#------------------------------------------------------------------------------
#$Date: 2016-03-22 21:19:14 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179017 $
#$URL: svn://www.crystallography.net/cod/cif/4/12/15/4121561.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4121561
loop_
_publ_author_name
'Han, Xin-Bao'
'Zhang, Zhi-Ming'
'Zhang, Teng'
'Li, Yang-Guang'
'Lin, Wenbin'
'You, Wansheng'
'Su, Zhong-Min'
'Wang, En-Bo'
_publ_section_title
;
 Polyoxometalate-based cobalt-phosphate molecular catalysts for visible
 light-driven water oxidation.
;
_journal_issue                   14
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              5359
_journal_page_last               5366
_journal_paper_doi               10.1021/ja412886e
_journal_volume                  136
_journal_year                    2014
_chemical_formula_sum            'Co16 Ge4 H240 Na32 O278 P4 W36'
_chemical_formula_weight         13401.32
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           197
_symmetry_cell_setting           cubic
_symmetry_space_group_name_Hall  'I 2 2 3'
_symmetry_space_group_name_H-M   'I 2 3'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   23.924(3)
_cell_length_b                   23.924(3)
_cell_length_c                   23.924(3)
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.98
_cell_measurement_theta_min      3.19
_cell_volume                     13693(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 0.01
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID IP'
_diffrn_measurement_method       Oscillation
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1532
_diffrn_reflns_av_sigmaI/netI    0.0739
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            49772
_diffrn_reflns_theta_full        24.98
_diffrn_reflns_theta_max         24.98
_diffrn_reflns_theta_min         3.19
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    16.619
_exptl_absorpt_correction_T_max  0.6355
_exptl_absorpt_correction_T_min  0.3162
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR by T.Higashi    8 March, 1995'
_exptl_crystal_colour            'dark purple'
_exptl_crystal_density_diffrn    3.250
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             12200
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_refine_diff_density_max         4.299
_refine_diff_density_min         -5.716
_refine_diff_density_rms         0.965
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.26(8)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     295
_refine_ls_number_reflns         4021
_refine_ls_number_restraints     170
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.1558
_refine_ls_R_factor_gt           0.1507
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0001P)²+20915.9648P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3676
_refine_ls_wR_factor_ref         0.3699
_reflns_number_gt                3731
_reflns_number_total             4021
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja412886e_si_007.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Cubic' changed to 'cubic' according
to
/usr/data/users/saulius/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4121557--4121563.cif.
;
_cod_original_sg_symbol_H-M      I23
_cod_database_code               4121561
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'z, x, y'
'z, -x, -y'
'-z, -x, y'
'-z, x, -y'
'y, z, x'
'-y, z, -x'
'y, -z, -x'
'-y, -z, x'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'z+1/2, x+1/2, y+1/2'
'z+1/2, -x+1/2, -y+1/2'
'-z+1/2, -x+1/2, y+1/2'
'-z+1/2, x+1/2, -y+1/2'
'y+1/2, z+1/2, x+1/2'
'-y+1/2, z+1/2, -x+1/2'
'y+1/2, -z+1/2, -x+1/2'
'-y+1/2, -z+1/2, x+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.29184(13) 0.54209(14) 0.73720(13) 0.0312(7) Uani 1 1 d .
W2 W 0.41983(13) 0.62368(14) 0.78012(12) 0.0292(7) Uani 1 1 d .
W3 W 0.27636(15) 0.68574(15) 0.79803(14) 0.0377(9) Uani 1 1 d .
P1 P 0.5796(5) 0.5796(5) 0.5796(5) 0.004(4) Uani 1 3 d S
Ge1 Ge 0.3346(3) 0.6654(3) 0.6654(3) 0.028(3) Uani 1 3 d SD
Co1 Co 0.4727(4) 0.6126(4) 0.6558(4) 0.022(2) Uani 1 1 d .
Co2 Co 0.4518(3) 0.5482(3) 0.5482(3) 0.023(3) Uani 1 3 d S
Na1 Na 0.5839(17) 0.7082(18) 0.6244(18) 0.061(10) Uani 1 1 d U
Na2 Na 0.5000 0.724(3) 1.0000 0.068(16) Uani 1 2 d SU
Na3 Na 0.3569(19) 0.6730(19) 1.079(2) 0.034(10) Uani 0.67 1 d PU
Na4 Na 0.491(2) 0.472(2) 0.795(2) 0.032(13) Uani 0.50 1 d PU
O1 O 0.4001(8) 0.6648(17) 0.6934(15) 0.011(8) Uani 1 1 d DU
O2 O 0.3566(15) 0.5688(15) 0.7539(15) 0.005(7) Uani 1 1 d U
O3 O 0.2679(14) 0.6140(14) 0.7725(14) 0.002(7) Uani 1 1 d U
O4 O 0.4385(19) 0.6003(19) 0.8453(19) 0.023(10) Uani 1 1 d U
O5 O 0.4535(17) 0.6331(16) 0.5709(17) 0.014(9) Uani 1 1 d U
O6 O 0.292(3) 0.762(3) 0.789(3) 0.053(16) Uani 1 1 d U
O7 O 0.355(3) 0.669(3) 0.804(3) 0.048(15) Uani 1 1 d U
O8 O 0.448(2) 0.692(2) 0.783(2) 0.033(12) Uani 1 1 d U
O9 O 0.5068(17) 0.6938(17) 0.6723(16) 0.013(9) Uani 1 1 d U
O10 O 0.330(3) 0.749(3) 1.034(3) 0.063(19) Uani 1 1 d U
O11 O 0.257(3) 0.688(3) 0.855(3) 0.066(19) Uani 1 1 d U
O12 O 0.5425(16) 0.5425(16) 0.5425(16) 0.011(3) Uani 1 3 d SU
O13 O 0.2926(4) 0.7074(4) 0.7074(4) 0.08(4) Uiso 1 3 d SD
O14 O 0.464(2) 0.582(2) 0.736(2) 0.026(10) Uani 1 1 d U
O15 O 0.6398(19) 0.5559(18) 0.5875(19) 0.022(10) Uani 1 1 d U
O1W O 0.466(2) 0.698(2) 0.901(2) 0.040(13) Uani 1 1 d U
O2W O 0.603(3) 0.790(3) 0.677(3) 0.047(15) Uani 1 1 d U
O3W O 0.395(3) 0.589(3) 1.046(3) 0.07(2) Uani 1 1 d U
O4W O 0.427(4) 0.786(4) 0.862(4) 0.021(19) Uani 0.50 1 d PU
O5W O 0.398(3) 0.601(3) 0.965(3) 0.07(2) Uani 1 1 d U
O6W O 0.284(4) 0.622(4) 0.943(4) 0.020(19) Uani 0.50 1 d PU
O7W O 0.369(3) 0.497(3) 0.903(3) 0.013(17) Uani 0.50 1 d PU
O8W O 0.538(3) 0.653(3) 0.862(3) 0.051(16) Uani 1 1 d U
O9W O 0.583(3) 0.848(3) 0.603(3) 0.052(16) Uani 1 1 d U
O10W O 0.5000 0.5000 0.953(5) 0.07(3) Uani 1 2 d SU
O11W O 0.414(3) 0.491(3) 0.813(3) 0.057(17) Uiso 1 1 d .
O12W O 0.478(3) 0.602(3) 0.999(4) 0.014(17) Uiso 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 W1 O9 86.8(17) . 7_665
O2 W1 O3 80.8(15) . .
O9 W1 O3 161.3(16) 7_665 .
O2 W1 O8 147.6(19) . 7_665
O9 W1 O8 100.7(19) 7_665 7_665
O3 W1 O8 82.9(17) . 7_665
O2 W1 O1 79.0(14) . 7_665
O9 W1 O1 83.1(15) 7_665 7_665
O3 W1 O1 80.8(13) . 7_665
O8 W1 O1 70.8(17) 7_665 7_665
O2 W1 O10 101(2) . 21_445
O9 W1 O10 133(2) 7_665 21_445
O3 W1 O10 64(2) . 21_445
O8 W1 O10 96(2) 7_665 21_445
O1 W1 O10 144.2(19) 7_665 21_445
O2 W1 Na1 81.8(13) . 7_665
O9 W1 Na1 24.8(15) 7_665 7_665
O3 W1 Na1 159.8(12) . 7_665
O8 W1 Na1 117.3(16) 7_665 7_665
O1 W1 Na1 105.8(12) 7_665 7_665
O10 W1 Na1 109.7(18) 21_445 7_665
O4 W2 O8 100(2) . .
O4 W2 O14 102(2) . .
O8 W2 O14 108(2) . .
O4 W2 O7 97(2) . .
O8 W2 O7 77(2) . .
O14 W2 O7 159(2) . .
O4 W2 O2 104.8(18) . .
O8 W2 O2 149.7(19) . .
O14 W2 O2 84.5(18) . .
O7 W2 O2 83(2) . .
O4 W2 O1 173.5(18) . .
O8 W2 O1 73.9(18) . .
O14 W2 O1 79.9(18) . .
O7 W2 O1 82(2) . .
O2 W2 O1 81.5(12) . .
O4 W2 Na4 59.1(19) . 2_665
O8 W2 Na4 114(2) . 2_665
O14 W2 Na4 43.0(19) . 2_665
O7 W2 Na4 154(2) . 2_665
O2 W2 Na4 93.9(14) . 2_665
O1 W2 Na4 122.7(14) . 2_665
O11 W3 O3 109(3) . .
O11 W3 O6 98(4) . 7_665
O3 W3 O6 91(2) . 7_665
O11 W3 O6 97(4) . .
O3 W3 O6 154(2) . .
O6 W3 O6 80(4) 7_665 .
O11 W3 O7 105(4) . .
O3 W3 O7 87(2) . .
O6 W3 O7 156(3) 7_665 .
O6 W3 O7 91(3) . .
O11 W3 O13 162(3) . .
O3 W3 O13 85.0(11) . .
O6 W3 O13 69(2) 7_665 .
O6 W3 O13 69(2) . .
O7 W3 O13 87.2(19) . .
O12 P1 O15 113.2(19) . 9
O12 P1 O15 113.2(18) . .
O15 P1 O15 105(2) 9 .
O12 P1 O15 113.2(18) . 5
O15 P1 O15 105(2) 9 5
O15 P1 O15 105(2) . 5
O12 P1 Na1 138.9(8) . .
O15 P1 Na1 66(2) 9 .
O15 P1 Na1 106(2) . .
O15 P1 Na1 40.8(19) 5 .
O12 P1 Na1 138.9(8) . 5
O15 P1 Na1 40.8(19) 9 5
O15 P1 Na1 66(2) . 5
O15 P1 Na1 106(2) 5 5
Na1 P1 Na1 69.5(12) . 5
O12 P1 Na1 138.9(8) . 9
O15 P1 Na1 106(2) 9 9
O15 P1 Na1 40.8(19) . 9
O15 P1 Na1 66(2) 5 9
Na1 P1 Na1 69.5(12) . 9
Na1 P1 Na1 69.5(12) 5 9
O1 Ge1 O1 110.9(13) 7_665 .
O1 Ge1 O1 110.9(13) 7_665 10_656
O1 Ge1 O1 110.9(13) . 10_656
O1 Ge1 O13 108.0(14) 7_665 .
O1 Ge1 O13 108.0(14) . .
O1 Ge1 O13 108.0(14) 10_656 .
O5 Co1 O14 85.4(18) 7_665 .
O5 Co1 O15 102.8(17) 7_665 9
O14 Co1 O15 99.5(19) . 9
O5 Co1 O5 79(2) 7_665 .
O14 Co1 O5 160.5(18) . .
O15 Co1 O5 95.5(17) 9 .
O5 Co1 O9 168.3(17) 7_665 .
O14 Co1 O9 100.7(17) . .
O15 Co1 O9 86.2(17) 9 .
O5 Co1 O9 92.8(15) . .
O5 Co1 O1 98.1(15) 7_665 .
O14 Co1 O1 75.6(16) . .
O15 Co1 O1 158.1(15) 9 .
O5 Co1 O1 94.8(14) . .
O9 Co1 O1 74.1(14) . .
O5 Co1 Na1 147.9(14) 7_665 .
O14 Co1 Na1 119.6(15) . .
O15 Co1 Na1 56.3(14) 9 .
O5 Co1 Na1 79.3(13) . .
O9 Co1 Na1 34.8(13) . .
O1 Co1 Na1 107.1(12) . .
O5 Co2 O5 76.9(18) 10_656 .
O5 Co2 O5 76.9(18) 10_656 7_665
O5 Co2 O5 76.9(18) . 7_665
O5 Co2 O12 167.7(13) 10_656 .
O5 Co2 O12 93.2(18) . .
O5 Co2 O12 108.4(15) 7_665 .
O5 Co2 O12 93.2(17) 10_656 3_656
O5 Co2 O12 108.4(15) . 3_656
O5 Co2 O12 167.7(13) 7_665 3_656
O12 Co2 O12 83(2) . 3_656
O5 Co2 O12 108.4(15) 10_656 2_665
O5 Co2 O12 167.7(13) . 2_665
O5 Co2 O12 93.2(17) 7_665 2_665
O12 Co2 O12 83(2) . 2_665
O12 Co2 O12 83(2) 3_656 2_665
O9 Na1 O15 107(2) . 5
O9 Na1 O2W 91(2) . .
O15 Na1 O2W 162(3) 5 .
O9 Na1 O15 66.2(17) . 9
O15 Na1 O15 54(2) 5 9
O2W Na1 O15 141(2) . 9
O9 Na1 P1 89.9(17) . .
O15 Na1 P1 26.1(12) 5 .
O2W Na1 P1 164(2) . .
O15 Na1 P1 28.5(10) 9 .
O9 Na1 Co1 33.8(12) . .
O15 Na1 Co1 74.1(16) 5 .
O2W Na1 Co1 124(2) . .
O15 Na1 Co1 36.1(10) 9 .
P1 Na1 Co1 56.2(7) . .
O9 Na1 Na4 100(2) . 10_656
O15 Na1 Na4 83.1(19) 5 10_656
O2W Na1 Na4 90(2) . 10_656
O15 Na1 Na4 123.6(18) 9 10_656
P1 Na1 Na4 105.7(14) . 10_656
Co1 Na1 Na4 104.3(14) . 10_656
O9 Na1 W1 19.9(12) . 10_656
O15 Na1 W1 123.2(19) 5 10_656
O2W Na1 W1 73.5(18) . 10_656
O15 Na1 W1 86.1(13) 9 10_656
P1 Na1 W1 109.3(12) . 10_656
Co1 Na1 W1 53.1(6) . 10_656
Na4 Na1 W1 90.4(13) 10_656 10_656
O9 Na1 Na1 79(2) . 5
O15 Na1 Na1 78.8(14) 5 5
O2W Na1 Na1 108.8(19) . 5
O15 Na1 Na1 38.6(12) 9 5
P1 Na1 Na1 55.3(6) . 5
Co1 Na1 Na1 64.5(11) . 5
Na4 Na1 Na1 160.9(12) 10_656 5
W1 Na1 Na1 94.1(16) 10_656 5
O9 Na1 Na1 136(2) . 9
O15 Na1 Na1 53.4(16) 5 9
O2W Na1 Na1 115.2(19) . 9
O15 Na1 Na1 71.9(11) 9 9
P1 Na1 Na1 55.3(6) . 9
Co1 Na1 Na1 107.7(9) . 9
Na4 Na1 Na1 113.2(19) 10_656 9
W1 Na1 Na1 153.9(16) 10_656 9
Na1 Na1 Na1 60.000(3) 5 9
O1W Na2 O1W 152(4) . 3_657
O1W Na2 O12W 72(2) . .
O1W Na2 O12W 80(3) 3_657 .
O1W Na2 O12W 80(3) . 3_657
O1W Na2 O12W 72(2) 3_657 3_657
O12W Na2 O12W 21(3) . 3_657
O1W Na2 Na3 95.1(16) . .
O1W Na2 Na3 76.6(15) 3_657 .
O12W Na2 Na3 63.9(18) . .
O12W Na2 Na3 82(2) 3_657 .
O1W Na2 Na3 76.6(15) . 3_657
O1W Na2 Na3 95.1(16) 3_657 3_657
O12W Na2 Na3 82(2) . 3_657
O12W Na2 Na3 63.9(18) 3_657 3_657
Na3 Na2 Na3 145(2) . 3_657
O4W Na3 O10 94(4) 23_466 .
O4W Na3 O3W 87(4) 23_466 .
O10 Na3 O3W 131(3) . .
O4W Na3 O8W 137(4) 23_466 3_657
O10 Na3 O8W 128(3) . 3_657
O3W Na3 O8W 72(3) . 3_657
O4W Na3 O9W 91(3) 23_466 8_657
O10 Na3 O9W 172(3) . 8_657
O3W Na3 O9W 56(3) . 8_657
O8W Na3 O9W 47(2) 3_657 8_657
O4W Na3 Na2 147(3) 23_466 .
O10 Na3 Na2 77(2) . .
O3W Na3 Na2 77(2) . .
O8W Na3 Na2 63.4(15) 3_657 .
O9W Na3 Na2 102.9(19) 8_657 .
Na4 Na4 O11W 93(5) 2_665 .
Na4 Na4 O14 115(4) 2_665 2_665
O11W Na4 O14 138(4) . 2_665
Na4 Na4 O11W 52(4) 2_665 2_665
O11W Na4 O11W 138(4) . 2_665
O14 Na4 O11W 83(3) 2_665 2_665
Na4 Na4 O4 115(5) 2_665 2_665
O11W Na4 O4 130(4) . 2_665
O14 Na4 O4 67(2) 2_665 2_665
O11W Na4 O4 65(2) 2_665 2_665
Na4 Na4 O9W 131(5) 2_665 7_665
O11W Na4 O9W 43(3) . 7_665
O14 Na4 O9W 113(3) 2_665 7_665
O11W Na4 O9W 143(3) 2_665 7_665
O4 Na4 O9W 90(2) 2_665 7_665
Na4 Na4 W2 119(5) 2_665 2_665
O11W Na4 W2 147(3) . 2_665
O14 Na4 W2 33.8(15) 2_665 2_665
O11W Na4 W2 70(2) 2_665 2_665
O4 Na4 W2 33.1(12) 2_665 2_665
O9W Na4 W2 104(2) 7_665 2_665
Na4 Na4 Na1 124(4) 2_665 7_665
O11W Na4 Na1 60(3) . 7_665
O14 Na4 Na1 78(2) 2_665 7_665
O11W Na4 Na1 156(3) 2_665 7_665
O4 Na4 Na1 119(2) 2_665 7_665
O9W Na4 Na1 60.1(18) 7_665 7_665
W2 Na4 Na1 100.6(17) 2_665 7_665
Ge1 O1 W1 128(2) . 10_656
Ge1 O1 Co1 123(2) . .
W1 O1 Co1 90.8(9) 10_656 .
Ge1 O1 W2 122.5(19) . .
W1 O1 W2 93.4(8) 10_656 .
Co1 O1 W2 88.1(10) . .
W1 O2 W2 162(2) . .
W3 O3 W1 156.2(19) . .
W2 O4 Na4 88(2) . 2_665
Co1 O5 Co2 96.5(17) 10_656 .
Co1 O5 Co1 138(2) 10_656 .
Co2 O5 Co1 91.6(16) . .
W3 O6 W3 127(4) 10_656 .
W3 O7 W2 148(4) . .
W2 O8 W1 119(3) . 10_656
W1 O9 Co1 112(2) 10_656 .
W1 O9 Na1 135(2) 10_656 .
Co1 O9 Na1 111(2) . .
Na3 O10 W1 125(3) . 17_455
P1 O12 Co2 120.3(16) . .
P1 O12 Co2 120.3(16) . 3_656
Co2 O12 Co2 97(2) . 3_656
P1 O12 Co2 120.3(16) . 2_665
Co2 O12 Co2 97(2) . 2_665
Co2 O12 Co2 97(2) 3_656 2_665
Ge1 O13 W3 121.3(4) . 7_665
Ge1 O13 W3 121.3(4) . 10_656
W3 O13 W3 95.4(5) 7_665 10_656
Ge1 O13 W3 121.3(4) . .
W3 O13 W3 95.4(5) 7_665 .
W3 O13 W3 95.4(5) 10_656 .
W2 O14 Co1 115(2) . .
W2 O14 Na4 103(3) . 2_665
Co1 O14 Na4 139(3) . 2_665
P1 O15 Co1 123(3) . 5
P1 O15 Na1 113(3) . 9
Co1 O15 Na1 123(2) 5 9
P1 O15 Na1 86(2) . 5
Co1 O15 Na1 87.6(17) 5 5
Na1 O15 Na1 88(2) 9 5
Na4 O9W Na3 147(3) 10_656 11_576
Na4 O11W Na4 35(3) . 2_665
O12W O12W Na2 79.6(15) 3_657 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O2 1.72(4) .
W1 O9 1.78(4) 7_665
W1 O3 2.00(3) .
W1 O8 2.10(5) 7_665
W1 O1 2.25(3) 7_665
W1 O10 2.46(8) 21_445
W1 Na1 3.68(4) 7_665
W2 O4 1.72(5) .
W2 O8 1.78(5) .
W2 O14 1.79(5) .
W2 O7 1.98(6) .
W2 O2 2.10(4) .
W2 O1 2.34(3) .
W2 Na4 3.14(6) 2_665
W3 O11 1.44(8) .
W3 O3 1.83(3) .
W3 O6 1.87(7) 7_665
W3 O6 1.88(6) .
W3 O7 1.93(6) .
W3 O13 2.263(9) .
P1 O12 1.53(7) .
P1 O15 1.56(5) 9
P1 O15 1.56(5) .
P1 O15 1.56(5) 5
P1 Na1 3.26(5) .
P1 Na1 3.26(5) 5
P1 Na1 3.26(5) 9
Ge1 O1 1.703(10) 7_665
Ge1 O1 1.703(10) .
Ge1 O1 1.703(10) 10_656
Ge1 O13 1.741(10) .
Co1 O5 1.97(4) 7_665
Co1 O14 2.05(5) .
Co1 O15 2.11(5) 9
Co1 O5 2.14(4) .
Co1 O9 2.14(4) .
Co1 O1 2.32(4) .
Co1 Na1 3.59(4) .
Co2 O5 2.10(4) 10_656
Co2 O5 2.10(4) .
Co2 O5 2.10(4) 7_665
Co2 O12 2.18(3) .
Co2 O12 2.18(4) 3_656
Co2 O12 2.18(4) 2_665
Na1 O9 2.20(6) .
Na1 O15 2.32(6) 5
Na1 O2W 2.37(8) .
Na1 O15 2.99(6) 9
Na1 Na4 3.70(7) 10_656
Na1 W1 3.68(4) 10_656
Na1 Na1 3.72(7) 5
Na1 Na1 3.72(7) 9
Na2 O1W 2.59(6) .
Na2 O1W 2.59(6) 3_657
Na2 O12W 2.96(10) .
Na2 O12W 2.96(10) 3_657
Na2 Na3 4.10(5) .
Na2 Na3 4.10(5) 3_657
Na3 O4W 1.91(10) 23_466
Na3 O10 2.19(9) .
Na3 O3W 2.35(9) .
Na3 O8W 2.92(8) 3_657
Na3 O9W 2.93(8) 8_657
Na4 Na4 1.42(12) 2_665
Na4 O11W 1.96(9) .
Na4 O14 2.20(8) 2_665
Na4 O11W 2.49(9) 2_665
Na4 O4 2.70(7) 2_665
Na4 O9W 2.91(9) 7_665
Na4 W2 3.14(6) 2_665
Na4 Na1 3.70(7) 7_665
O1 W1 2.25(3) 10_656
O4 Na4 2.70(7) 2_665
O5 Co1 1.97(4) 10_656
O6 W3 1.87(7) 10_656
O8 W1 2.10(5) 10_656
O9 W1 1.78(4) 10_656
O10 W1 2.46(8) 17_455
O12 Co2 2.18(4) 3_656
O12 Co2 2.18(4) 2_665
O13 W3 2.263(9) 7_665
O13 W3 2.263(9) 10_656
O14 Na4 2.20(8) 2_665
O15 Co1 2.11(5) 5
O15 Na1 2.32(6) 9
O15 Na1 2.99(6) 5
O4W Na3 1.91(10) 20_656
O8W Na3 2.92(8) 3_657
O9W Na4 2.91(9) 10_656
O9W Na3 2.93(8) 11_576
O11W Na4 2.49(9) 2_665
O12W O12W 1.07(16) 3_657
