#------------------------------------------------------------------------------
#$Date: 2019-11-25 08:48:01 +0200 (Mon, 25 Nov 2019) $
#$Revision: 240558 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/12/99/4129919.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4129919
loop_
_publ_author_name
'Chorazy, Szymon'
'Stanek, Jan J.'
'Nogaś, Wojciech'
'Majcher, Anna M.'
'Rams, Michał'
'Kozieł, Marcin'
'Juszyńska-Gałązka, Ewa'
'Nakabayashi, Koji'
'Ohkoshi, Shin-ichi'
'Sieklucka, Barbara'
'Podgajny, Robert'
_publ_section_title
;
 Tuning of Charge Transfer Assisted Phase Transition and Slow Magnetic
 Relaxation Functionalities in {Fe(9-x)Co(x)[W(CN)8]6} (x = 0-9) Molecular
 Solid Solution.
;
_journal_issue                   5
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              1635
_journal_page_last               1646
_journal_paper_doi               10.1021/jacs.5b11924
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C84 H60 Co5 Fe4 N48 O36 W6'
_chemical_formula_sum            'C84 H60 Co5 Fe4 N48 O36 W6'
_chemical_formula_weight         3938.95
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_creation_date             2015-01-27T11:53:33-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 114.6680(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   28.7689(10)
_cell_length_b                   18.6633(9)
_cell_length_c                   32.2252(13)
_cell_measurement_reflns_used    67284
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      2.995
_cell_measurement_wavelength     0.71075
_cell_volume                     15723.4(11)
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      130(2)
_diffrn_measured_fraction_theta_full 0.964
_diffrn_measured_fraction_theta_max 0.955
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0853
_diffrn_reflns_av_unetI/netI     0.0798
_diffrn_reflns_Laue_measured_fraction_full 0.964
_diffrn_reflns_Laue_measured_fraction_max 0.955
_diffrn_reflns_limit_h_max       37
_diffrn_reflns_limit_h_min       -37
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            67284
_diffrn_reflns_point_group_measured_fraction_full 0.964
_diffrn_reflns_point_group_measured_fraction_max 0.955
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_min         2.995
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.31
_exptl_absorpt_correction_T_max  0.654
_exptl_absorpt_correction_T_min  0.569
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Rigaku, 1995)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.664
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7484
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.08
_refine_diff_density_max         2.139
_refine_diff_density_min         -2.506
_refine_diff_density_rms         0.187
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     899
_refine_ls_number_reflns         17232
_refine_ls_number_restraints     92
_refine_ls_restrained_S_all      1.068
_refine_ls_R_factor_all          0.1228
_refine_ls_R_factor_gt           0.0803
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0460P)²+377.0876P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1477
_refine_ls_wR_factor_ref         0.1672
_reflns_Friedel_coverage         0
_reflns_number_gt                11861
_reflns_number_total             17232
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ja5b11924_si_003.cif
_cod_data_source_block           Co5Fe4W6_LT
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4129919
_shelx_estimated_absorpt_t_min   0.416
_shelx_estimated_absorpt_t_max   0.676
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
W1 W 0.41947(2) 0.83577(3) 0.11937(2) 0.04773(15) Uani 1 1 d . . . . .
W2 W 0.67612(2) 0.65742(3) 0.23703(2) 0.04199(14) Uani 1 1 d . . . . .
W3 W 0.44065(2) 0.44111(3) 0.12502(2) 0.04149(14) Uani 1 1 d . . . . .
Co1 Co 0.5 0.64417(10) 0.25 0.0260(4) Uani 1 2 d S T P . .
Co2 Co 0.60619(6) 0.92223(10) 0.23272(7) 0.0578(5) Uani 1 1 d . . . . .
Fe5 Fe 0.28416(6) 0.62231(10) 0.08712(5) 0.0471(4) Uani 1 1 d . . . . .
Fe3 Fe 0.62985(6) 0.38192(9) 0.24791(5) 0.0387(4) Uani 1 1 d . . . . .
Co4 Co 0.52782(6) 0.65137(11) 0.06814(5) 0.0548(5) Uani 1 1 d . . . . .
C11 C 0.4541(4) 0.7570(7) 0.1734(4) 0.040(3) Uani 1 1 d . . . . .
N11 N 0.4728(3) 0.7163(5) 0.2020(3) 0.034(2) Uani 1 1 d . . . . .
C12 C 0.4093(4) 0.8771(7) 0.1778(5) 0.050(3) Uani 1 1 d . . . . .
N12 N 0.4054(4) 0.8972(6) 0.2099(4) 0.058(3) Uani 1 1 d . . . . .
C13 C 0.4937(5) 0.8725(7) 0.1638(4) 0.049(3) Uani 1 1 d . . . . .
N13 N 0.5337(4) 0.8932(6) 0.1883(4) 0.058(3) Uani 1 1 d . . . . .
C14 C 0.4655(4) 0.7688(7) 0.0977(3) 0.045(3) Uani 1 1 d . . . . .
N14 N 0.4896(4) 0.7298(6) 0.0868(3) 0.049(3) Uani 1 1 d . . . . .
C15 C 0.3637(5) 0.7518(7) 0.1074(4) 0.054(3) Uani 1 1 d . . . . .
N15 N 0.3342(4) 0.7074(7) 0.0992(4) 0.063(3) Uani 1 1 d . . . . .
C16 C 0.3469(7) 0.8911(11) 0.0946(6) 0.105(7) Uani 1 1 d . . . . .
N16 N 0.3074(7) 0.9183(12) 0.0799(7) 0.155(8) Uani 1 1 d . . . . .
C17 C 0.3825(5) 0.8276(8) 0.0456(5) 0.064(4) Uani 1 1 d . . . . .
N17 N 0.3613(5) 0.8237(8) 0.0066(4) 0.082(4) Uani 1 1 d . . . . .
C18 C 0.4344(8) 0.9334(12) 0.0965(7) 0.120(8) Uani 1 1 d . . . . .
N18 N 0.4421(8) 0.9891(12) 0.0837(7) 0.177(11) Uani 1 1 d . . . . .
C21 C 0.6047(4) 0.6516(6) 0.2440(3) 0.040(3) Uani 1 1 d . . . . .
N21 N 0.5652(3) 0.6466(5) 0.2456(3) 0.034(2) Uani 1 1 d . . . . .
C22 C 0.6475(4) 0.7634(8) 0.2326(4) 0.050(3) Uani 1 1 d . . . . .
N22 N 0.6339(4) 0.8203(7) 0.2312(4) 0.063(3) Uani 1 1 d . . . . .
C23 C 0.6560(4) 0.5459(7) 0.2362(4) 0.040(3) Uani 1 1 d . . . . .
N23 N 0.6459(3) 0.4885(6) 0.2389(3) 0.048(3) Uani 1 1 d . . . . .
C24 C 0.6188(5) 0.6448(7) 0.1677(5) 0.051(3) Uani 1 1 d . . . . .
N24 N 0.5869(4) 0.6447(6) 0.1313(4) 0.053(3) Uani 1 1 d . . . . .
C25 C 0.6959(4) 0.6373(7) 0.3071(4) 0.051(3) Uani 1 1 d . . . . .
N25 N 0.7057(3) 0.6258(6) 0.3444(4) 0.050(3) Uani 1 1 d . . . . .
C26 C 0.7399(5) 0.5950(9) 0.2429(6) 0.084(5) Uani 1 1 d . . . . .
N26 N 0.7742(4) 0.5619(8) 0.2458(7) 0.123(7) Uani 1 1 d . . . . .
C27 C 0.7028(5) 0.7061(12) 0.1898(6) 0.101(7) Uani 1 1 d . . . A 1
N27A N 0.7215(10) 0.7554(16) 0.1733(14) 0.091(12) Uani 0.5 1 d . . P A 1
N27B N 0.7166(11) 0.7126(18) 0.1618(10) 0.074(9) Uani 0.5 1 d . U P B 2
C28 C 0.7412(4) 0.7233(8) 0.2763(4) 0.054(3) Uani 1 1 d . . . . .
N28 N 0.7756(4) 0.7593(7) 0.2949(4) 0.071(3) Uani 1 1 d . . . . .
C31 C 0.4654(4) 0.5257(7) 0.1769(4) 0.041(3) Uani 1 1 d . . . . .
N31 N 0.4772(3) 0.5704(5) 0.2037(3) 0.0311(19) Uani 1 1 d . . . . .
C32 C 0.5142(4) 0.4107(7) 0.1747(4) 0.041(3) Uani 1 1 d . . . . .
N32 N 0.5545(4) 0.3940(5) 0.2008(3) 0.044(2) Uani 1 1 d . . . . .
C33 C 0.4092(4) 0.4147(6) 0.1734(3) 0.038(3) Uani 1 1 d . . . . .
N33 N 0.3922(3) 0.4015(5) 0.1991(3) 0.045(2) Uani 1 1 d . . . . .
C34 C 0.4706(4) 0.5266(8) 0.0974(4) 0.049(3) Uani 1 1 d . . . . .
N34 N 0.4878(4) 0.5693(6) 0.0836(3) 0.053(3) Uani 1 1 d . . . . .
C35 C 0.3767(4) 0.5121(8) 0.1082(3) 0.048(3) Uani 1 1 d . . . . .
N35 N 0.3436(4) 0.5503(6) 0.1004(3) 0.053(3) Uani 1 1 d . . . . .
C36A C 0.4371(12) 0.330(2) 0.1332(11) 0.080(8) Uani 0.6 1 d . U P . .
N36A N 0.4330(11) 0.2663(16) 0.1352(10) 0.103(8) Uani 0.6 1 d . U P . .
C36B C 0.4160(13) 0.337(2) 0.1122(12) 0.050(8) Uani 0.4 1 d . U P . .
N36B N 0.3975(16) 0.280(2) 0.1064(15) 0.105(13) Uani 0.4 1 d . U P . .
C37A C 0.3780(11) 0.4089(17) 0.0645(10) 0.081(8) Uani 0.6 1 d . U P . .
N37A N 0.3464(11) 0.4005(17) 0.0287(11) 0.120(10) Uani 0.6 1 d . U P . .
C37B C 0.3966(11) 0.4379(18) 0.0518(10) 0.046(7) Uani 0.4 1 d . U P . .
N37B N 0.3745(14) 0.437(2) 0.0118(9) 0.095(12) Uani 0.4 1 d D . P . .
C38 C 0.4789(5) 0.3907(8) 0.0876(4) 0.055(3) Uani 1 1 d . . . . .
N38 N 0.5003(5) 0.3646(7) 0.0677(4) 0.081(4) Uani 1 1 d . . . . .
O41 O 0.4733(3) 0.6557(6) 0.0014(3) 0.070(3) Uani 1 1 d . . . C 1
C42A C 0.4270(13) 0.6945(19) -0.0155(12) 0.062(10) Uani 0.5 1 d . U P C 1
H42A H 0.409 0.6854 0.0036 0.093 Uiso 1 1 calc R U . C 1
H42B H 0.4059 0.6796 -0.0466 0.093 Uiso 1 1 calc R U . C 1
H42C H 0.4343 0.7453 -0.0151 0.093 Uiso 1 1 calc R U . C 1
O43 O 0.5646(4) 0.7306(6) 0.0483(4) 0.087(4) Uani 1 1 d . . . D 1
C44 C 0.6149(12) 0.7371(17) 0.0570(11) 0.210(14) Uani 1 1 d . U . D 1
H44A H 0.634 0.6978 0.0763 0.314 Uiso 1 1 calc R U . D 1
H44B H 0.628 0.7822 0.0724 0.314 Uiso 1 1 calc R U . D 1
H44C H 0.6187 0.736 0.0285 0.314 Uiso 1 1 calc R U . D 1
O45 O 0.5661(4) 0.5788(7) 0.0440(3) 0.075(3) Uani 1 1 d . . . E 1
C46A C 0.5553(12) 0.5139(19) 0.0315(11) 0.069(8) Uani 0.5 1 d . . P E 1
H46A H 0.5852 0.4904 0.0311 0.103 Uiso 0.5 1 calc R U P E 1
H46B H 0.5277 0.5125 0.0011 0.103 Uiso 0.5 1 calc R U P E 1
H46C H 0.5448 0.4893 0.0526 0.103 Uiso 0.5 1 calc R U P E 1
O51 O 0.2697(4) 0.6186(6) 0.0181(3) 0.079(3) Uani 1 1 d . . . F 1
C52A C 0.2680(14) 0.680(2) -0.0075(13) 0.100(11) Uani 0.5 1 d . U P F 1
H52A H 0.2691 0.7221 0.0102 0.15 Uiso 0.5 1 calc R U P F 1
H52B H 0.2366 0.6796 -0.0353 0.15 Uiso 0.5 1 calc R U P F 1
H52C H 0.2971 0.6797 -0.0153 0.15 Uiso 0.5 1 calc R U P F 1
O53 O 0.2225(3) 0.6909(6) 0.0695(3) 0.076(3) Uani 1 1 d . . . G 1
C54 C 0.2190(6) 0.7521(10) 0.0972(6) 0.096(6) Uani 1 1 d . . . G 1
H54A H 0.1863 0.7758 0.0815 0.144 Uiso 0.5 1 calc R U P G 1
H54B H 0.2221 0.735 0.1266 0.144 Uiso 0.5 1 calc R U P G 1
H54C H 0.2464 0.7858 0.1016 0.144 Uiso 0.5 1 calc R U P G 1
H54D H 0.2502 0.7552 0.125 0.144 Uiso 0.5 1 calc R U P G 1
H54E H 0.2144 0.7961 0.0798 0.144 Uiso 0.5 1 calc R U P G 1
H54F H 0.1901 0.7453 0.1049 0.144 Uiso 0.5 1 calc R U P G 1
O55 O 0.2330(4) 0.5372(6) 0.0717(4) 0.077(3) Uani 1 1 d D . . H 1
C56A C 0.2469(19) 0.473(2) 0.1084(13) 0.135(19) Uani 0.5 1 d . . P H 1
H56A H 0.2596 0.4323 0.0976 0.202 Uiso 0.5 1 calc R U P H 1
H56B H 0.2165 0.4592 0.1124 0.202 Uiso 0.5 1 calc R U P H 1
H56C H 0.273 0.4892 0.1374 0.202 Uiso 0.5 1 calc R U P H 1
O61 O 0.6204(4) 0.9535(6) 0.1767(4) 0.083(3) Uani 1 1 d . . . I 1
C62 C 0.6079(8) 0.9086(14) 0.1364(8) 0.139(9) Uani 1 1 d . . . I 1
H62A H 0.6132 0.8587 0.1456 0.208 Uiso 1 1 calc R U . I 1
H62B H 0.6297 0.9213 0.1214 0.208 Uiso 1 1 calc R U . I 1
H62C H 0.5723 0.9159 0.1156 0.208 Uiso 1 1 calc R U . I 1
O63 O 0.6772(3) 0.9584(6) 0.2743(4) 0.085(3) Uani 1 1 d . . . J 1
C64 C 0.7130(6) 0.9225(11) 0.3125(6) 0.100(6) Uani 1 1 d . . . J 1
H64A H 0.7214 0.9519 0.3395 0.15 Uiso 1 1 calc R U . J 1
H64B H 0.7438 0.9134 0.308 0.15 Uiso 1 1 calc R U . J 1
H64C H 0.6987 0.8774 0.3165 0.15 Uiso 1 1 calc R U . J 1
O65 O 0.5841(4) 1.0273(5) 0.2350(4) 0.083(3) Uani 1 1 d . . . K 1
C66 C 0.5334(8) 1.0530(12) 0.2073(9) 0.146(9) Uani 1 1 d . . . K 1
H66A H 0.5239 1.0394 0.1757 0.22 Uiso 1 1 calc R U . K 1
H66B H 0.5327 1.1048 0.2095 0.22 Uiso 1 1 calc R U . K 1
H66C H 0.5095 1.0321 0.2179 0.22 Uiso 1 1 calc R U . K 1
O71 O 0.7061(3) 0.3688(5) 0.2947(3) 0.063(2) Uani 1 1 d . . . L 1
C72 C 0.7499(6) 0.3994(11) 0.2892(7) 0.118(7) Uani 1 1 d . . . L 1
H72A H 0.7402 0.4105 0.2572 0.176 Uiso 1 1 calc R U . L 1
H72B H 0.7778 0.3651 0.2994 0.176 Uiso 1 1 calc R U . L 1
H72C H 0.7608 0.4429 0.3071 0.176 Uiso 1 1 calc R U . L 1
O73 O 0.6520(3) 0.3545(5) 0.1952(3) 0.062(3) Uani 1 1 d . . . M 1
C74 C 0.6343(6) 0.3881(12) 0.1522(5) 0.105(7) Uani 1 1 d . . . M 1
H74A H 0.5975 0.3823 0.1364 0.157 Uiso 1 1 calc R U . M 1
H74B H 0.6505 0.3665 0.1343 0.157 Uiso 1 1 calc R U . M 1
H74C H 0.6426 0.4388 0.1563 0.157 Uiso 1 1 calc R U . M 1
O75 O 0.6208(4) 0.2737(5) 0.2558(4) 0.076(3) Uani 1 1 d . . . N 1
C76A C 0.6478(15) 0.218(2) 0.2675(17) 0.120(14) Uani 0.5 1 d . U P N 1
H76A H 0.6263 0.1772 0.2661 0.18 Uiso 0.25 1 calc R U P N 1
H76B H 0.6642 0.2102 0.2469 0.18 Uiso 0.25 1 calc R U P N 1
H76C H 0.6737 0.2234 0.2984 0.18 Uiso 0.25 1 calc R U P N 1
H76D H 0.6832 0.23 0.2749 0.18 Uiso 0.25 1 calc R U P N 1
H76E H 0.6453 0.197 0.294 0.18 Uiso 0.25 1 calc R U P N 1
H76F H 0.6357 0.1837 0.2425 0.18 Uiso 0.25 1 calc R U P N 1
C42B C 0.4176(17) 0.655(2) -0.0118(14) 0.087(15) Uani 0.5 1 d . . P O 2
C46B C 0.5852(14) 0.508(2) 0.0650(13) 0.091(12) Uani 0.5 1 d . . P P 2
C52B C 0.3128(13) 0.611(3) 0.0026(10) 0.110(15) Uani 0.5 1 d . . P Q 2
C56B C 0.183(2) 0.539(3) 0.0796(15) 0.134(17) Uani 0.5 1 d . . P R 2
C76B C 0.6192(18) 0.220(3) 0.2250(17) 0.122(14) Uani 0.5 1 d . U P S 2
C1 C 0.1377(19) 0.624(3) 0.129(2) 0.18(2) Uiso 0.5 1 d D . P . .
O1 O 0.1023(9) 0.5770(13) 0.1354(8) 0.091(7) Uiso 0.5 1 d D . P . .
C2B C 0.335(3) 0.079(9) 0.146(4) 0.28(7) Uiso 0.3 1 d D . P . .
C2A C 0.3920(18) 0.079(3) 0.1432(12) 0.187(17) Uiso 0.7 1 d D . P . .
O2 O 0.3841(10) 0.0850(15) 0.1836(10) 0.244(11) Uiso 1 1 d D . . . .
C3 C 0.2764(18) 0.442(3) -0.1026(19) 0.17(2) Uiso 0.5 1 d D . P . .
O3 O 0.3266(17) 0.414(3) -0.0788(9) 0.23(2) Uiso 0.5 1 d D . P . .
C4A C 0.2911(18) 0.283(3) 0.1026(17) 0.21(2) Uiso 0.7 1 d D . P T 1
O4A O 0.2617(9) 0.3106(13) 0.1256(8) 0.147(8) Uiso 0.7 1 d D . P T 1
C4B C 0.305(2) 0.241(4) 0.118(2) 0.12(2) Uiso 0.3 1 d D . P U 2
O4B O 0.344(2) 0.212(3) 0.1586(19) 0.147(19) Uiso 0.3 1 d D . P U 2
C5A C -0.0266(15) 0.6672(19) 0.0953(13) 0.139(13) Uiso 0.7 1 d D . P . .
C5B C -0.053(4) 0.650(9) 0.061(7) 0.34(10) Uiso 0.3 1 d D . P . .
O5 O -0.0053(13) 0.6123(17) 0.0775(12) 0.302(14) Uiso 1 1 d D . . . .
C6 C 0.1937(19) 0.420(3) -0.0238(19) 0.20(3) Uiso 0.5 1 d D . P . .
O6A O 0.2401(18) 0.442(3) 0.0129(17) 0.135(17) Uiso 0.3 1 d D . P . .
O6B O 0.1695(17) 0.470(3) -0.0053(12) 0.104(19) Uiso 0.2 1 d D . P . .
O7 O 0.0168(11) 0.3397(16) 0.0001(10) 0.257(12) Uiso 1 1 d D . . . .
C7 C -0.0095(19) 0.394(2) 0.0138(18) 0.32(3) Uiso 1 1 d D . . . .
O8 O 0.5 0.256(2) 0.25 0.257(16) Uiso 1 2 d DS . P . .
C8 C 0.5466(9) 0.2212(16) 0.2774(10) 0.080(9) Uiso 0.5 1 d D . P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.849 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C18 W1 C13 70.0(6) . .
C18 W1 C14 98.5(8) . .
C13 W1 C14 79.9(4) . .
C18 W1 C15 145.3(6) . .
C13 W1 C15 144.7(4) . .
C14 W1 C15 91.8(5) . .
C18 W1 C16 76.2(8) . .
C13 W1 C16 129.7(7) . .
C14 W1 C16 142.4(6) . .
C15 W1 C16 75.5(7) . .
C18 W1 C12 96.9(8) . .
C13 W1 C12 76.2(4) . .
C14 W1 C12 145.0(4) . .
C15 W1 C12 93.1(5) . .
C16 W1 C12 72.0(6) . .
C18 W1 C17 75.6(7) . .
C13 W1 C17 131.0(5) . .
C14 W1 C17 71.8(4) . .
C15 W1 C17 76.4(5) . .
C16 W1 C17 70.8(6) . .
C12 W1 C17 142.8(5) . .
C18 W1 C11 141.6(6) . .
C13 W1 C11 71.6(4) . .
C14 W1 C11 74.3(4) . .
C15 W1 C11 73.1(4) . .
C16 W1 C11 131.8(6) . .
C12 W1 C11 74.2(4) . .
C17 W1 C11 133.0(5) . .
C26 W2 C25 88.3(6) . .
C26 W2 C22 144.8(5) . .
C25 W2 C22 99.3(5) . .
C26 W2 C28 75.7(5) . .
C25 W2 C28 72.2(5) . .
C22 W2 C28 74.1(5) . .
C26 W2 C23 71.8(5) . .
C25 W2 C23 78.1(4) . .
C22 W2 C23 143.4(4) . .
C28 W2 C23 136.1(5) . .
C26 W2 C21 142.2(5) . .
C25 W2 C21 74.0(4) . .
C22 W2 C21 72.3(4) . .
C28 W2 C21 126.8(4) . .
C23 W2 C21 72.0(4) . .
C26 W2 C24 107.0(6) . .
C25 W2 C24 146.1(4) . .
C22 W2 C24 85.7(5) . .
C28 W2 C24 140.3(5) . .
C23 W2 C24 78.3(4) . .
C21 W2 C24 75.7(4) . .
C26 W2 C27 75.3(7) . .
C25 W2 C27 143.7(6) . .
C22 W2 C27 78.7(6) . .
C28 W2 C27 72.5(6) . .
C23 W2 C27 124.5(7) . .
C21 W2 C27 136.4(5) . .
C24 W2 C27 70.2(5) . .
C36B W3 C36A 19.6(11) . .
C36B W3 C37A 57.0(13) . .
C36A W3 C37A 76.6(13) . .
C36B W3 C32 92.9(11) . .
C36A W3 C32 74.2(10) . .
C37A W3 C32 144.5(9) . .
C36B W3 C35 110.2(11) . .
C36A W3 C35 124.1(9) . .
C37A W3 C35 68.4(9) . .
C32 W3 C35 146.4(4) . .
C36B W3 C38 71.9(11) . .
C36A W3 C38 72.7(8) . .
C37A W3 C38 78.3(8) . .
C32 W3 C38 74.1(4) . .
C35 W3 C38 135.4(4) . .
C36B W3 C33 73.4(10) . .
C36A W3 C33 68.0(8) . .
C37A W3 C33 98.6(9) . .
C32 W3 C33 88.9(4) . .
C35 W3 C33 75.5(4) . .
C38 W3 C33 140.2(5) . .
C36B W3 C37B 76.0(13) . .
C36A W3 C37B 94.2(13) . .
C37A W3 C37B 26.0(10) . .
C32 W3 C37B 139.3(8) . .
C35 W3 C37B 72.0(8) . .
C38 W3 C37B 65.3(8) . .
C33 W3 C37B 123.4(8) . .
C36B W3 C34 140.9(10) . .
C36A W3 C34 145.7(8) . .
C37A W3 C34 99.3(9) . .
C32 W3 C34 93.7(4) . .
C35 W3 C34 83.6(5) . .
C38 W3 C34 73.1(5) . .
C33 W3 C34 145.1(4) . .
C37B W3 C34 74.1(9) . .
C36B W3 C31 144.2(10) . .
C36A W3 C31 129.3(9) . .
C37A W3 C31 142.1(8) . .
C32 W3 C31 73.4(4) . .
C35 W3 C31 73.7(4) . .
C38 W3 C31 131.4(4) . .
C33 W3 C31 73.4(4) . .
C37B W3 C31 135.1(9) . .
C34 W3 C31 74.1(4) . .
N31 Co1 N31 89.2(5) . 2_655
N31 Co1 N21 92.6(3) . 2_655
N31 Co1 N21 89.3(3) 2_655 2_655
N31 Co1 N21 89.3(3) . .
N31 Co1 N21 92.6(3) 2_655 .
N21 Co1 N21 177.3(5) 2_655 .
N31 Co1 N11 89.1(4) . .
N31 Co1 N11 176.6(3) 2_655 .
N21 Co1 N11 87.8(3) 2_655 .
N21 Co1 N11 90.4(3) . .
N31 Co1 N11 176.6(3) . 2_655
N31 Co1 N11 89.1(4) 2_655 2_655
N21 Co1 N11 90.4(3) 2_655 2_655
N21 Co1 N11 87.8(3) . 2_655
N11 Co1 N11 92.7(5) . 2_655
O63 Co2 N13 175.6(4) . .
O63 Co2 N12 88.8(4) . 2_655
N13 Co2 N12 93.9(4) . 2_655
O63 Co2 N22 91.7(4) . .
N13 Co2 N22 91.7(4) . .
N12 Co2 N22 91.2(5) 2_655 .
O63 Co2 O65 84.3(4) . .
N13 Co2 O65 92.1(4) . .
N12 Co2 O65 90.9(5) 2_655 .
N22 Co2 O65 175.4(4) . .
O63 Co2 O61 88.3(4) . .
N13 Co2 O61 88.9(4) . .
N12 Co2 O61 176.3(5) 2_655 .
N22 Co2 O61 91.2(5) . .
O65 Co2 O61 86.5(5) . .
O53 Fe5 N15 91.5(4) . .
O53 Fe5 N35 176.1(4) . .
N15 Fe5 N35 90.5(4) . .
O53 Fe5 O55 88.1(4) . .
N15 Fe5 O55 177.3(4) . .
N35 Fe5 O55 89.7(4) . .
O53 Fe5 O51 87.8(4) . .
N15 Fe5 O51 92.2(4) . .
N35 Fe5 O51 88.9(4) . .
O55 Fe5 O51 85.0(4) . .
O53 Fe5 N25 89.8(4) . 2_655
N15 Fe5 N25 89.9(4) . 2_655
N35 Fe5 N25 93.5(4) . 2_655
O55 Fe5 N25 92.8(4) . 2_655
O51 Fe5 N25 176.8(4) . 2_655
O75 Fe3 N32 92.9(4) . .
O75 Fe3 N33 88.5(4) . 2_655
N32 Fe3 N33 89.9(3) . 2_655
O75 Fe3 N23 173.8(4) . .
N32 Fe3 N23 91.1(4) . .
N33 Fe3 N23 96.2(4) 2_655 .
O75 Fe3 O71 86.8(4) . .
N32 Fe3 O71 179.2(4) . .
N33 Fe3 O71 90.9(4) 2_655 .
N23 Fe3 O71 89.1(4) . .
O75 Fe3 O73 87.6(4) . .
N32 Fe3 O73 90.7(3) . .
N33 Fe3 O73 176.0(4) 2_655 .
N23 Fe3 O73 87.7(4) . .
O71 Fe3 O73 88.5(4) . .
N24 Co4 N14 94.4(4) . .
N24 Co4 O41 174.1(4) . .
N14 Co4 O41 90.6(4) . .
N24 Co4 O43 91.8(4) . .
N14 Co4 O43 89.2(4) . .
O41 Co4 O43 85.1(4) . .
N24 Co4 O45 89.0(4) . .
N14 Co4 O45 174.2(4) . .
O41 Co4 O45 85.8(4) . .
O43 Co4 O45 86.0(5) . .
N24 Co4 N34 91.7(4) . .
N14 Co4 N34 92.1(4) . .
O41 Co4 N34 91.3(4) . .
O43 Co4 N34 176.1(4) . .
O45 Co4 N34 92.5(4) . .
N11 C11 W1 179.0(9) . .
C11 N11 Co1 175.8(8) . .
N12 C12 W1 177.3(11) . .
C12 N12 Co2 173.2(11) . 2_655
N13 C13 W1 178.8(12) . .
C13 N13 Co2 175.8(11) . .
N14 C14 W1 176.7(11) . .
C14 N14 Co4 173.8(10) . .
N15 C15 W1 177.0(12) . .
C15 N15 Fe5 176.3(11) . .
N16 C16 W1 177(2) . .
N17 C17 W1 177.6(12) . .
N18 C18 W1 179(3) . .
N21 C21 W2 176.6(9) . .
C21 N21 Co1 176.5(9) . .
N22 C22 W2 177.7(12) . .
C22 N22 Co2 174.9(11) . .
N23 C23 W2 175.0(10) . .
C23 N23 Fe3 176.7(11) . .
N24 C24 W2 173.5(12) . .
C24 N24 Co4 175.4(11) . .
N25 C25 W2 178.8(11) . .
C25 N25 Fe5 169.1(11) . 2_655
N26 C26 W2 179.4(19) . .
N27A C27 W2 157(3) . .
N28 C28 W2 176.3(12) . .
N31 C31 W3 178.4(8) . .
C31 N31 Co1 177.5(8) . .
N32 C32 W3 178.4(9) . .
C32 N32 Fe3 170.5(10) . .
N33 C33 W3 179.1(11) . .
C33 N33 Fe3 172.7(9) . 2_655
N34 C34 W3 177.4(11) . .
C34 N34 Co4 171.3(10) . .
N35 C35 W3 178.3(11) . .
C35 N35 Fe5 178.6(12) . .
C36B C36A N36A 100(5) . .
C36B C36A N36B 53(4) . .
N36A C36A N36B 47(2) . .
C36B C36A W3 77(5) . .
N36A C36A W3 176(3) . .
N36B C36A W3 129(3) . .
N36B N36A C36A 78(3) . .
N36B N36A C36B 51(3) . .
C36A C36B N36B 98(6) . .
C36A C36B N36A 53(4) . .
N36B C36B N36A 46(3) . .
C36A C36B C37A 147(6) . .
N36B C36B C37A 115(4) . .
N36A C36B C37A 160(3) . .
C36A C36B W3 84(5) . .
N36B C36B W3 172(4) . .
N36A C36B W3 136(3) . .
C37A C36B W3 63.3(14) . .
N36A N36B C36B 83(4) . .
N36A N36B C36A 55(3) . .
C37B C37A N37A 90(4) . .
N37A C37A N37B 50(2) . .
C37B C37A C36B 119(3) . .
N37A C37A C36B 130(3) . .
N37B C37A C36B 138(2) . .
C37B C37A W3 80(3) . .
N37A C37A W3 169(3) . .
N37B C37A W3 120(2) . .
C36B C37A W3 59.7(13) . .
C37A N37A N37B 89(3) . .
N37B N37A C37B 48.8(19) . .
C37A C37B N37B 108(4) . .
C37A C37B N37A 50(2) . .
N37B C37B N37A 58(2) . .
C37A C37B W3 74(3) . .
N37B C37B W3 177(3) . .
N37A C37B W3 124(2) . .
C37B N37B N37A 73(3) . .
N38 C38 W3 178.6(13) . .
C42A O41 Co4 127.2(15) . .
O41 C42A H42A 109.5 . .
O41 C42A H42B 109.5 . .
H42A C42A H42B 109.5 . .
O41 C42A H42C 109.5 . .
H42A C42A H42C 109.5 . .
H42B C42A H42C 109.5 . .
C44 O43 Co4 129.6(15) . .
O43 C44 H44A 109.5 . .
O43 C44 H44B 109.5 . .
H44A C44 H44B 109.5 . .
O43 C44 H44C 109.5 . .
H44A C44 H44C 109.5 . .
H44B C44 H44C 109.5 . .
C46A O45 Co4 129.5(16) . .
O45 C46A H46A 109.5 . .
O45 C46A H46B 109.5 . .
H46A C46A H46B 109.5 . .
O45 C46A H46C 109.5 . .
H46A C46A H46C 109.5 . .
H46B C46A H46C 109.5 . .
C52A O51 Fe5 123.1(18) . .
O51 C52A H52A 109.5 . .
O51 C52A H52B 109.5 . .
H52A C52A H52B 109.5 . .
O51 C52A H52C 109.5 . .
H52A C52A H52C 109.5 . .
H52B C52A H52C 109.5 . .
C54 O53 Fe5 125.4(8) . .
O53 C54 H54A 109.5 . .
O53 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
O53 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
O53 C54 H54D 109.5 . .
H54A C54 H54D 141.1 . .
H54B C54 H54D 56.3 . .
H54C C54 H54D 56.3 . .
O53 C54 H54E 109.5 . .
H54A C54 H54E 56.3 . .
H54B C54 H54E 141.1 . .
H54C C54 H54E 56.3 . .
H54D C54 H54E 109.5 . .
O53 C54 H54F 109.5 . .
H54A C54 H54F 56.3 . .
H54B C54 H54F 56.3 . .
H54C C54 H54F 141.1 . .
H54D C54 H54F 109.5 . .
H54E C54 H54F 109.5 . .
C56A O55 Fe5 117.2(16) . .
O55 C56A H56A 109.5 . .
O55 C56A H56B 109.5 . .
H56A C56A H56B 109.5 . .
O55 C56A H56C 109.5 . .
H56A C56A H56C 109.5 . .
H56B C56A H56C 109.5 . .
C62 O61 Co2 122.8(11) . .
O61 C62 H62A 109.5 . .
O61 C62 H62B 109.5 . .
H62A C62 H62B 109.5 . .
O61 C62 H62C 109.5 . .
H62A C62 H62C 109.5 . .
H62B C62 H62C 109.5 . .
C64 O63 Co2 125.9(9) . .
O63 C64 H64A 109.5 . .
O63 C64 H64B 109.5 . .
H64A C64 H64B 109.5 . .
O63 C64 H64C 109.5 . .
H64A C64 H64C 109.5 . .
H64B C64 H64C 109.5 . .
C66 O65 Co2 122.7(11) . .
O65 C66 H66A 109.5 . .
O65 C66 H66B 109.5 . .
H66A C66 H66B 109.5 . .
O65 C66 H66C 109.5 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
C72 O71 Fe3 124.3(9) . .
O71 C72 H72A 109.5 . .
O71 C72 H72B 109.5 . .
H72A C72 H72B 109.5 . .
O71 C72 H72C 109.5 . .
H72A C72 H72C 109.5 . .
H72B C72 H72C 109.5 . .
C74 O73 Fe3 125.2(8) . .
O73 C74 H74A 109.5 . .
O73 C74 H74B 109.5 . .
H74A C74 H74B 109.5 . .
O73 C74 H74C 109.5 . .
H74A C74 H74C 109.5 . .
H74B C74 H74C 109.5 . .
C76A O75 Fe3 139(2) . .
O75 C76A H76A 109.5 . .
O75 C76A H76B 109.5 . .
H76A C76A H76B 109.5 . .
O75 C76A H76C 109.5 . .
H76A C76A H76C 109.5 . .
H76B C76A H76C 109.5 . .
O75 C76A H76D 109.5 . .
H76A C76A H76D 141.1 . .
H76B C76A H76D 56.3 . .
H76C C76A H76D 56.3 . .
O75 C76A H76E 109.5 . .
H76A C76A H76E 56.3 . .
H76B C76A H76E 141.1 . .
H76C C76A H76E 56.3 . .
H76D C76A H76E 109.5 . .
O75 C76A H76F 109.5 . .
H76A C76A H76F 56.3 . .
H76B C76A H76F 56.3 . .
H76C C76A H76F 141.1 . .
H76D C76A H76F 109.5 . .
H76E C76A H76F 109.5 . .
O2 C2B C2A 53(3) . .
O2 C2A C2B 54(3) . .
C2A O2 C2B 73(6) . .
C5B C5A O5 68(4) . .
C5A C5B O5 67(4) . .
C5A O5 C5B 45(8) . .
O6A C6 O6B 85(4) . .
C8 O8 C8 126(4) 2_655 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 C18 2.078(19) .
W1 C13 2.129(13) .
W1 C14 2.138(13) .
W1 C15 2.160(14) .
W1 C16 2.162(15) .
W1 C12 2.163(14) .
W1 C17 2.166(15) .
W1 C11 2.177(13) .
W2 C26 2.115(14) .
W2 C25 2.119(13) .
W2 C22 2.124(14) .
W2 C28 2.154(13) .
W2 C23 2.158(13) .
W2 C21 2.160(12) .
W2 C24 2.167(14) .
W2 C27 2.170(15) .
W3 C36B 2.05(4) .
W3 C36A 2.09(4) .
W3 C37A 2.12(3) .
W3 C32 2.130(11) .
W3 C35 2.145(13) .
W3 C38 2.157(13) .
W3 C33 2.161(11) .
W3 C37B 2.16(3) .
W3 C34 2.173(14) .
W3 C31 2.192(14) .
Co1 N31 1.932(9) .
Co1 N31 1.932(9) 2_655
Co1 N21 1.940(8) 2_655
Co1 N21 1.940(8) .
Co1 N11 1.951(9) .
Co1 N11 1.951(9) 2_655
Co2 O63 2.035(9) .
Co2 N13 2.050(11) .
Co2 N12 2.066(12) 2_655
Co2 N22 2.071(13) .
Co2 O65 2.072(10) .
Co2 O61 2.094(11) .
Fe5 O53 2.067(10) .
Fe5 N15 2.070(12) .
Fe5 N35 2.073(11) .
Fe5 O55 2.080(10) .
Fe5 O51 2.086(10) .
Fe5 N25 2.102(11) 2_655
Fe3 O75 2.065(10) .
Fe3 N32 2.076(9) .
Fe3 N33 2.087(9) 2_655
Fe3 N23 2.090(12) .
Fe3 O71 2.095(8) .
Fe3 O73 2.113(8) .
Co4 N24 2.039(11) .
Co4 N14 2.064(11) .
Co4 O41 2.069(9) .
Co4 O43 2.069(10) .
Co4 O45 2.090(10) .
Co4 N34 2.097(11) .
C11 N11 1.141(14) .
C12 N12 1.148(15) .
N12 Co2 2.066(12) 2_655
C13 N13 1.155(15) .
C14 N14 1.158(15) .
C15 N15 1.134(15) .
C16 N16 1.149(19) .
C17 N17 1.148(16) .
C18 N18 1.17(2) .
C21 N21 1.164(13) .
C22 N22 1.126(15) .
C23 N23 1.122(14) .
C24 N24 1.148(15) .
C25 N25 1.136(15) .
N25 Fe5 2.102(11) 2_655
C26 N26 1.135(17) .
C27 N27A 1.29(3) .
C28 N28 1.138(15) .
C31 N31 1.146(14) .
C32 N32 1.154(13) .
C33 N33 1.150(13) .
N33 Fe3 2.087(9) 2_655
C34 N34 1.123(15) .
C35 N35 1.132(14) .
C38 N38 1.164(15) .
O41 C42A 1.41(4) .
C42A H42A 0.97 .
C42A H42B 0.97 .
C42A H42C 0.97 .
O43 C44 1.36(3) .
O45 C46A 1.27(3) .
O51 C52A 1.40(3) .
O53 C54 1.478(19) .
O55 C56A 1.61(5) .
O61 C62 1.46(2) .
O63 C64 1.404(19) .
O65 C66 1.44(2) .
O71 C72 1.462(18) .
O73 C74 1.408(16) .
O75 C76A 1.26(4) .
C1 O1 1.425(10) .
C2B O2 1.428(10) .
C2B C2A 1.69(12) .
C2A O2 1.416(10) .
C3 O3 1.423(10) .
C4A O4A 1.432(10) .
C4B O4B 1.428(10) .
C5A C5B 1.10(19) .
C5A O5 1.429(10) .
C5B O5 1.434(10) .
C6 O6A 1.421(10) .
C6 O6B 1.432(10) .
O7 C7 1.437(10) .
O8 C8 1.417(10) 2_655
O8 C8 1.417(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C36B C36A N36A N36B -9(5)
N36B C36A N36A C36B 9(5)
N36A C36A C36B N36B 9(5)
W3 C36A C36B N36B -172(4)
N36B C36A C36B N36A -9(5)
W3 C36A C36B N36A 179(2)
N36A C36A C36B C37A -174(7)
N36B C36A C36B C37A 177(11)
W3 C36A C36B C37A 5(8)
N36A C36A C36B W3 -179(2)
N36B C36A C36B W3 172(4)
N36B N36A C36B C36A 168(7)
C36A N36A C36B N36B -168(7)
N36B N36A C36B C37A -22(8)
C36A N36A C36B C37A 170(11)
N36B N36A C36B W3 169(5)
C36A N36A C36B W3 1(3)
C36A N36A N36B C36B 6(3)
C36B N36A N36B C36A -6(3)
C36A C36B N36B N36A -10(5)
C37A C36B N36B N36A 172(3)
N36A C36B N36B C36A 10(5)
C37A C36B N36B C36A -178(7)
C36B C36A N36B N36A 168(7)
W3 C36A N36B N36A 178(3)
N36A C36A N36B C36B -168(7)
W3 C36A N36B C36B 10(5)
C37B C37A N37A N37B 4(4)
C36B C37A N37A N37B -125(4)
W3 C37A N37A N37B 22(16)
N37B C37A N37A C37B -4(4)
C36B C37A N37A C37B -129(5)
W3 C37A N37A C37B 18(14)
N37A C37A C37B N37B -5(4)
C36B C37A C37B N37B 132(3)
W3 C37A C37B N37B 179(3)
N37B C37A C37B N37A 5(4)
C36B C37A C37B N37A 137(4)
W3 C37A C37B N37A -177(3)
N37A C37A C37B W3 177(3)
N37B C37A C37B W3 -179(3)
C36B C37A C37B W3 -47(3)
N37B N37A C37B C37A -175(5)
C37A N37A C37B N37B 175(5)
C37A N37A C37B W3 -4(3)
N37B N37A C37B W3 -179(4)
C37A C37B N37B N37A 4(4)
N37A C37B N37B C37A -4(4)
C37A N37A N37B C37B -3(3)
C37B N37A N37B C37A 3(3)
N37A C37A N37B C37B 174(6)
C36B C37A N37B C37B -78(5)
W3 C37A N37B C37B -2(4)
C37B C37A N37B N37A -174(6)
C36B C37A N37B N37A 108(4)
W3 C37A N37B N37A -175(4)
