#------------------------------------------------------------------------------
#$Date: 2016-03-22 21:58:49 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179029 $
#$URL: svn://www.crystallography.net/cod/cif/4/12/27/4122730.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4122730
loop_
_publ_author_name
'Inomata, Koya'
'Watanabe, Takahito'
'Tobita, Hiromi'
_publ_section_title
;
 Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis
 by Chloride Abstraction from N-Heterocyclic Carbene-Stabilized
 Chlorometallogermylenes.
;
_journal_issue                   41
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              14341
_journal_paper_doi               10.1021/ja506018f
_journal_volume                  136
_journal_year                    2014
_chemical_formula_moiety         '(C40 H54 Ge2 N4 O6 W2), 2(C32 H12 B F24)'
_chemical_formula_sum            'C104 H78 B2 F48 Ge2 N4 O6 W2'
_chemical_formula_weight         2926.2
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.179(3)
_cell_angle_beta                 99.600(4)
_cell_angle_gamma                93.475(3)
_cell_formula_units_Z            1
_cell_length_a                   12.7478(12)
_cell_length_b                   14.3085(10)
_cell_length_c                   16.6663(12)
_cell_measurement_reflns_used    55016
_cell_measurement_temperature    140(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      1.34
_cell_volume                     2770.7(4)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        'teXsan Ver.1.11'
_computing_molecular_graphics    'Yadokari-XG 2009'
_computing_publication_material  'Yadokari-XG 2009'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      140(2)
_diffrn_detector_area_resol_mean 10.00
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating-anode X-ray tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0957
_diffrn_reflns_av_sigmaI/netI    0.0852
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            32976
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         1.34
_exptl_absorpt_coefficient_mu    2.742
_exptl_absorpt_correction_T_max  0.7711
_exptl_absorpt_correction_T_min  0.5591
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Higashi, 1999)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.754
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       platelet
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.485
_refine_diff_density_min         -2.035
_refine_diff_density_rms         0.232
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.199
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     752
_refine_ls_number_reflns         12465
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.199
_refine_ls_R_factor_all          0.1062
_refine_ls_R_factor_gt           0.0842
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0863P)²+22.9581P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2026
_refine_ls_wR_factor_ref         0.2149
_reflns_number_gt                10193
_reflns_number_total             12465
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja506018f_si_002.cif
_cod_data_source_block           '[{Cp*(CO)3WGe(MeIMe)}2](BAr4)2_4'
_cod_depositor_comments
'Adding full bibliography for 4122725--4122730.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4122730
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.27760(3) 0.32768(3) 0.48467(2) 0.02743(13) Uani 1 1 d . . .
Ge1 Ge 0.41334(9) 0.48801(8) 0.51259(7) 0.0332(2) Uani 1 1 d . . .
C1 C 0.4226(10) 0.2936(8) 0.5272(7) 0.041(2) Uani 1 1 d . . .
O1 O 0.5005(7) 0.2684(7) 0.5482(6) 0.059(2) Uani 1 1 d . . .
C2 C 0.2473(9) 0.2776(8) 0.5752(8) 0.042(3) Uani 1 1 d . . .
O2 O 0.2231(8) 0.2444(7) 0.6249(6) 0.061(2) Uani 1 1 d . . .
C3 C 0.2217(8) 0.4464(8) 0.5636(6) 0.034(2) Uani 1 1 d . . .
O3 O 0.1803(6) 0.5135(6) 0.6027(5) 0.0448(18) Uani 1 1 d . . .
C4 C 0.2678(10) 0.2251(10) 0.3381(7) 0.051(3) Uani 1 1 d . . .
C5 C 0.2033(8) 0.1728(8) 0.3765(7) 0.040(2) Uani 1 1 d . . .
C6 C 0.1188(10) 0.2317(10) 0.3975(7) 0.047(3) Uani 1 1 d . . .
C7 C 0.1306(12) 0.3163(9) 0.3749(8) 0.055(4) Uani 1 1 d . . .
C8 C 0.2235(12) 0.3107(11) 0.3375(7) 0.060(4) Uani 1 1 d . . .
C9 C 0.3586(13) 0.1810(16) 0.2936(11) 0.104(8) Uani 1 1 d . . .
H1 H 0.3968 0.2322 0.2788 0.156 Uiso 1 1 calc R . .
H2 H 0.3288 0.1221 0.2397 0.156 Uiso 1 1 calc R . .
H3 H 0.4086 0.1604 0.3335 0.156 Uiso 1 1 calc R . .
C10 C 0.2147(14) 0.0707(10) 0.3817(12) 0.083(6) Uani 1 1 d . . .
H4 H 0.1956 0.0182 0.3225 0.124 Uiso 1 1 calc R . .
H5 H 0.1668 0.0582 0.4181 0.124 Uiso 1 1 calc R . .
H6 H 0.2891 0.0695 0.4080 0.124 Uiso 1 1 calc R . .
C11 C 0.0233(11) 0.1998(15) 0.4327(10) 0.085(6) Uani 1 1 d . . .
H7 H -0.0367 0.1638 0.3835 0.128 Uiso 1 1 calc R . .
H8 H 0.0006 0.2602 0.4733 0.128 Uiso 1 1 calc R . .
H9 H 0.0455 0.1554 0.4637 0.128 Uiso 1 1 calc R . .
C12 C 0.0561(19) 0.3933(16) 0.3808(13) 0.155(14) Uani 1 1 d . . .
H10 H 0.0028 0.3718 0.3258 0.232 Uiso 1 1 calc R . .
H11 H 0.0968 0.4583 0.3910 0.232 Uiso 1 1 calc R . .
H12 H 0.0195 0.4006 0.4296 0.232 Uiso 1 1 calc R . .
C13 C 0.263(2) 0.3780(18) 0.2907(11) 0.138(12) Uani 1 1 d . . .
H13 H 0.2197 0.3566 0.2313 0.206 Uiso 1 1 calc R . .
H14 H 0.3386 0.3711 0.2873 0.206 Uiso 1 1 calc R . .
H15 H 0.2567 0.4488 0.3241 0.206 Uiso 1 1 calc R . .
C14 C 0.4189(9) 0.5918(8) 0.6349(7) 0.036(2) Uani 1 1 d . . .
N1 N 0.4520(8) 0.5819(6) 0.7139(5) 0.038(2) Uani 1 1 d . . .
C15 C 0.4245(9) 0.6618(8) 0.7809(6) 0.038(2) Uani 1 1 d . . .
C16 C 0.3757(9) 0.7211(8) 0.7425(7) 0.039(2) Uani 1 1 d . . .
N2 N 0.3742(7) 0.6754(6) 0.6532(6) 0.0369(19) Uani 1 1 d . . .
C17 C 0.5003(10) 0.4974(9) 0.7266(8) 0.044(3) Uani 1 1 d . . .
H16 H 0.5263 0.4583 0.6739 0.067 Uiso 1 1 calc R . .
H17 H 0.4465 0.4538 0.7374 0.067 Uiso 1 1 calc R . .
H18 H 0.5605 0.5231 0.7772 0.067 Uiso 1 1 calc R . .
C18 C 0.4496(12) 0.6720(10) 0.8750(7) 0.052(3) Uani 1 1 d . . .
H19 H 0.4233 0.7328 0.9115 0.078 Uiso 1 1 calc R . .
H20 H 0.5274 0.6773 0.8945 0.078 Uiso 1 1 calc R . .
H21 H 0.4144 0.6124 0.8806 0.078 Uiso 1 1 calc R . .
C19 C 0.3297(12) 0.8150(11) 0.7816(9) 0.061(4) Uani 1 1 d . . .
H22 H 0.3550 0.8426 0.8455 0.092 Uiso 1 1 calc R . .
H23 H 0.2512 0.8007 0.7677 0.092 Uiso 1 1 calc R . .
H24 H 0.3523 0.8645 0.7576 0.092 Uiso 1 1 calc R . .
C20 C 0.3234(12) 0.7122(9) 0.5868(8) 0.051(3) Uani 1 1 d . . .
H25 H 0.3359 0.6697 0.5291 0.076 Uiso 1 1 calc R . .
H26 H 0.3544 0.7822 0.6016 0.076 Uiso 1 1 calc R . .
H27 H 0.2461 0.7093 0.5853 0.076 Uiso 1 1 calc R . .
B1 B 0.2305(9) 0.7744(8) 0.1069(7) 0.029(2) Uani 1 1 d . . .
C21 C 0.2107(8) 0.8497(7) 0.0537(6) 0.0294(19) Uani 1 1 d . . .
C22 C 0.1145(8) 0.8360(7) -0.0070(6) 0.0297(19) Uani 1 1 d . . .
H28 H 0.0603 0.7829 -0.0152 0.036 Uiso 1 1 calc R . .
C23 C 0.0952(8) 0.8966(7) -0.0554(6) 0.031(2) Uani 1 1 d . . .
C24 C 0.1697(9) 0.9764(7) -0.0439(7) 0.038(2) Uani 1 1 d . . .
H29 H 0.1557 1.0190 -0.0759 0.046 Uiso 1 1 calc R . .
C25 C 0.2667(9) 0.9934(7) 0.0158(6) 0.035(2) Uani 1 1 d . . .
C26 C 0.2860(8) 0.9311(7) 0.0636(6) 0.034(2) Uani 1 1 d . . .
H30 H 0.3522 0.9443 0.1040 0.040 Uiso 1 1 calc R . .
C27 C -0.0052(9) 0.8707(8) -0.1251(7) 0.040(2) Uani 1 1 d . . .
F1 F -0.0843(6) 0.8176(6) -0.1119(5) 0.065(2) Uani 1 1 d . . .
F2 F 0.0151(7) 0.8169(6) -0.2048(4) 0.070(2) Uani 1 1 d . . .
F3 F -0.0443(5) 0.9520(5) -0.1324(5) 0.0504(17) Uani 1 1 d . . .
C28 C 0.3467(10) 1.0792(8) 0.0277(8) 0.044(3) Uani 1 1 d . . .
F4 F 0.4338(8) 1.0902(7) 0.0861(7) 0.089(3) Uani 1 1 d . . .
F5 F 0.3786(10) 1.0736(9) -0.0457(6) 0.112(4) Uani 1 1 d . . .
F6 F 0.3120(8) 1.1655(6) 0.0538(10) 0.119(5) Uani 1 1 d . . .
C29 C 0.1953(7) 0.6555(7) 0.0396(6) 0.0272(18) Uani 1 1 d . . .
C30 C 0.1788(8) 0.5788(7) 0.0728(6) 0.031(2) Uani 1 1 d . . .
H31 H 0.1851 0.5966 0.1343 0.037 Uiso 1 1 calc R . .
C31 C 0.1533(8) 0.4772(7) 0.0165(7) 0.033(2) Uani 1 1 d . . .
C32 C 0.1378(8) 0.4475(8) -0.0737(7) 0.032(2) Uani 1 1 d . . .
H32 H 0.1179 0.3785 -0.1115 0.039 Uiso 1 1 calc R . .
C33 C 0.1523(8) 0.5224(8) -0.1068(6) 0.033(2) Uani 1 1 d . . .
C34 C 0.1832(8) 0.6230(7) -0.0506(7) 0.032(2) Uani 1 1 d . . .
H33 H 0.1967 0.6716 -0.0754 0.038 Uiso 1 1 calc R . .
C35 C 0.1471(9) 0.4008(9) 0.0564(8) 0.042(2) Uani 1 1 d . . .
F7 F 0.2455(6) 0.3945(5) 0.0995(5) 0.0507(17) Uani 1 1 d . . .
F8 F 0.0858(6) 0.4206(6) 0.1166(6) 0.059(2) Uani 1 1 d . . .
F9 F 0.1112(8) 0.3072(5) -0.0027(6) 0.074(3) Uani 1 1 d . . .
C36 C 0.1408(10) 0.4968(9) -0.2028(7) 0.046(3) Uani 1 1 d . . .
F10 F 0.2357(7) 0.4961(7) -0.2277(5) 0.066(2) Uani 1 1 d . . .
F11 F 0.0918(9) 0.4029(7) -0.2516(5) 0.083(3) Uani 1 1 d . . .
F12 F 0.0895(10) 0.5571(8) -0.2308(5) 0.099(4) Uani 1 1 d . . .
C37 C 0.3587(8) 0.7874(7) 0.1520(6) 0.0294(19) Uani 1 1 d . . .
C38 C 0.4271(8) 0.7198(7) 0.1158(6) 0.0300(19) Uani 1 1 d . . .
H34 H 0.4002 0.6643 0.0620 0.036 Uiso 1 1 calc R . .
C39 C 0.5356(8) 0.7311(7) 0.1566(7) 0.033(2) Uani 1 1 d . . .
C40 C 0.5787(8) 0.8113(8) 0.2332(7) 0.036(2) Uani 1 1 d . . .
H35 H 0.6522 0.8194 0.2601 0.044 Uiso 1 1 calc R . .
C41 C 0.5108(9) 0.8811(9) 0.2704(7) 0.042(3) Uani 1 1 d . A .
C42 C 0.4051(8) 0.8688(7) 0.2316(7) 0.036(2) Uani 1 1 d . . .
H36 H 0.3610 0.9168 0.2590 0.043 Uiso 1 1 calc R . .
C43 C 0.6073(9) 0.6581(9) 0.1150(7) 0.040(2) Uani 1 1 d . . .
F13 F 0.5627(8) 0.5618(6) 0.0952(8) 0.088(3) Uani 1 1 d . . .
F14 F 0.6982(7) 0.6662(7) 0.1673(6) 0.082(3) Uani 1 1 d . . .
F15 F 0.6257(10) 0.6605(10) 0.0434(7) 0.109(4) Uani 1 1 d . . .
C44 C 0.5582(12) 0.9650(11) 0.3571(9) 0.057(3) Uiso 1 1 d . . .
F16 F 0.579(2) 1.0491(18) 0.3440(15) 0.099(8) Uiso 0.51(2) 1 d P A 1
F17 F 0.645(2) 0.9504(17) 0.3999(15) 0.088(7) Uiso 0.51(2) 1 d P A 1
F18 F 0.4814(12) 0.9908(12) 0.4083(10) 0.053(5) Uiso 0.51(2) 1 d P A 1
F19 F 0.4949(16) 1.0294(16) 0.3866(13) 0.071(6) Uiso 0.49(2) 1 d P A 2
F20 F 0.6420(17) 1.0257(13) 0.3470(11) 0.063(6) Uiso 0.49(2) 1 d P A 2
F21 F 0.6090(14) 0.9316(12) 0.4177(10) 0.049(4) Uiso 0.49(2) 1 d P A 2
C45 C 0.1614(8) 0.7982(7) 0.1848(6) 0.0301(19) Uani 1 1 d . . .
C46 C 0.0655(8) 0.8394(7) 0.1836(6) 0.030(2) Uani 1 1 d . . .
H37 H 0.0397 0.8605 0.1368 0.036 Uiso 1 1 calc R . .
C47 C 0.0054(8) 0.8509(7) 0.2490(7) 0.034(2) Uani 1 1 d . . .
C48 C 0.0372(9) 0.8226(9) 0.3180(7) 0.042(3) Uani 1 1 d . . .
H38 H -0.0044 0.8301 0.3617 0.051 Uiso 1 1 calc R . .
C49 C 0.1339(10) 0.7819(10) 0.3215(7) 0.045(3) Uani 1 1 d . B .
C50 C 0.1932(8) 0.7719(9) 0.2580(7) 0.038(2) Uani 1 1 d . . .
H39 H 0.2596 0.7457 0.2638 0.045 Uiso 1 1 calc R . .
C51 C -0.0952(9) 0.8994(9) 0.2438(8) 0.042(2) Uani 1 1 d . . .
F22 F -0.0778(6) 0.9950(6) 0.2459(6) 0.064(2) Uani 1 1 d . . .
F23 F -0.1643(7) 0.8538(7) 0.1672(6) 0.079(3) Uani 1 1 d . . .
C52 C 0.1731(9) 0.7490(8) 0.3970(8) 0.063(4) Uiso 1 1 d D . .
F24 F 0.0990(13) 0.6910(13) 0.4104(12) 0.066(5) Uiso 0.58(2) 1 d PD B 1
F25 F 0.206(2) 0.8209(15) 0.4742(10) 0.106(8) Uiso 0.58(2) 1 d PD B 1
F26 F 0.2472(11) 0.6868(11) 0.3821(10) 0.067(5) Uiso 0.58(2) 1 d PD B 1
F27 F 0.122(3) 0.6640(19) 0.392(3) 0.123(14) Uiso 0.42(2) 1 d PD B 2
F28 F 0.163(2) 0.8223(15) 0.4717(11) 0.070(7) Uiso 0.42(2) 1 d PD B 2
F29 F 0.2788(11) 0.7722(19) 0.4219(16) 0.086(9) Uiso 0.42(2) 1 d PD B 2
F30 F -0.1471(7) 0.9057(7) 0.3072(6) 0.070(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 W1 C3 79.3(4) . .
C2 W1 C1 78.3(5) . .
C3 W1 C1 119.0(4) . .
C2 W1 C6 87.0(5) . .
C3 W1 C6 100.5(4) . .
C1 W1 C6 133.8(5) . .
C2 W1 C5 90.0(4) . .
C3 W1 C5 135.8(4) . .
C1 W1 C5 100.0(4) . .
C6 W1 C5 35.8(4) . .
C2 W1 C4 124.3(5) . .
C3 W1 C4 143.6(5) . .
C1 W1 C4 94.5(5) . .
C6 W1 C4 58.8(4) . .
C5 W1 C4 36.3(4) . .
C2 W1 C7 116.2(5) . .
C3 W1 C7 87.1(4) . .
C1 W1 C7 152.9(5) . .
C6 W1 C7 35.0(5) . .
C5 W1 C7 59.5(4) . .
C4 W1 C7 58.4(5) . .
C2 W1 C8 144.7(5) . .
C3 W1 C8 110.0(5) . .
C1 W1 C8 120.6(5) . .
C6 W1 C8 58.2(4) . .
C5 W1 C8 59.1(4) . .
C4 W1 C8 34.3(5) . .
C7 W1 C8 35.2(5) . .
C2 W1 Ge1 125.5(3) . .
C3 W1 Ge1 73.4(3) . .
C1 W1 Ge1 75.3(3) . .
C6 W1 Ge1 143.4(3) . .
C5 W1 Ge1 141.0(3) . .
C4 W1 Ge1 104.7(3) . .
C7 W1 Ge1 108.6(4) . .
C8 W1 Ge1 89.4(3) . .
C14 Ge1 Ge1 104.2(3) . 2_666
C14 Ge1 W1 109.4(3) . .
Ge1 Ge1 W1 134.22(7) 2_666 .
O1 C1 W1 175.6(10) . .
O2 C2 W1 175.4(10) . .
O3 C3 W1 173.1(9) . .
C8 C4 C5 108.9(12) . .
C8 C4 C9 127.1(15) . .
C5 C4 C9 123.4(15) . .
C8 C4 W1 73.8(7) . .
C5 C4 W1 71.2(6) . .
C9 C4 W1 128.2(10) . .
C6 C5 C4 105.1(11) . .
C6 C5 C10 127.2(12) . .
C4 C5 C10 127.2(13) . .
C6 C5 W1 72.0(6) . .
C4 C5 W1 72.5(6) . .
C10 C5 W1 126.1(9) . .
C7 C6 C5 110.1(11) . .
C7 C6 C11 126.0(14) . .
C5 C6 C11 123.7(13) . .
C7 C6 W1 73.8(7) . .
C5 C6 W1 72.2(6) . .
C11 C6 W1 124.7(8) . .
C6 C7 C8 107.1(11) . .
C6 C7 C12 127.2(19) . .
C8 C7 C12 125.5(18) . .
C6 C7 W1 71.2(6) . .
C8 C7 W1 72.8(7) . .
C12 C7 W1 125.3(9) . .
C4 C8 C7 108.9(11) . .
C4 C8 C13 123.0(18) . .
C7 C8 C13 127.6(18) . .
C4 C8 W1 71.9(7) . .
C7 C8 W1 72.0(6) . .
C13 C8 W1 128.6(9) . .
N2 C14 N1 105.9(9) . .
N2 C14 Ge1 125.5(8) . .
N1 C14 Ge1 127.7(8) . .
C14 N1 C15 109.5(9) . .
C14 N1 C17 126.3(9) . .
C15 N1 C17 124.0(9) . .
C16 C15 N1 106.5(9) . .
C16 C15 C18 131.2(11) . .
N1 C15 C18 122.2(11) . .
C15 C16 N2 106.5(9) . .
C15 C16 C19 130.1(11) . .
N2 C16 C19 123.4(11) . .
C14 N2 C16 111.5(9) . .
C14 N2 C20 124.0(9) . .
C16 N2 C20 124.4(9) . .
C21 B1 C45 111.4(8) . .
C21 B1 C29 110.6(8) . .
C45 B1 C29 108.5(8) . .
C21 B1 C37 110.5(8) . .
C45 B1 C37 108.3(7) . .
C29 B1 C37 107.6(8) . .
C22 C21 C26 115.1(9) . .
C22 C21 B1 120.9(8) . .
C26 C21 B1 124.0(9) . .
C23 C22 C21 123.0(9) . .
C24 C23 C22 120.7(9) . .
C24 C23 C27 119.6(9) . .
C22 C23 C27 119.5(9) . .
C23 C24 C25 118.5(9) . .
C24 C25 C26 120.3(10) . .
C24 C25 C28 118.3(9) . .
C26 C25 C28 121.5(9) . .
C25 C26 C21 122.4(9) . .
F1 C27 F3 106.1(10) . .
F1 C27 F2 107.6(10) . .
F3 C27 F2 105.7(8) . .
F1 C27 C23 113.7(9) . .
F3 C27 C23 112.8(9) . .
F2 C27 C23 110.5(9) . .
F6 C28 F4 104.4(11) . .
F6 C28 F5 103.6(12) . .
F4 C28 F5 106.4(12) . .
F6 C28 C25 113.8(11) . .
F4 C28 C25 113.8(9) . .
F5 C28 C25 113.8(10) . .
C34 C29 C30 115.6(8) . .
C34 C29 B1 123.7(8) . .
C30 C29 B1 120.6(8) . .
C31 C30 C29 121.0(9) . .
C32 C31 C30 122.0(9) . .
C32 C31 C35 120.1(9) . .
C30 C31 C35 117.9(9) . .
C31 C32 C33 117.3(9) . .
C32 C33 C34 120.8(9) . .
C32 C33 C36 120.9(9) . .
C34 C33 C36 118.3(10) . .
C29 C34 C33 123.2(9) . .
F8 C35 F9 107.3(9) . .
F8 C35 F7 104.9(9) . .
F9 C35 F7 105.3(10) . .
F8 C35 C31 114.0(10) . .
F9 C35 C31 113.2(10) . .
F7 C35 C31 111.4(9) . .
F12 C36 F11 107.0(11) . .
F12 C36 F10 106.7(11) . .
F11 C36 F10 102.6(10) . .
F12 C36 C33 113.8(9) . .
F11 C36 C33 113.3(10) . .
F10 C36 C33 112.7(10) . .
C38 C37 C42 115.8(9) . .
C38 C37 B1 122.7(8) . .
C42 C37 B1 121.4(8) . .
C37 C38 C39 121.7(9) . .
C40 C39 C38 121.2(9) . .
C40 C39 C43 118.4(9) . .
C38 C39 C43 120.3(9) . .
C39 C40 C41 117.9(9) . .
C42 C41 C40 120.8(9) . .
C42 C41 C44 122.2(10) . .
C40 C41 C44 117.0(10) . .
C41 C42 C37 122.6(9) . .
F15 C43 F14 108.9(11) . .
F15 C43 F13 105.4(11) . .
F14 C43 F13 103.5(10) . .
F15 C43 C39 114.6(10) . .
F14 C43 C39 113.2(9) . .
F13 C43 C39 110.4(9) . .
F19 C44 F17 127.7(18) . .
F19 C44 F16 67.7(16) . .
F17 C44 F16 107.5(19) . .
F19 C44 F21 113.7(16) . .
F17 C44 F21 29.7(11) . .
F16 C44 F21 130.5(17) . .
F19 C44 F18 34.1(10) . .
F17 C44 F18 111.9(16) . .
F16 C44 F18 101.1(16) . .
F21 C44 F18 87.1(13) . .
F19 C44 F20 101.9(15) . .
F17 C44 F20 73.7(16) . .
F16 C44 F20 38.0(12) . .
F21 C44 F20 102.2(14) . .
F18 C44 F20 130.6(14) . .
F19 C44 C41 114.7(14) . .
F17 C44 C41 115.6(15) . .
F16 C44 C41 109.2(15) . .
F21 C44 C41 113.1(12) . .
F18 C44 C41 110.6(12) . .
F20 C44 C41 109.7(12) . .
C46 C45 C50 114.0(9) . .
C46 C45 B1 124.8(8) . .
C50 C45 B1 121.1(9) . .
C45 C46 C47 122.3(9) . .
C48 C47 C46 122.2(10) . .
C48 C47 C51 119.3(10) . .
C46 C47 C51 118.4(9) . .
C47 C48 C49 116.9(10) . .
C50 C49 C48 120.8(10) . .
C50 C49 C52 120.1(10) . .
C48 C49 C52 119.1(10) . .
C49 C50 C45 123.8(10) . .
F30 C51 F23 107.9(10) . .
F30 C51 F22 106.0(10) . .
F23 C51 F22 101.4(10) . .
F30 C51 C47 114.2(10) . .
F23 C51 C47 113.1(10) . .
F22 C51 C47 113.2(9) . .
F25 C52 F27 119(2) . .
F25 C52 F24 103.3(16) . .
F27 C52 F24 23.6(19) . .
F25 C52 F29 65.1(16) . .
F27 C52 F29 123(2) . .
F24 C52 F29 135.9(17) . .
F25 C52 F26 108.5(16) . .
F27 C52 F26 78(2) . .
F24 C52 F26 99.5(14) . .
F29 C52 F26 52.2(12) . .
F25 C52 F28 24.2(15) . .
F27 C52 F28 108(2) . .
F24 C52 F28 87.4(15) . .
F29 C52 F28 89.3(18) . .
F26 C52 F28 130.0(17) . .
F25 C52 C49 116.5(15) . .
F27 C52 C49 115(2) . .
F24 C52 C49 113.3(12) . .
F29 C52 C49 109.5(14) . .
F26 C52 C49 113.9(11) . .
F28 C52 C49 108.1(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 C2 1.969(13) .
W1 C3 1.992(11) .
W1 C1 2.019(12) .
W1 C6 2.310(11) .
W1 C5 2.312(10) .
W1 C4 2.329(11) .
W1 C7 2.343(11) .
W1 C8 2.352(11) .
W1 Ge1 2.6368(11) .
Ge1 C14 2.029(11) .
Ge1 Ge1 2.345(2) 2_666
C1 O1 1.122(14) .
C2 O2 1.167(14) .
C3 O3 1.161(13) .
C4 C8 1.38(2) .
C4 C5 1.448(17) .
C4 C9 1.525(19) .
C5 C6 1.419(17) .
C5 C10 1.509(18) .
C6 C7 1.399(19) .
C6 C11 1.549(19) .
C7 C8 1.42(2) .
C7 C12 1.486(18) .
C8 C13 1.55(2) .
C14 N2 1.314(14) .
C14 N1 1.373(13) .
N1 C15 1.391(14) .
N1 C17 1.455(14) .
C15 C16 1.356(16) .
C15 C18 1.499(15) .
C16 N2 1.389(13) .
C16 C19 1.471(17) .
N2 C20 1.463(14) .
B1 C21 1.631(14) .
B1 C45 1.635(15) .
B1 C29 1.648(14) .
B1 C37 1.651(14) .
C21 C22 1.406(13) .
C21 C26 1.407(14) .
C22 C23 1.390(13) .
C23 C24 1.376(15) .
C23 C27 1.502(14) .
C24 C25 1.399(15) .
C25 C26 1.401(14) .
C25 C28 1.479(15) .
C27 F1 1.321(13) .
C27 F3 1.330(12) .
C27 F2 1.351(14) .
C28 F6 1.285(15) .
C28 F4 1.309(14) .
C28 F5 1.329(15) .
C29 C34 1.381(14) .
C29 C30 1.415(13) .
C30 C31 1.398(14) .
C31 C32 1.380(14) .
C31 C35 1.476(14) .
C32 C33 1.389(15) .
C33 C34 1.391(14) .
C33 C36 1.487(14) .
C35 F8 1.333(13) .
C35 F9 1.341(14) .
C35 F7 1.363(13) .
C36 F12 1.283(14) .
C36 F11 1.340(14) .
C36 F10 1.342(15) .
C37 C38 1.385(13) .
C37 C42 1.416(13) .
C38 C39 1.407(14) .
C39 C40 1.371(14) .
C39 C43 1.488(14) .
C40 C41 1.402(15) .
C41 C42 1.365(15) .
C41 C44 1.504(17) .
C43 F15 1.267(14) .
C43 F14 1.299(14) .
C43 F13 1.358(15) .
C44 F19 1.28(2) .
C44 F17 1.29(3) .
C44 F16 1.32(3) .
C44 F21 1.35(2) .
C44 F18 1.38(2) .
C44 F20 1.41(2) .
C45 C46 1.390(14) .
C45 C50 1.408(14) .
C46 C47 1.402(14) .
C47 C48 1.361(15) .
C47 C51 1.500(15) .
C48 C49 1.396(16) .
C49 C50 1.372(15) .
C49 C52 1.517(16) .
C51 F30 1.316(13) .
C51 F23 1.336(14) .
C51 F22 1.359(13) .
C52 F25 1.304(10) .
C52 F27 1.311(10) .
C52 F24 1.320(9) .
C52 F29 1.326(10) .
C52 F26 1.328(9) .
C52 F28 1.341(10) .
