#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:13:32 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179051 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/13/4301314.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4301314
loop_
_publ_author_name
'Cory A. Black'
'José Sánchez Costa'
'Wen Tian Fu'
'Chiara Massera'
'Olivier Roubeau'
'Simon J. Teat'
'Guillem Aromí'
'Patrick Gamez'
'Jan Reedijk'
_publ_contact_author             'Reedijk, J.'
_publ_contact_author_email       reedijk@chem.leidenuniv.nl
_publ_section_title
;
3-D Lanthanide Metal-Organic Frameworks: Structure, Photoluminescence, and
Magnetism
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1062
_journal_page_last               1068
_journal_paper_doi               10.1021/ic8017826
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C39 H50 Eu2 N8 O17'
_chemical_formula_sum            'C39 H50 Eu2 N8 O17'
_chemical_formula_weight         1206.80
_chemical_name_common            'compound 2.2dmf'
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.237(2)
_cell_angle_beta                 110.087(2)
_cell_angle_gamma                99.626(2)
_cell_formula_units_Z            1
_cell_length_a                   10.4692(6)
_cell_length_b                   11.2307(7)
_cell_length_c                   12.7358(8)
_cell_measurement_reflns_used    9957
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      33.30
_cell_measurement_theta_min      3.12
_cell_volume                     1334.08(14)
_computing_cell_refinement       'Bruker SAINT v7.34a'
_computing_data_collection       'Bruker APEX 2'
_computing_data_reduction        'Bruker SAINT v7.34a'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL & local programs'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'SIR97 through WinGX'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'Bruker APEX II CCD diffractometer'
_diffrn_measurement_method       'ω rotation with narrow frames'
_diffrn_radiation_monochromator  'silicon 111'
_diffrn_radiation_source         'Advanced Light Source station 11.3.1'
_diffrn_radiation_type           synchrotron
_diffrn_radiation_wavelength     0.77490
_diffrn_reflns_av_R_equivalents  0.0517
_diffrn_reflns_av_sigmaI/netI    0.0650
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            19042
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         33.60
_diffrn_reflns_theta_min         3.12
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.991
_exptl_absorpt_correction_T_max  0.80
_exptl_absorpt_correction_T_min  0.76
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS 2004/1 Bruker AXS, Madison, WI, US'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.502
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             602
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.560
_refine_diff_density_min         -1.001
_refine_diff_density_rms         0.196
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         7929
_refine_ls_number_restraints     499
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0526
_refine_ls_R_factor_gt           0.0506
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1076P)²+0.2364P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1526
_refine_ls_wR_factor_ref         0.1548
_reflns_number_gt                7327
_reflns_number_total             7929
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic8017826_si_002_3.cif
_cod_data_source_block           2.2dmf
_cod_database_code               4301314
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.394075(16) 0.450620(15) 0.324621(14) 0.02601(9) Uani 1 1 d . . .
O1 O 0.3474(3) 0.4980(3) 0.4939(3) 0.0367(7) Uani 1 1 d U . .
O2 O 0.3793(3) 0.5658(4) 0.6771(3) 0.0419(8) Uani 1 1 d U . .
O3 O 0.4292(4) 0.2771(3) 0.4037(3) 0.0443(8) Uani 1 1 d U I .
O4 O 0.4996(4) 0.3281(3) 0.5968(3) 0.0434(8) Uani 1 1 d U . .
O5 O 0.1637(4) 0.2932(4) 0.2344(4) 0.0564(11) Uani 1 1 d U I .
O6 O 0.3177(4) 0.2625(3) 0.1584(3) 0.0427(8) Uani 1 1 d U I .
O7 O 0.4182(5) 0.5286(4) 0.1637(3) 0.0530(9) Uani 1 1 d DU I .
O8 O 0.2068(16) 0.5615(12) 0.2611(12) 0.056(2) Uani 0.50 1 d PDU I 1
O8' O 0.1994(18) 0.5344(12) 0.2400(12) 0.058(3) Uani 0.50 1 d PDU I 2
O9 O -0.096(3) 0.737(3) 0.3453(18) 0.094(7) Uiso 0.25 1 d PDU J 1
O9' O -0.148(3) 0.772(3) 0.3522(18) 0.099(7) Uiso 0.25 1 d PDU K 2
C1 C 0.2986(4) 0.5278(4) 0.5698(4) 0.0344(8) Uani 1 1 d U . .
C2 C 0.1442(4) 0.5144(5) 0.5346(4) 0.0351(8) Uani 1 1 d U . .
C3 C 0.0900(5) 0.5604(6) 0.6159(4) 0.0438(11) Uani 1 1 d U . .
H3 H 0.1504 0.6010 0.6946 0.053 Uiso 0.50 1 calc PR G 1
C4 C -0.0554(5) 0.5452(6) 0.5788(4) 0.0438(11) Uani 1 1 d U . .
H4 H -0.0936 0.5767 0.6329 0.053 Uiso 1 1 calc R . .
C5 C 0.4690(6) 0.2531(4) 0.4994(4) 0.0401(10) Uani 1 1 d U . .
C6 C 0.4834(6) 0.1203(4) 0.4978(4) 0.0413(10) Uani 1 1 d U . .
C7 C 0.4873(7) 0.0401(5) 0.3998(5) 0.0513(13) Uani 1 1 d U . .
H7 H 0.4795 0.0674 0.3323 0.062 Uiso 0.50 1 calc PR E 1
C8 C 0.5027(8) -0.0795(5) 0.4035(5) 0.0530(14) Uani 1 1 d U . .
H8 H 0.5039 -0.1347 0.3372 0.064 Uiso 1 1 calc R . .
C9 C 0.2001(5) 0.2275(5) 0.1646(4) 0.0409(10) Uani 1 1 d DU I .
C10 C 0.0961(5) 0.1098(5) 0.0792(4) 0.0437(11) Uani 1 1 d DU . .
C11 C 0.1375(6) 0.0292(5) 0.0066(4) 0.0562(14) Uani 1 1 d DU B .
H11 H 0.2316 0.0481 0.0114 0.067 Uiso 0.80 1 calc PR A 1
C12 C 0.0398(6) -0.0800(6) -0.0736(5) 0.0584(15) Uani 1 1 d DU . .
H12 H 0.0674 -0.1337 -0.1245 0.070 Uiso 0.70 1 calc PR C 1
C13 C 0.5132(9) 0.6035(7) 0.1659(6) 0.0718(18) Uani 1 1 d DU . .
H13 H 0.5983 0.6215 0.2322 0.086 Uiso 1 1 calc R I .
C14 C 0.3934(16) 0.6434(14) -0.0164(10) 0.136(5) Uani 1 1 d DU . .
C15 C 0.6441(16) 0.7556(14) 0.0981(12) 0.138(5) Uani 1 1 d DU . .
C16 C 0.1929(15) 0.6602(14) 0.2647(13) 0.072(3) Uani 0.50 1 d PDU I 1
H16 H 0.2608 0.7231 0.3309 0.087 Uiso 0.50 1 calc PR I 1
C16' C 0.1914(17) 0.6270(15) 0.2167(11) 0.076(3) Uani 0.50 1 d PDU I 2
H16' H 0.2782 0.6865 0.2383 0.092 Uiso 0.50 1 calc PR I 2
C17 C 0.103(2) 0.8372(16) 0.2177(17) 0.086(4) Uani 0.50 1 d PDU I 1
C17' C 0.102(3) 0.7901(19) 0.146(2) 0.115(5) Uani 0.50 1 d PDU I 2
C18 C -0.014(3) 0.622(2) 0.0873(18) 0.119(5) Uani 0.50 1 d PDU I 1
C18' C -0.063(2) 0.588(2) 0.124(2) 0.112(5) Uani 0.50 1 d PDU I 2
C19 C 0.000(3) 0.781(3) 0.4334(18) 0.082(5) Uiso 0.25 1 d PDU J 1
H19 H 0.0875 0.7682 0.4326 0.099 Uiso 0.25 1 calc PR J 1
C19' C -0.121(2) 0.811(4) 0.4495(18) 0.078(5) Uiso 0.25 1 d PDU K 2
H19' H -0.1980 0.8174 0.4717 0.094 Uiso 0.25 1 calc PR K 2
C20 C -0.116(3) 0.858(3) 0.554(3) 0.078(7) Uiso 0.25 1 d PDU J 1
C20' C 0.130(3) 0.854(4) 0.513(3) 0.087(7) Uiso 0.25 1 d PDU K 2
C21 C 0.147(3) 0.902(4) 0.629(3) 0.097(8) Uiso 0.25 1 d PDU J 1
C21' C 0.007(4) 0.888(4) 0.652(2) 0.100(8) Uiso 0.25 1 d PDU K 2
N1 N 0.1690(12) 0.6225(13) 0.7296(9) 0.066(3) Uani 0.50 1 d PU H 2
H1A H 0.2612 0.6361 0.7565 0.079 Uiso 0.50 1 calc PR H 2
H1B H 0.1279 0.6490 0.7762 0.079 Uiso 0.50 1 calc PR H 2
N2 N 0.4782(15) 0.0770(11) 0.2938(9) 0.064(3) Uani 0.50 1 d PU F 2
H2A H 0.4825 0.0239 0.2351 0.077 Uiso 0.50 1 calc PR F 2
H2B H 0.4684 0.1522 0.2888 0.077 Uiso 0.50 1 calc PR F 2
N3 N 0.276(2) 0.0534(17) 0.0101(15) 0.066(6) Uani 0.20 1 d PDU B 2
H3A H 0.3390 0.1213 0.0593 0.079 Uiso 0.20 1 calc PR B 2
H3B H 0.2983 0.0006 -0.0369 0.079 Uiso 0.20 1 calc PR B 2
N3' N 0.0889(18) -0.1600(16) -0.1457(13) 0.083(5) Uani 0.30 1 d PDU D 2
H3A' H 0.0316 -0.2306 -0.1953 0.099 Uiso 0.30 1 calc PR D 2
H3B' H 0.1762 -0.1382 -0.1400 0.099 Uiso 0.30 1 calc PR D 2
N4 N 0.5173(10) 0.6664(8) 0.0880(7) 0.103(2) Uani 1 1 d DU I .
N5 N 0.0980(14) 0.7028(13) 0.1925(12) 0.085(3) Uani 0.50 1 d PDU I 1
N5' N 0.0759(15) 0.6622(14) 0.1630(10) 0.087(3) Uani 0.50 1 d PDU I 2
N6 N 0.0068(13) 0.8477(13) 0.5357(11) 0.073(3) Uiso 0.25 1 d PDU J 1
N6' N 0.0068(13) 0.8477(13) 0.5357(11) 0.073(3) Uiso 0.25 1 d PDU K 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C -0.0020 0.0020
'WCROMER Program in WinGX L.Kissel & R.H.Pratt Acta Cryst A46 170 1990'
H H 0.0000 0.0000
'WCROMER Program in WinGX L.Kissel & R.H.Pratt Acta Cryst A46 170 1990'
N N -0.0031 0.0041
'WCROMER Program in WinGX L.Kissel & R.H.Pratt Acta Cryst A46 170 1990'
O O -0.0042 0.0076
'WCROMER Program in WinGX L.Kissel & R.H.Pratt Acta Cryst A46 170 1990'
Eu Eu -0.2297 4.2695
'WCROMER Program in WinGX L.Kissel & R.H.Pratt Acta Cryst A46 170 1990'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O1 75.10(11) . 2_666 ?
O1 Eu1 O7 144.79(14) . . ?
O1 Eu1 O7 110.97(13) 2_666 . ?
O1 Eu1 O8 79.9(3) . . ?
O1 Eu1 O8 136.6(3) 2_666 . ?
O1 Eu1 O8' 85.2(4) . . ?
O1 Eu1 O8' 144.3(3) 2_666 . ?
O1 Eu1 C1 99.94(12) . 2_666 ?
O1 Eu1 C1 24.91(11) 2_666 2_666 ?
O2 Eu1 O1 124.40(12) 2_666 . ?
O2 Eu1 O1 49.55(11) 2_666 2_666 ?
O2 Eu1 O7 72.89(14) 2_666 . ?
O2 Eu1 O8 143.0(4) 2_666 . ?
O2 Eu1 O8' 142.5(4) 2_666 . ?
O2 Eu1 C1 24.65(12) 2_666 2_666 ?
O3 Eu1 O1 75.83(13) . . ?
O3 Eu1 O1 67.00(12) . 2_666 ?
O3 Eu1 O2 77.96(14) . 2_666 ?
O3 Eu1 O7 139.19(14) . . ?
O3 Eu1 O8 138.6(4) . . ?
O3 Eu1 O8' 136.5(4) . . ?
O3 Eu1 C1 71.29(14) . 2_666 ?
O4 Eu1 O1 77.37(12) 2_666 . ?
O4 Eu1 O1 68.05(12) 2_666 2_666 ?
O4 Eu1 O2 85.56(14) 2_666 2_666 ?
O4 Eu1 O3 132.03(12) 2_666 . ?
O4 Eu1 O7 73.63(13) 2_666 . ?
O4 Eu1 O8 72.2(3) 2_666 . ?
O4 Eu1 O8' 78.8(4) 2_666 . ?
O4 Eu1 C1 75.15(13) 2_666 2_666 ?
O5 Eu1 O1 87.17(13) . . ?
O5 Eu1 O1 140.10(15) . 2_666 ?
O5 Eu1 O2 130.31(14) . 2_666 ?
O5 Eu1 O3 74.16(16) . . ?
O5 Eu1 O4 142.66(15) . 2_666 ?
O5 Eu1 O7 104.14(16) . . ?
O5 Eu1 O8 71.7(4) . . ?
O5 Eu1 O8' 66.0(4) . . ?
O5 Eu1 C1 141.64(15) . 2_666 ?
O5 Eu1 C9 26.04(15) . . ?
O6 Eu1 O1 134.20(12) . . ?
O6 Eu1 O1 120.28(12) . 2_666 ?
O6 Eu1 O2 80.50(13) . 2_666 ?
O6 Eu1 O3 73.12(12) . . ?
O6 Eu1 O4 147.64(12) . 2_666 ?
O6 Eu1 O5 52.44(13) . . ?
O6 Eu1 O7 74.40(13) . . ?
O6 Eu1 O8 102.6(3) . . ?
O6 Eu1 O8' 94.9(3) . . ?
O6 Eu1 C1 100.98(13) . 2_666 ?
O6 Eu1 C9 26.45(14) . . ?
O7 Eu1 O8 72.6(4) . . ?
O7 Eu1 O8' 70.1(4) . . ?
O8 Eu1 O8' 7.8(5) . . ?
C1 Eu1 O7 91.57(15) 2_666 . ?
C1 Eu1 O8 146.6(3) 2_666 . ?
C1 Eu1 O8' 151.6(4) 2_666 . ?
C9 Eu1 O1 110.47(14) . . ?
C9 Eu1 O1 134.14(13) . 2_666 ?
C9 Eu1 O2 105.42(15) . 2_666 ?
C9 Eu1 O3 70.53(13) . . ?
C9 Eu1 O4 157.19(14) . 2_666 ?
C9 Eu1 O7 90.29(14) . . ?
C9 Eu1 O8 87.8(4) . . ?
C9 Eu1 O8' 80.5(3) . . ?
C9 Eu1 C1 122.35(14) . 2_666 ?
Eu1 O1 Eu1 104.90(11) . 2_666 ?
Eu1 O1 C1 167.5(3) . . ?
Eu1 O1 C1 86.8(3) 2_666 . ?
Eu1 O2 C1 103.0(3) 2_666 . ?
Eu1 O3 C5 140.0(3) . . ?
Eu1 O4 C5 132.8(3) 2_666 . ?
Eu1 O5 C9 93.0(3) . . ?
Eu1 O6 C9 92.8(3) . . ?
Eu1 O7 C13 127.9(4) . . ?
Eu1 O8 C16 140.5(12) . . ?
Eu1 O8' C16' 133.1(13) . . ?
Eu1 C1 O1 68.3(2) 2_666 . ?
Eu1 C1 O2 52.3(2) 2_666 . ?
Eu1 C1 C2 171.0(3) 2_666 . ?
O1 C1 C2 119.9(4) . . ?
O2 C1 O1 120.5(4) . . ?
O2 C1 C2 119.5(4) . . ?
C1 C2 C3 120.7(4) . . ?
C1 C2 C4 119.1(4) . 2_566 ?
C3 C2 C4 120.2(4) . 2_566 ?
H3 C3 C4 120.8 . . ?
H3 C3 N1 4.2 . . ?
C2 C3 H3 120.8 . . ?
C2 C3 C4 118.4(4) . . ?
C2 C3 N1 124.7(6) . . ?
N1 C3 C4 116.8(6) . . ?
C2 C4 H4 119.3 2_566 . ?
C2 C4 C3 121.3(4) 2_566 . ?
C3 C4 H4 119.3 . . ?
O3 C5 C6 116.5(4) . . ?
O4 C5 O3 126.4(4) . . ?
O4 C5 C6 117.2(4) . . ?
C5 C6 C7 121.1(4) . . ?
C5 C6 C8 119.0(5) . 2_656 ?
C7 C6 C8 119.8(4) . 2_656 ?
H7 C7 C8 120.6 . . ?
H7 C7 N2 2.9 . . ?
C6 C7 H7 120.6 . . ?
C6 C7 C8 118.8(5) . . ?
C6 C7 N2 123.4(6) . . ?
N2 C7 C8 117.8(6) . . ?
C6 C8 H8 119.3 2_656 . ?
C6 C8 C7 121.4(5) 2_656 . ?
C7 C8 H8 119.3 . . ?
Eu1 C9 O5 60.9(3) . . ?
Eu1 C9 O6 60.7(2) . . ?
Eu1 C9 C10 179.4(4) . . ?
O5 C9 C10 118.8(5) . . ?
O6 C9 O5 121.4(4) . . ?
O6 C9 C10 119.5(5) . . ?
C9 C10 C11 120.0(5) . . ?
C9 C10 C12 120.2(5) . 2 ?
C11 C10 C12 119.7(5) . 2 ?
H11 C11 C12 120.1 . . ?
H11 C11 N3 2.2 . . ?
C10 C11 H11 120.1 . . ?
C10 C11 C12 119.8(5) . . ?
C10 C11 N3 122.2(8) . . ?
N3 C11 C12 117.9(9) . . ?
C10 C12 H12 119.8 2 . ?
C10 C12 C11 120.5(6) 2 . ?
C10 C12 N3' 122.2(8) 2 . ?
C11 C12 H12 119.8 . . ?
H12 C12 N3' 3.1 . . ?
C11 C12 N3' 117.3(8) . . ?
O7 C13 H13 115.7 . . ?
O7 C13 N4 128.7(8) . . ?
H13 C13 N4 115.7 . . ?
O8 C16 H16 114.4 . . ?
O8 C16 N5 131.1(16) . . ?
H16 C16 N5 114.4 . . ?
O8' C16' H16' 115.7 . . ?
O8' C16' N5' 128.5(17) . . ?
H16' C16' N5' 115.7 . . ?
O9 C19 H19 115.2 . . ?
O9 C19 N6 130(3) . . ?
H19 C19 N6 115.2 . . ?
O9' C19' H19' 116.2 . . ?
H1A N1 H1B 120.0 . . ?
C3 N1 H1A 120.0 . . ?
C3 N1 H1B 120.0 . . ?
H2A N2 H2B 120.0 . . ?
C7 N2 H2A 120.0 . . ?
C7 N2 H2B 120.0 . . ?
H3A N3 H3B 120.0 . . ?
C11 N3 H3A 120.0 . . ?
C11 N3 H3B 120.0 . . ?
H3A' N3' H3B' 120.0 . . ?
C12 N3' H3A' 120.0 . . ?
C12 N3' H3B' 120.0 . . ?
C13 N4 C14 119.4(8) . . ?
C13 N4 C15 124.0(9) . . ?
C14 N4 C15 116.5(9) . . ?
C16 N5 C17 120.3(14) . . ?
C16 N5 C18 122.7(15) . . ?
C18 N5 C17 117.0(14) . . ?
C16' N5' C17' 115.2(14) . . ?
C16' N5' C18' 124.7(15) . . ?
C18' N5' C17' 120.0(15) . . ?
C19 N6 C20 120.9(17) . . ?
C19 N6 C21 117.2(17) . . ?
C20 N6 C21 121.8(18) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.352(3) . ?
Eu1 O1 2.768(3) 2_666 ?
Eu1 O2 2.418(3) 2_666 ?
Eu1 O3 2.387(3) . ?
Eu1 O4 2.399(3) 2_666 ?
Eu1 O5 2.478(4) . ?
Eu1 O6 2.473(3) . ?
Eu1 O7 2.452(4) . ?
Eu1 O8 2.483(12) . ?
Eu1 O8' 2.393(15) . ?
Eu1 C1 2.976(4) 2_666 ?
Eu1 C9 2.832(5) . ?
O1 Eu1 2.768(3) 2_666 ?
O1 C1 1.255(5) . ?
O2 Eu1 2.418(3) 2_666 ?
O2 C1 1.274(6) . ?
O3 C5 1.244(6) . ?
O4 Eu1 2.399(3) 2_666 ?
O4 C5 1.257(6) . ?
O5 C9 1.245(7) . ?
O6 C9 1.263(6) . ?
O7 C13 1.179(8) . ?
O8 C16 1.136(13) . ?
O8' C16' 1.144(13) . ?
O9 C19 1.166(16) . ?
O9' C19' 1.146(16) . ?
C1 Eu1 2.976(4) 2_666 ?
C1 C2 1.494(6) . ?
C2 C3 1.399(6) . ?
C2 C4 1.375(6) 2_566 ?
C3 H3 0.9500 . ?
C3 C4 1.399(6) . ?
C3 N1 1.363(11) . ?
C4 H4 0.9500 . ?
C4 C2 1.375(6) 2_566 ?
C5 C6 1.522(6) . ?
C6 C7 1.407(8) . ?
C6 C8 1.390(7) 2_656 ?
C7 H7 0.9500 . ?
C7 C8 1.387(7) . ?
C7 N2 1.465(11) . ?
C8 H8 0.9500 . ?
C8 C6 1.390(7) 2_656 ?
C9 C10 1.503(7) . ?
C10 C11 1.393(8) . ?
C10 C12 1.380(8) 2 ?
C11 H11 0.9500 . ?
C11 C12 1.403(7) . ?
C11 N3 1.41(2) . ?
C12 H12 0.9500 . ?
C12 C10 1.380(8) 2 ?
C12 N3' 1.438(19) . ?
C13 H13 0.9500 . ?
C13 N4 1.334(8) . ?
C16 H16 0.9500 . ?
C16 N5 1.328(13) . ?
C16' H16' 0.9500 . ?
C16' N5' 1.335(13) . ?
C19 H19 0.9500 . ?
C19 N6 1.344(15) . ?
C19' H19' 0.9500 . ?
N1 H1A 0.8800 . ?
N1 H1B 0.8800 . ?
N2 H2A 0.8800 . ?
N2 H2B 0.8800 . ?
N3 H3A 0.8800 . ?
N3 H3B 0.8800 . ?
N3' H3A' 0.8800 . ?
N3' H3B' 0.8800 . ?
N4 C14 1.444(13) . ?
N4 C15 1.472(13) . ?
N5 C17 1.468(16) . ?
N5' C17' 1.489(17) . ?
N5 C18 1.443(17) . ?
N5' C18' 1.416(17) . ?
N6 C20 1.405(17) . ?
N6 C21 1.467(18) . ?
