#------------------------------------------------------------------------------
#$Date: 2016-03-22 21:44:41 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179024 $
#$URL: svn://www.crystallography.net/cod/cif/4/12/22/4122258.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4122258
loop_
_publ_author_name
'Joost, Maximilian'
'Estevez, Laura'
'Mallet-Ladeira, Sonia'
'Miqueu, Karinne'
'Amgoune, Abderrahmane'
'Bourissou, Didier'
_publ_section_title
;
 Mechanisms of syn-Insertion of Alkynes and Allenes into Gold-Silicon
 Bonds: A Comprehensive Experimental/Theoretical Study.
;
_journal_issue                   29
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              10373
_journal_page_last               10382
_journal_paper_doi               10.1021/ja504024h
_journal_volume                  136
_journal_year                    2014
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C40 H40 Au O4 P Si, 0.5(C6 H6)'
_chemical_formula_sum            'C43 H43 Au O4 P Si'
_chemical_formula_weight         879.8
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90
_cell_angle_beta                 100.449(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.8649(4)
_cell_length_b                   23.9209(8)
_cell_length_c                   14.8877(6)
_cell_measurement_reflns_used    9936
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      27.55
_cell_measurement_theta_min      2.31
_cell_measurement_wavelength     0.71073
_cell_volume                     3805.1(2)
_computing_cell_refinement       'APEX2 and SAINT (Bruker, 2008)'
_computing_data_collection       'APEX2 (Bruker, 2008)'
_computing_data_reduction        'SAINT (Bruker, 2008)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker Kappa APEX II Quazar'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'multilayer optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'microfocus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0374
_diffrn_reflns_av_unetI/netI     0.0315
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            57915
_diffrn_reflns_theta_full        28.33
_diffrn_reflns_theta_max         28.33
_diffrn_reflns_theta_min         2.56
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.981
_exptl_absorpt_correction_T_max  0.7413
_exptl_absorpt_correction_T_min  0.6890
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.536
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       parallelepiped
_exptl_crystal_F_000             1764
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.513
_refine_diff_density_min         -0.459
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     456
_refine_ls_number_reflns         9427
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0374
_refine_ls_R_factor_gt           0.0236
_refine_ls_shift/su_max          0.018
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0190P)²+2.9936P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0474
_refine_ls_wR_factor_ref         0.0521
_reflns_number_gt                7667
_reflns_number_total             9427
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja504024h_si_001.cif
_cod_data_source_block           II
_cod_depositor_comments
'Adding full bibliography for 4122257--4122258.cif.'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4122258
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C2 C 0.5446(2) 0.32418(11) 0.06700(18) 0.0252(6) Uani 1 1 d .
C1 C 0.4979(2) 0.35324(10) 0.13049(17) 0.0226(5) Uani 1 1 d .
C5 C 0.5890(2) 0.35351(11) -0.00934(19) 0.0284(6) Uani 1 1 d .
C6 C 0.7676(3) 0.38108(17) -0.0686(3) 0.0639(11) Uani 1 1 d .
H6A H 0.7366 0.3635 -0.1278 0.096 Uiso 1 1 calc R
H6B H 0.859 0.3783 -0.0544 0.096 Uiso 1 1 calc R
H6C H 0.7429 0.4205 -0.0711 0.096 Uiso 1 1 calc R
C3 C 0.4861(3) 0.41513(11) 0.12091(18) 0.0285(6) Uani 1 1 d .
C4 C 0.5911(3) 0.50163(12) 0.1153(2) 0.0522(9) Uani 1 1 d .
H4A H 0.5046 0.5145 0.1115 0.078 Uiso 1 1 calc R
H4B H 0.6223 0.5136 0.0606 0.078 Uiso 1 1 calc R
H4C H 0.6436 0.5177 0.1696 0.078 Uiso 1 1 calc R
C7 C 0.6729(2) 0.10847(10) 0.06248(18) 0.0234(5) Uani 1 1 d .
C8 C 0.7022(2) 0.06047(11) 0.01743(19) 0.0272(6) Uani 1 1 d .
H8 H 0.6454 0.0469 -0.0341 0.033 Uiso 1 1 calc R
C9 C 0.8137(2) 0.03246(12) 0.0474(2) 0.0337(6) Uani 1 1 d .
H9 H 0.8339 0.0001 0.016 0.04 Uiso 1 1 calc R
C10 C 0.8954(3) 0.05171(13) 0.1232(2) 0.0398(7) Uani 1 1 d .
H10 H 0.971 0.0321 0.1446 0.048 Uiso 1 1 calc R
C11 C 0.8677(3) 0.09922(13) 0.1679(2) 0.0401(7) Uani 1 1 d .
H11 H 0.9243 0.1122 0.2199 0.048 Uiso 1 1 calc R
C12 C 0.7568(2) 0.12825(12) 0.13697(19) 0.0325(6) Uani 1 1 d .
H12 H 0.7389 0.1615 0.1669 0.039 Uiso 1 1 calc R
C13 C 0.4199(2) 0.10960(11) 0.09404(18) 0.0247(5) Uani 1 1 d .
C14 C 0.4528(2) 0.06090(12) 0.14226(19) 0.0318(6) Uani 1 1 d .
H14 H 0.5333 0.0451 0.1435 0.038 Uiso 1 1 calc R
C15 C 0.3688(3) 0.03496(13) 0.1889(2) 0.0394(7) Uani 1 1 d .
H15 H 0.3918 0.0014 0.2217 0.047 Uiso 1 1 calc R
C16 C 0.2524(3) 0.05781(14) 0.1877(2) 0.0430(8) Uani 1 1 d .
H16 H 0.1957 0.0404 0.2206 0.052 Uiso 1 1 calc R
C17 C 0.2179(3) 0.10632(13) 0.1385(3) 0.0478(9) Uani 1 1 d .
H17 H 0.1367 0.1216 0.1364 0.057 Uiso 1 1 calc R
C18 C 0.3017(2) 0.13261(12) 0.0924(2) 0.0380(7) Uani 1 1 d .
H18 H 0.2786 0.1663 0.0598 0.046 Uiso 1 1 calc R
C19 C 0.4647(2) 0.12466(10) -0.08760(18) 0.0243(5) Uani 1 1 d .
C20 C 0.3870(2) 0.07829(11) -0.1098(2) 0.0307(6) Uani 1 1 d .
H20 H 0.3657 0.0557 -0.0625 0.037 Uiso 1 1 calc R
C21 C 0.3409(2) 0.06503(12) -0.1997(2) 0.0338(6) Uani 1 1 d .
H21 H 0.2878 0.0335 -0.214 0.041 Uiso 1 1 calc R
C22 C 0.3716(3) 0.09730(13) -0.2689(2) 0.0373(7) Uani 1 1 d .
H22 H 0.3385 0.0886 -0.3308 0.045 Uiso 1 1 calc R
C23 C 0.4506(3) 0.14221(14) -0.2479(2) 0.0430(7) Uani 1 1 d .
H23 H 0.4742 0.1636 -0.2958 0.052 Uiso 1 1 calc R
C24 C 0.4961(3) 0.15661(12) -0.1581(2) 0.0327(6) Uani 1 1 d .
H24 H 0.5488 0.1883 -0.1446 0.039 Uiso 1 1 calc R
C25 C 0.5504(2) 0.25802(11) 0.26956(17) 0.0248(5) Uani 1 1 d .
C26 C 0.6782(3) 0.27022(12) 0.2967(2) 0.0357(7) Uani 1 1 d .
H26 H 0.7078 0.3067 0.2867 0.043 Uiso 1 1 calc R
C27 C 0.7621(3) 0.23014(13) 0.3379(2) 0.0394(7) Uani 1 1 d .
H27 H 0.8481 0.2394 0.3559 0.047 Uiso 1 1 calc R
C28 C 0.7214(3) 0.17697(13) 0.3528(2) 0.0390(7) Uani 1 1 d .
H28 H 0.7788 0.1497 0.3819 0.047 Uiso 1 1 calc R
C29 C 0.5963(3) 0.16347(12) 0.3251(2) 0.0369(7) Uani 1 1 d .
H29 H 0.5679 0.1267 0.3343 0.044 Uiso 1 1 calc R
C30 C 0.5124(2) 0.20352(11) 0.28386(18) 0.0290(6) Uani 1 1 d .
H30 H 0.4269 0.1936 0.2649 0.035 Uiso 1 1 calc R
C31 C 0.2764(2) 0.28517(11) 0.17995(18) 0.0254(5) Uani 1 1 d .
C32 C 0.2149(3) 0.29676(12) 0.09216(19) 0.0336(6) Uani 1 1 d .
H32 H 0.2552 0.3191 0.0534 0.04 Uiso 1 1 calc R
C33 C 0.0952(3) 0.27632(14) 0.0594(2) 0.0429(7) Uani 1 1 d .
H33 H 0.0551 0.2848 -0.0012 0.052 Uiso 1 1 calc R
C34 C 0.0348(3) 0.24406(13) 0.1142(2) 0.0425(8) Uani 1 1 d .
H34 H -0.0469 0.2302 0.0916 0.051 Uiso 1 1 calc R
C35 C 0.0928(3) 0.23191(11) 0.2016(2) 0.0358(7) Uani 1 1 d .
H35 H 0.0512 0.2097 0.2398 0.043 Uiso 1 1 calc R
C36 C 0.2123(2) 0.25208(11) 0.2342(2) 0.0305(6) Uani 1 1 d .
H36 H 0.2517 0.2433 0.2949 0.037 Uiso 1 1 calc R
C37 C 0.4216(2) 0.36378(11) 0.32525(18) 0.0283(6) Uani 1 1 d .
C38 C 0.5397(3) 0.39934(14) 0.3534(2) 0.0465(8) Uani 1 1 d .
H38A H 0.554 0.4219 0.3013 0.07 Uiso 1 1 calc R
H38B H 0.6118 0.3748 0.3731 0.07 Uiso 1 1 calc R
H38C H 0.5289 0.424 0.4039 0.07 Uiso 1 1 calc R
C39 C 0.3079(3) 0.40291(13) 0.3009(2) 0.0426(7) Uani 1 1 d .
H39A H 0.3023 0.427 0.3532 0.064 Uiso 1 1 calc R
H39B H 0.2314 0.3805 0.2856 0.064 Uiso 1 1 calc R
H39C H 0.3176 0.4261 0.2483 0.064 Uiso 1 1 calc R
C40 C 0.4050(3) 0.32919(13) 0.4093(2) 0.0440(8) Uani 1 1 d .
H40A H 0.4753 0.3032 0.4249 0.066 Uiso 1 1 calc R
H40B H 0.3266 0.3081 0.3955 0.066 Uiso 1 1 calc R
H40C H 0.4027 0.3543 0.461 0.066 Uiso 1 1 calc R
C41 C -0.0424(3) 0.50750(15) 0.0801(2) 0.0523(9) Uani 1 1 d .
H41 H -0.0712 0.5124 0.1362 0.063 Uiso 1 1 calc R
C42 C 0.0544(3) 0.47061(16) 0.0758(2) 0.0544(9) Uani 1 1 d .
H42 H 0.0915 0.4504 0.1288 0.065 Uiso 1 1 calc R
C43 C 0.0971(3) 0.46303(14) -0.0045(2) 0.0481(8) Uani 1 1 d .
H43 H 0.1636 0.4377 -0.0077 0.058 Uiso 1 1 calc R
Si1 Si 0.43588(6) 0.31552(3) 0.22537(5) 0.02200(14) Uani 1 1 d .
P1 P 0.52462(6) 0.14453(3) 0.02963(5) 0.02277(14) Uani 1 1 d .
Au1 Au 0.538730(9) 0.238758(4) 0.052766(7) 0.02451(4) Uani 1 1 d .
O3 O 0.5243(2) 0.37375(9) -0.07488(15) 0.0461(5) Uani 1 1 d .
O4 O 0.71450(18) 0.35286(9) 0.00179(15) 0.0447(5) Uani 1 1 d .
O1 O 0.38822(19) 0.44002(9) 0.11402(17) 0.0501(6) Uani 1 1 d .
O2 O 0.59492(17) 0.44098(7) 0.12135(15) 0.0370(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
C1 C2 C5 120.6(2) .
C1 C2 Au1 125.35(19) .
C5 C2 Au1 113.47(18) .
C2 C1 C3 118.9(2) .
C2 C1 Si1 120.46(19) .
C3 C1 Si1 120.45(18) .
O3 C5 O4 122.6(3) .
O3 C5 C2 126.1(2) .
O4 C5 C2 111.3(2) .
O4 C6 H6A 109.5 .
O4 C6 H6B 109.5 .
H6A C6 H6B 109.5 .
O4 C6 H6C 109.5 .
H6A C6 H6C 109.5 .
H6B C6 H6C 109.5 .
O1 C3 O2 122.6(2) .
O1 C3 C1 123.9(2) .
O2 C3 C1 113.5(2) .
O2 C4 H4A 109.5 .
O2 C4 H4B 109.5 .
H4A C4 H4B 109.5 .
O2 C4 H4C 109.5 .
H4A C4 H4C 109.5 .
H4B C4 H4C 109.5 .
C12 C7 C8 119.4(2) .
C12 C7 P1 118.5(2) .
C8 C7 P1 122.0(2) .
C9 C8 C7 120.4(3) .
C9 C8 H8 119.8 .
C7 C8 H8 119.8 .
C10 C9 C8 119.8(3) .
C10 C9 H9 120.1 .
C8 C9 H9 120.1 .
C11 C10 C9 120.3(3) .
C11 C10 H10 119.8 .
C9 C10 H10 119.8 .
C10 C11 C12 120.2(3) .
C10 C11 H11 119.9 .
C12 C11 H11 119.9 .
C7 C12 C11 119.9(3) .
C7 C12 H12 120.1 .
C11 C12 H12 120.1 .
C14 C13 C18 119.6(2) .
C14 C13 P1 122.24(19) .
C18 C13 P1 118.2(2) .
C13 C14 C15 120.3(3) .
C13 C14 H14 119.9 .
C15 C14 H14 119.9 .
C16 C15 C14 120.2(3) .
C16 C15 H15 119.9 .
C14 C15 H15 119.9 .
C15 C16 C17 120.0(3) .
C15 C16 H16 120 .
C17 C16 H16 120 .
C18 C17 C16 120.1(3) .
C18 C17 H17 119.9 .
C16 C17 H17 119.9 .
C17 C18 C13 119.9(3) .
C17 C18 H18 120.1 .
C13 C18 H18 120.1 .
C24 C19 C20 118.6(3) .
C24 C19 P1 119.3(2) .
C20 C19 P1 122.2(2) .
C21 C20 C19 120.7(3) .
C21 C20 H20 119.7 .
C19 C20 H20 119.7 .
C22 C21 C20 120.2(3) .
C22 C21 H21 119.9 .
C20 C21 H21 119.9 .
C23 C22 C21 119.7(3) .
C23 C22 H22 120.2 .
C21 C22 H22 120.2 .
C22 C23 C24 120.9(3) .
C22 C23 H23 119.6 .
C24 C23 H23 119.6 .
C23 C24 C19 120.0(3) .
C23 C24 H24 120 .
C19 C24 H24 120 .
C30 C25 C26 117.1(2) .
C30 C25 Si1 122.52(19) .
C26 C25 Si1 120.2(2) .
C27 C26 C25 121.3(3) .
C27 C26 H26 119.4 .
C25 C26 H26 119.4 .
C28 C27 C26 120.4(3) .
C28 C27 H27 119.8 .
C26 C27 H27 119.8 .
C27 C28 C29 119.5(3) .
C27 C28 H28 120.2 .
C29 C28 H28 120.2 .
C28 C29 C30 120.1(3) .
C28 C29 H29 119.9 .
C30 C29 H29 119.9 .
C29 C30 C25 121.6(3) .
C29 C30 H30 119.2 .
C25 C30 H30 119.2 .
C32 C31 C36 116.8(2) .
C32 C31 Si1 121.1(2) .
C36 C31 Si1 122.0(2) .
C31 C32 C33 121.4(3) .
C31 C32 H32 119.3 .
C33 C32 H32 119.3 .
C34 C33 C32 120.4(3) .
C34 C33 H33 119.8 .
C32 C33 H33 119.8 .
C35 C34 C33 119.8(3) .
C35 C34 H34 120.1 .
C33 C34 H34 120.1 .
C34 C35 C36 119.9(3) .
C34 C35 H35 120.1 .
C36 C35 H35 120.1 .
C35 C36 C31 121.7(3) .
C35 C36 H36 119.1 .
C31 C36 H36 119.1 .
C38 C37 C40 107.0(2) .
C38 C37 C39 108.9(2) .
C40 C37 C39 108.1(2) .
C38 C37 Si1 111.48(19) .
C40 C37 Si1 110.24(19) .
C39 C37 Si1 111.01(19) .
C37 C38 H38A 109.5 .
C37 C38 H38B 109.5 .
H38A C38 H38B 109.5 .
C37 C38 H38C 109.5 .
H38A C38 H38C 109.5 .
H38B C38 H38C 109.5 .
C37 C39 H39A 109.5 .
C37 C39 H39B 109.5 .
H39A C39 H39B 109.5 .
C37 C39 H39C 109.5 .
H39A C39 H39C 109.5 .
H39B C39 H39C 109.5 .
C37 C40 H40A 109.5 .
C37 C40 H40B 109.5 .
H40A C40 H40B 109.5 .
C37 C40 H40C 109.5 .
H40A C40 H40C 109.5 .
H40B C40 H40C 109.5 .
C43 C41 C42 120.7(3) 3_565
C43 C41 H41 119.7 3_565
C42 C41 H41 119.7 .
C43 C42 C41 120.4(3) .
C43 C42 H42 119.8 .
C41 C42 H42 119.8 .
C41 C43 C42 118.9(3) 3_565
C41 C43 H43 120.5 3_565
C42 C43 H43 120.5 .
C31 Si1 C25 110.39(11) .
C31 Si1 C1 110.05(11) .
C25 Si1 C1 107.70(11) .
C31 Si1 C37 108.22(11) .
C25 Si1 C37 108.05(12) .
C1 Si1 C37 112.41(11) .
C19 P1 C7 106.34(12) .
C19 P1 C13 103.74(12) .
C7 P1 C13 104.44(12) .
C19 P1 Au1 114.02(9) .
C7 P1 Au1 113.38(8) .
C13 P1 Au1 113.93(8) .
C2 Au1 P1 176.85(7) .
C5 O4 C6 115.7(3) .
C3 O2 C4 116.5(2) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C2 C1 1.344(4) .
C2 C5 1.489(4) .
C2 Au1 2.054(3) .
C1 C3 1.491(4) .
C1 Si1 1.900(3) .
C5 O3 1.197(3) .
C5 O4 1.343(3) .
C6 O4 1.451(4) .
C6 H6A 0.98 .
C6 H6B 0.98 .
C6 H6C 0.98 .
C3 O1 1.207(3) .
C3 O2 1.333(3) .
C4 O2 1.454(3) .
C4 H4A 0.98 .
C4 H4B 0.98 .
C4 H4C 0.98 .
C7 C12 1.385(4) .
C7 C8 1.395(4) .
C7 P1 1.815(2) .
C8 C9 1.385(4) .
C8 H8 0.95 .
C9 C10 1.382(4) .
C9 H9 0.95 .
C10 C11 1.377(4) .
C10 H10 0.95 .
C11 C12 1.394(4) .
C11 H11 0.95 .
C12 H12 0.95 .
C13 C14 1.381(4) .
C13 C18 1.393(3) .
C13 P1 1.819(3) .
C14 C15 1.390(4) .
C14 H14 0.95 .
C15 C16 1.375(4) .
C15 H15 0.95 .
C16 C17 1.387(5) .
C16 H16 0.95 .
C17 C18 1.387(4) .
C17 H17 0.95 .
C18 H18 0.95 .
C19 C24 1.390(4) .
C19 C20 1.397(4) .
C19 P1 1.812(3) .
C20 C21 1.379(4) .
C20 H20 0.95 .
C21 C22 1.375(4) .
C21 H21 0.95 .
C22 C23 1.375(4) .
C22 H22 0.95 .
C23 C24 1.383(4) .
C23 H23 0.95 .
C24 H24 0.95 .
C25 C30 1.396(4) .
C25 C26 1.405(4) .
C25 Si1 1.891(3) .
C26 C27 1.387(4) .
C26 H26 0.95 .
C27 C28 1.378(4) .
C27 H27 0.95 .
C28 C29 1.386(4) .
C28 H28 0.95 .
C29 C30 1.386(4) .
C29 H29 0.95 .
C30 H30 0.95 .
C31 C32 1.384(4) .
C31 C36 1.404(4) .
C31 Si1 1.887(3) .
C32 C33 1.392(4) .
C32 H32 0.95 .
C33 C34 1.373(5) .
C33 H33 0.95 .
C34 C35 1.370(5) .
C34 H34 0.95 .
C35 C36 1.388(4) .
C35 H35 0.95 .
C36 H36 0.95 .
C37 C38 1.533(4) .
C37 C40 1.537(4) .
C37 C39 1.540(4) .
C37 Si1 1.911(3) .
C38 H38A 0.98 .
C38 H38B 0.98 .
C38 H38C 0.98 .
C39 H39A 0.98 .
C39 H39B 0.98 .
C39 H39C 0.98 .
C40 H40A 0.98 .
C40 H40B 0.98 .
C40 H40C 0.98 .
C41 C43 1.369(5) 3_565
C41 C42 1.384(5) .
C41 H41 0.95 .
C42 C43 1.371(5) .
C42 H42 0.95 .
C43 C41 1.369(5) 3_565
C43 H43 0.95 .
P1 Au1 2.2812(7) .
