#------------------------------------------------------------------------------
#$Date: 2019-11-25 16:33:10 +0200 (Mon, 25 Nov 2019) $
#$Revision: 241331 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/13/10/4131020.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4131020
loop_
_publ_author_name
'Hau, Sam C. K.'
'Yeung, Margaret C.-L.'
'Yam, Vivian W.-W.'
'Mak, Thomas C. W.'
_publ_section_title
;
 Assembly of Heterometallic Silver(I)-Copper(I) Alkyl-1,3-diynyl Clusters
 via Inner-Core Expansion.
;
_journal_issue                   41
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              13732
_journal_page_last               13739
_journal_paper_doi               10.1021/jacs.6b08674
_journal_volume                  138
_journal_year                    2016
_chemical_formula_sum            'C132 H138 Ag10 Cu2 O2 P2'
_chemical_formula_weight         3024.14
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.523(2)
_cell_angle_beta                 111.227(2)
_cell_angle_gamma                90.437(2)
_cell_formula_units_Z            1
_cell_length_a                   13.1713(13)
_cell_length_b                   15.8646(15)
_cell_length_c                   17.2421(17)
_cell_measurement_reflns_used    9900
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.98
_cell_measurement_theta_min      2.51
_cell_volume                     3278.1(6)
_computing_cell_refinement       SAINT(Bruker,2001)
_computing_data_collection       APEX2(Bruker,2003)
_computing_data_reduction        APEX2(Bruker,2003)
_computing_molecular_graphics    DIAMOND
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX II CCD diffractometer'
_diffrn_measurement_method       'φ and ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0679
_diffrn_reflns_av_sigmaI/netI    0.0515
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            57456
_diffrn_reflns_theta_full        25.25
_diffrn_reflns_theta_max         25.25
_diffrn_reflns_theta_min         1.30
_exptl_absorpt_coefficient_mu    1.844
_exptl_absorpt_correction_T_max  0.5258
_exptl_absorpt_correction_T_min  0.4591
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.532
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1504
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.40
_refine_diff_density_max         2.141
_refine_diff_density_min         -1.560
_refine_diff_density_rms         0.264
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.072
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     662
_refine_ls_number_reflns         11828
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.074
_refine_ls_R_factor_all          0.0748
_refine_ls_R_factor_gt           0.0705
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1540P)²+3.3150P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1908
_refine_ls_wR_factor_ref         0.2008
_reflns_number_gt                10617
_reflns_number_total             11828
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ja6b08674_si_002.cif
_cod_data_source_block           8
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               4131020
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.89213(5) 1.03127(4) 0.95083(4) 0.02654(17) Uani 1 1 d .
P1 P 0.99790(10) 1.00047(9) 0.70748(8) 0.0285(3) Uani 1 1 d .
Ag1 Ag 0.80812(4) 0.88696(3) 0.97178(3) 0.03871(16) Uani 1 1 d .
Ag2 Ag 0.75222(3) 0.70619(3) 0.92128(3) 0.03803(15) Uani 1 1 d .
Ag3 Ag 0.91788(3) 0.66883(3) 0.85263(3) 0.03843(15) Uani 1 1 d .
Ag4 Ag 1.05036(4) 0.82591(3) 0.92924(3) 0.04383(16) Uani 1 1 d .
Ag5 Ag 1.01148(3) 1.00508(3) 0.85186(2) 0.03327(15) Uani 1 1 d .
C1 C 0.8567(4) 0.9226(3) 0.8644(3) 0.0308(11) Uani 1 1 d .
C2 C 0.8247(4) 0.8630(3) 0.8036(3) 0.0319(11) Uani 1 1 d .
C3 C 0.7905(5) 0.7952(4) 0.7332(4) 0.0412(13) Uani 1 1 d .
C4 C 0.7635(6) 0.7362(4) 0.6736(4) 0.0509(16) Uani 1 1 d .
C5 C 0.7277(8) 0.6656(5) 0.5969(5) 0.068(2) Uani 1 1 d .
C6 C 0.8125(11) 0.5984(6) 0.6108(6) 0.093(3) Uani 1 1 d .
H6A H 0.8837 0.6253 0.6186 0.139 Uiso 1 1 calc R
H6B H 0.7895 0.5502 0.5610 0.139 Uiso 1 1 calc R
H6C H 0.8182 0.5770 0.6616 0.139 Uiso 1 1 calc R
C7 C 0.6174(10) 0.6246(7) 0.5849(7) 0.101(4) Uani 1 1 d .
H7A H 0.5637 0.6677 0.5761 0.152 Uiso 1 1 calc R
H7B H 0.6229 0.6033 0.6357 0.152 Uiso 1 1 calc R
H7C H 0.5940 0.5764 0.5351 0.152 Uiso 1 1 calc R
C8 C 0.7227(13) 0.7013(7) 0.5197(5) 0.112(5) Uani 1 1 d .
H8A H 0.6662 0.7420 0.5087 0.168 Uiso 1 1 calc R
H8B H 0.7051 0.6537 0.4697 0.168 Uiso 1 1 calc R
H8C H 0.7937 0.7312 0.5312 0.168 Uiso 1 1 calc R
C9 C 0.9644(4) 1.1306(3) 0.9337(3) 0.0312(11) Uani 1 1 d .
C10 C 0.9967(4) 1.1962(3) 0.9201(4) 0.0332(11) Uani 1 1 d .
C11 C 1.0336(5) 1.2705(3) 0.9059(4) 0.0364(12) Uani 1 1 d .
C12 C 1.0710(5) 1.3360(4) 0.8961(4) 0.0415(13) Uani 1 1 d .
C13 C 1.1138(5) 1.4156(4) 0.8830(4) 0.0428(14) Uani 1 1 d .
C14 C 1.0869(6) 1.4932(4) 0.9381(5) 0.0531(16) Uani 1 1 d .
H14A H 1.0074 1.4933 0.9211 0.080 Uiso 1 1 calc R
H14B H 1.1164 1.5465 0.9304 0.080 Uiso 1 1 calc R
H14C H 1.1197 1.4897 0.9981 0.080 Uiso 1 1 calc R
C15 C 1.0601(8) 1.4203(5) 0.7895(5) 0.065(2) Uani 1 1 d .
H15A H 1.0761 1.3701 0.7537 0.097 Uiso 1 1 calc R
H15B H 1.0888 1.4733 0.7808 0.097 Uiso 1 1 calc R
H15C H 0.9808 1.4205 0.7740 0.097 Uiso 1 1 calc R
C16 C 1.2372(6) 1.4143(4) 0.9078(6) 0.0584(19) Uani 1 1 d .
H16A H 1.2531 1.3649 0.8710 0.088 Uiso 1 1 calc R
H16B H 1.2708 1.4094 0.9673 0.088 Uiso 1 1 calc R
H16C H 1.2671 1.4679 0.9009 0.088 Uiso 1 1 calc R
C17 C 0.8366(4) 1.0438(3) 1.0438(3) 0.0280(10) Uani 1 1 d .
C18 C 0.7778(4) 1.0464(3) 1.0859(3) 0.0271(10) Uani 1 1 d .
C19 C 0.7024(4) 1.0470(4) 1.1245(3) 0.0350(12) Uani 1 1 d .
C20 C 0.6347(4) 1.0454(4) 1.1545(4) 0.0361(12) Uani 1 1 d .
C21 C 0.5443(5) 1.0417(4) 1.1859(4) 0.0417(13) Uani 1 1 d .
C22 C 0.4405(5) 1.0034(5) 1.1079(4) 0.0498(15) Uani 1 1 d .
H22A H 0.4513 0.9449 1.0822 0.075 Uiso 1 1 calc R
H22B H 0.4261 1.0397 1.0659 0.075 Uiso 1 1 calc R
H22C H 0.3782 1.0012 1.1260 0.075 Uiso 1 1 calc R
C23 C 0.5699(5) 0.9839(6) 1.2504(5) 0.060(2) Uani 1 1 d .
H23A H 0.5801 0.9258 1.2234 0.090 Uiso 1 1 calc R
H23B H 0.5092 0.9809 1.2701 0.090 Uiso 1 1 calc R
H23C H 0.6370 1.0079 1.2991 0.090 Uiso 1 1 calc R
C24 C 0.5261(7) 1.1341(6) 1.2238(6) 0.071(2) Uani 1 1 d .
H24A H 0.5092 1.1686 1.1801 0.106 Uiso 1 1 calc R
H24B H 0.5925 1.1603 1.2721 0.106 Uiso 1 1 calc R
H24C H 0.4650 1.1322 1.2433 0.106 Uiso 1 1 calc R
C25 C 0.6967(5) 0.8061(3) 0.9943(4) 0.0339(11) Uani 1 1 d .
C26 C 0.6257(4) 0.7915(3) 1.0208(4) 0.0339(11) Uani 1 1 d .
C27 C 0.5476(5) 0.7717(4) 1.0500(4) 0.0394(12) Uani 1 1 d .
C28 C 0.4811(5) 0.7505(4) 1.0771(4) 0.0437(14) Uani 1 1 d .
C29 C 0.4004(5) 0.7186(5) 1.1082(4) 0.0498(16) Uani 1 1 d .
C30 C 0.4652(9) 0.7105(7) 1.2010(6) 0.086(3) Uani 1 1 d .
H30A H 0.4933 0.7681 1.2371 0.129 Uiso 1 1 calc R
H30B H 0.5265 0.6754 1.2023 0.129 Uiso 1 1 calc R
H30C H 0.4169 0.6828 1.2222 0.129 Uiso 1 1 calc R
C31 C 0.3567(10) 0.6260(7) 1.0543(7) 0.103(4) Uani 1 1 d .
H31A H 0.3152 0.6287 0.9950 0.154 Uiso 1 1 calc R
H31B H 0.3090 0.5998 1.0770 0.154 Uiso 1 1 calc R
H31C H 0.4184 0.5910 1.0569 0.154 Uiso 1 1 calc R
C32 C 0.3154(9) 0.7789(9) 1.1068(10) 0.128(6) Uani 1 1 d .
H32A H 0.2762 0.7852 1.0483 0.192 Uiso 1 1 calc R
H32B H 0.3497 0.8353 1.1430 0.192 Uiso 1 1 calc R
H32C H 0.2638 0.7562 1.1284 0.192 Uiso 1 1 calc R
C33 C 0.7753(5) 0.5961(4) 0.8433(4) 0.0425(13) Uani 1 1 d .
C34 C 0.7570(5) 0.5234(4) 0.7972(4) 0.0407(13) Uani 1 1 d .
C35 C 0.7370(5) 0.4444(4) 0.7431(4) 0.0466(14) Uani 1 1 d .
C36 C 0.7237(6) 0.3770(4) 0.6939(5) 0.0572(18) Uani 1 1 d .
C37 C 0.7109(8) 0.2957(5) 0.6292(7) 0.079(3) Uani 1 1 d .
C38 C 0.6001(11) 0.2494(8) 0.6051(8) 0.123(5) Uani 1 1 d .
H38A H 0.5432 0.2854 0.5786 0.184 Uiso 1 1 calc R
H38B H 0.5916 0.2379 0.6563 0.184 Uiso 1 1 calc R
H38C H 0.5934 0.1946 0.5647 0.184 Uiso 1 1 calc R
C39 C 0.7057(19) 0.3251(9) 0.5468(10) 0.182(10) Uani 1 1 d .
H39A H 0.6408 0.3565 0.5268 0.273 Uiso 1 1 calc R
H39B H 0.7017 0.2743 0.5025 0.273 Uiso 1 1 calc R
H39C H 0.7714 0.3630 0.5594 0.273 Uiso 1 1 calc R
C40 C 0.8023(13) 0.2411(8) 0.6699(14) 0.200(11) Uani 1 1 d .
H40A H 0.8734 0.2727 0.6848 0.300 Uiso 1 1 calc R
H40B H 0.7965 0.1866 0.6295 0.300 Uiso 1 1 calc R
H40C H 0.7956 0.2292 0.7216 0.300 Uiso 1 1 calc R
C41 C 1.0707(5) 0.7077(3) 0.8518(4) 0.0357(12) Uani 1 1 d .
C42 C 1.1434(5) 0.6767(3) 0.8302(4) 0.0343(11) Uani 1 1 d .
C43 C 1.2260(5) 0.6401(4) 0.8075(4) 0.0443(14) Uani 1 1 d .
C44 C 1.2966(6) 0.6078(4) 0.7891(5) 0.0524(17) Uani 1 1 d .
C45 C 1.3900(6) 0.5691(5) 0.7703(6) 0.065(2) Uani 1 1 d .
C46 C 1.3554(9) 0.4763(7) 0.7235(8) 0.107(4) Uani 1 1 d .
H46A H 1.3407 0.4431 0.7611 0.160 Uiso 1 1 calc R
H46B H 1.4139 0.4519 0.7061 0.160 Uiso 1 1 calc R
H46C H 1.2890 0.4737 0.6729 0.160 Uiso 1 1 calc R
C47 C 1.4811(9) 0.5648(10) 0.8571(10) 0.144(7) Uani 1 1 d .
H47A H 1.4498 0.5366 0.8901 0.217 Uiso 1 1 calc R
H47B H 1.5116 0.6234 0.8891 0.217 Uiso 1 1 calc R
H47C H 1.5391 0.5316 0.8468 0.217 Uiso 1 1 calc R
C48 C 1.4378(16) 0.6252(12) 0.7343(13) 0.166(7) Uani 1 1 d U
H48A H 1.3834 0.6325 0.6801 0.250 Uiso 1 1 calc R
H48B H 1.5008 0.5997 0.7244 0.250 Uiso 1 1 calc R
H48C H 1.4618 0.6815 0.7739 0.250 Uiso 1 1 calc R
C49 C 1.0637(4) 0.9115(3) 0.6656(3) 0.0303(10) Uani 1 1 d .
C50 C 1.1284(4) 0.9212(4) 0.6203(4) 0.0358(12) Uani 1 1 d .
H50A H 1.1401 0.9761 0.6092 0.043 Uiso 1 1 calc R
C51 C 1.1767(5) 0.8505(4) 0.5906(4) 0.0457(14) Uani 1 1 d .
H51A H 1.2219 0.8573 0.5597 0.055 Uiso 1 1 calc R
C52 C 1.1592(6) 0.7713(4) 0.6061(4) 0.0505(16) Uani 1 1 d .
H52A H 1.1918 0.7230 0.5855 0.061 Uiso 1 1 calc R
C53 C 1.0937(7) 0.7616(4) 0.6518(5) 0.0556(18) Uani 1 1 d .
H53A H 1.0805 0.7065 0.6617 0.067 Uiso 1 1 calc R
C54 C 1.0479(5) 0.8320(4) 0.6829(4) 0.0433(13) Uani 1 1 d .
H54A H 1.0056 0.8259 0.7162 0.052 Uiso 1 1 calc R
C55 C 0.8581(4) 0.9840(4) 0.6294(3) 0.0330(11) Uani 1 1 d .
C56 C 0.8339(5) 0.9500(4) 0.5437(4) 0.0414(13) Uani 1 1 d .
H56A H 0.8913 0.9362 0.5236 0.050 Uiso 1 1 calc R
C57 C 0.7258(6) 0.9359(5) 0.4871(5) 0.0543(16) Uani 1 1 d .
H57A H 0.7096 0.9118 0.4284 0.065 Uiso 1 1 calc R
C58 C 0.6425(5) 0.9563(5) 0.5151(5) 0.065(2) Uani 1 1 d .
H58A H 0.5687 0.9467 0.4761 0.078 Uiso 1 1 calc R
C59 C 0.6671(6) 0.9918(6) 0.6025(6) 0.068(2) Uani 1 1 d .
H59A H 0.6097 1.0070 0.6224 0.081 Uiso 1 1 calc R
C60 C 0.7733(5) 1.0044(5) 0.6585(4) 0.0483(15) Uani 1 1 d .
H60A H 0.7895 1.0270 0.7174 0.058 Uiso 1 1 calc R
C61 C 1.0618(4) 1.0945(3) 0.6913(3) 0.0309(11) Uani 1 1 d .
C62 C 1.1617(5) 1.1307(4) 0.7546(4) 0.0405(13) Uani 1 1 d .
H62A H 1.1898 1.1093 0.8053 0.049 Uiso 1 1 calc R
C63 C 1.2198(5) 1.1969(4) 0.7440(4) 0.0472(14) Uani 1 1 d .
H63A H 1.2881 1.2209 0.7869 0.057 Uiso 1 1 calc R
C64 C 1.1784(6) 1.2288(4) 0.6703(4) 0.0486(15) Uani 1 1 d .
H64A H 1.2189 1.2739 0.6623 0.058 Uiso 1 1 calc R
C65 C 1.0787(6) 1.1950(4) 0.6087(4) 0.0478(15) Uani 1 1 d .
H65A H 1.0493 1.2180 0.5591 0.057 Uiso 1 1 calc R
C66 C 1.0213(5) 1.1275(4) 0.6188(4) 0.0393(12) Uani 1 1 d .
H66A H 0.9532 1.1036 0.5755 0.047 Uiso 1 1 calc R
O1W O 0.9718(15) 0.5604(12) 0.4424(11) 0.227(7) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C9 Cu1 C1 119.0(2) . .
C9 Cu1 C17 120.8(2) . .
C1 Cu1 C17 119.6(2) . .
C9 Cu1 Ag4 61.00(16) . 2_777
C1 Cu1 Ag4 177.00(15) . 2_777
C17 Cu1 Ag4 60.89(14) . 2_777
C9 Cu1 Ag1 174.66(15) . .
C1 Cu1 Ag1 57.79(15) . .
C17 Cu1 Ag1 63.16(14) . .
Ag4 Cu1 Ag1 121.92(3) 2_777 .
C9 Cu1 Ag5 60.44(15) . .
C1 Cu1 Ag5 63.07(15) . .
C17 Cu1 Ag5 166.30(14) . .
Ag4 Cu1 Ag5 115.67(2) 2_777 .
Ag1 Cu1 Ag5 114.80(2) . .
C9 Cu1 Cu1 92.50(15) . 2_777
C1 Cu1 Cu1 90.01(15) . 2_777
C17 Cu1 Cu1 94.99(14) . 2_777
Ag4 Cu1 Cu1 87.00(3) 2_777 2_777
Ag1 Cu1 Cu1 83.37(3) . 2_777
Ag5 Cu1 Cu1 71.36(2) . 2_777
C55 P1 C49 103.0(2) . .
C55 P1 C61 106.2(2) . .
C49 P1 C61 102.7(2) . .
C55 P1 Ag5 114.11(18) . .
C49 P1 Ag5 113.63(16) . .
C61 P1 Ag5 115.76(17) . .
C25 Ag1 C1 143.0(2) . .
C25 Ag1 C17 117.84(18) . .
C1 Ag1 C17 89.26(17) . .
C25 Ag1 Cu1 157.82(14) . .
C1 Ag1 Cu1 45.58(13) . .
C17 Ag1 Cu1 44.44(11) . .
C25 Ag1 Ag2 48.21(14) . .
C1 Ag1 Ag2 105.08(13) . .
C17 Ag1 Ag2 165.41(11) . .
Cu1 Ag1 Ag2 150.15(2) . .
C25 Ag1 Ag5 111.57(16) . 2_777
C1 Ag1 Ag5 105.25(14) . 2_777
C17 Ag1 Ag5 47.64(11) . 2_777
Cu1 Ag1 Ag5 68.164(18) . 2_777
Ag2 Ag1 Ag5 128.060(19) . 2_777
C33 Ag2 C25 168.4(2) . .
C33 Ag2 Ag1 141.61(17) . .
C25 Ag2 Ag1 48.28(14) . .
C33 Ag2 Ag3 48.26(16) . .
C25 Ag2 Ag3 142.99(15) . .
Ag1 Ag2 Ag3 95.397(17) . .
C41 Ag3 C33 164.7(2) . .
C41 Ag3 Ag4 49.30(15) . .
C33 Ag3 Ag4 144.99(17) . .
C41 Ag3 Ag2 147.46(15) . .
C33 Ag3 Ag2 46.59(16) . .
Ag4 Ag3 Ag2 98.469(18) . .
C41 Ag4 C17 121.19(19) . 2_777
C41 Ag4 C9 136.55(19) . 2_777
C17 Ag4 C9 90.51(18) 2_777 2_777
C41 Ag4 Cu1 157.78(16) . 2_777
C17 Ag4 Cu1 45.67(12) 2_777 2_777
C9 Ag4 Cu1 45.47(13) 2_777 2_777
C41 Ag4 Ag3 47.85(15) . .
C17 Ag4 Ag3 164.38(12) 2_777 .
C9 Ag4 Ag3 104.86(13) 2_777 .
Cu1 Ag4 Ag3 148.81(2) 2_777 .
C41 Ag4 Ag5 119.66(15) . .
C17 Ag4 Ag5 46.16(11) 2_777 .
C9 Ag4 Ag5 103.66(12) 2_777 .
Cu1 Ag4 Ag5 66.838(19) 2_777 .
Ag3 Ag4 Ag5 124.99(2) . .
C17 Ag5 P1 123.51(13) 2_777 .
C17 Ag5 C9 103.83(17) 2_777 .
P1 Ag5 C9 120.84(13) . .
C17 Ag5 C1 99.46(16) 2_777 .
P1 Ag5 C1 114.86(13) . .
C9 Ag5 C1 86.59(17) . .
C17 Ag5 Cu1 94.54(12) 2_777 .
P1 Ag5 Cu1 141.34(4) . .
C9 Ag5 Cu1 44.73(12) . .
C1 Ag5 Cu1 44.30(12) . .
C17 Ag5 Ag1 50.21(12) 2_777 2_777
P1 Ag5 Ag1 128.68(4) . 2_777
C9 Ag5 Ag1 59.49(13) . 2_777
C1 Ag5 Ag1 116.31(12) . 2_777
Cu1 Ag5 Ag1 79.356(19) . 2_777
C17 Ag5 Ag4 45.95(11) 2_777 .
P1 Ag5 Ag4 120.15(4) . .
C9 Ag5 Ag4 118.05(12) . .
C1 Ag5 Ag4 58.85(11) . .
Cu1 Ag5 Ag4 80.024(18) . .
Ag1 Ag5 Ag4 89.954(16) 2_777 .
C2 C1 Cu1 170.3(5) . .
C2 C1 Ag1 108.1(4) . .
Cu1 C1 Ag1 76.62(18) . .
C2 C1 Ag5 106.9(4) . .
Cu1 C1 Ag5 72.63(16) . .
Ag1 C1 Ag5 138.1(2) . .
C1 C2 C3 178.3(6) . .
C4 C3 C2 178.4(8) . .
C3 C4 C5 177.3(8) . .
C4 C5 C7 108.9(7) . .
C4 C5 C8 109.4(6) . .
C7 C5 C8 111.5(9) . .
C4 C5 C6 108.1(7) . .
C7 C5 C6 109.9(8) . .
C8 C5 C6 109.1(9) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C5 C7 H7A 109.5 . .
C5 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C5 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C5 C8 H8A 109.5 . .
C5 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C5 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C10 C9 Cu1 171.9(5) . .
C10 C9 Ag4 105.0(4) . 2_777
Cu1 C9 Ag4 73.53(17) . 2_777
C10 C9 Ag5 110.0(4) . .
Cu1 C9 Ag5 74.82(17) . .
Ag4 C9 Ag5 138.0(2) 2_777 .
C9 C10 C11 179.3(7) . .
C12 C11 C10 177.0(7) . .
C11 C12 C13 178.7(7) . .
C12 C13 C15 109.5(6) . .
C12 C13 C16 108.7(5) . .
C15 C13 C16 110.0(6) . .
C12 C13 C14 109.0(5) . .
C15 C13 C14 109.1(6) . .
C16 C13 C14 110.5(6) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 H15A 109.5 . .
C13 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C13 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C13 C16 H16A 109.5 . .
C13 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C13 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 Cu1 164.5(4) . .
C18 C17 Ag4 115.6(4) . 2_777
Cu1 C17 Ag4 73.44(15) . 2_777
C18 C17 Ag5 94.0(3) . 2_777
Cu1 C17 Ag5 99.1(2) . 2_777
Ag4 C17 Ag5 87.89(16) 2_777 2_777
C18 C17 Ag1 101.3(3) . .
Cu1 C17 Ag1 72.41(16) . .
Ag4 C17 Ag1 142.3(2) 2_777 .
Ag5 C17 Ag1 82.14(15) 2_777 .
C17 C18 C19 173.6(5) . .
C20 C19 C18 177.3(6) . .
C19 C20 C21 176.0(6) . .
C20 C21 C23 110.0(5) . .
C20 C21 C24 109.1(6) . .
C23 C21 C24 112.3(6) . .
C20 C21 C22 107.0(5) . .
C23 C21 C22 110.0(6) . .
C24 C21 C22 108.4(6) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C26 C25 Ag2 121.7(4) . .
C26 C25 Ag1 154.7(4) . .
Ag2 C25 Ag1 83.51(19) . .
C25 C26 C27 177.6(6) . .
C28 C27 C26 176.6(6) . .
C27 C28 C29 176.3(7) . .
C32 C29 C28 111.5(6) . .
C32 C29 C30 109.9(9) . .
C28 C29 C30 106.3(6) . .
C32 C29 C31 114.8(9) . .
C28 C29 C31 106.7(6) . .
C30 C29 C31 107.3(8) . .
C29 C30 H30A 109.5 . .
C29 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C29 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C29 C31 H31A 109.5 . .
C29 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C29 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C29 C32 H32A 109.5 . .
C29 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C29 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C34 C33 Ag2 159.5(5) . .
C34 C33 Ag3 115.3(5) . .
Ag2 C33 Ag3 85.2(2) . .
C33 C34 C35 177.3(7) . .
C36 C35 C34 176.3(7) . .
C35 C36 C37 175.9(8) . .
C36 C37 C38 109.6(7) . .
C36 C37 C40 106.8(9) . .
C38 C37 C40 111.2(11) . .
C36 C37 C39 105.4(8) . .
C38 C37 C39 104.2(12) . .
C40 C37 C39 119.2(13) . .
C37 C38 H38A 109.5 . .
C37 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
C37 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
C37 C39 H39A 109.5 . .
C37 C39 H39B 109.5 . .
H39A C39 H39B 109.5 . .
C37 C39 H39C 109.5 . .
H39A C39 H39C 109.5 . .
H39B C39 H39C 109.5 . .
C37 C40 H40A 109.5 . .
C37 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C37 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C42 C41 Ag3 139.5(5) . .
C42 C41 Ag4 136.9(5) . .
Ag3 C41 Ag4 82.86(19) . .
C41 C42 C43 178.3(6) . .
C44 C43 C42 178.7(7) . .
C43 C44 C45 177.0(9) . .
C48 C45 C44 110.7(9) . .
C48 C45 C46 118.7(11) . .
C44 C45 C46 108.9(7) . .
C48 C45 C47 105.2(12) . .
C44 C45 C47 107.3(7) . .
C46 C45 C47 105.2(9) . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C45 C47 H47A 109.5 . .
C45 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C45 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C45 C48 H48A 109.5 . .
C45 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C45 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C50 C49 C54 120.1(5) . .
C50 C49 P1 122.9(4) . .
C54 C49 P1 116.9(4) . .
C49 C50 C51 119.9(5) . .
C49 C50 H50A 120.1 . .
C51 C50 H50A 120.1 . .
C52 C51 C50 120.1(6) . .
C52 C51 H51A 119.9 . .
C50 C51 H51A 119.9 . .
C51 C52 C53 119.9(6) . .
C51 C52 H52A 120.1 . .
C53 C52 H52A 120.1 . .
C54 C53 C52 120.0(6) . .
C54 C53 H53A 120.0 . .
C52 C53 H53A 120.0 . .
C53 C54 C49 119.9(6) . .
C53 C54 H54A 120.0 . .
C49 C54 H54A 120.0 . .
C56 C55 C60 119.6(5) . .
C56 C55 P1 122.2(4) . .
C60 C55 P1 118.2(4) . .
C55 C56 C57 120.1(6) . .
C55 C56 H56A 119.9 . .
C57 C56 H56A 119.9 . .
C58 C57 C56 120.6(7) . .
C58 C57 H57A 119.7 . .
C56 C57 H57A 119.7 . .
C57 C58 C59 119.4(6) . .
C57 C58 H58A 120.3 . .
C59 C58 H58A 120.3 . .
C60 C59 C58 120.0(7) . .
C60 C59 H59A 120.0 . .
C58 C59 H59A 120.0 . .
C59 C60 C55 120.3(6) . .
C59 C60 H60A 119.8 . .
C55 C60 H60A 119.8 . .
C66 C61 C62 119.0(5) . .
C66 C61 P1 124.1(4) . .
C62 C61 P1 116.7(4) . .
C63 C62 C61 120.4(5) . .
C63 C62 H62A 119.8 . .
C61 C62 H62A 119.8 . .
C62 C63 C64 119.8(6) . .
C62 C63 H63A 120.1 . .
C64 C63 H63A 120.1 . .
C65 C64 C63 120.0(6) . .
C65 C64 H64A 120.0 . .
C63 C64 H64A 120.0 . .
C64 C65 C66 120.1(6) . .
C64 C65 H65A 119.9 . .
C66 C65 H65A 119.9 . .
C61 C66 C65 120.6(6) . .
C61 C66 H66A 119.7 . .
C65 C66 H66A 119.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 C9 1.960(5) .
Cu1 C1 1.967(5) .
Cu1 C17 1.968(5) .
Cu1 Ag4 2.6366(7) 2_777
Cu1 Ag1 2.6790(7) .
Cu1 Ag5 2.6879(7) .
Cu1 Cu1 3.0266(12) 2_777
P1 C55 1.824(5) .
P1 C49 1.825(5) .
P1 C61 1.825(5) .
P1 Ag5 2.4165(13) .
Ag1 C25 2.129(5) .
Ag1 C1 2.330(5) .
Ag1 C17 2.508(5) .
Ag1 Ag2 2.8340(6) .
Ag1 Ag5 3.2328(7) 2_777
Ag2 C33 2.078(6) .
Ag2 C25 2.127(5) .
Ag2 Ag3 2.8500(6) .
Ag3 C41 2.106(6) .
Ag3 C33 2.134(6) .
Ag3 Ag4 2.8194(6) .
Ag4 C41 2.154(5) .
Ag4 C17 2.403(5) 2_777
Ag4 C9 2.405(5) 2_777
Ag4 Cu1 2.6366(8) 2_777
Ag4 Ag5 3.3413(6) .
Ag5 C17 2.412(5) 2_777
Ag5 C9 2.423(5) .
Ag5 C1 2.511(5) .
Ag5 Ag1 3.2328(7) 2_777
C1 C2 1.204(8) .
C2 C3 1.381(8) .
C3 C4 1.185(9) .
C4 C5 1.475(9) .
C5 C7 1.513(13) .
C5 C8 1.529(12) .
C5 C6 1.538(15) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 C10 1.218(8) .
C9 Ag4 2.405(5) 2_777
C10 C11 1.371(7) .
C11 C12 1.213(8) .
C12 C13 1.469(8) .
C13 C15 1.525(10) .
C13 C16 1.525(9) .
C13 C14 1.527(9) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C18 1.233(7) .
C17 Ag4 2.403(5) 2_777
C17 Ag5 2.412(5) 2_777
C18 C19 1.381(7) .
C19 C20 1.184(8) .
C20 C21 1.480(7) .
C21 C23 1.528(9) .
C21 C24 1.540(10) .
C21 C22 1.541(9) .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C26 1.218(8) .
C26 C27 1.358(8) .
C27 C28 1.207(8) .
C28 C29 1.478(8) .
C29 C32 1.474(12) .
C29 C30 1.549(12) .
C29 C31 1.551(12) .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 C34 1.230(9) .
C34 C35 1.364(9) .
C35 C36 1.191(9) .
C36 C37 1.492(10) .
C37 C38 1.505(14) .
C37 C40 1.53(2) .
C37 C39 1.560(18) .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 H39A 0.9800 .
C39 H39B 0.9800 .
C39 H39C 0.9800 .
C40 H40A 0.9800 .
C40 H40B 0.9800 .
C40 H40C 0.9800 .
C41 C42 1.219(8) .
C42 C43 1.380(8) .
C43 C44 1.176(9) .
C44 C45 1.489(8) .
C45 C48 1.439(17) .
C45 C46 1.507(13) .
C45 C47 1.558(18) .
C46 H46A 0.9800 .
C46 H46B 0.9800 .
C46 H46C 0.9800 .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 C50 1.373(7) .
C49 C54 1.384(8) .
C50 C51 1.394(8) .
C50 H50A 0.9500 .
C51 C52 1.370(10) .
C51 H51A 0.9500 .
C52 C53 1.389(10) .
C52 H52A 0.9500 .
C53 C54 1.380(9) .
C53 H53A 0.9500 .
C54 H54A 0.9500 .
C55 C56 1.384(8) .
C55 C60 1.395(8) .
C56 C57 1.391(9) .
C56 H56A 0.9500 .
C57 C58 1.366(11) .
C57 H57A 0.9500 .
C58 C59 1.415(12) .
C58 H58A 0.9500 .
C59 C60 1.368(10) .
C59 H59A 0.9500 .
C60 H60A 0.9500 .
C61 C66 1.380(8) .
C61 C62 1.397(8) .
C62 C63 1.375(9) .
C62 H62A 0.9500 .
C63 C64 1.388(10) .
C63 H63A 0.9500 .
C64 C65 1.375(10) .
C64 H64A 0.9500 .
C65 C66 1.380(9) .
C65 H65A 0.9500 .
C66 H66A 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C9 Cu1 Ag1 C25 -179(56) . .
C1 Cu1 Ag1 C25 -124.1(5) . .
C17 Cu1 Ag1 C25 42.7(4) . .
Ag4 Cu1 Ag1 C25 59.5(4) 2_777 .
Ag5 Cu1 Ag1 C25 -152.4(4) . .
Cu1 Cu1 Ag1 C25 141.7(4) 2_777 .
C9 Cu1 Ag1 C1 -54.7(18) . .
C17 Cu1 Ag1 C1 166.8(2) . .
Ag4 Cu1 Ag1 C1 -176.48(18) 2_777 .
Ag5 Cu1 Ag1 C1 -28.29(18) . .
Cu1 Cu1 Ag1 C1 -94.20(18) 2_777 .
C9 Cu1 Ag1 C17 138.5(18) . .
C1 Cu1 Ag1 C17 -166.8(2) . .
Ag4 Cu1 Ag1 C17 16.75(16) 2_777 .
Ag5 Cu1 Ag1 C17 164.94(16) . .
Cu1 Cu1 Ag1 C17 99.03(16) 2_777 .
C9 Cu1 Ag1 Ag2 -42.1(18) . .
C1 Cu1 Ag1 Ag2 12.64(18) . .
C17 Cu1 Ag1 Ag2 179.41(16) . .
Ag4 Cu1 Ag1 Ag2 -163.85(4) 2_777 .
Ag5 Cu1 Ag1 Ag2 -15.65(6) . .
Cu1 Cu1 Ag1 Ag2 -81.57(5) 2_777 .
C9 Cu1 Ag1 Ag5 87.4(18) . 2_777
C1 Cu1 Ag1 Ag5 142.14(18) . 2_777
C17 Cu1 Ag1 Ag5 -51.09(16) . 2_777
Ag4 Cu1 Ag1 Ag5 -34.35(3) 2_777 2_777
Ag5 Cu1 Ag1 Ag5 113.85(3) . 2_777
Cu1 Cu1 Ag1 Ag5 47.93(2) 2_777 2_777
C25 Ag1 Ag2 C33 171.2(3) . .
C1 Ag1 Ag2 C33 20.8(3) . .
C17 Ag1 Ag2 C33 -170.2(5) . .
Cu1 Ag1 Ag2 C33 11.5(3) . .
Ag5 Ag1 Ag2 C33 -103.0(3) 2_777 .
C1 Ag1 Ag2 C25 -150.4(2) . .
C17 Ag1 Ag2 C25 18.7(5) . .
Cu1 Ag1 Ag2 C25 -159.7(2) . .
Ag5 Ag1 Ag2 C25 85.8(2) 2_777 .
C25 Ag1 Ag2 Ag3 -172.1(2) . .
C1 Ag1 Ag2 Ag3 37.56(13) . .
C17 Ag1 Ag2 Ag3 -153.4(4) . .
Cu1 Ag1 Ag2 Ag3 28.25(5) . .
Ag5 Ag1 Ag2 Ag3 -86.29(3) 2_777 .
C33 Ag2 Ag3 C41 -170.4(4) . .
C25 Ag2 Ag3 C41 13.6(4) . .
Ag1 Ag2 Ag3 C41 23.5(3) . .
C25 Ag2 Ag3 C33 -176.0(3) . .
Ag1 Ag2 Ag3 C33 -166.1(2) . .
C33 Ag2 Ag3 Ag4 -177.5(2) . .
C25 Ag2 Ag3 Ag4 6.5(3) . .
Ag1 Ag2 Ag3 Ag4 16.40(2) . .
C33 Ag3 Ag4 C41 171.8(4) . .
Ag2 Ag3 Ag4 C41 175.0(2) . .
C41 Ag3 Ag4 C17 50.0(5) . 2_777
C33 Ag3 Ag4 C17 -138.2(5) . 2_777
Ag2 Ag3 Ag4 C17 -135.0(4) . 2_777
C41 Ag3 Ag4 C9 -140.6(2) . 2_777
C33 Ag3 Ag4 C9 31.2(3) . 2_777
Ag2 Ag3 Ag4 C9 34.35(13) . 2_777
C41 Ag3 Ag4 Cu1 -156.3(2) . 2_777
C33 Ag3 Ag4 Cu1 15.5(3) . 2_777
Ag2 Ag3 Ag4 Cu1 18.65(5) . 2_777
C41 Ag3 Ag4 Ag5 100.4(2) . .
C33 Ag3 Ag4 Ag5 -87.8(3) . .
Ag2 Ag3 Ag4 Ag5 -84.59(2) . .
C55 P1 Ag5 C17 148.6(2) . 2_777
C49 P1 Ag5 C17 30.9(2) . 2_777
C61 P1 Ag5 C17 -87.6(2) . 2_777
C55 P1 Ag5 C9 -74.6(2) . .
C49 P1 Ag5 C9 167.7(2) . .
C61 P1 Ag5 C9 49.2(2) . .
C55 P1 Ag5 C1 27.0(2) . .
C49 P1 Ag5 C1 -90.7(2) . .
C61 P1 Ag5 C1 150.8(2) . .
C55 P1 Ag5 Cu1 -19.9(2) . .
C49 P1 Ag5 Cu1 -137.59(19) . .
C61 P1 Ag5 Cu1 103.93(19) . .
C55 P1 Ag5 Ag1 -148.33(19) . 2_777
C49 P1 Ag5 Ag1 93.9(2) . 2_777
C61 P1 Ag5 Ag1 -24.53(19) . 2_777
C55 P1 Ag5 Ag4 94.0(2) . .
C49 P1 Ag5 Ag4 -23.7(2) . .
C61 P1 Ag5 Ag4 -142.16(18) . .
C9 Cu1 Ag5 C17 105.1(2) . 2_777
C1 Cu1 Ag5 C17 -98.9(2) . 2_777
C17 Cu1 Ag5 C17 6.0(7) . 2_777
Ag4 Cu1 Ag5 C17 78.07(12) 2_777 2_777
Ag1 Cu1 Ag5 C17 -72.17(12) . 2_777
Cu1 Cu1 Ag5 C17 0.97(12) 2_777 2_777
C9 Cu1 Ag5 P1 -84.51(19) . .
C1 Cu1 Ag5 P1 71.49(17) . .
C17 Cu1 Ag5 P1 176.4(6) . .
Ag4 Cu1 Ag5 P1 -111.54(6) 2_777 .
Ag1 Cu1 Ag5 P1 98.22(6) . .
Cu1 Cu1 Ag5 P1 171.36(6) 2_777 .
C1 Cu1 Ag5 C9 156.0(2) . .
C17 Cu1 Ag5 C9 -99.1(6) . .
Ag4 Cu1 Ag5 C9 -27.03(18) 2_777 .
Ag1 Cu1 Ag5 C9 -177.27(18) . .
Cu1 Cu1 Ag5 C9 -104.13(18) 2_777 .
C9 Cu1 Ag5 C1 -156.0(2) . .
C17 Cu1 Ag5 C1 104.9(6) . .
Ag4 Cu1 Ag5 C1 176.97(17) 2_777 .
Ag1 Cu1 Ag5 C1 26.73(17) . .
Cu1 Cu1 Ag5 C1 99.87(17) 2_777 .
C9 Cu1 Ag5 Ag1 57.02(18) . 2_777
C1 Cu1 Ag5 Ag1 -146.97(16) . 2_777
C17 Cu1 Ag5 Ag1 -42.1(6) . 2_777
Ag4 Cu1 Ag5 Ag1 30.00(3) 2_777 2_777
Ag1 Cu1 Ag5 Ag1 -120.25(2) . 2_777
Cu1 Cu1 Ag5 Ag1 -47.10(2) 2_777 2_777
C9 Cu1 Ag5 Ag4 148.87(18) . .
C1 Cu1 Ag5 Ag4 -55.13(16) . .
C17 Cu1 Ag5 Ag4 49.8(6) . .
Ag4 Cu1 Ag5 Ag4 121.84(2) 2_777 .
Ag1 Cu1 Ag5 Ag4 -28.40(3) . .
Cu1 Cu1 Ag5 Ag4 44.74(2) 2_777 .
C41 Ag4 Ag5 C17 -106.2(2) . 2_777
C9 Ag4 Ag5 C17 77.3(2) 2_777 2_777
Cu1 Ag4 Ag5 C17 49.99(17) 2_777 2_777
Ag3 Ag4 Ag5 C17 -163.26(17) . 2_777
C41 Ag4 Ag5 P1 2.83(18) . .
C17 Ag4 Ag5 P1 109.06(17) 2_777 .
C9 Ag4 Ag5 P1 -173.69(13) 2_777 .
Cu1 Ag4 Ag5 P1 159.05(4) 2_777 .
Ag3 Ag4 Ag5 P1 -54.21(5) . .
C41 Ag4 Ag5 C9 171.7(2) . .
C17 Ag4 Ag5 C9 -82.0(2) 2_777 .
C9 Ag4 Ag5 C9 -4.8(3) 2_777 .
Cu1 Ag4 Ag5 C9 -32.04(14) 2_777 .
Ag3 Ag4 Ag5 C9 114.70(14) . .
C41 Ag4 Ag5 C1 105.4(2) . .
C17 Ag4 Ag5 C1 -148.4(2) 2_777 .
C9 Ag4 Ag5 C1 -71.15(19) 2_777 .
Cu1 Ag4 Ag5 C1 -98.42(14) 2_777 .
Ag3 Ag4 Ag5 C1 48.33(14) . .
C41 Ag4 Ag5 Cu1 147.39(18) . .
C17 Ag4 Ag5 Cu1 -106.38(17) 2_777 .
C9 Ag4 Ag5 Cu1 -29.13(13) 2_777 .
Cu1 Ag4 Ag5 Cu1 -56.39(3) 2_777 .
Ag3 Ag4 Ag5 Cu1 90.36(3) . .
C41 Ag4 Ag5 Ag1 -133.41(18) . 2_777
C17 Ag4 Ag5 Ag1 -27.18(17) 2_777 2_777
C9 Ag4 Ag5 Ag1 50.07(13) 2_777 2_777
Cu1 Ag4 Ag5 Ag1 22.810(18) 2_777 2_777
Ag3 Ag4 Ag5 Ag1 169.56(2) . 2_777
C9 Cu1 C1 C2 -65(3) . .
C17 Cu1 C1 C2 107(3) . .
Ag4 Cu1 C1 C2 -154(2) 2_777 .
Ag1 Cu1 C1 C2 120(3) . .
Ag5 Cu1 C1 C2 -88(3) . .
Cu1 Cu1 C1 C2 -157(3) 2_777 .
C9 Cu1 C1 Ag1 175.02(17) . .
C17 Cu1 C1 Ag1 -13.6(2) . .
Ag4 Cu1 C1 Ag1 85(3) 2_777 .
Ag5 Cu1 C1 Ag1 151.15(16) . .
Cu1 Cu1 C1 Ag1 82.16(10) 2_777 .
C9 Cu1 C1 Ag5 23.9(2) . .
C17 Cu1 C1 Ag5 -164.74(16) . .
Ag4 Cu1 C1 Ag5 -66(3) 2_777 .
Ag1 Cu1 C1 Ag5 -151.15(16) . .
Cu1 Cu1 C1 Ag5 -68.99(8) 2_777 .
C25 Ag1 C1 C2 -22.5(6) . .
C17 Ag1 C1 C2 -162.0(4) . .
Cu1 Ag1 C1 C2 -171.2(5) . .
Ag2 Ag1 C1 C2 15.3(4) . .
Ag5 Ag1 C1 C2 152.6(4) 2_777 .
C25 Ag1 C1 Cu1 148.7(3) . .
C17 Ag1 C1 Cu1 9.22(16) . .
Ag2 Ag1 C1 Cu1 -173.53(9) . .
Ag5 Ag1 C1 Cu1 -36.20(15) 2_777 .
C25 Ag1 C1 Ag5 -167.8(3) . .
C17 Ag1 C1 Ag5 52.8(3) . .
Cu1 Ag1 C1 Ag5 43.6(2) . .
Ag2 Ag1 C1 Ag5 -129.9(3) . .
Ag5 Ag1 C1 Ag5 7.4(3) 2_777 .
C17 Ag5 C1 C2 -103.3(4) 2_777 .
P1 Ag5 C1 C2 30.6(4) . .
C9 Ag5 C1 C2 153.2(4) . .
Cu1 Ag5 C1 C2 169.9(5) . .
Ag1 Ag5 C1 C2 -153.4(3) 2_777 .
Ag4 Ag5 C1 C2 -80.9(4) . .
C17 Ag5 C1 Cu1 86.80(17) 2_777 .
P1 Ag5 C1 Cu1 -139.24(10) . .
C9 Ag5 C1 Cu1 -16.66(17) . .
Ag1 Ag5 C1 Cu1 36.70(17) 2_777 .
Ag4 Ag5 C1 Cu1 109.24(16) . .
C17 Ag5 C1 Ag1 42.2(4) 2_777 .
P1 Ag5 C1 Ag1 176.1(3) . .
C9 Ag5 C1 Ag1 -61.3(3) . .
Cu1 Ag5 C1 Ag1 -44.6(3) . .
Ag1 Ag5 C1 Ag1 -8.0(4) 2_777 .
Ag4 Ag5 C1 Ag1 64.6(3) . .
Cu1 C1 C2 C3 90(22) . .
Ag1 C1 C2 C3 -152(22) . .
Ag5 C1 C2 C3 5(22) . .
C1 C2 C3 C4 67(36) . .
C2 C3 C4 C5 -142(21) . .
C3 C4 C5 C7 -95(17) . .
C3 C4 C5 C8 27(18) . .
C3 C4 C5 C6 145(17) . .
C1 Cu1 C9 C10 103(4) . .
C17 Cu1 C9 C10 -68(4) . .
Ag4 Cu1 C9 C10 -81(4) 2_777 .
Ag1 Cu1 C9 C10 155(2) . .
Ag5 Cu1 C9 C10 127(4) . .
Cu1 Cu1 C9 C10 -166(4) 2_777 .
C1 Cu1 C9 Ag4 -176.58(17) . 2_777
C17 Cu1 C9 Ag4 12.1(2) . 2_777
Ag1 Cu1 C9 Ag4 -124.4(17) . 2_777
Ag5 Cu1 C9 Ag4 -152.08(16) . 2_777
Cu1 Cu1 C9 Ag4 -85.18(9) 2_777 2_777
C1 Cu1 C9 Ag5 -24.5(2) . .
C17 Cu1 C9 Ag5 164.21(17) . .
Ag4 Cu1 C9 Ag5 152.08(16) 2_777 .
Ag1 Cu1 C9 Ag5 27.7(18) . .
Cu1 Cu1 C9 Ag5 66.89(9) 2_777 .
C17 Ag5 C9 C10 104.4(4) 2_777 .
P1 Ag5 C9 C10 -39.6(5) . .
C1 Ag5 C9 C10 -156.7(4) . .
Cu1 Ag5 C9 C10 -173.2(5) . .
Ag1 Ag5 C9 C10 79.9(4) 2_777 .
Ag4 Ag5 C9 C10 151.6(4) . .
C17 Ag5 C9 Cu1 -82.38(18) 2_777 .
P1 Ag5 C9 Cu1 133.60(10) . .
C1 Ag5 C9 Cu1 16.53(17) . .
Ag1 Ag5 C9 Cu1 -106.87(17) 2_777 .
Ag4 Ag5 C9 Cu1 -35.23(18) . .
C17 Ag5 C9 Ag4 -40.2(4) 2_777 2_777
P1 Ag5 C9 Ag4 175.8(2) . 2_777
C1 Ag5 C9 Ag4 58.7(3) . 2_777
Cu1 Ag5 C9 Ag4 42.2(2) . 2_777
Ag1 Ag5 C9 Ag4 -64.7(3) 2_777 2_777
Ag4 Ag5 C9 Ag4 7.0(4) . 2_777
Cu1 C9 C10 C11 103(47) . .
Ag4 C9 C10 C11 25(48) 2_777 .
Ag5 C9 C10 C11 -132(47) . .
C9 C10 C11 C12 48(54) . .
C10 C11 C12 C13 -175(100) . .
C11 C12 C13 C15 -39(33) . .
C11 C12 C13 C16 -159(32) . .
C11 C12 C13 C14 81(33) . .
C9 Cu1 C17 C18 115.9(15) . .
C1 Cu1 C17 C18 -55.4(16) . .
Ag4 Cu1 C17 C18 128.0(16) 2_777 .
Ag1 Cu1 C17 C18 -68.2(15) . .
Ag5 Cu1 C17 C18 -153.0(12) . .
Cu1 Cu1 C17 C18 -148.2(15) 2_777 .
C9 Cu1 C17 Ag4 -12.1(2) . 2_777
C1 Cu1 C17 Ag4 176.61(17) . 2_777
Ag1 Cu1 C17 Ag4 163.74(15) . 2_777
Ag5 Cu1 C17 Ag4 79.0(6) . 2_777
Cu1 Cu1 C17 Ag4 83.76(8) 2_777 2_777
C9 Cu1 C17 Ag5 -97.2(2) . 2_777
C1 Cu1 C17 Ag5 91.6(2) . 2_777
Ag4 Cu1 C17 Ag5 -85.04(16) 2_777 2_777
Ag1 Cu1 C17 Ag5 78.70(14) . 2_777
Ag5 Cu1 C17 Ag5 -6.1(7) . 2_777
Cu1 Cu1 C17 Ag5 -1.28(15) 2_777 2_777
C9 Cu1 C17 Ag1 -175.89(18) . .
C1 Cu1 C17 Ag1 12.9(2) . .
Ag4 Cu1 C17 Ag1 -163.74(15) 2_777 .
Ag5 Cu1 C17 Ag1 -84.8(6) . .
Cu1 Cu1 C17 Ag1 -79.98(8) 2_777 .
C25 Ag1 C17 C18 2.2(4) . .
C1 Ag1 C17 C18 155.9(4) . .
Cu1 Ag1 C17 C18 165.3(4) . .
Ag2 Ag1 C17 C18 -13.5(7) . .
Ag5 Ag1 C17 C18 -92.5(3) 2_777 .
C25 Ag1 C17 Cu1 -163.17(18) . .
C1 Ag1 C17 Cu1 -9.41(17) . .
Ag2 Ag1 C17 Cu1 -178.8(3) . .
Ag5 Ag1 C17 Cu1 102.18(17) 2_777 .
C25 Ag1 C17 Ag4 170.8(3) . 2_777
C1 Ag1 C17 Ag4 -35.4(4) . 2_777
Cu1 Ag1 C17 Ag4 -26.0(2) . 2_777
Ag2 Ag1 C17 Ag4 155.2(2) . 2_777
Ag5 Ag1 C17 Ag4 76.2(3) 2_777 2_777
C25 Ag1 C17 Ag5 94.7(2) . 2_777
C1 Ag1 C17 Ag5 -111.59(16) . 2_777
Cu1 Ag1 C17 Ag5 -102.18(17) . 2_777
Ag2 Ag1 C17 Ag5 79.0(5) . 2_777
Cu1 C17 C18 C19 -1(6) . .
Ag4 C17 C18 C19 123(5) 2_777 .
Ag5 C17 C18 C19 -148(5) 2_777 .
Ag1 C17 C18 C19 -65(5) . .
C17 C18 C19 C20 20(16) . .
C18 C19 C20 C21 -19(19) . .
C19 C20 C21 C23 127(9) . .
C19 C20 C21 C24 -109(9) . .
C19 C20 C21 C22 8(9) . .
C33 Ag2 C25 C26 25.7(14) . .
Ag1 Ag2 C25 C26 177.3(6) . .
Ag3 Ag2 C25 C26 -169.5(4) . .
C33 Ag2 C25 Ag1 -151.7(11) . .
Ag3 Ag2 C25 Ag1 13.2(3) . .
C1 Ag1 C25 C26 -122.1(11) . .
C17 Ag1 C25 C26 10.5(12) . .
Cu1 Ag1 C25 C26 -21.9(15) . .
Ag2 Ag1 C25 C26 -174.7(13) . .
Ag5 Ag1 C25 C26 62.9(12) 2_777 .
C1 Ag1 C25 Ag2 52.6(4) . .
C17 Ag1 C25 Ag2 -174.77(14) . .
Cu1 Ag1 C25 Ag2 152.8(3) . .
Ag5 Ag1 C25 Ag2 -122.40(12) 2_777 .
Ag2 C25 C26 C27 24(16) . .
Ag1 C25 C26 C27 -162(15) . .
C25 C26 C27 C28 20(24) . .
C26 C27 C28 C29 -37(20) . .
C27 C28 C29 C32 -148(10) . .
C27 C28 C29 C30 92(10) . .
C27 C28 C29 C31 -22(11) . .
C25 Ag2 C33 C34 -6(2) . .
Ag1 Ag2 C33 C34 -151.3(15) . .
Ag3 Ag2 C33 C34 -174.0(18) . .
C25 Ag2 C33 Ag3 167.8(10) . .
Ag1 Ag2 C33 Ag3 22.6(4) . .
C41 Ag3 C33 C34 -22.3(13) . .
Ag4 Ag3 C33 C34 -178.0(4) . .
Ag2 Ag3 C33 C34 177.7(7) . .
C41 Ag3 C33 Ag2 160.1(8) . .
Ag4 Ag3 C33 Ag2 4.3(4) . .
Ag2 C33 C34 C35 121(14) . .
Ag3 C33 C34 C35 -52(15) . .
C33 C34 C35 C36 36(24) . .
C34 C35 C36 C37 -13(24) . .
C35 C36 C37 C38 -140(13) . .
C35 C36 C37 C40 99(13) . .
C35 C36 C37 C39 -28(14) . .
C33 Ag3 C41 C42 8.3(15) . .
Ag4 Ag3 C41 C42 170.2(8) . .
Ag2 Ag3 C41 C42 161.0(6) . .
C33 Ag3 C41 Ag4 -161.9(8) . .
Ag2 Ag3 C41 Ag4 -9.3(4) . .
C17 Ag4 C41 C42 23.2(8) 2_777 .
C9 Ag4 C41 C42 -107.6(7) 2_777 .
Cu1 Ag4 C41 C42 -24.1(10) 2_777 .
Ag3 Ag4 C41 C42 -170.7(8) . .
Ag5 Ag4 C41 C42 77.3(7) . .
C17 Ag4 C41 Ag3 -166.05(15) 2_777 .
C9 Ag4 C41 Ag3 63.1(3) 2_777 .
Cu1 Ag4 C41 Ag3 146.6(3) 2_777 .
Ag5 Ag4 C41 Ag3 -111.99(13) . .
Ag3 C41 C42 C43 -60(25) . .
Ag4 C41 C42 C43 106(24) . .
C41 C42 C43 C44 2(56) . .
C42 C43 C44 C45 -71(44) . .
C43 C44 C45 C48 -90(14) . .
C43 C44 C45 C46 137(14) . .
C43 C44 C45 C47 24(14) . .
C55 P1 C49 C50 99.9(5) . .
C61 P1 C49 C50 -10.4(5) . .
Ag5 P1 C49 C50 -136.1(4) . .
C55 P1 C49 C54 -81.5(5) . .
C61 P1 C49 C54 168.2(5) . .
Ag5 P1 C49 C54 42.5(5) . .
C54 C49 C50 C51 1.0(8) . .
P1 C49 C50 C51 179.6(5) . .
C49 C50 C51 C52 0.5(9) . .
C50 C51 C52 C53 -0.5(10) . .
C51 C52 C53 C54 -1.1(11) . .
C52 C53 C54 C49 2.6(11) . .
C50 C49 C54 C53 -2.5(9) . .
P1 C49 C54 C53 178.8(6) . .
C49 P1 C55 C56 -33.1(5) . .
C61 P1 C55 C56 74.4(5) . .
Ag5 P1 C55 C56 -156.8(4) . .
C49 P1 C55 C60 145.0(5) . .
C61 P1 C55 C60 -107.5(5) . .
Ag5 P1 C55 C60 21.3(5) . .
C60 C55 C56 C57 -0.3(9) . .
P1 C55 C56 C57 177.8(5) . .
C55 C56 C57 C58 0.8(10) . .
C56 C57 C58 C59 -0.2(11) . .
C57 C58 C59 C60 -0.9(12) . .
C58 C59 C60 C55 1.4(12) . .
C56 C55 C60 C59 -0.8(10) . .
P1 C55 C60 C59 -179.0(6) . .
C55 P1 C61 C66 -17.2(5) . .
C49 P1 C61 C66 90.6(5) . .
Ag5 P1 C61 C66 -145.0(4) . .
C55 P1 C61 C62 167.3(4) . .
C49 P1 C61 C62 -84.9(5) . .
Ag5 P1 C61 C62 39.5(5) . .
C66 C61 C62 C63 -1.3(9) . .
P1 C61 C62 C63 174.4(5) . .
C61 C62 C63 C64 0.7(10) . .
C62 C63 C64 C65 1.0(10) . .
C63 C64 C65 C66 -2.0(10) . .
C62 C61 C66 C65 0.3(9) . .
P1 C61 C66 C65 -175.1(5) . .
C64 C65 C66 C61 1.4(10) . .
