#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:09:53 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179048 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/10/4301073.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4301073
loop_
_publ_author_name
'Giuliano Bandoli'
'Davide Barreca'
'Alberto Gasparotto'
'Chiara Maccato'
'Roberta Seraglia'
'Eugenio Tondello'
'Anjana Devi'
'Roland A. Fischer'
'Manuela Winter'
_publ_section_title
;
A Cobalt(II) Hexafluoroacetylacetonate Ethylenediamine Complex As a CVD
Molecular Source of Cobalt Oxide Nanostructures
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              82
_journal_page_last               89
_journal_paper_doi               10.1021/ic801212v
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C16 H18 Co F12 N2 O4'
_chemical_formula_weight         589.25
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.279(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.1629(2)
_cell_length_b                   10.35360(10)
_cell_length_c                   17.2325(3)
_cell_measurement_reflns_used    20000
_cell_measurement_temperature    107(2)
_cell_measurement_theta_max      27.499
_cell_measurement_theta_min      2.60
_cell_volume                     2230.00(6)
_computing_cell_refinement       'CrysAlis RED 1.171.13, Oxford Diffraction'
_computing_data_collection       'CrysAlis CCD 1.171.13, Oxford Diffraction'
_computing_data_reduction        'CrysAlis RED 1.171.13, Oxford Diffraction'
_computing_molecular_graphics    SHELXL-97
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      107(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Sapphire2-CCD, Oxford Diffraction'
_diffrn_measurement_method       '1106 images at 1.0 deg. in ω and 20 sec.'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0307
_diffrn_reflns_av_sigmaI/netI    0.0217
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            41371
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         3.06
_exptl_absorpt_coefficient_mu    0.896
_exptl_absorpt_correction_T_max  0.7103
_exptl_absorpt_correction_T_min  0.6156
_exptl_absorpt_correction_type   'numeric analytical'
_exptl_absorpt_process_details   'Gaussian face-indexed'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.755
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1180
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.41
_refine_diff_density_max         0.439
_refine_diff_density_min         -0.244
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.014
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     320
_refine_ls_number_reflns         5134
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0273
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0442P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0663
_refine_ls_wR_factor_ref         0.0677
_reflns_number_gt                4173
_reflns_number_total             5134
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic801212v_si_001.cif
_cod_data_source_block           Co(hfa)2_tmeda
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4301073
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.597413(14) 0.111565(16) 0.846035(11) 0.01821(6) Uani 1 1 d . . .
O11 O 0.75790(8) 0.16472(9) 0.88398(6) 0.0226(2) Uani 1 1 d . . .
C12 C 0.82384(11) 0.12419(13) 0.94877(8) 0.0208(3) Uani 1 1 d . . .
C121 C 0.92387(12) 0.20873(14) 0.97897(9) 0.0265(3) Uani 1 1 d . . .
F121 F 0.99177(8) 0.17040(10) 1.05020(6) 0.0434(3) Uani 1 1 d . . .
F122 F 0.89730(8) 0.33094(8) 0.98819(6) 0.0400(2) Uani 1 1 d . . .
F123 F 0.97795(7) 0.21028(9) 0.92546(6) 0.0349(2) Uani 1 1 d . . .
C13 C 0.81804(11) 0.01434(13) 0.99368(8) 0.0221(3) Uani 1 1 d . . .
H13 H 0.8747 -0.0038 1.0424 0.026 Uiso 1 1 calc R . .
C14 C 0.73136(11) -0.06960(13) 0.96906(8) 0.0201(3) Uani 1 1 d . . .
C141 C 0.74092(11) -0.20042(13) 1.01243(9) 0.0237(3) Uani 1 1 d . . .
F141 F 0.78104(8) -0.28877(8) 0.97339(6) 0.0387(2) Uani 1 1 d . . .
F142 F 0.80507(7) -0.19802(9) 1.08965(5) 0.0335(2) Uani 1 1 d . . .
F143 F 0.64632(7) -0.24381(8) 1.01337(6) 0.0335(2) Uani 1 1 d . . .
O15 O 0.64543(8) -0.05570(9) 0.91224(6) 0.0221(2) Uani 1 1 d . . .
O21 O 0.55475(8) 0.28577(9) 0.78703(6) 0.0227(2) Uani 1 1 d . . .
C22 C 0.56269(11) 0.39379(13) 0.82115(9) 0.0211(3) Uani 1 1 d . . .
C221 C 0.52801(12) 0.50573(14) 0.76060(9) 0.0285(3) Uani 1 1 d . . .
F221 F 0.42204(8) 0.50482(11) 0.72702(7) 0.0545(3) Uani 1 1 d . . .
F222 F 0.56925(9) 0.49585(9) 0.69985(6) 0.0431(2) Uani 1 1 d . . .
F223 F 0.55471(10) 0.62096(8) 0.79410(6) 0.0496(3) Uani 1 1 d . . .
C23 C 0.59458(12) 0.42214(13) 0.90397(9) 0.0253(3) Uani 1 1 d . . .
H23 H 0.6061 0.5096 0.9211 0.030 Uiso 1 1 calc R . .
C24 C 0.61008(11) 0.32516(13) 0.96270(8) 0.0224(3) Uani 1 1 d . . .
C241 C 0.64958(14) 0.36518(14) 1.05289(9) 0.0313(4) Uani 1 1 d . . .
F241 F 0.73703(8) 0.29795(11) 1.09217(6) 0.0491(3) Uani 1 1 d . . .
F242 F 0.57761(9) 0.33846(9) 1.09030(6) 0.0437(2) Uani 1 1 d . . .
F243 F 0.67302(11) 0.48908(10) 1.06488(6) 0.0626(4) Uani 1 1 d . . .
O25 O 0.59561(8) 0.20635(9) 0.95245(6) 0.0223(2) Uani 1 1 d . . .
N31 N 0.43389(9) 0.04314(11) 0.81163(7) 0.0230(3) Uani 1 1 d . . .
C311 C 0.40968(12) -0.02292(15) 0.87989(9) 0.0311(3) Uani 1 1 d . . .
H31A H 0.4205 0.0372 0.9257 0.047 Uiso 1 1 calc R . .
H31B H 0.4574 -0.0973 0.8975 0.047 Uiso 1 1 calc R . .
H31C H 0.3352 -0.0524 0.8617 0.047 Uiso 1 1 calc R . .
C312 C 0.35664(12) 0.14999(15) 0.78409(9) 0.0283(3) Uani 1 1 d . . .
H31D H 0.2836 0.1156 0.7684 0.042 Uiso 1 1 calc R . .
H31E H 0.3685 0.1929 0.7370 0.042 Uiso 1 1 calc R . .
H31F H 0.3665 0.2124 0.8286 0.042 Uiso 1 1 calc R . .
C32 C 0.42534(13) -0.04899(15) 0.74423(10) 0.0310(3) Uani 1 1 d . . .
H32A H 0.3490 -0.0632 0.7133 0.037 Uiso 1 1 calc R . .
H32B H 0.4567 -0.1330 0.7672 0.037 Uiso 1 1 calc R . .
C33 C 0.48331(12) 0.00199(15) 0.68699(9) 0.0302(3) Uani 1 1 d . . .
H33A H 0.4772 -0.0613 0.6427 0.036 Uiso 1 1 calc R . .
H33B H 0.4496 0.0837 0.6618 0.036 Uiso 1 1 calc R . .
N34 N 0.59788(9) 0.02499(11) 0.73220(7) 0.0231(3) Uani 1 1 d . . .
C341 C 0.64525(14) 0.11038(14) 0.68387(9) 0.0313(3) Uani 1 1 d . . .
H34A H 0.7211 0.1246 0.7138 0.047 Uiso 1 1 calc R . .
H34B H 0.6076 0.1934 0.6747 0.047 Uiso 1 1 calc R . .
H34C H 0.6385 0.0697 0.6311 0.047 Uiso 1 1 calc R . .
C342 C 0.65872(13) -0.09761(14) 0.74555(10) 0.0290(3) Uani 1 1 d . . .
H34D H 0.6578 -0.1336 0.6927 0.043 Uiso 1 1 calc R . .
H34E H 0.6258 -0.1592 0.7737 0.043 Uiso 1 1 calc R . .
H34F H 0.7328 -0.0812 0.7791 0.043 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O21 Co1 O15 176.06(4) . . ?
O21 Co1 O11 90.93(4) . . ?
O15 Co1 O11 86.76(4) . . ?
O21 Co1 O25 86.87(4) . . ?
O15 Co1 O25 89.70(4) . . ?
O11 Co1 O25 83.67(4) . . ?
O21 Co1 N34 89.60(4) . . ?
O15 Co1 N34 93.80(4) . . ?
O11 Co1 N34 95.94(4) . . ?
O25 Co1 N34 176.45(4) . . ?
O21 Co1 N31 93.30(4) . . ?
O15 Co1 N31 89.00(4) . . ?
O11 Co1 N31 175.76(4) . . ?
O25 Co1 N31 96.33(4) . . ?
N34 Co1 N31 84.33(4) . . ?
C12 O11 Co1 122.89(9) . . ?
O11 C12 C13 128.78(13) . . ?
O11 C12 C121 113.16(12) . . ?
C13 C12 C121 118.04(12) . . ?
F123 C121 F121 106.99(12) . . ?
F123 C121 F122 106.75(12) . . ?
F121 C121 F122 107.32(12) . . ?
F123 C121 C12 111.21(12) . . ?
F121 C121 C12 113.58(12) . . ?
F122 C121 C12 110.66(12) . . ?
C14 C13 C12 121.61(13) . . ?
C14 C13 H13 119.2 . . ?
C12 C13 H13 119.2 . . ?
O15 C14 C13 128.39(13) . . ?
O15 C14 C141 113.52(12) . . ?
C13 C14 C141 118.00(12) . . ?
F143 C141 F142 107.25(11) . . ?
F143 C141 F141 107.10(12) . . ?
F142 C141 F141 106.74(11) . . ?
F143 C141 C14 111.76(11) . . ?
F142 C141 C14 113.54(12) . . ?
F141 C141 C14 110.11(11) . . ?
C14 O15 Co1 125.11(9) . . ?
C22 O21 Co1 125.47(9) . . ?
O21 C22 C23 128.75(13) . . ?
O21 C22 C221 113.14(12) . . ?
C23 C22 C221 118.08(12) . . ?
F223 C221 F222 107.18(12) . . ?
F223 C221 F221 107.12(13) . . ?
F222 C221 F221 106.78(13) . . ?
F223 C221 C22 113.80(12) . . ?
F222 C221 C22 111.81(12) . . ?
F221 C221 C22 109.80(12) . . ?
C22 C23 C24 121.51(13) . . ?
C22 C23 H23 119.2 . . ?
C24 C23 H23 119.2 . . ?
O25 C24 C23 128.72(13) . . ?
O25 C24 C241 113.44(12) . . ?
C23 C24 C241 117.84(12) . . ?
F243 C241 F242 107.03(13) . . ?
F243 C241 F241 107.79(14) . . ?
F242 C241 F241 106.12(12) . . ?
F243 C241 C24 114.17(12) . . ?
F242 C241 C24 111.60(13) . . ?
F241 C241 C24 109.74(12) . . ?
C24 O25 Co1 122.98(9) . . ?
C312 N31 C311 107.68(12) . . ?
C312 N31 C32 110.83(11) . . ?
C311 N31 C32 110.11(11) . . ?
C312 N31 Co1 111.60(9) . . ?
C311 N31 Co1 112.16(9) . . ?
C32 N31 Co1 104.49(9) . . ?
N31 C311 H31A 109.5 . . ?
N31 C311 H31B 109.5 . . ?
H31A C311 H31B 109.5 . . ?
N31 C311 H31C 109.5 . . ?
H31A C311 H31C 109.5 . . ?
H31B C311 H31C 109.5 . . ?
N31 C312 H31D 109.5 . . ?
N31 C312 H31E 109.5 . . ?
H31D C312 H31E 109.5 . . ?
N31 C312 H31F 109.5 . . ?
H31D C312 H31F 109.5 . . ?
H31E C312 H31F 109.5 . . ?
N31 C32 C33 110.85(12) . . ?
N31 C32 H32A 109.5 . . ?
C33 C32 H32A 109.5 . . ?
N31 C32 H32B 109.5 . . ?
C33 C32 H32B 109.5 . . ?
H32A C32 H32B 108.1 . . ?
N34 C33 C32 110.48(12) . . ?
N34 C33 H33A 109.6 . . ?
C32 C33 H33A 109.6 . . ?
N34 C33 H33B 109.6 . . ?
C32 C33 H33B 109.6 . . ?
H33A C33 H33B 108.1 . . ?
C341 N34 C342 107.27(11) . . ?
C341 N34 C33 109.80(11) . . ?
C342 N34 C33 110.82(11) . . ?
C341 N34 Co1 112.66(9) . . ?
C342 N34 Co1 111.75(9) . . ?
C33 N34 Co1 104.58(8) . . ?
N34 C341 H34A 109.5 . . ?
N34 C341 H34B 109.5 . . ?
H34A C341 H34B 109.5 . . ?
N34 C341 H34C 109.5 . . ?
H34A C341 H34C 109.5 . . ?
H34B C341 H34C 109.5 . . ?
N34 C342 H34D 109.5 . . ?
N34 C342 H34E 109.5 . . ?
H34D C342 H34E 109.5 . . ?
N34 C342 H34F 109.5 . . ?
H34D C342 H34F 109.5 . . ?
H34E C342 H34F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 O21 2.0601(9) . ?
Co1 O15 2.0610(9) . ?
Co1 O11 2.0801(10) . ?
Co1 O25 2.0866(9) . ?
Co1 N34 2.1586(12) . ?
Co1 N31 2.1647(12) . ?
O11 C12 1.2523(16) . ?
C12 C13 1.3911(19) . ?
C12 C121 1.5300(19) . ?
C121 F123 1.3301(17) . ?
C121 F121 1.3322(16) . ?
C121 F122 1.3355(17) . ?
C13 C14 1.3904(19) . ?
C13 H13 0.9500 . ?
C14 O15 1.2507(16) . ?
C14 C141 1.5330(19) . ?
C141 F143 1.3287(16) . ?
C141 F142 1.3341(16) . ?
C141 F141 1.3384(16) . ?
O21 C22 1.2525(16) . ?
C22 C23 1.387(2) . ?
C22 C221 1.5303(19) . ?
C221 F223 1.3239(18) . ?
C221 F222 1.3257(18) . ?
C221 F221 1.3319(18) . ?
C23 C24 1.3945(19) . ?
C23 H23 0.9500 . ?
C24 O25 1.2488(17) . ?
C24 C241 1.533(2) . ?
C241 F243 1.3205(17) . ?
C241 F242 1.3314(19) . ?
C241 F241 1.3337(19) . ?
N31 C312 1.4765(18) . ?
N31 C311 1.4791(18) . ?
N31 C32 1.4798(18) . ?
C311 H31A 0.9800 . ?
C311 H31B 0.9800 . ?
C311 H31C 0.9800 . ?
C312 H31D 0.9800 . ?
C312 H31E 0.9800 . ?
C312 H31F 0.9800 . ?
C32 C33 1.519(2) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 N34 1.4836(19) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
N34 C341 1.4798(18) . ?
N34 C342 1.4798(18) . ?
C341 H34A 0.9800 . ?
C341 H34B 0.9800 . ?
C341 H34C 0.9800 . ?
C342 H34D 0.9800 . ?
C342 H34E 0.9800 . ?
C342 H34F 0.9800 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C341 H34B F121 0.98 2.62 3.4088(18) 137.7 4_565
C342 H34F F222 0.98 2.64 3.540(2) 153.0 2_646
C311 H31A F143 0.98 2.65 3.5219(19) 148.2 3_657
C311 H31B F242 0.98 2.56 3.3033(18) 132.7 3_657
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O21 Co1 O11 C12 150.40(10) . . . . ?
O15 Co1 O11 C12 -26.41(10) . . . . ?
O25 Co1 O11 C12 63.65(10) . . . . ?
N34 Co1 O11 C12 -119.90(11) . . . . ?
N31 Co1 O11 C12 -26.5(6) . . . . ?
Co1 O11 C12 C13 21.5(2) . . . . ?
Co1 O11 C12 C121 -160.02(9) . . . . ?
O11 C12 C121 F123 -62.73(16) . . . . ?
C13 C12 C121 F123 115.95(14) . . . . ?
O11 C12 C121 F121 176.51(12) . . . . ?
C13 C12 C121 F121 -4.80(19) . . . . ?
O11 C12 C121 F122 55.73(16) . . . . ?
C13 C12 C121 F122 -125.58(14) . . . . ?
O11 C12 C13 C14 0.4(2) . . . . ?
C121 C12 C13 C14 -178.07(13) . . . . ?
C12 C13 C14 O15 -7.9(2) . . . . ?
C12 C13 C14 C141 168.59(13) . . . . ?
O15 C14 C141 F143 -32.21(16) . . . . ?
C13 C14 C141 F143 150.83(12) . . . . ?
O15 C14 C141 F142 -153.69(12) . . . . ?
C13 C14 C141 F142 29.35(17) . . . . ?
O15 C14 C141 F141 86.70(14) . . . . ?
C13 C14 C141 F141 -90.26(15) . . . . ?
C13 C14 O15 Co1 -8.8(2) . . . . ?
C141 C14 O15 Co1 174.60(8) . . . . ?
O21 Co1 O15 C14 -33.2(6) . . . . ?
O11 Co1 O15 C14 20.89(11) . . . . ?
O25 Co1 O15 C14 -62.78(11) . . . . ?
N34 Co1 O15 C14 116.64(11) . . . . ?
N31 Co1 O15 C14 -159.11(11) . . . . ?
O15 Co1 O21 C22 -12.8(6) . . . . ?
O11 Co1 O21 C22 -66.84(11) . . . . ?
O25 Co1 O21 C22 16.77(11) . . . . ?
N34 Co1 O21 C22 -162.77(11) . . . . ?
N31 Co1 O21 C22 112.93(11) . . . . ?
Co1 O21 C22 C23 -4.2(2) . . . . ?
Co1 O21 C22 C221 178.00(9) . . . . ?
O21 C22 C221 F223 -167.80(13) . . . . ?
C23 C22 C221 F223 14.19(19) . . . . ?
O21 C22 C221 F222 -46.18(17) . . . . ?
C23 C22 C221 F222 135.81(14) . . . . ?
O21 C22 C221 F221 72.15(16) . . . . ?
C23 C22 C221 F221 -105.86(15) . . . . ?
O21 C22 C23 C24 -8.5(2) . . . . ?
C221 C22 C23 C24 169.12(13) . . . . ?
C22 C23 C24 O25 -2.7(2) . . . . ?
C22 C23 C24 C241 177.66(14) . . . . ?
O25 C24 C241 F243 175.13(14) . . . . ?
C23 C24 C241 F243 -5.2(2) . . . . ?
O25 C24 C241 F242 -63.34(17) . . . . ?
C23 C24 C241 F242 116.33(15) . . . . ?
O25 C24 C241 F241 54.00(17) . . . . ?
C23 C24 C241 F241 -126.32(14) . . . . ?
C23 C24 O25 Co1 23.5(2) . . . . ?
C241 C24 O25 Co1 -156.87(10) . . . . ?
O21 Co1 O25 C24 -25.34(11) . . . . ?
O15 Co1 O25 C24 152.71(11) . . . . ?
O11 Co1 O25 C24 65.94(10) . . . . ?
N34 Co1 O25 C24 -17.8(7) . . . . ?
N31 Co1 O25 C24 -118.32(11) . . . . ?
O21 Co1 N31 C312 -16.62(9) . . . . ?
O15 Co1 N31 C312 160.19(9) . . . . ?
O11 Co1 N31 C312 160.3(5) . . . . ?
O25 Co1 N31 C312 70.60(9) . . . . ?
N34 Co1 N31 C312 -105.89(9) . . . . ?
O21 Co1 N31 C311 -137.55(10) . . . . ?
O15 Co1 N31 C311 39.26(10) . . . . ?
O11 Co1 N31 C311 39.3(6) . . . . ?
O25 Co1 N31 C311 -50.33(10) . . . . ?
N34 Co1 N31 C311 133.18(10) . . . . ?
O21 Co1 N31 C32 103.20(9) . . . . ?
O15 Co1 N31 C32 -79.99(9) . . . . ?
O11 Co1 N31 C32 -79.9(6) . . . . ?
O25 Co1 N31 C32 -169.58(9) . . . . ?
N34 Co1 N31 C32 13.93(9) . . . . ?
C312 N31 C32 C33 79.44(15) . . . . ?
C311 N31 C32 C33 -161.53(12) . . . . ?
Co1 N31 C32 C33 -40.90(13) . . . . ?
N31 C32 C33 N34 58.72(16) . . . . ?
C32 C33 N34 C341 -162.58(12) . . . . ?
C32 C33 N34 C342 79.09(15) . . . . ?
C32 C33 N34 Co1 -41.48(13) . . . . ?
O21 Co1 N34 C341 40.62(10) . . . . ?
O15 Co1 N34 C341 -137.40(10) . . . . ?
O11 Co1 N34 C341 -50.27(10) . . . . ?
O25 Co1 N34 C341 33.1(7) . . . . ?
N31 Co1 N34 C341 133.98(10) . . . . ?
O21 Co1 N34 C342 161.49(9) . . . . ?
O15 Co1 N34 C342 -16.54(9) . . . . ?
O11 Co1 N34 C342 70.59(9) . . . . ?
O25 Co1 N34 C342 154.0(6) . . . . ?
N31 Co1 N34 C342 -105.15(10) . . . . ?
O21 Co1 N34 C33 -78.57(9) . . . . ?
O15 Co1 N34 C33 103.40(9) . . . . ?
O11 Co1 N34 C33 -169.47(9) . . . . ?
O25 Co1 N34 C33 -86.1(7) . . . . ?
N31 Co1 N34 C33 14.79(9) . . . . ?
