113 -56.3(5) . .
C115 C114 N104 U2 -86.7(4) . .
C121 C114 N104 U2 93.6(4) . .
C123 C122 N105 C121 165.8(4) . .
C123 C122 N105 Eu2 7.0(5) . .
C114 C121 N105 C122 139.3(4) . .
C120 C121 N105 C122 -45.6(5) . .
C114 C121 N105 Eu2 -66.8(5) . .
C120 C121 N105 Eu2 108.3(4) . .
C125 C126 N106 C123 -0.3(6) . .
C127 C126 N106 C123 -175.1(4) . .
C125 C126 N106 Eu2 -173.6(4) . .
C127 C126 N106 Eu2 11.6(7) . .
C124 C123 N106 C126 1.1(6) . .
C122 C123 N106 C126 -176.3(4) . .
Eu2 C123 N106 C126 -175.0(5) . .
C124 C123 N106 Eu2 176.0(3) . .
C122 C123 N106 Eu2 -1.3(6) . .
C131 C130 N107 C133 0.4(5) . .
C127 C130 N107 C133 175.6(4) . .
C131 C130 N107 Eu2 -178.1(3) . .
C127 C130 N107 Eu2 -2.9(7) . .
C134 C133 N107 C130 177.9(4) . .
C132 C133 N107 C130 0.0(5) . .
Eu2 C133 N107 C130 -178.9(5) . .
C134 C133 N107 Eu2 -3.2(5) . .
C132 C133 N107 Eu2 178.9(3) . .
C133 C134 N108 C135 -163.1(4) . .
C133 C134 N108 Eu2 -5.5(5) . .
C136 C135 N108 C134 48.3(5) . .
C142 C135 N108 C134 -138.2(4) . .
C136 C135 N108 Eu2 -105.3(4) . .
C142 C135 N108 Eu2 68.2(5) . .
C146 C147 N109 C143 -1.2(7) . .
C146 C147 N109 Eu2 168.7(4) . .
C144 C143 N109 C147 -0.5(7) . .
C144 C143 N109 Eu2 -169.9(3) . .
C203 C204 N200 C200 1.1(13) . .
C201 C200 N200 C204 0.0(14) . .
U1 O1 Eu1 N7 174(3) . .
U1 O1 Eu1 N6 -45(3) . .
U1 O1 Eu1 N9 65(3) . .
U1 O1 Eu1 N5 -7(3) . .
U1 O1 Eu1 N10 -105(3) . .
U1 O1 Eu1 N8 134(3) . .
U1 O1 Eu1 C33 152(3) . .
U1 O1 Eu1 C23 -32(3) . .
U1 O1 Eu1 C22 -18(3) . .
C30 N7 Eu1 O1 158.6(4) . .
C33 N7 Eu1 O1 -51.8(4) . .
C30 N7 Eu1 N6 1.2(4) . .
C33 N7 Eu1 N6 150.9(3) . .
C30 N7 Eu1 N9 -88.2(4) . .
C33 N7 Eu1 N9 61.4(3) . .
C30 N7 Eu1 N5 -19.8(5) . .
C33 N7 Eu1 N5 129.9(3) . .
C30 N7 Eu1 N10 79.8(4) . .
C33 N7 Eu1 N10 -130.6(3) . .
C30 N7 Eu1 N8 -159.3(4) . .
C33 N7 Eu1 N8 -9.6(3) . .
C30 N7 Eu1 C33 -149.6(6) . .
C30 N7 Eu1 C23 0.2(4) . .
C33 N7 Eu1 C23 149.8(3) . .
C30 N7 Eu1 C22 -8.5(5) . .
C33 N7 Eu1 C22 141.1(3) . .
C30 N7 Eu1 U1 158.8(3) . .
C33 N7 Eu1 U1 -51.5(3) . .
C26 N6 Eu1 O1 -127.6(5) . .
C23 N6 Eu1 O1 28.4(4) . .
C26 N6 Eu1 N7 26.8(5) . .
C23 N6 Eu1 N7 -177.3(3) . .
C26 N6 Eu1 N9 117.9(5) . .
C23 N6 Eu1 N9 -86.2(3) . .
C26 N6 Eu1 N5 -168.0(5) . .
C23 N6 Eu1 N5 -12.0(3) . .
C26 N6 Eu1 N10 -67.0(5) . .
C23 N6 Eu1 N10 89.0(3) . .
C26 N6 Eu1 N8 54.5(5) . .
C23 N6 Eu1 N8 -149.6(3) . .
C26 N6 Eu1 C33 37.9(5) . .
C23 N6 Eu1 C33 -166.2(3) . .
C26 N6 Eu1 C23 -156.0(7) . .
C26 N6 Eu1 C22 -164.9(5) . .
C23 N6 Eu1 C22 -8.9(3) . .
C26 N6 Eu1 U1 -129.2(4) . .
C23 N6 Eu1 U1 26.8(4) . .
C43 N9 Eu1 O1 -5.9(4) . .
C47 N9 Eu1 O1 173.4(3) . .
C43 N9 Eu1 N7 -147.1(3) . .
C47 N9 Eu1 N7 32.2(4) . .
C43 N9 Eu1 N6 140.6(4) . .
C47 N9 Eu1 N6 -40.0(4) . .
C43 N9 Eu1 N5 72.4(3) . .
C47 N9 Eu1 N5 -108.2(4) . .
C43 N9 Eu1 N10 117.2(6) . .
C47 N9 Eu1 N10 -63.5(7) . .
C43 N9 Eu1 N8 -78.5(3) . .
C47 N9 Eu1 N8 100.8(4) . .
C43 N9 Eu1 C33 -126.5(4) . .
C47 N9 Eu1 C33 52.9(4) . .
C43 N9 Eu1 C23 118.0(4) . .
C47 N9 Eu1 C23 -62.7(4) . .
C43 N9 Eu1 C22 94.0(4) . .
C47 N9 Eu1 C22 -86.7(4) . .
C43 N9 Eu1 U1 -4.6(4) . .
C47 N9 Eu1 U1 174.7(3) . .
C22 N5 Eu1 O1 -151.3(3) . .
C21 N5 Eu1 O1 47.4(3) . .
C22 N5 Eu1 N7 27.6(4) . .
C21 N5 Eu1 N7 -133.6(3) . .
C22 N5 Eu1 N6 6.1(3) . .
C21 N5 Eu1 N6 -155.1(4) . .
C22 N5 Eu1 N9 101.7(3) . .
C21 N5 Eu1 N9 -59.5(3) . .
C22 N5 Eu1 N10 -69.7(3) . .
C21 N5 Eu1 N10 129.0(3) . .
C22 N5 Eu1 N8 144.4(3) . .
C21 N5 Eu1 N8 -16.8(4) . .
C22 N5 Eu1 C33 63.6(4) . .
C21 N5 Eu1 C33 -97.7(4) . .
C22 N5 Eu1 C23 -0.2(3) . .
C21 N5 Eu1 C23 -161.4(4) . .
C21 N5 Eu1 C22 -161.2(5) . .
C22 N5 Eu1 U1 -151.5(3) . .
C21 N5 Eu1 U1 47.3(3) . .
C48 N10 Eu1 O1 -60.7(3) . .
C52 N10 Eu1 O1 129.7(4) . .
C48 N10 Eu1 N7 78.5(3) . .
C52 N10 Eu1 N7 -91.2(4) . .
C48 N10 Eu1 N6 150.4(3) . .
C52 N10 Eu1 N6 -19.3(4) . .
C48 N10 Eu1 N9 174.3(5) . .
C52 N10 Eu1 N9 4.6(8) . .
C48 N10 Eu1 N5 -142.5(3) . .
C52 N10 Eu1 N5 47.8(4) . .
C48 N10 Eu1 N8 11.5(4) . .
C52 N10 Eu1 N8 -158.2(4) . .
C48 N10 Eu1 C33 60.4(3) . .
C52 N10 Eu1 C33 -109.3(4) . .
C48 N10 Eu1 C23 173.5(3) . .
C52 N10 Eu1 C23 3.9(4) . .
C48 N10 Eu1 C22 -162.8(3) . .
C52 N10 Eu1 C22 27.5(4) . .
C48 N10 Eu1 U1 -62.0(3) . .
C52 N10 Eu1 U1 128.4(4) . .
C34 N8 Eu1 O1 163.2(3) . .
C35 N8 Eu1 O1 -46.9(3) . .
C34 N8 Eu1 N7 10.1(3) . .
C35 N8 Eu1 N7 160.0(4) . .
C34 N8 Eu1 N6 -18.1(4) . .
C35 N8 Eu1 N6 131.9(3) . .
C34 N8 Eu1 N9 -87.6(3) . .
C35 N8 Eu1 N9 62.3(3) . .
C34 N8 Eu1 N5 -131.0(3) . .
C35 N8 Eu1 N5 19.0(4) . .
C34 N8 Eu1 N10 88.7(3) . .
C35 N8 Eu1 N10 -121.4(3) . .
C34 N8 Eu1 C33 4.9(3) . .
C35 N8 Eu1 C33 154.9(4) . .
C34 N8 Eu1 C23 -45.6(4) . .
C35 N8 Eu1 C23 104.3(4) . .
C34 N8 Eu1 C22 -103.6(3) . .
C35 N8 Eu1 C22 46.4(5) . .
C34 N8 Eu1 U1 164.2(3) . .
C35 N8 Eu1 U1 -45.9(3) . .
C32 C33 Eu1 O1 180.0(6) . .
N7 C33 Eu1 O1 142.3(3) . .
C34 C33 Eu1 O1 -29.6(3) . .
C32 C33 Eu1 N7 37.7(6) . .
C34 C33 Eu1 N7 -172.0(5) . .
C32 C33 Eu1 N6 10.0(7) . .
N7 C33 Eu1 N6 -27.7(3) . .
C34 C33 Eu1 N6 160.4(3) . .
C32 C33 Eu1 N9 -79.3(7) . .
N7 C33 Eu1 N9 -116.9(3) . .
C34 C33 Eu1 N9 71.1(3) . .
C32 C33 Eu1 N5 -41.9(8) . .
N7 C33 Eu1 N5 -79.6(4) . .
C34 C33 Eu1 N5 108.4(3) . .
C32 C33 Eu1 N10 89.5(7) . .
N7 C33 Eu1 N10 51.8(3) . .
C34 C33 Eu1 N10 -120.1(3) . .
C32 C33 Eu1 N8 -154.7(7) . .
N7 C33 Eu1 N8 167.6(4) . .
C34 C33 Eu1 N8 -4.3(2) . .
C32 C33 Eu1 C23 4.2(7) . .
N7 C33 Eu1 C23 -33.5(3) . .
C34 C33 Eu1 C23 154.5(3) . .
C32 C33 Eu1 C22 -13.8(7) . .
N7 C33 Eu1 C22 -51.5(3) . .
C34 C33 Eu1 C22 136.5(3) . .
C32 C33 Eu1 U1 -179.2(6) . .
N7 C33 Eu1 U1 143.1(3) . .
C34 C33 Eu1 U1 -28.9(3) . .
N6 C23 Eu1 O1 -160.5(3) . .
C24 C23 Eu1 O1 -126.4(8) . .
C22 C23 Eu1 O1 35.1(3) . .
N6 C23 Eu1 N7 2.6(3) . .
C24 C23 Eu1 N7 36.7(8) . .
C22 C23 Eu1 N7 -161.8(3) . .
C24 C23 Eu1 N6 34.2(7) . .
C22 C23 Eu1 N6 -164.4(5) . .
N6 C23 Eu1 N9 93.4(3) . .
C24 C23 Eu1 N9 127.6(8) . .
C22 C23 Eu1 N9 -70.9(3) . .
N6 C23 Eu1 N5 164.6(4) . .
C24 C23 Eu1 N5 -161.3(8) . .
C22 C23 Eu1 N5 0.2(2) . .
N6 C23 Eu1 N10 -86.7(3) . .
C24 C23 Eu1 N10 -52.6(8) . .
C22 C23 Eu1 N10 108.9(3) . .
N6 C23 Eu1 N8 53.7(5) . .
C24 C23 Eu1 N8 87.9(8) . .
C22 C23 Eu1 N8 -110.6(3) . .
N6 C23 Eu1 C33 15.2(4) . .
C24 C23 Eu1 C33 49.4(8) . .
C22 C23 Eu1 C33 -149.2(3) . .
N6 C23 Eu1 C22 164.4(5) . .
C24 C23 Eu1 C22 -161.5(9) . .
N6 C23 Eu1 U1 -161.4(3) . .
C24 C23 Eu1 U1 -127.2(7) . .
C22 C23 Eu1 U1 34.2(3) . .
N5 C22 Eu1 O1 29.1(3) . .
C23 C22 Eu1 O1 -150.6(3) . .
N5 C22 Eu1 N7 -159.6(3) . .
C23 C22 Eu1 N7 20.8(3) . .
N5 C22 Eu1 N6 -172.2(4) . .
C23 C22 Eu1 N6 8.1(3) . .
N5 C22 Eu1 N9 -73.6(3) . .
C23 C22 Eu1 N9 106.7(3) . .
C23 C22 Eu1 N5 -179.7(5) . .
N5 C22 Eu1 N10 111.1(3) . .
C23 C22 Eu1 N10 -68.6(3) . .
N5 C22 Eu1 N8 -58.2(4) . .
C23 C22 Eu1 N8 122.1(3) . .
N5 C22 Eu1 C33 -138.9(3) . .
C23 C22 Eu1 C33 41.4(3) . .
N5 C22 Eu1 C23 179.7(5) . .
N5 C22 Eu1 U1 28.7(3) . .
C23 C22 Eu1 U1 -151.0(3) . .
U2 O3 Eu2 N106 -101(2) . .
U2 O3 Eu2 N107 127(2) . .
U2 O3 Eu2 N109 12(2) . .
U2 O3 Eu2 N111 -156(3) . .
U2 O3 Eu2 N110 -177(3) . .
U2 O3 Eu2 N108 86(2) . .
U2 O3 Eu2 N105 -59(2) . .
U2 O3 Eu2 C123 -81(2) . .
U2 O3 Eu2 C133 109(2) . .
C126 N106 Eu2 O3 -138.8(4) . .
C123 N106 Eu2 O3 48.4(4) . .
C126 N106 Eu2 N107 10.8(4) . .
C123 N106 Eu2 N107 -162.0(3) . .
C126 N106 Eu2 N109 106.1(4) . .
C123 N106 Eu2 N109 -66.7(3) . .
C126 N106 Eu2 N111 -83.6(6) . .
C123 N106 Eu2 N111 103.5(5) . .
C126 N106 Eu2 N110 -65.6(6) . .
C123 N106 Eu2 N110 121.6(5) . .
C126 N106 Eu2 N108 30.5(5) . .
C123 N106 Eu2 N108 -142.3(3) . .
C126 N106 Eu2 N105 176.2(5) . .
C123 N106 Eu2 N105 3.3(3) . .
C126 N106 Eu2 C123 172.8(7) . .
C126 N106 Eu2 C133 16.1(4) . .
C123 N106 Eu2 C133 -156.8(3) . .
C126 N106 Eu2 U2 -141.1(4) . .
C123 N106 Eu2 U2 46.0(4) . .
C130 N107 Eu2 O3 134.6(4) . .
C133 N107 Eu2 O3 -43.8(4) . .
C130 N107 Eu2 N106 -15.3(4) . .
C133 N107 Eu2 N106 166.3(3) . .
C130 N107 Eu2 N109 -108.0(4) . .
C133 N107 Eu2 N109 73.6(3) . .
C130 N107 Eu2 N111 62.4(6) . .
C133 N107 Eu2 N111 -116.0(4) . .
C130 N107 Eu2 N110 76.9(6) . .
C133 N107 Eu2 N110 -101.6(5) . .
C130 N107 Eu2 N108 178.7(5) . .
C133 N107 Eu2 N108 0.3(3) . .
C130 N107 Eu2 N105 -36.4(5) . .
C133 N107 Eu2 N105 145.2(3) . .
C130 N107 Eu2 C123 -22.1(5) . .
C133 N107 Eu2 C123 159.5(3) . .
C130 N107 Eu2 C133 178.4(7) . .
C130 N107 Eu2 U2 136.5(4) . .
C133 N107 Eu2 U2 -41.9(4) . .
C147 N109 Eu2 O3 -168.2(3) . .
C143 N109 Eu2 O3 1.0(3) . .
C147 N109 Eu2 N106 -24.6(3) . .
C143 N109 Eu2 N106 144.6(3) . .
C147 N109 Eu2 N107 47.7(3) . .
C143 N109 Eu2 N107 -143.1(3) . .
C147 N109 Eu2 N111 -77.9(14) . .
C143 N109 Eu2 N111 91.2(13) . .
C147 N109 Eu2 N110 81(2) . .
C143 N109 Eu2 N110 -110(2) . .
C147 N109 Eu2 N108 113.8(3) . .
C143 N109 Eu2 N108 -77.0(3) . .
C147 N109 Eu2 N105 -91.5(3) . .
C143 N109 Eu2 N105 77.7(3) . .
C147 N109 Eu2 C123 -45.2(3) . .
C143 N109 Eu2 C123 124.0(3) . .
C147 N109 Eu2 C133 69.2(3) . .
C143 N109 Eu2 C133 -121.6(3) . .
C147 N109 Eu2 U2 -167.9(3) . .
C143 N109 Eu2 U2 1.3(3) . .
C134 N108 Eu2 O3 155.5(3) . .
C135 N108 Eu2 O3 -49.6(3) . .
C134 N108 Eu2 N106 -17.6(4) . .
C135 N108 Eu2 N106 137.3(3) . .
C134 N108 Eu2 N107 2.5(3) . .
C135 N108 Eu2 N107 157.5(3) . .
C134 N108 Eu2 N109 -99.8(3) . .
C135 N108 Eu2 N109 55.1(3) . .
C134 N108 Eu2 N111 82.8(4) . .
C135 N108 Eu2 N111 -122.2(4) . .
C134 N108 Eu2 N110 75.5(4) . .
C135 N108 Eu2 N110 -129.6(4) . .
C134 N108 Eu2 N105 -140.4(3) . .
C135 N108 Eu2 N105 14.6(4) . .
C134 N108 Eu2 C123 -48.4(4) . .
C135 N108 Eu2 C123 106.6(4) . .
C134 N108 Eu2 C133 2.7(3) . .
C135 N108 Eu2 C133 157.6(4) . .
C134 N108 Eu2 U2 157.0(3) . .
C135 N108 Eu2 U2 -48.0(3) . .
C122 N105 Eu2 O3 -157.9(3) . .
C121 N105 Eu2 O3 46.9(3) . .
C122 N105 Eu2 N106 -5.2(3) . .
C121 N105 Eu2 N106 -160.4(4) . .
C122 N105 Eu2 N107 16.2(4) . .
C121 N105 Eu2 N107 -139.0(3) . .
C122 N105 Eu2 N109 96.4(3) . .
C121 N105 Eu2 N109 -58.7(3) . .
C122 N105 Eu2 N111 -80.8(4) . .
C121 N105 Eu2 N111 124.0(4) . .
C122 N105 Eu2 N110 -82.3(4) . .
C121 N105 Eu2 N110 122.5(4) . .
C122 N105 Eu2 N108 137.9(3) . .
C121 N105 Eu2 N108 -17.3(4) . .
C122 N105 Eu2 C123 -3.5(3) . .
C121 N105 Eu2 C123 -158.6(4) . .
C122 N105 Eu2 C133 46.6(4) . .
C121 N105 Eu2 C133 -108.6(4) . .
C122 N105 Eu2 U2 -159.3(3) . .
C121 N105 Eu2 U2 45.6(3) . .
N106 C123 Eu2 O3 -145.1(3) . .
C124 C123 Eu2 O3 -153.0(7) . .
C122 C123 Eu2 O3 33.7(3) . .
C124 C123 Eu2 N106 -7.9(7) . .
C122 C123 Eu2 N106 178.8(5) . .
N106 C123 Eu2 N107 17.1(3) . .
C124 C123 Eu2 N107 9.2(8) . .
C122 C123 Eu2 N107 -164.0(3) . .
N106 C123 Eu2 N109 113.3(3) . .
C124 C123 Eu2 N109 105.3(8) . .
C122 C123 Eu2 N109 -67.9(3) . .
N106 C123 Eu2 N111 -73.2(4) . .
C124 C123 Eu2 N111 -81.1(8) . .
C122 C123 Eu2 N111 105.7(4) . .
N106 C123 Eu2 N110 -59.6(5) . .
C124 C123 Eu2 N110 -67.6(8) . .
C122 C123 Eu2 N110 119.2(4) . .
N106 C123 Eu2 N108 63.4(4) . .
C124 C123 Eu2 N108 55.5(9) . .
C122 C123 Eu2 N108 -117.7(3) . .
N106 C123 Eu2 N105 -175.7(4) . .
C124 C123 Eu2 N105 176.3(8) . .
C122 C123 Eu2 N105 3.1(2) . .
N106 C123 Eu2 C133 25.6(3) . .
C124 C123 Eu2 C133 17.6(8) . .
C122 C123 Eu2 C133 -155.6(2) . .
N106 C123 Eu2 U2 -146.9(3) . .
C124 C123 Eu2 U2 -154.8(7) . .
C122 C123 Eu2 U2 31.9(3) . .
C134 C133 Eu2 O3 -34.5(3) . .
N107 C133 Eu2 O3 148.3(3) . .
C132 C133 Eu2 O3 146.0(6) . .
C134 C133 Eu2 N106 164.2(3) . .
N107 C133 Eu2 N106 -13.1(3) . .
C132 C133 Eu2 N106 -15.3(7) . .
C134 C133 Eu2 N107 177.2(5) . .
C132 C133 Eu2 N107 -2.2(6) . .
C134 C133 Eu2 N109 69.6(3) . .
N107 C133 Eu2 N109 -107.6(3) . .
C132 C133 Eu2 N109 -109.8(7) . .
C134 C133 Eu2 N111 -116.9(4) . .
N107 C133 Eu2 N111 65.9(4) . .
C132 C133 Eu2 N111 63.7(7) . .
C134 C133 Eu2 N110 -108.6(4) . .
N107 C133 Eu2 N110 74.2(4) . .
C132 C133 Eu2 N110 71.9(7) . .
C134 C133 Eu2 N108 -2.4(2) . .
N107 C133 Eu2 N108 -179.6(4) . .
C132 C133 Eu2 N108 178.2(7) . .
C134 C133 Eu2 N105 116.6(3) . .
N107 C133 Eu2 N105 -60.6(4) . .
C132 C133 Eu2 N105 -62.8(7) . .
C134 C133 Eu2 C123 154.6(2) . .
N107 C133 Eu2 C123 -22.6(3) . .
C132 C133 Eu2 C123 -24.8(7) . .
C134 C133 Eu2 U2 -32.8(3) . .
N107 C133 Eu2 U2 150.0(3) . .
C132 C133 Eu2 U2 147.7(6) . .
Eu1 O1 U1 O2 -69(3) . .
Eu1 O1 U1 O2 -63(3) . 3_657
Eu1 O1 U1 N3 80(3) . .
Eu1 O1 U1 N2 152(3) . .
Eu1 O1 U1 N1 -143(3) . .
Eu1 O1 U1 N4 14(3) . .
Eu1 O1 U1 U1 -64(3) . 3_657
U1 O2 U1 O1 5.5(13) 3_657 .
U1 O2 U1 O2 0.0 3_657 3_657
U1 O2 U1 N3 -143.63(11) 3_657 .
U1 O2 U1 N2 144.25(11) 3_657 .
U1 O2 U1 N1 78.01(12) 3_657 .
U1 O2 U1 N4 -76.09(12) 3_657 .
U1 O2 U1 Eu1 -10.5(8) 3_657 .
C9 N3 U1 O1 98.1(4) . .
C12 N3 U1 O1 -54.9(3) . .
C9 N3 U1 O2 -84.3(4) . .
C12 N3 U1 O2 122.8(3) . .
C9 N3 U1 O2 -151.3(3) . 3_657
C12 N3 U1 O2 55.7(3) . 3_657
C9 N3 U1 N2 9.2(4) . .
C12 N3 U1 N2 -143.7(3) . .
C9 N3 U1 N1 32.1(4) . .
C12 N3 U1 N1 -120.9(3) . .
C9 N3 U1 N4 170.7(4) . .
C12 N3 U1 N4 17.7(3) . .
C9 N3 U1 U1 -112.3(4) . 3_657
C12 N3 U1 U1 94.8(3) . 3_657
C9 N3 U1 Eu1 99.6(4) . .
C12 N3 U1 Eu1 -53.3(3) . .
C5 N2 U1 O1 -102.4(4) . .
C2 N2 U1 O1 58.5(3) . .
C5 N2 U1 O2 80.7(4) . .
C2 N2 U1 O2 -118.4(3) . .
C5 N2 U1 O2 147.6(3) . 3_657
C2 N2 U1 O2 -51.5(3) . 3_657
C5 N2 U1 N3 -12.7(4) . .
C2 N2 U1 N3 148.2(3) . .
C5 N2 U1 N1 -174.9(4) . .
C2 N2 U1 N1 -14.0(3) . .
C5 N2 U1 N4 -37.2(4) . .
C2 N2 U1 N4 123.7(3) . .
C5 N2 U1 U1 108.3(4) . 3_657
C2 N2 U1 U1 -90.8(3) . 3_657
C5 N2 U1 Eu1 -101.6(4) . .
C2 N2 U1 Eu1 59.3(3) . .
C1 N1 U1 O1 -79.1(3) . .
C42 N1 U1 O1 69.9(3) . .
C1 N1 U1 O2 105.4(3) . .
C42 N1 U1 O2 -105.6(3) . .
C1 N1 U1 O2 175.2(3) . 3_657
C42 N1 U1 O2 -35.8(3) . 3_657
C1 N1 U1 N3 -6.9(3) . .
C42 N1 U1 N3 142.1(3) . .
C1 N1 U1 N2 17.0(3) . .
C42 N1 U1 N2 166.0(3) . .
C1 N1 U1 N4 -115.4(3) . .
C42 N1 U1 N4 33.6(4) . .
C1 N1 U1 U1 144.6(3) . 3_657
C42 N1 U1 U1 -66.4(3) . 3_657
C1 N1 U1 Eu1 -80.1(3) . .
C42 N1 U1 Eu1 68.9(3) . .
C13 N4 U1 O1 77.2(3) . .
C14 N4 U1 O1 -69.2(3) . .
C13 N4 U1 O2 -107.5(3) . .
C14 N4 U1 O2 106.1(3) . .
C13 N4 U1 O2 -176.6(3) . 3_657
C14 N4 U1 O2 37.0(3) . 3_657
C13 N4 U1 N3 -19.1(3) . .
C14 N4 U1 N3 -165.5(3) . .
C13 N4 U1 N2 6.3(4) . .
C14 N4 U1 N2 -140.1(3) . .
C13 N4 U1 N1 113.5(3) . .
C14 N4 U1 N1 -32.9(4) . .
C13 N4 U1 U1 -146.3(3) . 3_657
C14 N4 U1 U1 67.3(3) . 3_657
C13 N4 U1 Eu1 77.6(3) . .
C14 N4 U1 Eu1 -68.8(3) . .
N7 Eu1 U1 O1 -6(3) . .
N6 Eu1 U1 O1 136(3) . .
N9 Eu1 U1 O1 -115(3) . .
N5 Eu1 U1 O1 173(3) . .
N10 Eu1 U1 O1 75(3) . .
N8 Eu1 U1 O1 -46(3) . .
C33 Eu1 U1 O1 -28(3) . .
C23 Eu1 U1 O1 148(3) . .
C22 Eu1 U1 O1 162(3) . .
O1 Eu1 U1 O2 127(3) . .
N7 Eu1 U1 O2 120.7(7) . .
N6 Eu1 U1 O2 -96.5(8) . .
N9 Eu1 U1 O2 12.1(7) . .
N5 Eu1 U1 O2 -60.3(7) . .
N10 Eu1 U1 O2 -157.6(7) . .
N8 Eu1 U1 O2 81.0(7) . .
C33 Eu1 U1 O2 99.0(7) . .
C23 Eu1 U1 O2 -84.6(7) . .
C22 Eu1 U1 O2 -70.6(7) . .
O1 Eu1 U1 O2 117(3) . 3_657
N7 Eu1 U1 O2 110.39(14) . 3_657
N6 Eu1 U1 O2 -106.75(15) . 3_657
N9 Eu1 U1 O2 1.79(10) . 3_657
N5 Eu1 U1 O2 -70.53(10) . 3_657
N10 Eu1 U1 O2 -167.87(10) . 3_657
N8 Eu1 U1 O2 70.72(9) . 3_657
C33 Eu1 U1 O2 88.74(11) . 3_657
C23 Eu1 U1 O2 -94.91(12) . 3_657
C22 Eu1 U1 O2 -80.88(10) . 3_657
O1 Eu1 U1 N3 -100(3) . .
N7 Eu1 U1 N3 -106.05(15) . .
N6 Eu1 U1 N3 36.81(17) . .
N9 Eu1 U1 N3 145.35(12) . .
N5 Eu1 U1 N3 73.03(11) . .
N10 Eu1 U1 N3 -24.31(12) . .
N8 Eu1 U1 N3 -145.71(11) . .
C33 Eu1 U1 N3 -127.70(13) . .
C23 Eu1 U1 N3 48.66(13) . .
C22 Eu1 U1 N3 62.68(11) . .
O1 Eu1 U1 N2 -28(3) . .
N7 Eu1 U1 N2 -34.21(15) . .
N6 Eu1 U1 N2 108.65(16) . .
N9 Eu1 U1 N2 -142.81(12) . .
N5 Eu1 U1 N2 144.87(11) . .
N10 Eu1 U1 N2 47.53(11) . .
N8 Eu1 U1 N2 -73.88(11) . .
C33 Eu1 U1 N2 -55.86(12) . .
C23 Eu1 U1 N2 120.49(13) . .
C22 Eu1 U1 N2 134.52(11) . .
O1 Eu1 U1 N1 37(3) . .
N7 Eu1 U1 N1 30.67(15) . .
N6 Eu1 U1 N1 173.54(16) . .
N9 Eu1 U1 N1 -77.93(12) . .
N5 Eu1 U1 N1 -150.25(11) . .
N10 Eu1 U1 N1 112.41(11) . .
N8 Eu1 U1 N1 -8.99(11) . .
C33 Eu1 U1 N1 9.02(12) . .
C23 Eu1 U1 N1 -174.62(13) . .
C22 Eu1 U1 N1 -160.59(11) . .
O1 Eu1 U1 N4 -166(3) . .
N7 Eu1 U1 N4 -172.30(15) . .
N6 Eu1 U1 N4 -29.44(16) . .
N9 Eu1 U1 N4 79.10(12) . .
N5 Eu1 U1 N4 6.78(11) . .
N10 Eu1 U1 N4 -90.56(12) . .
N8 Eu1 U1 N4 148.03(11) . .
C33 Eu1 U1 N4 166.05(12) . .
C23 Eu1 U1 N4 -17.60(13) . .
C22 Eu1 U1 N4 -3.57(11) . .
O1 Eu1 U1 U1 118(3) . 3_657
N7 Eu1 U1 U1 111.14(13) . 3_657
N6 Eu1 U1 U1 -106.00(14) . 3_657
N9 Eu1 U1 U1 2.54(8) . 3_657
N5 Eu1 U1 U1 -69.78(8) . 3_657
N10 Eu1 U1 U1 -167.12(8) . 3_657
N8 Eu1 U1 U1 71.48(7) . 3_657
C33 Eu1 U1 U1 89.49(10) . 3_657
C23 Eu1 U1 U1 -94.15(10) . 3_657
C22 Eu1 U1 U1 -80.13(8) . 3_657
Eu2 O3 U2 O4 -4(3) . .
Eu2 O3 U2 O4 -12(2) . 3_776
Eu2 O3 U2 N103 132(2) . .
Eu2 O3 U2 N102 -157(2) . .
Eu2 O3 U2 N104 67(2) . .
Eu2 O3 U2 N101 -92(2) . .
Eu2 O3 U2 U2 -11(3) . 3_776
U2 O4 U2 O3 -8.7(10) 3_776 .
U2 O4 U2 O4 0.0 3_776 3_776
U2 O4 U2 N103 -144.42(11) 3_776 .
U2 O4 U2 N102 144.58(11) 3_776 .
U2 O4 U2 N104 -77.42(12) 3_776 .
U2 O4 U2 N101 77.80(12) 3_776 .
U2 O4 U2 Eu2 -9.5(6) 3_776 .
C109 N103 U2 O3 102.7(4) . .
C112 N103 U2 O3 -56.0(3) . .
C109 N103 U2 O4 -81.8(4) . .
C112 N103 U2 O4 119.5(3) . .
C109 N103 U2 O4 -147.3(3) . 3_776
C112 N103 U2 O4 53.9(3) . 3_776
C109 N103 U2 N102 13.7(4) . .
C112 N103 U2 N102 -145.1(3) . .
C109 N103 U2 N104 174.9(4) . .
C112 N103 U2 N104 16.2(3) . .
C109 N103 U2 N101 36.7(4) . .
C112 N103 U2 N101 -122.0(3) . .
C109 N103 U2 U2 -109.1(4) . 3_776
C112 N103 U2 U2 92.2(3) . 3_776
C109 N103 U2 Eu2 104.1(4) . .
C112 N103 U2 Eu2 -54.6(3) . .
C105 N102 U2 O3 -102.8(4) . .
C102 N102 U2 O3 54.7(3) . .
C105 N102 U2 O4 80.1(4) . .
C102 N102 U2 O4 -122.4(3) . .
C105 N102 U2 O4 148.1(3) . 3_776
C102 N102 U2 O4 -54.5(3) . 3_776
C105 N102 U2 N103 -12.5(4) . .
C102 N102 U2 N103 145.0(3) . .
C105 N102 U2 N104 -36.5(4) . .
C102 N102 U2 N104 121.0(3) . .
C105 N102 U2 N101 -174.2(4) . .
C102 N102 U2 N101 -16.7(3) . .
C105 N102 U2 U2 108.0(4) . 3_776
C102 N102 U2 U2 -94.5(3) . 3_776
C105 N102 U2 Eu2 -103.5(4) . .
C102 N102 U2 Eu2 54.0(3) . .
C113 N104 U2 O3 80.3(3) . .
C114 N104 U2 O3 -70.9(3) . .
C113 N104 U2 O4 -106.0(3) . .
C114 N104 U2 O4 102.8(3) . .
C113 N104 U2 O4 -175.0(3) . 3_776
C114 N104 U2 O4 33.7(3) . 3_776
C113 N104 U2 N103 -17.0(3) . .
C114 N104 U2 N103 -168.3(3) . .
C113 N104 U2 N102 7.7(3) . .
C114 N104 U2 N102 -143.6(3) . .
C113 N104 U2 N101 113.0(3) . .
C114 N104 U2 N101 -38.2(4) . .
C113 N104 U2 U2 -144.8(3) . 3_776
C114 N104 U2 U2 63.9(3) . 3_776
C113 N104 U2 Eu2 82.0(3) . .
C114 N104 U2 Eu2 -69.2(3) . .
C101 N101 U2 O3 -78.6(3) . .
C142 N101 U2 O3 69.8(3) . .
C101 N101 U2 O4 108.2(3) . .
C142 N101 U2 O4 -103.4(3) . .
C101 N101 U2 O4 177.0(3) . 3_776
C142 N101 U2 O4 -34.5(3) . 3_776
C101 N101 U2 N103 -5.5(3) . .
C142 N101 U2 N103 143.0(3) . .
C101 N101 U2 N102 18.4(3) . .
C142 N101 U2 N102 166.9(3) . .
C101 N101 U2 N104 -111.6(3) . .
C142 N101 U2 N104 36.9(4) . .
C101 N101 U2 U2 147.2(3) . 3_776
C142 N101 U2 U2 -64.3(3) . 3_776
C101 N101 U2 Eu2 -80.5(3) . .
C142 N101 U2 Eu2 67.9(3) . .
N106 Eu2 U2 O3 81(2) . .
N107 Eu2 U2 O3 -54(2) . .
N109 Eu2 U2 O3 -169(2) . .
N111 Eu2 U2 O3 24(2) . .
N110 Eu2 U2 O3 3(2) . .
N108 Eu2 U2 O3 -94(2) . .
N105 Eu2 U2 O3 121(2) . .
C123 Eu2 U2 O3 100(2) . .
C133 Eu2 U2 O3 -72(2) . .
O3 Eu2 U2 O4 177(3) . .
N106 Eu2 U2 O4 -102.3(5) . .
N107 Eu2 U2 O4 122.6(5) . .
N109 Eu2 U2 O4 8.5(5) . .
N111 Eu2 U2 O4 -159.4(6) . .
N110 Eu2 U2 O4 -179.6(6) . .
N108 Eu2 U2 O4 83.4(5) . .
N105 Eu2 U2 O4 -62.2(5) . .
C123 Eu2 U2 O4 -83.1(5) . .
C133 Eu2 U2 O4 105.0(5) . .
O3 Eu2 U2 O4 168(2) . 3_776
N106 Eu2 U2 O4 -111.41(15) . 3_776
N107 Eu2 U2 O4 113.45(15) . 3_776
N109 Eu2 U2 O4 -0.66(10) . 3_776
N111 Eu2 U2 O4 -168.6(4) . 3_776
N110 Eu2 U2 O4 171.2(4) . 3_776
N108 Eu2 U2 O4 74.23(10) . 3_776
N105 Eu2 U2 O4 -71.29(9) . 3_776
C123 Eu2 U2 O4 -92.27(12) . 3_776
C133 Eu2 U2 O4 95.84(11) . 3_776
O3 Eu2 U2 N103 -48(2) . .
N106 Eu2 U2 N103 32.85(16) . .
N107 Eu2 U2 N103 -102.29(15) . .
N109 Eu2 U2 N103 143.60(11) . .
N111 Eu2 U2 N103 -24.3(4) . .
N110 Eu2 U2 N103 -44.5(4) . .
N108 Eu2 U2 N103 -141.52(11) . .
N105 Eu2 U2 N103 72.96(11) . .
C123 Eu2 U2 N103 51.99(13) . .
C133 Eu2 U2 N103 -119.90(12) . .
O3 Eu2 U2 N102 23(2) . .
N106 Eu2 U2 N102 103.49(16) . .
N107 Eu2 U2 N102 -31.65(15) . .
N109 Eu2 U2 N102 -145.76(11) . .
N111 Eu2 U2 N102 46.3(4) . .
N110 Eu2 U2 N102 26.1(4) . .
N108 Eu2 U2 N102 -70.88(11) . .
N105 Eu2 U2 N102 143.60(11) . .
C123 Eu2 U2 N102 122.63(13) . .
C133 Eu2 U2 N102 -49.26(12) . .
O3 Eu2 U2 N104 -113(2) . .
N106 Eu2 U2 N104 -32.18(17) . .
N107 Eu2 U2 N104 -167.32(16) . .
N109 Eu2 U2 N104 78.57(11) . .
N111 Eu2 U2 N104 -89.3(4) . .
N110 Eu2 U2 N104 -109.5(4) . .
N108 Eu2 U2 N104 153.46(11) . .
N105 Eu2 U2 N104 7.94(11) . .
C123 Eu2 U2 N104 -13.04(13) . .
C133 Eu2 U2 N104 175.07(12) . .
O3 Eu2 U2 N101 87(2) . .
N106 Eu2 U2 N101 167.90(17) . .
N107 Eu2 U2 N101 32.75(16) . .
N109 Eu2 U2 N101 -81.35(11) . .
N111 Eu2 U2 N101 110.7(4) . .
N110 Eu2 U2 N101 90.5(4) . .
N108 Eu2 U2 N101 -6.47(11) . .
N105 Eu2 U2 N101 -151.99(11) . .
C123 Eu2 U2 N101 -172.97(13) . .
C133 Eu2 U2 N101 15.15(12) . .
O3 Eu2 U2 U2 169(2) . 3_776
N106 Eu2 U2 U2 -110.43(14) . 3_776
N107 Eu2 U2 U2 114.43(13) . 3_776
N109 Eu2 U2 U2 0.32(8) . 3_776
N111 Eu2 U2 U2 -167.6(4) . 3_776
N110 Eu2 U2 U2 172.2(4) . 3_776
N108 Eu2 U2 U2 75.20(8) . 3_776
N105 Eu2 U2 U2 -70.32(7) . 3_776
C123 Eu2 U2 U2 -91.29(10) . 3_776
C133 Eu2 U2 U2 96.82(9) . 3_776
O3 Eu2 N110 C152 60.2(15) . .
N106 Eu2 N110 C152 -81.5(15) . .
N107 Eu2 N110 C152 -153.4(16) . .
N109 Eu2 N110 C152 172.7(14) . .
N111 Eu2 N110 C152 -19.8(14) . .
N108 Eu2 N110 C152 140.4(15) . .
N105 Eu2 N110 C152 -15.5(16) . .
C123 Eu2 N110 C152 -62.2(15) . .
C133 Eu2 N110 C152 -175.6(15) . .
U2 Eu2 N110 C152 60.1(15) . .
O3 Eu2 N110 C148 -124.4(12) . .
N106 Eu2 N110 C148 93.9(12) . .
N107 Eu2 N110 C148 22.0(11) . .
N109 Eu2 N110 C148 -12(3) . .
N111 Eu2 N110 C148 156(2) . .
N108 Eu2 N110 C148 -44.2(12) . .
N105 Eu2 N110 C148 159.9(11) . .
C123 Eu2 N110 C148 113.2(12) . .
C133 Eu2 N110 C148 -0.3(11) . .
U2 Eu2 N110 C148 -124.5(12) . .
C152 N110 C148 C149 5(3) . .
Eu2 N110 C148 C149 -169.9(9) . .
N110 C148 C149 C150 -7(2) . .
C148 C149 C150 C151 4(4) . .
C148 N110 C152 C151 -2(3) . .
Eu2 N110 C152 C151 174.2(19) . .
C149 C150 C151 C152 -1(5) . .
N110 C152 C151 C150 -1(5) . .
O3 Eu2 N111 C157 123.3(11) . .
N106 Eu2 N111 C157 -24.3(10) . .
N107 Eu2 N111 C157 -95.7(11) . .
N109 Eu2 N111 C157 30(2) . .
N110 Eu2 N111 C157 -140(2) . .
N108 Eu2 N111 C157 -162.1(10) . .
N105 Eu2 N111 C157 43.5(11) . .
C123 Eu2 N111 C157 -2.4(11) . .
C133 Eu2 N111 C157 -116.1(11) . .
U2 Eu2 N111 C157 122.6(11) . .
O3 Eu2 N111 C153 -70.8(12) . .
N106 Eu2 N111 C153 141.7(13) . .
N107 Eu2 N111 C153 70.3(13) . .
N109 Eu2 N111 C153 -163.6(12) . .
N110 Eu2 N111 C153 25.5(13) . .
N108 Eu2 N111 C153 3.8(14) . .
N105 Eu2 N111 C153 -150.6(12) . .
C123 Eu2 N111 C153 163.6(13) . .
C133 Eu2 N111 C153 49.9(13) . .
U2 Eu2 N111 C153 -71.4(12) . .
C157 N111 C153 C154 6(3) . .
Eu2 N111 C153 C154 -162(2) . .
N111 C153 C154 C155 -4(4) . .
C157 C156 C155 C154 3(3) . .
C153 C154 C155 C156 0(4) . .
C153 N111 C157 C156 -3(2) . .
Eu2 N111 C157 C156 163.7(9) . .
C155 C156 C157 N111 -1(2) . .
