#------------------------------------------------------------------------------
#$Date: 2017-10-04 18:16:43 +0300 (Wed, 04 Oct 2017) $
#$Revision: 201643 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/12/65/4126551.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4126551
loop_
_publ_author_name
'Morrison, Gregory'
'Latshaw, Allison M.'
'Spagnuolo, Nicholas R.'
'Zur Loye, Hans-Conrad'
_publ_section_title
;
 Observation of Intense X-ray Scintillation in a Family of Mixed Anion
 Silicates, Cs3RESi4O10F2 (RE = Y, Eu-Lu), Obtained via an Enhanced Flux
 Crystal Growth Technique.
;
_journal_name_full               'Journal of the American Chemical Society'
_journal_paper_doi               10.1021/jacs.7b08559
_journal_year                    2017
_chemical_formula_moiety         'Cs3 Dy F2 O10 Si4'
_chemical_formula_sum            'Cs3 Dy F2 O10 Si4'
_chemical_formula_weight         871.59
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_date             2017-03-30
_audit_creation_method
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5103)
;
_cell_angle_alpha                95.7630(10)
_cell_angle_beta                 90.1000(10)
_cell_angle_gamma                119.7430(10)
_cell_formula_units_Z            2
_cell_length_a                   7.0856(2)
_cell_length_b                   7.1360(3)
_cell_length_c                   16.1856(5)
_cell_measurement_reflns_used    9202
_cell_measurement_temperature    304(2)
_cell_measurement_theta_max      37.85
_cell_measurement_theta_min      2.53
_cell_volume                     705.72(4)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       'Bruker APEXII v2014.9-0 (Bruker, 2014)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_diffrn_ambient_temperature      303.9
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0315
_diffrn_reflns_av_unetI/netI     0.0149
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            63900
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        26.000
_diffrn_reflns_theta_max         37.876
_diffrn_reflns_theta_min         2.534
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    13.322
_exptl_absorpt_correction_T_max  0.0814
_exptl_absorpt_correction_T_min  0.0322
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/4 (Bruker,2014/4) was used for absorption correction.
wR2(int) was 0.0965 before and 0.0416 after correction.
The Ratio of minimum to maximum transmission is 0.3956.
The λ/2 correction factor is 0.00150.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    4.102
_exptl_crystal_description       'hexagonal plate'
_exptl_crystal_F_000             770
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_refine_diff_density_max         2.635
_refine_diff_density_min         -2.479
_refine_diff_density_rms         0.214
_refine_ls_extinction_coef       0.00362(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014)'
_refine_ls_goodness_of_fit_ref   1.114
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     186
_refine_ls_number_reflns         7633
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.114
_refine_ls_R_factor_all          0.0281
_refine_ls_R_factor_gt           0.0258
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0147P)²+5.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0648
_refine_ls_wR_factor_ref         0.0656
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7250
_reflns_number_total             7633
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ja7b08559_si_006.cif
_cod_data_source_block           Cs3DySi4O10F2
_cod_database_code               4126551
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.691
_shelx_estimated_absorpt_t_min   0.415
_olex2_refinement_description
;
1. Twinned data refinement
 Scales: 0.8743(10) 0.1257(10)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Dy1 Dy 0.5000 1.0000 0.0000 0.01144(4) Uani 1 2 d S T P
Dy2 Dy 0.5000 1.0000 0.5000 0.01654(4) Uani 1 2 d S T P
Cs1 Cs 0.84482(4) 0.68397(4) 0.05172(2) 0.02194(5) Uani 1 1 d . . .
Cs2 Cs 0.87163(5) 0.73098(5) 0.31830(2) 0.02948(6) Uani 1 1 d . . .
Cs3 Cs -0.18321(8) 0.64511(6) 0.58297(2) 0.04261(8) Uani 1 1 d . . .
Si1 Si 0.54985(16) 1.09411(13) 0.28477(5) 0.01195(13) Uani 1 1 d . . .
Si2 Si 0.37445(15) 0.29248(15) 0.16614(6) 0.01151(14) Uani 1 1 d . . .
Si3 Si 0.29219(14) 0.66380(14) 0.17231(6) 0.01165(14) Uani 1 1 d . . .
Si4 Si -0.07685(15) 0.21063(15) 0.17392(6) 0.01196(14) Uani 1 1 d . . .
O1 O 0.1181(4) 0.1513(4) 0.18605(18) 0.0168(4) Uani 1 1 d . . .
O2 O 0.7797(4) 1.1168(5) 0.25415(19) 0.0196(5) Uani 1 1 d . . .
O3 O 0.4421(4) 0.5503(4) 0.18312(18) 0.0162(4) Uani 1 1 d . . .
O4 O 0.3550(4) 0.8503(4) 0.25083(18) 0.0190(5) Uani 1 1 d . . .
O5 O 0.4206(5) 0.2330(5) 0.07530(18) 0.0215(5) Uani 1 1 d . . .
O6 O 0.5563(7) 1.1473(5) 0.38174(17) 0.0275(6) Uani 1 1 d . . .
O7 O 0.0417(4) 0.4770(4) 0.18895(17) 0.0155(4) Uani 1 1 d . . .
O8 O -0.2026(5) 0.1132(5) 0.08624(19) 0.0229(5) Uani 1 1 d . . .
O9 O 0.3023(5) 0.7421(5) 0.08437(18) 0.0212(5) Uani 1 1 d . . .
O10 O 0.5155(5) 1.2683(4) 0.23847(18) 0.0195(5) Uani 1 1 d . . .
F1 F 0.6060(6) 0.7692(6) 0.4491(2) 0.0371(7) Uani 1 1 d . . .
F2 F 0.1587(5) 0.7618(6) 0.4567(2) 0.0361(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cs Cs -0.3680 2.1192 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cs1 Dy1 Cs1 180.0 1_455 2_775
Cs1 Dy1 Cs1 115.935(7) . 1_565
Cs1 Dy1 Cs1 64.065(7) . 2_665
Cs1 Dy1 Cs1 115.912(6) 1_455 .
Cs1 Dy1 Cs1 63.336(7) 1_455 2_665
Cs1 Dy1 Cs1 180.0 1_565 2_665
Cs1 Dy1 Cs1 63.336(6) 2_775 1_565
Cs1 Dy1 Cs1 64.088(6) 1_455 2_675
Cs1 Dy1 Cs1 64.064(7) 2_675 1_565
Cs1 Dy1 Cs1 115.912(6) 2_775 2_675
Cs1 Dy1 Cs1 116.664(6) 2_775 2_665
Cs1 Dy1 Cs1 180.0 . 2_675
Cs1 Dy1 Cs1 115.936(7) 2_675 2_665
Cs1 Dy1 Cs1 116.664(6) 1_455 1_565
Cs1 Dy1 Cs1 64.088(6) 2_775 .
O5 Dy1 Cs1 45.64(8) 2_665 .
O5 Dy1 Cs1 131.94(8) 1_565 2_665
O5 Dy1 Cs1 110.10(8) 2_665 1_455
O5 Dy1 Cs1 134.36(8) 1_565 .
O5 Dy1 Cs1 69.90(8) 2_665 2_775
O5 Dy1 Cs1 134.36(8) 2_665 2_675
O5 Dy1 Cs1 48.06(8) 2_665 2_665
O5 Dy1 Cs1 45.64(8) 1_565 2_675
O5 Dy1 Cs1 69.90(8) 1_565 1_455
O5 Dy1 Cs1 110.10(8) 1_565 2_775
O5 Dy1 Cs1 48.06(8) 1_565 1_565
O5 Dy1 Cs1 131.94(8) 2_665 1_565
O5 Dy1 O5 180.00(13) 2_665 1_565
O5 Dy1 O8 89.87(11) 2_665 2_565
O5 Dy1 O8 90.13(11) 2_665 1_665
O5 Dy1 O8 89.87(11) 1_565 1_665
O5 Dy1 O8 90.13(11) 1_565 2_565
O5 Dy1 O9 89.61(11) 2_665 2_675
O5 Dy1 O9 90.39(11) 2_665 .
O5 Dy1 O9 89.61(11) 1_565 .
O5 Dy1 O9 90.39(11) 1_565 2_675
O8 Dy1 Cs1 49.89(8) 2_565 2_675
O8 Dy1 Cs1 129.26(8) 1_665 1_455
O8 Dy1 Cs1 50.74(8) 1_665 2_775
O8 Dy1 Cs1 49.89(8) 1_665 .
O8 Dy1 Cs1 130.11(8) 2_565 .
O8 Dy1 Cs1 110.97(8) 2_565 1_565
O8 Dy1 Cs1 50.74(8) 2_565 1_455
O8 Dy1 Cs1 69.03(8) 1_665 1_565
O8 Dy1 Cs1 129.26(8) 2_565 2_775
O8 Dy1 Cs1 69.03(8) 2_565 2_665
O8 Dy1 Cs1 110.97(8) 1_665 2_665
O8 Dy1 Cs1 130.11(8) 1_665 2_675
O8 Dy1 O8 180.0(2) 2_565 1_665
O8 Dy1 O9 88.90(11) 2_565 2_675
O8 Dy1 O9 88.90(11) 1_665 .
O8 Dy1 O9 91.10(11) 2_565 .
O8 Dy1 O9 91.10(11) 1_665 2_675
O9 Dy1 Cs1 133.09(8) . 2_775
O9 Dy1 Cs1 71.69(8) . .
O9 Dy1 Cs1 50.10(8) 2_675 1_565
O9 Dy1 Cs1 46.91(8) 2_675 2_775
O9 Dy1 Cs1 129.90(8) 2_675 2_665
O9 Dy1 Cs1 133.09(8) 2_675 1_455
O9 Dy1 Cs1 108.31(8) 2_675 .
O9 Dy1 Cs1 71.69(8) 2_675 2_675
O9 Dy1 Cs1 129.90(8) . 1_565
O9 Dy1 Cs1 50.10(8) . 2_665
O9 Dy1 Cs1 108.31(8) . 2_675
O9 Dy1 Cs1 46.91(8) . 1_455
O9 Dy1 O9 180.0 . 2_675
Cs3 Dy2 Cs3 74.768(8) 2_576 .
Cs3 Dy2 Cs3 105.232(8) 2_576 2_676
Cs3 Dy2 Cs3 180.0 2_566 1_665
Cs3 Dy2 Cs3 112.931(10) 2_566 2_676
Cs3 Dy2 Cs3 114.341(10) 2_566 2_576
Cs3 Dy2 Cs3 180.0 . 2_676
Cs3 Dy2 Cs3 65.659(10) 1_665 2_576
Cs3 Dy2 Cs3 105.232(8) 1_655 .
Cs3 Dy2 Cs3 65.659(10) 2_566 1_655
Cs3 Dy2 Cs3 67.069(10) 1_665 2_676
Cs3 Dy2 Cs3 114.341(10) 1_665 1_655
Cs3 Dy2 Cs3 74.768(8) 1_655 2_676
Cs3 Dy2 Cs3 180.0 2_576 1_655
Cs3 Dy2 Cs3 67.068(10) 2_566 .
Cs3 Dy2 Cs3 112.932(10) 1_665 .
O6 Dy2 Cs3 101.73(8) . 2_566
O6 Dy2 Cs3 118.69(11) . .
O6 Dy2 Cs3 125.01(10) . 1_655
O6 Dy2 Cs3 78.27(8) 2_676 2_566
O6 Dy2 Cs3 61.31(11) . 2_676
O6 Dy2 Cs3 78.27(8) . 1_665
O6 Dy2 Cs3 54.99(10) 2_676 1_655
O6 Dy2 Cs3 101.73(8) 2_676 1_665
O6 Dy2 Cs3 61.31(11) 2_676 .
O6 Dy2 Cs3 54.99(10) . 2_576
O6 Dy2 Cs3 118.69(11) 2_676 2_676
O6 Dy2 Cs3 125.01(10) 2_676 2_576
O6 Dy2 O6 180.0(2) . 2_676
F1 Dy2 Cs3 68.93(10) . 2_676
F1 Dy2 Cs3 39.72(9) . 1_655
F1 Dy2 Cs3 45.83(11) . 2_566
F1 Dy2 Cs3 134.17(11) . 1_665
F1 Dy2 Cs3 39.72(9) 2_676 2_576
F1 Dy2 Cs3 134.17(11) 2_676 2_566
F1 Dy2 Cs3 111.07(10) . .
F1 Dy2 Cs3 111.06(10) 2_676 2_676
F1 Dy2 Cs3 68.94(10) 2_676 .
F1 Dy2 Cs3 45.83(11) 2_676 1_665
F1 Dy2 Cs3 140.28(9) . 2_576
F1 Dy2 Cs3 140.28(9) 2_676 1_655
F1 Dy2 O6 88.30(13) 2_676 .
F1 Dy2 O6 91.70(13) 2_676 2_676
F1 Dy2 O6 88.30(13) . 2_676
F1 Dy2 O6 91.71(13) . .
F1 Dy2 F1 180.0 . 2_676
F2 Dy2 Cs3 71.24(10) 2_676 1_655
F2 Dy2 Cs3 36.51(9) 2_676 2_676
F2 Dy2 Cs3 143.49(9) 2_676 .
F2 Dy2 Cs3 108.76(10) 2_676 2_576
F2 Dy2 Cs3 36.51(9) . .
F2 Dy2 Cs3 143.49(9) . 2_676
F2 Dy2 Cs3 46.33(10) . 2_566
F2 Dy2 Cs3 133.67(10) 2_676 2_566
F2 Dy2 Cs3 46.33(10) 2_676 1_665
F2 Dy2 Cs3 71.24(10) . 2_576
F2 Dy2 Cs3 133.67(10) . 1_665
F2 Dy2 Cs3 108.76(10) . 1_655
F2 Dy2 O6 90.84(13) . .
F2 Dy2 O6 89.16(13) . 2_676
F2 Dy2 O6 90.84(13) 2_676 2_676
F2 Dy2 O6 89.16(13) 2_676 .
F2 Dy2 F1 89.53(13) . 2_676
F2 Dy2 F1 89.53(13) 2_676 .
F2 Dy2 F1 90.47(13) . .
F2 Dy2 F1 90.47(13) 2_676 2_676
F2 Dy2 F2 180.0(2) 2_676 .
Si2 Cs1 Si3 97.32(2) . 1_655
Si2 Cs1 Si4 97.29(2) . 1_665
Si3 Cs1 Si4 95.96(2) 1_655 1_665
O1 Cs1 Si2 105.99(5) 1_665 .
O1 Cs1 Si3 71.32(4) 1_665 1_655
O1 Cs1 Si4 25.41(4) 1_665 1_665
O1 Cs1 O7 83.73(6) 1_665 1_655
O3 Cs1 Si2 25.95(4) . .
O3 Cs1 Si3 104.75(5) . 1_655
O3 Cs1 Si4 71.90(5) . 1_665
O3 Cs1 O1 84.75(6) . 1_665
O3 Cs1 O7 83.75(6) . 1_655
O5 Cs1 Si2 97.52(6) 2_665 .
O5 Cs1 Si2 24.34(5) . .
O5 Cs1 Si3 164.97(6) 2_665 1_655
O5 Cs1 Si3 103.52(6) . 1_655
O5 Cs1 Si4 84.53(6) 2_665 1_665
O5 Cs1 Si4 119.34(5) . 1_665
O5 Cs1 O1 130.34(7) . 1_665
O5 Cs1 O1 106.68(7) 2_665 1_665
O5 Cs1 O3 47.74(7) . .
O5 Cs1 O3 89.72(7) 2_665 .
O5 Cs1 O5 89.14(8) 2_665 .
O5 Cs1 O7 78.31(7) . 1_655
O5 Cs1 O7 167.20(7) 2_665 1_655
O5 Cs1 O8 60.82(7) 2_665 1_665
O5 Cs1 O8 80.08(8) 2_665 2_665
O5 Cs1 O8 116.03(8) . 1_665
O5 Cs1 O8 138.12(7) . 2_665
O5 Cs1 O9 80.55(7) 2_665 2_665
O5 Cs1 O9 141.41(8) 2_665 1_655
O5 Cs1 O9 59.65(7) . 2_665
O7 Cs1 Si2 72.00(4) 1_655 .
O7 Cs1 Si3 25.82(4) 1_655 1_655
O7 Cs1 Si4 103.74(5) 1_655 1_665
O8 Cs1 Si2 100.45(6) 1_665 .
O8 Cs1 Si2 162.30(6) 2_665 .
O8 Cs1 Si3 85.05(5) 2_665 1_655
O8 Cs1 Si3 118.47(5) 1_665 1_655
O8 Cs1 Si4 99.91(6) 2_665 1_665
O8 Cs1 Si4 23.74(5) 1_665 1_665
O8 Cs1 O1 91.41(7) 2_665 1_665
O8 Cs1 O1 47.17(7) 1_665 1_665
O8 Cs1 O3 167.61(7) 2_665 .
O8 Cs1 O3 75.06(7) 1_665 .
O8 Cs1 O7 127.24(7) 1_665 1_655
O8 Cs1 O7 107.59(7) 2_665 1_655
O8 Cs1 O8 93.69(8) 1_665 2_665
O8 Cs1 O9 141.36(7) 1_665 2_665
O8 Cs1 O9 78.63(7) 2_665 2_665
O9 Cs1 Si2 119.54(5) 1_655 .
O9 Cs1 Si2 83.68(5) 2_665 .
O9 Cs1 Si3 23.70(5) 1_655 1_655
O9 Cs1 Si3 98.73(5) 2_665 1_655
O9 Cs1 Si4 99.92(6) 1_655 1_665
O9 Cs1 Si4 165.04(5) 2_665 1_665
O9 Cs1 O1 166.67(7) 2_665 1_665
O9 Cs1 O1 74.87(7) 1_655 1_665
O9 Cs1 O3 106.80(7) 2_665 .
O9 Cs1 O3 128.30(7) 1_655 .
O9 Cs1 O5 119.92(8) 1_655 .
O9 Cs1 O7 90.80(7) 2_665 1_655
O9 Cs1 O7 47.67(7) 1_655 1_655
O9 Cs1 O8 117.13(8) 1_655 1_665
O9 Cs1 O8 61.35(7) 1_655 2_665
O9 Cs1 O9 92.46(8) 1_655 2_665
Si1 Cs2 Cs3 164.565(15) 1_545 2_676
Si1 Cs2 Si2 46.039(19) 1_545 .
Si1 Cs2 Si3 83.64(2) 1_545 1_655
Si2 Cs2 Cs3 143.682(17) . 2_676
Si2 Cs2 Si3 90.91(2) . 1_655
Si3 Cs2 Cs3 105.439(16) 1_655 2_676
O1 Cs2 Cs3 60.11(5) 1_665 2_676
O1 Cs2 Si1 135.29(5) 1_665 1_545
O1 Cs2 Si2 99.14(5) 1_665 .
O1 Cs2 Si3 67.56(4) 1_665 1_655
O2 Cs2 Cs3 55.82(5) . 2_676
O2 Cs2 Si1 133.64(6) . 1_545
O2 Cs2 Si2 88.37(6) . .
O2 Cs2 Si3 109.16(5) . 1_655
O2 Cs2 O1 42.95(6) . 1_665
O3 Cs2 Cs3 119.54(4) . 2_676
O3 Cs2 Si1 69.57(5) . 1_545
O3 Cs2 Si2 24.16(4) . .
O3 Cs2 Si3 100.83(5) . 1_655
O3 Cs2 O1 82.68(6) . 1_665
O3 Cs2 O2 64.34(7) . .
O4 Cs2 Cs3 83.70(5) 1_655 2_676
O4 Cs2 Si1 102.70(5) 1_655 1_545
O4 Cs2 Si2 114.08(5) 1_655 .
O4 Cs2 Si3 23.52(5) 1_655 1_655
O4 Cs2 O1 61.88(7) 1_655 1_665
O4 Cs2 O2 104.28(7) 1_655 .
O4 Cs2 O3 120.34(7) 1_655 .
O7 Cs2 Cs3 129.08(4) 1_655 2_676
O7 Cs2 Si1 60.68(5) 1_655 1_545
O7 Cs2 Si2 71.11(5) 1_655 .
O7 Cs2 Si3 23.64(5) 1_655 1_655
O7 Cs2 O1 84.15(6) 1_655 1_665
O7 Cs2 O2 119.73(7) 1_655 .
O7 Cs2 O3 86.79(6) 1_655 .
O7 Cs2 O4 46.19(6) 1_655 1_655
O10 Cs2 Cs3 163.45(5) 1_545 2_676
O10 Cs2 Si1 23.46(5) 1_545 1_545
O10 Cs2 Si2 22.58(5) 1_545 .
O10 Cs2 Si3 87.48(6) 1_545 1_655
O10 Cs2 O1 118.05(7) 1_545 1_665
O10 Cs2 O2 110.57(7) 1_545 .
O10 Cs2 O3 46.25(6) 1_545 .
O10 Cs2 O4 110.41(7) 1_545 1_655
O10 Cs2 O7 64.23(7) 1_545 1_655
F1 Cs2 Cs3 73.56(8) . 2_676
F1 Cs2 Si1 95.24(8) . 1_545
F1 Cs2 Si2 95.67(8) . .
F1 Cs2 Si3 169.70(7) . 1_655
F1 Cs2 O1 118.90(8) . 1_665
F1 Cs2 O2 79.01(8) . .
F1 Cs2 O3 88.29(9) . .
F1 Cs2 O4 150.03(9) . 1_655
F1 Cs2 O7 155.57(9) . 1_655
F1 Cs2 O10 95.56(10) . 1_545
F1 Cs2 F2 84.69(9) . 1_655
F2 Cs2 Cs3 73.91(7) 1_655 2_676
F2 Cs2 Si1 94.85(7) 1_655 1_545
F2 Cs2 Si2 140.84(7) 1_655 .
F2 Cs2 Si3 85.21(7) 1_655 1_655
F2 Cs2 O1 114.95(8) 1_655 1_665
F2 Cs2 O2 129.64(9) 1_655 .
F2 Cs2 O3 162.27(8) 1_655 .
F2 Cs2 O4 70.18(9) 1_655 1_655
F2 Cs2 O7 92.89(9) 1_655 1_655
F2 Cs2 O10 118.27(9) 1_655 1_545
Dy2 Cs3 Dy2 105.232(8) 1_455 .
Dy2 Cs3 Dy2 112.932(10) 1_445 .
Dy2 Cs3 Dy2 114.341(10) 1_445 1_455
Dy2 Cs3 Cs2 84.470(8) 1_445 1_455
Dy2 Cs3 Si4 113.871(16) 1_445 2_566
Cs2 Cs3 Dy2 64.618(7) 1_455 .
Cs2 Cs3 Dy2 175.784(11) 2_676 1_445
Cs2 Cs3 Dy2 68.716(8) 2_676 .
Cs2 Cs3 Dy2 66.310(7) 1_455 1_455
Cs2 Cs3 Dy2 68.267(8) 2_676 1_455
Cs2 Cs3 Cs2 99.701(9) 2_676 1_455
Cs2 Cs3 Si4 62.034(15) 2_676 2_566
Si4 Cs3 Dy2 88.263(15) 2_566 .
Si4 Cs3 Dy2 118.734(16) 2_566 1_455
Si4 Cs3 Cs2 152.091(18) 2_566 1_455
O2 Cs3 Dy2 65.71(5) 2_676 .
O2 Cs3 Dy2 120.14(5) 2_676 1_455
O2 Cs3 Dy2 123.67(5) 2_676 1_445
O2 Cs3 Cs2 129.48(5) 2_676 1_455
O2 Cs3 Cs2 53.00(5) 2_676 2_676
O2 Cs3 Si4 22.71(5) 2_676 2_566
O2 Cs3 O6 107.77(7) 2_676 2_576
O6 Cs3 Dy2 112.17(6) 2_576 1_445
O6 Cs3 Dy2 127.75(5) 2_576 .
O6 Cs3 Dy2 29.96(4) 2_576 1_455
O6 Cs3 Cs2 68.25(5) 2_576 2_676
O6 Cs3 Cs2 95.29(5) 2_576 1_455
O6 Cs3 Si4 96.58(5) 2_576 2_566
F1 Cs3 Dy2 96.84(7) 1_455 .
F1 Cs3 Dy2 89.43(7) 2_566 1_455
F1 Cs3 Dy2 27.53(6) 1_455 1_455
F1 Cs3 Dy2 32.24(6) 2_566 1_445
F1 Cs3 Dy2 95.21(7) 1_455 1_445
F1 Cs3 Dy2 143.02(6) 2_566 .
F1 Cs3 Cs2 41.62(6) 1_455 1_455
F1 Cs3 Cs2 92.36(7) 2_566 1_455
F1 Cs3 Cs2 147.15(6) 2_566 2_676
F1 Cs3 Cs2 88.37(7) 1_455 2_676
F1 Cs3 Si4 145.83(6) 1_455 2_566
F1 Cs3 Si4 114.49(7) 2_566 2_566
F1 Cs3 O2 140.83(9) 1_455 2_676
F1 Cs3 O2 134.75(8) 2_566 2_676
F1 Cs3 O6 80.35(8) 2_566 2_576
F1 Cs3 O6 54.07(7) 1_455 2_576
F1 Cs3 F1 80.57(11) 2_566 1_455
F1 Cs3 F2 119.61(10) 2_566 .
F1 Cs3 F2 63.49(8) 2_566 2_566
F2 Cs3 Dy2 32.27(6) 2_566 1_445
F2 Cs3 Dy2 25.90(6) . .
F2 Cs3 Dy2 94.22(7) . 1_445
F2 Cs3 Dy2 86.26(6) 2_566 .
F2 Cs3 Dy2 142.75(6) 2_566 1_455
F2 Cs3 Dy2 98.93(7) . 1_455
F2 Cs3 Cs2 42.01(6) . 1_455
F2 Cs3 Cs2 88.54(7) . 2_676
F2 Cs3 Cs2 146.46(6) 2_566 2_676
F2 Cs3 Cs2 88.54(7) 2_566 1_455
F2 Cs3 Si4 96.52(7) 2_566 2_566
F2 Cs3 Si4 112.79(6) . 2_566
F2 Cs3 O2 96.98(8) 2_566 2_676
F2 Cs3 O2 90.78(8) . 2_676
F2 Cs3 O6 128.19(9) . 2_576
F2 Cs3 O6 143.78(8) 2_566 2_576
F2 Cs3 F1 117.47(10) 2_566 1_455
F2 Cs3 F1 80.86(8) . 1_455
F2 Cs3 F2 75.98(11) 2_566 .
Cs2 Si1 Cs2 112.32(2) 1_455 .
Cs2 Si1 Cs2 120.83(3) 1_565 .
Cs2 Si1 Cs2 121.81(3) 1_565 1_455
O2 Si1 Cs2 46.84(10) . .
O2 Si1 Cs2 85.16(11) . 1_565
O2 Si1 Cs2 152.67(11) . 1_455
O4 Si1 Cs2 157.98(12) . 1_565
O4 Si1 Cs2 80.00(11) . .
O4 Si1 Cs2 45.29(10) . 1_455
O4 Si1 O2 107.85(15) . .
O6 Si1 Cs2 90.15(15) . .
O6 Si1 Cs2 76.81(12) . 1_565
O6 Si1 Cs2 81.28(15) . 1_455
O6 Si1 O2 112.0(2) . .
O6 Si1 O4 112.67(17) . .
O6 Si1 O10 109.72(18) . .
O10 Si1 Cs2 90.63(11) . 1_455
O10 Si1 Cs2 152.02(12) . .
O10 Si1 Cs2 49.95(10) . 1_565
O10 Si1 O2 105.95(15) . .
O10 Si1 O4 108.41(16) . .
Cs1 Si2 Cs1 71.205(17) . 2_665
Cs1 Si2 Cs1 124.21(2) . 1_445
Cs1 Si2 Cs1 65.166(15) 2_665 1_445
Cs1 Si2 Cs2 132.27(3) 2_665 .
Cs1 Si2 Cs2 67.345(16) . .
Cs2 Si2 Cs1 162.10(3) . 1_445
O1 Si2 Cs1 85.33(11) . 2_665
O1 Si2 Cs1 154.88(11) . .
O1 Si2 Cs1 47.50(10) . 1_445
O1 Si2 Cs2 128.35(11) . .
O1 Si2 O3 106.62(14) . .
O3 Si2 Cs1 139.23(10) . 1_445
O3 Si2 Cs1 63.28(10) . .
O3 Si2 Cs1 84.44(11) . 2_665
O3 Si2 Cs2 56.39(10) . .
O5 Si2 Cs1 47.70(12) . 2_665
O5 Si2 Cs1 56.97(12) . .
O5 Si2 Cs1 68.08(12) . 1_445
O5 Si2 Cs2 118.67(13) . .
O5 Si2 O1 112.94(16) . .
O5 Si2 O3 111.35(16) . .
O5 Si2 O10 114.64(17) . 1_545
O10 Si2 Cs1 97.41(11) 1_545 .
O10 Si2 Cs1 162.12(12) 1_545 2_665
O10 Si2 Cs1 114.17(11) 1_545 1_445
O10 Si2 Cs2 48.13(10) 1_545 .
O10 Si2 O1 107.49(15) 1_545 .
O10 Si2 O3 103.06(15) 1_545 .
Cs1 Si3 Cs1 68.728(17) 1_455 2_665
Cs1 Si3 Cs2 66.895(15) 1_455 1_455
Cs2 Si3 Cs1 126.74(2) 1_455 2_665
O3 Si3 Cs1 81.10(10) . 2_665
O3 Si3 Cs1 148.94(11) . 1_455
O3 Si3 Cs2 132.32(11) . 1_455
O3 Si3 O7 105.48(13) . .
O4 Si3 Cs1 102.99(11) . 1_455
O4 Si3 Cs1 166.60(12) . 2_665
O4 Si3 Cs2 54.18(10) . 1_455
O4 Si3 O3 108.01(15) . .
O4 Si3 O7 103.28(14) . .
O7 Si3 Cs1 64.75(10) . 1_455
O7 Si3 Cs1 83.07(10) . 2_665
O7 Si3 Cs2 52.05(9) . 1_455
O9 Si3 Cs1 51.54(12) . 2_665
O9 Si3 Cs1 52.43(11) . 1_455
O9 Si3 Cs2 114.26(12) . 1_455
O9 Si3 O3 113.17(16) . .
O9 Si3 O4 115.10(16) . .
O9 Si3 O7 110.94(16) . .
Cs1 Si4 Cs1 68.889(17) 1_445 2_665
Cs1 Si4 Cs2 64.242(15) 1_445 1_445
Cs1 Si4 Cs2 127.49(2) 2_665 1_445
Cs1 Si4 Cs3 136.46(2) 2_665 2_566
Cs1 Si4 Cs3 117.06(2) 1_445 2_566
Cs3 Si4 Cs2 57.320(14) 2_566 1_445
O1 Si4 Cs1 62.89(10) . 1_445
O1 Si4 Cs1 82.12(10) . 2_665
O1 Si4 Cs2 56.45(10) . 1_445
O1 Si4 Cs3 66.77(10) . 2_566
O2 Si4 Cs1 101.12(11) 1_445 1_445
O2 Si4 Cs1 166.41(12) 1_445 2_665
O2 Si4 Cs2 49.54(10) 1_445 1_445
O2 Si4 Cs3 55.80(11) 1_445 2_566
O2 Si4 O1 101.86(15) 1_445 .
O2 Si4 O7 107.48(15) 1_445 .
O7 Si4 Cs1 83.51(10) . 2_665
O7 Si4 Cs1 151.07(10) . 1_445
O7 Si4 Cs2 134.46(11) . 1_445
O7 Si4 Cs3 77.18(10) . 2_566
O7 Si4 O1 106.08(14) . .
O8 Si4 Cs1 51.10(12) . 2_665
O8 Si4 Cs1 55.98(12) . 1_445
O8 Si4 Cs2 112.89(13) . 1_445
O8 Si4 Cs3 169.58(13) . 2_566
O8 Si4 O1 111.92(16) . .
O8 Si4 O2 115.91(17) . 1_445
O8 Si4 O7 112.64(16) . .
Cs1 O1 Cs2 75.68(5) 1_445 1_445
Si2 O1 Cs1 111.90(12) . 1_445
Si2 O1 Cs2 128.50(13) . 1_445
Si2 O1 Si4 128.46(17) . .
Si4 O1 Cs1 91.71(11) . 1_445
Si4 O1 Cs2 100.89(11) . 1_445
Cs2 O2 Cs3 71.18(6) . 2_676
Si1 O2 Cs2 112.47(12) . .
Si1 O2 Cs3 111.04(14) . 2_676
Si4 O2 Cs2 108.88(13) 1_665 .
Si4 O2 Cs3 101.50(12) 1_665 2_676
Si4 O2 Si1 133.52(19) 1_665 .
Cs2 O3 Cs1 79.46(6) . .
Si2 O3 Cs1 90.77(11) . .
Si2 O3 Cs2 99.44(11) . .
Si3 O3 Cs1 115.11(13) . .
Si3 O3 Cs2 126.39(13) . .
Si3 O3 Si2 129.50(17) . .
Si1 O4 Cs2 114.22(13) . 1_455
Si3 O4 Cs2 102.30(12) . 1_455
Si3 O4 Si1 139.97(19) . .
Dy1 O5 Cs1 100.22(10) 1_545 .
Dy1 O5 Cs1 102.72(10) 1_545 2_665
Cs1 O5 Cs1 90.86(8) 2_665 .
Si2 O5 Dy1 141.59(18) . 1_545
Si2 O5 Cs1 110.12(15) . 2_665
Si2 O5 Cs1 98.68(14) . .
Dy2 O6 Cs3 95.05(11) . 2_576
Si1 O6 Dy2 142.83(19) . .
Si1 O6 Cs3 105.78(17) . 2_576
Cs2 O7 Cs1 79.96(6) 1_455 1_455
Si3 O7 Cs1 89.43(11) . 1_455
Si3 O7 Cs2 104.31(11) . 1_455
Si4 O7 Cs1 112.84(12) . 1_455
Si4 O7 Cs2 122.63(13) . 1_455
Si4 O7 Si3 130.14(17) . .
Dy1 O8 Cs1 97.82(10) 1_445 1_445
Dy1 O8 Cs1 96.61(10) 1_445 2_665
Cs1 O8 Cs1 86.31(8) 1_445 2_665
Si4 O8 Dy1 151.17(19) . 1_445
Si4 O8 Cs1 106.74(14) . 2_665
Si4 O8 Cs1 100.28(14) . 1_445
Dy1 O9 Cs1 97.66(10) . 2_665
Dy1 O9 Cs1 100.65(10) . 1_455
Cs1 O9 Cs1 87.54(8) 1_455 2_665
Si3 O9 Dy1 146.11(19) . .
Si3 O9 Cs1 106.37(14) . 2_665
Si3 O9 Cs1 103.86(14) . 1_455
Si1 O10 Cs2 106.58(12) . 1_565
Si2 O10 Cs2 109.29(13) 1_565 1_565
Si2 O10 Si1 144.08(19) 1_565 .
Dy2 F1 Cs2 139.02(16) . .
Dy2 F1 Cs3 112.75(13) . 1_655
Dy2 F1 Cs3 101.93(13) . 2_566
Cs2 F1 Cs3 103.53(11) . 2_566
Cs2 F1 Cs3 94.09(9) . 1_655
Cs3 F1 Cs3 99.43(11) 2_566 1_655
Dy2 F2 Cs2 133.42(15) . 1_455
Dy2 F2 Cs3 117.59(14) . .
Dy2 F2 Cs3 101.39(13) . 2_566
Cs2 F2 Cs3 94.62(9) 1_455 .
Cs2 F2 Cs3 102.16(11) 1_455 2_566
Cs3 F2 Cs3 104.02(11) 2_566 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 Cs1 4.1645(3) 1_455
Dy1 Cs1 4.2228(3) 2_665
Dy1 Cs1 4.1947(3) 2_675
Dy1 Cs1 4.1645(3) 2_775
Dy1 Cs1 4.1947(3) .
Dy1 Cs1 4.2228(3) 1_565
Dy1 O5 2.256(3) 2_665
Dy1 O5 2.256(3) 1_565
Dy1 O8 2.262(3) 1_665
Dy1 O8 2.262(3) 2_565
Dy1 O9 2.273(3) .
Dy1 O9 2.273(3) 2_675
Dy2 Cs3 4.4936(5) .
Dy2 Cs3 4.4236(5) 1_655
Dy2 Cs3 4.4236(5) 2_576
Dy2 Cs3 4.0656(4) 2_566
Dy2 Cs3 4.4937(5) 2_676
Dy2 Cs3 4.0656(4) 1_665
Dy2 O6 2.218(3) 2_676
Dy2 O6 2.218(3) .
Dy2 F1 2.217(3) 2_676
Dy2 F1 2.217(3) .
Dy2 F2 2.215(3) .
Dy2 F2 2.215(3) 2_676
Cs1 Si2 3.7635(10) .
Cs1 Si3 3.7902(9) 1_655
Cs1 Si4 3.8443(10) 1_665
Cs1 O1 3.423(3) 1_665
Cs1 O3 3.362(3) .
Cs1 O5 3.074(3) 2_665
Cs1 O5 3.192(3) .
Cs1 O7 3.428(3) 1_655
Cs1 O8 3.246(3) 2_665
Cs1 O8 3.238(3) 1_665
Cs1 O9 3.269(3) 2_665
Cs1 O9 3.094(3) 1_655
Cs2 Cs3 4.0070(5) 2_676
Cs2 Si1 3.9200(9) 1_545
Cs2 Si2 3.9689(10) .
Cs2 Si3 3.9885(9) 1_655
Cs2 O1 3.568(3) 1_665
Cs2 O2 3.381(3) .
Cs2 O3 3.351(3) .
Cs2 O4 3.310(3) 1_655
Cs2 O7 3.246(3) 1_655
Cs2 O10 3.131(3) 1_545
Cs2 F1 2.916(3) .
Cs2 F2 2.940(3) 1_655
Cs3 Dy2 4.4236(5) 1_455
Cs3 Dy2 4.0656(4) 1_445
Cs3 Cs2 4.3788(5) 1_455
Cs3 Cs2 4.0070(5) 2_676
Cs3 Si4 4.1494(10) 2_566
Cs3 O2 3.502(3) 2_676
Cs3 O6 3.637(4) 2_576
Cs3 F1 2.980(4) 2_566
Cs3 F1 3.065(4) 1_455
Cs3 F2 3.017(4) .
Cs3 F2 3.000(4) 2_566
Si1 Cs2 4.2472(10) 1_455
Si1 Cs2 3.9200(9) 1_565
Si1 O2 1.638(3) .
Si1 O4 1.630(3) .
Si1 O6 1.572(3) .
Si1 O10 1.629(3) .
Si2 Cs1 3.9032(10) 2_665
Si2 Cs1 4.3082(10) 1_445
Si2 O1 1.634(3) .
Si2 O3 1.647(3) .
Si2 O5 1.569(3) .
Si2 O10 1.615(3) 1_545
Si3 Cs1 4.0050(10) 2_665
Si3 Cs1 3.7902(9) 1_455
Si3 Cs2 3.9885(9) 1_455
Si3 O3 1.642(3) .
Si3 O4 1.629(3) .
Si3 O7 1.651(3) .
Si3 O9 1.570(3) .
Si4 Cs1 3.9941(10) 2_665
Si4 Cs1 3.8443(10) 1_445
Si4 Cs2 4.2047(10) 1_445
Si4 Cs3 4.1494(10) 2_566
Si4 O1 1.650(3) .
Si4 O2 1.634(3) 1_445
Si4 O7 1.643(3) .
Si4 O8 1.573(3) .
O1 Cs1 3.423(3) 1_445
O1 Cs2 3.568(3) 1_445
O2 Cs3 3.502(3) 2_676
O2 Si4 1.635(3) 1_665
O4 Cs2 3.310(3) 1_455
O5 Dy1 2.256(3) 1_545
O5 Cs1 3.074(3) 2_665
O6 Cs3 3.637(4) 2_576
O7 Cs1 3.428(3) 1_455
O7 Cs2 3.246(3) 1_455
O8 Dy1 2.262(3) 1_445
O8 Cs1 3.238(3) 1_445
O8 Cs1 3.246(3) 2_665
O9 Cs1 3.094(3) 1_455
O9 Cs1 3.269(3) 2_665
O10 Cs2 3.131(3) 1_565
O10 Si2 1.615(3) 1_565
F1 Cs3 3.065(4) 1_655
F1 Cs3 2.980(4) 2_566
F2 Cs2 2.940(3) 1_455
F2 Cs3 3.000(4) 2_566
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Cs1 Si2 O1 Cs1 80.9(2) . 1_445
Cs1 Si2 O1 Cs1 60.21(9) 2_665 1_445
Cs1 Si2 O1 Cs2 169.73(11) . 1_445
Cs1 Si2 O1 Cs2 149.02(14) 2_665 1_445
Cs1 Si2 O1 Cs2 88.80(15) 1_445 1_445
Cs1 Si2 O1 Si4 -111.1(3) 1_445 .
Cs1 Si2 O1 Si4 -30.2(4) . .
Cs1 Si2 O1 Si4 -50.9(2) 2_665 .
Cs1 Si2 O3 Cs1 -71.74(5) 2_665 .
Cs1 Si2 O3 Cs1 -112.35(11) 1_445 .
Cs1 Si2 O3 Cs2 168.21(7) 1_445 .
Cs1 Si2 O3 Cs2 -79.44(7) . .
Cs1 Si2 O3 Cs2 -151.18(7) 2_665 .
Cs1 Si2 O3 Si3 124.1(3) . .
Cs1 Si2 O3 Si3 11.8(3) 1_445 .
Cs1 Si2 O3 Si3 52.4(2) 2_665 .
Cs1 Si2 O5 Dy1 118.8(3) . 1_545
Cs1 Si2 O5 Dy1 -71.3(3) 1_445 1_545
Cs1 Si2 O5 Dy1 -147.1(4) 2_665 1_545
Cs1 Si2 O5 Cs1 94.13(13) 2_665 .
Cs1 Si2 O5 Cs1 75.76(11) 1_445 2_665
Cs1 Si2 O5 Cs1 -94.13(13) . 2_665
Cs1 Si2 O5 Cs1 169.89(12) 1_445 .
Cs1 Si3 O3 Cs1 62.86(9) 2_665 .
Cs1 Si3 O3 Cs1 76.5(2) 1_455 .
Cs1 Si3 O3 Cs2 158.28(14) 2_665 .
Cs1 Si3 O3 Cs2 171.93(7) 1_455 .
Cs1 Si3 O3 Si2 -37.4(4) 1_455 .
Cs1 Si3 O3 Si2 -51.1(2) 2_665 .
Cs1 Si3 O4 Cs2 98.8(4) 2_665 1_455
Cs1 Si3 O4 Cs2 48.45(10) 1_455 1_455
Cs1 Si3 O4 Si1 -107.4(3) 1_455 .
Cs1 Si3 O4 Si1 -57.0(7) 2_665 .
Cs1 Si3 O7 Cs1 -69.71(4) 2_665 1_455
Cs1 Si3 O7 Cs2 -149.20(8) 2_665 1_455
Cs1 Si3 O7 Cs2 -79.49(7) 1_455 1_455
Cs1 Si3 O7 Si4 120.0(2) 1_455 .
Cs1 Si3 O7 Si4 50.2(2) 2_665 .
Cs1 Si3 O9 Dy1 -133.4(4) 2_665 .
Cs1 Si3 O9 Dy1 135.1(4) 1_455 .
Cs1 Si3 O9 Cs1 91.52(13) 2_665 1_455
Cs1 Si3 O9 Cs1 -91.52(13) 1_455 2_665
Cs1 Si4 O1 Cs1 -70.27(5) 2_665 1_445
Cs1 Si4 O1 Cs2 -146.01(7) 2_665 1_445
Cs1 Si4 O1 Cs2 -75.74(6) 1_445 1_445
Cs1 Si4 O1 Si2 120.0(2) 1_445 .
Cs1 Si4 O1 Si2 49.7(2) 2_665 .
Cs1 Si4 O7 Cs1 59.57(9) 2_665 1_455
Cs1 Si4 O7 Cs1 76.7(2) 1_445 1_455
Cs1 Si4 O7 Cs2 152.16(13) 2_665 1_455
Cs1 Si4 O7 Cs2 169.32(9) 1_445 1_455
Cs1 Si4 O7 Si3 -33.2(4) 1_445 .
Cs1 Si4 O7 Si3 -50.4(2) 2_665 .
Cs1 Si4 O8 Dy1 128.1(5) 1_445 1_445
Cs1 Si4 O8 Dy1 -142.7(5) 2_665 1_445
Cs1 Si4 O8 Cs1 -89.21(12) 1_445 2_665
Cs1 Si4 O8 Cs1 89.21(12) 2_665 1_445
Cs2 Si1 O2 Cs2 -47.1(3) 1_455 .
Cs2 Si1 O2 Cs2 141.68(11) 1_565 .
Cs2 Si1 O2 Cs3 64.09(9) 1_565 2_676
Cs2 Si1 O2 Cs3 -124.70(19) 1_455 2_676
Cs2 Si1 O2 Cs3 -77.59(12) . 2_676
Cs2 Si1 O2 Si4 104.0(3) 1_455 1_665
Cs2 Si1 O2 Si4 151.1(4) . 1_665
Cs2 Si1 O2 Si4 -67.2(3) 1_565 1_665
Cs2 Si1 O4 Cs2 -62.0(3) 1_565 1_455
Cs2 Si1 O4 Cs2 135.82(12) . 1_455
Cs2 Si1 O4 Si3 -70.2(3) . .
Cs2 Si1 O4 Si3 154.0(4) 1_455 .
Cs2 Si1 O4 Si3 91.9(4) 1_565 .
Cs2 Si1 O6 Dy2 -44.4(4) . .
Cs2 Si1 O6 Dy2 68.1(4) 1_455 .
Cs2 Si1 O6 Dy2 -166.2(4) 1_565 .
Cs2 Si1 O6 Cs3 72.25(8) 1_565 2_576
Cs2 Si1 O6 Cs3 -53.47(8) 1_455 2_576
Cs2 Si1 O6 Cs3 -166.04(9) . 2_576
Cs2 Si1 O10 Cs2 -81.1(2) . 1_565
Cs2 Si1 O10 Cs2 132.79(9) 1_455 1_565
Cs2 Si1 O10 Si2 177.2(4) 1_565 1_565
Cs2 Si1 O10 Si2 -50.0(4) 1_455 1_565
Cs2 Si1 O10 Si2 96.1(4) . 1_565
Cs2 Si2 O1 Cs1 -157.04(5) . 1_445
Cs2 Si2 O1 Cs2 -68.24(18) . 1_445
Cs2 Si2 O1 Si4 91.8(2) . .
Cs2 Si2 O3 Cs1 79.44(7) . .
Cs2 Si2 O3 Si3 -156.4(3) . .
Cs2 Si2 O5 Dy1 90.3(3) . 1_545
Cs2 Si2 O5 Cs1 -122.61(10) . 2_665
Cs2 Si2 O5 Cs1 -28.48(14) . .
Cs2 Si3 O3 Cs1 -164.59(4) 1_455 .
Cs2 Si3 O3 Cs2 -69.17(18) 1_455 .
Cs2 Si3 O3 Si2 81.5(3) 1_455 .
Cs2 Si3 O4 Si1 -155.8(4) 1_455 .
Cs2 Si3 O7 Cs1 79.49(8) 1_455 1_455
Cs2 Si3 O7 Si4 -160.6(3) 1_455 .
Cs2 Si3 O9 Dy1 108.0(3) 1_455 .
Cs2 Si3 O9 Cs1 -27.16(14) 1_455 1_455
Cs2 Si3 O9 Cs1 -118.68(8) 1_455 2_665
Cs2 Si4 O1 Cs1 75.74(6) 1_445 1_445
Cs2 Si4 O1 Si2 -164.2(3) 1_445 .
Cs2 Si4 O7 Cs1 -162.13(5) 1_445 1_455
Cs2 Si4 O7 Cs2 -69.55(18) 1_445 1_455
Cs2 Si4 O7 Si3 87.9(2) 1_445 .
Cs2 Si4 O8 Dy1 96.7(4) 1_445 1_445
Cs2 Si4 O8 Cs1 -31.34(13) 1_445 1_445
Cs2 Si4 O8 Cs1 -120.55(9) 1_445 2_665
Cs3 Si4 O1 Cs1 140.88(8) 2_566 1_445
Cs3 Si4 O1 Cs2 65.14(6) 2_566 1_445
Cs3 Si4 O1 Si2 -99.1(2) 2_566 .
Cs3 Si4 O7 Cs1 -159.71(11) 2_566 1_455
Cs3 Si4 O7 Cs2 -67.12(12) 2_566 1_455
Cs3 Si4 O7 Si3 90.4(2) 2_566 .
Cs3 Si4 O8 Dy1 77.6(9) 2_566 1_445
Cs3 Si4 O8 Cs1 -139.7(6) 2_566 2_665
Cs3 Si4 O8 Cs1 -50.5(7) 2_566 1_445
O1 Si2 O3 Cs1 -155.17(12) . .
O1 Si2 O3 Cs2 125.39(12) . .
O1 Si2 O3 Si3 -31.0(3) . .
O1 Si2 O5 Dy1 -87.4(3) . 1_545
O1 Si2 O5 Cs1 153.83(11) . .
O1 Si2 O5 Cs1 59.70(17) . 2_665
O1 Si4 O7 Cs1 139.40(13) . 1_455
O1 Si4 O7 Cs2 -128.01(15) . 1_455
O1 Si4 O7 Si3 29.5(3) . .
O1 Si4 O8 Dy1 158.2(4) . 1_445
O1 Si4 O8 Cs1 30.19(17) . 1_445
O1 Si4 O8 Cs1 -59.03(17) . 2_665
O2 Si1 O4 Cs2 173.95(13) . 1_455
O2 Si1 O4 Si3 -32.1(4) . .
O2 Si1 O6 Dy2 -87.0(4) . .
O2 Si1 O6 Cs3 151.41(13) . 2_576
O2 Si1 O10 Cs2 -69.21(16) . 1_565
O2 Si1 O10 Si2 108.0(4) . 1_565
O2 Si4 O1 Cs1 96.54(13) 1_445 1_445
O2 Si4 O1 Cs2 20.79(15) 1_445 1_445
O2 Si4 O1 Si2 -143.4(2) 1_445 .
O2 Si4 O7 Cs1 -112.24(14) 1_445 1_455
O2 Si4 O7 Cs2 -19.65(19) 1_445 1_455
O2 Si4 O7 Si3 137.8(2) 1_445 .
O2 Si4 O8 Dy1 42.0(5) 1_445 1_445
O2 Si4 O8 Cs1 -175.24(12) 1_445 2_665
O2 Si4 O8 Cs1 -86.03(16) 1_445 1_445
O3 Si2 O1 Cs1 142.98(13) . 1_445
O3 Si2 O1 Cs2 -128.21(16) . 1_445
O3 Si2 O1 Si4 31.9(3) . .
O3 Si2 O5 Dy1 152.7(3) . 1_545
O3 Si2 O5 Cs1 33.91(16) . .
O3 Si2 O5 Cs1 -60.22(18) . 2_665
O3 Si3 O4 Cs2 -129.68(12) . 1_455
O3 Si3 O4 Si1 74.5(3) . .
O3 Si3 O7 Cs1 -148.44(12) . 1_455
O3 Si3 O7 Cs2 132.07(13) . 1_455
O3 Si3 O7 Si4 -28.5(3) . .
O3 Si3 O9 Dy1 -77.1(4) . .
O3 Si3 O9 Cs1 147.82(12) . 1_455
O3 Si3 O9 Cs1 56.30(16) . 2_665
O4 Si1 O2 Cs2 -56.49(18) . .
O4 Si1 O2 Cs3 -134.08(14) . 2_676
O4 Si1 O2 Si4 94.6(3) . 1_665
O4 Si1 O6 Dy2 34.8(5) . .
O4 Si1 O6 Cs3 -86.82(16) . 2_576
O4 Si1 O10 Cs2 175.25(12) . 1_565
O4 Si1 O10 Si2 -7.5(4) . 1_565
O4 Si3 O3 Cs1 -107.02(15) . .
O4 Si3 O3 Cs2 -11.6(2) . .
O4 Si3 O3 Si2 139.1(2) . .
O4 Si3 O7 Cs1 98.29(13) . 1_455
O4 Si3 O7 Cs2 18.80(15) . 1_455
O4 Si3 O7 Si4 -141.8(2) . .
O4 Si3 O9 Dy1 47.8(4) . .
O4 Si3 O9 Cs1 -87.30(16) . 1_455
O4 Si3 O9 Cs1 -178.82(12) . 2_665
O5 Si2 O1 Cs1 20.37(18) . 1_445
O5 Si2 O1 Cs2 109.18(18) . 1_445
O5 Si2 O1 Si4 -90.7(2) . .
O5 Si2 O3 Cs1 -31.58(16) . .
O5 Si2 O3 Cs2 -111.01(15) . .
O5 Si2 O3 Si3 92.6(3) . .
O6 Si1 O2 Cs2 68.01(18) . .
O6 Si1 O2 Cs3 -9.58(18) . 2_676
O6 Si1 O2 Si4 -140.9(3) . 1_665
O6 Si1 O4 Cs2 49.9(2) . 1_455
O6 Si1 O4 Si3 -156.2(3) . .
O6 Si1 O10 Cs2 51.8(2) . 1_565
O6 Si1 O10 Si2 -131.0(4) . 1_565
O7 Si3 O3 Cs1 143.06(13) . .
O7 Si3 O3 Cs2 -121.52(16) . .
O7 Si3 O3 Si2 29.1(3) . .
O7 Si3 O4 Cs2 -18.27(15) . 1_455
O7 Si3 O4 Si1 -174.1(3) . .
O7 Si3 O9 Dy1 164.6(3) . .
O7 Si3 O9 Cs1 -62.03(16) . 2_665
O7 Si3 O9 Cs1 29.49(17) . 1_455
O7 Si4 O1 Cs1 -151.13(11) . 1_445
O7 Si4 O1 Cs2 133.12(12) . 1_445
O7 Si4 O1 Si2 -31.1(3) . .
O7 Si4 O8 Dy1 -82.3(4) . 1_445
O7 Si4 O8 Cs1 149.61(12) . 1_445
O7 Si4 O8 Cs1 60.40(17) . 2_665
O8 Si4 O1 Cs1 -27.92(16) . 1_445
O8 Si4 O1 Cs2 -103.66(16) . 1_445
O8 Si4 O1 Si2 92.1(3) . .
O8 Si4 O7 Cs1 16.64(19) . 1_455
O8 Si4 O7 Cs2 109.23(18) . 1_455
O8 Si4 O7 Si3 -93.3(3) . .
O9 Si3 O3 Cs1 21.61(19) . .
O9 Si3 O3 Cs2 117.03(18) . .
O9 Si3 O3 Si2 -92.3(3) . .
O9 Si3 O4 Cs2 102.79(15) . 1_455
O9 Si3 O4 Si1 -53.0(4) . .
O9 Si3 O7 Cs1 -25.55(15) . 1_455
O9 Si3 O7 Cs2 -105.04(15) . 1_455
O9 Si3 O7 Si4 94.4(3) . .
O10 Si1 O2 Cs2 -172.41(13) . .
O10 Si1 O2 Cs3 110.01(14) . 2_676
O10 Si1 O2 Si4 -21.3(3) . 1_665
O10 Si1 O4 Cs2 -71.76(18) . 1_455
O10 Si1 O4 Si3 82.2(3) . .
O10 Si1 O6 Dy2 155.7(4) . .
O10 Si1 O6 Cs3 34.06(18) . 2_576
O10 Si2 O1 Cs1 -107.07(14) 1_545 1_445
O10 Si2 O1 Cs2 -18.3(2) 1_545 1_445
O10 Si2 O1 Si4 141.8(2) 1_545 .
O10 Si2 O3 Cs1 91.80(13) 1_545 .
O10 Si2 O3 Cs2 12.36(15) 1_545 .
O10 Si2 O3 Si3 -144.1(2) 1_545 .
O10 Si2 O5 Dy1 36.2(4) 1_545 1_545
O10 Si2 O5 Cs1 -82.59(15) 1_545 .
O10 Si2 O5 Cs1 -176.72(13) 1_545 2_665
loop_
_twin_individual_id
_twin_individual_mass_fraction_refined
1 0.8743(10)
2 0.1257(10)
