#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:14:46 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179052 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/14/4301448.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4301448
loop_
_publ_author_name
'Jacob Schneider'
'Pingwu Du'
'Xiaoyong Wang'
'William W. Brennessel'
'Richard Eisenberg'
_publ_section_title
;
Synthesis, Electrochemistry, Photophysics, and Solvatochromism in New
Cyclometalated 6-Phenyl-4-(p-R-phenyl)-2,2'-bipyridyl (R = Me, COOMe,
P(O)(OEt)2) (CNN) Platinum(II) Thiophenolate Chromophores
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1498
_journal_page_last               1506
_journal_paper_doi               10.1021/ic801767q
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C23 H17 Cl0.89 I0.11 N2 Pt, C2 H3 N'
_chemical_formula_sum            'C25 H20 Cl0.89 I0.11 N3 Pt'
_chemical_formula_weight         602.58
_chemical_name_common            eisjs37
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.315(3)
_cell_length_b                   6.6392(17)
_cell_length_c                   23.221(6)
_cell_measurement_reflns_used    4045
_cell_measurement_temperature    100.0(1)
_cell_measurement_theta_max      32.89
_cell_measurement_theta_min      3.06
_cell_volume                     2052.8(9)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100.0(1)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker SMART APEX II CCD Platform'
_diffrn_measurement_method       'Area detector, ω scans per φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0358
_diffrn_reflns_av_sigmaI/netI    0.0202
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            35175
_diffrn_reflns_theta_full        32.56
_diffrn_reflns_theta_max         32.56
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    7.128
_exptl_absorpt_correction_T_max  0.6544
_exptl_absorpt_correction_T_min  0.1317
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2007)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.950
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1159
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.06
_refine_diff_density_max         2.140
_refine_diff_density_min         -1.288
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     184
_refine_ls_number_reflns         3979
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0295
_refine_ls_R_factor_gt           0.0222
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0174P)²+3.2653P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0450
_refine_ls_wR_factor_ref         0.0470
_reflns_number_gt                3466
_reflns_number_total             3979
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic801767q_si_002_2.cif
_cod_data_source_block           eisjs37
_cod_original_cell_volume        2052.7(9)
_cod_database_code               4301448
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.019500(9) 0.7500 0.919695(5) 0.01567(3) Uani 1 2 d S . .
Cl1 Cl -0.10454(5) 0.7500 0.84675(3) 0.0241(2) Uani 0.8948(16) 2 d SP A 1
I1 I -0.10454(5) 0.7500 0.84675(3) 0.0241(2) Uani 0.1052(16) 2 d SP A 5
N1 N 0.12059(19) 0.7500 0.98071(11) 0.0150(5) Uani 1 2 d S A .
N2 N -0.0731(2) 0.7500 0.99338(12) 0.0181(5) Uani 1 2 d S A .
C1 C 0.1412(2) 0.7500 0.86973(13) 0.0183(6) Uani 1 2 d S A .
C2 C 0.1502(3) 0.7500 0.80964(14) 0.0258(7) Uani 1 2 d S . .
H2A H 0.0913 0.7500 0.7866 0.031 Uiso 1 2 calc SR A .
C3 C 0.2440(3) 0.7500 0.78313(16) 0.0348(9) Uani 1 2 d S A .
H3A H 0.2481 0.7500 0.7423 0.042 Uiso 1 2 calc SR . .
C4 C 0.3317(3) 0.7500 0.81551(15) 0.0324(9) Uani 1 2 d S . .
H4A H 0.3953 0.7500 0.7970 0.039 Uiso 1 2 calc SR A .
C5 C 0.3256(3) 0.7500 0.87542(14) 0.0251(7) Uani 1 2 d S A .
H5A H 0.3851 0.7500 0.8979 0.030 Uiso 1 2 calc SR . .
C6 C 0.2321(2) 0.7500 0.90220(14) 0.0182(6) Uani 1 2 d S . .
C7 C 0.2187(2) 0.7500 0.96485(13) 0.0162(5) Uani 1 2 d S A .
C8 C 0.2920(2) 0.7500 1.00795(13) 0.0180(6) Uani 1 2 d S . .
H8A H 0.3610 0.7500 0.9976 0.022 Uiso 1 2 calc SR A .
C9 C 0.2647(2) 0.7500 1.06647(13) 0.0170(6) Uani 1 2 d S A .
C10 C 0.1618(2) 0.7500 1.07961(13) 0.0170(5) Uani 1 2 d S . .
H10A H 0.1409 0.7500 1.1187 0.020 Uiso 1 2 calc SR A .
C11 C 0.0902(2) 0.7500 1.03626(13) 0.0160(5) Uani 1 2 d S A .
C12 C -0.0192(2) 0.7500 1.04333(13) 0.0161(5) Uani 1 2 d S . .
C13 C -0.0678(2) 0.7500 1.09643(14) 0.0192(6) Uani 1 2 d S A .
H13A H -0.0296 0.7500 1.1310 0.023 Uiso 1 2 calc SR . .
C14 C -0.1717(3) 0.7500 1.09903(15) 0.0222(6) Uani 1 2 d S . .
H14A H -0.2052 0.7500 1.1351 0.027 Uiso 1 2 calc SR A .
C15 C -0.2260(3) 0.7500 1.04798(15) 0.0222(6) Uani 1 2 d S A .
H15A H -0.2973 0.7500 1.0485 0.027 Uiso 1 2 calc SR . .
C16 C -0.1742(2) 0.7500 0.99633(15) 0.0198(6) Uani 1 2 d S . .
H16A H -0.2115 0.7500 0.9615 0.024 Uiso 1 2 calc SR A .
C17 C 0.3419(2) 0.7500 1.11273(13) 0.0171(6) Uani 1 2 d S . .
C18 C 0.4443(3) 0.7500 1.10011(14) 0.0198(6) Uani 1 2 d S A .
H18A H 0.4656 0.7500 1.0611 0.024 Uiso 1 2 calc SR . .
C19 C 0.5156(3) 0.7500 1.14372(14) 0.0227(6) Uani 1 2 d S . .
H19A H 0.5848 0.7500 1.1338 0.027 Uiso 1 2 calc SR A .
C20 C 0.4885(3) 0.7500 1.20183(14) 0.0222(6) Uani 1 2 d S A .
C21 C 0.3864(3) 0.7500 1.21428(14) 0.0279(8) Uani 1 2 d S . .
H21A H 0.3654 0.7500 1.2534 0.033 Uiso 1 2 calc SR A .
C22 C 0.3147(3) 0.7500 1.17135(14) 0.0248(7) Uani 1 2 d S A .
H22A H 0.2456 0.7500 1.1816 0.030 Uiso 1 2 calc SR . .
C23 C 0.5670(3) 0.7500 1.24847(15) 0.0301(8) Uani 1 2 d S . .
H23A H 0.5669 0.6193 1.2681 0.045 Uiso 0.50 1 calc PR A -1
H23B H 0.5519 0.8567 1.2763 0.045 Uiso 0.50 1 calc PR A -1
H23C H 0.6332 0.7740 1.2314 0.045 Uiso 0.50 1 calc PR A -1
N3 N 0.5654(3) 0.7500 0.96791(15) 0.0350(8) Uani 1 2 d S . .
C24 C 0.5856(3) 0.7500 0.92019(16) 0.0254(7) Uani 1 2 d S . .
C25 C 0.6116(3) 0.7500 0.85891(15) 0.0296(8) Uani 1 2 d S . .
H25A H 0.6836 0.7235 0.8545 0.044 Uiso 0.50 1 calc PR B -1
H25B H 0.5954 0.8816 0.8422 0.044 Uiso 0.50 1 calc PR B -1
H25C H 0.5731 0.6449 0.8391 0.044 Uiso 0.50 1 calc PR B -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pt1 C1 82.08(12) . . ?
N1 Pt1 N2 79.31(11) . . ?
C1 Pt1 N2 161.38(12) . . ?
N1 Pt1 Cl1 179.25(8) . . ?
C1 Pt1 Cl1 98.67(9) . . ?
N2 Pt1 Cl1 99.95(8) . . ?
C11 N1 C7 123.2(3) . . ?
C11 N1 Pt1 119.0(2) . . ?
C7 N1 Pt1 117.8(2) . . ?
C16 N2 C12 118.8(3) . . ?
C16 N2 Pt1 128.7(2) . . ?
C12 N2 Pt1 112.5(2) . . ?
C2 C1 C6 117.0(3) . . ?
C2 C1 Pt1 130.5(3) . . ?
C6 C1 Pt1 112.5(2) . . ?
C3 C2 C1 121.2(3) . . ?
C3 C2 H2A 119.4 . . ?
C1 C2 H2A 119.4 . . ?
C2 C3 C4 121.0(3) . . ?
C2 C3 H3A 119.5 . . ?
C4 C3 H3A 119.5 . . ?
C3 C4 C5 119.4(4) . . ?
C3 C4 H4A 120.3 . . ?
C5 C4 H4A 120.3 . . ?
C6 C5 C4 119.9(3) . . ?
C6 C5 H5A 120.0 . . ?
C4 C5 H5A 120.0 . . ?
C5 C6 C1 121.5(3) . . ?
C5 C6 C7 123.5(3) . . ?
C1 C6 C7 115.0(3) . . ?
N1 C7 C8 118.5(3) . . ?
N1 C7 C6 112.7(3) . . ?
C8 C7 C6 128.8(3) . . ?
C7 C8 C9 120.8(3) . . ?
C7 C8 H8A 119.6 . . ?
C9 C8 H8A 119.6 . . ?
C10 C9 C8 117.5(3) . . ?
C10 C9 C17 121.2(3) . . ?
C8 C9 C17 121.3(3) . . ?
C11 C10 C9 120.9(3) . . ?
C11 C10 H10A 119.5 . . ?
C9 C10 H10A 119.5 . . ?
N1 C11 C10 119.1(3) . . ?
N1 C11 C12 113.9(3) . . ?
C10 C11 C12 127.0(3) . . ?
N2 C12 C13 120.6(3) . . ?
N2 C12 C11 115.3(3) . . ?
C13 C12 C11 124.1(3) . . ?
C14 C13 C12 120.2(3) . . ?
C14 C13 H13A 119.9 . . ?
C12 C13 H13A 119.9 . . ?
C13 C14 C15 118.9(3) . . ?
C13 C14 H14A 120.6 . . ?
C15 C14 H14A 120.6 . . ?
C16 C15 C14 118.7(3) . . ?
C16 C15 H15A 120.6 . . ?
C14 C15 H15A 120.6 . . ?
N2 C16 C15 122.8(3) . . ?
N2 C16 H16A 118.6 . . ?
C15 C16 H16A 118.6 . . ?
C18 C17 C22 117.0(3) . . ?
C18 C17 C9 121.6(3) . . ?
C22 C17 C9 121.4(3) . . ?
C19 C18 C17 121.0(3) . . ?
C19 C18 H18A 119.5 . . ?
C17 C18 H18A 119.5 . . ?
C18 C19 C20 121.8(3) . . ?
C18 C19 H19A 119.1 . . ?
C20 C19 H19A 119.1 . . ?
C21 C20 C19 117.0(3) . . ?
C21 C20 C23 122.0(3) . . ?
C19 C20 C23 121.0(3) . . ?
C22 C21 C20 121.7(3) . . ?
C22 C21 H21A 119.1 . . ?
C20 C21 H21A 119.1 . . ?
C21 C22 C17 121.4(3) . . ?
C21 C22 H22A 119.3 . . ?
C17 C22 H22A 119.3 . . ?
C20 C23 H23A 109.5 . . ?
C20 C23 H23B 109.5 . . ?
C20 C23 H23C 109.5 . . ?
N3 C24 C25 180.0(4) . . ?
C24 C25 H25A 109.5 . . ?
C24 C25 H25B 109.5 . . ?
C24 C25 H25C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N1 1.954(3) . ?
Pt1 C1 1.993(3) . ?
Pt1 N2 2.109(3) . ?
Pt1 Cl1 2.3657(7) . ?
N1 C11 1.352(4) . ?
N1 C7 1.358(4) . ?
N2 C16 1.348(4) . ?
N2 C12 1.364(4) . ?
C1 C2 1.400(4) . ?
C1 C6 1.426(4) . ?
C2 C3 1.392(5) . ?
C2 H2A 0.9500 . ?
C3 C4 1.389(5) . ?
C3 H3A 0.9500 . ?
C4 C5 1.393(5) . ?
C4 H4A 0.9500 . ?
C5 C6 1.392(5) . ?
C5 H5A 0.9500 . ?
C6 C7 1.466(4) . ?
C7 C8 1.398(4) . ?
C8 C9 1.407(4) . ?
C8 H8A 0.9500 . ?
C9 C10 1.404(4) . ?
C9 C17 1.486(4) . ?
C10 C11 1.387(4) . ?
C10 H10A 0.9500 . ?
C11 C12 1.465(5) . ?
C12 C13 1.393(4) . ?
C13 C14 1.384(5) . ?
C13 H13A 0.9500 . ?
C14 C15 1.388(5) . ?
C14 H14A 0.9500 . ?
C15 C16 1.383(5) . ?
C15 H15A 0.9500 . ?
C16 H16A 0.9500 . ?
C17 C18 1.395(5) . ?
C17 C22 1.408(4) . ?
C18 C19 1.388(5) . ?
C18 H18A 0.9500 . ?
C19 C20 1.397(5) . ?
C19 H19A 0.9500 . ?
C20 C21 1.390(5) . ?
C20 C23 1.505(5) . ?
C21 C22 1.380(5) . ?
C21 H21A 0.9500 . ?
C22 H22A 0.9500 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
N3 C24 1.140(5) . ?
C24 C25 1.464(5) . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Pt1 N1 C11 180.000(1) . . . . ?
N2 Pt1 N1 C11 0.000(1) . . . . ?
Cl1 Pt1 N1 C11 0.00(5) . . . . ?
C1 Pt1 N1 C7 0.000(1) . . . . ?
N2 Pt1 N1 C7 180.000(1) . . . . ?
Cl1 Pt1 N1 C7 180.00(5) . . . . ?
N1 Pt1 N2 C16 180.000(1) . . . . ?
C1 Pt1 N2 C16 180.000(2) . . . . ?
Cl1 Pt1 N2 C16 0.000(1) . . . . ?
N1 Pt1 N2 C12 0.000(1) . . . . ?
C1 Pt1 N2 C12 0.000(2) . . . . ?
Cl1 Pt1 N2 C12 180.000(1) . . . . ?
N1 Pt1 C1 C2 180.000(1) . . . . ?
N2 Pt1 C1 C2 180.000(2) . . . . ?
Cl1 Pt1 C1 C2 0.000(1) . . . . ?
N1 Pt1 C1 C6 0.0 . . . . ?
N2 Pt1 C1 C6 0.000(2) . . . . ?
Cl1 Pt1 C1 C6 180.0 . . . . ?
C6 C1 C2 C3 0.000(2) . . . . ?
Pt1 C1 C2 C3 180.000(1) . . . . ?
C1 C2 C3 C4 0.000(2) . . . . ?
C2 C3 C4 C5 0.000(2) . . . . ?
C3 C4 C5 C6 0.000(2) . . . . ?
C4 C5 C6 C1 0.000(2) . . . . ?
C4 C5 C6 C7 180.000(1) . . . . ?
C2 C1 C6 C5 0.000(2) . . . . ?
Pt1 C1 C6 C5 180.000(1) . . . . ?
C2 C1 C6 C7 180.000(1) . . . . ?
Pt1 C1 C6 C7 0.000(1) . . . . ?
C11 N1 C7 C8 0.000(2) . . . . ?
Pt1 N1 C7 C8 180.000(1) . . . . ?
C11 N1 C7 C6 180.000(1) . . . . ?
Pt1 N1 C7 C6 0.000(1) . . . . ?
C5 C6 C7 N1 180.000(1) . . . . ?
C1 C6 C7 N1 0.000(1) . . . . ?
C5 C6 C7 C8 0.000(2) . . . . ?
C1 C6 C7 C8 180.000(1) . . . . ?
N1 C7 C8 C9 0.000(2) . . . . ?
C6 C7 C8 C9 180.000(1) . . . . ?
C7 C8 C9 C10 0.000(2) . . . . ?
C7 C8 C9 C17 180.000(1) . . . . ?
C8 C9 C10 C11 0.000(2) . . . . ?
C17 C9 C10 C11 180.000(1) . . . . ?
C7 N1 C11 C10 0.000(2) . . . . ?
Pt1 N1 C11 C10 180.000(1) . . . . ?
C7 N1 C11 C12 180.000(1) . . . . ?
Pt1 N1 C11 C12 0.000(2) . . . . ?
C9 C10 C11 N1 0.000(2) . . . . ?
C9 C10 C11 C12 180.000(2) . . . . ?
C16 N2 C12 C13 0.000(2) . . . . ?
Pt1 N2 C12 C13 180.000(1) . . . . ?
C16 N2 C12 C11 180.000(1) . . . . ?
Pt1 N2 C12 C11 0.000(2) . . . . ?
N1 C11 C12 N2 0.000(2) . . . . ?
C10 C11 C12 N2 180.000(2) . . . . ?
N1 C11 C12 C13 180.000(2) . . . . ?
C10 C11 C12 C13 0.000(2) . . . . ?
N2 C12 C13 C14 0.000(2) . . . . ?
C11 C12 C13 C14 180.000(2) . . . . ?
C12 C13 C14 C15 0.000(2) . . . . ?
C13 C14 C15 C16 0.000(2) . . . . ?
C12 N2 C16 C15 0.000(2) . . . . ?
Pt1 N2 C16 C15 180.000(1) . . . . ?
C14 C15 C16 N2 0.000(2) . . . . ?
C10 C9 C17 C18 180.000(2) . . . . ?
C8 C9 C17 C18 0.000(2) . . . . ?
C10 C9 C17 C22 0.000(2) . . . . ?
C8 C9 C17 C22 180.000(2) . . . . ?
C22 C17 C18 C19 0.000(2) . . . . ?
C9 C17 C18 C19 180.000(2) . . . . ?
C17 C18 C19 C20 0.000(3) . . . . ?
C18 C19 C20 C21 0.000(2) . . . . ?
C18 C19 C20 C23 180.000(2) . . . . ?
C19 C20 C21 C22 0.000(2) . . . . ?
C23 C20 C21 C22 180.000(2) . . . . ?
C20 C21 C22 C17 0.000(2) . . . . ?
C18 C17 C22 C21 0.000(2) . . . . ?
C9 C17 C22 C21 180.000(2) . . . . ?
