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#$Date: 2016-03-22 13:49:12 +0200 (Tue, 22 Mar 2016) $
#$Revision: 178979 $
#$URL: svn://www.crystallography.net/cod/cif/4/12/02/4120223.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4120223
loop_
_publ_author_name
'Kota Sasano'
'Jun Takaya'
'Nobuharu Iwasawa'
_publ_section_title
;
 Palladium(II)-Catalyzed Direct Carboxylation of Alkenyl C-H Bonds with
 CO2
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              10954
_journal_page_last               10957
_journal_paper_doi               10.1021/ja405503y
_journal_volume                  135
_journal_year                    2013
_chemical_formula_sum            'C34 H35 Cs O5 Pd'
_chemical_formula_weight         762.93
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.830(5)
_cell_angle_beta                 94.785(6)
_cell_angle_gamma                100.526(2)
_cell_formula_units_Z            2
_cell_length_a                   9.403(4)
_cell_length_b                   12.127(5)
_cell_length_c                   14.748(5)
_cell_measurement_reflns_used    3310
_cell_measurement_temperature    138(2)
_cell_measurement_theta_max      30.4468
_cell_measurement_theta_min      1.8322
_cell_volume                     1536.0(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      138(2)
_diffrn_measured_fraction_theta_full 0.957
_diffrn_measured_fraction_theta_max 0.957
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0493
_diffrn_reflns_av_sigmaI/netI    0.0725
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9182
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.83
_exptl_absorpt_coefficient_mu    1.812
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.5442
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.649
_exptl_crystal_description       prism
_exptl_crystal_F_000             760
_exptl_crystal_size_max          0.207
_exptl_crystal_size_mid          0.051
_exptl_crystal_size_min          0.02
_refine_diff_density_max         3.836
_refine_diff_density_min         -3.046
_refine_diff_density_rms         0.306
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.124
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         5187
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.124
_refine_ls_R_factor_all          0.1055
_refine_ls_R_factor_gt           0.0802
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1896P)²+1.1912P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2317
_refine_ls_wR_factor_ref         0.2870
_reflns_number_gt                3776
_reflns_number_total             5187
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja405503y_si_003.cif
_cod_data_source_block           shelxl
_cod_original_cell_volume        1536.1(10)
_cod_database_code               4120223
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.55490(9) 0.54137(7) 0.23526(5) 0.0265(3) Uani 1 1 d .
O1 O 0.6534(9) 0.4571(7) 0.1247(5) 0.0363(19) Uani 1 1 d .
C1 C 0.7591(12) 0.3980(10) 0.1263(8) 0.031(2) Uani 1 1 d .
C2 C 0.8239(12) 0.3644(9) 0.0435(8) 0.032(2) Uani 1 1 d .
H1 H 0.7868 0.3783 -0.0111 0.038 Uiso 1 1 calc R
C3 C 0.9446(12) 0.3097(10) 0.0389(9) 0.035(3) Uani 1 1 d .
H2 H 0.9879 0.2891 -0.0172 0.042 Uiso 1 1 calc R
C4 C 0.9969(13) 0.2876(11) 0.1202(8) 0.037(3) Uani 1 1 d .
H3 H 1.0755 0.2507 0.1192 0.044 Uiso 1 1 calc R
C5 C 0.9319(12) 0.3205(10) 0.2025(8) 0.034(3) Uani 1 1 d .
H4 H 0.9714 0.3081 0.2572 0.041 Uiso 1 1 calc R
C6 C 0.8091(11) 0.3720(9) 0.2086(7) 0.026(2) Uani 1 1 d .
C7 C 0.7402(11) 0.3991(9) 0.2974(7) 0.026(2) Uani 1 1 d .
C8 C 0.6398(11) 0.4668(9) 0.3143(7) 0.028(2) Uani 1 1 d .
H5 H 0.6067 0.4792 0.3739 0.033 Uiso 1 1 calc R
C9 C 0.7782(11) 0.3448(10) 0.3703(8) 0.030(2) Uani 1 1 d .
C10 C 0.7420(11) 0.2187(10) 0.3469(7) 0.028(2) Uani 1 1 d .
H6 H 0.7044 0.1677 0.2830 0.033 Uiso 1 1 calc R
C11 C 0.7625(14) 0.1704(12) 0.4198(9) 0.042(3) Uani 1 1 d .
H7 H 0.7353 0.0878 0.4048 0.051 Uiso 1 1 calc R
C12 C 0.8230(13) 0.2460(11) 0.5134(8) 0.035(3) Uani 1 1 d .
H8 H 0.8409 0.2140 0.5611 0.043 Uiso 1 1 calc R
C13 C 0.8567(12) 0.3670(12) 0.5367(9) 0.039(3) Uani 1 1 d .
H9 H 0.8961 0.4165 0.6007 0.046 Uiso 1 1 calc R
C14 C 0.8349(13) 0.4176(12) 0.4696(8) 0.039(3) Uani 1 1 d .
H10 H 0.8572 0.5010 0.4884 0.046 Uiso 1 1 calc R
O2 O 0.4640(9) 0.6295(7) 0.1496(5) 0.0345(18) Uani 1 1 d .
C15 C 0.4495(11) 0.7370(11) 0.2067(8) 0.032(2) Uani 1 1 d .
C16 C 0.4142(13) 0.8225(10) 0.1700(7) 0.031(2) Uani 1 1 d .
H11 H 0.4011 0.8039 0.1029 0.037 Uiso 1 1 calc R
C17 C 0.3978(13) 0.9348(10) 0.2305(9) 0.036(3) Uani 1 1 d .
H12 H 0.3750 0.9897 0.2036 0.043 Uiso 1 1 calc R
C18 C 0.4159(13) 0.9644(11) 0.3316(9) 0.037(3) Uani 1 1 d .
H13 H 0.4049 1.0387 0.3728 0.045 Uiso 1 1 calc R
C19 C 0.4503(13) 0.8809(11) 0.3689(8) 0.037(3) Uani 1 1 d .
H14 H 0.4635 0.9006 0.4362 0.045 Uiso 1 1 calc R
C20 C 0.4663(11) 0.7679(10) 0.3095(7) 0.028(2) Uani 1 1 d .
C21 C 0.4911(11) 0.6763(10) 0.3528(7) 0.028(2) Uani 1 1 d .
C22 C 0.3868(12) 0.5684(10) 0.3204(7) 0.031(2) Uani 1 1 d .
C23 C 0.5976(12) 0.7208(10) 0.4448(7) 0.029(2) Uani 1 1 d .
C24 C 0.5586(14) 0.6904(11) 0.5229(8) 0.038(3) Uani 1 1 d .
H15 H 0.4655 0.6448 0.5184 0.046 Uiso 1 1 calc R
C25 C 0.6614(15) 0.7291(11) 0.6106(9) 0.046(3) Uani 1 1 d .
H16 H 0.6360 0.7080 0.6631 0.056 Uiso 1 1 calc R
C26 C 0.7981(14) 0.7976(12) 0.6168(8) 0.046(3) Uani 1 1 d .
H17 H 0.8657 0.8234 0.6737 0.055 Uiso 1 1 calc R
C27 C 0.8346(14) 0.8277(12) 0.5382(9) 0.044(3) Uani 1 1 d .
H18 H 0.9264 0.8744 0.5413 0.052 Uiso 1 1 calc R
C28 C 0.7332(12) 0.7876(11) 0.4556(8) 0.038(3) Uani 1 1 d .
H19 H 0.7598 0.8079 0.4030 0.046 Uiso 1 1 calc R
Cs1 Cs 0.32323(7) 0.37281(6) -0.00667(4) 0.0319(3) Uani 1 1 d .
C29 C 0.4618(16) 0.1696(15) 0.1006(12) 0.059(4) Uani 1 1 d .
O3 O 0.3117(11) 0.1535(8) 0.0828(7) 0.056(3) Uani 1 1 d .
C30 C 0.2361(16) 0.0365(12) 0.0168(12) 0.060(4) Uani 1 1 d .
C31 C 0.2291(15) 0.0143(13) -0.0884(12) 0.056(4) Uani 1 1 d .
O4 O 0.1471(9) 0.0926(8) -0.1136(5) 0.040(2) Uani 1 1 d .
C32 C 0.1442(15) 0.0763(12) -0.2138(10) 0.048(3) Uani 1 1 d .
C33 C 0.0262(14) 0.1398(12) -0.2390(9) 0.044(3) Uani 1 1 d .
O5 O 0.0732(10) 0.2659(8) -0.1867(6) 0.048(2) Uani 1 1 d .
C34 C -0.0218(15) 0.3304(13) -0.2153(10) 0.052(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cs Cs -0.3680 2.1192 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C8 Pd1 O1 90.2(4) . .
C8 Pd1 C22 91.1(4) . .
O1 Pd1 C22 157.2(4) . .
C8 Pd1 O2 178.3(4) . .
O1 Pd1 O2 90.4(3) . .
C22 Pd1 O2 88.9(4) . .
C8 Pd1 C21 96.2(4) . .
O1 Pd1 C21 163.6(4) . .
C22 Pd1 C21 38.1(4) . .
O2 Pd1 C21 82.8(3) . .
C8 Pd1 Cs1 123.9(3) . .
O1 Pd1 Cs1 62.5(2) . .
C22 Pd1 Cs1 98.4(3) . .
O2 Pd1 Cs1 57.7(2) . .
C21 Pd1 Cs1 124.0(3) . .
C8 Pd1 Cs1 132.9(3) . 2_665
O1 Pd1 Cs1 48.7(2) . 2_665
C22 Pd1 Cs1 135.9(3) . 2_665
O2 Pd1 Cs1 47.0(2) . 2_665
C21 Pd1 Cs1 118.3(3) . 2_665
Cs1 Pd1 Cs1 62.65(3) . 2_665
C1 O1 Pd1 128.7(6) . .
C1 O1 Cs1 118.0(7) . 2_665
Pd1 O1 Cs1 102.3(3) . 2_665
C1 O1 Cs1 131.5(6) . .
Pd1 O1 Cs1 84.9(3) . .
Cs1 O1 Cs1 78.03(16) 2_665 .
O1 C1 C2 116.9(10) . .
O1 C1 C6 123.3(9) . .
C2 C1 C6 119.8(10) . .
O1 C1 Cs1 44.6(5) . 2_665
C2 C1 Cs1 78.3(7) . 2_665
C6 C1 Cs1 150.9(7) . 2_665
C1 C2 C3 122.2(11) . .
C1 C2 Cs1 81.3(7) . 2_665
C3 C2 Cs1 145.0(8) . 2_665
C1 C2 H1 118.9 . .
C3 C2 H1 118.9 . .
Cs1 C2 H1 46.2 2_665 .
C4 C3 C2 118.1(11) . .
C4 C3 Cs1 88.4(7) . 1_655
C2 C3 Cs1 137.3(8) . 1_655
C4 C3 H2 120.9 . .
C2 C3 H2 120.9 . .
Cs1 C3 H2 46.6 1_655 .
C5 C4 C3 119.6(11) . .
C5 C4 Cs1 145.8(8) . 1_655
C3 C4 Cs1 70.7(7) . 1_655
C5 C4 H3 120.2 . .
C3 C4 H3 120.2 . .
Cs1 C4 H3 60.4 1_655 .
C4 C5 C6 123.7(10) . .
C4 C5 H4 118.2 . .
C6 C5 H4 118.2 . .
C5 C6 C1 116.3(10) . .
C5 C6 C7 120.8(9) . .
C1 C6 C7 122.9(9) . .
C8 C7 C6 123.2(10) . .
C8 C7 C9 118.1(9) . .
C6 C7 C9 118.7(9) . .
C7 C8 Pd1 130.1(8) . .
C7 C8 H5 114.9 . .
Pd1 C8 H5 114.9 . .
C14 C9 C10 116.9(10) . .
C14 C9 C7 121.3(10) . .
C10 C9 C7 121.2(9) . .
C11 C10 C9 120.3(9) . .
C11 C10 H6 119.9 . .
C9 C10 H6 119.9 . .
C12 C11 C10 119.5(12) . .
C12 C11 H7 120.2 . .
C10 C11 H7 120.2 . .
C11 C12 C13 120.6(11) . .
C11 C12 H8 119.7 . .
C13 C12 H8 119.7 . .
C14 C13 C12 121.9(11) . .
C14 C13 H9 119.1 . .
C12 C13 H9 119.1 . .
C13 C14 C9 120.7(12) . .
C13 C14 H10 119.6 . .
C9 C14 H10 119.6 . .
C15 O2 Pd1 110.1(6) . .
C15 O2 Cs1 116.4(7) . 2_665
Pd1 O2 Cs1 102.0(3) . 2_665
C15 O2 Cs1 149.7(6) . .
Pd1 O2 Cs1 87.3(3) . .
Cs1 O2 Cs1 81.93(18) 2_665 .
O2 C15 C16 122.8(10) . .
O2 C15 C20 120.0(10) . .
C16 C15 C20 117.2(10) . .
O2 C15 Cs1 45.4(5) . 2_665
C16 C15 Cs1 91.8(7) . 2_665
C20 C15 Cs1 136.4(7) . 2_665
C15 C16 C17 122.4(10) . .
C15 C16 H11 118.8 . .
C17 C16 H11 118.8 . .
C16 C17 C18 119.9(11) . .
C16 C17 H12 120.1 . .
C18 C17 H12 120.1 . .
C19 C18 C17 118.4(11) . .
C19 C18 H13 120.8 . .
C17 C18 H13 120.8 . .
C18 C19 C20 122.5(11) . .
C18 C19 H14 118.7 . .
C20 C19 H14 118.7 . .
C19 C20 C15 119.6(10) . .
C19 C20 C21 120.5(9) . .
C15 C20 C21 119.8(9) . .
C22 C21 C23 124.1(10) . .
C22 C21 C20 116.8(9) . .
C23 C21 C20 116.6(10) . .
C22 C21 Pd1 68.9(6) . .
C23 C21 Pd1 112.8(7) . .
C20 C21 Pd1 103.3(6) . .
C21 C22 Pd1 73.0(6) . .
C28 C23 C24 117.5(10) . .
C28 C23 C21 123.2(10) . .
C24 C23 C21 119.2(10) . .
C23 C24 C25 119.9(12) . .
C23 C24 H15 120.1 . .
C25 C24 H15 120.1 . .
C26 C25 C24 119.5(12) . .
C26 C25 H16 120.2 . .
C24 C25 H16 120.2 . .
C27 C26 C25 119.6(11) . .
C27 C26 H17 120.2 . .
C25 C26 H17 120.2 . .
C28 C27 C26 118.7(13) . .
C28 C27 H18 120.7 . .
C26 C27 H18 120.7 . .
C23 C28 C27 124.7(12) . .
C23 C28 H19 117.6 . .
C27 C28 H19 117.6 . .
O2 Cs1 O1 57.2(2) 2_665 2_665
O2 Cs1 O5 87.1(2) 2_665 .
O1 Cs1 O5 71.0(2) 2_665 .
O2 Cs1 O2 98.07(18) 2_665 .
O1 Cs1 O2 75.5(2) 2_665 .
O5 Cs1 O2 135.9(2) . .
O2 Cs1 O4 96.6(2) 2_665 .
O1 Cs1 O4 119.4(2) 2_665 .
O5 Cs1 O4 52.5(2) . .
O2 Cs1 O4 163.4(2) . .
O2 Cs1 O1 74.25(19) 2_665 .
O1 Cs1 O1 101.97(16) 2_665 .
O5 Cs1 O1 160.7(2) . .
O2 Cs1 O1 54.12(19) . .
O4 Cs1 O1 123.64(19) . .
O2 Cs1 O3 113.9(2) 2_665 .
O1 Cs1 O3 169.4(2) 2_665 .
O5 Cs1 O3 104.2(2) . .
O2 Cs1 O3 113.1(2) . .
O4 Cs1 O3 53.1(2) . .
O1 Cs1 O3 79.6(2) . .
O2 Cs1 C3 149.3(2) 2_665 1_455
O1 Cs1 C3 108.4(2) 2_665 1_455
O5 Cs1 C3 62.2(3) . 1_455
O2 Cs1 C3 104.2(2) . 1_455
O4 Cs1 C3 65.4(2) . 1_455
O1 Cs1 C3 136.2(2) . 1_455
O3 Cs1 C3 76.3(2) . 1_455
O2 Cs1 Pd1 103.79(14) 2_665 .
O1 Cs1 Pd1 107.44(15) 2_665 .
O5 Cs1 Pd1 166.03(17) . .
O2 Cs1 Pd1 34.97(13) . .
O4 Cs1 Pd1 132.74(14) . .
O1 Cs1 Pd1 32.57(13) . .
O3 Cs1 Pd1 79.62(17) . .
C3 Cs1 Pd1 106.60(19) 1_455 .
O2 Cs1 C29 97.9(3) 2_665 .
O1 Cs1 C29 153.8(3) 2_665 .
O5 Cs1 C29 119.7(3) . .
O2 Cs1 C29 103.0(3) . .
O4 Cs1 C29 67.2(3) . .
O1 Cs1 C29 59.6(3) . .
O3 Cs1 C29 21.8(3) . .
C3 Cs1 C29 97.4(3) 1_455 .
Pd1 Cs1 C29 68.0(3) . .
O2 Cs1 C32 79.6(3) 2_665 .
O1 Cs1 C32 99.0(3) 2_665 .
O5 Cs1 C32 39.3(3) . .
O2 Cs1 C32 174.4(3) . .
O4 Cs1 C32 21.4(3) . .
O1 Cs1 C32 129.2(2) . .
O3 Cs1 C32 72.5(3) . .
C3 Cs1 C32 76.2(3) 1_455 .
Pd1 Cs1 C32 150.5(2) . .
C29 Cs1 C32 82.4(3) . .
O2 Cs1 C15 18.2(2) 2_665 2_665
O1 Cs1 C15 71.5(2) 2_665 2_665
O5 Cs1 C15 80.9(2) . 2_665
O2 Cs1 C15 114.4(2) . 2_665
O4 Cs1 C15 79.2(2) . 2_665
O1 Cs1 C15 79.8(2) . 2_665
O3 Cs1 C15 98.6(2) . 2_665
C3 Cs1 C15 139.4(2) 1_455 2_665
Pd1 Cs1 C15 112.06(16) . 2_665
C29 Cs1 C15 86.1(3) . 2_665
C32 Cs1 C15 64.1(3) . 2_665
O3 C29 Cs1 63.7(7) . .
C29 O3 C30 114.7(11) . .
C29 O3 Cs1 94.5(8) . .
C30 O3 Cs1 115.0(8) . .
O3 C30 C31 116.8(13) . .
O4 C31 C30 109.4(11) . .
C32 O4 C31 110.3(10) . .
C32 O4 Cs1 101.8(7) . .
C31 O4 Cs1 110.2(7) . .
O4 C32 C33 106.2(11) . .
O4 C32 Cs1 56.8(6) . .
C33 C32 Cs1 87.6(7) . .
O5 C33 C32 109.2(9) . .
C33 O5 C34 111.9(9) . .
C33 O5 Cs1 121.8(7) . .
C34 O5 Cs1 125.5(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 C8 1.907(10) .
Pd1 O1 2.007(7) .
Pd1 C22 2.104(11) .
Pd1 O2 2.130(7) .
Pd1 C21 2.157(10) .
Pd1 Cs1 3.7126(14) .
Pd1 Cs1 4.0437(15) 2_665
O1 C1 1.330(13) .
O1 Cs1 3.110(8) 2_665
O1 Cs1 3.307(8) .
C1 C2 1.380(16) .
C1 C6 1.419(14) .
C1 Cs1 3.914(11) 2_665
C2 C3 1.410(15) .
C2 Cs1 3.876(11) 2_665
C2 H1 0.9300 .
C3 C4 1.386(16) .
C3 Cs1 3.670(11) 1_655
C3 H2 0.9300 .
C4 C5 1.374(16) .
C4 Cs1 3.886(12) 1_655
C4 H3 0.9300 .
C5 C6 1.405(15) .
C5 H4 0.9300 .
C6 C7 1.473(14) .
C7 C8 1.346(14) .
C7 C9 1.490(15) .
C8 H5 0.9300 .
C9 C14 1.425(16) .
C9 C10 1.416(15) .
C10 C11 1.404(16) .
C10 H6 0.9300 .
C11 C12 1.375(17) .
C11 H7 0.9300 .
C12 C13 1.357(17) .
C12 H8 0.9300 .
C13 C14 1.349(17) .
C13 H9 0.9300 .
C14 H10 0.9300 .
O2 C15 1.329(14) .
O2 Cs1 3.022(8) 2_665
O2 Cs1 3.142(8) .
C15 C16 1.399(15) .
C15 C20 1.419(15) .
C15 Cs1 3.804(11) 2_665
C16 C17 1.396(16) .
C16 H11 0.9300 .
C17 C18 1.398(16) .
C17 H12 0.9300 .
C18 C19 1.379(17) .
C18 H13 0.9300 .
C19 C20 1.397(15) .
C19 H14 0.9300 .
C20 C21 1.499(14) .
C21 C22 1.390(16) .
C21 C23 1.488(14) .
C23 C28 1.345(16) .
C23 C24 1.380(16) .
C24 C25 1.429(15) .
C24 H15 0.9300 .
C25 C26 1.37(2) .
C25 H16 0.9300 .
C26 C27 1.381(19) .
C26 H17 0.9300 .
C27 C28 1.364(16) .
C27 H18 0.9300 .
C28 H19 0.9300 .
Cs1 O2 3.022(8) 2_665
Cs1 O1 3.110(8) 2_665
Cs1 O5 3.126(8) .
Cs1 O4 3.264(9) .
Cs1 O3 3.336(10) .
Cs1 C3 3.670(11) 1_455
Cs1 C29 3.708(15) .
Cs1 C32 3.817(13) .
Cs1 C15 3.804(11) 2_665
C29 O3 1.379(17) .
O3 C30 1.431(16) .
C30 C31 1.48(2) .
C31 O4 1.446(15) .
O4 C32 1.421(16) .
C32 C33 1.549(18) .
C33 O5 1.422(15) .
O5 C34 1.416(16) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C8 Pd1 O1 C1 -12.5(10) . .
C22 Pd1 O1 C1 -105.8(12) . .
O2 Pd1 O1 C1 165.9(9) . .
C21 Pd1 O1 C1 100.9(14) . .
Cs1 Pd1 O1 C1 -141.4(10) . .
Cs1 Pd1 O1 C1 142.1(11) 2_665 .
C8 Pd1 O1 Cs1 -154.6(4) . 2_665
C22 Pd1 O1 Cs1 112.1(9) . 2_665
O2 Pd1 O1 Cs1 23.9(3) . 2_665
C21 Pd1 O1 Cs1 -41.2(13) . 2_665
Cs1 Pd1 O1 Cs1 76.56(19) . 2_665
C8 Pd1 O1 Cs1 128.8(3) . .
C22 Pd1 O1 Cs1 35.5(9) . .
O2 Pd1 O1 Cs1 -52.7(3) . .
C21 Pd1 O1 Cs1 -117.8(12) . .
Cs1 Pd1 O1 Cs1 -76.56(19) 2_665 .
Pd1 O1 C1 C2 -170.0(8) . .
Cs1 O1 C1 C2 -32.8(12) 2_665 .
Cs1 O1 C1 C2 66.2(13) . .
Pd1 O1 C1 C6 8.2(16) . .
Cs1 O1 C1 C6 145.3(9) 2_665 .
Cs1 O1 C1 C6 -115.6(10) . .
Pd1 O1 C1 Cs1 -137.2(11) . 2_665
Cs1 O1 C1 Cs1 99.0(8) . 2_665
O1 C1 C2 C3 175.0(10) . .
C6 C1 C2 C3 -3.3(17) . .
Cs1 C1 C2 C3 152.1(11) 2_665 .
O1 C1 C2 Cs1 22.9(9) . 2_665
C6 C1 C2 Cs1 -155.4(10) . 2_665
C1 C2 C3 C4 1.2(17) . .
Cs1 C2 C3 C4 127.4(12) 2_665 .
C1 C2 C3 Cs1 -120.9(12) . 1_655
Cs1 C2 C3 Cs1 5(2) 2_665 1_655
C2 C3 C4 C5 -0.9(17) . .
Cs1 C3 C4 C5 144.1(11) 1_655 .
C2 C3 C4 Cs1 -144.9(11) . 1_655
C3 C4 C5 C6 2.8(18) . .
Cs1 C4 C5 C6 102.1(15) 1_655 .
C4 C5 C6 C1 -4.7(17) . .
C4 C5 C6 C7 176.6(11) . .
O1 C1 C6 C5 -173.4(10) . .
C2 C1 C6 C5 4.8(16) . .
Cs1 C1 C6 C5 -118.3(14) 2_665 .
O1 C1 C6 C7 5.3(17) . .
C2 C1 C6 C7 -176.5(10) . .
Cs1 C1 C6 C7 60.3(19) 2_665 .
C5 C6 C7 C8 168.0(10) . .
C1 C6 C7 C8 -10.6(17) . .
C5 C6 C7 C9 -14.7(15) . .
C1 C6 C7 C9 166.7(10) . .
C6 C7 C8 Pd1 1.8(16) . .
C9 C7 C8 Pd1 -175.5(8) . .
O1 Pd1 C8 C7 7.4(10) . .
C22 Pd1 C8 C7 164.6(11) . .
O2 Pd1 C8 C7 -104(13) . .
C21 Pd1 C8 C7 -157.5(10) . .
Cs1 Pd1 C8 C7 63.7(11) . .
Cs1 Pd1 C8 C7 -18.7(12) 2_665 .
C8 C7 C9 C14 -58.7(15) . .
C6 C7 C9 C14 123.9(11) . .
C8 C7 C9 C10 113.0(12) . .
C6 C7 C9 C10 -64.4(14) . .
C14 C9 C10 C11 -0.1(16) . .
C7 C9 C10 C11 -172.2(10) . .
C9 C10 C11 C12 -2.4(17) . .
C10 C11 C12 C13 3.0(18) . .
C11 C12 C13 C14 -1.1(18) . .
C12 C13 C14 C9 -1.5(18) . .
C10 C9 C14 C13 2.0(17) . .
C7 C9 C14 C13 174.1(11) . .
C8 Pd1 O2 C15 -38(13) . .
O1 Pd1 O2 C15 -148.8(7) . .
C22 Pd1 O2 C15 54.0(7) . .
C21 Pd1 O2 C15 16.3(7) . .
Cs1 Pd1 O2 C15 154.6(8) . .
Cs1 Pd1 O2 C15 -124.2(8) 2_665 .
C8 Pd1 O2 Cs1 86(13) . 2_665
O1 Pd1 O2 Cs1 -24.6(3) . 2_665
C22 Pd1 O2 Cs1 178.2(4) . 2_665
C21 Pd1 O2 Cs1 140.5(4) . 2_665
Cs1 Pd1 O2 Cs1 -81.2(2) . 2_665
C8 Pd1 O2 Cs1 168(13) . .
O1 Pd1 O2 Cs1 56.6(3) . .
C22 Pd1 O2 Cs1 -100.6(3) . .
C21 Pd1 O2 Cs1 -138.3(3) . .
Cs1 Pd1 O2 Cs1 81.2(2) 2_665 .
Pd1 O2 C15 C16 169.9(9) . .
Cs1 O2 C15 C16 54.4(12) 2_665 .
Cs1 O2 C15 C16 -68.2(18) . .
Pd1 O2 C15 C20 -11.8(12) . .
Cs1 O2 C15 C20 -127.3(9) 2_665 .
Cs1 O2 C15 C20 110.1(13) . .
Pd1 O2 C15 Cs1 115.4(6) . 2_665
Cs1 O2 C15 Cs1 -122.7(14) . 2_665
O2 C15 C16 C17 179.4(10) . .
C20 C15 C16 C17 1.0(16) . .
Cs1 C15 C16 C17 -145.3(10) 2_665 .
C15 C16 C17 C18 -0.5(18) . .
C16 C17 C18 C19 0.3(18) . .
C17 C18 C19 C20 -0.7(18) . .
C18 C19 C20 C15 1.2(18) . .
C18 C19 C20 C21 -174.7(11) . .
O2 C15 C20 C19 -179.8(10) . .
C16 C15 C20 C19 -1.3(16) . .
Cs1 C15 C20 C19 125.0(10) 2_665 .
O2 C15 C20 C21 -3.8(15) . .
C16 C15 C20 C21 174.6(10) . .
Cs1 C15 C20 C21 -59.0(15) 2_665 .
C19 C20 C21 C22 119.4(12) . .
C15 C20 C21 C22 -56.5(13) . .
C19 C20 C21 C23 -43.4(14) . .
C15 C20 C21 C23 140.7(10) . .
C19 C20 C21 Pd1 -167.7(9) . .
C15 C20 C21 Pd1 16.3(11) . .
C8 Pd1 C21 C22 -83.8(7) . .
O1 Pd1 C21 C22 163.6(10) . .
O2 Pd1 C21 C22 97.5(6) . .
Cs1 Pd1 C21 C22 54.8(7) . .
Cs1 Pd1 C21 C22 129.4(5) 2_665 .
C8 Pd1 C21 C23 35.5(8) . .
O1 Pd1 C21 C23 -77.1(15) . .
C22 Pd1 C21 C23 119.3(10) . .
O2 Pd1 C21 C23 -143.1(8) . .
Cs1 Pd1 C21 C23 174.2(6) . .
Cs1 Pd1 C21 C23 -111.3(7) 2_665 .
C8 Pd1 C21 C20 162.2(7) . .
O1 Pd1 C21 C20 49.7(15) . .
C22 Pd1 C21 C20 -114.0(9) . .
O2 Pd1 C21 C20 -16.4(7) . .
Cs1 Pd1 C21 C20 -59.1(8) . .
Cs1 Pd1 C21 C20 15.5(8) 2_665 .
C23 C21 C22 Pd1 -104.0(10) . .
C20 C21 C22 Pd1 94.6(8) . .
C8 Pd1 C22 C21 98.7(6) . .
O1 Pd1 C22 C21 -168.2(8) . .
O2 Pd1 C22 C21 -79.6(6) . .
Cs1 Pd1 C22 C21 -136.8(6) . .
Cs1 Pd1 C22 C21 -77.7(7) 2_665 .
C22 C21 C23 C28 147.9(12) . .
C20 C21 C23 C28 -50.6(15) . .
Pd1 C21 C23 C28 68.7(13) . .
C22 C21 C23 C24 -30.4(16) . .
C20 C21 C23 C24 131.0(11) . .
Pd1 C21 C23 C24 -109.7(10) . .
C28 C23 C24 C25 -0.5(17) . .
C21 C23 C24 C25 178.0(10) . .
C23 C24 C25 C26 0.7(18) . .
C24 C25 C26 C27 -0.2(19) . .
C25 C26 C27 C28 -0.4(18) . .
C24 C23 C28 C27 -0.2(19) . .
C21 C23 C28 C27 -178.6(11) . .
C26 C27 C28 C23 1(2) . .
C15 O2 Cs1 O2 130.4(14) . 2_665
Pd1 O2 Cs1 O2 -102.5(3) . 2_665
Cs1 O2 Cs1 O2 0.0 2_665 2_665
C15 O2 Cs1 O1 77.4(13) . 2_665
Pd1 O2 Cs1 O1 -155.6(3) . 2_665
Cs1 O2 Cs1 O1 -53.02(19) 2_665 2_665
C15 O2 Cs1 O5 36.2(15) . .
Pd1 O2 Cs1 O5 163.2(3) . .
Cs1 O2 Cs1 O5 -94.2(3) 2_665 .
C15 O2 Cs1 O4 -77.7(15) . .
Pd1 O2 Cs1 O4 49.4(8) . .
Cs1 O2 Cs1 O4 151.9(6) 2_665 .
C15 O2 Cs1 O1 -165.8(14) . .
Pd1 O2 Cs1 O1 -38.7(2) . .
Cs1 O2 Cs1 O1 63.8(2) 2_665 .
C15 O2 Cs1 O3 -109.3(13) . .
Pd1 O2 Cs1 O3 17.8(3) . .
Cs1 O2 Cs1 O3 120.3(2) 2_665 .
C15 O2 Cs1 C3 -28.4(14) . 1_455
Pd1 O2 Cs1 C3 98.7(3) . 1_455
Cs1 O2 Cs1 C3 -158.8(2) 2_665 1_455
C15 O2 Cs1 Pd1 -127.1(14) . .
Cs1 O2 Cs1 Pd1 102.5(3) 2_665 .
C15 O2 Cs1 C29 -129.5(13) . .
Pd1 O2 Cs1 C29 -2.5(3) . .
Cs1 O2 Cs1 C29 100.1(3) 2_665 .
C15 O2 Cs1 C32 66(3) . .
Pd1 O2 Cs1 C32 -167(3) . .
Cs1 O2 Cs1 C32 -64(3) 2_665 .
C15 O2 Cs1 C15 138.9(12) . 2_665
Pd1 O2 Cs1 C15 -94.1(3) . 2_665
Cs1 O2 Cs1 C15 8.5(3) 2_665 2_665
C1 O1 Cs1 O2 -66.3(9) . 2_665
Pd1 O1 Cs1 O2 154.3(3) . 2_665
Cs1 O1 Cs1 O2 50.60(18) 2_665 2_665
C1 O1 Cs1 O1 -116.9(9) . 2_665
Pd1 O1 Cs1 O1 103.7(3) . 2_665
Cs1 O1 Cs1 O1 0.0 2_665 2_665
C1 O1 Cs1 O5 -50.8(12) . .
Pd1 O1 Cs1 O5 169.9(5) . .
Cs1 O1 Cs1 O5 66.2(7) 2_665 .
C1 O1 Cs1 O2 -178.9(9) . .
Pd1 O1 Cs1 O2 41.7(2) . .
Cs1 O1 Cs1 O2 -62.0(2) 2_665 .
C1 O1 Cs1 O4 21.2(9) . .
Pd1 O1 Cs1 O4 -118.2(2) . .
Cs1 O1 Cs1 O4 138.08(19) 2_665 .
C1 O1 Cs1 O3 52.3(9) . .
Pd1 O1 Cs1 O3 -87.0(3) . .
Cs1 O1 Cs1 O3 169.3(2) 2_665 .
C1 O1 Cs1 C3 109.5(9) . 1_455
Pd1 O1 Cs1 C3 -29.8(4) . 1_455
Cs1 O1 Cs1 C3 -133.5(3) 2_665 1_455
C1 O1 Cs1 Pd1 139.4(10) . .
Cs1 O1 Cs1 Pd1 -103.7(3) 2_665 .
C1 O1 Cs1 C29 42.9(9) . .
Pd1 O1 Cs1 C29 -96.4(4) . .
Cs1 O1 Cs1 C29 159.9(4) 2_665 .
C1 O1 Cs1 C32 -4.6(10) . .
Pd1 O1 Cs1 C32 -143.9(3) . .
Cs1 O1 Cs1 C32 112.3(3) 2_665 .
C1 O1 Cs1 C15 -48.5(9) . 2_665
Pd1 O1 Cs1 C15 172.1(3) . 2_665
Cs1 O1 Cs1 C15 68.4(2) 2_665 2_665
C8 Pd1 Cs1 O2 -95.2(4) . 2_665
O1 Pd1 Cs1 O2 -25.4(3) . 2_665
C22 Pd1 Cs1 O2 167.7(3) . 2_665
O2 Pd1 Cs1 O2 84.3(3) . 2_665
C21 Pd1 Cs1 O2 137.1(4) . 2_665
Cs1 Pd1 Cs1 O2 29.93(15) 2_665 2_665
C8 Pd1 Cs1 O1 -154.8(4) . 2_665
O1 Pd1 Cs1 O1 -85.0(3) . 2_665
C22 Pd1 Cs1 O1 108.2(3) . 2_665
O2 Pd1 Cs1 O1 24.8(3) . 2_665
C21 Pd1 Cs1 O1 77.5(4) . 2_665
Cs1 Pd1 Cs1 O1 -29.59(15) 2_665 2_665
C8 Pd1 Cs1 O5 124.1(8) . .
O1 Pd1 Cs1 O5 -166.1(8) . .
C22 Pd1 Cs1 O5 27.0(8) . .
O2 Pd1 Cs1 O5 -56.3(8) . .
C21 Pd1 Cs1 O5 -3.6(8) . .
Cs1 Pd1 Cs1 O5 -110.7(7) 2_665 .
C8 Pd1 Cs1 O2 -179.6(5) . .
O1 Pd1 Cs1 O2 -109.8(4) . .
C22 Pd1 Cs1 O2 83.4(4) . .
C21 Pd1 Cs1 O2 52.7(4) . .
Cs1 Pd1 Cs1 O2 -54.4(2) 2_665 .
C8 Pd1 Cs1 O4 17.6(4) . .
O1 Pd1 Cs1 O4 87.4(3) . .
C22 Pd1 Cs1 O4 -79.5(4) . .
O2 Pd1 Cs1 O4 -162.8(3) . .
C21 Pd1 Cs1 O4 -110.1(4) . .
Cs1 Pd1 Cs1 O4 142.8(2) 2_665 .
C8 Pd1 Cs1 O1 -69.8(5) . .
C22 Pd1 Cs1 O1 -166.9(4) . .
O2 Pd1 Cs1 O1 109.8(4) . .
C21 Pd1 Cs1 O1 162.5(4) . .
Cs1 Pd1 Cs1 O1 55.4(3) 2_665 .
C8 Pd1 Cs1 O3 17.0(4) . .
O1 Pd1 Cs1 O3 86.8(3) . .
C22 Pd1 Cs1 O3 -80.0(4) . .
O2 Pd1 Cs1 O3 -163.4(3) . .
C21 Pd1 Cs1 O3 -110.7(4) . .
Cs1 Pd1 Cs1 O3 142.20(18) 2_665 .
C8 Pd1 Cs1 C3 89.2(4) . 1_455
O1 Pd1 Cs1 C3 159.0(3) . 1_455
C22 Pd1 Cs1 C3 -7.9(4) . 1_455
O2 Pd1 Cs1 C3 -91.3(3) . 1_455
C21 Pd1 Cs1 C3 -38.5(4) . 1_455
Cs1 Pd1 Cs1 C3 -145.66(18) 2_665 1_455
C8 Pd1 Cs1 C29 -2.2(5) . .
O1 Pd1 Cs1 C29 67.6(4) . .
C22 Pd1 Cs1 C29 -99.3(4) . .
O2 Pd1 Cs1 C29 177.4(4) . .
C21 Pd1 Cs1 C29 -129.9(5) . .
Cs1 Pd1 Cs1 C29 123.0(3) 2_665 .
C8 Pd1 Cs1 C32 -2.1(6) . .
O1 Pd1 Cs1 C32 67.7(5) . .
C22 Pd1 Cs1 C32 -99.2(6) . .
O2 Pd1 Cs1 C32 177.4(5) . .
C21 Pd1 Cs1 C32 -129.8(6) . .
Cs1 Pd1 Cs1 C32 123.0(5) 2_665 .
C8 Pd1 Cs1 C15 -78.1(4) . 2_665
O1 Pd1 Cs1 C15 -8.3(3) . 2_665
C22 Pd1 Cs1 C15 -175.2(4) . 2_665
O2 Pd1 Cs1 C15 101.4(3) . 2_665
C21 Pd1 Cs1 C15 154.2(4) . 2_665
Cs1 Pd1 Cs1 C15 47.03(19) 2_665 2_665
O2 Cs1 C29 O3 -139.1(8) 2_665 .
O1 Cs1 C29 O3 -155.9(6) 2_665 .
O5 Cs1 C29 O3 -47.9(10) . .
O2 Cs1 C29 O3 120.6(8) . .
O4 Cs1 C29 O3 -45.2(8) . .
O1 Cs1 C29 O3 154.3(10) . .
C3 Cs1 C29 O3 14.1(9) 1_455 .
Pd1 Cs1 C29 O3 119.1(9) . .
C32 Cs1 C29 O3 -60.9(9) . .
C15 Cs1 C29 O3 -125.2(9) 2_665 .
Cs1 C29 O3 C30 120.2(11) . .
O2 Cs1 O3 C29 45.1(9) 2_665 .
O1 Cs1 O3 C29 76.9(15) 2_665 .
O5 Cs1 O3 C29 138.3(9) . .
O2 Cs1 O3 C29 -65.7(9) . .
O4 Cs1 O3 C29 125.1(9) . .
O1 Cs1 O3 C29 -22.3(9) . .
C3 Cs1 O3 C29 -165.6(9) 1_455 .
Pd1 Cs1 O3 C29 -55.5(9) . .
C32 Cs1 O3 C29 114.8(9) . .
C15 Cs1 O3 C29 55.5(9) 2_665 .
O2 Cs1 O3 C30 -74.8(9) 2_665 .
O1 Cs1 O3 C30 -43.0(17) 2_665 .
O5 Cs1 O3 C30 18.4(10) . .
O2 Cs1 O3 C30 174.3(9) . .
O4 Cs1 O3 C30 5.1(9) . .
O1 Cs1 O3 C30 -142.3(9) . .
C3 Cs1 O3 C30 74.5(9) 1_455 .
Pd1 Cs1 O3 C30 -175.4(9) . .
C29 Cs1 O3 C30 -119.9(14) . .
C32 Cs1 O3 C30 -5.2(9) . .
C15 Cs1 O3 C30 -64.4(9) 2_665 .
C29 O3 C30 C31 -82.6(15) . .
Cs1 O3 C30 C31 25.5(15) . .
O3 C30 C31 O4 -63.6(16) . .
C30 C31 O4 C32 177.6(11) . .
C30 C31 O4 Cs1 65.9(12) . .
O2 Cs1 O4 C32 -37.1(7) 2_665 .
O1 Cs1 O4 C32 18.8(7) 2_665 .
O5 Cs1 O4 C32 44.1(7) . .
O2 Cs1 O4 C32 170.9(7) . .
O1 Cs1 O4 C32 -112.6(7) . .
O3 Cs1 O4 C32 -152.1(8) . .
C3 Cs1 O4 C32 116.9(7) 1_455 .
Pd1 Cs1 O4 C32 -152.8(6) . .
C29 Cs1 O4 C32 -132.9(8) . .
C15 Cs1 O4 C32 -42.6(7) 2_665 .
O2 Cs1 O4 C31 79.9(8) 2_665 .
O1 Cs1 O4 C31 135.9(8) 2_665 .
O5 Cs1 O4 C31 161.2(9) . .
O2 Cs1 O4 C31 -72.1(11) . .
O1 Cs1 O4 C31 4.5(9) . .
O3 Cs1 O4 C31 -35.0(8) . .
C3 Cs1 O4 C31 -126.0(9) 1_455 .
Pd1 Cs1 O4 C31 -35.8(9) . .
C29 Cs1 O4 C31 -15.8(8) . .
C32 Cs1 O4 C31 117.1(11) . .
C15 Cs1 O4 C31 74.4(8) 2_665 .
C31 O4 C32 C33 167.1(10) . .
Cs1 O4 C32 C33 -76.0(9) . .
C31 O4 C32 Cs1 -116.9(9) . .
O2 Cs1 C32 O4 142.5(7) 2_665 .
O1 Cs1 C32 O4 -163.5(7) 2_665 .
O5 Cs1 C32 O4 -119.2(9) . .
O2 Cs1 C32 O4 -152(2) . .
O1 Cs1 C32 O4 82.9(7) . .
O3 Cs1 C32 O4 23.1(6) . .
C3 Cs1 C32 O4 -56.6(7) 1_455 .
Pd1 Cs1 C32 O4 42.9(10) . .
C29 Cs1 C32 O4 43.0(7) . .
C15 Cs1 C32 O4 132.3(7) 2_665 .
O2 Cs1 C32 C33 -106.4(8) 2_665 .
O1 Cs1 C32 C33 -52.3(8) 2_665 .
O5 Cs1 C32 C33 -8.0(7) . .
O2 Cs1 C32 C33 -41(3) . .
O4 Cs1 C32 C33 111.2(11) . .
O1 Cs1 C32 C33 -165.9(7) . .
O3 Cs1 C32 C33 134.3(8) . .
C3 Cs1 C32 C33 54.6(8) 1_455 .
Pd1 Cs1 C32 C33 154.1(6) . .
C29 Cs1 C32 C33 154.1(8) . .
C15 Cs1 C32 C33 -116.5(8) 2_665 .
O4 C32 C33 O5 66.2(13) . .
Cs1 C32 C33 O5 11.8(9) . .
C32 C33 O5 C34 173.1(12) . .
C32 C33 O5 Cs1 -17.1(14) . .
O2 Cs1 O5 C33 87.2(9) 2_665 .
O1 Cs1 O5 C33 143.4(9) 2_665 .
O2 Cs1 O5 C33 -174.1(8) . .
O4 Cs1 O5 C33 -13.4(8) . .
O1 Cs1 O5 C33 72.2(12) . .
O3 Cs1 O5 C33 -26.7(9) . .
C3 Cs1 O5 C33 -92.5(9) 1_455 .
Pd1 Cs1 O5 C33 -130.8(8) . .
C29 Cs1 O5 C33 -10.2(10) . .
C32 Cs1 O5 C33 10.3(8) . .
C15 Cs1 O5 C33 70.0(9) 2_665 .
O2 Cs1 O5 C34 -104.4(10) 2_665 .
O1 Cs1 O5 C34 -48.2(10) 2_665 .
O2 Cs1 O5 C34 -5.8(12) . .
O4 Cs1 O5 C34 155.0(11) . .
O1 Cs1 O5 C34 -119.4(11) . .
O3 Cs1 O5 C34 141.6(10) . .
C3 Cs1 O5 C34 75.9(10) 1_455 .
Pd1 Cs1 O5 C34 37.5(15) . .
C29 Cs1 O5 C34 158.1(10) . .
C32 Cs1 O5 C34 178.6(12) . .
C15 Cs1 O5 C34 -121.7(10) 2_665 .
