#------------------------------------------------------------------------------
#$Date: 2016-03-22 21:51:41 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179026 $
#$URL: svn://www.crystallography.net/cod/cif/4/12/24/4122459.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4122459
loop_
_publ_author_name
'Li, Feng'
'Sevov, Slavi C.'
_publ_section_title
;
 Synthesis, structures, and solution dynamics of tetrasubstituted
 nine-atom germanium deltahedral clusters.
;
_journal_issue                   34
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              12056
_journal_page_last               12063
_journal_paper_doi               10.1021/ja505826x
_journal_volume                  136
_journal_year                    2014
_chemical_formula_moiety         'C39 H108 Ge9 Si12 Sn'
_chemical_formula_sum            'C39 H108 Ge9 Si12 Sn'
_chemical_formula_weight         1686.78
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           148
_symmetry_cell_setting           rhombohedral
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            42
_cell_length_a                   64.496(14)
_cell_length_b                   64.496(14)
_cell_length_c                   22.031(5)
_cell_measurement_reflns_used    9823
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.27
_cell_measurement_theta_min      2.36
_cell_volume                     79365(3)
_computing_cell_refinement       'Bruker SAINT v7.60A'
_computing_data_collection       'Bruker APEX-II v2008-6'
_computing_data_reduction        'Bruker SAINT v7.60A'
_computing_molecular_graphics    SHELXL-XP
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 83.33
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1896
_diffrn_reflns_av_sigmaI/netI    0.1020
_diffrn_reflns_limit_h_max       76
_diffrn_reflns_limit_h_min       -76
_diffrn_reflns_limit_k_max       76
_diffrn_reflns_limit_k_min       -76
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            295701
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         0.63
_exptl_absorpt_coefficient_mu    4.062
_exptl_absorpt_correction_T_max  0.6868
_exptl_absorpt_correction_T_min  0.2933
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Sheldrick, 2008'
_exptl_crystal_colour            Black-reddish
_exptl_crystal_density_diffrn    1.482
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Needle
_exptl_crystal_F_000             35616
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         4.621
_refine_diff_density_min         -1.706
_refine_diff_density_rms         0.298
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.949
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1282
_refine_ls_number_reflns         31076
_refine_ls_number_restraints     234
_refine_ls_restrained_S_all      0.948
_refine_ls_R_factor_all          0.2022
_refine_ls_R_factor_gt           0.1028
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1339P)²+6161.0615P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2420
_refine_ls_wR_factor_ref         0.2883
_reflns_number_gt                16020
_reflns_number_total             31076
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja505826x_si_004.cif
_cod_data_source_block           mo_lf041_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Rhombohedral' changed to
'rhombohedral' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4122457--4122459.cif.
;
_cod_original_cell_volume        79366(29)
_cod_original_sg_symbol_H-M      R-3
_cod_database_code               4122459
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Sn1 Sn 0.430719(19) 0.144102(19) 0.13121(4) 0.0351(3) Uani 1 1 d .
Ge1 Ge 0.42550(3) 0.15343(3) 0.24718(7) 0.0326(4) Uani 1 1 d .
Ge2 Ge 0.45788(3) 0.14031(3) 0.27172(7) 0.0298(4) Uani 1 1 d .
Ge3 Ge 0.40733(3) 0.10696(3) 0.27205(7) 0.0300(4) Uani 1 1 d .
Ge4 Ge 0.42401(3) 0.16020(3) 0.41209(6) 0.0272(3) Uani 1 1 d .
Ge5 Ge 0.45615(3) 0.14579(3) 0.40920(6) 0.0261(3) Uani 1 1 d .
Ge6 Ge 0.40652(3) 0.11292(3) 0.40886(6) 0.0248(3) Uani 1 1 d .
Ge7 Ge 0.39508(3) 0.13420(3) 0.32832(6) 0.0268(3) Uani 1 1 d .
Ge8 Ge 0.45572(3) 0.17424(3) 0.32810(6) 0.0264(3) Uani 1 1 d .
Ge9 Ge 0.43662(3) 0.10754(3) 0.34795(7) 0.0295(4) Uani 1 1 d .
Si1 Si 0.35390(7) 0.12235(7) 0.31799(17) 0.0289(9) Uani 1 1 d .
Si2 Si 0.33083(8) 0.08036(8) 0.3058(2) 0.0391(10) Uani 1 1 d .
Si3 Si 0.34422(9) 0.13511(9) 0.4075(2) 0.0465(12) Uani 1 1 d .
Si4 Si 0.35157(8) 0.14423(8) 0.23581(18) 0.0346(10) Uani 1 1 d .
Si5 Si 0.48970(7) 0.21320(7) 0.31838(17) 0.0281(9) Uani 1 1 d .
Si6 Si 0.52384(8) 0.21062(8) 0.2974(2) 0.0460(12) Uani 1 1 d .
Si7 Si 0.48033(9) 0.23348(8) 0.24387(19) 0.0418(11) Uani 1 1 d .
Si8 Si 0.49343(9) 0.23267(8) 0.4114(2) 0.0447(12) Uani 1 1 d .
Si9 Si 0.44306(7) 0.07439(7) 0.34785(18) 0.0287(9) Uani 1 1 d .
Si10 Si 0.46291(10) 0.07669(10) 0.4386(2) 0.0538(13) Uani 1 1 d .
Si11 Si 0.40577(9) 0.03929(8) 0.3430(2) 0.0527(13) Uani 1 1 d .
Si12 Si 0.46666(8) 0.07853(8) 0.2616(2) 0.0395(11) Uani 1 1 d U
C1 C 0.4149(3) 0.1606(3) 0.0772(8) 0.049(4) Uani 1 1 d U
H1A H 0.4205 0.1621 0.0348 0.059 Uiso 1 1 calc R
H1B H 0.3973 0.1500 0.0771 0.059 Uiso 1 1 calc R
C2 C 0.4206(3) 0.1853(3) 0.0995(8) 0.050(4) Uani 1 1 d U
H2A H 0.4382 0.1963 0.0982 0.060 Uiso 1 1 calc R
H2B H 0.4154 0.1841 0.1423 0.060 Uiso 1 1 calc R
C3 C 0.4084(3) 0.1957(3) 0.0613(8) 0.054(5) Uani 1 1 d U
H3A H 0.4138 0.1970 0.0186 0.064 Uiso 1 1 calc R
H3B H 0.3909 0.1848 0.0625 0.064 Uiso 1 1 calc R
C4 C 0.4141(4) 0.2200(3) 0.0835(9) 0.069(6) Uani 1 1 d U
H4A H 0.4061 0.2263 0.0574 0.103 Uiso 1 1 calc R
H4B H 0.4314 0.2310 0.0823 0.103 Uiso 1 1 calc R
H4C H 0.4083 0.2188 0.1253 0.103 Uiso 1 1 calc R
C5 C 0.4135(3) 0.1069(3) 0.1039(7) 0.042(4) Uani 1 1 d U
H5A H 0.4184 0.1060 0.0618 0.051 Uiso 1 1 calc R
H5B H 0.4192 0.0984 0.1304 0.051 Uiso 1 1 calc R
C6 C 0.3865(3) 0.0944(3) 0.1072(7) 0.036(4) Uani 1 1 d U
H6A H 0.3807 0.1017 0.0770 0.043 Uiso 1 1 calc R
H6B H 0.3818 0.0970 0.1479 0.043 Uiso 1 1 calc R
C7 C 0.3743(3) 0.0672(3) 0.0951(7) 0.049(4) Uani 1 1 d U
H7A H 0.3807 0.0600 0.1239 0.058 Uiso 1 1 calc R
H7B H 0.3569 0.0599 0.1024 0.058 Uiso 1 1 calc R
C8 C 0.3783(3) 0.0618(3) 0.0317(7) 0.049(4) Uani 1 1 d U
H8A H 0.3705 0.0444 0.0262 0.074 Uiso 1 1 calc R
H8B H 0.3956 0.0690 0.0243 0.074 Uiso 1 1 calc R
H8C H 0.3716 0.0684 0.0030 0.074 Uiso 1 1 calc R
C9 C 0.4680(3) 0.1602(3) 0.1037(8) 0.050(4) Uani 1 1 d U
H9A H 0.4693 0.1658 0.0613 0.060 Uiso 1 1 calc R
H9B H 0.4775 0.1745 0.1292 0.060 Uiso 1 1 calc R
C10 C 0.4789(3) 0.1452(3) 0.1073(8) 0.046(4) Uani 1 1 d U
H10A H 0.4689 0.1303 0.0841 0.056 Uiso 1 1 calc R
H10B H 0.4788 0.1406 0.1502 0.056 Uiso 1 1 calc R
C11 C 0.5046(3) 0.1569(4) 0.0832(9) 0.063(5) Uani 1 1 d U
H11A H 0.5041 0.1547 0.0386 0.076 Uiso 1 1 calc R
H11B H 0.5127 0.1743 0.0915 0.076 Uiso 1 1 calc R
C12 C 0.5182(6) 0.1473(6) 0.1098(14) 0.146(12) Uani 1 1 d U
H12A H 0.5344 0.1553 0.0927 0.220 Uiso 1 1 calc R
H12B H 0.5104 0.1301 0.1012 0.220 Uiso 1 1 calc R
H12C H 0.5191 0.1498 0.1538 0.220 Uiso 1 1 calc R
C13 C 0.2985(3) 0.0713(3) 0.3141(11) 0.077(7) Uani 1 1 d .
H13A H 0.2886 0.0539 0.3092 0.115 Uiso 1 1 calc R
H13B H 0.2941 0.0793 0.2831 0.115 Uiso 1 1 calc R
H13C H 0.2958 0.0759 0.3545 0.115 Uiso 1 1 calc R
C14 C 0.3347(4) 0.0710(3) 0.2283(8) 0.067(6) Uani 1 1 d .
H14A H 0.3249 0.0536 0.2246 0.100 Uiso 1 1 calc R
H14B H 0.3515 0.0760 0.2218 0.100 Uiso 1 1 calc R
H14C H 0.3295 0.0786 0.1978 0.100 Uiso 1 1 calc R
C15 C 0.3403(3) 0.0656(3) 0.3649(9) 0.059(5) Uani 1 1 d .
H15A H 0.3308 0.0482 0.3603 0.089 Uiso 1 1 calc R
H15B H 0.3376 0.0701 0.4055 0.089 Uiso 1 1 calc R
H15C H 0.3573 0.0709 0.3598 0.089 Uiso 1 1 calc R
C16 C 0.3635(4) 0.1682(3) 0.4145(9) 0.068(6) Uani 1 1 d .
H16A H 0.3594 0.1736 0.4520 0.102 Uiso 1 1 calc R
H16B H 0.3608 0.1759 0.3796 0.102 Uiso 1 1 calc R
H16C H 0.3803 0.1724 0.4157 0.102 Uiso 1 1 calc R
C17 C 0.3122(3) 0.1275(4) 0.4032(9) 0.062(5) Uani 1 1 d .
H17A H 0.3079 0.1328 0.4405 0.093 Uiso 1 1 calc R
H17B H 0.3019 0.1102 0.3986 0.093 Uiso 1 1 calc R
H17C H 0.3100 0.1357 0.3683 0.093 Uiso 1 1 calc R
C18 C 0.3478(4) 0.1201(4) 0.4755(7) 0.084(8) Uani 1 1 d .
H18A H 0.3436 0.1259 0.5120 0.127 Uiso 1 1 calc R
H18B H 0.3645 0.1238 0.4784 0.127 Uiso 1 1 calc R
H18C H 0.3373 0.1028 0.4719 0.127 Uiso 1 1 calc R
C19 C 0.3748(3) 0.1759(3) 0.2441(8) 0.056(5) Uani 1 1 d .
H19A H 0.3739 0.1851 0.2099 0.084 Uiso 1 1 calc R
H19B H 0.3906 0.1772 0.2446 0.084 Uiso 1 1 calc R
H19C H 0.3723 0.1822 0.2821 0.084 Uiso 1 1 calc R
C20 C 0.3570(4) 0.1334(4) 0.1637(8) 0.074(6) Uani 1 1 d .
H20A H 0.3559 0.1427 0.1300 0.111 Uiso 1 1 calc R
H20B H 0.3449 0.1164 0.1583 0.111 Uiso 1 1 calc R
H20C H 0.3730 0.1351 0.1643 0.111 Uiso 1 1 calc R
C21 C 0.3213(3) 0.1409(4) 0.2335(8) 0.069(6) Uani 1 1 d .
H21A H 0.3203 0.1500 0.1992 0.103 Uiso 1 1 calc R
H21B H 0.3184 0.1470 0.2714 0.103 Uiso 1 1 calc R
H21C H 0.3093 0.1239 0.2287 0.103 Uiso 1 1 calc R
C22 C 0.5494(3) 0.2408(3) 0.2874(8) 0.056(5) Uani 1 1 d .
H22A H 0.5638 0.2399 0.2786 0.084 Uiso 1 1 calc R
H22B H 0.5518 0.2501 0.3247 0.084 Uiso 1 1 calc R
H22C H 0.5462 0.2487 0.2537 0.084 Uiso 1 1 calc R
C23 C 0.5288(4) 0.1955(5) 0.3638(12) 0.108(9) Uani 1 1 d .
H23A H 0.5430 0.1941 0.3566 0.162 Uiso 1 1 calc R
H23B H 0.5148 0.1795 0.3691 0.162 Uiso 1 1 calc R
H23C H 0.5312 0.2050 0.4005 0.162 Uiso 1 1 calc R
C24 C 0.5212(4) 0.1940(4) 0.2270(11) 0.094(8) Uani 1 1 d U
H24A H 0.5359 0.1934 0.2205 0.141 Uiso 1 1 calc R
H24B H 0.5186 0.2021 0.1926 0.141 Uiso 1 1 calc R
H24C H 0.5076 0.1777 0.2305 0.141 Uiso 1 1 calc R
C25 C 0.4987(4) 0.2666(3) 0.2547(8) 0.063(5) Uani 1 1 d .
H25A H 0.4946 0.2747 0.2234 0.094 Uiso 1 1 calc R
H25B H 0.5157 0.2716 0.2515 0.094 Uiso 1 1 calc R
H25C H 0.4955 0.2708 0.2949 0.094 Uiso 1 1 calc R
C26 C 0.4860(4) 0.2259(4) 0.1660(7) 0.070(6) Uani 1 1 d .
H26A H 0.4819 0.2345 0.1358 0.105 Uiso 1 1 calc R
H26B H 0.4760 0.2086 0.1593 0.105 Uiso 1 1 calc R
H26C H 0.5029 0.2306 0.1620 0.105 Uiso 1 1 calc R
C27 C 0.4481(3) 0.2246(3) 0.2499(9) 0.061(5) Uani 1 1 d .
H27A H 0.4442 0.2330 0.2189 0.092 Uiso 1 1 calc R
H27B H 0.4449 0.2288 0.2902 0.092 Uiso 1 1 calc R
H27C H 0.4382 0.2073 0.2437 0.092 Uiso 1 1 calc R
C28 C 0.5224(3) 0.2615(3) 0.4111(8) 0.068(6) Uani 1 1 d .
H28A H 0.5243 0.2699 0.4496 0.102 Uiso 1 1 calc R
H28B H 0.5225 0.2715 0.3775 0.102 Uiso 1 1 calc R
H28C H 0.5356 0.2583 0.4061 0.102 Uiso 1 1 calc R
C29 C 0.4687(4) 0.2391(4) 0.4197(9) 0.075(6) Uani 1 1 d .
H29A H 0.4703 0.2472 0.4586 0.113 Uiso 1 1 calc R
H29B H 0.4534 0.2240 0.4187 0.113 Uiso 1 1 calc R
H29C H 0.4693 0.2494 0.3864 0.113 Uiso 1 1 calc R
C30 C 0.4929(4) 0.2146(3) 0.4769(8) 0.071(6) Uani 1 1 d .
H30A H 0.4945 0.2233 0.5145 0.106 Uiso 1 1 calc R
H30B H 0.5062 0.2114 0.4736 0.106 Uiso 1 1 calc R
H30C H 0.4777 0.1994 0.4773 0.106 Uiso 1 1 calc R
C31 C 0.4919(3) 0.1055(4) 0.4408(9) 0.086(8) Uani 1 1 d .
H31A H 0.5003 0.1065 0.4787 0.129 Uiso 1 1 calc R
H31B H 0.4889 0.1189 0.4384 0.129 Uiso 1 1 calc R
H31C H 0.5019 0.1062 0.4063 0.129 Uiso 1 1 calc R
C32 C 0.4441(4) 0.0761(4) 0.5046(8) 0.087(8) Uani 1 1 d .
H32A H 0.4525 0.0771 0.5426 0.130 Uiso 1 1 calc R
H32B H 0.4287 0.0612 0.5038 0.130 Uiso 1 1 calc R
H32C H 0.4415 0.0898 0.5017 0.130 Uiso 1 1 calc R
C33 C 0.4692(5) 0.0519(5) 0.4442(13) 0.128(10) Uani 1 1 d U
H33A H 0.4775 0.0532 0.4826 0.192 Uiso 1 1 calc R
H33B H 0.4794 0.0527 0.4102 0.192 Uiso 1 1 calc R
H33C H 0.4542 0.0366 0.4429 0.192 Uiso 1 1 calc R
C34 C 0.3868(3) 0.0377(4) 0.4073(9) 0.071(6) Uani 1 1 d .
H34A H 0.3713 0.0229 0.4047 0.107 Uiso 1 1 calc R
H34B H 0.3843 0.0515 0.4059 0.107 Uiso 1 1 calc R
H34C H 0.3947 0.0380 0.4455 0.107 Uiso 1 1 calc R
C35 C 0.3902(4) 0.0367(5) 0.2719(10) 0.118(9) Uani 1 1 d U
H35A H 0.3747 0.0217 0.2719 0.176 Uiso 1 1 calc R
H35B H 0.3999 0.0366 0.2378 0.176 Uiso 1 1 calc R
H35C H 0.3875 0.0503 0.2677 0.176 Uiso 1 1 calc R
C36 C 0.4111(5) 0.0142(4) 0.3484(14) 0.119(9) Uani 1 1 d U
H36A H 0.3958 -0.0008 0.3466 0.179 Uiso 1 1 calc R
H36B H 0.4191 0.0151 0.3869 0.179 Uiso 1 1 calc R
H36C H 0.4213 0.0149 0.3146 0.179 Uiso 1 1 calc R
C37 C 0.4961(3) 0.1061(3) 0.2669(10) 0.075(7) Uani 1 1 d .
H37A H 0.5057 0.1075 0.2309 0.113 Uiso 1 1 calc R
H37B H 0.5045 0.1054 0.3033 0.113 Uiso 1 1 calc R
H37C H 0.4939 0.1200 0.2695 0.113 Uiso 1 1 calc R
C38 C 0.4707(4) 0.0518(4) 0.2584(9) 0.077(7) Uani 1 1 d .
H38A H 0.4805 0.0530 0.2229 0.115 Uiso 1 1 calc R
H38B H 0.4551 0.0372 0.2552 0.115 Uiso 1 1 calc R
H38C H 0.4788 0.0511 0.2954 0.115 Uiso 1 1 calc R
C39 C 0.4510(3) 0.0795(4) 0.1913(7) 0.064(6) Uani 1 1 d .
H39A H 0.4609 0.0812 0.1558 0.097 Uiso 1 1 calc R
H39B H 0.4483 0.0931 0.1933 0.097 Uiso 1 1 calc R
H39C H 0.4356 0.0646 0.1879 0.097 Uiso 1 1 calc R
Sn2 Sn 0.43084(2) 0.14375(2) 0.88397(5) 0.0426(3) Uani 1 1 d .
Ge10 Ge 0.43376(3) 0.12689(3) 0.76889(7) 0.0401(4) Uani 1 1 d .
Ge11 Ge 0.45266(3) 0.17534(3) 0.75285(7) 0.0353(4) Uani 1 1 d .
Ge12 Ge 0.40230(3) 0.14353(3) 0.75872(7) 0.0360(4) Uani 1 1 d .
Ge13 Ge 0.43219(3) 0.12383(3) 0.60866(7) 0.0299(4) Uani 1 1 d .
Ge14 Ge 0.45054(3) 0.17142(3) 0.61215(6) 0.0281(4) Uani 1 1 d .
Ge15 Ge 0.40163(3) 0.14012(3) 0.61444(7) 0.0301(4) Uani 1 1 d .
Ge16 Ge 0.40070(3) 0.11044(3) 0.69369(6) 0.0284(4) Uani 1 1 d .
Ge17 Ge 0.46340(3) 0.14977(3) 0.68812(7) 0.0293(4) Uani 1 1 d .
Ge18 Ge 0.42257(3) 0.17632(3) 0.68334(7) 0.0349(4) Uani 1 1 d .
Si13 Si 0.36482(7) 0.07287(7) 0.70389(16) 0.0262(9) Uani 1 1 d .
Si14 Si 0.35956(8) 0.05469(7) 0.60853(17) 0.0335(10) Uani 1 1 d .
Si15 Si 0.37087(8) 0.04990(7) 0.77672(18) 0.0372(10) Uani 1 1 d .
Si16 Si 0.33337(8) 0.07977(8) 0.7300(2) 0.0381(10) Uani 1 1 d .
Si17 Si 0.50360(7) 0.15788(7) 0.69454(17) 0.0303(9) Uani 1 1 d .
Si18 Si 0.49989(8) 0.12018(8) 0.7091(2) 0.0435(11) Uani 1 1 d .
Si19 Si 0.52190(8) 0.17499(9) 0.60114(19) 0.0430(11) Uani 1 1 d .
Si20 Si 0.52519(8) 0.18488(9) 0.7727(2) 0.0476(12) Uani 1 1 d .
Si21 Si 0.41809(7) 0.21041(7) 0.69009(19) 0.0327(9) Uani 1 1 d .
Si22 Si 0.45706(8) 0.24317(8) 0.7038(2) 0.0421(11) Uani 1 1 d .
Si23 Si 0.40107(8) 0.21298(9) 0.5989(2) 0.0445(11) Uani 1 1 d .
Si24 Si 0.39297(8) 0.20493(8) 0.77239(19) 0.0353(10) Uani 1 1 d .
C40 C 0.4498(3) 0.1813(3) 0.9130(8) 0.047(4) Uani 1 1 d U
H40A H 0.4462 0.1908 0.8840 0.056 Uiso 1 1 calc R
H40B H 0.4435 0.1824 0.9532 0.056 Uiso 1 1 calc R
C41 C 0.4758(3) 0.1921(3) 0.9175(8) 0.053(5) Uani 1 1 d U
H41A H 0.4818 0.1900 0.8780 0.064 Uiso 1 1 calc R
H41B H 0.4793 0.1831 0.9482 0.064 Uiso 1 1 calc R
C42 C 0.4899(3) 0.2188(3) 0.9343(8) 0.062(5) Uani 1 1 d U
H42A H 0.5073 0.2247 0.9306 0.074 Uiso 1 1 calc R
H42B H 0.4858 0.2281 0.9057 0.074 Uiso 1 1 calc R
C43 C 0.4843(3) 0.2226(3) 0.9974(9) 0.068(6) Uani 1 1 d U
H43A H 0.4935 0.2397 1.0073 0.103 Uiso 1 1 calc R
H43B H 0.4886 0.2136 1.0257 0.103 Uiso 1 1 calc R
H43C H 0.4671 0.2170 1.0008 0.103 Uiso 1 1 calc R
C44 C 0.4484(3) 0.1275(3) 0.9277(8) 0.059(5) Uani 1 1 d U
H44A H 0.4651 0.1352 0.9130 0.070 Uiso 1 1 calc R
H44B H 0.4489 0.1307 0.9719 0.070 Uiso 1 1 calc R
C45 C 0.4369(3) 0.1009(3) 0.9181(7) 0.044(4) Uani 1 1 d U
H45A H 0.4200 0.0934 0.9313 0.053 Uiso 1 1 calc R
H45B H 0.4368 0.0980 0.8740 0.053 Uiso 1 1 calc R
C46 C 0.4480(4) 0.0882(3) 0.9496(9) 0.067(5) Uani 1 1 d U
H46A H 0.4454 0.0884 0.9939 0.080 Uiso 1 1 calc R
H46B H 0.4654 0.0971 0.9420 0.080 Uiso 1 1 calc R
C47 C 0.4379(4) 0.0627(4) 0.9292(10) 0.081(7) Uani 1 1 d U
H47A H 0.4457 0.0553 0.9517 0.122 Uiso 1 1 calc R
H47B H 0.4408 0.0624 0.8856 0.122 Uiso 1 1 calc R
H47C H 0.4206 0.0537 0.9369 0.122 Uiso 1 1 calc R
C48 C 0.3958(3) 0.1265(3) 0.9224(7) 0.044(4) Uani 1 1 d U
H48A H 0.3885 0.1104 0.9364 0.053 Uiso 1 1 calc R
H48B H 0.4027 0.1326 0.9615 0.053 Uiso 1 1 d R
C49 C 0.3829(3) 0.1406(3) 0.9266(7) 0.037(4) Uani 1 1 d U
H49A H 0.3796 0.1440 0.8851 0.044 Uiso 1 1 calc R
H49B H 0.3936 0.1561 0.9466 0.044 Uiso 1 1 calc R
C50 C 0.3597(3) 0.1282(3) 0.9611(8) 0.048(4) Uani 1 1 d U
H50A H 0.3494 0.1122 0.9430 0.058 Uiso 1 1 calc R
H50B H 0.3631 0.1258 1.0036 0.058 Uiso 1 1 calc R
C51 C 0.3461(3) 0.1415(4) 0.9616(10) 0.069(6) Uani 1 1 d U
H51A H 0.3312 0.1323 0.9844 0.103 Uiso 1 1 calc R
H51B H 0.3424 0.1438 0.9198 0.103 Uiso 1 1 calc R
H51C H 0.3559 0.1572 0.9809 0.103 Uiso 1 1 calc R
C52 C 0.4015(3) 0.0538(3) 0.7686(8) 0.051(5) Uani 1 1 d .
H52A H 0.4037 0.0441 0.7993 0.077 Uiso 1 1 calc R
H52B H 0.4135 0.0707 0.7743 0.077 Uiso 1 1 calc R
H52C H 0.4032 0.0486 0.7280 0.077 Uiso 1 1 calc R
C53 C 0.3689(4) 0.0595(3) 0.8542(7) 0.055(5) Uani 1 1 d .
H53A H 0.3715 0.0496 0.8837 0.082 Uiso 1 1 calc R
H53B H 0.3530 0.0576 0.8605 0.082 Uiso 1 1 calc R
H53C H 0.3812 0.0763 0.8596 0.082 Uiso 1 1 calc R
C54 C 0.3476(3) 0.0176(3) 0.7666(8) 0.058(5) Uani 1 1 d .
H54A H 0.3500 0.0079 0.7969 0.087 Uiso 1 1 calc R
H54B H 0.3489 0.0124 0.7258 0.087 Uiso 1 1 calc R
H54C H 0.3316 0.0157 0.7719 0.087 Uiso 1 1 calc R
C55 C 0.3843(3) 0.0483(3) 0.5954(7) 0.050(4) Uani 1 1 d .
H55A H 0.3823 0.0407 0.5556 0.075 Uiso 1 1 calc R
H55B H 0.3840 0.0375 0.6271 0.075 Uiso 1 1 calc R
H55C H 0.3997 0.0633 0.5966 0.075 Uiso 1 1 calc R
C56 C 0.3310(3) 0.0254(3) 0.6076(8) 0.071(6) Uani 1 1 d .
H56A H 0.3289 0.0179 0.5677 0.107 Uiso 1 1 calc R
H56B H 0.3176 0.0280 0.6159 0.107 Uiso 1 1 calc R
H56C H 0.3316 0.0149 0.6389 0.107 Uiso 1 1 calc R
C57 C 0.3599(4) 0.0744(4) 0.5449(8) 0.069(6) Uani 1 1 d .
H57A H 0.3577 0.0662 0.5060 0.104 Uiso 1 1 calc R
H57B H 0.3753 0.0894 0.5447 0.104 Uiso 1 1 calc R
H57C H 0.3469 0.0779 0.5509 0.104 Uiso 1 1 calc R
C58 C 0.3383(3) 0.0948(3) 0.8054(8) 0.059(5) Uani 1 1 d .
H58A H 0.3249 0.0973 0.8145 0.088 Uiso 1 1 calc R
H58B H 0.3532 0.1103 0.8043 0.088 Uiso 1 1 calc R
H58C H 0.3395 0.0847 0.8368 0.088 Uiso 1 1 calc R
C59 C 0.3306(3) 0.0988(3) 0.6698(8) 0.058(5) Uani 1 1 d .
H59A H 0.3175 0.1017 0.6803 0.087 Uiso 1 1 calc R
H59B H 0.3271 0.0905 0.6306 0.087 Uiso 1 1 calc R
H59C H 0.3456 0.1141 0.6669 0.087 Uiso 1 1 calc R
C60 C 0.3054(3) 0.0502(3) 0.7381(8) 0.052(5) Uani 1 1 d .
H60A H 0.2921 0.0528 0.7490 0.079 Uiso 1 1 calc R
H60B H 0.3076 0.0409 0.7701 0.079 Uiso 1 1 calc R
H60C H 0.3018 0.0415 0.6996 0.079 Uiso 1 1 calc R
C61 C 0.4813(4) 0.1048(3) 0.7774(9) 0.066(6) Uani 1 1 d .
H61A H 0.4801 0.0891 0.7822 0.100 Uiso 1 1 calc R
H61B H 0.4652 0.1027 0.7721 0.100 Uiso 1 1 calc R
H61C H 0.4888 0.1146 0.8135 0.100 Uiso 1 1 calc R
C62 C 0.4846(3) 0.1017(3) 0.6410(8) 0.058(5) Uani 1 1 d .
H62A H 0.4827 0.0858 0.6457 0.088 Uiso 1 1 calc R
H62B H 0.4942 0.1094 0.6048 0.088 Uiso 1 1 calc R
H62C H 0.4688 0.1003 0.6367 0.088 Uiso 1 1 calc R
C63 C 0.5298(3) 0.1233(4) 0.7190(9) 0.070(6) Uani 1 1 d .
H63A H 0.5281 0.1075 0.7252 0.105 Uiso 1 1 calc R
H63B H 0.5377 0.1334 0.7545 0.105 Uiso 1 1 calc R
H63C H 0.5395 0.1307 0.6827 0.105 Uiso 1 1 calc R
C64 C 0.5302(4) 0.2072(3) 0.6009(7) 0.074(7) Uani 1 1 d .
H64A H 0.5378 0.2145 0.5622 0.111 Uiso 1 1 calc R
H64B H 0.5413 0.2155 0.6343 0.111 Uiso 1 1 calc R
H64C H 0.5157 0.2084 0.6063 0.111 Uiso 1 1 calc R
C65 C 0.5490(3) 0.1721(4) 0.5911(8) 0.070(6) Uani 1 1 d .
H65A H 0.5566 0.1792 0.5522 0.105 Uiso 1 1 calc R
H65B H 0.5444 0.1551 0.5916 0.105 Uiso 1 1 calc R
H65C H 0.5603 0.1805 0.6242 0.105 Uiso 1 1 calc R
C66 C 0.5013(3) 0.1592(3) 0.5359(7) 0.056(5) Uani 1 1 d .
H66A H 0.5094 0.1667 0.4977 0.084 Uiso 1 1 calc R
H66B H 0.4868 0.1604 0.5399 0.084 Uiso 1 1 calc R
H66C H 0.4970 0.1423 0.5360 0.084 Uiso 1 1 calc R
C67 C 0.5202(3) 0.2113(3) 0.7736(8) 0.057(5) Uani 1 1 d .
H67A H 0.5294 0.2221 0.8067 0.086 Uiso 1 1 calc R
H67B H 0.5031 0.2056 0.7796 0.086 Uiso 1 1 calc R
H67C H 0.5254 0.2198 0.7348 0.086 Uiso 1 1 calc R
C68 C 0.5159(3) 0.1692(4) 0.8470(6) 0.063(6) Uani 1 1 d .
H68A H 0.5250 0.1805 0.8797 0.095 Uiso 1 1 calc R
H68B H 0.5192 0.1559 0.8474 0.095 Uiso 1 1 calc R
H68C H 0.4988 0.1630 0.8531 0.095 Uiso 1 1 calc R
C69 C 0.5575(3) 0.1960(4) 0.7595(8) 0.074(6) Uani 1 1 d .
H69A H 0.5669 0.2072 0.7917 0.112 Uiso 1 1 calc R
H69B H 0.5622 0.2041 0.7201 0.112 Uiso 1 1 calc R
H69C H 0.5604 0.1824 0.7597 0.112 Uiso 1 1 calc R
C70 C 0.4760(3) 0.2443(4) 0.6391(10) 0.084(7) Uani 1 1 d U
H70A H 0.4922 0.2579 0.6444 0.127 Uiso 1 1 calc R
H70B H 0.4692 0.2463 0.6012 0.127 Uiso 1 1 calc R
H70C H 0.4765 0.2294 0.6375 0.127 Uiso 1 1 calc R
C71 C 0.4712(4) 0.2416(3) 0.7751(10) 0.080(7) Uani 1 1 d .
H71A H 0.4873 0.2556 0.7782 0.120 Uiso 1 1 calc R
H71B H 0.4723 0.2269 0.7753 0.120 Uiso 1 1 calc R
H71C H 0.4615 0.2413 0.8097 0.120 Uiso 1 1 calc R
C72 C 0.4558(3) 0.2710(3) 0.7103(8) 0.058(5) Uani 1 1 d .
H72A H 0.4720 0.2846 0.7160 0.087 Uiso 1 1 calc R
H72B H 0.4458 0.2698 0.7452 0.087 Uiso 1 1 calc R
H72C H 0.4488 0.2733 0.6732 0.087 Uiso 1 1 calc R
C73 C 0.4026(4) 0.2425(4) 0.5939(8) 0.068(6) Uani 1 1 d .
H73A H 0.3955 0.2436 0.5555 0.101 Uiso 1 1 calc R
H73B H 0.4194 0.2554 0.5956 0.101 Uiso 1 1 calc R
H73C H 0.3938 0.2443 0.6279 0.101 Uiso 1 1 calc R
C74 C 0.3700(4) 0.1897(4) 0.5956(9) 0.073(6) Uani 1 1 d .
H74A H 0.3630 0.1909 0.5573 0.109 Uiso 1 1 calc R
H74B H 0.3613 0.1915 0.6296 0.109 Uiso 1 1 calc R
H74C H 0.3690 0.1740 0.5981 0.109 Uiso 1 1 calc R
C75 C 0.4162(3) 0.2086(4) 0.5329(9) 0.075(6) Uani 1 1 d .
H75A H 0.4087 0.2098 0.4953 0.112 Uiso 1 1 calc R
H75B H 0.4147 0.1927 0.5353 0.112 Uiso 1 1 calc R
H75C H 0.4331 0.2209 0.5330 0.112 Uiso 1 1 calc R
C76 C 0.3639(3) 0.1761(3) 0.7672(9) 0.066(6) Uani 1 1 d .
H76A H 0.3539 0.1746 0.8025 0.100 Uiso 1 1 calc R
H76B H 0.3669 0.1627 0.7665 0.100 Uiso 1 1 calc R
H76C H 0.3555 0.1760 0.7300 0.100 Uiso 1 1 calc R
C77 C 0.4078(3) 0.2043(3) 0.8455(7) 0.055(5) Uani 1 1 d .
H77A H 0.3971 0.2020 0.8796 0.082 Uiso 1 1 calc R
H77B H 0.4228 0.2195 0.8505 0.082 Uiso 1 1 calc R
H77C H 0.4112 0.1911 0.8444 0.082 Uiso 1 1 calc R
C78 C 0.3874(3) 0.2311(3) 0.7744(8) 0.060(5) Uani 1 1 d .
H78A H 0.3769 0.2292 0.8086 0.090 Uiso 1 1 calc R
H78B H 0.3798 0.2316 0.7364 0.090 Uiso 1 1 calc R
H78C H 0.4027 0.2461 0.7791 0.090 Uiso 1 1 calc R
Sn3 Sn 1.0000 1.0000 0.12621(8) 0.0400(5) Uani 1 3 d S
Ge19 Ge 0.97806(3) 0.97217(3) 0.24522(8) 0.0425(4) Uani 1 1 d .
Ge20 Ge 0.96413(3) 0.99258(3) 0.31661(7) 0.0347(4) Uani 1 1 d .
Ge21 Ge 0.97922(3) 0.97379(3) 0.39423(7) 0.0324(4) Uani 1 1 d .
Si25 Si 0.92471(8) 0.98601(9) 0.3131(2) 0.0459(12) Uani 1 1 d .
Si26 Si 0.90441(9) 0.96321(13) 0.2279(2) 0.0720(19) Uani 1 1 d .
Si27 Si 0.90744(12) 0.96383(13) 0.4022(3) 0.0809(19) Uani 1 1 d U
Si28 Si 0.92621(14) 1.02326(15) 0.3096(4) 0.111(3) Uani 1 1 d .
C79 C 0.9657(3) 0.9754(3) 0.0866(8) 0.056(5) Uani 1 1 d .
H79A H 0.9530 0.9763 0.1099 0.067 Uiso 1 1 calc R
H79B H 0.9653 0.9805 0.0445 0.067 Uiso 1 1 calc R
C80 C 0.9601(3) 0.9497(3) 0.0854(7) 0.049(4) Uani 1 1 d .
H80A H 0.9736 0.9491 0.0658 0.058 Uiso 1 1 calc R
H80B H 0.9589 0.9441 0.1277 0.058 Uiso 1 1 calc R
C81 C 0.9373(3) 0.9328(3) 0.0526(9) 0.062(5) Uani 1 1 d .
H81A H 0.9239 0.9341 0.0706 0.074 Uiso 1 1 calc R
H81B H 0.9388 0.9378 0.0096 0.074 Uiso 1 1 calc R
C82 C 0.9310(4) 0.9073(4) 0.0545(11) 0.083(7) Uani 1 1 d U
H82A H 0.9160 0.8975 0.0325 0.124 Uiso 1 1 calc R
H82B H 0.9291 0.9020 0.0969 0.124 Uiso 1 1 calc R
H82C H 0.9438 0.9056 0.0355 0.124 Uiso 1 1 calc R
C83 C 0.9106(3) 0.9380(3) 0.2147(9) 0.068(6) Uani 1 1 d .
H83A H 0.9018 0.9289 0.1788 0.102 Uiso 1 1 calc R
H83B H 0.9054 0.9274 0.2502 0.102 Uiso 1 1 calc R
H83C H 0.9278 0.9445 0.2083 0.102 Uiso 1 1 calc R
C84 C 0.8720(4) 0.9502(6) 0.2420(12) 0.128(10) Uani 1 1 d U
H84A H 0.8629 0.9405 0.2070 0.192 Uiso 1 1 calc R
H84B H 0.8683 0.9631 0.2482 0.192 Uiso 1 1 calc R
H84C H 0.8674 0.9401 0.2783 0.192 Uiso 1 1 calc R
C85 C 0.9138(5) 0.9827(4) 0.1583(9) 0.094(7) Uani 1 1 d U
H85A H 0.9053 0.9731 0.1228 0.141 Uiso 1 1 calc R
H85B H 0.9311 0.9898 0.1522 0.141 Uiso 1 1 calc R
H85C H 0.9100 0.9955 0.1637 0.141 Uiso 1 1 calc R
C86 C 0.9086(4) 0.9349(4) 0.3944(10) 0.100(8) Uani 1 1 d U
H86A H 0.9015 0.9250 0.4305 0.151 Uiso 1 1 calc R
H86B H 0.9253 0.9388 0.3902 0.151 Uiso 1 1 calc R
H86C H 0.8995 0.9261 0.3583 0.151 Uiso 1 1 calc R
C87 C 0.9247(4) 0.9811(5) 0.4708(9) 0.088(8) Uani 1 1 d .
H87A H 0.9173 0.9716 0.5074 0.133 Uiso 1 1 calc R
H87B H 0.9245 0.9961 0.4732 0.133 Uiso 1 1 calc R
H87C H 0.9413 0.9844 0.4677 0.133 Uiso 1 1 calc R
C88 C 0.8766(4) 0.9576(5) 0.4109(10) 0.105(8) Uani 1 1 d U
H88A H 0.8697 0.9484 0.4481 0.157 Uiso 1 1 calc R
H88B H 0.8671 0.9484 0.3759 0.157 Uiso 1 1 calc R
H88C H 0.8766 0.9728 0.4134 0.157 Uiso 1 1 calc R
C89 C 0.9461(6) 1.0418(6) 0.2459(16) 0.159(13) Uani 1 1 d U
H89A H 0.9466 1.0573 0.2448 0.239 Uiso 1 1 calc R
H89B H 0.9397 1.0334 0.2073 0.239 Uiso 1 1 calc R
H89C H 0.9623 1.0445 0.2522 0.239 Uiso 1 1 calc R
C90 C 0.8955(6) 1.0169(6) 0.2907(16) 0.160(13) Uani 1 1 d U
H90A H 0.8952 1.0320 0.2887 0.240 Uiso 1 1 calc R
H90B H 0.8843 1.0066 0.3221 0.240 Uiso 1 1 calc R
H90C H 0.8906 1.0088 0.2513 0.240 Uiso 1 1 calc R
C91 C 0.9354(5) 1.0371(5) 0.3869(13) 0.131(11) Uani 1 1 d U
H91A H 0.9362 1.0527 0.3871 0.197 Uiso 1 1 calc R
H91B H 0.9511 1.0392 0.3971 0.197 Uiso 1 1 calc R
H91C H 0.9236 1.0266 0.4170 0.197 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Sn1 C5 106.7(6) . .
C1 Sn1 C9 107.1(6) . .
C5 Sn1 C9 106.5(6) . .
C1 Sn1 Ge1 105.6(5) . .
C5 Sn1 Ge1 117.4(4) . .
C9 Sn1 Ge1 113.0(5) . .
Ge7 Ge1 Ge8 87.93(7) . .
Ge7 Ge1 Ge2 104.13(7) . .
Ge8 Ge1 Ge2 59.93(6) . .
Ge7 Ge1 Ge3 59.85(6) . .
Ge8 Ge1 Ge3 104.16(7) . .
Ge2 Ge1 Ge3 65.00(6) . .
Ge7 Ge1 Sn1 136.94(8) . .
Ge8 Ge1 Sn1 130.69(8) . .
Ge2 Ge1 Sn1 85.19(6) . .
Ge3 Ge1 Sn1 88.72(6) . .
Ge9 Ge2 Ge8 98.86(7) . .
Ge9 Ge2 Ge1 102.59(7) . .
Ge8 Ge2 Ge1 56.40(6) . .
Ge9 Ge2 Ge3 55.13(5) . .
Ge8 Ge2 Ge3 96.41(6) . .
Ge1 Ge2 Ge3 57.52(5) . .
Ge9 Ge3 Ge7 98.89(7) . .
Ge9 Ge3 Ge1 102.43(7) . .
Ge7 Ge3 Ge1 56.36(6) . .
Ge9 Ge3 Ge2 54.98(5) . .
Ge7 Ge3 Ge2 96.37(6) . .
Ge1 Ge3 Ge2 57.48(5) . .
Ge7 Ge4 Ge8 84.42(6) . .
Ge7 Ge4 Ge5 101.16(6) . .
Ge8 Ge4 Ge5 58.89(5) . .
Ge7 Ge4 Ge6 58.68(5) . .
Ge8 Ge4 Ge6 101.01(6) . .
Ge5 Ge4 Ge6 63.84(5) . .
Ge9 Ge5 Ge8 98.49(7) . .
Ge9 Ge5 Ge4 104.97(7) . .
Ge8 Ge5 Ge4 58.63(5) . .
Ge9 Ge5 Ge6 55.96(5) . .
Ge8 Ge5 Ge6 96.98(6) . .
Ge4 Ge5 Ge6 58.23(5) . .
Ge9 Ge6 Ge7 98.78(7) . .
Ge9 Ge6 Ge4 104.85(7) . .
Ge7 Ge6 Ge4 58.55(5) . .
Ge9 Ge6 Ge5 56.12(5) . .
Ge7 Ge6 Ge5 96.98(6) . .
Ge4 Ge6 Ge5 57.94(5) . .
Si1 Ge7 Ge1 124.66(11) . .
Si1 Ge7 Ge4 127.57(12) . .
Ge1 Ge7 Ge4 93.25(7) . .
Si1 Ge7 Ge6 117.87(11) . .
Ge1 Ge7 Ge6 113.49(7) . .
Ge4 Ge7 Ge6 62.76(6) . .
Si1 Ge7 Ge3 114.12(12) . .
Ge1 Ge7 Ge3 63.79(6) . .
Ge4 Ge7 Ge3 114.92(7) . .
Ge6 Ge7 Ge3 72.53(6) . .
Si5 Ge8 Ge1 124.49(11) . .
Si5 Ge8 Ge4 126.09(11) . .
Ge1 Ge8 Ge4 93.16(7) . .
Si5 Ge8 Ge5 118.93(11) . .
Ge1 Ge8 Ge5 113.50(7) . .
Ge4 Ge8 Ge5 62.47(6) . .
Si5 Ge8 Ge2 116.16(12) . .
Ge1 Ge8 Ge2 63.66(6) . .
Ge4 Ge8 Ge2 114.81(7) . .
Ge5 Ge8 Ge2 72.83(6) . .
Si9 Ge9 Ge2 119.41(11) . .
Si9 Ge9 Ge3 117.11(12) . .
Ge2 Ge9 Ge3 69.89(6) . .
Si9 Ge9 Ge6 128.16(12) . .
Ge2 Ge9 Ge6 112.03(7) . .
Ge3 Ge9 Ge6 74.40(6) . .
Si9 Ge9 Ge5 130.80(12) . .
Ge2 Ge9 Ge5 74.86(6) . .
Ge3 Ge9 Ge5 112.00(7) . .
Ge6 Ge9 Ge5 67.92(6) . .
Si3 Si1 Si4 109.3(2) . .
Si3 Si1 Si2 111.9(2) . .
Si4 Si1 Si2 114.1(2) . .
Si3 Si1 Ge7 104.94(19) . .
Si4 Si1 Ge7 106.12(18) . .
Si2 Si1 Ge7 109.95(19) . .
C13 Si2 C14 107.2(10) . .
C13 Si2 C15 111.3(9) . .
C14 Si2 C15 110.0(9) . .
C13 Si2 Si1 108.2(6) . .
C14 Si2 Si1 111.4(6) . .
C15 Si2 Si1 108.8(6) . .
C18 Si3 C17 108.3(9) . .
C18 Si3 C16 110.1(10) . .
C17 Si3 C16 108.7(9) . .
C18 Si3 Si1 111.8(6) . .
C17 Si3 Si1 108.6(6) . .
C16 Si3 Si1 109.3(6) . .
C20 Si4 C19 107.6(9) . .
C20 Si4 C21 108.7(9) . .
C19 Si4 C21 111.1(9) . .
C20 Si4 Si1 110.8(7) . .
C19 Si4 Si1 109.2(5) . .
C21 Si4 Si1 109.4(6) . .
Si6 Si5 Si8 111.2(2) . .
Si6 Si5 Si7 114.5(2) . .
Si8 Si5 Si7 107.2(2) . .
Si6 Si5 Ge8 110.2(2) . .
Si8 Si5 Ge8 106.26(19) . .
Si7 Si5 Ge8 107.01(19) . .
C22 Si6 C24 106.9(10) . .
C22 Si6 C23 110.6(10) . .
C24 Si6 C23 110.2(12) . .
C22 Si6 Si5 109.0(6) . .
C24 Si6 Si5 113.0(8) . .
C23 Si6 Si5 107.2(6) . .
C25 Si7 C27 108.4(9) . .
C25 Si7 C26 108.8(9) . .
C27 Si7 C26 108.5(9) . .
C25 Si7 Si5 110.7(6) . .
C27 Si7 Si5 109.6(6) . .
C26 Si7 Si5 110.9(7) . .
C30 Si8 C29 108.6(10) . .
C30 Si8 C28 109.0(9) . .
C29 Si8 C28 109.0(10) . .
C30 Si8 Si5 112.3(6) . .
C29 Si8 Si5 109.7(7) . .
C28 Si8 Si5 108.3(6) . .
Si10 Si9 Si11 111.4(3) . .
Si10 Si9 Si12 112.3(2) . .
Si11 Si9 Si12 111.4(2) . .
Si10 Si9 Ge9 106.2(2) . .
Si11 Si9 Ge9 108.3(2) . .
Si12 Si9 Ge9 106.97(19) . .
C33 Si10 C31 108.3(12) . .
C33 Si10 C32 110.5(13) . .
C31 Si10 C32 108.4(9) . .
C33 Si10 Si9 110.8(9) . .
C31 Si10 Si9 109.3(7) . .
C32 Si10 Si9 109.5(7) . .
C36 Si11 C35 108.3(14) . .
C36 Si11 C34 108.6(11) . .
C35 Si11 C34 109.5(11) . .
C36 Si11 Si9 107.3(9) . .
C35 Si11 Si9 112.4(8) . .
C34 Si11 Si9 110.6(7) . .
C37 Si12 C39 109.6(9) . .
C37 Si12 C38 109.7(10) . .
C39 Si12 C38 109.1(10) . .
C37 Si12 Si9 110.6(7) . .
C39 Si12 Si9 110.0(6) . .
C38 Si12 Si9 107.8(6) . .
C2 C1 Sn1 114.1(11) . .
C2 C1 H1A 108.7 . .
Sn1 C1 H1A 108.7 . .
C2 C1 H1B 108.7 . .
Sn1 C1 H1B 108.7 . .
H1A C1 H1B 107.6 . .
C1 C2 C3 111.9(14) . .
C1 C2 H2A 109.2 . .
C3 C2 H2A 109.2 . .
C1 C2 H2B 109.2 . .
C3 C2 H2B 109.2 . .
H2A C2 H2B 107.9 . .
C4 C3 C2 111.8(15) . .
C4 C3 H3A 109.2 . .
C2 C3 H3A 109.2 . .
C4 C3 H3B 109.2 . .
C2 C3 H3B 109.2 . .
H3A C3 H3B 107.9 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C6 C5 Sn1 113.2(10) . .
C6 C5 H5A 108.9 . .
Sn1 C5 H5A 108.9 . .
C6 C5 H5B 108.9 . .
Sn1 C5 H5B 108.9 . .
H5A C5 H5B 107.7 . .
C5 C6 C7 113.3(13) . .
C5 C6 H6A 108.9 . .
C7 C6 H6A 108.9 . .
C5 C6 H6B 108.9 . .
C7 C6 H6B 108.9 . .
H6A C6 H6B 107.7 . .
C8 C7 C6 112.2(14) . .
C8 C7 H7A 109.2 . .
C6 C7 H7A 109.2 . .
C8 C7 H7B 109.2 . .
C6 C7 H7B 109.2 . .
H7A C7 H7B 107.9 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 Sn1 117.0(12) . .
C10 C9 H9A 108.1 . .
Sn1 C9 H9A 108.1 . .
C10 C9 H9B 108.1 . .
Sn1 C9 H9B 108.1 . .
H9A C9 H9B 107.3 . .
C9 C10 C11 114.5(15) . .
C9 C10 H10A 108.6 . .
C11 C10 H10A 108.6 . .
C9 C10 H10B 108.6 . .
C11 C10 H10B 108.6 . .
H10A C10 H10B 107.6 . .
C12 C11 C10 112.9(19) . .
C12 C11 H11A 109.0 . .
C10 C11 H11A 109.0 . .
C12 C11 H11B 109.0 . .
C10 C11 H11B 109.0 . .
H11A C11 H11B 107.8 . .
C11 C12 H12A 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
Si2 C13 H13A 109.5 . .
Si2 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
Si2 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
Si2 C14 H14A 109.5 . .
Si2 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
Si2 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Si2 C15 H15A 109.5 . .
Si2 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
Si2 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
Si3 C16 H16A 109.5 . .
Si3 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
Si3 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
Si3 C17 H17A 109.5 . .
Si3 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
Si3 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
Si3 C18 H18A 109.5 . .
Si3 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
Si3 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
Si4 C19 H19A 109.5 . .
Si4 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
Si4 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
Si4 C20 H20A 109.5 . .
Si4 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
Si4 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
Si4 C21 H21A 109.5 . .
Si4 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
Si4 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
Si6 C22 H22A 109.5 . .
Si6 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
Si6 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
Si6 C23 H23A 109.5 . .
Si6 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
Si6 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
Si6 C24 H24A 109.5 . .
Si6 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
Si6 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
Si7 C25 H25A 109.5 . .
Si7 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
Si7 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
Si7 C26 H26A 109.5 . .
Si7 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
Si7 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
Si7 C27 H27A 109.5 . .
Si7 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
Si7 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
Si8 C28 H28A 109.5 . .
Si8 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
Si8 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
Si8 C29 H29A 109.5 . .
Si8 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
Si8 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
Si8 C30 H30A 109.5 . .
Si8 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
Si8 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
Si10 C31 H31A 109.5 . .
Si10 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
Si10 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
Si10 C32 H32A 109.5 . .
Si10 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
Si10 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
Si10 C33 H33A 109.5 . .
Si10 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
Si10 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
Si11 C34 H34A 109.5 . .
Si11 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
Si11 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
Si11 C35 H35A 109.5 . .
Si11 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
Si11 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
Si11 C36 H36A 109.5 . .
Si11 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
Si11 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
Si12 C37 H37A 109.5 . .
Si12 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
Si12 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
Si12 C38 H38A 109.5 . .
Si12 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
Si12 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
Si12 C39 H39A 109.5 . .
Si12 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
Si12 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
C44 Sn2 C48 104.5(7) . .
C44 Sn2 C40 105.8(6) . .
C48 Sn2 C40 108.7(6) . .
C44 Sn2 Ge10 93.7(5) . .
C48 Sn2 Ge10 114.6(4) . .
C40 Sn2 Ge10 125.7(4) . .
Ge16 Ge10 Ge17 90.99(7) . .
Ge16 Ge10 Ge12 57.73(6) . .
Ge17 Ge10 Ge12 102.10(7) . .
Ge16 Ge10 Ge11 101.42(7) . .
Ge17 Ge10 Ge11 57.40(6) . .
Ge12 Ge10 Ge11 62.52(6) . .
Ge16 Ge10 Sn2 124.06(8) . .
Ge17 Ge10 Sn2 126.76(8) . .
Ge12 Ge10 Sn2 73.45(6) . .
Ge11 Ge10 Sn2 75.70(6) . .
Ge18 Ge11 Ge17 98.08(7) . .
Ge18 Ge11 Ge10 101.47(7) . .
Ge17 Ge11 Ge10 56.01(6) . .
Ge18 Ge11 Ge12 54.93(6) . .
Ge17 Ge11 Ge12 98.13(7) . .
Ge10 Ge11 Ge12 58.51(6) . .
Ge18 Ge12 Ge16 96.99(7) . .
Ge18 Ge12 Ge10 102.15(7) . .
Ge16 Ge12 Ge10 56.03(6) . .
Ge18 Ge12 Ge11 55.34(6) . .
Ge16 Ge12 Ge11 97.63(7) . .
Ge10 Ge12 Ge11 58.96(6) . .
Ge17 Ge13 Ge16 87.26(7) . .
Ge17 Ge13 Ge15 101.83(7) . .
Ge16 Ge13 Ge15 58.76(6) . .
Ge17 Ge13 Ge14 58.63(5) . .
Ge16 Ge13 Ge14 100.70(7) . .
Ge15 Ge13 Ge14 62.41(6) . .
Ge18 Ge14 Ge17 96.22(7) . .
Ge18 Ge14 Ge13 103.11(7) . .
Ge17 Ge14 Ge13 58.28(6) . .
Ge18 Ge14 Ge15 57.00(6) . .
Ge17 Ge14 Ge15 98.72(6) . .
Ge13 Ge14 Ge15 58.40(5) . .
Ge18 Ge15 Ge16 94.73(7) . .
Ge18 Ge15 Ge13 103.51(7) . .
Ge16 Ge15 Ge13 58.95(6) . .
Ge18 Ge15 Ge14 56.70(6) . .
Ge16 Ge15 Ge14 98.59(6) . .
Ge13 Ge15 Ge14 59.19(5) . .
Si13 Ge16 Ge10 124.23(11) . .
Si13 Ge16 Ge12 114.45(11) . .
Ge10 Ge16 Ge12 66.24(7) . .
Si13 Ge16 Ge15 118.09(11) . .
Ge10 Ge16 Ge15 116.12(8) . .
Ge12 Ge16 Ge15 77.32(7) . .
Si13 Ge16 Ge13 127.76(11) . .
Ge10 Ge16 Ge13 88.70(7) . .
Ge12 Ge16 Ge13 115.90(7) . .
Ge15 Ge16 Ge13 62.29(6) . .
Si17 Ge17 Ge10 121.20(12) . .
Si17 Ge17 Ge11 116.59(12) . .
Ge10 Ge17 Ge11 66.59(7) . .
Si17 Ge17 Ge13 126.79(12) . .
Ge10 Ge17 Ge13 88.95(7) . .
Ge11 Ge17 Ge13 115.50(8) . .
Si17 Ge17 Ge14 122.14(12) . .
Ge10 Ge17 Ge14 115.32(8) . .
Ge11 Ge17 Ge14 75.18(7) . .
Ge13 Ge17 Ge14 63.09(6) . .
Si21 Ge18 Ge12 119.54(12) . .
Si21 Ge18 Ge11 116.32(12) . .
Ge12 Ge18 Ge11 69.73(7) . .
Si21 Ge18 Ge14 125.67(12) . .
Ge12 Ge18 Ge14 114.41(8) . .
Ge11 Ge18 Ge14 76.42(7) . .
Si21 Ge18 Ge15 129.67(13) . .
Ge12 Ge18 Ge15 78.75(7) . .
Ge11 Ge18 Ge15 114.01(8) . .
Ge14 Ge18 Ge15 66.30(6) . .
Si15 Si13 Si14 109.0(2) . .
Si15 Si13 Si16 112.6(2) . .
Si14 Si13 Si16 113.0(2) . .
Si15 Si13 Ge16 108.85(19) . .
Si14 Si13 Ge16 104.37(18) . .
Si16 Si13 Ge16 108.75(19) . .
C56 Si14 C55 107.2(9) . .
C56 Si14 C57 110.4(9) . .
C55 Si14 C57 108.2(8) . .
C56 Si14 Si13 109.8(6) . .
C55 Si14 Si13 108.9(5) . .
C57 Si14 Si13 112.2(6) . .
C53 Si15 C52 106.8(8) . .
C53 Si15 C54 109.4(8) . .
C52 Si15 C54 110.0(8) . .
C53 Si15 Si13 111.1(5) . .
C52 Si15 Si13 110.4(5) . .
C54 Si15 Si13 109.1(6) . .
C60 Si16 C58 105.8(7) . .
C60 Si16 C59 112.1(8) . .
C58 Si16 C59 109.7(9) . .
C60 Si16 Si13 108.4(6) . .
C58 Si16 Si13 112.0(6) . .
C59 Si16 Si13 109.0(6) . .
Si20 Si17 Si18 112.6(2) . .
Si20 Si17 Si19 108.7(2) . .
Si18 Si17 Si19 111.9(2) . .
Si20 Si17 Ge17 112.6(2) . .
Si18 Si17 Ge17 104.22(19) . .
Si19 Si17 Ge17 106.67(19) . .
C63 Si18 C61 108.7(9) . .
C63 Si18 C62 110.9(9) . .
C61 Si18 C62 108.3(9) . .
C63 Si18 Si17 110.1(7) . .
C61 Si18 Si17 111.5(6) . .
C62 Si18 Si17 107.4(6) . .
C65 Si19 C64 110.5(10) . .
C65 Si19 C66 107.5(9) . .
C64 Si19 C66 109.5(8) . .
C65 Si19 Si17 109.5(6) . .
C64 Si19 Si17 108.7(6) . .
C66 Si19 Si17 111.3(6) . .
C69 Si20 C68 109.9(9) . .
C69 Si20 C67 108.7(9) . .
C68 Si20 C67 109.2(8) . .
C69 Si20 Si17 107.8(6) . .
C68 Si20 Si17 109.4(7) . .
C67 Si20 Si17 111.8(5) . .
Si23 Si21 Si24 111.3(2) . .
Si23 Si21 Si22 112.0(2) . .
Si24 Si21 Si22 112.6(2) . .
Si23 Si21 Ge18 107.0(2) . .
Si24 Si21 Ge18 107.8(2) . .
Si22 Si21 Ge18 105.7(2) . .
C72 Si22 C71 104.6(9) . .
C72 Si22 C70 111.7(10) . .
C71 Si22 C70 108.8(11) . .
C72 Si22 Si21 109.6(6) . .
C71 Si22 Si21 113.2(7) . .
C70 Si22 Si21 108.9(6) . .
C74 Si23 C75 106.8(10) . .
C74 Si23 C73 108.6(9) . .
C75 Si23 C73 110.3(10) . .
C74 Si23 Si21 109.9(6) . .
C75 Si23 Si21 111.3(7) . .
C73 Si23 Si21 109.7(6) . .
C76 Si24 C77 107.4(9) . .
C76 Si24 C78 110.1(9) . .
C77 Si24 C78 108.8(8) . .
C76 Si24 Si21 112.3(6) . .
C77 Si24 Si21 110.3(6) . .
C78 Si24 Si21 108.0(6) . .
C41 C40 Sn2 114.8(11) . .
C41 C40 H40A 108.6 . .
Sn2 C40 H40A 108.6 . .
C41 C40 H40B 108.6 . .
Sn2 C40 H40B 108.6 . .
H40A C40 H40B 107.5 . .
C40 C41 C42 116.5(15) . .
C40 C41 H41A 108.2 . .
C42 C41 H41A 108.2 . .
C40 C41 H41B 108.2 . .
C42 C41 H41B 108.2 . .
H41A C41 H41B 107.3 . .
C43 C42 C41 110.6(16) . .
C43 C42 H42A 109.5 . .
C41 C42 H42A 109.5 . .
C43 C42 H42B 109.5 . .
C41 C42 H42B 109.5 . .
H42A C42 H42B 108.1 . .
C42 C43 H43A 109.5 . .
C42 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
C42 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
C45 C44 Sn2 114.8(12) . .
C45 C44 H44A 108.6 . .
Sn2 C44 H44A 108.6 . .
C45 C44 H44B 108.6 . .
Sn2 C44 H44B 108.6 . .
H44A C44 H44B 107.5 . .
C46 C45 C44 117.4(15) . .
C46 C45 H45A 108.0 . .
C44 C45 H45A 108.0 . .
C46 C45 H45B 108.0 . .
C44 C45 H45B 108.0 . .
H45A C45 H45B 107.2 . .
C45 C46 C47 113.4(16) . .
C45 C46 H46A 108.9 . .
C47 C46 H46A 108.9 . .
C45 C46 H46B 108.9 . .
C47 C46 H46B 108.9 . .
H46A C46 H46B 107.7 . .
C46 C47 H47A 109.5 . .
C46 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C46 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C49 C48 Sn2 118.0(11) . .
C49 C48 H48A 121.0 . .
Sn2 C48 H48A 121.0 . .
C49 C48 H48B 89.1 . .
Sn2 C48 H48B 89.2 . .
H48A C48 H48B 91.6 . .
C48 C49 C50 114.3(13) . .
C48 C49 H49A 108.7 . .
C50 C49 H49A 108.7 . .
C48 C49 H49B 108.7 . .
C50 C49 H49B 108.7 . .
H49A C49 H49B 107.6 . .
C51 C50 C49 114.1(14) . .
C51 C50 H50A 108.7 . .
C49 C50 H50A 108.7 . .
C51 C50 H50B 108.7 . .
C49 C50 H50B 108.7 . .
H50A C50 H50B 107.6 . .
C50 C51 H51A 109.5 . .
C50 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
C50 C51 H51C 109.5 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
Si15 C52 H52A 109.5 . .
Si15 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
Si15 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
Si15 C53 H53A 109.5 . .
Si15 C53 H53B 109.5 . .
H53A C53 H53B 109.5 . .
Si15 C53 H53C 109.5 . .
H53A C53 H53C 109.5 . .
H53B C53 H53C 109.5 . .
Si15 C54 H54A 109.5 . .
Si15 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
Si15 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
Si14 C55 H55A 109.5 . .
Si14 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
Si14 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
Si14 C56 H56A 109.5 . .
Si14 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
Si14 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
Si14 C57 H57A 109.5 . .
Si14 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
Si14 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
Si16 C58 H58A 109.5 . .
Si16 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
Si16 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
Si16 C59 H59A 109.5 . .
Si16 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
Si16 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
Si16 C60 H60A 109.5 . .
Si16 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
Si16 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
Si18 C61 H61A 109.5 . .
Si18 C61 H61B 109.5 . .
H61A C61 H61B 109.5 . .
Si18 C61 H61C 109.5 . .
H61A C61 H61C 109.5 . .
H61B C61 H61C 109.5 . .
Si18 C62 H62A 109.5 . .
Si18 C62 H62B 109.5 . .
H62A C62 H62B 109.5 . .
Si18 C62 H62C 109.5 . .
H62A C62 H62C 109.5 . .
H62B C62 H62C 109.5 . .
Si18 C63 H63A 109.5 . .
Si18 C63 H63B 109.5 . .
H63A C63 H63B 109.5 . .
Si18 C63 H63C 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
Si19 C64 H64A 109.5 . .
Si19 C64 H64B 109.5 . .
H64A C64 H64B 109.5 . .
Si19 C64 H64C 109.5 . .
H64A C64 H64C 109.5 . .
H64B C64 H64C 109.5 . .
Si19 C65 H65A 109.5 . .
Si19 C65 H65B 109.5 . .
H65A C65 H65B 109.5 . .
Si19 C65 H65C 109.5 . .
H65A C65 H65C 109.5 . .
H65B C65 H65C 109.5 . .
Si19 C66 H66A 109.5 . .
Si19 C66 H66B 109.5 . .
H66A C66 H66B 109.5 . .
Si19 C66 H66C 109.5 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
Si20 C67 H67A 109.5 . .
Si20 C67 H67B 109.5 . .
H67A C67 H67B 109.5 . .
Si20 C67 H67C 109.5 . .
H67A C67 H67C 109.5 . .
H67B C67 H67C 109.5 . .
Si20 C68 H68A 109.5 . .
Si20 C68 H68B 109.5 . .
H68A C68 H68B 109.5 . .
Si20 C68 H68C 109.5 . .
H68A C68 H68C 109.5 . .
H68B C68 H68C 109.5 . .
Si20 C69 H69A 109.5 . .
Si20 C69 H69B 109.5 . .
H69A C69 H69B 109.5 . .
Si20 C69 H69C 109.5 . .
H69A C69 H69C 109.5 . .
H69B C69 H69C 109.5 . .
Si22 C70 H70A 109.5 . .
Si22 C70 H70B 109.5 . .
H70A C70 H70B 109.5 . .
Si22 C70 H70C 109.5 . .
H70A C70 H70C 109.5 . .
H70B C70 H70C 109.5 . .
Si22 C71 H71A 109.5 . .
Si22 C71 H71B 109.5 . .
H71A C71 H71B 109.5 . .
Si22 C71 H71C 109.5 . .
H71A C71 H71C 109.5 . .
H71B C71 H71C 109.5 . .
Si22 C72 H72A 109.5 . .
Si22 C72 H72B 109.5 . .
H72A C72 H72B 109.5 . .
Si22 C72 H72C 109.5 . .
H72A C72 H72C 109.5 . .
H72B C72 H72C 109.5 . .
Si23 C73 H73A 109.5 . .
Si23 C73 H73B 109.5 . .
H73A C73 H73B 109.5 . .
Si23 C73 H73C 109.5 . .
H73A C73 H73C 109.5 . .
H73B C73 H73C 109.5 . .
Si23 C74 H74A 109.5 . .
Si23 C74 H74B 109.5 . .
H74A C74 H74B 109.5 . .
Si23 C74 H74C 109.5 . .
H74A C74 H74C 109.5 . .
H74B C74 H74C 109.5 . .
Si23 C75 H75A 109.5 . .
Si23 C75 H75B 109.5 . .
H75A C75 H75B 109.5 . .
Si23 C75 H75C 109.5 . .
H75A C75 H75C 109.5 . .
H75B C75 H75C 109.5 . .
Si24 C76 H76A 109.5 . .
Si24 C76 H76B 109.5 . .
H76A C76 H76B 109.5 . .
Si24 C76 H76C 109.5 . .
H76A C76 H76C 109.5 . .
H76B C76 H76C 109.5 . .
Si24 C77 H77A 109.5 . .
Si24 C77 H77B 109.5 . .
H77A C77 H77B 109.5 . .
Si24 C77 H77C 109.5 . .
H77A C77 H77C 109.5 . .
H77B C77 H77C 109.5 . .
Si24 C78 H78A 109.5 . .
Si24 C78 H78B 109.5 . .
H78A C78 H78B 109.5 . .
Si24 C78 H78C 109.5 . .
H78A C78 H78C 109.5 . .
H78B C78 H78C 109.5 . .
C79 Sn3 C79 104.8(5) 3_675 2_765
C79 Sn3 C79 104.8(5) 3_675 .
C79 Sn3 C79 104.8(5) 2_765 .
C79 Sn3 Ge19 138.7(4) 3_675 .
C79 Sn3 Ge19 111.3(5) 2_765 .
C79 Sn3 Ge19 85.0(4) . .
C79 Sn3 Ge19 111.3(5) 3_675 2_765
C79 Sn3 Ge19 85.0(4) 2_765 2_765
C79 Sn3 Ge19 138.7(4) . 2_765
Ge19 Sn3 Ge19 54.63(6) . 2_765
C79 Sn3 Ge19 85.0(4) 3_675 3_675
C79 Sn3 Ge19 138.7(4) 2_765 3_675
C79 Sn3 Ge19 111.3(5) . 3_675
Ge19 Sn3 Ge19 54.63(6) . 3_675
Ge19 Sn3 Ge19 54.63(6) 2_765 3_675
Ge20 Ge19 Ge20 95.08(9) 2_765 .
Ge20 Ge19 Ge19 55.35(7) 2_765 2_765
Ge20 Ge19 Ge19 99.44(6) . 2_765
Ge20 Ge19 Ge19 99.73(6) 2_765 3_675
Ge20 Ge19 Ge19 54.96(7) . 3_675
Ge19 Ge19 Ge19 60.004(1) 2_765 3_675
Ge20 Ge19 Sn3 114.59(8) 2_765 .
Ge20 Ge19 Sn3 114.23(7) . .
Ge19 Ge19 Sn3 62.69(3) 2_765 .
Ge19 Ge19 Sn3 62.69(3) 3_675 .
Si25 Ge20 Ge19 118.37(14) . 3_675
Si25 Ge20 Ge19 121.70(14) . .
Ge19 Ge20 Ge19 69.68(10) 3_675 .
Si25 Ge20 Ge21 121.71(14) . 3_675
Ge19 Ge20 Ge21 81.51(7) 3_675 3_675
Ge19 Ge20 Ge21 116.59(8) . 3_675
Si25 Ge20 Ge21 124.68(14) . .
Ge19 Ge20 Ge21 116.80(8) 3_675 .
Ge19 Ge20 Ge21 81.27(7) . .
Ge21 Ge20 Ge21 63.23(8) 3_675 .
Ge20 Ge21 Ge20 91.70(9) 2_765 .
Ge20 Ge21 Ge21 58.40(6) 2_765 2_765
Ge20 Ge21 Ge21 101.13(6) . 2_765
Ge20 Ge21 Ge21 101.15(6) 2_765 3_675
Ge20 Ge21 Ge21 58.37(7) . 3_675
Ge21 Ge21 Ge21 59.997(1) 2_765 3_675
Si26 Si25 Si28 109.8(3) . .
Si26 Si25 Si27 109.9(3) . .
Si28 Si25 Si27 114.3(4) . .
Si26 Si25 Ge20 110.7(2) . .
Si28 Si25 Ge20 109.1(3) . .
Si27 Si25 Ge20 102.8(2) . .
C84 Si26 C83 108.2(12) . .
C84 Si26 C85 110.8(12) . .
C83 Si26 C85 108.5(10) . .
C84 Si26 Si25 107.5(9) . .
C83 Si26 Si25 111.9(6) . .
C85 Si26 Si25 109.9(8) . .
C88 Si27 C87 107.6(10) . .
C88 Si27 C86 111.4(12) . .
C87 Si27 C86 110.5(11) . .
C88 Si27 Si25 110.6(9) . .
C87 Si27 Si25 110.6(8) . .
C86 Si27 Si25 106.3(8) . .
C90 Si28 C89 106.6(16) . .
C90 Si28 C91 110.8(14) . .
C89 Si28 C91 115.1(15) . .
C90 Si28 Si25 106.7(11) . .
C89 Si28 Si25 110.0(10) . .
C91 Si28 Si25 107.3(10) . .
C80 C79 Sn3 114.2(11) . .
C80 C79 H79A 108.7 . .
Sn3 C79 H79A 108.7 . .
C80 C79 H79B 108.7 . .
Sn3 C79 H79B 108.7 . .
H79A C79 H79B 107.6 . .
C81 C80 C79 114.7(15) . .
C81 C80 H80A 108.6 . .
C79 C80 H80A 108.6 . .
C81 C80 H80B 108.6 . .
C79 C80 H80B 108.6 . .
H80A C80 H80B 107.6 . .
C82 C81 C80 114.6(16) . .
C82 C81 H81A 108.6 . .
C80 C81 H81A 108.6 . .
C82 C81 H81B 108.6 . .
C80 C81 H81B 108.6 . .
H81A C81 H81B 107.6 . .
C81 C82 H82A 109.5 . .
C81 C82 H82B 109.5 . .
H82A C82 H82B 109.5 . .
C81 C82 H82C 109.5 . .
H82A C82 H82C 109.5 . .
H82B C82 H82C 109.5 . .
Si26 C83 H83A 109.5 . .
Si26 C83 H83B 109.5 . .
H83A C83 H83B 109.5 . .
Si26 C83 H83C 109.5 . .
H83A C83 H83C 109.5 . .
H83B C83 H83C 109.5 . .
Si26 C84 H84A 109.5 . .
Si26 C84 H84B 109.5 . .
H84A C84 H84B 109.5 . .
Si26 C84 H84C 109.5 . .
H84A C84 H84C 109.5 . .
H84B C84 H84C 109.5 . .
Si26 C85 H85A 109.5 . .
Si26 C85 H85B 109.5 . .
H85A C85 H85B 109.5 . .
Si26 C85 H85C 109.5 . .
H85A C85 H85C 109.5 . .
H85B C85 H85C 109.5 . .
Si27 C86 H86A 109.5 . .
Si27 C86 H86B 109.5 . .
H86A C86 H86B 109.5 . .
Si27 C86 H86C 109.5 . .
H86A C86 H86C 109.5 . .
H86B C86 H86C 109.5 . .
Si27 C87 H87A 109.5 . .
Si27 C87 H87B 109.5 . .
H87A C87 H87B 109.5 . .
Si27 C87 H87C 109.5 . .
H87A C87 H87C 109.5 . .
H87B C87 H87C 109.5 . .
Si27 C88 H88A 109.5 . .
Si27 C88 H88B 109.5 . .
H88A C88 H88B 109.5 . .
Si27 C88 H88C 109.5 . .
H88A C88 H88C 109.5 . .
H88B C88 H88C 109.5 . .
Si28 C89 H89A 109.5 . .
Si28 C89 H89B 109.5 . .
H89A C89 H89B 109.5 . .
Si28 C89 H89C 109.5 . .
H89A C89 H89C 109.5 . .
H89B C89 H89C 109.5 . .
Si28 C90 H90A 109.5 . .
Si28 C90 H90B 109.5 . .
H90A C90 H90B 109.5 . .
Si28 C90 H90C 109.5 . .
H90A C90 H90C 109.5 . .
H90B C90 H90C 109.5 . .
Si28 C91 H91A 109.5 . .
Si28 C91 H91B 109.5 . .
H91A C91 H91B 109.5 . .
Si28 C91 H91C 109.5 . .
H91A C91 H91C 109.5 . .
H91B C91 H91C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 C1 2.165(16) .
Sn1 C5 2.162(15) .
Sn1 C9 2.174(16) .
Sn1 Ge1 2.6843(19) .
Ge1 Ge7 2.480(2) .
Ge1 Ge8 2.483(2) .
Ge1 Ge2 2.671(2) .
Ge1 Ge3 2.673(2) .
Ge2 Ge9 2.504(2) .
Ge2 Ge8 2.580(2) .
Ge2 Ge3 2.871(2) .
Ge3 Ge9 2.509(2) .
Ge3 Ge7 2.576(2) .
Ge4 Ge7 2.563(2) .
Ge4 Ge8 2.564(2) .
Ge4 Ge5 2.663(2) .
Ge4 Ge6 2.672(2) .
Ge5 Ge9 2.527(2) .
Ge5 Ge8 2.571(2) .
Ge5 Ge6 2.820(2) .
Ge6 Ge9 2.522(2) .
Ge6 Ge7 2.567(2) .
Ge7 Si1 2.379(4) .
Ge8 Si5 2.378(4) .
Ge9 Si9 2.373(4) .
Si1 Si3 2.339(6) .
Si1 Si4 2.346(5) .
Si1 Si2 2.364(6) .
Si2 C13 1.874(16) .
Si2 C14 1.867(18) .
Si2 C15 1.885(17) .
Si3 C18 1.859(18) .
Si3 C17 1.874(17) .
Si3 C16 1.861(19) .
Si4 C20 1.839(17) .
Si4 C19 1.840(16) .
Si4 C21 1.854(16) .
Si5 Si6 2.336(6) .
Si5 Si8 2.351(6) .
Si5 Si7 2.358(6) .
Si6 C22 1.830(17) .
Si6 C24 1.84(2) .
Si6 C23 1.87(2) .
Si7 C25 1.867(17) .
Si7 C27 1.863(19) .
Si7 C26 1.869(18) .
Si8 C30 1.846(19) .
Si8 C29 1.84(2) .
Si8 C28 1.864(16) .
Si9 Si10 2.338(6) .
Si9 Si11 2.340(6) .
Si9 Si12 2.365(6) .
Si10 C33 1.84(2) .
Si10 C31 1.86(2) .
Si10 C32 1.881(19) .
Si11 C36 1.82(2) .
Si11 C35 1.83(2) .
Si11 C34 1.842(19) .
Si12 C37 1.846(17) .
Si12 C39 1.865(16) .
Si12 C38 1.873(17) .
C1 C2 1.53(2) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 C3 1.52(2) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 C4 1.50(2) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 C6 1.51(2) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 C7 1.54(2) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C8 1.49(2) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 C10 1.46(2) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.53(2) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C12 1.43(3) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 H35A 0.9800 .
C35 H35B 0.9800 .
C35 H35C 0.9800 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
Sn2 C44 2.119(18) .
Sn2 C48 2.134(15) .
Sn2 C40 2.193(16) .
Sn2 Ge10 2.802(2) .
Ge10 Ge16 2.481(2) .
Ge10 Ge17 2.485(2) .
Ge10 Ge12 2.738(2) .
Ge10 Ge11 2.751(2) .
Ge11 Ge18 2.497(2) .
Ge11 Ge17 2.525(2) .
Ge11 Ge12 2.848(2) .
Ge12 Ge18 2.485(2) .
Ge12 Ge16 2.529(2) .
Ge13 Ge17 2.559(2) .
Ge13 Ge16 2.574(2) .
Ge13 Ge15 2.660(2) .
Ge13 Ge14 2.682(2) .
Ge14 Ge18 2.526(2) .
Ge14 Ge17 2.568(2) .
Ge14 Ge15 2.768(2) .
Ge15 Ge18 2.535(2) .
Ge15 Ge16 2.569(2) .
Ge16 Si13 2.381(4) .
Ge17 Si17 2.379(4) .
Ge18 Si21 2.362(4) .
Si13 Si15 2.345(6) .
Si13 Si14 2.346(5) .
Si13 Si16 2.355(6) .
Si14 C56 1.864(17) .
Si14 C55 1.862(16) .
Si14 C57 1.887(17) .
Si15 C53 1.841(15) .
Si15 C52 1.870(18) .
Si15 C54 1.874(16) .
Si16 C60 1.865(16) .
Si16 C58 1.868(16) .
Si16 C59 1.877(17) .
Si17 Si20 2.348(6) .
Si17 Si18 2.343(6) .
Si17 Si19 2.354(6) .
Si18 C63 1.848(18) .
Si18 C61 1.869(17) .
Si18 C62 1.862(17) .
Si19 C65 1.860(18) .
Si19 C64 1.866(19) .
Si19 C66 1.874(17) .
Si20 C69 1.857(18) .
Si20 C68 1.859(15) .
Si20 C67 1.887(19) .
Si21 Si23 2.334(6) .
Si21 Si24 2.337(6) .
Si21 Si22 2.359(6) .
Si22 C72 1.841(16) .
Si22 C71 1.85(2) .
Si22 C70 1.853(18) .
Si23 C74 1.81(2) .
Si23 C75 1.85(2) .
Si23 C73 1.863(19) .
Si24 C76 1.872(17) .
Si24 C77 1.882(15) .
Si24 C78 1.896(15) .
C40 C41 1.46(2) .
C40 H40A 0.9900 .
C40 H40B 0.9900 .
C41 C42 1.54(2) .
C41 H41A 0.9900 .
C41 H41B 0.9900 .
C42 C43 1.49(2) .
C42 H42A 0.9900 .
C42 H42B 0.9900 .
C43 H43A 0.9800 .
C43 H43B 0.9800 .
C43 H43C 0.9800 .
C44 C45 1.51(2) .
C44 H44A 0.9900 .
C44 H44B 0.9900 .
C45 C46 1.50(2) .
C45 H45A 0.9900 .
C45 H45B 0.9900 .
C46 C47 1.51(3) .
C46 H46A 0.9900 .
C46 H46B 0.9900 .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
C48 C49 1.51(2) .
C48 H48A 0.9500 .
C48 H48B 0.9601 .
C49 C50 1.50(2) .
C49 H49A 0.9900 .
C49 H49B 0.9900 .
C50 C51 1.50(2) .
C50 H50A 0.9900 .
C50 H50B 0.9900 .
C51 H51A 0.9800 .
C51 H51B 0.9800 .
C51 H51C 0.9800 .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C53 H53A 0.9800 .
C53 H53B 0.9800 .
C53 H53C 0.9800 .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C55 H55A 0.9800 .
C55 H55B 0.9800 .
C55 H55C 0.9800 .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
C57 H57A 0.9800 .
C57 H57B 0.9800 .
C57 H57C 0.9800 .
C58 H58A 0.9800 .
C58 H58B 0.9800 .
C58 H58C 0.9800 .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C61 H61A 0.9800 .
C61 H61B 0.9800 .
C61 H61C 0.9800 .
C62 H62A 0.9800 .
C62 H62B 0.9800 .
C62 H62C 0.9800 .
C63 H63A 0.9800 .
C63 H63B 0.9800 .
C63 H63C 0.9800 .
C64 H64A 0.9800 .
C64 H64B 0.9800 .
C64 H64C 0.9800 .
C65 H65A 0.9800 .
C65 H65B 0.9800 .
C65 H65C 0.9800 .
C66 H66A 0.9800 .
C66 H66B 0.9800 .
C66 H66C 0.9800 .
C67 H67A 0.9800 .
C67 H67B 0.9800 .
C67 H67C 0.9800 .
C68 H68A 0.9800 .
C68 H68B 0.9800 .
C68 H68C 0.9800 .
C69 H69A 0.9800 .
C69 H69B 0.9800 .
C69 H69C 0.9800 .
C70 H70A 0.9800 .
C70 H70B 0.9800 .
C70 H70C 0.9800 .
C71 H71A 0.9800 .
C71 H71B 0.9800 .
C71 H71C 0.9800 .
C72 H72A 0.9800 .
C72 H72B 0.9800 .
C72 H72C 0.9800 .
C73 H73A 0.9800 .
C73 H73B 0.9800 .
C73 H73C 0.9800 .
C74 H74A 0.9800 .
C74 H74B 0.9800 .
C74 H74C 0.9800 .
C75 H75A 0.9800 .
C75 H75B 0.9800 .
C75 H75C 0.9800 .
C76 H76A 0.9800 .
C76 H76B 0.9800 .
C76 H76C 0.9800 .
C77 H77A 0.9800 .
C77 H77B 0.9800 .
C77 H77C 0.9800 .
C78 H78A 0.9800 .
C78 H78B 0.9800 .
C78 H78C 0.9800 .
Sn3 C79 2.161(18) 3_675
Sn3 C79 2.161(18) 2_765
Sn3 C79 2.161(18) .
Sn3 Ge19 3.091(2) .
Sn3 Ge19 3.092(2) 2_765
Sn3 Ge19 3.092(2) 3_675
Ge19 Ge20 2.477(2) 2_765
Ge19 Ge20 2.489(2) .
Ge19 Ge19 2.837(3) 2_765
Ge19 Ge19 2.837(3) 3_675
Ge20 Si25 2.360(5) .
Ge20 Ge19 2.477(2) 3_675
Ge20 Ge21 2.553(2) 3_675
Ge20 Ge21 2.553(2) .
Ge21 Ge20 2.553(2) 2_765
Ge21 Ge21 2.677(3) 2_765
Ge21 Ge21 2.677(3) 3_675
Si25 Si26 2.340(7) .
Si25 Si28 2.357(9) .
Si25 Si27 2.356(8) .
Si26 C84 1.85(2) .
Si26 C83 1.88(2) .
Si26 C85 1.88(2) .
Si27 C88 1.83(2) .
Si27 C87 1.88(2) .
Si27 C86 1.91(3) .
Si28 C90 1.86(3) .
Si28 C89 1.87(3) .
Si28 C91 1.88(3) .
C79 C80 1.51(2) .
C79 H79A 0.9900 .
C79 H79B 0.9900 .
C80 C81 1.51(2) .
C80 H80A 0.9900 .
C80 H80B 0.9900 .
C81 C82 1.48(2) .
C81 H81A 0.9900 .
C81 H81B 0.9900 .
C82 H82A 0.9800 .
C82 H82B 0.9800 .
C82 H82C 0.9800 .
C83 H83A 0.9800 .
C83 H83B 0.9800 .
C83 H83C 0.9800 .
C84 H84A 0.9800 .
C84 H84B 0.9800 .
C84 H84C 0.9800 .
C85 H85A 0.9800 .
C85 H85B 0.9800 .
C85 H85C 0.9800 .
C86 H86A 0.9800 .
C86 H86B 0.9800 .
C86 H86C 0.9800 .
C87 H87A 0.9800 .
C87 H87B 0.9800 .
C87 H87C 0.9800 .
C88 H88A 0.9800 .
C88 H88B 0.9800 .
C88 H88C 0.9800 .
C89 H89A 0.9800 .
C89 H89B 0.9800 .
C89 H89C 0.9800 .
C90 H90A 0.9800 .
C90 H90B 0.9800 .
C90 H90C 0.9800 .
C91 H91A 0.9800 .
C91 H91B 0.9800 .
C91 H91C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C1 Sn1 Ge1 Ge7 89.6(5) . .
C5 Sn1 Ge1 Ge7 -29.1(5) . .
C9 Sn1 Ge1 Ge7 -153.7(5) . .
C1 Sn1 Ge1 Ge8 -122.2(5) . .
C5 Sn1 Ge1 Ge8 119.1(5) . .
C9 Sn1 Ge1 Ge8 -5.5(5) . .
C1 Sn1 Ge1 Ge2 -164.8(5) . .
C5 Sn1 Ge1 Ge2 76.4(5) . .
C9 Sn1 Ge1 Ge2 -48.1(5) . .
C1 Sn1 Ge1 Ge3 130.1(5) . .
C5 Sn1 Ge1 Ge3 11.4(5) . .
C9 Sn1 Ge1 Ge3 -113.1(5) . .
Ge7 Ge1 Ge2 Ge9 13.24(9) . .
Ge8 Ge1 Ge2 Ge9 92.35(7) . .
Ge3 Ge1 Ge2 Ge9 -33.22(6) . .
Sn1 Ge1 Ge2 Ge9 -124.06(7) . .
Ge7 Ge1 Ge2 Ge8 -79.11(7) . .
Ge3 Ge1 Ge2 Ge8 -125.58(7) . .
Sn1 Ge1 Ge2 Ge8 143.59(7) . .
Ge7 Ge1 Ge2 Ge3 46.46(6) . .
Ge8 Ge1 Ge2 Ge3 125.58(7) . .
Sn1 Ge1 Ge2 Ge3 -90.84(6) . .
Ge7 Ge1 Ge3 Ge9 -92.49(7) . .
Ge8 Ge1 Ge3 Ge9 -13.42(9) . .
Ge2 Ge1 Ge3 Ge9 33.13(6) . .
Sn1 Ge1 Ge3 Ge9 118.41(7) . .
Ge8 Ge1 Ge3 Ge7 79.07(7) . .
Ge2 Ge1 Ge3 Ge7 125.62(7) . .
Sn1 Ge1 Ge3 Ge7 -149.10(7) . .
Ge7 Ge1 Ge3 Ge2 -125.62(7) . .
Ge8 Ge1 Ge3 Ge2 -46.55(6) . .
Sn1 Ge1 Ge3 Ge2 85.29(6) . .
Ge8 Ge2 Ge3 Ge9 -96.35(7) . .
Ge1 Ge2 Ge3 Ge9 -139.33(8) . .
Ge9 Ge2 Ge3 Ge7 96.41(7) . .
Ge8 Ge2 Ge3 Ge7 0.06(7) . .
Ge1 Ge2 Ge3 Ge7 -42.92(6) . .
Ge9 Ge2 Ge3 Ge1 139.33(8) . .
Ge8 Ge2 Ge3 Ge1 42.98(6) . .
Ge7 Ge4 Ge5 Ge9 -14.50(8) . .
Ge8 Ge4 Ge5 Ge9 -90.92(7) . .
Ge6 Ge4 Ge5 Ge9 32.10(6) . .
Ge7 Ge4 Ge5 Ge8 76.43(7) . .
Ge6 Ge4 Ge5 Ge8 123.02(6) . .
Ge7 Ge4 Ge5 Ge6 -46.59(6) . .
Ge8 Ge4 Ge5 Ge6 -123.02(6) . .
Ge7 Ge4 Ge6 Ge9 91.31(7) . .
Ge8 Ge4 Ge6 Ge9 14.85(8) . .
Ge5 Ge4 Ge6 Ge9 -32.15(6) . .
Ge8 Ge4 Ge6 Ge7 -76.45(7) . .
Ge5 Ge4 Ge6 Ge7 -123.45(7) . .
Ge7 Ge4 Ge6 Ge5 123.45(7) . .
Ge8 Ge4 Ge6 Ge5 47.00(6) . .
Ge8 Ge5 Ge6 Ge9 95.56(7) . .
Ge4 Ge5 Ge6 Ge9 141.72(7) . .
Ge9 Ge5 Ge6 Ge7 -95.90(7) . .
Ge8 Ge5 Ge6 Ge7 -0.34(7) . .
Ge4 Ge5 Ge6 Ge7 45.82(6) . .
Ge9 Ge5 Ge6 Ge4 -141.72(7) . .
Ge8 Ge5 Ge6 Ge4 -46.16(6) . .
Ge8 Ge1 Ge7 Si1 149.98(14) . .
Ge2 Ge1 Ge7 Si1 -151.76(14) . .
Ge3 Ge1 Ge7 Si1 -102.32(15) . .
Sn1 Ge1 Ge7 Si1 -53.56(19) . .
Ge8 Ge1 Ge7 Ge4 8.56(7) . .
Ge2 Ge1 Ge7 Ge4 66.82(8) . .
Ge3 Ge1 Ge7 Ge4 116.26(7) . .
Sn1 Ge1 Ge7 Ge4 165.02(10) . .
Ge8 Ge1 Ge7 Ge6 -53.07(8) . .
Ge2 Ge1 Ge7 Ge6 5.19(10) . .
Ge3 Ge1 Ge7 Ge6 54.63(7) . .
Sn1 Ge1 Ge7 Ge6 103.39(11) . .
Ge8 Ge1 Ge7 Ge3 -107.70(7) . .
Ge2 Ge1 Ge7 Ge3 -49.44(7) . .
Sn1 Ge1 Ge7 Ge3 48.76(11) . .
Ge8 Ge4 Ge7 Si1 -147.99(14) . .
Ge5 Ge4 Ge7 Si1 155.27(14) . .
Ge6 Ge4 Ge7 Si1 105.51(15) . .
Ge8 Ge4 Ge7 Ge1 -8.32(7) . .
Ge5 Ge4 Ge7 Ge1 -65.07(7) . .
Ge6 Ge4 Ge7 Ge1 -114.82(7) . .
Ge8 Ge4 Ge7 Ge6 106.50(6) . .
Ge5 Ge4 Ge7 Ge6 49.75(6) . .
Ge8 Ge4 Ge7 Ge3 54.20(8) . .
Ge5 Ge4 Ge7 Ge3 -2.54(9) . .
Ge6 Ge4 Ge7 Ge3 -52.30(7) . .
Ge9 Ge6 Ge7 Si1 137.67(13) . .
Ge4 Ge6 Ge7 Si1 -120.23(14) . .
Ge5 Ge6 Ge7 Si1 -165.66(13) . .
Ge9 Ge6 Ge7 Ge1 -20.97(9) . .
Ge4 Ge6 Ge7 Ge1 81.13(8) . .
Ge5 Ge6 Ge7 Ge1 35.70(9) . .
Ge9 Ge6 Ge7 Ge4 -102.10(7) . .
Ge5 Ge6 Ge7 Ge4 -45.43(6) . .
Ge9 Ge6 Ge7 Ge3 29.11(6) . .
Ge4 Ge6 Ge7 Ge3 131.21(7) . .
Ge5 Ge6 Ge7 Ge3 85.79(6) . .
Ge9 Ge3 Ge7 Si1 -142.63(12) . .
Ge1 Ge3 Ge7 Si1 118.30(12) . .
Ge2 Ge3 Ge7 Si1 161.91(12) . .
Ge9 Ge3 Ge7 Ge1 99.07(7) . .
Ge2 Ge3 Ge7 Ge1 43.61(6) . .
Ge9 Ge3 Ge7 Ge4 18.22(9) . .
Ge1 Ge3 Ge7 Ge4 -80.85(8) . .
Ge2 Ge3 Ge7 Ge4 -37.23(8) . .
Ge9 Ge3 Ge7 Ge6 -29.30(6) . .
Ge1 Ge3 Ge7 Ge6 -128.37(7) . .
Ge2 Ge3 Ge7 Ge6 -84.75(6) . .
Ge7 Ge1 Ge8 Si5 -147.46(14) . .
Ge2 Ge1 Ge8 Si5 104.89(15) . .
Ge3 Ge1 Ge8 Si5 154.37(14) . .
Sn1 Ge1 Ge8 Si5 53.61(18) . .
Ge7 Ge1 Ge8 Ge4 -8.56(7) . .
Ge2 Ge1 Ge8 Ge4 -116.21(7) . .
Ge3 Ge1 Ge8 Ge4 -66.73(8) . .
Sn1 Ge1 Ge8 Ge4 -167.48(9) . .
Ge7 Ge1 Ge8 Ge5 52.71(8) . .
Ge2 Ge1 Ge8 Ge5 -54.94(7) . .
Ge3 Ge1 Ge8 Ge5 -5.46(10) . .
Sn1 Ge1 Ge8 Ge5 -106.21(10) . .
Ge7 Ge1 Ge8 Ge2 107.65(7) . .
Ge3 Ge1 Ge8 Ge2 49.48(7) . .
Sn1 Ge1 Ge8 Ge2 -51.27(9) . .
Ge7 Ge4 Ge8 Si5 146.21(14) . .
Ge5 Ge4 Ge8 Si5 -107.17(14) . .
Ge6 Ge4 Ge8 Si5 -157.23(13) . .
Ge7 Ge4 Ge8 Ge1 8.31(7) . .
Ge5 Ge4 Ge8 Ge1 114.93(7) . .
Ge6 Ge4 Ge8 Ge1 64.88(7) . .
Ge7 Ge4 Ge8 Ge5 -106.62(6) . .
Ge6 Ge4 Ge8 Ge5 -50.06(6) . .
Ge7 Ge4 Ge8 Ge2 -54.04(8) . .
Ge5 Ge4 Ge8 Ge2 52.58(7) . .
Ge6 Ge4 Ge8 Ge2 2.52(9) . .
Ge9 Ge5 Ge8 Si5 -139.50(13) . .
Ge4 Ge5 Ge8 Si5 118.09(13) . .
Ge6 Ge5 Ge8 Si5 163.99(13) . .
Ge9 Ge5 Ge8 Ge1 21.55(9) . .
Ge4 Ge5 Ge8 Ge1 -80.86(8) . .
Ge6 Ge5 Ge8 Ge1 -34.96(9) . .
Ge9 Ge5 Ge8 Ge4 102.41(7) . .
Ge6 Ge5 Ge8 Ge4 45.90(6) . .
Ge9 Ge5 Ge8 Ge2 -28.61(6) . .
Ge4 Ge5 Ge8 Ge2 -131.02(7) . .
Ge6 Ge5 Ge8 Ge2 -85.12(6) . .
Ge9 Ge2 Ge8 Si5 143.28(12) . .
Ge1 Ge2 Ge8 Si5 -117.43(13) . .
Ge3 Ge2 Ge8 Si5 -161.10(12) . .
Ge9 Ge2 Ge8 Ge1 -99.28(7) . .
Ge3 Ge2 Ge8 Ge1 -43.66(6) . .
Ge9 Ge2 Ge8 Ge4 -18.56(9) . .
Ge1 Ge2 Ge8 Ge4 80.72(8) . .
Ge3 Ge2 Ge8 Ge4 37.06(8) . .
Ge9 Ge2 Ge8 Ge5 28.93(6) . .
Ge1 Ge2 Ge8 Ge5 128.21(7) . .
Ge3 Ge2 Ge8 Ge5 84.55(6) . .
Ge8 Ge2 Ge9 Si9 -157.80(13) . .
Ge1 Ge2 Ge9 Si9 144.81(13) . .
Ge3 Ge2 Ge9 Si9 110.53(14) . .
Ge8 Ge2 Ge9 Ge3 91.67(7) . .
Ge1 Ge2 Ge9 Ge3 34.28(7) . .
Ge8 Ge2 Ge9 Ge6 28.86(9) . .
Ge1 Ge2 Ge9 Ge6 -28.52(9) . .
Ge3 Ge2 Ge9 Ge6 -62.80(7) . .
Ge8 Ge2 Ge9 Ge5 -29.15(6) . .
Ge1 Ge2 Ge9 Ge5 -86.54(7) . .
Ge3 Ge2 Ge9 Ge5 -120.82(7) . .
Ge7 Ge3 Ge9 Si9 154.84(12) . .
Ge1 Ge3 Ge9 Si9 -147.82(12) . .
Ge2 Ge3 Ge9 Si9 -113.58(13) . .
Ge7 Ge3 Ge9 Ge2 -91.58(7) . .
Ge1 Ge3 Ge9 Ge2 -34.24(7) . .
Ge7 Ge3 Ge9 Ge6 29.55(6) . .
Ge1 Ge3 Ge9 Ge6 86.88(7) . .
Ge2 Ge3 Ge9 Ge6 121.13(7) . .
Ge7 Ge3 Ge9 Ge5 -28.19(9) . .
Ge1 Ge3 Ge9 Ge5 29.14(9) . .
Ge2 Ge3 Ge9 Ge5 63.38(7) . .
Ge7 Ge6 Ge9 Si9 -142.13(15) . .
Ge4 Ge6 Ge9 Si9 158.21(14) . .
Ge5 Ge6 Ge9 Si9 125.31(16) . .
Ge7 Ge6 Ge9 Ge2 30.48(9) . .
Ge4 Ge6 Ge9 Ge2 -29.18(9) . .
Ge5 Ge6 Ge9 Ge2 -62.08(7) . .
Ge7 Ge6 Ge9 Ge3 -29.65(6) . .
Ge4 Ge6 Ge9 Ge3 -89.31(7) . .
Ge5 Ge6 Ge9 Ge3 -122.20(7) . .
Ge7 Ge6 Ge9 Ge5 92.55(7) . .
Ge4 Ge6 Ge9 Ge5 32.90(6) . .
Ge8 Ge5 Ge9 Si9 145.23(15) . .
Ge4 Ge5 Ge9 Si9 -155.09(14) . .
Ge6 Ge5 Ge9 Si9 -122.05(16) . .
Ge8 Ge5 Ge9 Ge2 29.23(6) . .
Ge4 Ge5 Ge9 Ge2 88.91(7) . .
Ge6 Ge5 Ge9 Ge2 121.95(7) . .
Ge8 Ge5 Ge9 Ge3 -31.19(9) . .
Ge4 Ge5 Ge9 Ge3 28.49(9) . .
Ge6 Ge5 Ge9 Ge3 61.52(7) . .
Ge8 Ge5 Ge9 Ge6 -92.72(7) . .
Ge4 Ge5 Ge9 Ge6 -33.04(6) . .
Ge1 Ge7 Si1 Si3 -135.70(17) . .
Ge4 Ge7 Si1 Si3 -7.5(2) . .
Ge6 Ge7 Si1 Si3 68.3(2) . .
Ge3 Ge7 Si1 Si3 150.48(17) . .
Ge1 Ge7 Si1 Si4 -20.1(2) . .
Ge4 Ge7 Si1 Si4 108.16(18) . .
Ge6 Ge7 Si1 Si4 -176.10(15) . .
Ge3 Ge7 Si1 Si4 -93.88(19) . .
Ge1 Ge7 Si1 Si2 103.77(19) . .
Ge4 Ge7 Si1 Si2 -128.00(17) . .
Ge6 Ge7 Si1 Si2 -52.3(2) . .
Ge3 Ge7 Si1 Si2 30.0(2) . .
Si3 Si1 Si2 C13 52.1(8) . .
Si4 Si1 Si2 C13 -72.6(8) . .
Ge7 Si1 Si2 C13 168.3(8) . .
Si3 Si1 Si2 C14 169.7(8) . .
Si4 Si1 Si2 C14 45.0(8) . .
Ge7 Si1 Si2 C14 -74.1(8) . .
Si3 Si1 Si2 C15 -68.9(7) . .
Si4 Si1 Si2 C15 166.3(6) . .
Ge7 Si1 Si2 C15 47.3(7) . .
Si4 Si1 Si3 C18 -175.9(9) . .
Si2 Si1 Si3 C18 56.8(9) . .
Ge7 Si1 Si3 C18 -62.4(9) . .
Si4 Si1 Si3 C17 64.7(7) . .
Si2 Si1 Si3 C17 -62.6(7) . .
Ge7 Si1 Si3 C17 178.2(7) . .
Si4 Si1 Si3 C16 -53.7(7) . .
Si2 Si1 Si3 C16 179.0(7) . .
Ge7 Si1 Si3 C16 59.7(7) . .
Si3 Si1 Si4 C20 -176.0(8) . .
Si2 Si1 Si4 C20 -49.9(8) . .
Ge7 Si1 Si4 C20 71.3(8) . .
Si3 Si1 Si4 C19 65.6(7) . .
Si2 Si1 Si4 C19 -168.3(7) . .
Ge7 Si1 Si4 C19 -47.1(7) . .
Si3 Si1 Si4 C21 -56.1(8) . .
Si2 Si1 Si4 C21 70.0(8) . .
Ge7 Si1 Si4 C21 -168.8(8) . .
Ge1 Ge8 Si5 Si6 -100.2(2) . .
Ge4 Ge8 Si5 Si6 134.09(18) . .
Ge5 Ge8 Si5 Si6 58.6(2) . .
Ge2 Ge8 Si5 Si6 -25.4(2) . .
Ge1 Ge8 Si5 Si8 139.18(17) . .
Ge4 Ge8 Si5 Si8 13.5(2) . .
Ge5 Ge8 Si5 Si8 -62.0(2) . .
Ge2 Ge8 Si5 Si8 -146.02(17) . .
Ge1 Ge8 Si5 Si7 24.8(2) . .
Ge4 Ge8 Si5 Si7 -100.85(19) . .
Ge5 Ge8 Si5 Si7 -176.34(15) . .
Ge2 Ge8 Si5 Si7 99.64(19) . .
Si8 Si5 Si6 C22 -64.5(7) . .
Si7 Si5 Si6 C22 57.2(7) . .
Ge8 Si5 Si6 C22 177.9(6) . .
Si8 Si5 Si6 C24 176.8(9) . .
Si7 Si5 Si6 C24 -61.5(9) . .
Ge8 Si5 Si6 C24 59.2(9) . .
Si8 Si5 Si6 C23 55.2(10) . .
Si7 Si5 Si6 C23 176.9(9) . .
Ge8 Si5 Si6 C23 -62.4(10) . .
Si6 Si5 Si7 C25 -81.8(7) . .
Si8 Si5 Si7 C25 42.1(7) . .
Ge8 Si5 Si7 C25 155.8(7) . .
Si6 Si5 Si7 C27 158.7(6) . .
Si8 Si5 Si7 C27 -77.4(7) . .
Ge8 Si5 Si7 C27 36.2(6) . .
Si6 Si5 Si7 C26 39.0(8) . .
Si8 Si5 Si7 C26 162.8(7) . .
Ge8 Si5 Si7 C26 -83.5(7) . .
Si6 Si5 Si8 C30 -69.1(8) . .
Si7 Si5 Si8 C30 165.0(7) . .
Ge8 Si5 Si8 C30 50.9(7) . .
Si6 Si5 Si8 C29 170.1(7) . .
Si7 Si5 Si8 C29 44.2(8) . .
Ge8 Si5 Si8 C29 -70.0(7) . .
Si6 Si5 Si8 C28 51.3(8) . .
Si7 Si5 Si8 C28 -74.6(8) . .
Ge8 Si5 Si8 C28 171.2(8) . .
Ge2 Ge9 Si9 Si10 113.3(2) . .
Ge3 Ge9 Si9 Si10 -165.58(18) . .
Ge6 Ge9 Si9 Si10 -74.5(2) . .
Ge5 Ge9 Si9 Si10 18.1(3) . .
Ge2 Ge9 Si9 Si11 -126.89(19) . .
Ge3 Ge9 Si9 Si11 -45.8(2) . .
Ge6 Ge9 Si9 Si11 45.2(3) . .
Ge5 Ge9 Si9 Si11 137.92(19) . .
Ge2 Ge9 Si9 Si12 -6.7(2) . .
Ge3 Ge9 Si9 Si12 74.3(2) . .
Ge6 Ge9 Si9 Si12 165.39(15) . .
Ge5 Ge9 Si9 Si12 -101.9(2) . .
Si11 Si9 Si10 C33 62.6(11) . .
Si12 Si9 Si10 C33 -63.1(11) . .
Ge9 Si9 Si10 C33 -179.7(11) . .
Si11 Si9 Si10 C31 -178.1(7) . .
Si12 Si9 Si10 C31 56.2(7) . .
Ge9 Si9 Si10 C31 -60.4(7) . .
Si11 Si9 Si10 C32 -59.5(9) . .
Si12 Si9 Si10 C32 174.8(8) . .
Ge9 Si9 Si10 C32 58.2(8) . .
Si10 Si9 Si11 C36 -59.6(10) . .
Si12 Si9 Si11 C36 66.6(10) . .
Ge9 Si9 Si11 C36 -176.1(10) . .
Si10 Si9 Si11 C35 -178.7(11) . .
Si12 Si9 Si11 C35 -52.4(11) . .
Ge9 Si9 Si11 C35 64.9(11) . .
Si10 Si9 Si11 C34 58.6(8) . .
Si12 Si9 Si11 C34 -175.2(8) . .
Ge9 Si9 Si11 C34 -57.8(8) . .
Si10 Si9 Si12 C37 -53.4(7) . .
Si11 Si9 Si12 C37 -179.1(7) . .
Ge9 Si9 Si12 C37 62.8(7) . .
Si10 Si9 Si12 C39 -174.6(7) . .
Si11 Si9 Si12 C39 59.6(8) . .
Ge9 Si9 Si12 C39 -58.5(8) . .
Si10 Si9 Si12 C38 66.6(8) . .
Si11 Si9 Si12 C38 -59.2(8) . .
Ge9 Si9 Si12 C38 -177.3(8) . .
C5 Sn1 C1 C2 167.1(12) . .
C9 Sn1 C1 C2 -79.2(13) . .
Ge1 Sn1 C1 C2 41.5(13) . .
Sn1 C1 C2 C3 -178.2(12) . .
C1 C2 C3 C4 179.8(15) . .
C1 Sn1 C5 C6 -53.3(12) . .
C9 Sn1 C5 C6 -167.4(11) . .
Ge1 Sn1 C5 C6 64.8(12) . .
Sn1 C5 C6 C7 -173.2(10) . .
C5 C6 C7 C8 -65.2(18) . .
C1 Sn1 C9 C10 -148.7(13) . .
C5 Sn1 C9 C10 -35.0(14) . .
Ge1 Sn1 C9 C10 95.4(13) . .
Sn1 C9 C10 C11 175.9(12) . .
C9 C10 C11 C12 154(2) . .
C44 Sn2 Ge10 Ge16 137.9(5) . .
C48 Sn2 Ge10 Ge16 30.1(5) . .
C40 Sn2 Ge10 Ge16 -109.6(5) . .
C44 Sn2 Ge10 Ge17 -100.0(5) . .
C48 Sn2 Ge10 Ge17 152.2(5) . .
C40 Sn2 Ge10 Ge17 12.4(5) . .
C44 Sn2 Ge10 Ge12 167.1(5) . .
C48 Sn2 Ge10 Ge12 59.3(5) . .
C40 Sn2 Ge10 Ge12 -80.5(5) . .
C44 Sn2 Ge10 Ge11 -127.8(5) . .
C48 Sn2 Ge10 Ge11 124.4(5) . .
C40 Sn2 Ge10 Ge11 -15.4(5) . .
Ge16 Ge10 Ge11 Ge18 8.29(9) . .
Ge17 Ge10 Ge11 Ge18 92.07(8) . .
Ge12 Ge10 Ge11 Ge18 -35.74(7) . .
Sn2 Ge10 Ge11 Ge18 -114.27(7) . .
Ge16 Ge10 Ge11 Ge17 -83.78(8) . .
Ge12 Ge10 Ge11 Ge17 -127.81(7) . .
Sn2 Ge10 Ge11 Ge17 153.66(7) . .
Ge16 Ge10 Ge11 Ge12 44.02(7) . .
Ge17 Ge10 Ge11 Ge12 127.81(7) . .
Sn2 Ge10 Ge11 Ge12 -78.53(6) . .
Ge16 Ge10 Ge12 Ge18 -90.28(8) . .
Ge17 Ge10 Ge12 Ge18 -6.86(9) . .
Ge11 Ge10 Ge12 Ge18 36.04(7) . .
Sn2 Ge10 Ge12 Ge18 118.23(7) . .
Ge17 Ge10 Ge12 Ge16 83.43(8) . .
Ge11 Ge10 Ge12 Ge16 126.33(7) . .
Sn2 Ge10 Ge12 Ge16 -151.48(7) . .
Ge16 Ge10 Ge12 Ge11 -126.33(7) . .
Ge17 Ge10 Ge12 Ge11 -42.90(7) . .
Sn2 Ge10 Ge12 Ge11 82.19(6) . .
Ge17 Ge11 Ge12 Ge18 -94.19(8) . .
Ge10 Ge11 Ge12 Ge18 -135.63(8) . .
Ge18 Ge11 Ge12 Ge16 93.24(8) . .
Ge17 Ge11 Ge12 Ge16 -0.95(8) . .
Ge10 Ge11 Ge12 Ge16 -42.39(6) . .
Ge18 Ge11 Ge12 Ge10 135.63(8) . .
Ge17 Ge11 Ge12 Ge10 41.43(6) . .
Ge17 Ge13 Ge14 Ge18 -89.24(7) . .
Ge16 Ge13 Ge14 Ge18 -9.16(8) . .
Ge15 Ge13 Ge14 Ge18 36.88(6) . .
Ge16 Ge13 Ge14 Ge17 80.08(7) . .
Ge15 Ge13 Ge14 Ge17 126.12(7) . .
Ge17 Ge13 Ge14 Ge15 -126.12(7) . .
Ge16 Ge13 Ge14 Ge15 -46.04(6) . .
Ge17 Ge13 Ge15 Ge18 8.00(8) . .
Ge16 Ge13 Ge15 Ge18 87.38(7) . .
Ge14 Ge13 Ge15 Ge18 -36.80(6) . .
Ge17 Ge13 Ge15 Ge16 -79.39(7) . .
Ge14 Ge13 Ge15 Ge16 -124.19(7) . .
Ge17 Ge13 Ge15 Ge14 44.80(6) . .
Ge16 Ge13 Ge15 Ge14 124.19(7) . .
Ge17 Ge14 Ge15 Ge18 91.78(8) . .
Ge13 Ge14 Ge15 Ge18 135.82(8) . .
Ge18 Ge14 Ge15 Ge16 -90.03(8) . .
Ge17 Ge14 Ge15 Ge16 1.75(8) . .
Ge13 Ge14 Ge15 Ge16 45.78(6) . .
Ge18 Ge14 Ge15 Ge13 -135.82(8) . .
Ge17 Ge14 Ge15 Ge13 -44.04(6) . .
Ge17 Ge10 Ge16 Si13 151.96(14) . .
Ge12 Ge10 Ge16 Si13 -104.33(15) . .
Ge11 Ge10 Ge16 Si13 -151.15(14) . .
Sn2 Ge10 Ge16 Si13 -70.80(17) . .
Ge17 Ge10 Ge16 Ge12 -103.71(7) . .
Ge11 Ge10 Ge16 Ge12 -46.82(7) . .
Sn2 Ge10 Ge16 Ge12 33.53(9) . .
Ge17 Ge10 Ge16 Ge15 -42.59(10) . .
Ge12 Ge10 Ge16 Ge15 61.12(8) . .
Ge11 Ge10 Ge16 Ge15 14.30(10) . .
Sn2 Ge10 Ge16 Ge15 94.65(10) . .
Ge17 Ge10 Ge16 Ge13 15.46(7) . .
Ge12 Ge10 Ge16 Ge13 119.16(7) . .
Ge11 Ge10 Ge16 Ge13 72.34(7) . .
Sn2 Ge10 Ge16 Ge13 152.69(8) . .
Ge18 Ge12 Ge16 Si13 -141.67(12) . .
Ge10 Ge12 Ge16 Si13 118.36(13) . .
Ge11 Ge12 Ge16 Si13 162.50(12) . .
Ge18 Ge12 Ge16 Ge10 99.97(8) . .
Ge11 Ge12 Ge16 Ge10 44.15(6) . .
Ge18 Ge12 Ge16 Ge15 -26.34(7) . .
Ge10 Ge12 Ge16 Ge15 -126.31(7) . .
Ge11 Ge12 Ge16 Ge15 -82.16(7) . .
Ge18 Ge12 Ge16 Ge13 23.93(10) . .
Ge10 Ge12 Ge16 Ge13 -76.04(8) . .
Ge11 Ge12 Ge16 Ge13 -31.89(9) . .
Ge18 Ge15 Ge16 Si13 136.82(13) . .
Ge13 Ge15 Ge16 Si13 -120.25(13) . .
Ge14 Ge15 Ge16 Si13 -166.18(12) . .
Ge18 Ge15 Ge16 Ge10 -29.56(10) . .
Ge13 Ge15 Ge16 Ge10 73.37(8) . .
Ge14 Ge15 Ge16 Ge10 27.44(10) . .
Ge18 Ge15 Ge16 Ge12 25.67(7) . .
Ge13 Ge15 Ge16 Ge12 128.60(7) . .
Ge14 Ge15 Ge16 Ge12 82.67(7) . .
Ge18 Ge15 Ge16 Ge13 -102.93(7) . .
Ge14 Ge15 Ge16 Ge13 -45.93(6) . .
Ge17 Ge13 Ge16 Si13 -148.98(14) . .
Ge15 Ge13 Ge16 Si13 105.42(15) . .
Ge14 Ge13 Ge16 Si13 153.67(14) . .
Ge17 Ge13 Ge16 Ge10 -15.02(7) . .
Ge15 Ge13 Ge16 Ge10 -120.62(7) . .
Ge14 Ge13 Ge16 Ge10 -72.37(7) . .
Ge17 Ge13 Ge16 Ge12 47.66(9) . .
Ge15 Ge13 Ge16 Ge12 -57.95(8) . .
Ge14 Ge13 Ge16 Ge12 -9.69(10) . .
Ge17 Ge13 Ge16 Ge15 105.61(7) . .
Ge14 Ge13 Ge16 Ge15 48.25(6) . .
Ge16 Ge10 Ge17 Si17 -149.12(14) . .
Ge12 Ge10 Ge17 Si17 153.73(14) . .
Ge11 Ge10 Ge17 Si17 107.93(15) . .
Sn2 Ge10 Ge17 Si17 75.48(17) . .
Ge16 Ge10 Ge17 Ge11 102.95(8) . .
Ge12 Ge10 Ge17 Ge11 45.80(7) . .
Sn2 Ge10 Ge17 Ge11 -32.45(9) . .
Ge16 Ge10 Ge17 Ge13 -15.55(7) . .
Ge12 Ge10 Ge17 Ge13 -72.70(8) . .
Ge11 Ge10 Ge17 Ge13 -118.50(7) . .
Sn2 Ge10 Ge17 Ge13 -150.95(9) . .
Ge16 Ge10 Ge17 Ge14 43.82(10) . .
Ge12 Ge10 Ge17 Ge14 -13.33(10) . .
Ge11 Ge10 Ge17 Ge14 -59.13(8) . .
Sn2 Ge10 Ge17 Ge14 -91.58(10) . .
Ge18 Ge11 Ge17 Si17 147.08(13) . .
Ge10 Ge11 Ge17 Si17 -114.50(13) . .
Ge12 Ge11 Ge17 Si17 -157.39(12) . .
Ge18 Ge11 Ge17 Ge10 -98.43(7) . .
Ge12 Ge11 Ge17 Ge10 -42.89(6) . .
Ge18 Ge11 Ge17 Ge13 -21.65(10) . .
Ge10 Ge11 Ge17 Ge13 76.78(8) . .
Ge12 Ge11 Ge17 Ge13 33.89(9) . .
Ge18 Ge11 Ge17 Ge14 28.20(7) . .
Ge10 Ge11 Ge17 Ge14 126.63(7) . .
Ge12 Ge11 Ge17 Ge14 83.74(7) . .
Ge16 Ge13 Ge17 Si17 144.28(14) . .
Ge15 Ge13 Ge17 Si17 -158.43(14) . .
Ge14 Ge13 Ge17 Si17 -111.43(15) . .
Ge16 Ge13 Ge17 Ge10 14.99(7) . .
Ge15 Ge13 Ge17 Ge10 72.27(8) . .
Ge14 Ge13 Ge17 Ge10 119.28(8) . .
Ge16 Ge13 Ge17 Ge11 -48.33(9) . .
Ge15 Ge13 Ge17 Ge11 8.95(10) . .
Ge14 Ge13 Ge17 Ge11 55.96(8) . .
Ge16 Ge13 Ge17 Ge14 -104.29(7) . .
Ge15 Ge13 Ge17 Ge14 -47.00(6) . .
Ge18 Ge14 Ge17 Si17 -140.09(14) . .
Ge13 Ge14 Ge17 Si17 118.32(15) . .
Ge15 Ge14 Ge17 Si17 162.43(14) . .
Ge18 Ge14 Ge17 Ge10 26.84(10) . .
Ge13 Ge14 Ge17 Ge10 -74.76(8) . .
Ge15 Ge14 Ge17 Ge10 -30.65(10) . .
Ge18 Ge14 Ge17 Ge11 -27.73(7) . .
Ge13 Ge14 Ge17 Ge11 -129.32(7) . .
Ge15 Ge14 Ge17 Ge11 -85.21(7) . .
Ge18 Ge14 Ge17 Ge13 101.59(7) . .
Ge15 Ge14 Ge17 Ge13 44.11(6) . .
Ge16 Ge12 Ge18 Si21 156.02(14) . .
Ge10 Ge12 Ge18 Si21 -147.31(14) . .
Ge11 Ge12 Ge18 Si21 -109.51(15) . .
Ge16 Ge12 Ge18 Ge11 -94.47(7) . .
Ge10 Ge12 Ge18 Ge11 -37.80(7) . .
Ge16 Ge12 Ge18 Ge14 -30.73(10) . .
Ge10 Ge12 Ge18 Ge14 25.94(10) . .
Ge11 Ge12 Ge18 Ge14 63.74(8) . .
Ge16 Ge12 Ge18 Ge15 26.57(7) . .
Ge10 Ge12 Ge18 Ge15 83.24(7) . .
Ge11 Ge12 Ge18 Ge15 121.04(7) . .
Ge17 Ge11 Ge18 Si21 -151.89(13) . .
Ge10 Ge11 Ge18 Si21 151.29(13) . .
Ge12 Ge11 Ge18 Si21 113.81(14) . .
Ge17 Ge11 Ge18 Ge12 94.30(7) . .
Ge10 Ge11 Ge18 Ge12 37.48(7) . .
Ge17 Ge11 Ge18 Ge14 -28.54(7) . .
Ge10 Ge11 Ge18 Ge14 -85.36(7) . .
Ge12 Ge11 Ge18 Ge14 -122.84(7) . .
Ge17 Ge11 Ge18 Ge15 27.39(10) . .
Ge10 Ge11 Ge18 Ge15 -29.43(10) . .
Ge12 Ge11 Ge18 Ge15 -66.91(8) . .
Ge17 Ge14 Ge18 Si21 140.73(15) . .
Ge13 Ge14 Ge18 Si21 -160.45(15) . .
Ge15 Ge14 Ge18 Si21 -122.89(16) . .
Ge17 Ge14 Ge18 Ge12 -32.04(9) . .
Ge13 Ge14 Ge18 Ge12 26.78(10) . .
Ge15 Ge14 Ge18 Ge12 64.34(8) . .
Ge17 Ge14 Ge18 Ge11 27.90(7) . .
Ge13 Ge14 Ge18 Ge11 86.72(7) . .
Ge15 Ge14 Ge18 Ge11 124.27(7) . .
Ge17 Ge14 Ge18 Ge15 -96.38(7) . .
Ge13 Ge14 Ge18 Ge15 -37.55(6) . .
Ge16 Ge15 Ge18 Si21 -145.23(15) . .
Ge13 Ge15 Ge18 Si21 155.60(15) . .
Ge14 Ge15 Ge18 Si21 117.60(16) . .
Ge16 Ge15 Ge18 Ge12 -26.01(7) . .
Ge13 Ge15 Ge18 Ge12 -85.19(7) . .
Ge14 Ge15 Ge18 Ge12 -123.19(7) . .
Ge16 Ge15 Ge18 Ge11 35.61(9) . .
Ge13 Ge15 Ge18 Ge11 -23.56(10) . .
Ge14 Ge15 Ge18 Ge11 -61.56(8) . .
Ge16 Ge15 Ge18 Ge14 97.17(7) . .
Ge13 Ge15 Ge18 Ge14 38.00(7) . .
Ge10 Ge16 Si13 Si15 -17.2(2) . .
Ge12 Ge16 Si13 Si15 -94.14(19) . .
Ge15 Ge16 Si13 Si15 177.62(15) . .
Ge13 Ge16 Si13 Si15 102.30(19) . .
Ge10 Ge16 Si13 Si14 -133.43(16) . .
Ge12 Ge16 Si13 Si14 149.62(16) . .
Ge15 Ge16 Si13 Si14 61.4(2) . .
Ge13 Ge16 Si13 Si14 -13.9(2) . .
Ge10 Ge16 Si13 Si16 105.76(19) . .
Ge12 Ge16 Si13 Si16 28.8(2) . .
Ge15 Ge16 Si13 Si16 -59.4(2) . .
Ge13 Ge16 Si13 Si16 -134.75(17) . .
Si15 Si13 Si14 C56 66.8(8) . .
Si16 Si13 Si14 C56 -59.1(8) . .
Ge16 Si13 Si14 C56 -177.1(8) . .
Si15 Si13 Si14 C55 -50.3(6) . .
Si16 Si13 Si14 C55 -176.2(6) . .
Ge16 Si13 Si14 C55 65.9(6) . .
Si15 Si13 Si14 C57 -170.1(7) . .
Si16 Si13 Si14 C57 64.0(8) . .
Ge16 Si13 Si14 C57 -54.0(8) . .
Si14 Si13 Si15 C53 -168.2(7) . .
Si16 Si13 Si15 C53 -42.1(7) . .
Ge16 Si13 Si15 C53 78.5(7) . .
Si14 Si13 Si15 C52 73.4(6) . .
Si16 Si13 Si15 C52 -160.5(6) . .
Ge16 Si13 Si15 C52 -39.8(6) . .
Si14 Si13 Si15 C54 -47.6(7) . .
Si16 Si13 Si15 C54 78.5(7) . .
Ge16 Si13 Si15 C54 -160.8(7) . .
Si15 Si13 Si16 C60 -59.1(6) . .
Si14 Si13 Si16 C60 64.8(6) . .
Ge16 Si13 Si16 C60 -179.8(6) . .
Si15 Si13 Si16 C58 57.2(7) . .
Si14 Si13 Si16 C58 -178.9(6) . .
Ge16 Si13 Si16 C58 -63.5(7) . .
Si15 Si13 Si16 C59 178.7(6) . .
Si14 Si13 Si16 C59 -57.3(7) . .
Ge16 Si13 Si16 C59 58.0(7) . .
Ge10 Ge17 Si17 Si20 -68.6(2) . .
Ge11 Ge17 Si17 Si20 8.9(2) . .
Ge13 Ge17 Si17 Si20 176.21(16) . .
Ge14 Ge17 Si17 Si20 97.6(2) . .
Ge10 Ge17 Si17 Si18 53.7(2) . .
Ge11 Ge17 Si17 Si18 131.25(17) . .
Ge13 Ge17 Si17 Si18 -61.5(2) . .
Ge14 Ge17 Si17 Si18 -140.09(16) . .
Ge10 Ge17 Si17 Si19 172.28(17) . .
Ge11 Ge17 Si17 Si19 -110.22(19) . .
Ge13 Ge17 Si17 Si19 57.1(2) . .
Ge14 Ge17 Si17 Si19 -21.6(2) . .
Si20 Si17 Si18 C63 -54.9(8) . .
Si19 Si17 Si18 C63 68.0(8) . .
Ge17 Si17 Si18 C63 -177.1(7) . .
Si20 Si17 Si18 C61 65.8(8) . .
Si19 Si17 Si18 C61 -171.3(7) . .
Ge17 Si17 Si18 C61 -56.5(8) . .
Si20 Si17 Si18 C62 -175.7(7) . .
Si19 Si17 Si18 C62 -52.8(7) . .
Ge17 Si17 Si18 C62 62.0(7) . .
Si20 Si17 Si19 C65 78.1(8) . .
Si18 Si17 Si19 C65 -46.9(8) . .
Ge17 Si17 Si19 C65 -160.3(8) . .
Si20 Si17 Si19 C64 -42.6(8) . .
Si18 Si17 Si19 C64 -167.6(7) . .
Ge17 Si17 Si19 C64 79.0(7) . .
Si20 Si17 Si19 C66 -163.3(7) . .
Si18 Si17 Si19 C66 71.7(7) . .
Ge17 Si17 Si19 C66 -41.6(7) . .
Si18 Si17 Si20 C69 77.9(8) . .
Si19 Si17 Si20 C69 -46.7(8) . .
Ge17 Si17 Si20 C69 -164.6(8) . .
Si18 Si17 Si20 C68 -41.6(7) . .
Si19 Si17 Si20 C68 -166.2(7) . .
Ge17 Si17 Si20 C68 75.8(7) . .
Si18 Si17 Si20 C67 -162.7(6) . .
Si19 Si17 Si20 C67 72.7(7) . .
Ge17 Si17 Si20 C67 -45.3(7) . .
Ge12 Ge18 Si21 Si23 -120.74(18) . .
Ge11 Ge18 Si21 Si23 158.70(16) . .
Ge14 Ge18 Si21 Si23 66.8(2) . .
Ge15 Ge18 Si21 Si23 -20.4(3) . .
Ge12 Ge18 Si21 Si24 -0.9(2) . .
Ge11 Ge18 Si21 Si24 -81.4(2) . .
Ge14 Ge18 Si21 Si24 -173.31(15) . .
Ge15 Ge18 Si21 Si24 99.4(2) . .
Ge12 Ge18 Si21 Si22 119.74(18) . .
Ge11 Ge18 Si21 Si22 39.2(2) . .
Ge14 Ge18 Si21 Si22 -52.7(2) . .
Ge15 Ge18 Si21 Si22 -139.97(17) . .
Si23 Si21 Si22 C72 64.3(7) . .
Si24 Si21 Si22 C72 -62.1(7) . .
Ge18 Si21 Si22 C72 -179.5(6) . .
Si23 Si21 Si22 C71 -179.4(8) . .
Si24 Si21 Si22 C71 54.3(8) . .
Ge18 Si21 Si22 C71 -63.2(8) . .
Si23 Si21 Si22 C70 -58.2(9) . .
Si24 Si21 Si22 C70 175.4(9) . .
Ge18 Si21 Si22 C70 58.0(9) . .
Si24 Si21 Si23 C74 -45.5(8) . .
Si22 Si21 Si23 C74 -172.5(8) . .
Ge18 Si21 Si23 C74 72.1(8) . .
Si24 Si21 Si23 C75 -163.7(8) . .
Si22 Si21 Si23 C75 69.3(8) . .
Ge18 Si21 Si23 C75 -46.1(8) . .
Si24 Si21 Si23 C73 73.9(7) . .
Si22 Si21 Si23 C73 -53.1(7) . .
Ge18 Si21 Si23 C73 -168.5(7) . .
Si23 Si21 Si24 C76 62.8(8) . .
Si22 Si21 Si24 C76 -170.4(7) . .
Ge18 Si21 Si24 C76 -54.3(8) . .
Si23 Si21 Si24 C77 -177.4(7) . .
Si22 Si21 Si24 C77 -50.7(7) . .
Ge18 Si21 Si24 C77 65.5(7) . .
Si23 Si21 Si24 C78 -58.6(7) . .
Si22 Si21 Si24 C78 68.1(7) . .
Ge18 Si21 Si24 C78 -175.8(6) . .
C44 Sn2 C40 C41 39.2(14) . .
C48 Sn2 C40 C41 150.9(12) . .
Ge10 Sn2 C40 C41 -67.4(14) . .
Sn2 C40 C41 C42 176.7(12) . .
C40 C41 C42 C43 67(2) . .
C48 Sn2 C44 C45 60.5(14) . .
C40 Sn2 C44 C45 175.2(12) . .
Ge10 Sn2 C44 C45 -56.1(13) . .
Sn2 C44 C45 C46 -178.0(13) . .
C44 C45 C46 C47 -170.3(17) . .
C44 Sn2 C48 C49 150.2(12) . .
C40 Sn2 C48 C49 37.6(13) . .
Ge10 Sn2 C48 C49 -108.8(11) . .
Sn2 C48 C49 C50 -172.8(11) . .
C48 C49 C50 C51 -176.0(15) . .
C79 Sn3 Ge19 Ge20 -102.3(7) 3_675 2_765
C79 Sn3 Ge19 Ge20 47.0(5) 2_765 2_765
C79 Sn3 Ge19 Ge20 150.9(5) . 2_765
Ge19 Sn3 Ge19 Ge20 -19.94(7) 2_765 2_765
Ge19 Sn3 Ge19 Ge20 -88.44(6) 3_675 2_765
C79 Sn3 Ge19 Ge20 5.9(7) 3_675 .
C79 Sn3 Ge19 Ge20 155.2(5) 2_765 .
C79 Sn3 Ge19 Ge20 -100.9(5) . .
Ge19 Sn3 Ge19 Ge20 88.28(6) 2_765 .
Ge19 Sn3 Ge19 Ge20 19.78(7) 3_675 .
C79 Sn3 Ge19 Ge19 -82.4(7) 3_675 2_765
C79 Sn3 Ge19 Ge19 66.9(5) 2_765 2_765
C79 Sn3 Ge19 Ge19 170.9(5) . 2_765
Ge19 Sn3 Ge19 Ge19 -68.50(2) 3_675 2_765
C79 Sn3 Ge19 Ge19 -13.9(7) 3_675 3_675
C79 Sn3 Ge19 Ge19 135.4(5) 2_765 3_675
C79 Sn3 Ge19 Ge19 -120.7(5) . 3_675
Ge19 Sn3 Ge19 Ge19 68.50(2) 2_765 3_675
Ge20 Ge19 Ge20 Si25 -150.15(17) 2_765 .
Ge19 Ge19 Ge20 Si25 154.17(16) 2_765 .
Ge19 Ge19 Ge20 Si25 111.52(17) 3_675 .
Sn3 Ge19 Ge20 Si25 89.98(17) . .
Ge20 Ge19 Ge20 Ge19 98.33(8) 2_765 3_675
Ge19 Ge19 Ge20 Ge19 42.65(4) 2_765 3_675
Sn3 Ge19 Ge20 Ge19 -21.55(7) . 3_675
Ge20 Ge19 Ge20 Ge21 29.51(10) 2_765 3_675
Ge19 Ge19 Ge20 Ge21 -26.17(9) 2_765 3_675
Ge19 Ge19 Ge20 Ge21 -68.82(8) 3_675 3_675
Sn3 Ge19 Ge20 Ge21 -90.36(9) . 3_675
Ge20 Ge19 Ge20 Ge21 -24.58(7) 2_765 .
Ge19 Ge19 Ge20 Ge21 -80.26(6) 2_765 .
Ge19 Ge19 Ge20 Ge21 -122.91(7) 3_675 .
Sn3 Ge19 Ge20 Ge21 -144.45(7) . .
Si25 Ge20 Ge21 Ge20 146.42(18) . 2_765
Ge19 Ge20 Ge21 Ge20 -38.17(9) 3_675 2_765
Ge19 Ge20 Ge21 Ge20 23.72(7) . 2_765
Ge21 Ge20 Ge21 Ge20 -102.06(6) 3_675 2_765
Si25 Ge20 Ge21 Ge21 -155.48(16) . 2_765
Ge19 Ge20 Ge21 Ge21 19.92(10) 3_675 2_765
Ge19 Ge20 Ge21 Ge21 81.82(7) . 2_765
Ge21 Ge20 Ge21 Ge21 -43.97(3) 3_675 2_765
Si25 Ge20 Ge21 Ge21 -111.52(17) . 3_675
Ge19 Ge20 Ge21 Ge21 63.89(9) 3_675 3_675
Ge19 Ge20 Ge21 Ge21 125.78(8) . 3_675
Ge19 Ge20 Si25 Si26 74.6(3) 3_675 .
Ge19 Ge20 Si25 Si26 -8.0(3) . .
Ge21 Ge20 Si25 Si26 172.4(2) 3_675 .
Ge21 Ge20 Si25 Si26 -110.1(3) . .
Ge19 Ge20 Si25 Si28 -46.4(3) 3_675 .
Ge19 Ge20 Si25 Si28 -128.9(3) . .
Ge21 Ge20 Si25 Si28 51.4(3) 3_675 .
Ge21 Ge20 Si25 Si28 128.9(3) . .
Ge19 Ge20 Si25 Si27 -168.1(2) 3_675 .
Ge19 Ge20 Si25 Si27 109.4(2) . .
Ge21 Ge20 Si25 Si27 -70.3(3) 3_675 .
Ge21 Ge20 Si25 Si27 7.2(3) . .
Si28 Si25 Si26 C84 -78.9(12) . .
Si27 Si25 Si26 C84 47.8(12) . .
Ge20 Si25 Si26 C84 160.6(11) . .
Si28 Si25 Si26 C83 162.4(7) . .
Si27 Si25 Si26 C83 -71.0(7) . .
Ge20 Si25 Si26 C83 41.9(7) . .
Si28 Si25 Si26 C85 41.8(9) . .
Si27 Si25 Si26 C85 168.4(8) . .
Ge20 Si25 Si26 C85 -78.7(8) . .
Si26 Si25 Si27 C88 -64.6(10) . .
Si28 Si25 Si27 C88 59.5(10) . .
Ge20 Si25 Si27 C88 177.6(9) . .
Si26 Si25 Si27 C87 176.4(8) . .
Si28 Si25 Si27 C87 -59.6(9) . .
Ge20 Si25 Si27 C87 58.5(8) . .
Si26 Si25 Si27 C86 56.4(9) . .
Si28 Si25 Si27 C86 -179.5(8) . .
Ge20 Si25 Si27 C86 -61.4(8) . .
Si26 Si25 Si28 C90 46.9(13) . .
Si27 Si25 Si28 C90 -77.2(12) . .
Ge20 Si25 Si28 C90 168.4(12) . .
Si26 Si25 Si28 C89 -68.3(12) . .
Si27 Si25 Si28 C89 167.6(12) . .
Ge20 Si25 Si28 C89 53.1(12) . .
Si26 Si25 Si28 C91 165.8(10) . .
Si27 Si25 Si28 C91 41.7(11) . .
Ge20 Si25 Si28 C91 -72.8(11) . .
C79 Sn3 C79 C80 155.2(9) 3_675 .
C79 Sn3 C79 C80 45.1(17) 2_765 .
Ge19 Sn3 C79 C80 -65.6(12) . .
Ge19 Sn3 C79 C80 -54.3(15) 2_765 .
Ge19 Sn3 C79 C80 -114.5(12) 3_675 .
Sn3 C79 C80 C81 -174.5(13) . .
C79 C80 C81 C82 -176.6(17) . .
