#------------------------------------------------------------------------------
#$Date: 2019-11-26 02:49:10 +0200 (Tue, 26 Nov 2019) $
#$Revision: 242438 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/13/24/4132465.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4132465
loop_
_publ_author_name
'Messina, Marco S.'
'Stauber, Julia M.'
'Waddington, Mary A.'
'Rheingold, Arnold L.'
'Maynard, Heather D.'
'Spokoyny, Alexander M.'
_publ_section_title
;
 Organometallic Gold(III) Reagents for Cysteine Arylation.
;
_journal_issue                   23
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              7065
_journal_page_last               7069
_journal_paper_doi               10.1021/jacs.8b04115
_journal_volume                  140
_journal_year                    2018
_chemical_formula_moiety         'C34 H45 Au Cl N O P, 2(F3 Sb0.5), H2 O'
_chemical_formula_sum            'C34 H47 Au Cl F6 N O2 P Sb'
_chemical_formula_weight         1000.86
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2018-01-12
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2017.08.10 svn.r3458 for OlexSys, GUI svn.r5381)
;
_cell_angle_alpha                112.015(2)
_cell_angle_beta                 105.708(2)
_cell_angle_gamma                91.052(3)
_cell_formula_units_Z            2
_cell_length_a                   9.5384(10)
_cell_length_b                   13.2116(13)
_cell_length_c                   15.7777(11)
_cell_measurement_reflns_used    9942
_cell_measurement_temperature    100
_cell_measurement_theta_max      28.288
_cell_measurement_theta_min      2.277
_cell_volume                     1758.4(3)
_computing_cell_refinement       'SAINT V8.38A (?, 2016)'
_computing_data_collection       'APEX2 v2013.6-2 (Bruker, 2013)'
_computing_data_reduction        'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'XT (Sheldrick, 2008)'
_diffrn_ambient_temperature      100.0
_diffrn_detector                 'Bruker APEX CCD'
_diffrn_detector_area_resol_mean 8.0
_diffrn_detector_type            'CCD Area Detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       'Kappa Four-Circle Diffractometer'
_diffrn_measurement_device_type  'Bruker X8 APEX'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_av_unetI/netI     0.0393
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            31512
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.284
_diffrn_reflns_theta_min         1.459
_diffrn_source                   'sealed tube'
_diffrn_source_type              fine-focus
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.121
_exptl_absorpt_correction_T_max  0.5633
_exptl_absorpt_correction_T_min  0.4270
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2016/2 (Bruker,2016/2) was used for absorption correction. wR2(int) was 0.0936 before and 0.0406 after correction. The Ratio of minimum to maximum transmission is 0.7580. The λ/2 correction factor is Not present.'
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.890
_exptl_crystal_description       block
_exptl_crystal_F_000             980
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.022
_refine_diff_density_min         -0.862
_refine_diff_density_rms         0.124
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     438
_refine_ls_number_reflns         8736
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0337
_refine_ls_R_factor_gt           0.0256
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0213P)²+1.3677P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0516
_refine_ls_wR_factor_ref         0.0543
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7650
_reflns_number_total             8736
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ja8b04115_si_001.cif
_cod_data_source_block           p-1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_diffrn_radiation_probe' value 'X-ray' was changed to
'x-ray' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_database_code               4132465
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.459
_shelx_estimated_absorpt_t_min   0.309
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H) groups
2.a Ternary CH refined with riding coordinates:
 C17(H17), C19(H19), C21(H21), C27(H27), C29(H29), C31(H31)
2.b Secondary CH2 refined with riding coordinates:
 C16(H16A,H16B), C18(H18A,H18B), C20(H20A,H20B), C22(H22A,H22B), C23(H23A,
 H23B), C24(H24A,H24B), C26(H26A,H26B), C28(H28A,H28B), C30(H30A,H30B),
 C32(H32A,H32B), C33(H33A,H33B), C34(H34A,H34B)
2.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C5(H5), C6(H6), C10(H10), C11(H11), C12(H12), C13(H13)
2.d Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C8(H8A,H8B,H8C)
2.e Idealised tetrahedral OH refined as rotating group:
 O1(H1)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Au1 Au 0.85959(2) 0.40618(2) 0.27766(2) 0.01149(4) Uani 1 1 d . . .
Sb1 Sb 1.000000 0.500000 0.000000 0.01519(7) Uani 1 2 d S T P
Sb2 Sb 1.000000 0.000000 0.500000 0.02199(8) Uani 1 2 d S T P
Cl1 Cl 1.11332(8) 0.46651(6) 0.35062(5) 0.01469(15) Uani 1 1 d . . .
P1 P 0.60737(9) 0.35595(6) 0.22415(6) 0.01173(16) Uani 1 1 d . . .
F1 F 1.0141(4) 0.4357(3) 0.0867(2) 0.0807(11) Uani 1 1 d . . .
F2 F 1.2018(3) 0.5138(2) 0.0260(2) 0.0640(9) Uani 1 1 d . . .
F3 F 1.0179(3) 0.63781(19) 0.09980(19) 0.0509(7) Uani 1 1 d . . .
F4 F 1.1012(3) -0.0884(2) 0.41896(18) 0.0494(7) Uani 1 1 d . . .
F5 F 0.8253(3) -0.0605(2) 0.39980(18) 0.0500(7) Uani 1 1 d . . .
F6 F 1.0222(3) 0.11201(19) 0.45851(18) 0.0476(7) Uani 1 1 d . . .
O1 O 1.0888(3) -0.0417(2) 0.12480(18) 0.0264(6) Uani 1 1 d . . .
H1 H 1.101882 -0.072971 0.163374 0.040 Uiso 1 1 calc GR . .
O2 O 1.1532(3) -0.1563(2) 0.2394(2) 0.0332(7) Uani 1 1 d . . .
H2A H 1.109(6) -0.220(4) 0.205(4) 0.066(18) Uiso 1 1 d . . .
H2B H 1.151(5) -0.141(4) 0.297(4) 0.049(15) Uiso 1 1 d . . .
N1 N 0.8118(3) 0.5775(2) 0.32767(19) 0.0152(6) Uani 1 1 d . . .
C1 C 0.9215(3) 0.2529(2) 0.2280(2) 0.0140(6) Uani 1 1 d . . .
C2 C 0.9654(3) 0.2231(3) 0.1454(2) 0.0157(7) Uani 1 1 d . . .
H2 H 0.957143 0.270481 0.111952 0.019 Uiso 1 1 calc R . .
C3 C 1.0211(4) 0.1244(3) 0.1121(2) 0.0182(7) Uani 1 1 d . . .
H3 H 1.050651 0.104021 0.055707 0.022 Uiso 1 1 calc R . .
C4 C 1.0337(4) 0.0548(3) 0.1614(2) 0.0187(7) Uani 1 1 d . . .
C5 C 0.9921(3) 0.0859(3) 0.2445(2) 0.0178(7) Uani 1 1 d . . .
H5 H 0.999960 0.038706 0.278024 0.021 Uiso 1 1 calc R . .
C6 C 0.9388(3) 0.1861(3) 0.2786(2) 0.0152(7) Uani 1 1 d . . .
H6 H 0.914211 0.208494 0.336910 0.018 Uiso 1 1 calc R . .
C7 C 0.8916(4) 0.6355(3) 0.2854(3) 0.0216(7) Uani 1 1 d . . .
H7A H 0.995811 0.626156 0.302196 0.032 Uiso 1 1 calc GR . .
H7B H 0.881760 0.714136 0.310745 0.032 Uiso 1 1 calc GR . .
H7C H 0.849287 0.604129 0.215480 0.032 Uiso 1 1 calc GR . .
C8 C 0.8713(4) 0.6281(3) 0.4348(2) 0.0207(7) Uani 1 1 d . . .
H8A H 0.820992 0.588276 0.461870 0.031 Uiso 1 1 calc GR . .
H8B H 0.854784 0.705505 0.458370 0.031 Uiso 1 1 calc GR . .
H8C H 0.976876 0.623766 0.454138 0.031 Uiso 1 1 calc GR . .
C9 C 0.6531(4) 0.5863(3) 0.2991(2) 0.0146(6) Uani 1 1 d . . .
C10 C 0.6091(4) 0.6911(3) 0.3186(2) 0.0169(7) Uani 1 1 d . . .
H10 H 0.680750 0.754628 0.346762 0.020 Uiso 1 1 calc R . .
C11 C 0.4612(4) 0.7020(3) 0.2965(2) 0.0211(7) Uani 1 1 d . . .
H11 H 0.431385 0.772885 0.307867 0.025 Uiso 1 1 calc R . .
C12 C 0.3567(4) 0.6105(3) 0.2582(2) 0.0184(7) Uani 1 1 d . . .
H12 H 0.255289 0.618643 0.245221 0.022 Uiso 1 1 calc R . .
C13 C 0.3998(4) 0.5071(3) 0.2388(2) 0.0170(7) Uani 1 1 d . . .
H13 H 0.327263 0.444399 0.212000 0.020 Uiso 1 1 calc R . .
C14 C 0.5485(3) 0.4931(3) 0.2580(2) 0.0135(6) Uani 1 1 d . . .
C15 C 0.5526(3) 0.2895(2) 0.2984(2) 0.0127(6) Uani 1 1 d . . .
C16 C 0.6569(4) 0.3505(3) 0.4020(2) 0.0170(7) Uani 1 1 d . . .
H16A H 0.760262 0.344707 0.402193 0.020 Uiso 1 1 calc R . .
H16B H 0.644378 0.429505 0.425925 0.020 Uiso 1 1 calc R . .
C17 C 0.6215(4) 0.2992(3) 0.4681(2) 0.0224(8) Uani 1 1 d . . .
H17 H 0.689020 0.338841 0.534607 0.027 Uiso 1 1 calc R . .
C18 C 0.4619(4) 0.3108(3) 0.4687(3) 0.0251(8) Uani 1 1 d . . .
H18A H 0.438822 0.279952 0.512426 0.030 Uiso 1 1 calc R . .
H18B H 0.448332 0.389589 0.491883 0.030 Uiso 1 1 calc R . .
C19 C 0.3590(4) 0.2492(3) 0.3674(3) 0.0210(7) Uani 1 1 d . . .
H19 H 0.254990 0.255875 0.368045 0.025 Uiso 1 1 calc R . .
C20 C 0.3800(4) 0.1271(3) 0.3319(3) 0.0228(8) Uani 1 1 d . . .
H20A H 0.357860 0.094626 0.374825 0.027 Uiso 1 1 calc R . .
H20B H 0.311990 0.086535 0.266599 0.027 Uiso 1 1 calc R . .
C21 C 0.5388(4) 0.1171(3) 0.3306(2) 0.0196(7) Uani 1 1 d . . .
H21 H 0.552909 0.037566 0.307294 0.024 Uiso 1 1 calc R . .
C22 C 0.5683(4) 0.1658(3) 0.2616(2) 0.0160(7) Uani 1 1 d . . .
H22A H 0.497491 0.126815 0.197016 0.019 Uiso 1 1 calc R . .
H22B H 0.668686 0.155669 0.256481 0.019 Uiso 1 1 calc R . .
C23 C 0.3926(4) 0.3011(3) 0.3014(3) 0.0192(7) Uani 1 1 d . . .
H23A H 0.379332 0.379951 0.325485 0.023 Uiso 1 1 calc R . .
H23B H 0.323631 0.263744 0.235948 0.023 Uiso 1 1 calc R . .
C24 C 0.6435(4) 0.1784(3) 0.4320(3) 0.0234(8) Uani 1 1 d . . .
H24A H 0.623721 0.145510 0.475245 0.028 Uiso 1 1 calc R . .
H24B H 0.746434 0.171690 0.431332 0.028 Uiso 1 1 calc R . .
C25 C 0.5286(3) 0.2848(2) 0.0908(2) 0.0128(6) Uani 1 1 d . . .
C26 C 0.3584(3) 0.2599(3) 0.0558(2) 0.0182(7) Uani 1 1 d . . .
H26A H 0.325974 0.209733 0.082259 0.022 Uiso 1 1 calc R . .
H26B H 0.315552 0.329127 0.078535 0.022 Uiso 1 1 calc R . .
C27 C 0.3048(4) 0.2058(3) -0.0547(2) 0.0213(7) Uani 1 1 d . . .
H27 H 0.195093 0.190443 -0.077050 0.026 Uiso 1 1 calc R . .
C28 C 0.3543(4) 0.2850(3) -0.0945(3) 0.0284(9) Uani 1 1 d . . .
H28A H 0.317708 0.251915 -0.165388 0.034 Uiso 1 1 calc R . .
H28B H 0.312478 0.354733 -0.071639 0.034 Uiso 1 1 calc R . .
C29 C 0.5211(4) 0.3085(3) -0.0619(2) 0.0248(8) Uani 1 1 d . . .
H29 H 0.552379 0.359312 -0.088936 0.030 Uiso 1 1 calc R . .
C30 C 0.5865(4) 0.2009(3) -0.0965(2) 0.0237(8) Uani 1 1 d . . .
H30A H 0.553665 0.166437 -0.167424 0.028 Uiso 1 1 calc R . .
H30B H 0.695161 0.216329 -0.074575 0.028 Uiso 1 1 calc R . .
C31 C 0.5363(4) 0.1229(3) -0.0564(2) 0.0181(7) Uani 1 1 d . . .
H31 H 0.578501 0.052470 -0.079599 0.022 Uiso 1 1 calc R . .
C32 C 0.5903(4) 0.1749(3) 0.0533(2) 0.0173(7) Uani 1 1 d . . .
H32A H 0.699042 0.188133 0.075683 0.021 Uiso 1 1 calc R . .
H32B H 0.557698 0.123802 0.078961 0.021 Uiso 1 1 calc R . .
C33 C 0.5776(4) 0.3632(3) 0.0488(2) 0.0189(7) Uani 1 1 d . . .
H33A H 0.537533 0.433662 0.071935 0.023 Uiso 1 1 calc R . .
H33B H 0.686187 0.379101 0.070352 0.023 Uiso 1 1 calc R . .
C34 C 0.3684(4) 0.0980(3) -0.0905(2) 0.0212(7) Uani 1 1 d . . .
H34A H 0.332608 0.062943 -0.161309 0.025 Uiso 1 1 calc R . .
H34B H 0.336431 0.046506 -0.064964 0.025 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Au1 Cl1 173.17(3) . .
N1 Au1 Cl1 90.80(7) . .
N1 Au1 P1 86.11(7) . .
C1 Au1 Cl1 84.85(9) . .
C1 Au1 P1 98.62(9) . .
C1 Au1 N1 174.16(11) . .
F1 Sb1 F1 180.0 . 2_765
F1 Sb1 F2 89.94(16) . .
F1 Sb1 F2 90.06(16) 2_765 .
F1 Sb1 F2 90.06(16) . 2_765
F1 Sb1 F2 89.94(16) 2_765 2_765
F1 Sb1 F3 88.74(14) 2_765 2_765
F1 Sb1 F3 91.26(14) . 2_765
F1 Sb1 F3 88.74(14) . .
F1 Sb1 F3 91.26(14) 2_765 .
F2 Sb1 F2 180.0 . 2_765
F2 Sb1 F3 89.79(11) . .
F2 Sb1 F3 90.21(11) . 2_765
F2 Sb1 F3 90.21(11) 2_765 .
F2 Sb1 F3 89.79(11) 2_765 2_765
F3 Sb1 F3 180.00(16) 2_765 .
F4 Sb2 F4 180.00(12) . 2_756
F5 Sb2 F4 88.61(12) 2_756 2_756
F5 Sb2 F4 88.61(12) . .
F5 Sb2 F4 91.39(12) 2_756 .
F5 Sb2 F4 91.39(12) . 2_756
F5 Sb2 F5 180.0 2_756 .
F6 Sb2 F4 89.32(12) 2_756 .
F6 Sb2 F4 90.68(12) . .
F6 Sb2 F4 89.32(12) . 2_756
F6 Sb2 F4 90.68(12) 2_756 2_756
F6 Sb2 F5 89.62(12) . .
F6 Sb2 F5 90.38(12) . 2_756
F6 Sb2 F5 90.38(12) 2_756 .
F6 Sb2 F5 89.62(12) 2_756 2_756
F6 Sb2 F6 180.0 2_756 .
C14 P1 Au1 99.44(10) . .
C14 P1 C15 107.47(14) . .
C14 P1 C25 106.66(14) . .
C15 P1 Au1 109.71(10) . .
C15 P1 C25 117.30(14) . .
C25 P1 Au1 114.42(10) . .
C7 N1 Au1 106.37(19) . .
C8 N1 Au1 108.15(19) . .
C8 N1 C7 109.9(3) . .
C9 N1 Au1 113.15(19) . .
C9 N1 C7 110.2(2) . .
C9 N1 C8 109.0(2) . .
C2 C1 Au1 116.6(2) . .
C6 C1 Au1 122.9(2) . .
C6 C1 C2 120.0(3) . .
C3 C2 C1 120.0(3) . .
C2 C3 C4 120.1(3) . .
O1 C4 C3 117.4(3) . .
O1 C4 C5 122.9(3) . .
C5 C4 C3 119.6(3) . .
C4 C5 C6 120.1(3) . .
C1 C6 C5 120.1(3) . .
C10 C9 N1 118.7(3) . .
C14 C9 N1 120.9(3) . .
C14 C9 C10 120.3(3) . .
C11 C10 C9 119.8(3) . .
C12 C11 C10 120.4(3) . .
C11 C12 C13 119.8(3) . .
C12 C13 C14 121.2(3) . .
C9 C14 P1 119.8(2) . .
C9 C14 C13 118.4(3) . .
C13 C14 P1 121.7(2) . .
C16 C15 P1 106.3(2) . .
C22 C15 P1 111.6(2) . .
C22 C15 C16 110.1(3) . .
C22 C15 C23 107.8(3) . .
C23 C15 P1 113.1(2) . .
C23 C15 C16 108.0(3) . .
C17 C16 C15 109.8(3) . .
C18 C17 C16 109.1(3) . .
C24 C17 C16 109.4(3) . .
C24 C17 C18 110.3(3) . .
C19 C18 C17 109.3(3) . .
C18 C19 C20 109.6(3) . .
C18 C19 C23 109.0(3) . .
C20 C19 C23 110.7(3) . .
C21 C20 C19 109.0(3) . .
C20 C21 C22 108.5(3) . .
C20 C21 C24 109.7(3) . .
C24 C21 C22 110.9(3) . .
C21 C22 C15 110.0(3) . .
C19 C23 C15 109.7(3) . .
C17 C24 C21 109.5(3) . .
C26 C25 P1 113.7(2) . .
C32 C25 P1 110.6(2) . .
C32 C25 C26 107.9(3) . .
C32 C25 C33 109.3(3) . .
C33 C25 P1 106.1(2) . .
C33 C25 C26 109.2(3) . .
C27 C26 C25 109.5(3) . .
C28 C27 C26 109.1(3) . .
C34 C27 C26 110.2(3) . .
C34 C27 C28 109.7(3) . .
C29 C28 C27 109.9(3) . .
C28 C29 C30 110.0(3) . .
C28 C29 C33 109.6(3) . .
C30 C29 C33 109.2(3) . .
C31 C30 C29 109.2(3) . .
C30 C31 C32 110.0(3) . .
C30 C31 C34 110.3(3) . .
C34 C31 C32 109.4(3) . .
C31 C32 C25 110.0(3) . .
C29 C33 C25 109.4(3) . .
C27 C34 C31 108.7(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 Cl1 2.3559(8) .
Au1 P1 2.3157(8) .
Au1 N1 2.201(3) .
Au1 C1 2.042(3) .
Sb1 F1 1.839(2) .
Sb1 F1 1.839(2) 2_765
Sb1 F2 1.847(2) .
Sb1 F2 1.847(2) 2_765
Sb1 F3 1.875(2) .
Sb1 F3 1.875(2) 2_765
Sb2 F4 1.877(2) 2_756
Sb2 F4 1.877(2) .
Sb2 F5 1.869(2) 2_756
Sb2 F5 1.869(2) .
Sb2 F6 1.858(2) 2_756
Sb2 F6 1.858(2) .
P1 C14 1.832(3) .
P1 C15 1.871(3) .
P1 C25 1.874(3) .
O1 C4 1.369(4) .
N1 C7 1.500(4) .
N1 C8 1.498(4) .
N1 C9 1.478(4) .
C1 C2 1.396(4) .
C1 C6 1.381(4) .
C2 C3 1.386(4) .
C3 C4 1.397(5) .
C4 C5 1.389(5) .
C5 C6 1.392(4) .
C9 C10 1.400(4) .
C9 C14 1.392(4) .
C10 C11 1.382(5) .
C11 C12 1.379(5) .
C12 C13 1.379(4) .
C13 C14 1.399(4) .
C15 C16 1.554(4) .
C15 C22 1.541(4) .
C15 C23 1.549(4) .
C16 C17 1.539(4) .
C17 C18 1.536(5) .
C17 C24 1.520(5) .
C18 C19 1.525(5) .
C19 C20 1.533(5) .
C19 C23 1.538(5) .
C20 C21 1.528(5) .
C21 C22 1.537(4) .
C21 C24 1.531(5) .
C25 C26 1.551(4) .
C25 C32 1.543(4) .
C25 C33 1.547(4) .
C26 C27 1.543(4) .
C27 C28 1.531(5) .
C27 C34 1.527(5) .
C28 C29 1.520(5) .
C29 C30 1.530(5) .
C29 C33 1.547(4) .
C30 C31 1.526(5) .
C31 C32 1.533(4) .
C31 C34 1.531(5) .
