#------------------------------------------------------------------------------
#$Date: 2016-03-22 21:15:57 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179016 $
#$URL: svn://www.crystallography.net/cod/cif/4/12/14/4121446.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4121446
loop_
_publ_author_name
'Yeon, Jeongho'
'Smith, Mark D.'
'Tapp, Joshua'
'Möller, Angela'
'Zur Loye, Hans-Conrad'
_publ_section_title
;
 Application of a Mild Hydrothermal Approach Containing an in Situ
 Reduction Step to the Growth of Single Crystals of the Quaternary
 U(IV)-Containing Fluorides Na4MU6F30 (M = Mn(2+), Co(2+), Ni(2+), Cu(2+),
 and Zn(2+)) Crystal Growth, Structures, and Magnetic Properties.
;
_journal_issue                   10
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              3955
_journal_page_last               3963
_journal_paper_doi               10.1021/ja412725r
_journal_volume                  136
_journal_year                    2014
_chemical_formula_moiety         'Co F30 Na4 U6'
_chemical_formula_sum            'Co F30 Na4 U6'
_chemical_formula_weight         2149.07
_chemical_name_systematic
;
 ? 
;
_space_group_crystal_system      trigonal
_space_group_IT_number           165
_space_group_name_Hall           '-P 3 2"c'
_space_group_name_H-M_alt        'P -3 c 1'
_symmetry_space_group_name_Hall  '-P 3 2"c'
_symmetry_space_group_name_H-M   'P -3 c 1'
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   difmap
_audit_creation_date             2013-02-18
_audit_creation_method
;
  Olex2 1.2
  (compiled Dec  5 2012 16:17:34, GUI svn.r4385)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   9.8882(3)
_cell_length_b                   9.8882(3)
_cell_length_c                   13.0152(9)
_cell_measurement_reflns_used    7320
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      34.81
_cell_measurement_theta_min      2.38
_cell_volume                     1102.09(9)
_computing_cell_refinement       'SAINT v6.45A (Bruker, 2003)'
_computing_data_reduction        'SAINT v6.45A (Bruker, 2003)'
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
SHELXL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
olex2.solve (L.J. Bourhis, O.V. Dolomanov, R.J. Gildea, J.A.K. Howard,
H. Puschmann, in preparation, 2011)
;
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0565
_diffrn_reflns_av_unetI/netI     0.0233
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            28190
_diffrn_reflns_theta_full        35.04
_diffrn_reflns_theta_max         35.04
_diffrn_reflns_theta_min         2.38
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           37.0
_diffrn_source_power             1.739
_diffrn_source_target            Mo
_diffrn_source_voltage           47.0
_exptl_absorpt_coefficient_mu    44.973
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.282664
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS v.2.10 (Bruker,2003) was used for absorption correction.
R(int) was 0.2686 before and 0.0521 after correction.
The Ratio of minimum to maximum transmission is 0.2827.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            'light green'
_exptl_crystal_density_diffrn    6.476
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'hexagonal plate'
_exptl_crystal_F_000             1786
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.04
_refine_diff_density_max         6.067
_refine_diff_density_min         -2.152
_refine_diff_density_rms         0.421
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.148
_refine_ls_matrix_type           full
_refine_ls_number_parameters     66
_refine_ls_number_reflns         1635
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.148
_refine_ls_R_factor_all          0.0342
_refine_ls_R_factor_gt           0.0304
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0293P)²+18.1029P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0676
_refine_ls_wR_factor_ref         0.0689
_reflns_number_gt                1531
_reflns_number_total             1635
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja412725r_si_002.cif
_cod_data_source_block           Na4CoU6F30
_cod_database_code               4121446
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-y, x-y, z'
3 '-x+y, -x, z'
4 'x-y, -y, -z+1/2'
5 '-x, -x+y, -z+1/2'
6 'y, x, -z+1/2'
7 '-x, -y, -z'
8 'y, -x+y, -z'
9 'x-y, x, -z'
10 '-x+y, y, z-1/2'
11 'x, x-y, z-1/2'
12 '-y, -x, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
U1 U 0.39872(2) 0.32341(2) 0.398514(15) 0.00663(7) Uani 1 1 d .
Co1 Co 0.0000 0.0000 0.2500 0.0098(3) Uani 1 6 d S
Na1 Na 0.3333 0.6667 0.3404(3) 0.0105(8) Uani 1 3 d S
Na2 Na 0.0000 0.0000 0.5000 0.0244(15) Uani 1 6 d S
Na3 Na 0.037(2) 0.338(3) 0.2857(17) 0.028(4) Uiso 0.16667 1 d P
F1 F 0.3056(5) 0.4376(4) 0.2833(3) 0.0127(7) Uani 1 1 d .
F2 F 0.1901(4) 0.3106(4) 0.4797(3) 0.0110(6) Uani 1 1 d .
F3 F 0.5319(4) 0.4136(4) 0.5523(3) 0.0108(6) Uani 1 1 d .
F4 F 0.1904(4) 0.1058(5) 0.3403(3) 0.0141(7) Uani 1 1 d .
F5 F 0.5112(5) 0.1696(5) 0.3631(3) 0.0143(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
U U -9.6767 9.6646 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Na3 U1 Na3 107.2(2) 6 2_665
Na3 U1 Na3 124.3(7) 3 2_665
Na3 U1 Na3 18.3(7) 3 6
F1 U1 Na3 67.5(4) 6 2_665
F1 U1 Na3 59.7(4) . 2_665
F1 U1 Na3 41.0(4) 6 6
F1 U1 Na3 90.1(4) . 6
F1 U1 Na3 59.3(4) 6 3
F1 U1 Na3 104.4(4) . 3
F1 U1 F1 61.36(16) . 6
F1 U1 F2 141.22(14) . 8_556
F1 U1 F3 111.52(13) 6 7_666
F1 U1 F3 67.47(12) . 7_666
F1 U1 F5 128.45(13) . .
F2 U1 Na3 119.2(4) . 6
F2 U1 Na3 156.7(4) 8_556 2_665
F2 U1 Na3 114.6(3) . 2_665
F2 U1 Na3 67.7(4) 8_556 3
F2 U1 Na3 86.0(4) 8_556 6
F2 U1 Na3 111.0(4) . 3
F2 U1 F1 126.93(13) 8_556 6
F2 U1 F1 128.80(13) . 6
F2 U1 F1 75.96(13) . .
F2 U1 F2 72.51(14) . 8_556
F2 U1 F3 72.40(13) . 7_666
F2 U1 F3 86.83(13) . .
F2 U1 F3 121.53(12) 8_556 7_666
F2 U1 F5 142.76(14) . 3_665
F2 U1 F5 140.61(14) . .
F3 U1 Na3 152.4(4) 7_666 6
F3 U1 Na3 137.1(4) . 6
F3 U1 Na3 170.6(4) 7_666 3
F3 U1 Na3 124.5(4) . 3
F3 U1 Na3 48.1(3) 7_666 2_665
F3 U1 Na3 88.7(4) . 2_665
F3 U1 F1 142.51(13) . 6
F3 U1 F1 131.09(13) . .
F3 U1 F2 69.11(13) . 8_556
F3 U1 F3 63.70(14) . 7_666
F3 U1 F5 93.27(13) . .
F4 U1 Na3 39.6(4) . 3
F4 U1 Na3 134.0(4) . 2_665
F4 U1 Na3 45.0(4) . 6
F4 U1 F1 72.69(14) . 6
F4 U1 F1 81.46(14) . .
F4 U1 F2 68.78(13) . 8_556
F4 U1 F2 74.32(14) . .
F4 U1 F3 137.32(14) . .
F4 U1 F3 138.79(13) . 7_666
F4 U1 F5 79.40(14) . .
F4 U1 F5 141.21(14) . 3_665
F5 U1 Na3 44.6(4) . 6
F5 U1 Na3 104.8(4) . 2_665
F5 U1 Na3 96.7(4) 3_665 6
F5 U1 Na3 40.2(4) . 3
F5 U1 Na3 106.3(4) 3_665 3
F5 U1 Na3 38.0(4) 3_665 2_665
F5 U1 F1 72.15(14) 3_665 6
F5 U1 F1 67.31(13) . 6
F5 U1 F1 95.62(14) 3_665 .
F5 U1 F2 70.85(13) . 8_556
F5 U1 F2 123.16(14) 3_665 8_556
F5 U1 F3 70.91(13) 3_665 7_666
F5 U1 F3 71.43(14) 3_665 .
F5 U1 F3 141.30(13) . 7_666
F5 U1 F5 72.4(2) 3_665 .
Na3 Co1 Na3 117.94(19) 3 .
Na3 Co1 Na3 131.9(7) 2 6
Na3 Co1 Na3 117.94(19) 4 6
Na3 Co1 Na3 117.94(19) 2 .
Na3 Co1 Na3 20.1(7) 5 .
Na3 Co1 Na3 109.5(8) 6 .
Na3 Co1 Na3 131.9(7) 4 .
Na3 Co1 Na3 20.1(7) 4 2
Na3 Co1 Na3 109.5(8) 2 5
Na3 Co1 Na3 20.1(7) 3 6
Na3 Co1 Na3 117.94(19) 4 5
Na3 Co1 Na3 131.9(7) 3 5
Na3 Co1 Na3 117.94(19) 2 3
Na3 Co1 Na3 109.5(8) 4 3
Na3 Co1 Na3 117.94(19) 6 5
F4 Co1 Na3 51.3(4) 3 4
F4 Co1 Na3 45.1(4) 5 4
F4 Co1 Na3 131.8(4) 6 4
F4 Co1 Na3 139.9(4) . 4
F4 Co1 Na3 45.1(4) 3 2
F4 Co1 Na3 131.8(4) 2 3
F4 Co1 Na3 77.6(4) 4 4
F4 Co1 Na3 96.5(4) 2 4
F4 Co1 Na3 51.3(4) 5 2
F4 Co1 Na3 131.8(4) . 2
F4 Co1 Na3 96.5(4) 4 2
F4 Co1 Na3 139.9(4) 5 3
F4 Co1 Na3 77.6(4) 2 2
F4 Co1 Na3 51.3(4) 4 3
F4 Co1 Na3 139.9(4) 6 2
F4 Co1 Na3 77.6(4) 3 3
F4 Co1 Na3 96.5(4) 6 3
F4 Co1 Na3 45.1(4) . 3
F4 Co1 Na3 51.3(4) . 6
F4 Co1 Na3 45.1(4) 2 .
F4 Co1 Na3 139.9(4) 4 .
F4 Co1 Na3 77.6(4) . .
F4 Co1 Na3 131.8(4) 5 6
F4 Co1 Na3 45.1(4) 4 6
F4 Co1 Na3 139.9(4) 2 6
F4 Co1 Na3 96.5(4) 3 6
F4 Co1 Na3 77.6(4) 6 6
F4 Co1 Na3 139.9(4) 3 5
F4 Co1 Na3 45.1(4) 6 5
F4 Co1 Na3 96.5(4) . 5
F4 Co1 Na3 131.8(4) 4 5
F4 Co1 Na3 77.6(4) 5 5
F4 Co1 Na3 51.3(4) 6 .
F4 Co1 Na3 131.8(4) 3 .
F4 Co1 Na3 51.3(4) 2 5
F4 Co1 Na3 96.5(4) 5 .
F4 Co1 F4 174.1(2) 4 2
F4 Co1 F4 89.34(16) . 2
F4 Co1 F4 95.0(2) 6 2
F4 Co1 F4 89.34(16) 3 2
F4 Co1 F4 86.6(2) 5 2
F4 Co1 F4 95.0(2) . 4
F4 Co1 F4 89.34(16) 6 4
F4 Co1 F4 86.6(2) 3 4
F4 Co1 F4 89.34(16) 5 4
F4 Co1 F4 86.6(2) 6 .
F4 Co1 F4 89.34(16) 3 .
F4 Co1 F4 174.1(2) 5 .
F4 Co1 F4 174.1(2) 3 6
F4 Co1 F4 89.34(16) 5 6
F4 Co1 F4 95.0(2) 5 3
U1 Na1 U1 116.21(4) 3_565 2_665
U1 Na1 U1 116.21(4) 2_665 .
U1 Na1 U1 116.21(4) 3_565 .
Na3 Na1 U1 61.1(4) 2_665 .
Na3 Na1 U1 67.5(4) . .
Na3 Na1 U1 176.3(4) 3_565 .
Na3 Na1 U1 176.3(4) 2_665 3_565
Na3 Na1 U1 61.1(4) . 3_565
Na3 Na1 U1 67.5(4) 3_565 3_565
Na3 Na1 U1 61.1(4) 3_565 2_665
Na3 Na1 U1 67.5(4) 2_665 2_665
Na3 Na1 U1 176.3(4) . 2_665
Na3 Na1 Na3 115.1(3) 3_565 2_665
Na3 Na1 Na3 115.1(3) . 2_665
Na3 Na1 Na3 115.1(3) 3_565 .
F1 Na1 U1 107.78(10) 2_665 .
F1 Na1 U1 135.95(11) . 2_665
F1 Na1 U1 135.95(11) 3_565 .
F1 Na1 U1 33.88(10) 2_665 2_665
F1 Na1 U1 33.88(10) . .
F1 Na1 U1 107.78(10) . 3_565
F1 Na1 U1 107.78(10) 3_565 2_665
F1 Na1 U1 33.88(10) 3_565 3_565
F1 Na1 U1 135.95(11) 2_665 3_565
F1 Na1 Na3 46.9(4) . .
F1 Na1 Na3 46.9(4) 3_565 3_565
F1 Na1 Na3 146.0(4) 2_665 .
F1 Na1 Na3 68.5(4) 3_565 .
F1 Na1 Na3 68.5(4) 2_665 3_565
F1 Na1 Na3 46.9(4) 2_665 2_665
F1 Na1 Na3 68.5(4) . 2_665
F1 Na1 Na3 146.0(4) . 3_565
F1 Na1 Na3 146.0(4) 3_565 2_665
F1 Na1 F1 109.80(14) 2_665 .
F1 Na1 F1 109.80(14) 3_565 .
F1 Na1 F1 109.80(13) 3_565 2_665
F1 Na1 F3 70.10(13) . 7_666
F1 Na1 F3 157.8(2) . 8_566
F1 Na1 F3 90.29(14) 2_665 7_666
F1 Na1 F3 157.8(2) 3_565 7_666
F1 Na1 F3 70.10(13) 2_665 8_566
F1 Na1 F3 70.10(13) 3_565 9_556
F1 Na1 F3 157.8(2) 2_665 9_556
F1 Na1 F3 90.29(14) 3_565 8_566
F1 Na1 F3 90.29(14) . 9_556
F3 Na1 U1 36.95(9) 9_556 3_565
F3 Na1 U1 83.39(10) 8_566 3_565
F3 Na1 U1 36.95(9) 8_566 2_665
F3 Na1 U1 124.01(15) 7_666 3_565
F3 Na1 U1 124.01(15) 9_556 2_665
F3 Na1 U1 124.01(15) 8_566 .
F3 Na1 U1 83.39(10) 7_666 2_665
F3 Na1 U1 36.95(9) 7_666 .
F3 Na1 U1 83.39(10) 9_556 .
F3 Na1 Na3 141.9(4) 9_556 2_665
F3 Na1 Na3 55.8(4) 7_666 2_665
F3 Na1 Na3 100.3(4) 7_666 .
F3 Na1 Na3 100.3(4) 8_566 2_665
F3 Na1 Na3 55.8(4) 9_556 .
F3 Na1 Na3 141.9(4) 7_666 3_565
F3 Na1 Na3 141.9(4) 8_566 .
F3 Na1 Na3 55.8(4) 8_566 3_565
F3 Na1 Na3 100.3(4) 9_556 3_565
F3 Na1 F3 87.70(18) 9_556 7_666
F3 Na1 F3 87.70(18) 8_566 7_666
F3 Na1 F3 87.70(18) 8_566 9_556
F2 Na2 F2 60.95(3) 7_556 3
F2 Na2 F2 119.05(3) 2 3
F2 Na2 F2 60.95(3) 8_556 3
F2 Na2 F2 119.06(3) . 3
F2 Na2 F2 119.06(3) 8_556 7_556
F2 Na2 F2 60.94(3) 2 7_556
F2 Na2 F2 180.000(1) 9_556 3
F2 Na2 F2 119.05(3) 8_556 9_556
F2 Na2 F2 60.94(3) . 9_556
F2 Na2 F2 60.95(3) 2 9_556
F2 Na2 F2 119.05(3) 7_556 9_556
F2 Na2 F2 180.0 8_556 2
F2 Na2 F2 60.94(3) 8_556 .
F2 Na2 F2 119.06(3) 2 .
F2 Na2 F2 180.0 7_556 .
F4 Na2 F2 106.07(12) 3 8_556
F4 Na2 F2 73.93(12) 9_556 8_556
F4 Na2 F2 121.79(11) 7_556 8_556
F4 Na2 F2 58.21(11) . 8_556
F4 Na2 F2 73.93(12) 3 2
F4 Na2 F2 106.07(12) 2 7_556
F4 Na2 F2 61.27(12) 8_556 8_556
F4 Na2 F2 118.73(12) 2 8_556
F4 Na2 F2 106.07(12) 9_556 2
F4 Na2 F2 121.79(11) . 2
F4 Na2 F2 118.73(12) 8_556 2
F4 Na2 F2 121.79(11) 9_556 7_556
F4 Na2 F2 61.27(12) 2 2
F4 Na2 F2 73.93(12) 8_556 7_556
F4 Na2 F2 58.21(11) 7_556 2
F4 Na2 F2 58.21(11) 3 7_556
F4 Na2 F2 61.27(12) 7_556 7_556
F4 Na2 F2 118.73(12) . 7_556
F4 Na2 F2 73.93(12) 2 .
F4 Na2 F2 106.07(12) 7_556 3
F4 Na2 F2 61.27(12) 3 3
F4 Na2 F2 118.73(12) 9_556 3
F4 Na2 F2 106.07(12) 8_556 .
F4 Na2 F2 58.21(11) 9_556 .
F4 Na2 F2 118.73(12) 7_556 .
F4 Na2 F2 121.79(11) 3 .
F4 Na2 F2 61.27(12) . .
F4 Na2 F2 61.27(12) 9_556 9_556
F4 Na2 F2 58.21(11) 2 9_556
F4 Na2 F2 121.79(11) 8_556 9_556
F4 Na2 F2 106.07(12) . 9_556
F4 Na2 F2 118.73(12) 3 9_556
F4 Na2 F2 121.79(11) 2 3
F4 Na2 F2 58.21(11) 8_556 3
F4 Na2 F2 73.93(12) 7_556 9_556
F4 Na2 F2 73.93(12) . 3
F4 Na2 F4 180.00(11) 8_556 2
F4 Na2 F4 64.72(13) . 2
F4 Na2 F4 115.28(13) 7_556 2
F4 Na2 F4 64.72(13) 3 2
F4 Na2 F4 115.28(13) 9_556 2
F4 Na2 F4 115.28(13) . 8_556
F4 Na2 F4 64.72(13) 7_556 8_556
F4 Na2 F4 115.28(13) 3 8_556
F4 Na2 F4 64.72(13) 9_556 8_556
F4 Na2 F4 180.0 7_556 .
F4 Na2 F4 64.72(13) 3 .
F4 Na2 F4 115.28(13) 9_556 .
F4 Na2 F4 115.28(13) 3 7_556
F4 Na2 F4 64.72(13) 9_556 7_556
F4 Na2 F4 180.0 9_556 3
U1 Na3 U1 78.5(4) 2 3_565
U1 Na3 U1 147.3(7) 2 6
U1 Na3 U1 131.6(7) 6 3_565
Co1 Na3 U1 75.3(5) . 2
Co1 Na3 U1 75.1(4) . 6
Co1 Na3 U1 153.3(7) . 3_565
Na1 Na3 U1 68.3(4) . 3_565
Na1 Na3 U1 74.1(5) . 6
Na1 Na3 U1 137.5(7) . 2
Na1 Na3 Co1 131.5(7) . .
Na3 Na3 U1 100.8(11) 5 3_565
Na3 Na3 U1 82(2) 5 2
Na3 Na3 U1 80(2) 5 6
Na3 Na3 Co1 79.9(4) 5 .
Na3 Na3 Na1 129.3(18) 5 .
Na3 Na3 F1 123(3) 5 .
Na3 Na3 F3 142.6(10) 5 9_556
Na3 Na3 F4 65.8(14) 5 6
Na3 Na3 F4 87.6(14) 5 2
Na3 Na3 F5 67.2(19) 5 6
Na3 Na3 F5 86(2) 5 2
F1 Na3 U1 147.1(9) . 2
F1 Na3 U1 43.0(4) . 6
F1 Na3 U1 113.4(8) . 3_565
F1 Na3 Co1 87.1(6) . .
F1 Na3 Na1 45.3(4) . .
F1 Na3 F3 80.6(7) . 9_556
F1 Na3 F4 69.7(6) . 6
F1 Na3 F5 66.4(6) . 6
F3 Na3 U1 91.8(6) 9_556 2
F3 Na3 U1 42.1(3) 9_556 3_565
F3 Na3 U1 118.8(7) 9_556 6
F3 Na3 Co1 133.9(8) 9_556 .
F3 Na3 Na1 45.7(4) 9_556 .
F4 Na3 U1 39.2(3) 6 6
F4 Na3 U1 113.6(8) 2 6
F4 Na3 U1 38.6(4) 2 2
F4 Na3 U1 114.8(8) 2 3_565
F4 Na3 U1 163.1(8) 6 3_565
F4 Na3 U1 108.3(7) 6 2
F4 Na3 Co1 38.6(4) 2 .
F4 Na3 Co1 38.8(3) 6 .
F4 Na3 Na1 111.2(7) 6 .
F4 Na3 Na1 142.8(9) 2 .
F4 Na3 F1 114.6(9) 2 .
F4 Na3 F3 149.0(9) 6 9_556
F4 Na3 F3 109.8(8) 2 9_556
F4 Na3 F4 76.4(7) 2 6
F4 Na3 F5 79.3(7) 2 2
F4 Na3 F5 145.3(10) 2 6
F5 Na3 U1 145.9(8) 6 2
F5 Na3 U1 160.4(9) 2 6
F5 Na3 U1 41.3(3) 6 6
F5 Na3 U1 38.2(4) 2 3_565
F5 Na3 U1 93.8(6) 6 3_565
F5 Na3 U1 41.1(4) 2 2
F5 Na3 Co1 110.6(7) 6 .
F5 Na3 Co1 116.2(8) 2 .
F5 Na3 Na1 105.0(8) 2 .
F5 Na3 Na1 64.6(5) 6 .
F5 Na3 F1 146.7(11) 2 .
F5 Na3 F3 104.6(8) 6 9_556
F5 Na3 F3 66.2(6) 2 9_556
F5 Na3 F4 143.2(10) 2 6
F5 Na3 F4 71.8(6) 6 6
F5 Na3 F5 120.0(9) 2 6
U1 F1 U1 118.39(16) . 6
U1 F1 Na3 115.5(6) . .
Na1 F1 U1 113.23(18) . .
Na1 F1 U1 119.87(18) . 6
Na1 F1 Na3 87.8(6) . .
Na3 F1 U1 96.0(6) . 6
U1 F2 U1 152.55(18) . 9_556
U1 F2 Na2 101.91(13) . .
U1 F2 Na2 99.51(12) 9_556 .
U1 F3 U1 116.30(14) . 7_666
U1 F3 Na1 134.42(18) . 7_666
U1 F3 Na3 111.6(5) . 8_556
U1 F3 Na3 89.9(5) 7_666 8_556
Na1 F3 U1 107.76(15) 7_666 7_666
Na1 F3 Na3 78.5(5) 7_666 8_556
U1 F4 Na2 104.19(15) . .
U1 F4 Na3 101.8(5) . 3
U1 F4 Na3 95.9(5) . 6
Co1 F4 U1 150.3(2) . .
Co1 F4 Na2 87.56(14) . .
Co1 F4 Na3 89.8(5) . 6
Co1 F4 Na3 96.3(6) . 3
Na3 F4 Na2 117.8(5) 3 .
Na3 F4 Na2 143.4(5) 6 .
U1 F5 U1 153.1(2) 2_655 .
U1 F5 Na3 94.1(5) . 6
U1 F5 Na3 112.6(5) 2_655 6
Na3 F5 U1 98.7(6) 3 .
Na3 F5 U1 103.8(6) 3 2_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
U1 F1 2.326(4) .
U1 F1 2.418(4) 6
U1 F2 2.355(4) 8_556
U1 F2 2.264(3) .
U1 F3 2.316(4) .
U1 F3 2.421(4) 7_666
U1 F4 2.240(4) .
U1 F5 2.298(4) 3_665
U1 F5 2.335(4) .
Co1 Na3 3.21(2) .
Co1 Na3 3.21(2) 5
Co1 Na3 3.21(2) 6
Co1 Na3 3.21(2) 3
Co1 Na3 3.21(2) 2
Co1 Na3 3.21(2) 4
Co1 F4 2.013(4) 2
Co1 F4 2.013(4) 4
Co1 F4 2.013(4) .
Co1 F4 2.013(4) 6
Co1 F4 2.013(4) 3
Co1 F4 2.013(4) 5
Na1 Na3 3.18(2) 2_665
Na1 Na3 3.18(2) .
Na1 Na3 3.18(2) 3_565
Na1 F1 2.266(4) .
Na1 F1 2.266(4) 3_565
Na1 F1 2.266(4) 2_665
Na1 F3 2.326(4) 9_556
Na1 F3 2.326(4) 8_566
Na1 F3 2.326(4) 7_666
Na2 F2 2.695(4) 3
Na2 F2 2.695(4) 9_556
Na2 F2 2.695(4) .
Na2 F2 2.695(4) 7_556
Na2 F2 2.695(4) 2
Na2 F2 2.695(4) 8_556
Na2 F4 2.644(4) 2
Na2 F4 2.644(4) 8_556
Na2 F4 2.644(4) .
Na2 F4 2.644(4) 7_556
Na2 F4 2.644(4) 3
Na2 F4 2.644(4) 9_556
Na3 Na3 1.12(4) 5
Na3 F1 2.33(2) .
Na3 F3 2.69(2) 9_556
Na3 F4 2.51(2) 6
Na3 F4 2.29(2) 2
Na3 F5 2.48(2) 6
Na3 F5 2.29(2) 2
F1 U1 2.418(4) 6
F2 U1 2.355(4) 9_556
F3 U1 2.421(4) 7_666
F3 Na1 2.326(4) 7_666
F3 Na3 2.69(2) 8_556
F4 Na3 2.29(2) 3
F4 Na3 2.51(2) 6
F5 U1 2.298(4) 2_655
F5 Na3 2.48(2) 6
F5 Na3 2.29(2) 3
