#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:02:03 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179046 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/08/4300853.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4300853
loop_
_publ_author_name
'Zhengwen Li'
'Seán T. Barry'
'Roy G. Gordon'
_publ_section_title
;

Synthesis and Characterization of Copper(I) Amidinates as Precursors for

Atomic Layer Deposition (ALD) of Copper Metal

;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1728
_journal_page_last               1735
_journal_paper_doi               10.1021/ic048492u
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C20 H42 Cu2 N4'
_chemical_formula_sum            'C20 H42 Cu2 N4'
_chemical_formula_weight         465.66
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.842(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.884(2)
_cell_length_b                   10.950(2)
_cell_length_c                   12.9230(19)
_cell_measurement_temperature    193(2)
_cell_volume                     2405.0(6)
_computing_cell_refinement       'SMART (BRUKER, V5.625, 2001)'
_computing_data_collection       'ASTRO (BRUKER, V5.007, 1997)'
_computing_data_reduction        'SAINT (BRUKER, V6.22, 2001)'
_computing_molecular_graphics    'SHELXTL (BRUKER, 2000, V6.1)'
_computing_publication_material  'XCIF (Sheldrick and BRUKER, 1997, V5.1)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      193(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker CCD'
_diffrn_measurement_method       'ω, 0.3 deg'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0641
_diffrn_reflns_av_sigmaI/netI    0.0470
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            8589
_diffrn_reflns_theta_full        28.26
_diffrn_reflns_theta_max         28.26
_diffrn_reflns_theta_min         2.21
_diffrn_source                   'normal-focus sealed tube'
_diffrn_standards_decay_%        <1
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.779
_exptl_absorpt_correction_T_max  0.9653
_exptl_absorpt_correction_T_min  0.8708
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            clear
_exptl_crystal_density_diffrn    1.286
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             992
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.300
_refine_diff_density_min         -0.574
_refine_diff_density_rms         0.108
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     191
_refine_ls_number_reflns         2983
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0497
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0311P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0700
_refine_ls_wR_factor_ref         0.0762
_reflns_number_gt                1947
_reflns_number_total             2983
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic048492usi20050114_035217.cif
_cod_data_source_block           rg12
_cod_depositor_comments
;
The following automatic conversions were performed:
'_exptl_absorpt_correction_type' value 'Empirical' changed to 'empirical'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        2405.1(7)
_cod_database_code               4300853
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.5000 0.51544(3) 0.2500 0.05214(13) Uani 1 2 d S . .
Cu2 Cu 0.5000 0.73490(3) 0.2500 0.04819(12) Uani 1 2 d S . .
N1 N 0.59924(10) 0.52068(16) 0.24938(18) 0.0582(5) Uani 1 1 d . . .
N2 N 0.59995(10) 0.73002(15) 0.25232(17) 0.0544(4) Uani 1 1 d . . .
C1 C 0.63414(11) 0.6256(2) 0.2484(2) 0.0566(5) Uani 1 1 d . A .
C2 C 0.71275(14) 0.6262(2) 0.2416(3) 0.1004(10) Uani 1 1 d . . .
H2BA H 0.7296 0.7107 0.2409 0.151 Uiso 1 1 calc R A .
H2BB H 0.7069 0.5848 0.1711 0.151 Uiso 1 1 calc R . .
H2BC H 0.7522 0.5834 0.3085 0.151 Uiso 1 1 calc R . .
C3 C 0.6432(10) 0.8438(14) 0.2772(10) 0.066(3) Uani 0.50 1 d P A 1
H3A H 0.6968 0.8294 0.2818 0.079 Uiso 0.50 1 calc PR A 1
C4 C 0.5931(5) 0.9226(8) 0.1676(11) 0.095(5) Uani 0.50 1 d P A 1
H4A H 0.5390 0.9317 0.1606 0.115 Uiso 0.50 1 calc PR A 1
H4B H 0.6165 1.0051 0.1769 0.115 Uiso 0.50 1 calc PR A 1
C5 C 0.5894(8) 0.8675(12) 0.0627(10) 0.103(3) Uani 0.50 1 d P A 1
H5A H 0.5592 0.9206 -0.0029 0.154 Uiso 0.50 1 calc PR A 1
H5B H 0.5637 0.7876 0.0510 0.154 Uiso 0.50 1 calc PR A 1
H5C H 0.6428 0.8574 0.0696 0.154 Uiso 0.50 1 calc PR A 1
C6 C 0.6503(8) 0.9154(12) 0.3829(10) 0.118(7) Uani 0.50 1 d P A 1
H6A H 0.6797 0.8669 0.4523 0.177 Uiso 0.50 1 calc PR A 1
H6B H 0.5976 0.9329 0.3764 0.177 Uiso 0.50 1 calc PR A 1
H6C H 0.6781 0.9923 0.3878 0.177 Uiso 0.50 1 calc PR A 1
C7 C 0.6414(3) 0.3994(5) 0.2711(4) 0.0366(13) Uani 0.50 1 d P B 1
H7A H 0.6952 0.4129 0.2764 0.044 Uiso 0.50 1 calc PR B 1
C8 C 0.5910(3) 0.3281(5) 0.1574(5) 0.0466(11) Uani 0.50 1 d P B 1
H8A H 0.6118 0.2439 0.1646 0.056 Uiso 0.50 1 calc PR B 1
H8B H 0.5362 0.3225 0.1477 0.056 Uiso 0.50 1 calc PR B 1
C9 C 0.5908(12) 0.3871(19) 0.0501(15) 0.085(3) Uani 0.50 1 d P B 1
H9A H 0.5584 0.3381 -0.0177 0.127 Uiso 0.50 1 calc PR B 1
H9B H 0.6447 0.3911 0.0579 0.127 Uiso 0.50 1 calc PR B 1
H9C H 0.5690 0.4698 0.0411 0.127 Uiso 0.50 1 calc PR B 1
C10 C 0.6486(7) 0.3325(10) 0.3732(11) 0.0626(19) Uani 0.50 1 d P B 1
H10A H 0.6806 0.3800 0.4422 0.094 Uiso 0.50 1 calc PR B 1
H10B H 0.6738 0.2535 0.3764 0.094 Uiso 0.50 1 calc PR B 1
H10C H 0.5962 0.3193 0.3694 0.094 Uiso 0.50 1 calc PR B 1
C3B C 0.6295(9) 0.8524(14) 0.2277(11) 0.066(3) Uani 0.50 1 d P A 2
H3BA H 0.6853 0.8418 0.2403 0.080 Uiso 0.50 1 calc PR A 2
C4B C 0.6281(5) 0.9380(7) 0.3126(10) 0.097(5) Uani 0.50 1 d P A 2
H4BA H 0.5733 0.9476 0.3026 0.116 Uiso 0.50 1 calc PR A 2
H4BB H 0.6469 1.0187 0.3007 0.116 Uiso 0.50 1 calc PR A 2
C5B C 0.6830(6) 0.8911(13) 0.4419(8) 0.104(3) Uani 0.50 1 d P A 2
H5BA H 0.6788 0.9481 0.4974 0.157 Uiso 0.50 1 calc PR A 2
H5BB H 0.7379 0.8870 0.4537 0.157 Uiso 0.50 1 calc PR A 2
H5BC H 0.6657 0.8098 0.4529 0.157 Uiso 0.50 1 calc PR A 2
C6B C 0.5827(10) 0.9122(16) 0.1088(11) 0.127(7) Uani 0.50 1 d P A 2
H6BA H 0.6100 0.9860 0.1030 0.191 Uiso 0.50 1 calc PR A 2
H6BB H 0.5299 0.9339 0.0997 0.191 Uiso 0.50 1 calc PR A 2
H6BC H 0.5783 0.8546 0.0483 0.191 Uiso 0.50 1 calc PR A 2
C7B C 0.6245(4) 0.4037(6) 0.2100(7) 0.0619(19) Uani 0.50 1 d P B 2
H7BA H 0.6823 0.4105 0.2336 0.074 Uiso 0.50 1 calc PR B 2
C8B C 0.6141(5) 0.3093(6) 0.2723(12) 0.131(4) Uani 0.50 1 d P B 2
H8B1 H 0.6316 0.2323 0.2503 0.158 Uiso 0.50 1 calc PR B 2
H8B2 H 0.5573 0.3012 0.2516 0.158 Uiso 0.50 1 calc PR B 2
C9B C 0.6588(11) 0.3258(17) 0.4020(15) 0.144(7) Uani 0.50 1 d P B 2
H9BA H 0.6474 0.2571 0.4409 0.217 Uiso 0.50 1 calc PR B 2
H9BB H 0.6424 0.4022 0.4245 0.217 Uiso 0.50 1 calc PR B 2
H9BC H 0.7155 0.3288 0.4239 0.217 Uiso 0.50 1 calc PR B 2
C10B C 0.5840(12) 0.3698(16) 0.0768(15) 0.113(8) Uani 0.50 1 d P B 2
H10D H 0.6056 0.2925 0.0650 0.169 Uiso 0.50 1 calc PR B 2
H10E H 0.5945 0.4346 0.0330 0.169 Uiso 0.50 1 calc PR B 2
H10F H 0.5271 0.3616 0.0504 0.169 Uiso 0.50 1 calc PR B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Cu1 N1 176.50(10) . 2_655 ?
N1 Cu1 Cu2 88.25(5) . . ?
N1 Cu1 Cu2 88.25(5) 2_655 . ?
N2 Cu2 N2 176.73(10) 2_655 . ?
N2 Cu2 Cu1 88.37(5) 2_655 . ?
N2 Cu2 Cu1 88.37(5) . . ?
C1 N1 C7 122.6(3) . . ?
C1 N1 C7B 119.6(3) . . ?
C7 N1 C7B 27.1(2) . . ?
C1 N1 Cu1 121.80(14) . . ?
C7 N1 Cu1 114.7(2) . . ?
C7B N1 Cu1 115.6(3) . . ?
C1 N2 C3 120.9(7) . . ?
C1 N2 C3B 121.1(7) . . ?
C3 N2 C3B 22.3(7) . . ?
C1 N2 Cu2 121.86(14) . . ?
C3 N2 Cu2 116.5(7) . . ?
C3B N2 Cu2 115.2(7) . . ?
N2 C1 N1 119.62(17) . . ?
N2 C1 C2 120.1(2) . . ?
N1 C1 C2 120.3(2) . . ?
C1 C2 H2BA 109.5 . . ?
C1 C2 H2BB 109.5 . . ?
H2BA C2 H2BB 109.5 . . ?
C1 C2 H2BC 109.5 . . ?
H2BA C2 H2BC 109.5 . . ?
H2BB C2 H2BC 109.5 . . ?
N2 C3 C6 117.4(9) . . ?
N2 C3 C4 102.2(9) . . ?
C6 C3 C4 107.9(12) . . ?
N2 C3 H3A 109.6 . . ?
C6 C3 H3A 109.6 . . ?
C4 C3 H3A 109.6 . . ?
C5 C4 C3 112.1(9) . . ?
C5 C4 H4A 109.2 . . ?
C3 C4 H4A 109.2 . . ?
C5 C4 H4B 109.2 . . ?
C3 C4 H4B 109.2 . . ?
H4A C4 H4B 107.9 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C3 C6 H6A 109.5 . . ?
C3 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
C3 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C10 C7 N1 116.3(5) . . ?
C10 C7 C8 112.1(7) . . ?
N1 C7 C8 102.0(4) . . ?
C10 C7 H7A 108.7 . . ?
N1 C7 H7A 108.7 . . ?
C8 C7 H7A 108.7 . . ?
C9 C8 C7 113.7(9) . . ?
C9 C8 H8A 108.8 . . ?
C7 C8 H8A 108.8 . . ?
C9 C8 H8B 108.8 . . ?
C7 C8 H8B 108.8 . . ?
H8A C8 H8B 107.7 . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C7 C10 H10A 109.5 . . ?
C7 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C7 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C4B C3B N2 106.1(9) . . ?
C4B C3B C6B 106.7(11) . . ?
N2 C3B C6B 118.2(12) . . ?
C4B C3B H3BA 108.5 . . ?
N2 C3B H3BA 108.5 . . ?
C6B C3B H3BA 108.5 . . ?
C3B C4B C5B 111.1(9) . . ?
C3B C4B H4BA 109.4 . . ?
C5B C4B H4BA 109.4 . . ?
C3B C4B H4BB 109.4 . . ?
C5B C4B H4BB 109.4 . . ?
H4BA C4B H4BB 108.0 . . ?
C4B C5B H5BA 109.5 . . ?
C4B C5B H5BB 109.5 . . ?
H5BA C5B H5BB 109.5 . . ?
C4B C5B H5BC 109.5 . . ?
H5BA C5B H5BC 109.5 . . ?
H5BB C5B H5BC 109.5 . . ?
C3B C6B H6BA 109.5 . . ?
C3B C6B H6BB 109.5 . . ?
H6BA C6B H6BB 109.5 . . ?
C3B C6B H6BC 109.5 . . ?
H6BA C6B H6BC 109.5 . . ?
H6BB C6B H6BC 109.5 . . ?
C8B C7B N1 106.9(6) . . ?
C8B C7B C10B 109.5(10) . . ?
N1 C7B C10B 118.8(8) . . ?
C8B C7B H7BA 107.0 . . ?
N1 C7B H7BA 107.0 . . ?
C10B C7B H7BA 107.0 . . ?
C7B C8B C9B 113.7(11) . . ?
C7B C8B H8B1 108.8 . . ?
C9B C8B H8B1 108.8 . . ?
C7B C8B H8B2 108.8 . . ?
C9B C8B H8B2 108.8 . . ?
H8B1 C8B H8B2 107.7 . . ?
C8B C9B H9BA 109.5 . . ?
C8B C9B H9BB 109.5 . . ?
H9BA C9B H9BB 109.5 . . ?
C8B C9B H9BC 109.5 . . ?
H9BA C9B H9BC 109.5 . . ?
H9BB C9B H9BC 109.5 . . ?
C7B C10B H10D 109.5 . . ?
C7B C10B H10E 109.5 . . ?
H10D C10B H10E 109.5 . . ?
C7B C10B H10F 109.5 . . ?
H10D C10B H10F 109.5 . . ?
H10E C10B H10F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 N1 1.8785(17) . ?
Cu1 N1 1.8785(17) 2_655 ?
Cu1 Cu2 2.4031(6) . ?
Cu2 N2 1.8755(17) 2_655 ?
Cu2 N2 1.8755(17) . ?
N1 C1 1.327(3) . ?
N1 C7 1.510(6) . ?
N1 C7B 1.529(6) . ?
N2 C1 1.325(3) . ?
N2 C3 1.447(14) . ?
N2 C3B 1.537(14) . ?
C1 C2 1.525(2) . ?
C2 H2BA 0.9800 . ?
C2 H2BB 0.9800 . ?
C2 H2BC 0.9800 . ?
C3 C6 1.530(19) . ?
C3 C4 1.575(15) . ?
C3 H3A 1.0000 . ?
C4 C5 1.457(15) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C5 H5C 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C6 H6C 0.9800 . ?
C7 C10 1.462(14) . ?
C7 C8 1.567(7) . ?
C7 H7A 1.0000 . ?
C8 C9 1.528(17) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C3B C4B 1.45(2) . ?
C3B C6B 1.545(19) . ?
C3B H3BA 1.0000 . ?
C4B C5B 1.619(16) . ?
C4B H4BA 0.9900 . ?
C4B H4BB 0.9900 . ?
C5B H5BA 0.9800 . ?
C5B H5BB 0.9800 . ?
C5B H5BC 0.9800 . ?
C6B H6BA 0.9800 . ?
C6B H6BB 0.9800 . ?
C6B H6BC 0.9800 . ?
C7B C8B 1.375(10) . ?
C7B C10B 1.593(18) . ?
C7B H7BA 1.0000 . ?
C8B C9B 1.52(2) . ?
C8B H8B1 0.9900 . ?
C8B H8B2 0.9900 . ?
C9B H9BA 0.9800 . ?
C9B H9BB 0.9800 . ?
C9B H9BC 0.9800 . ?
C10B H10D 0.9800 . ?
C10B H10E 0.9800 . ?
C10B H10F 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Cu1 Cu2 N2 178.96(8) . . . 2_655 ?
N1 Cu1 Cu2 N2 -1.04(8) 2_655 . . 2_655 ?
N1 Cu1 Cu2 N2 -1.04(8) . . . . ?
N1 Cu1 Cu2 N2 178.96(8) 2_655 . . . ?
N1 Cu1 N1 C1 -0.47(19) 2_655 . . . ?
Cu2 Cu1 N1 C1 -0.47(19) . . . . ?
N1 Cu1 N1 C7 169.3(2) 2_655 . . . ?
Cu2 Cu1 N1 C7 169.3(2) . . . . ?
N1 Cu1 N1 C7B -160.7(3) 2_655 . . . ?
Cu2 Cu1 N1 C7B -160.7(3) . . . . ?
N2 Cu2 N2 C1 2.83(19) 2_655 . . . ?
Cu1 Cu2 N2 C1 2.83(19) . . . . ?
N2 Cu2 N2 C3 -167.5(5) 2_655 . . . ?
Cu1 Cu2 N2 C3 -167.5(5) . . . . ?
N2 Cu2 N2 C3B 167.7(6) 2_655 . . . ?
Cu1 Cu2 N2 C3B 167.7(6) . . . . ?
C3 N2 C1 N1 166.0(5) . . . . ?
C3B N2 C1 N1 -167.9(6) . . . . ?
Cu2 N2 C1 N1 -3.9(3) . . . . ?
C3 N2 C1 C2 -14.5(6) . . . . ?
C3B N2 C1 C2 11.6(7) . . . . ?
Cu2 N2 C1 C2 175.54(19) . . . . ?
C7 N1 C1 N2 -166.3(3) . . . . ?
C7B N1 C1 N2 162.1(4) . . . . ?
Cu1 N1 C1 N2 2.6(3) . . . . ?
C7 N1 C1 C2 14.2(4) . . . . ?
C7B N1 C1 C2 -17.4(5) . . . . ?
Cu1 N1 C1 C2 -176.83(19) . . . . ?
C1 N2 C3 C6 -120.5(12) . . . . ?
C3B N2 C3 C6 142(4) . . . . ?
Cu2 N2 C3 C6 50.0(13) . . . . ?
C1 N2 C3 C4 121.8(8) . . . . ?
C3B N2 C3 C4 24(3) . . . . ?
Cu2 N2 C3 C4 -67.8(9) . . . . ?
N2 C3 C4 C5 -61.2(12) . . . . ?
C6 C3 C4 C5 174.4(10) . . . . ?
C1 N1 C7 C10 117.8(7) . . . . ?
C7B N1 C7 C10 -150.1(13) . . . . ?
Cu1 N1 C7 C10 -51.8(7) . . . . ?
C1 N1 C7 C8 -119.9(4) . . . . ?
C7B N1 C7 C8 -27.8(7) . . . . ?
Cu1 N1 C7 C8 70.5(4) . . . . ?
C10 C7 C8 C9 -172.6(10) . . . . ?
N1 C7 C8 C9 62.3(9) . . . . ?
C1 N2 C3B C4B -138.1(7) . . . . ?
C3 N2 C3B C4B -42(3) . . . . ?
Cu2 N2 C3B C4B 56.9(9) . . . . ?
C1 N2 C3B C6B 102.3(13) . . . . ?
C3 N2 C3B C6B -161(5) . . . . ?
Cu2 N2 C3B C6B -62.7(15) . . . . ?
N2 C3B C4B C5B 58.9(12) . . . . ?
C6B C3B C4B C5B -174.2(10) . . . . ?
C1 N1 C7B C8B 148.6(6) . . . . ?
C7 N1 C7B C8B 44.1(9) . . . . ?
Cu1 N1 C7B C8B -50.7(7) . . . . ?
C1 N1 C7B C10B -86.9(10) . . . . ?
C7 N1 C7B C10B 168.5(15) . . . . ?
Cu1 N1 C7B C10B 73.8(10) . . . . ?
N1 C7B C8B C9B -56.8(9) . . . . ?
C10B C7B C8B C9B 173.2(11) . . . . ?
