#------------------------------------------------------------------------------
#$Date: 2019-11-25 16:33:10 +0200 (Mon, 25 Nov 2019) $
#$Revision: 241331 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/13/10/4131014.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4131014
loop_
_publ_author_name
'Hau, Sam C. K.'
'Yeung, Margaret C.-L.'
'Yam, Vivian W.-W.'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of Heterometallic Silver(I)-Copper(I) Alkyl-1,3-diynyl Clusters
 via Inner-Core Expansion.
;
_journal_issue                   41
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13732
_journal_page_last               13739
_journal_paper_doi               10.1021/jacs.6b08674
_journal_volume                  138
_journal_year                    2016
_chemical_formula_moiety         'C129 H111 Ag3 Cu P6, 2(F3 P0.5)'
_chemical_formula_sum            'C129 H111 Ag3 Cu F6 P7'
_chemical_formula_weight         2379.12
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2016-07-20
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_cell_angle_alpha                94.708(2)
_cell_angle_beta                 90.237(2)
_cell_angle_gamma                111.692(2)
_cell_formula_units_Z            2
_cell_length_a                   13.6648(14)
_cell_length_b                   15.9205(18)
_cell_length_c                   27.740(3)
_cell_measurement_reflns_used    9983
_cell_measurement_temperature    173
_cell_measurement_theta_max      27.86
_cell_measurement_theta_min      2.28
_cell_volume                     5584.7(10)
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173.15
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1379
_diffrn_reflns_av_unetI/netI     0.1186
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            81763
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         0.74
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.866
_exptl_absorpt_correction_T_max  0.7811
_exptl_absorpt_correction_T_min  0.6712
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            'clear yellowish yellow'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   yellowish
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.415
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2428
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.3
_refine_diff_density_max         1.353
_refine_diff_density_min         -1.089
_refine_diff_density_rms         0.186
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1318
_refine_ls_number_reflns         20074
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.1109
_refine_ls_R_factor_gt           0.0731
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1027P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1752
_refine_ls_wR_factor_ref         0.2005
_reflns_number_gt                13796
_reflns_number_total             20074
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja6b08674_si_002.cif
_cod_data_source_block           2
_cod_original_cell_volume        5584.6(11)
_cod_database_code               4131014
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C5(H5), C12(H12), C19(H19)
2.b Me refined with riding coordinates:
 C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C13(H13A,H13B,H13C), C14(H14A,H14B,H14C),
 C20(H20A,H20B,H20C), C21(H21A,H21B,H21C)
2.c Aromatic/amide H refined with riding coordinates:
 C23(H23), C24(H24), C25(H25), C26(H26), C27(H27), C29(H29), C30(H30),
 C31(H31), C32(H32), C33(H33), C35(H35), C36(H36), C37(H37), C38(H38), C39(H39),
  C41(H41), C42(H42), C43(H43), C44(H44), C45(H45), C47(H47), C48(H48),
 C49(H49), C50(H50), C51(H51), C53(H53), C54(H54), C55(H55), C56(H56), C57(H57),
  C59(H59), C60(H60), C61(H61), C62(H62), C63(H63), C65(H65), C66(H66),
 C67(H67), C68(H68), C69(H69), C71(H71), C72(H72), C73(H73), C74(H74), C75(H75),
  C77(H77), C78(H78), C79(H79), C80(H80), C81(H81), C83(H83), C84(H84),
 C85(H85), C86(H86), C87(H87), C89(H89), C90(H90), C91(H91), C92(H92), C93(H93),
  C95(H95), C96(H96), C97(H97), C98(H98), C99(H99), C101(H101), C102(H102),
 C103(H103), C104(H104), C105(H105), C107(H107), C108(H108), C109(H109),
 C110(H110), C111(H111), C113(H113), C114(H114), C115(H115), C116(H116),
 C117(H117), C119(H119), C120(H120), C121(H121), C122(H122), C123(H123),
 C125(H125), C126(H126), C127(H127), C128(H128), C129(H129)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_site_symmetry_order
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ag1 Ag 0.94200(4) 0.37603(3) 0.247168(18) 0.02449(14) Uani 1 d 1 . . .
Ag2 Ag 0.86912(4) 0.11551(3) 0.333986(17) 0.02511(14) Uani 1 d 1 . . .
Ag3 Ag 0.76544(4) 0.07930(3) 0.167076(17) 0.02422(14) Uani 1 d 1 . . .
Cu1 Cu 0.85443(6) 0.18863(5) 0.25050(3) 0.02191(19) Uani 1 d 1 . . .
P1 P 0.83781(14) 0.47600(12) 0.25195(7) 0.0284(4) Uani 1 d 1 . . .
P2 P 1.13590(13) 0.45064(11) 0.23733(6) 0.0248(4) Uani 1 d 1 . . .
P3 P 0.74482(14) 0.11151(11) 0.39995(6) 0.0272(4) Uani 1 d 1 . . .
P4 P 1.00194(13) 0.04693(11) 0.35098(6) 0.0247(4) Uani 1 d 1 . . .
P5 P 0.56873(13) 0.01788(12) 0.15540(6) 0.0270(4) Uani 1 d 1 . . .
P6 P 0.87817(13) 0.05494(11) 0.10165(6) 0.0246(4) Uani 1 d 1 . . .
C1 C 0.9268(5) 0.2691(4) 0.3083(2) 0.0235(14) Uani 1 d 1 . . .
C2 C 0.9817(5) 0.3226(4) 0.3409(2) 0.0283(15) Uani 1 d 1 . . .
C3 C 1.0472(5) 0.3848(4) 0.3758(3) 0.0321(16) Uani 1 d 1 . . .
C4 C 1.1063(6) 0.4384(5) 0.4061(3) 0.0435(19) Uani 1 d 1 . . .
C5 C 1.1834(7) 0.5057(6) 0.4410(3) 0.058(2) Uani 1 d 1 . . .
H5 H 1.1989 0.4715 0.4667 0.069 Uiso 1 calc 1 R . .
C6 C 1.2865(7) 0.5545(7) 0.4174(4) 0.077(3) Uani 1 d 1 . . .
H6A H 1.3141 0.5098 0.4029 0.116 Uiso 1 calc 1 R . .
H6B H 1.3376 0.5954 0.4419 0.116 Uiso 1 calc 1 R . .
H6C H 1.2746 0.5896 0.3922 0.116 Uiso 1 calc 1 R . .
C7 C 1.1385(10) 0.5699(8) 0.4650(5) 0.104(4) Uani 1 d 1 . . .
H7A H 1.0727 0.5356 0.4802 0.156 Uiso 1 calc 1 R . .
H7B H 1.1242 0.6060 0.4409 0.156 Uiso 1 calc 1 R . .
H7C H 1.1890 0.6104 0.4899 0.156 Uiso 1 calc 1 R . .
C8 C 0.8385(5) 0.2431(4) 0.1917(2) 0.0275(15) Uani 1 d 1 . . .
C9 C 0.8284(5) 0.2836(4) 0.1573(2) 0.0297(15) Uani 1 d 1 . . .
C10 C 0.8197(5) 0.3333(5) 0.1190(3) 0.0349(17) Uani 1 d 1 . . .
C11 C 0.8101(7) 0.3765(5) 0.0879(3) 0.050(2) Uani 1 d 1 . . .
C12 C 0.7977(9) 0.4302(7) 0.0483(3) 0.075(3) Uani 1 d 1 . . .
H12 H 0.7199 0.4139 0.0440 0.090 Uiso 1 calc 1 R . .
C13 C 0.8392(17) 0.5240(8) 0.0595(4) 0.169(9) Uani 1 d 1 . . .
H13A H 0.8260 0.5540 0.0320 0.254 Uiso 1 calc 1 R . .
H13B H 0.9153 0.5443 0.0661 0.254 Uiso 1 calc 1 R . .
H13C H 0.8055 0.5398 0.0881 0.254 Uiso 1 calc 1 R . .
C14 C 0.8289(19) 0.4036(9) 0.0039(5) 0.194(11) Uani 1 d 1 . . .
H14A H 0.8181 0.4403 -0.0208 0.291 Uiso 1 calc 1 R . .
H14B H 0.7869 0.3394 -0.0052 0.291 Uiso 1 calc 1 R . .
H14C H 0.9036 0.4124 0.0063 0.291 Uiso 1 calc 1 R . .
C15 C 0.8049(5) 0.0563(4) 0.2506(2) 0.0226(14) Uani 1 d 1 . . .
C16 C 0.7732(5) -0.0271(4) 0.2489(2) 0.0235(14) Uani 1 d 1 . . .
C17 C 0.7293(5) -0.1210(5) 0.2457(3) 0.0310(16) Uani 1 d 1 . . .
C18 C 0.6870(6) -0.2027(5) 0.2425(3) 0.0353(17) Uani 1 d 1 . . .
C19 C 0.6269(6) -0.3020(5) 0.2368(3) 0.045(2) Uani 1 d 1 . . .
H19 H 0.6785 -0.3326 0.2315 0.054 Uiso 1 calc 1 R . .
C20 C 0.5534(6) -0.3266(5) 0.1922(3) 0.055(2) Uani 1 d 1 . . .
H20A H 0.5944 -0.3048 0.1638 0.082 Uiso 1 calc 1 R . .
H20B H 0.5012 -0.2981 0.1967 0.082 Uiso 1 calc 1 R . .
H20C H 0.5173 -0.3926 0.1874 0.082 Uiso 1 calc 1 R . .
C21 C 0.5685(7) -0.3347(6) 0.2814(4) 0.061(3) Uani 1 d 1 . . .
H21A H 0.6184 -0.3183 0.3093 0.091 Uiso 1 calc 1 R . .
H21B H 0.5325 -0.4008 0.2771 0.091 Uiso 1 calc 1 R . .
H21C H 0.5165 -0.3064 0.2872 0.091 Uiso 1 calc 1 R . .
C22 C 0.9071(5) 0.5848(4) 0.2271(3) 0.0309(16) Uani 1 d 1 . . .
C23 C 0.8936(6) 0.6654(5) 0.2437(3) 0.0361(17) Uani 1 d 1 . . .
H23 H 0.8543 0.6675 0.2717 0.043 Uiso 1 calc 1 R . .
C24 C 0.9381(7) 0.7420(5) 0.2189(3) 0.052(2) Uani 1 d 1 . . .
H24 H 0.9283 0.7964 0.2298 0.062 Uiso 1 calc 1 R . .
C25 C 0.9967(7) 0.7403(5) 0.1784(3) 0.049(2) Uani 1 d 1 . . .
H25 H 1.0265 0.7930 0.1616 0.059 Uiso 1 calc 1 R . .
C26 C 1.0113(6) 0.6615(6) 0.1628(3) 0.051(2) Uani 1 d 1 . . .
H26 H 1.0523 0.6602 0.1354 0.062 Uiso 1 calc 1 R . .
C27 C 0.9662(6) 0.5839(5) 0.1871(3) 0.0386(18) Uani 1 d 1 . . .
H27 H 0.9763 0.5297 0.1759 0.046 Uiso 1 calc 1 R . .
C28 C 0.7086(5) 0.4372(5) 0.2195(3) 0.0318(16) Uani 1 d 1 . . .
C29 C 0.6840(6) 0.4842(5) 0.1846(3) 0.0398(18) Uani 1 d 1 . . .
H29 H 0.7364 0.5381 0.1751 0.048 Uiso 1 calc 1 R . .
C30 C 0.5836(7) 0.4533(6) 0.1634(3) 0.055(2) Uani 1 d 1 . . .
H30 H 0.5683 0.4846 0.1384 0.066 Uiso 1 calc 1 R . .
C31 C 0.5061(6) 0.3776(6) 0.1783(4) 0.056(3) Uani 1 d 1 . . .
H31 H 0.4360 0.3595 0.1655 0.068 Uiso 1 calc 1 R . .
C32 C 0.5290(7) 0.3288(6) 0.2110(4) 0.060(3) Uani 1 d 1 . . .
H32 H 0.4756 0.2752 0.2202 0.072 Uiso 1 calc 1 R . .
C33 C 0.6319(6) 0.3570(5) 0.2317(3) 0.045(2) Uani 1 d 1 . . .
H33 H 0.6486 0.3213 0.2538 0.054 Uiso 1 calc 1 R . .
C34 C 0.8057(6) 0.5050(4) 0.3136(3) 0.0331(17) Uani 1 d 1 . . .
C35 C 0.8701(7) 0.5024(6) 0.3520(3) 0.048(2) Uani 1 d 1 . . .
H35 H 0.9294 0.4863 0.3454 0.058 Uiso 1 calc 1 R . .
C36 C 0.8501(8) 0.5224(6) 0.3989(3) 0.062(3) Uani 1 d 1 . . .
H36 H 0.8962 0.5219 0.4245 0.075 Uiso 1 calc 1 R . .
C37 C 0.7636(7) 0.5432(6) 0.4086(3) 0.054(2) Uani 1 d 1 . . .
H37 H 0.7487 0.5559 0.4412 0.065 Uiso 1 calc 1 R . .
C38 C 0.6972(6) 0.5460(5) 0.3713(3) 0.0418(19) Uani 1 d 1 . . .
H38 H 0.6380 0.5619 0.3785 0.050 Uiso 1 calc 1 R . .
C39 C 0.7163(6) 0.5261(5) 0.3248(3) 0.0388(18) Uani 1 d 1 . . .
H39 H 0.6692 0.5264 0.2996 0.047 Uiso 1 calc 1 R . .
C40 C 1.1896(5) 0.5713(4) 0.2592(2) 0.0280(15) Uani 1 d 1 . . .
C41 C 1.1574(7) 0.5959(5) 0.3032(3) 0.049(2) Uani 1 d 1 . . .
H41 H 1.1076 0.5501 0.3200 0.059 Uiso 1 calc 1 R . .
C42 C 1.1947(8) 0.6849(5) 0.3242(3) 0.059(2) Uani 1 d 1 . . .
H42 H 1.1688 0.7000 0.3541 0.071 Uiso 1 calc 1 R . .
C43 C 1.2693(7) 0.7501(5) 0.3009(3) 0.050(2) Uani 1 d 1 . . .
H43 H 1.2975 0.8108 0.3153 0.060 Uiso 1 calc 1 R . .
C44 C 1.3033(7) 0.7287(5) 0.2573(3) 0.050(2) Uani 1 d 1 . . .
H44 H 1.3546 0.7746 0.2412 0.060 Uiso 1 calc 1 R . .
C45 C 1.2627(6) 0.6395(5) 0.2363(3) 0.0427(19) Uani 1 d 1 . . .
H45 H 1.2861 0.6255 0.2056 0.051 Uiso 1 calc 1 R . .
C46 C 1.1762(5) 0.4445(4) 0.1750(2) 0.0284(15) Uani 1 d 1 . . .
C47 C 1.1002(5) 0.4151(5) 0.1380(3) 0.0346(17) Uani 1 d 1 . . .
H47 H 1.0284 0.4015 0.1454 0.042 Uiso 1 calc 1 R . .
C48 C 1.1264(6) 0.4052(5) 0.0905(3) 0.0414(19) Uani 1 d 1 . . .
H48 H 1.0728 0.3844 0.0656 0.050 Uiso 1 calc 1 R . .
C49 C 1.2302(6) 0.4253(5) 0.0791(3) 0.0432(19) Uani 1 d 1 . . .
H49 H 1.2479 0.4188 0.0463 0.052 Uiso 1 calc 1 R . .
C50 C 1.3075(6) 0.4545(5) 0.1147(3) 0.0408(19) Uani 1 d 1 . . .
H50 H 1.3789 0.4682 0.1067 0.049 Uiso 1 calc 1 R . .
C51 C 1.2816(5) 0.4641(5) 0.1626(3) 0.0373(18) Uani 1 d 1 . . .
H51 H 1.3357 0.4842 0.1873 0.045 Uiso 1 calc 1 R . .
C52 C 1.2193(5) 0.4038(4) 0.2695(2) 0.0243(14) Uani 1 d 1 . . .
C53 C 1.1868(6) 0.3091(5) 0.2676(3) 0.0336(16) Uani 1 d 1 . . .
H53 H 1.1230 0.2718 0.2506 0.040 Uiso 1 calc 1 R . .
C54 C 1.2463(6) 0.2697(5) 0.2902(3) 0.0409(19) Uani 1 d 1 . . .
H54 H 1.2244 0.2055 0.2882 0.049 Uiso 1 calc 1 R . .
C55 C 1.3382(6) 0.3234(6) 0.3159(3) 0.044(2) Uani 1 d 1 . . .
H55 H 1.3780 0.2958 0.3323 0.053 Uiso 1 calc 1 R . .
C56 C 1.3721(6) 0.4161(6) 0.3178(3) 0.048(2) Uani 1 d 1 . . .
H56 H 1.4360 0.4529 0.3348 0.058 Uiso 1 calc 1 R . .
C57 C 1.3121(6) 0.4558(5) 0.2947(3) 0.0420(19) Uani 1 d 1 . . .
H57 H 1.3355 0.5201 0.2962 0.050 Uiso 1 calc 1 R . .
C58 C 0.6792(5) 0.1933(4) 0.4003(2) 0.0287(15) Uani 1 d 1 . . .
C59 C 0.6499(5) 0.2143(5) 0.3570(3) 0.0389(18) Uani 1 d 1 . . .
H59 H 0.6664 0.1892 0.3273 0.047 Uiso 1 calc 1 R . .
C60 C 0.5948(6) 0.2737(6) 0.3573(3) 0.050(2) Uani 1 d 1 . . .
H60 H 0.5725 0.2870 0.3274 0.060 Uiso 1 calc 1 R . .
C61 C 0.5729(6) 0.3121(5) 0.3988(3) 0.0425(19) Uani 1 d 1 . . .
H61 H 0.5380 0.3537 0.3979 0.051 Uiso 1 calc 1 R . .
C62 C 0.6013(7) 0.2908(6) 0.4424(3) 0.054(2) Uani 1 d 1 . . .
H62 H 0.5840 0.3162 0.4717 0.065 Uiso 1 calc 1 R . .
C63 C 0.6553(6) 0.2319(5) 0.4436(3) 0.045(2) Uani 1 d 1 . . .
H63 H 0.6759 0.2181 0.4738 0.054 Uiso 1 calc 1 R . .
C64 C 0.6362(6) 0.0033(5) 0.4068(3) 0.0360(17) Uani 1 d 1 . . .
C65 C 0.5438(7) -0.0026(6) 0.4284(3) 0.055(2) Uani 1 d 1 . . .
H65 H 0.5351 0.0515 0.4410 0.066 Uiso 1 calc 1 R . .
C66 C 0.4628(7) -0.0856(6) 0.4322(4) 0.064(3) Uani 1 d 1 . . .
H66 H 0.3980 -0.0880 0.4456 0.077 Uiso 1 calc 1 R . .
C67 C 0.4766(8) -0.1627(6) 0.4168(4) 0.079(3) Uani 1 d 1 . . .
H67 H 0.4231 -0.2197 0.4214 0.095 Uiso 1 calc 1 R . .
C68 C 0.5691(8) -0.1600(6) 0.3941(5) 0.088(4) Uani 1 d 1 . . .
H68 H 0.5774 -0.2143 0.3817 0.105 Uiso 1 calc 1 R . .
C69 C 0.6478(7) -0.0763(5) 0.3902(3) 0.054(2) Uani 1 d 1 . . .
H69 H 0.7117 -0.0736 0.3757 0.065 Uiso 1 calc 1 R . .
C70 C 0.8150(6) 0.1422(5) 0.4595(2) 0.0316(16) Uani 1 d 1 . . .
C71 C 0.7886(7) 0.0870(6) 0.4973(3) 0.052(2) Uani 1 d 1 . . .
H71 H 0.7326 0.0295 0.4930 0.063 Uiso 1 calc 1 R . .
C72 C 0.8441(9) 0.1157(8) 0.5415(3) 0.075(3) Uani 1 d 1 . . .
H72 H 0.8242 0.0786 0.5677 0.090 Uiso 1 calc 1 R . .
C73 C 0.9264(8) 0.1965(8) 0.5475(3) 0.067(3) Uani 1 d 1 . . .
H73 H 0.9646 0.2154 0.5776 0.080 Uiso 1 calc 1 R . .
C74 C 0.9549(7) 0.2512(7) 0.5100(3) 0.062(3) Uani 1 d 1 . . .
H74 H 1.0123 0.3079 0.5143 0.074 Uiso 1 calc 1 R . .
C75 C 0.8990(6) 0.2231(6) 0.4660(3) 0.049(2) Uani 1 d 1 . . .
H75 H 0.9194 0.2604 0.4400 0.059 Uiso 1 calc 1 R . .
C76 C 0.9376(5) -0.0519(4) 0.3848(2) 0.0264(15) Uani 1 d 1 . . .
C77 C 0.9297(5) -0.0403(5) 0.4350(2) 0.0307(16) Uani 1 d 1 . . .
H77 H 0.9672 0.0168 0.4524 0.037 Uiso 1 calc 1 R . .
C78 C 0.8666(6) -0.1132(5) 0.4592(3) 0.0390(18) Uani 1 d 1 . . .
H78 H 0.8593 -0.1046 0.4931 0.047 Uiso 1 calc 1 R . .
C79 C 0.8147(6) -0.1970(5) 0.4354(3) 0.0416(19) Uani 1 d 1 . . .
H79 H 0.7736 -0.2465 0.4526 0.050 Uiso 1 calc 1 R . .
C80 C 0.8230(6) -0.2083(5) 0.3861(3) 0.0436(19) Uani 1 d 1 . . .
H80 H 0.7873 -0.2664 0.3694 0.052 Uiso 1 calc 1 R . .
C81 C 0.8827(5) -0.1365(4) 0.3603(3) 0.0328(16) Uani 1 d 1 . . .
H81 H 0.8861 -0.1452 0.3262 0.039 Uiso 1 calc 1 R . .
C82 C 1.0570(5) 0.0028(4) 0.2993(2) 0.0251(14) Uani 1 d 1 . . .
C83 C 1.0601(5) 0.0401(5) 0.2557(2) 0.0305(16) Uani 1 d 1 . . .
H83 H 1.0270 0.0826 0.2527 0.037 Uiso 1 calc 1 R . .
C84 C 1.1093(6) 0.0178(5) 0.2169(3) 0.0380(18) Uani 1 d 1 . . .
H84 H 1.1118 0.0456 0.1876 0.046 Uiso 1 calc 1 R . .
C85 C 1.1565(6) -0.0471(5) 0.2204(3) 0.0416(19) Uani 1 d 1 . . .
H85 H 1.1911 -0.0633 0.1936 0.050 Uiso 1 calc 1 R . .
C86 C 1.1514(6) -0.0865(5) 0.2634(3) 0.047(2) Uani 1 d 1 . . .
H86 H 1.1826 -0.1303 0.2661 0.056 Uiso 1 calc 1 R . .
C87 C 1.1021(6) -0.0633(5) 0.3021(3) 0.0370(17) Uani 1 d 1 . . .
H87 H 1.0982 -0.0920 0.3312 0.044 Uiso 1 calc 1 R . .
C88 C 1.1201(5) 0.1188(4) 0.3882(2) 0.0264(15) Uani 1 d 1 . . .
C89 C 1.1262(6) 0.2035(5) 0.4082(3) 0.0393(18) Uani 1 d 1 . . .
H89 H 1.0690 0.2226 0.4034 0.047 Uiso 1 calc 1 R . .
C90 C 1.2142(7) 0.2601(5) 0.4350(3) 0.050(2) Uani 1 d 1 . . .
H90 H 1.2164 0.3172 0.4491 0.059 Uiso 1 calc 1 R . .
C91 C 1.2983(6) 0.2352(5) 0.4416(3) 0.045(2) Uani 1 d 1 . . .
H91 H 1.3589 0.2752 0.4599 0.054 Uiso 1 calc 1 R . .
C92 C 1.2958(6) 0.1536(6) 0.4220(3) 0.053(2) Uani 1 d 1 . . .
H92 H 1.3542 0.1361 0.4268 0.064 Uiso 1 calc 1 R . .
C93 C 1.2059(6) 0.0946(5) 0.3945(3) 0.046(2) Uani 1 d 1 . . .
H93 H 1.2047 0.0379 0.3802 0.055 Uiso 1 calc 1 R . .
C94 C 0.5263(5) 0.0797(4) 0.1125(3) 0.0293(15) Uani 1 d 1 . . .
C95 C 0.5661(5) 0.1752(5) 0.1189(3) 0.0359(17) Uani 1 d 1 . . .
H95 H 0.6095 0.2055 0.1467 0.043 Uiso 1 calc 1 R . .
C96 C 0.5428(6) 0.2255(5) 0.0853(3) 0.0409(19) Uani 1 d 1 . . .
H96 H 0.5695 0.2898 0.0903 0.049 Uiso 1 calc 1 R . .
C97 C 0.4795(6) 0.1809(6) 0.0439(3) 0.0427(19) Uani 1 d 1 . . .
H97 H 0.4640 0.2152 0.0206 0.051 Uiso 1 calc 1 R . .
C98 C 0.4410(6) 0.0897(6) 0.0372(3) 0.045(2) Uani 1 d 1 . . .
H98 H 0.3978 0.0598 0.0093 0.054 Uiso 1 calc 1 R . .
C99 C 0.4642(5) 0.0381(5) 0.0714(3) 0.0394(18) Uani 1 d 1 . . .
H99 H 0.4367 -0.0262 0.0661 0.047 Uiso 1 calc 1 R . .
C100 C 0.4989(5) -0.1016(5) 0.1334(2) 0.0303(16) Uani 1 d 1 . . .
C101 C 0.3930(5) -0.1485(5) 0.1444(3) 0.0356(17) Uani 1 d 1 . . .
H101 H 0.3568 -0.1194 0.1645 0.043 Uiso 1 calc 1 R . .
C102 C 0.3420(6) -0.2383(5) 0.1253(3) 0.046(2) Uani 1 d 1 . . .
H102 H 0.2702 -0.2696 0.1321 0.055 Uiso 1 calc 1 R . .
C103 C 0.3945(6) -0.2829(5) 0.0965(3) 0.0425(19) Uani 1 d 1 . . .
H103 H 0.3597 -0.3446 0.0845 0.051 Uiso 1 calc 1 R . .
C104 C 0.4995(6) -0.2351(5) 0.0857(3) 0.0429(19) Uani 1 d 1 . . .
H104 H 0.5358 -0.2634 0.0651 0.051 Uiso 1 calc 1 R . .
C105 C 0.5499(6) -0.1462(5) 0.1052(3) 0.0383(18) Uani 1 d 1 . . .
H105 H 0.6221 -0.1152 0.0989 0.046 Uiso 1 calc 1 R . .
C106 C 0.5041(5) 0.0293(5) 0.2116(3) 0.0324(16) Uani 1 d 1 . . .
C107 C 0.5194(6) -0.0157(5) 0.2507(3) 0.0413(19) Uani 1 d 1 . . .
H107 H 0.5613 -0.0517 0.2464 0.050 Uiso 1 calc 1 R . .
C108 C 0.4769(6) -0.0099(6) 0.2948(3) 0.051(2) Uani 1 d 1 . . .
H108 H 0.4875 -0.0427 0.3201 0.062 Uiso 1 calc 1 R . .
C109 C 0.4185(7) 0.0438(7) 0.3019(3) 0.060(3) Uani 1 d 1 . . .
H109 H 0.3905 0.0501 0.3327 0.072 Uiso 1 calc 1 R . .
C110 C 0.4006(7) 0.0882(6) 0.2649(4) 0.061(3) Uani 1 d 1 . . .
H110 H 0.3598 0.1249 0.2703 0.074 Uiso 1 calc 1 R . .
C111 C 0.4412(6) 0.0809(5) 0.2187(3) 0.049(2) Uani 1 d 1 . . .
H111 H 0.4260 0.1105 0.1929 0.058 Uiso 1 calc 1 R . .
C112 C 0.8648(5) 0.1075(4) 0.0470(2) 0.0255(14) Uani 1 d 1 . . .
C113 C 0.9452(6) 0.1381(5) 0.0146(3) 0.0373(18) Uani 1 d 1 . . .
H113 H 1.0112 0.1333 0.0211 0.045 Uiso 1 calc 1 R . .
C114 C 0.9306(6) 0.1753(5) -0.0269(3) 0.0429(19) Uani 1 d 1 . . .
H114 H 0.9865 0.1960 -0.0485 0.051 Uiso 1 calc 1 R . .
C115 C 0.8346(6) 0.1826(5) -0.0370(3) 0.044(2) Uani 1 d 1 . . .
H115 H 0.8241 0.2069 -0.0658 0.053 Uiso 1 calc 1 R . .
C116 C 0.7548(6) 0.1544(5) -0.0050(3) 0.0415(19) Uani 1 d 1 . . .
H116 H 0.6896 0.1605 -0.0116 0.050 Uiso 1 calc 1 R . .
C117 C 0.7684(5) 0.1168(5) 0.0371(3) 0.0343(17) Uani 1 d 1 . . .
H117 H 0.7127 0.0976 0.0589 0.041 Uiso 1 calc 1 R . .
C118 C 0.8386(5) -0.0661(4) 0.0823(2) 0.0264(15) Uani 1 d 1 . . .
C119 C 0.8074(5) -0.1021(5) 0.0344(2) 0.0305(16) Uani 1 d 1 . . .
H119 H 0.8118 -0.0629 0.0098 0.037 Uiso 1 calc 1 R . .
C120 C 0.7697(6) -0.1963(5) 0.0230(3) 0.0415(19) Uani 1 d 1 . . .
H120 H 0.7472 -0.2208 -0.0094 0.050 Uiso 1 calc 1 R . .
C121 C 0.7651(6) -0.2534(5) 0.0581(3) 0.044(2) Uani 1 d 1 . . .
H121 H 0.7401 -0.3172 0.0502 0.053 Uiso 1 calc 1 R . .
C122 C 0.7975(6) -0.2167(5) 0.1054(3) 0.0420(19) Uani 1 d 1 . . .
H122 H 0.7954 -0.2559 0.1297 0.050 Uiso 1 calc 1 R . .
C123 C 0.8323(5) -0.1245(5) 0.1175(3) 0.0343(17) Uani 1 d 1 . . .
H123 H 0.8522 -0.1008 0.1502 0.041 Uiso 1 calc 1 R . .
C124 C 1.0223(5) 0.0933(5) 0.1106(2) 0.0273(15) Uani 1 d 1 . . .
C125 C 1.0787(5) 0.0433(5) 0.0909(2) 0.0295(15) Uani 1 d 1 . . .
H125 H 1.0428 -0.0141 0.0735 0.035 Uiso 1 calc 1 R . .
C126 C 1.1889(6) 0.0775(5) 0.0966(3) 0.0381(18) Uani 1 d 1 . . .
H126 H 1.2279 0.0429 0.0836 0.046 Uiso 1 calc 1 R . .
C127 C 1.2402(6) 0.1612(5) 0.1210(3) 0.0422(19) Uani 1 d 1 . . .
H127 H 1.3150 0.1852 0.1240 0.051 Uiso 1 calc 1 R . .
C128 C 1.1840(6) 0.2106(5) 0.1411(3) 0.0430(19) Uani 1 d 1 . . .
H128 H 1.2201 0.2682 0.1583 0.052 Uiso 1 calc 1 R . .
C129 C 1.0757(5) 0.1768(5) 0.1362(3) 0.0332(16) Uani 1 d 1 . . .
H129 H 1.0373 0.2109 0.1505 0.040 Uiso 1 calc 1 R . .
P7 P 0.5000 0.5000 0.5000 0.0533(9) Uani 1 d 2 S T P
F1 F 0.4793(5) 0.4612(4) 0.4445(2) 0.0909(19) Uani 1 d 1 . . .
F2 F 0.5232(7) 0.5971(4) 0.4830(3) 0.117(3) Uani 1 d 1 . . .
F3 F 0.3822(5) 0.4862(7) 0.5028(3) 0.128(3) Uani 1 d 1 . . .
P8 P 0.5000 0.5000 0.0000 0.0411(7) Uani 1 d 2 S T P
F4 F 0.4337(5) 0.4072(4) 0.0213(2) 0.0870(19) Uani 1 d 1 . . .
F5 F 0.4103(6) 0.5354(6) 0.0101(3) 0.150(4) Uani 1 d 1 . . .
F6 F 0.5414(7) 0.5371(5) 0.0524(2) 0.139(4) Uani 1 d 1 . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Ag1 Cu1 123.95(5) . .
P1 Ag1 P2 117.04(6) . .
P2 Ag1 Cu1 119.00(4) . .
C1 Ag1 Cu1 43.77(15) . .
C1 Ag1 P1 120.98(16) . .
C1 Ag1 P2 104.16(15) . .
C1 Ag1 C8 87.0(2) . .
C8 Ag1 Cu1 43.24(15) . .
C8 Ag1 P1 105.31(16) . .
C8 Ag1 P2 119.47(16) . .
P3 Ag2 Cu1 120.65(5) . .
P3 Ag2 P4 115.06(6) . .
P4 Ag2 Cu1 124.29(5) . .
C1 Ag2 Cu1 44.67(15) . .
C1 Ag2 P3 105.47(16) . .
C1 Ag2 P4 119.98(15) . .
C1 Ag2 C15 88.7(2) . .
C15 Ag2 Cu1 44.22(15) . .
C15 Ag2 P3 121.30(14) . .
C15 Ag2 P4 104.41(15) . .
P5 Ag3 Cu1 118.42(5) . .
P6 Ag3 Cu1 120.63(5) . .
P6 Ag3 P5 120.68(6) . .
C8 Ag3 Cu1 43.58(16) . .
C8 Ag3 P5 112.61(16) . .
C8 Ag3 P6 105.61(16) . .
C8 Ag3 C15 87.2(2) . .
C15 Ag3 Cu1 43.65(15) . .
C15 Ag3 P5 107.03(14) . .
C15 Ag3 P6 118.70(15) . .
Ag2 Cu1 Ag1 119.67(3) . .
Ag2 Cu1 Ag3 120.91(3) . .
Ag3 Cu1 Ag1 119.30(3) . .
C1 Cu1 Ag1 59.28(17) . .
C1 Cu1 Ag2 60.39(17) . .
C1 Cu1 Ag3 176.43(19) . .
C8 Cu1 Ag1 59.71(19) . .
C8 Cu1 Ag2 177.2(2) . .
C8 Cu1 Ag3 59.98(19) . .
C8 Cu1 C1 118.9(3) . .
C8 Cu1 C15 120.1(3) . .
C15 Cu1 Ag1 174.74(18) . .
C15 Cu1 Ag2 60.85(18) . .
C15 Cu1 Ag3 60.09(18) . .
C15 Cu1 C1 121.0(2) . .
C22 P1 Ag1 112.3(2) . .
C22 P1 C28 101.7(3) . .
C28 P1 Ag1 119.2(2) . .
C34 P1 Ag1 114.2(2) . .
C34 P1 C22 105.5(3) . .
C34 P1 C28 102.3(3) . .
C40 P2 Ag1 113.6(2) . .
C40 P2 C52 103.2(3) . .
C46 P2 Ag1 114.0(2) . .
C46 P2 C40 105.9(3) . .
C46 P2 C52 102.8(3) . .
C52 P2 Ag1 115.9(2) . .
C58 P3 Ag2 116.9(2) . .
C58 P3 C64 103.5(3) . .
C58 P3 C70 101.6(3) . .
C64 P3 Ag2 117.8(2) . .
C64 P3 C70 104.4(3) . .
C70 P3 Ag2 110.8(2) . .
C76 P4 Ag2 107.8(2) . .
C76 P4 C88 105.4(3) . .
C82 P4 Ag2 117.9(2) . .
C82 P4 C76 104.4(3) . .
C82 P4 C88 103.1(3) . .
C88 P4 Ag2 116.9(2) . .
C94 P5 Ag3 111.3(2) . .
C94 P5 C100 103.7(3) . .
C100 P5 Ag3 119.7(2) . .
C106 P5 Ag3 111.8(2) . .
C106 P5 C94 106.0(3) . .
C106 P5 C100 103.1(3) . .
C112 P6 Ag3 112.3(2) . .
C112 P6 C118 105.1(3) . .
C112 P6 C124 102.4(3) . .
C118 P6 Ag3 110.7(2) . .
C118 P6 C124 103.4(3) . .
C124 P6 Ag3 121.5(2) . .
Ag2 C1 Ag1 151.9(3) . .
Cu1 C1 Ag1 77.0(2) . .
Cu1 C1 Ag2 74.94(19) . .
C2 C1 Ag1 99.0(4) . .
C2 C1 Ag2 108.9(5) . .
C2 C1 Cu1 172.5(6) . .
C1 C2 C3 177.1(7) . .
C4 C3 C2 178.5(9) . .
C3 C4 C5 176.6(9) . .
C4 C5 H5 107.2 . .
C4 C5 C6 111.4(8) . .
C4 C5 C7 111.3(8) . .
C6 C5 H5 107.2 . .
C7 C5 H5 107.2 . .
C7 C5 C6 112.3(9) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6B 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C5 C7 H7A 109.5 . .
C5 C7 H7B 109.5 . .
C5 C7 H7C 109.5 . .
H7A C7 H7B 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
Ag3 C8 Ag1 152.6(3) . .
Cu1 C8 Ag1 77.1(2) . .
Cu1 C8 Ag3 76.4(2) . .
C9 C8 Ag1 98.3(5) . .
C9 C8 Ag3 108.5(5) . .
C9 C8 Cu1 174.5(6) . .
C8 C9 C10 177.6(7) . .
C11 C10 C9 177.3(9) . .
C10 C11 C12 179.4(10) . .
C11 C12 H12 105.0 . .
C13 C12 C11 114.7(9) . .
C13 C12 H12 105.0 . .
C14 C12 C11 112.9(10) . .
C14 C12 H12 105.0 . .
C14 C12 C13 112.9(11) . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13B 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C12 C14 H14A 109.5 . .
C12 C14 H14B 109.5 . .
C12 C14 H14C 109.5 . .
H14A C14 H14B 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Ag2 C15 Ag3 151.1(3) . .
Cu1 C15 Ag2 74.9(2) . .
Cu1 C15 Ag3 76.3(2) . .
C16 C15 Ag2 107.3(5) . .
C16 C15 Ag3 101.6(5) . .
C16 C15 Cu1 177.8(5) . .
C15 C16 C17 175.1(7) . .
C18 C17 C16 177.3(7) . .
C17 C18 C19 175.0(7) . .
C18 C19 H19 107.8 . .
C18 C19 C20 109.7(6) . .
C18 C19 C21 111.6(7) . .
C20 C19 H19 107.8 . .
C21 C19 H19 107.8 . .
C21 C19 C20 111.8(7) . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20B 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C19 C21 H21A 109.5 . .
C19 C21 H21B 109.5 . .
C19 C21 H21C 109.5 . .
H21A C21 H21B 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C23 C22 P1 123.0(6) . .
C27 C22 P1 117.3(5) . .
C27 C22 C23 119.4(6) . .
C22 C23 H23 120.3 . .
C24 C23 C22 119.3(7) . .
C24 C23 H23 120.3 . .
C23 C24 H24 119.5 . .
C25 C24 C23 120.9(8) . .
C25 C24 H24 119.5 . .
C24 C25 H25 120.3 . .
C26 C25 C24 119.5(7) . .
C26 C25 H25 120.3 . .
C25 C26 H26 119.9 . .
C25 C26 C27 120.2(8) . .
C27 C26 H26 119.9 . .
C22 C27 C26 120.7(7) . .
C22 C27 H27 119.7 . .
C26 C27 H27 119.7 . .
C29 C28 P1 123.6(6) . .
C29 C28 C33 118.9(7) . .
C33 C28 P1 117.5(6) . .
C28 C29 H29 119.7 . .
C28 C29 C30 120.5(8) . .
C30 C29 H29 119.7 . .
C29 C30 H30 119.9 . .
C31 C30 C29 120.1(8) . .
C31 C30 H30 119.9 . .
C30 C31 H31 119.8 . .
C32 C31 C30 120.4(8) . .
C32 C31 H31 119.8 . .
C31 C32 H32 119.8 . .
C31 C32 C33 120.3(8) . .
C33 C32 H32 119.8 . .
C28 C33 C32 119.6(8) . .
C28 C33 H33 120.2 . .
C32 C33 H33 120.2 . .
C35 C34 P1 118.6(6) . .
C35 C34 C39 117.6(7) . .
C39 C34 P1 123.8(6) . .
C34 C35 H35 119.2 . .
C36 C35 C34 121.6(8) . .
C36 C35 H35 119.2 . .
C35 C36 H36 120.2 . .
C37 C36 C35 119.5(9) . .
C37 C36 H36 120.2 . .
C36 C37 H37 119.7 . .
C36 C37 C38 120.5(8) . .
C38 C37 H37 119.7 . .
C37 C38 H38 119.8 . .
C39 C38 C37 120.3(8) . .
C39 C38 H38 119.8 . .
C34 C39 H39 119.8 . .
C38 C39 C34 120.4(8) . .
C38 C39 H39 119.8 . .
C41 C40 P2 117.4(5) . .
C41 C40 C45 116.6(7) . .
C45 C40 P2 125.9(6) . .
C40 C41 H41 118.6 . .
C40 C41 C42 122.9(8) . .
C42 C41 H41 118.6 . .
C41 C42 H42 120.8 . .
C43 C42 C41 118.5(8) . .
C43 C42 H42 120.8 . .
C42 C43 H43 119.7 . .
C44 C43 C42 120.6(8) . .
C44 C43 H43 119.7 . .
C43 C44 H44 120.1 . .
C43 C44 C45 119.9(7) . .
C45 C44 H44 120.1 . .
C40 C45 C44 121.5(7) . .
C40 C45 H45 119.3 . .
C44 C45 H45 119.3 . .
C47 C46 P2 119.2(5) . .
C47 C46 C51 117.7(7) . .
C51 C46 P2 123.0(5) . .
C46 C47 H47 119.4 . .
C48 C47 C46 121.3(7) . .
C48 C47 H47 119.4 . .
C47 C48 H48 119.9 . .
C47 C48 C49 120.1(7) . .
C49 C48 H48 119.9 . .
C48 C49 H49 119.9 . .
C50 C49 C48 120.3(7) . .
C50 C49 H49 119.9 . .
C49 C50 H50 120.0 . .
C49 C50 C51 119.9(7) . .
C51 C50 H50 120.0 . .
C46 C51 H51 119.7 . .
C50 C51 C46 120.7(7) . .
C50 C51 H51 119.7 . .
C53 C52 P2 117.6(5) . .
C57 C52 P2 124.2(5) . .
C57 C52 C53 118.2(6) . .
C52 C53 H53 119.7 . .
C54 C53 C52 120.5(7) . .
C54 C53 H53 119.7 . .
C53 C54 H54 119.9 . .
C53 C54 C55 120.1(7) . .
C55 C54 H54 119.9 . .
C54 C55 H55 119.8 . .
C56 C55 C54 120.3(7) . .
C56 C55 H55 119.8 . .
C55 C56 H56 120.3 . .
C55 C56 C57 119.5(7) . .
C57 C56 H56 120.3 . .
C52 C57 C56 121.3(7) . .
C52 C57 H57 119.4 . .
C56 C57 H57 119.4 . .
C59 C58 P3 118.8(5) . .
C59 C58 C63 119.7(6) . .
C63 C58 P3 121.5(5) . .
C58 C59 H59 120.6 . .
C58 C59 C60 118.7(7) . .
C60 C59 H59 120.6 . .
C59 C60 H60 119.0 . .
C61 C60 C59 122.0(8) . .
C61 C60 H60 119.0 . .
C60 C61 H61 120.2 . .
C60 C61 C62 119.5(7) . .
C62 C61 H61 120.2 . .
C61 C62 H62 119.9 . .
C61 C62 C63 120.3(8) . .
C63 C62 H62 119.9 . .
C58 C63 H63 120.1 . .
C62 C63 C58 119.7(7) . .
C62 C63 H63 120.1 . .
C65 C64 P3 123.2(6) . .
C65 C64 C69 117.9(7) . .
C69 C64 P3 118.8(6) . .
C64 C65 H65 119.2 . .
C64 C65 C66 121.5(8) . .
C66 C65 H65 119.2 . .
C65 C66 H66 120.2 . .
C67 C66 C65 119.6(9) . .
C67 C66 H66 120.2 . .
C66 C67 H67 119.6 . .
C66 C67 C68 120.8(8) . .
C68 C67 H67 119.6 . .
C67 C68 H68 120.9 . .
C69 C68 C67 118.2(9) . .
C69 C68 H68 120.9 . .
C64 C69 C68 121.8(8) . .
C64 C69 H69 119.1 . .
C68 C69 H69 119.1 . .
C71 C70 P3 123.5(6) . .
C75 C70 P3 117.8(6) . .
C75 C70 C71 118.7(7) . .
C70 C71 H71 119.9 . .
C70 C71 C72 120.1(9) . .
C72 C71 H71 119.9 . .
C71 C72 H72 119.9 . .
C73 C72 C71 120.2(9) . .
C73 C72 H72 119.9 . .
C72 C73 H73 119.8 . .
C72 C73 C74 120.3(9) . .
C74 C73 H73 119.8 . .
C73 C74 H74 120.2 . .
C73 C74 C75 119.5(9) . .
C75 C74 H74 120.2 . .
C70 C75 C74 121.0(8) . .
C70 C75 H75 119.5 . .
C74 C75 H75 119.5 . .
C77 C76 P4 120.0(5) . .
C81 C76 P4 120.2(5) . .
C81 C76 C77 119.1(6) . .
C76 C77 H77 120.4 . .
C78 C77 C76 119.3(6) . .
C78 C77 H77 120.4 . .
C77 C78 H78 119.1 . .
C79 C78 C77 121.7(7) . .
C79 C78 H78 119.1 . .
C78 C79 H79 120.6 . .
C78 C79 C80 118.9(7) . .
C80 C79 H79 120.6 . .
C79 C80 H80 119.3 . .
C79 C80 C81 121.3(7) . .
C81 C80 H80 119.3 . .
C76 C81 H81 120.2 . .
C80 C81 C76 119.6(7) . .
C80 C81 H81 120.2 . .
C83 C82 P4 118.3(5) . .
C83 C82 C87 118.0(6) . .
C87 C82 P4 123.6(5) . .
C82 C83 H83 119.0 . .
C84 C83 C82 122.0(7) . .
C84 C83 H83 119.0 . .
C83 C84 H84 120.2 . .
C83 C84 C85 119.6(7) . .
C85 C84 H84 120.2 . .
C84 C85 H85 120.6 . .
C86 C85 C84 118.9(7) . .
C86 C85 H85 120.6 . .
C85 C86 H86 119.5 . .
C87 C86 C85 121.0(7) . .
C87 C86 H86 119.5 . .
C82 C87 H87 119.8 . .
C86 C87 C82 120.5(7) . .
C86 C87 H87 119.8 . .
C89 C88 P4 119.0(5) . .
C93 C88 P4 122.8(5) . .
C93 C88 C89 118.1(7) . .
C88 C89 H89 119.6 . .
C90 C89 C88 120.8(7) . .
C90 C89 H89 119.6 . .
C89 C90 H90 119.6 . .
C91 C90 C89 120.8(7) . .
C91 C90 H90 119.6 . .
C90 C91 H91 119.9 . .
C92 C91 C90 120.2(7) . .
C92 C91 H91 119.9 . .
C91 C92 H92 120.1 . .
C91 C92 C93 119.8(8) . .
C93 C92 H92 120.1 . .
C88 C93 C92 120.4(7) . .
C88 C93 H93 119.8 . .
C92 C93 H93 119.8 . .
C95 C94 P5 118.7(5) . .
C99 C94 P5 123.3(5) . .
C99 C94 C95 117.8(7) . .
C94 C95 H95 119.6 . .
C96 C95 C94 120.9(7) . .
C96 C95 H95 119.6 . .
C95 C96 H96 120.1 . .
C95 C96 C97 119.8(7) . .
C97 C96 H96 120.1 . .
C96 C97 H97 120.0 . .
C98 C97 C96 119.9(7) . .
C98 C97 H97 120.0 . .
C97 C98 H98 119.8 . .
C97 C98 C99 120.5(7) . .
C99 C98 H98 119.8 . .
C94 C99 C98 121.1(7) . .
C94 C99 H99 119.5 . .
C98 C99 H99 119.5 . .
C101 C100 P5 121.3(5) . .
C105 C100 P5 119.6(5) . .
C105 C100 C101 119.1(7) . .
C100 C101 H101 120.4 . .
C102 C101 C100 119.2(7) . .
C102 C101 H101 120.4 . .
C101 C102 H102 119.4 . .
C101 C102 C103 121.2(7) . .
C103 C102 H102 119.4 . .
C102 C103 H103 120.6 . .
C102 C103 C104 118.8(7) . .
C104 C103 H103 120.6 . .
C103 C104 H104 120.2 . .
C105 C104 C103 119.6(7) . .
C105 C104 H104 120.2 . .
C100 C105 C104 122.0(7) . .
C100 C105 H105 119.0 . .
C104 C105 H105 119.0 . .
C107 C106 P5 118.2(5) . .
C111 C106 P5 124.4(6) . .
C111 C106 C107 117.5(7) . .
C106 C107 H107 118.5 . .
C108 C107 C106 123.0(8) . .
C108 C107 H107 118.5 . .
C107 C108 H108 120.5 . .
C107 C108 C109 119.1(9) . .
C109 C108 H108 120.5 . .
C108 C109 H109 120.0 . .
C110 C109 C108 120.1(8) . .
C110 C109 H109 120.0 . .
C109 C110 H110 119.2 . .
C109 C110 C111 121.7(8) . .
C111 C110 H110 119.2 . .
C106 C111 C110 118.7(8) . .
C106 C111 H111 120.7 . .
C110 C111 H111 120.7 . .
C113 C112 P6 123.0(5) . .
C113 C112 C117 118.4(6) . .
C117 C112 P6 118.5(5) . .
C112 C113 H113 119.5 . .
C114 C113 C112 121.0(7) . .
C114 C113 H113 119.5 . .
C113 C114 H114 119.9 . .
C113 C114 C115 120.2(7) . .
C115 C114 H114 119.9 . .
C114 C115 H115 120.2 . .
C116 C115 C114 119.7(7) . .
C116 C115 H115 120.2 . .
C115 C116 H116 119.6 . .
C115 C116 C117 120.7(7) . .
C117 C116 H116 119.6 . .
C112 C117 H117 120.0 . .
C116 C117 C112 119.9(6) . .
C116 C117 H117 120.0 . .
C119 C118 P6 122.8(5) . .
C123 C118 P6 117.8(5) . .
C123 C118 C119 119.2(6) . .
C118 C119 H119 120.2 . .
C120 C119 C118 119.7(7) . .
C120 C119 H119 120.2 . .
C119 C120 H120 119.7 . .
C121 C120 C119 120.6(7) . .
C121 C120 H120 119.7 . .
C120 C121 H121 120.4 . .
C120 C121 C122 119.1(7) . .
C122 C121 H121 120.4 . .
C121 C122 H122 119.5 . .
C123 C122 C121 121.1(7) . .
C123 C122 H122 119.5 . .
C118 C123 H123 119.9 . .
C122 C123 C118 120.3(7) . .
C122 C123 H123 119.9 . .
C125 C124 P6 121.9(5) . .
C125 C124 C129 119.5(6) . .
C129 C124 P6 118.6(5) . .
C124 C125 H125 120.1 . .
C124 C125 C126 119.8(7) . .
C126 C125 H125 120.1 . .
C125 C126 H126 120.1 . .
C127 C126 C125 119.7(7) . .
C127 C126 H126 120.1 . .
C126 C127 H127 119.8 . .
C126 C127 C128 120.5(7) . .
C128 C127 H127 119.8 . .
C127 C128 H128 119.9 . .
C129 C128 C127 120.1(7) . .
C129 C128 H128 119.9 . .
C124 C129 H129 119.8 . .
C128 C129 C124 120.4(7) . .
C128 C129 H129 119.8 . .
F1 P7 F1 179.999(2) . 2_666
F2 P7 F1 92.0(3) 2_666 .
F2 P7 F1 88.0(3) 2_666 2_666
F2 P7 F1 92.0(3) . 2_666
F2 P7 F1 88.0(3) . .
F2 P7 F2 180.0(5) . 2_666
F3 P7 F1 91.1(4) 2_666 .
F3 P7 F1 88.9(4) 2_666 2_666
F3 P7 F1 88.9(4) . .
F3 P7 F1 91.1(4) . 2_666
F3 P7 F2 90.9(5) . 2_666
F3 P7 F2 90.9(5) 2_666 .
F3 P7 F2 89.1(5) . .
F3 P7 F2 89.1(5) 2_666 2_666
F3 P7 F3 180.0(7) . 2_666
F4 P8 F4 180.0(3) . 2_665
F5 P8 F4 90.6(4) . .
F5 P8 F4 90.6(4) 2_665 2_665
F5 P8 F4 89.4(4) 2_665 .
F5 P8 F4 89.4(4) . 2_665
F5 P8 F5 179.996(2) . 2_665
F6 P8 F4 86.9(4) 2_665 2_665
F6 P8 F4 93.1(4) . 2_665
F6 P8 F4 93.1(4) 2_665 .
F6 P8 F4 86.9(4) . .
F6 P8 F5 87.1(5) . .
F6 P8 F5 87.1(5) 2_665 2_665
F6 P8 F5 92.9(6) . 2_665
F6 P8 F5 92.9(6) 2_665 .
F6 P8 F6 180.0(7) . 2_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 Cu1 2.7837(9) .
Ag1 P1 2.4940(18) .
Ag1 P2 2.4977(17) .
Ag1 C1 2.456(6) .
Ag1 C8 2.466(6) .
Ag2 Cu1 2.7147(9) .
Ag2 P3 2.4905(18) .
Ag2 P4 2.5001(17) .
Ag2 C1 2.444(6) .
Ag2 C15 2.455(6) .
Ag3 Cu1 2.7595(9) .
Ag3 P5 2.5068(17) .
Ag3 P6 2.4833(17) .
Ag3 C8 2.458(6) .
Ag3 C15 2.462(6) .
Cu1 C1 1.977(6) .
Cu1 C8 1.957(7) .
Cu1 C15 1.961(6) .
P1 C22 1.833(7) .
P1 C28 1.845(7) .
P1 C34 1.831(7) .
P2 C40 1.832(7) .
P2 C46 1.823(7) .
P2 C52 1.839(7) .
P3 C58 1.833(7) .
P3 C64 1.836(7) .
P3 C70 1.842(7) .
P4 C76 1.832(6) .
P4 C82 1.830(7) .
P4 C88 1.846(7) .
P5 C94 1.825(7) .
P5 C100 1.834(7) .
P5 C106 1.824(7) .
P6 C112 1.830(7) .
P6 C118 1.831(7) .
P6 C124 1.843(7) .
C1 C2 1.224(9) .
C2 C3 1.379(9) .
C3 C4 1.205(10) .
C4 C5 1.477(11) .
C5 H5 1.0000 .
C5 C6 1.516(13) .
C5 C7 1.491(14) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 C9 1.229(9) .
C9 C10 1.406(9) .
C10 C11 1.182(10) .
C11 C12 1.493(11) .
C12 H12 1.0000 .
C12 C13 1.395(15) .
C12 C14 1.389(17) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C16 1.231(8) .
C16 C17 1.386(9) .
C17 C18 1.207(9) .
C18 C19 1.481(10) .
C19 H19 1.0000 .
C19 C20 1.521(12) .
C19 C21 1.499(12) .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 C23 1.406(10) .
C22 C27 1.378(10) .
C23 H23 0.9500 .
C23 C24 1.387(10) .
C24 H24 0.9500 .
C24 C25 1.386(12) .
C25 H25 0.9500 .
C25 C26 1.377(12) .
C26 H26 0.9500 .
C26 C27 1.392(10) .
C27 H27 0.9500 .
C28 C29 1.382(10) .
C28 C33 1.388(10) .
C29 H29 0.9500 .
C29 C30 1.385(11) .
C30 H30 0.9500 .
C30 C31 1.375(12) .
C31 H31 0.9500 .
C31 C32 1.348(13) .
C32 H32 0.9500 .
C32 C33 1.411(12) .
C33 H33 0.9500 .
C34 C35 1.392(11) .
C34 C39 1.412(10) .
C35 H35 0.9500 .
C35 C36 1.366(12) .
C36 H36 0.9500 .
C36 C37 1.362(12) .
C37 H37 0.9500 .
C37 C38 1.388(12) .
C38 H38 0.9500 .
C38 C39 1.352(10) .
C39 H39 0.9500 .
C40 C41 1.376(10) .
C40 C45 1.377(9) .
C41 H41 0.9500 .
C41 C42 1.391(11) .
C42 H42 0.9500 .
C42 C43 1.367(12) .
C43 H43 0.9500 .
C43 C44 1.359(12) .
C44 H44 0.9500 .
C44 C45 1.394(10) .
C45 H45 0.9500 .
C46 C47 1.380(9) .
C46 C51 1.408(9) .
C47 H47 0.9500 .
C47 C48 1.378(10) .
C48 H48 0.9500 .
C48 C49 1.378(10) .
C49 H49 0.9500 .
C49 C50 1.363(11) .
C50 H50 0.9500 .
C50 C51 1.388(10) .
C51 H51 0.9500 .
C52 C53 1.402(9) .
C52 C57 1.379(10) .
C53 H53 0.9500 .
C53 C54 1.373(10) .
C54 H54 0.9500 .
C54 C55 1.383(11) .
C55 H55 0.9500 .
C55 C56 1.371(11) .
C56 H56 0.9500 .
C56 C57 1.389(10) .
C57 H57 0.9500 .
C58 C59 1.369(10) .
C58 C63 1.401(10) .
C59 H59 0.9500 .
C59 C60 1.410(11) .
C60 H60 0.9500 .
C60 C61 1.344(11) .
C61 H61 0.9500 .
C61 C62 1.374(12) .
C62 H62 0.9500 .
C62 C63 1.393(10) .
C63 H63 0.9500 .
C64 C65 1.376(11) .
C64 C69 1.376(10) .
C65 H65 0.9500 .
C65 C66 1.389(11) .
C66 H66 0.9500 .
C66 C67 1.346(13) .
C67 H67 0.9500 .
C67 C68 1.402(14) .
C68 H68 0.9500 .
C68 C69 1.383(12) .
C69 H69 0.9500 .
C70 C71 1.386(10) .
C70 C75 1.370(11) .
C71 H71 0.9500 .
C71 C72 1.391(13) .
C72 H72 0.9500 .
C72 C73 1.357(14) .
C73 H73 0.9500 .
C73 C74 1.374(14) .
C74 H74 0.9500 .
C74 C75 1.387(11) .
C75 H75 0.9500 .
C76 C77 1.400(9) .
C76 C81 1.392(9) .
C77 H77 0.9500 .
C77 C78 1.390(9) .
C78 H78 0.9500 .
C78 C79 1.367(10) .
C79 H79 0.9500 .
C79 C80 1.374(11) .
C80 H80 0.9500 .
C80 C81 1.391(10) .
C81 H81 0.9500 .
C82 C83 1.386(9) .
C82 C87 1.410(9) .
C83 H83 0.9500 .
C83 C84 1.362(10) .
C84 H84 0.9500 .
C84 C85 1.414(11) .
C85 H85 0.9500 .
C85 C86 1.384(11) .
C86 H86 0.9500 .
C86 C87 1.367(11) .
C87 H87 0.9500 .
C88 C89 1.389(9) .
C88 C93 1.378(10) .
C89 H89 0.9500 .
C89 C90 1.375(11) .
C90 H90 0.9500 .
C90 C91 1.363(11) .
C91 H91 0.9500 .
C91 C92 1.354(11) .
C92 H92 0.9500 .
C92 C93 1.412(11) .
C93 H93 0.9500 .
C94 C95 1.408(9) .
C94 C99 1.382(10) .
C95 H95 0.9500 .
C95 C96 1.386(10) .
C96 H96 0.9500 .
C96 C97 1.407(11) .
C97 H97 0.9500 .
C97 C98 1.345(11) .
C98 H98 0.9500 .
C98 C99 1.412(11) .
C99 H99 0.9500 .
C100 C101 1.409(9) .
C100 C105 1.371(10) .
C101 H101 0.9500 .
C101 C102 1.394(10) .
C102 H102 0.9500 .
C102 C103 1.395(11) .
C103 H103 0.9500 .
C103 C104 1.400(11) .
C104 H104 0.9500 .
C104 C105 1.386(10) .
C105 H105 0.9500 .
C106 C107 1.403(10) .
C106 C111 1.396(10) .
C107 H107 0.9500 .
C107 C108 1.366(11) .
C108 H108 0.9500 .
C108 C109 1.373(13) .
C109 H109 0.9500 .
C109 C110 1.364(13) .
C110 H110 0.9500 .
C110 C111 1.411(12) .
C111 H111 0.9500 .
C112 C113 1.392(9) .
C112 C117 1.407(9) .
C113 H113 0.9500 .
C113 C114 1.384(10) .
C114 H114 0.9500 .
C114 C115 1.389(11) .
C115 H115 0.9500 .
C115 C116 1.375(11) .
C116 H116 0.9500 .
C116 C117 1.396(10) .
C117 H117 0.9500 .
C118 C119 1.403(9) .
C118 C123 1.384(9) .
C119 H119 0.9500 .
C119 C120 1.400(10) .
C120 H120 0.9500 .
C120 C121 1.373(11) .
C121 H121 0.9500 .
C121 C122 1.393(11) .
C122 H122 0.9500 .
C122 C123 1.376(10) .
C123 H123 0.9500 .
C124 C125 1.383(9) .
C124 C129 1.389(9) .
C125 H125 0.9500 .
C125 C126 1.403(10) .
C126 H126 0.9500 .
C126 C127 1.371(11) .
C127 H127 0.9500 .
C127 C128 1.378(11) .
C128 H128 0.9500 .
C128 C129 1.377(9) .
C129 H129 0.9500 .
P7 F1 1.595(5) 2_666
P7 F1 1.595(5) .
P7 F2 1.571(7) .
P7 F2 1.571(7) 2_666
P7 F3 1.545(6) 2_666
P7 F3 1.545(6) .
P8 F4 1.584(5) 2_665
P8 F4 1.584(5) .
P8 F5 1.544(7) .
P8 F5 1.544(7) 2_665
P8 F6 1.544(6) .
P8 F6 1.544(6) 2_665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
Ag1 Cu1 C1 Ag2 -179.8(2)
Ag1 Cu1 C1 C2 -58(4)
Ag1 Cu1 C8 Ag3 172.8(2)
Ag1 Cu1 C8 C9 -32(6)
Ag1 Cu1 C15 Ag2 97(2)
Ag1 Cu1 C15 Ag3 -85(2)
Ag1 Cu1 C15 C16 -77(14)
Ag1 P1 C22 C23 -150.1(5)
Ag1 P1 C22 C27 36.8(6)
Ag1 P1 C28 C29 -121.6(6)
Ag1 P1 C28 C33 59.6(6)
Ag1 P1 C34 C35 24.5(6)
Ag1 P1 C34 C39 -152.5(5)
Ag1 P2 C40 C41 44.8(6)
Ag1 P2 C40 C45 -137.9(6)
Ag1 P2 C46 C47 10.9(6)
Ag1 P2 C46 C51 -165.8(5)
Ag1 P2 C52 C53 43.6(6)
Ag1 P2 C52 C57 -137.3(6)
Ag1 C1 C2 C3 -44(15)
Ag1 C8 C9 C10 8(19)
Ag2 Cu1 C1 Ag1 179.8(2)
Ag2 Cu1 C1 C2 122(4)
Ag2 Cu1 C8 Ag1 78(4)
Ag2 Cu1 C8 Ag3 -109(4)
Ag2 Cu1 C8 C9 45(9)
Ag2 Cu1 C15 Ag3 178.1(2)
Ag2 Cu1 C15 C16 -174(100)
Ag2 P3 C58 C59 36.5(6)
Ag2 P3 C58 C63 -145.9(5)
Ag2 P3 C64 C65 -156.0(6)
Ag2 P3 C64 C69 25.0(8)
Ag2 P3 C70 C71 -123.8(6)
Ag2 P3 C70 C75 54.7(6)
Ag2 P4 C76 C77 -83.4(5)
Ag2 P4 C76 C81 87.1(5)
Ag2 P4 C82 C83 26.6(6)
Ag2 P4 C82 C87 -157.3(5)
Ag2 P4 C88 C89 5.3(6)
Ag2 P4 C88 C93 -170.5(5)
Ag2 C1 C2 C3 133(15)
Ag2 C15 C16 C17 122(8)
Ag3 Cu1 C1 Ag1 67(3)
Ag3 Cu1 C1 Ag2 -112(3)
Ag3 Cu1 C1 C2 10(7)
Ag3 Cu1 C8 Ag1 -172.8(2)
Ag3 Cu1 C8 C9 155(6)
Ag3 Cu1 C15 Ag2 -178.1(2)
Ag3 Cu1 C15 C16 8(14)
Ag3 P5 C94 C95 -49.9(6)
Ag3 P5 C94 C99 124.3(5)
Ag3 P5 C100 C101 153.7(5)
Ag3 P5 C100 C105 -27.0(7)
Ag3 P5 C106 C107 -61.3(6)
Ag3 P5 C106 C111 117.9(6)
Ag3 P6 C112 C113 151.6(5)
Ag3 P6 C112 C117 -28.9(6)
Ag3 P6 C118 C119 122.1(5)
Ag3 P6 C118 C123 -53.1(5)
Ag3 P6 C124 C125 142.7(5)
Ag3 P6 C124 C129 -40.2(6)
Ag3 C8 C9 C10 -166(18)
Ag3 C15 C16 C17 -56(8)
Cu1 Ag1 P1 C22 -159.1(2)
Cu1 Ag1 P1 C28 -40.4(3)
Cu1 Ag1 P1 C34 80.8(3)
Cu1 Ag1 P2 C40 -157.1(2)
Cu1 Ag1 P2 C46 81.4(2)
Cu1 Ag1 P2 C52 -37.7(2)
Cu1 Ag1 C1 Ag2 0.5(4)
Cu1 Ag1 C1 C2 173.6(6)
Cu1 Ag1 C8 Ag3 -15.3(5)
Cu1 Ag1 C8 C9 177.0(6)
Cu1 Ag2 P3 C58 -22.0(3)
Cu1 Ag2 P3 C64 102.3(3)
Cu1 Ag2 P3 C70 -137.7(2)
Cu1 Ag2 P4 C76 -142.5(2)
Cu1 Ag2 P4 C82 -24.8(2)
Cu1 Ag2 P4 C88 99.0(2)
Cu1 Ag2 C1 Ag1 -0.5(4)
Cu1 Ag2 C1 C2 -173.3(6)
Cu1 Ag2 C15 Ag3 -3.9(4)
Cu1 Ag2 C15 C16 179.8(6)
Cu1 Ag3 P5 C94 103.3(2)
Cu1 Ag3 P5 C100 -135.6(3)
Cu1 Ag3 P5 C106 -15.0(3)
Cu1 Ag3 P6 C112 -111.7(2)
Cu1 Ag3 P6 C118 131.2(2)
Cu1 Ag3 P6 C124 9.9(3)
Cu1 Ag3 C8 Ag1 15.3(5)
Cu1 Ag3 C8 C9 -177.5(6)
Cu1 Ag3 C15 Ag2 3.8(4)
Cu1 Ag3 C15 C16 -179.7(5)
Cu1 C1 C2 C3 13(18)
Cu1 C8 C9 C10 39(23)
Cu1 C15 C16 C17 -64(18)
P1 Ag1 Cu1 Ag2 -101.42(6)
P1 Ag1 Cu1 Ag3 82.59(6)
P1 Ag1 Cu1 C1 -101.2(2)
P1 Ag1 Cu1 C8 75.5(2)
P1 Ag1 Cu1 C15 164(2)
P1 Ag1 P2 C40 23.9(2)
P1 Ag1 P2 C46 -97.5(2)
P1 Ag1 P2 C52 143.3(2)
P1 Ag1 C1 Ag2 108.8(6)
P1 Ag1 C1 Cu1 108.35(16)
P1 Ag1 C1 C2 -78.1(5)
P1 Ag1 C8 Ag3 -138.9(6)
P1 Ag1 C8 Cu1 -123.64(15)
P1 Ag1 C8 C9 53.4(5)
P1 C22 C23 C24 -171.6(6)
P1 C22 C27 C26 172.7(6)
P1 C28 C29 C30 -176.7(6)
P1 C28 C33 C32 174.3(6)
P1 C34 C35 C36 -179.4(7)
P1 C34 C39 C38 179.3(5)
P2 Ag1 Cu1 Ag2 79.72(6)
P2 Ag1 Cu1 Ag3 -96.26(6)
P2 Ag1 Cu1 C1 80.0(2)
P2 Ag1 Cu1 C8 -103.4(2)
P2 Ag1 Cu1 C15 -14(2)
P2 Ag1 P1 C22 19.8(3)
P2 Ag1 P1 C28 138.5(3)
P2 Ag1 P1 C34 -100.3(3)
P2 Ag1 C1 Ag2 -116.9(6)
P2 Ag1 C1 Cu1 -117.36(15)
P2 Ag1 C1 C2 56.2(5)
P2 Ag1 C8 Ag3 86.9(6)
P2 Ag1 C8 Cu1 102.23(18)
P2 Ag1 C8 C9 -80.7(5)
P2 C40 C41 C42 178.3(7)
P2 C40 C45 C44 -176.3(6)
P2 C46 C47 C48 -176.8(6)
P2 C46 C51 C50 177.1(5)
P2 C52 C53 C54 179.0(6)
P2 C52 C57 C56 -179.4(6)
P3 Ag2 Cu1 Ag1 81.12(6)
P3 Ag2 Cu1 Ag3 -102.97(6)
P3 Ag2 Cu1 C1 80.9(2)
P3 Ag2 Cu1 C8 5(4)
P3 Ag2 Cu1 C15 -104.9(2)
P3 Ag2 P4 C76 36.8(2)
P3 Ag2 P4 C82 154.5(2)
P3 Ag2 P4 C88 -81.6(2)
P3 Ag2 C1 Ag1 -118.7(6)
P3 Ag2 C1 Cu1 -118.19(15)
P3 Ag2 C1 C2 68.5(5)
P3 Ag2 C15 Ag3 99.5(5)
P3 Ag2 C15 Cu1 103.33(16)
P3 Ag2 C15 C16 -76.9(5)
P3 C58 C59 C60 176.9(6)
P3 C58 C63 C62 -177.2(6)
P3 C64 C65 C66 179.0(7)
P3 C64 C69 C68 -179.8(9)
P3 C70 C71 C72 -178.7(7)
P3 C70 C75 C74 179.2(6)
P4 Ag2 Cu1 Ag1 -99.59(6)
P4 Ag2 Cu1 Ag3 76.33(6)
P4 Ag2 Cu1 C1 -99.8(2)
P4 Ag2 Cu1 C8 -176(4)
P4 Ag2 Cu1 C15 74.4(2)
P4 Ag2 P3 C58 158.7(2)
P4 Ag2 P3 C64 -77.0(3)
P4 Ag2 P3 C70 43.0(3)
P4 Ag2 C1 Ag1 109.5(6)
P4 Ag2 C1 Cu1 109.98(16)
P4 Ag2 C1 C2 -63.3(5)
P4 Ag2 C15 Ag3 -128.6(5)
P4 Ag2 C15 Cu1 -124.76(13)
P4 Ag2 C15 C16 55.0(5)
P4 C76 C77 C78 169.8(5)
P4 C76 C81 C80 -171.7(6)
P4 C82 C83 C84 173.3(5)
P4 C82 C87 C86 -173.3(6)
P4 C88 C89 C90 -178.2(6)
P4 C88 C93 C92 177.9(6)
P5 Ag3 Cu1 Ag1 -100.88(6)
P5 Ag3 Cu1 Ag2 83.19(6)
P5 Ag3 Cu1 C1 -166(3)
P5 Ag3 Cu1 C8 -93.8(2)
P5 Ag3 Cu1 C15 85.1(2)
P5 Ag3 P6 C112 62.2(2)
P5 Ag3 P6 C118 -54.9(2)
P5 Ag3 P6 C124 -176.2(3)
P5 Ag3 C8 Ag1 123.4(6)
P5 Ag3 C8 Cu1 108.07(16)
P5 Ag3 C8 C9 -69.5(5)
P5 Ag3 C15 Ag2 -109.7(5)
P5 Ag3 C15 Cu1 -113.57(14)
P5 Ag3 C15 C16 66.7(4)
P5 C94 C95 C96 175.0(5)
P5 C94 C99 C98 -174.5(6)
P5 C100 C101 C102 177.6(5)
P5 C100 C105 C104 -176.8(6)
P5 C106 C107 C108 178.4(6)
P5 C106 C111 C110 -176.5(6)
P6 Ag3 Cu1 Ag1 73.17(6)
P6 Ag3 Cu1 Ag2 -102.76(6)
P6 Ag3 Cu1 C1 8(3)
P6 Ag3 Cu1 C8 80.3(2)
P6 Ag3 Cu1 C15 -100.8(2)
P6 Ag3 P5 C94 -70.7(3)
P6 Ag3 P5 C100 50.4(3)
P6 Ag3 P5 C106 171.0(3)
P6 Ag3 C8 Ag1 -102.9(6)
P6 Ag3 C8 Cu1 -118.29(15)
P6 Ag3 C8 C9 64.2(5)
P6 Ag3 C15 Ag2 109.4(5)
P6 Ag3 C15 Cu1 105.53(16)
P6 Ag3 C15 C16 -74.2(4)
P6 C112 C113 C114 178.3(6)
P6 C112 C117 C116 -178.3(6)
P6 C118 C119 C120 -174.7(5)
P6 C118 C123 C122 176.4(5)
P6 C124 C125 C126 176.7(5)
P6 C124 C129 C128 -175.8(6)
C1 Ag1 Cu1 Ag2 -0.2(2)
C1 Ag1 Cu1 Ag3 -176.2(2)
C1 Ag1 Cu1 C8 176.7(3)
C1 Ag1 Cu1 C15 -94(2)
C1 Ag1 P1 C22 148.6(3)
C1 Ag1 P1 C28 -92.7(3)
C1 Ag1 P1 C34 28.5(3)
C1 Ag1 P2 C40 -112.5(3)
C1 Ag1 P2 C46 126.0(3)
C1 Ag1 P2 C52 6.9(3)
C1 Ag1 C8 Ag3 -17.6(6)
C1 Ag1 C8 Cu1 -2.3(2)
C1 Ag1 C8 C9 174.7(5)
C1 Ag2 Cu1 Ag1 0.2(2)
C1 Ag2 Cu1 Ag3 176.1(2)
C1 Ag2 Cu1 C8 -76(4)
C1 Ag2 Cu1 C15 174.2(3)
C1 Ag2 P3 C58 24.1(3)
C1 Ag2 P3 C64 148.4(3)
C1 Ag2 P3 C70 -91.6(3)
C1 Ag2 P4 C76 164.4(3)
C1 Ag2 P4 C82 -77.9(3)
C1 Ag2 P4 C88 45.9(3)
C1 Ag2 C15 Ag3 -7.9(5)
C1 Ag2 C15 Cu1 -4.1(2)
C1 Ag2 C15 C16 175.7(5)
C1 Cu1 C8 Ag1 3.3(3)
C1 Cu1 C8 Ag3 176.1(2)
C1 Cu1 C8 C9 -29(6)
C1 Cu1 C15 Ag2 5.9(3)
C1 Cu1 C15 Ag3 -176.0(2)
C1 Cu1 C15 C16 -168(14)
C1 C2 C3 C4 -60(39)
C2 C3 C4 C5 50(40)
C3 C4 C5 C6 0(15)
C3 C4 C5 C7 126(14)
C8 Ag1 Cu1 Ag2 -176.9(2)
C8 Ag1 Cu1 Ag3 7.1(2)
C8 Ag1 Cu1 C1 -176.7(3)
C8 Ag1 Cu1 C15 89(2)
C8 Ag1 P1 C22 -115.6(3)
C8 Ag1 P1 C28 3.1(3)
C8 Ag1 P1 C34 124.3(3)
C8 Ag1 P2 C40 152.9(3)
C8 Ag1 P2 C46 31.4(3)
C8 Ag1 P2 C52 -87.7(3)
C8 Ag1 C1 Ag2 2.8(6)
C8 Ag1 C1 Cu1 2.3(2)
C8 Ag1 C1 C2 175.9(5)
C8 Ag3 Cu1 Ag1 -7.1(2)
C8 Ag3 Cu1 Ag2 177.0(2)
C8 Ag3 Cu1 C1 -73(3)
C8 Ag3 Cu1 C15 178.9(3)
C8 Ag3 P5 C94 55.1(3)
C8 Ag3 P5 C100 176.2(3)
C8 Ag3 P5 C106 -63.2(3)
C8 Ag3 P6 C112 -66.8(3)
C8 Ag3 P6 C118 176.1(3)
C8 Ag3 P6 C124 54.7(3)
C8 Ag3 C15 Ag2 3.1(5)
C8 Ag3 C15 Cu1 -0.8(2)
C8 Ag3 C15 C16 179.5(5)
C8 Cu1 C1 Ag1 -3.3(3)
C8 Cu1 C1 Ag2 176.9(2)
C8 Cu1 C1 C2 -61(4)
C8 Cu1 C15 Ag2 -177.0(2)
C8 Cu1 C15 Ag3 1.1(3)
C8 Cu1 C15 C16 9(14)
C8 C9 C10 C11 -72(28)
C9 C10 C11 C12 -135(84)
C10 C11 C12 C13 -164(100)
C10 C11 C12 C14 -33(90)
C15 Ag2 Cu1 Ag1 -174.0(2)
C15 Ag2 Cu1 Ag3 1.9(2)
C15 Ag2 Cu1 C1 -174.2(3)
C15 Ag2 Cu1 C8 110(4)
C15 Ag2 P3 C58 -74.0(3)
C15 Ag2 P3 C64 50.2(3)
C15 Ag2 P3 C70 170.3(3)
C15 Ag2 P4 C76 -98.6(3)
C15 Ag2 P4 C82 19.1(3)
C15 Ag2 P4 C88 142.9(3)
C15 Ag2 C1 Ag1 3.6(6)
C15 Ag2 C1 Cu1 4.0(2)
C15 Ag2 C1 C2 -169.2(5)
C15 Ag3 Cu1 Ag1 174.0(2)
C15 Ag3 Cu1 Ag2 -1.9(2)
C15 Ag3 Cu1 C1 108(3)
C15 Ag3 Cu1 C8 -178.9(3)
C15 Ag3 P5 C94 149.3(3)
C15 Ag3 P5 C100 -89.6(3)
C15 Ag3 P5 C106 31.0(3)
C15 Ag3 P6 C112 -162.3(3)
C15 Ag3 P6 C118 80.6(3)
C15 Ag3 P6 C124 -40.7(3)
C15 Ag3 C8 Ag1 16.1(6)
C15 Ag3 C8 Cu1 0.8(2)
C15 Ag3 C8 C9 -176.8(5)
C15 Cu1 C1 Ag1 173.9(2)
C15 Cu1 C1 Ag2 -5.9(3)
C15 Cu1 C1 C2 116(4)
C15 Cu1 C8 Ag1 -173.9(2)
C15 Cu1 C8 Ag3 -1.1(3)
C15 Cu1 C8 C9 154(6)
C15 C16 C17 C18 -6(23)
C16 C17 C18 C19 10(25)
C17 C18 C19 C20 35(10)
C17 C18 C19 C21 -90(10)
C22 P1 C28 C29 2.4(7)
C22 P1 C28 C33 -176.4(6)
C22 P1 C34 C35 -99.4(6)
C22 P1 C34 C39 83.7(6)
C22 C23 C24 C25 -0.8(12)
C23 C22 C27 C26 -0.7(11)
C23 C24 C25 C26 -0.3(13)
C24 C25 C26 C27 1.0(13)
C25 C26 C27 C22 -0.5(12)
C27 C22 C23 C24 1.4(11)
C28 P1 C22 C23 81.3(6)
C28 P1 C22 C27 -91.8(6)
C28 P1 C34 C35 154.7(6)
C28 P1 C34 C39 -22.3(6)
C28 C29 C30 C31 2.8(12)
C29 C28 C33 C32 -4.6(11)
C29 C30 C31 C32 -5.1(13)
C30 C31 C32 C33 2.5(14)
C31 C32 C33 C28 2.4(13)
C33 C28 C29 C30 2.1(11)
C34 P1 C22 C23 -25.1(7)
C34 P1 C22 C27 161.8(6)
C34 P1 C28 C29 111.4(6)
C34 P1 C28 C33 -67.4(6)
C34 C35 C36 C37 1.8(14)
C35 C34 C39 C38 2.3(10)
C35 C36 C37 C38 -1.3(14)
C36 C37 C38 C39 1.4(12)
C37 C38 C39 C34 -1.9(11)
C39 C34 C35 C36 -2.2(12)
C40 P2 C46 C47 -114.8(6)
C40 P2 C46 C51 68.5(6)
C40 P2 C52 C53 168.5(5)
C40 P2 C52 C57 -12.4(7)
C40 C41 C42 C43 -2.4(14)
C41 C40 C45 C44 1.1(11)
C41 C42 C43 C44 2.3(14)
C42 C43 C44 C45 -0.6(13)
C43 C44 C45 C40 -1.2(12)
C45 C40 C41 C42 0.7(12)
C46 P2 C40 C41 170.7(6)
C46 P2 C40 C45 -12.0(7)
C46 P2 C52 C53 -81.5(6)
C46 P2 C52 C57 97.6(6)
C46 C47 C48 C49 -0.5(11)
C47 C46 C51 C50 0.3(10)
C47 C48 C49 C50 0.5(12)
C48 C49 C50 C51 -0.1(12)
C49 C50 C51 C46 -0.3(11)
C51 C46 C47 C48 0.1(10)
C52 P2 C40 C41 -81.6(6)
C52 P2 C40 C45 95.7(7)
C52 P2 C46 C47 137.2(5)
C52 P2 C46 C51 -39.5(6)
C52 C53 C54 C55 1.3(11)
C53 C52 C57 C56 -0.3(11)
C53 C54 C55 C56 -1.9(12)
C54 C55 C56 C57 1.5(12)
C55 C56 C57 C52 -0.4(13)
C57 C52 C53 C54 -0.2(11)
C58 P3 C64 C65 -25.3(8)
C58 P3 C64 C69 155.7(7)
C58 P3 C70 C71 111.3(7)
C58 P3 C70 C75 -70.2(6)
C58 C59 C60 C61 1.9(12)
C59 C58 C63 C62 0.5(12)
C59 C60 C61 C62 -2.4(13)
C60 C61 C62 C63 2.0(13)
C61 C62 C63 C58 -1.0(13)
C63 C58 C59 C60 -0.8(11)
C64 P3 C58 C59 -94.8(6)
C64 P3 C58 C63 82.9(7)
C64 P3 C70 C71 4.0(7)
C64 P3 C70 C75 -177.6(6)
C64 C65 C66 C67 3.6(16)
C65 C64 C69 C68 1.2(14)
C65 C66 C67 C68 -4.2(18)
C66 C67 C68 C69 3.4(19)
C67 C68 C69 C64 -1.8(17)
C69 C64 C65 C66 -2.0(14)
C70 P3 C58 C59 157.2(6)
C70 P3 C58 C63 -25.1(7)
C70 P3 C64 C65 80.7(8)
C70 P3 C64 C69 -98.3(7)
C70 C71 C72 C73 -2.1(15)
C71 C70 C75 C74 -2.2(12)
C71 C72 C73 C74 0.9(16)
C72 C73 C74 C75 -0.3(14)
C73 C74 C75 C70 1.0(13)
C75 C70 C71 C72 2.8(12)
C76 P4 C82 C83 146.2(5)
C76 P4 C82 C87 -37.8(6)
C76 P4 C88 C89 -114.5(6)
C76 P4 C88 C93 69.8(7)
C76 C77 C78 C79 2.3(11)
C77 C76 C81 C80 -1.2(10)
C77 C78 C79 C80 -1.9(11)
C78 C79 C80 C81 -0.1(12)
C79 C80 C81 C76 1.7(11)
C81 C76 C77 C78 -0.7(10)
C82 P4 C76 C77 150.5(5)
C82 P4 C76 C81 -39.0(6)
C82 P4 C88 C89 136.3(6)
C82 P4 C88 C93 -39.4(7)
C82 C83 C84 C85 1.6(11)
C83 C82 C87 C86 2.8(10)
C83 C84 C85 C86 0.1(11)
C84 C85 C86 C87 -0.2(12)
C85 C86 C87 C82 -1.2(12)
C87 C82 C83 C84 -3.1(10)
C88 P4 C76 C77 42.2(6)
C88 P4 C76 C81 -147.3(5)
C88 P4 C82 C83 -103.9(5)
C88 P4 C82 C87 72.2(6)
C88 C89 C90 C91 1.5(12)
C89 C88 C93 C92 2.1(11)
C89 C90 C91 C92 -0.6(13)
C90 C91 C92 C93 0.5(13)
C91 C92 C93 C88 -1.3(13)
C93 C88 C89 C90 -2.2(11)
C94 P5 C100 C101 -81.4(6)
C94 P5 C100 C105 97.9(6)
C94 P5 C106 C107 177.2(5)
C94 P5 C106 C111 -3.6(7)
C94 C95 C96 C97 -0.7(11)
C95 C94 C99 C98 -0.3(10)
C95 C96 C97 C98 0.7(11)
C96 C97 C98 C99 -0.5(11)
C97 C98 C99 C94 0.3(11)
C99 C94 C95 C96 0.5(10)
C100 P5 C94 C95 -180.0(5)
C100 P5 C94 C99 -5.8(7)
C100 P5 C106 C107 68.6(6)
C100 P5 C106 C111 -112.2(6)
C100 C101 C102 C103 1.4(11)
C101 C100 C105 C104 2.5(11)
C101 C102 C103 C104 -1.9(11)
C102 C103 C104 C105 2.6(11)
C103 C104 C105 C100 -2.9(11)
C105 C100 C101 C102 -1.7(10)
C106 P5 C94 C95 71.9(6)
C106 P5 C94 C99 -114.0(6)
C106 P5 C100 C101 28.9(6)
C106 P5 C100 C105 -151.8(6)
C106 C107 C108 C109 -1.6(12)
C107 C106 C111 C110 2.7(11)
C107 C108 C109 C110 2.2(13)
C108 C109 C110 C111 -0.3(14)
C109 C110 C111 C106 -2.2(13)
C111 C106 C107 C108 -0.8(11)
C112 P6 C118 C119 0.7(6)
C112 P6 C118 C123 -174.6(5)
C112 P6 C124 C125 -91.1(6)
C112 P6 C124 C129 86.0(6)
C112 C113 C114 C115 -0.2(12)
C113 C112 C117 C116 1.2(10)
C113 C114 C115 C116 1.4(12)
C114 C115 C116 C117 -1.3(12)
C115 C116 C117 C112 0.0(11)
C117 C112 C113 C114 -1.1(11)
C118 P6 C112 C113 -88.0(6)
C118 P6 C112 C117 91.4(6)
C118 P6 C124 C125 17.9(6)
C118 P6 C124 C129 -165.0(5)
C118 C119 C120 C121 -1.3(10)
C119 C118 C123 C122 1.0(10)
C119 C120 C121 C122 0.6(11)
C120 C121 C122 C123 1.0(11)
C121 C122 C123 C118 -1.8(11)
C123 C118 C119 C120 0.5(10)
C124 P6 C112 C113 19.7(7)
C124 P6 C112 C117 -160.9(5)
C124 P6 C118 C119 -106.3(6)
C124 P6 C118 C123 78.4(5)
C124 C125 C126 C127 -1.2(10)
C125 C124 C129 C128 1.4(10)
C125 C126 C127 C128 1.9(11)
C126 C127 C128 C129 -0.9(12)
C127 C128 C129 C124 -0.8(11)
C129 C124 C125 C126 -0.4(10)
