#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:21:52 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179057 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/19/4301945.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4301945
loop_
_publ_author_name
'Yanling Guo'
'Wei Dou'
'Xiaoyan Zhou'
'Weisheng Liu'
'Wenwu Qin'
'Zhipeng Zang'
'Hongrui Zhang'
'Daqi Wang'
_publ_contact_author_address
; Department of Chemistry and State Key Laboratory 
  of Applied Organic Chemistry, 
  Lanzhou University, Lanzhou 210093, China 
  State Key Laboratory of Coordination Chemistry,
  Nanjing University, Nanjing 210093, China
;
_publ_contact_author_email       ' liuws@lzu.edu.cn '
_publ_contact_author_fax         ' +86-931-8912582 '
_publ_contact_author_name        'Weisheng Liu'
_publ_contact_author_phone       ' +86-931-8915151 '
_publ_section_title
;
Influence of Conformational Flexibility on Self-Assembly and Luminescence
Properties of Lanthanide Coordination Polymers with Flexibleexo-Bidentate
Biphenol Derivatives
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3581
_journal_page_last               3590
_journal_paper_doi               10.1021/ic802060e
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C46 H44 Br2 Eu N5 O16'
_chemical_formula_weight         1234.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.629(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.6969(11)
_cell_length_b                   21.820(3)
_cell_length_c                   18.2704(18)
_cell_measurement_reflns_used    1967
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      25.701
_cell_measurement_theta_min      2.205
_cell_volume                     5056.4(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2594
_diffrn_reflns_av_sigmaI/netI    0.3204
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            21022
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    2.893
_exptl_absorpt_correction_T_max  0.6094
_exptl_absorpt_correction_T_min  0.4773
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.622
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             2464
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.549
_refine_diff_density_min         -1.007
_refine_diff_density_rms         0.150
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.990
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     629
_refine_ls_number_reflns         8749
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.990
_refine_ls_R_factor_all          0.2194
_refine_ls_R_factor_gt           0.0966
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0001P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1832
_refine_ls_wR_factor_ref         0.2002
_reflns_number_gt                2355
_reflns_number_total             8749
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic802060e_si_001_3.cif
_cod_data_source_block           '[3]'
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5056.4(9)
_cod_database_code               4301945
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C39 C 0.7583(12) 0.9855(9) 0.7852(7) 0.088(6) Uani 1 1 d G . .
C40 C 0.7662(14) 1.0483(9) 0.7745(7) 0.096(6) Uani 1 1 d G . .
H40 H 0.7055 1.0718 0.7673 0.115 Uiso 1 1 calc R . .
C41 C 0.8647(19) 1.0760(6) 0.7745(7) 0.122(8) Uani 1 1 d G . .
H41 H 0.8700 1.1181 0.7673 0.147 Uiso 1 1 calc R . .
C42 C 0.9554(13) 1.0409(11) 0.7852(7) 0.120(8) Uani 1 1 d G . .
H42 H 1.0214 1.0594 0.7852 0.144 Uiso 1 1 calc R . .
C43 C 0.9475(14) 0.9780(10) 0.7960(7) 0.122(8) Uani 1 1 d G . .
H43 H 1.0082 0.9545 0.8031 0.146 Uiso 1 1 calc R . .
C44 C 0.8490(19) 0.9503(5) 0.7960(7) 0.107(7) Uani 1 1 d G . .
H44 H 0.8437 0.9082 0.8032 0.128 Uiso 1 1 calc R . .
Eu1 Eu 0.38154(7) 0.88916(4) 0.87886(5) 0.0741(4) Uani 1 1 d . . .
Br1 Br 1.05866(18) 0.49982(11) 0.84658(14) 0.1169(9) Uani 1 1 d . . .
Br2 Br 0.4295(2) 0.66299(12) 0.88592(14) 0.1318(10) Uani 1 1 d . . .
N1 N 0.6317(17) 0.7993(8) 0.9892(10) 0.109(6) Uani 1 1 d . . .
H1 H 0.6712 0.7756 1.0162 0.131 Uiso 1 1 calc R . .
N2 N 0.6448(13) 0.9050(8) 0.7422(8) 0.084(5) Uani 1 1 d . . .
H2 H 0.6866 0.9005 0.7069 0.100 Uiso 1 1 calc R . .
N3 N 0.4872(16) 1.0067(10) 0.8936(11) 0.088(5) Uani 1 1 d . . .
N4 N 0.2555(18) 0.7825(11) 0.8814(14) 0.108(7) Uani 1 1 d . . .
N5 N 0.2304(19) 0.9286(9) 0.7726(13) 0.105(6) Uani 1 1 d . . .
O1 O 0.7603(11) 0.6205(6) 1.0398(7) 0.088(4) Uani 1 1 d . . .
O2 O 0.8043(11) 0.9433(8) 0.5662(7) 0.094(4) Uani 1 1 d . . .
O3 O 0.4777(11) 0.8303(6) 0.9566(8) 0.093(4) Uani 1 1 d . . .
O4 O 0.6465(14) 0.7181(6) 1.0928(7) 0.100(4) Uani 1 1 d . . .
O5 O 0.5109(9) 0.8680(5) 0.8013(6) 0.076(4) Uani 1 1 d . . .
O6 O 0.6975(11) 0.8481(6) 0.6251(7) 0.081(4) Uani 1 1 d . . .
O7 O 0.5210(10) 0.9607(6) 0.9304(6) 0.076(4) Uani 1 1 d . . .
O8 O 0.4122(11) 0.9985(6) 0.8554(8) 0.088(4) Uani 1 1 d . . .
O9 O 0.5350(11) 1.0526(6) 0.9032(7) 0.092(4) Uani 1 1 d . . .
O10 O 0.3123(12) 0.7939(7) 0.8334(8) 0.105(5) Uani 1 1 d . . .
O11 O 0.2476(11) 0.8183(7) 0.9304(9) 0.108(5) Uani 1 1 d . . .
O12 O 0.2025(16) 0.7346(9) 0.8796(11) 0.161(7) Uani 1 1 d . . .
O13 O 0.3222(12) 0.9120(6) 0.7565(7) 0.095(4) Uani 1 1 d . . .
O14 O 0.2127(12) 0.9262(7) 0.8375(9) 0.111(5) Uani 1 1 d . . .
O15 O 0.1746(16) 0.9564(8) 0.7234(11) 0.154(7) Uani 1 1 d . . .
O16 O 0.3197(11) 0.9380(6) 0.9847(6) 0.094(4) Uani 1 1 d . A .
H16 H 0.3562 0.9286 1.0211 0.141 Uiso 1 1 d R . .
C1 C 0.832(2) 0.5964(9) 0.9990(12) 0.084(6) Uani 1 1 d . . .
C2 C 0.939(2) 0.6050(10) 1.0063(11) 0.098(6) Uani 1 1 d . . .
H2A H 0.9688 0.6311 1.0419 0.117 Uiso 1 1 calc R . .
C3 C 1.0013(18) 0.5737(10) 0.9592(13) 0.095(6) Uani 1 1 d . . .
H3 H 1.0737 0.5798 0.9651 0.114 Uiso 1 1 calc R . .
C4 C 0.9693(18) 0.5368(9) 0.9075(11) 0.079(6) Uani 1 1 d . . .
C5 C 0.860(2) 0.5303(9) 0.9008(11) 0.085(6) Uani 1 1 d . . .
H5 H 0.8323 0.5048 0.8639 0.103 Uiso 1 1 calc R . .
C6 C 0.7925(18) 0.5579(9) 0.9433(11) 0.075(5) Uani 1 1 d . . .
C7 C 0.678(2) 0.5495(11) 0.9332(10) 0.083(6) Uani 1 1 d . . .
C8 C 0.635(2) 0.4923(11) 0.9247(10) 0.082(6) Uani 1 1 d . . .
C9 C 0.5245(19) 0.4891(10) 0.9059(10) 0.083(6) Uani 1 1 d . . .
H9 H 0.4930 0.4508 0.8996 0.100 Uiso 1 1 calc R . .
C10 C 0.4626(19) 0.5412(13) 0.8968(10) 0.102(7) Uani 1 1 d . . .
H10 H 0.3904 0.5383 0.8866 0.122 Uiso 1 1 calc R . .
C11 C 0.511(2) 0.5974(11) 0.9032(11) 0.095(7) Uani 1 1 d . . .
C12 C 0.617(2) 0.5969(11) 0.9219(10) 0.086(6) Uani 1 1 d . . .
H12 H 0.6494 0.6350 0.9271 0.103 Uiso 1 1 calc R . .
C13 C 0.7979(18) 0.6626(9) 1.0965(12) 0.103(7) Uani 1 1 d . . .
H13A H 0.8531 0.6435 1.1271 0.124 Uiso 1 1 calc R . .
H13B H 0.8264 0.6992 1.0747 0.124 Uiso 1 1 calc R . .
C14 C 0.7124(19) 0.6778(10) 1.1386(12) 0.102(7) Uani 1 1 d . . .
H14A H 0.7363 0.6986 1.1832 0.122 Uiso 1 1 calc R . .
H14B H 0.6738 0.6413 1.1514 0.122 Uiso 1 1 calc R . .
C15 C 0.533(2) 0.8045(11) 1.0045(14) 0.092(7) Uani 1 1 d . . .
C16 C 0.498(2) 0.7798(11) 1.0737(13) 0.084(6) Uani 1 1 d . . .
C17 C 0.552(2) 0.7379(11) 1.1117(13) 0.085(6) Uani 1 1 d . . .
C18 C 0.510(2) 0.7180(9) 1.1772(12) 0.091(6) Uani 1 1 d . . .
H18 H 0.5444 0.6874 1.2045 0.109 Uiso 1 1 calc R . .
C19 C 0.425(2) 0.7414(10) 1.1999(12) 0.097(7) Uani 1 1 d . . .
H19 H 0.4027 0.7315 1.2461 0.116 Uiso 1 1 calc R . .
C20 C 0.3661(17) 0.7828(10) 1.1539(14) 0.097(6) Uani 1 1 d . . .
H20 H 0.3001 0.7960 1.1673 0.116 Uiso 1 1 calc R . .
C21 C 0.406(2) 0.8027(9) 1.0908(13) 0.094(6) Uani 1 1 d . . .
H21 H 0.3701 0.8311 1.0610 0.113 Uiso 1 1 calc R . .
C22 C 0.6772(19) 0.8302(10) 0.9315(13) 0.117(8) Uani 1 1 d . . .
H22A H 0.6980 0.8712 0.9469 0.141 Uiso 1 1 calc R . .
H22B H 0.6268 0.8336 0.8902 0.141 Uiso 1 1 calc R . .
C23 C 0.777(3) 0.7927(18) 0.9087(16) 0.118(8) Uani 1 1 d . . .
C24 C 0.876(4) 0.8171(15) 0.9275(15) 0.155(10) Uani 1 1 d . . .
H24 H 0.8828 0.8555 0.9492 0.186 Uiso 1 1 calc R . .
C25 C 0.963(2) 0.7816(17) 0.9123(15) 0.131(9) Uani 1 1 d . . .
H25 H 1.0310 0.7962 0.9234 0.157 Uiso 1 1 calc R . .
C26 C 0.949(3) 0.7252(17) 0.8811(15) 0.129(9) Uani 1 1 d . . .
H26 H 1.0085 0.7018 0.8729 0.155 Uiso 1 1 calc R . .
C27 C 0.852(3) 0.7010(14) 0.8612(14) 0.133(9) Uani 1 1 d . . .
H27 H 0.8443 0.6629 0.8388 0.159 Uiso 1 1 calc R . .
C28 C 0.766(3) 0.737(2) 0.8765(17) 0.144(10) Uani 1 1 d . . .
H28 H 0.6983 0.7222 0.8644 0.173 Uiso 1 1 calc R . .
C29 C 0.8457(16) 0.8856(10) 0.5735(10) 0.088(6) Uani 1 1 d . . .
H29A H 0.8804 0.8804 0.6215 0.106 Uiso 1 1 calc R . .
H29B H 0.8965 0.8781 0.5365 0.106 Uiso 1 1 calc R . .
C30 C 0.7562(16) 0.8437(8) 0.5641(10) 0.084(6) Uani 1 1 d . . .
H30A H 0.7136 0.8547 0.5207 0.101 Uiso 1 1 calc R . .
H30B H 0.7810 0.8020 0.5585 0.101 Uiso 1 1 calc R . .
C31 C 0.5733(18) 0.8651(9) 0.7507(11) 0.079(6) Uani 1 1 d . . .
C32 C 0.5656(17) 0.8133(10) 0.6990(11) 0.076(5) Uani 1 1 d . . .
C33 C 0.6201(18) 0.8050(11) 0.6369(12) 0.081(6) Uani 1 1 d . . .
C34 C 0.6030(17) 0.7583(10) 0.5922(11) 0.082(6) Uani 1 1 d . . .
H34 H 0.6417 0.7541 0.5505 0.099 Uiso 1 1 calc R . .
C35 C 0.527(2) 0.7154(10) 0.6078(13) 0.104(7) Uani 1 1 d . . .
H35 H 0.5140 0.6831 0.5754 0.124 Uiso 1 1 calc R . .
C36 C 0.4692(17) 0.7188(9) 0.6686(13) 0.100(7) Uani 1 1 d . . .
H36 H 0.4154 0.6917 0.6791 0.120 Uiso 1 1 calc R . .
C37 C 0.5014(17) 0.7690(11) 0.7146(11) 0.090(6) Uani 1 1 d . . .
H37 H 0.4735 0.7702 0.7607 0.108 Uiso 1 1 calc R . .
C38 C 0.6575(15) 0.9554(9) 0.7879(10) 0.087(6) Uani 1 1 d . . .
H38A H 0.6477 0.9424 0.8379 0.104 Uiso 1 1 calc R . .
H38B H 0.6027 0.9849 0.7750 0.104 Uiso 1 1 calc R . .
C45 C 0.220(3) 0.958(2) 1.0098(17) 0.165(11) Uani 1 1 d . . .
H45A H 0.2191 0.9458 1.0609 0.199 Uiso 0.58(6) 1 calc PR A 1
H45B H 0.1671 0.9334 0.9836 0.199 Uiso 0.58(6) 1 calc PR A 1
H45C H 0.1990 0.9883 0.9736 0.199 Uiso 0.42(6) 1 d PR A 2
H45D H 0.2355 0.9801 1.0549 0.199 Uiso 0.42(6) 1 d PR A 2
C46 C 0.183(4) 1.024(3) 1.006(2) 0.16(3) Uani 0.58(6) 1 d P A 1
H46A H 0.2413 1.0508 1.0159 0.247 Uiso 0.58(6) 1 calc PR A 1
H46B H 0.1303 1.0303 1.0411 0.247 Uiso 0.58(6) 1 calc PR A 1
H46C H 0.1528 1.0320 0.9575 0.247 Uiso 0.58(6) 1 calc PR A 1
C46' C 0.136(7) 0.916(4) 1.036(4) 0.16(4) Uani 0.42(6) 1 d P A 2
H46D H 0.1422 0.8761 1.0138 0.247 Uiso 0.42(6) 1 calc PR A 2
H46E H 0.0676 0.9325 1.0234 0.247 Uiso 0.42(6) 1 calc PR A 2
H46F H 0.1436 0.9114 1.0886 0.247 Uiso 0.42(6) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C40 C39 C44 120.0 . . ?
C40 C39 C38 121.6(18) . . ?
C44 C39 C38 118.4(18) . . ?
C41 C40 C39 120.0 . . ?
C41 C40 H40 120.0 . . ?
C39 C40 H40 120.0 . . ?
C42 C41 C40 120.0 . . ?
C42 C41 H41 120.0 . . ?
C40 C41 H41 120.0 . . ?
C41 C42 C43 120.0 . . ?
C41 C42 H42 120.0 . . ?
C43 C42 H42 120.0 . . ?
C44 C43 C42 120.0 . . ?
C44 C43 H43 120.0 . . ?
C42 C43 H43 120.0 . . ?
C43 C44 C39 120.0 . . ?
C43 C44 H44 120.0 . . ?
C39 C44 H44 120.0 . . ?
O3 Eu1 O5 83.7(4) . . ?
O3 Eu1 O16 86.1(4) . . ?
O5 Eu1 O16 151.4(4) . . ?
O3 Eu1 O13 149.0(5) . . ?
O5 Eu1 O13 70.3(5) . . ?
O16 Eu1 O13 124.7(5) . . ?
O3 Eu1 O14 148.6(5) . . ?
O5 Eu1 O14 122.6(5) . . ?
O16 Eu1 O14 77.2(5) . . ?
O13 Eu1 O14 52.3(5) . . ?
O3 Eu1 O10 84.4(5) . . ?
O5 Eu1 O10 82.6(4) . . ?
O16 Eu1 O10 122.9(5) . . ?
O13 Eu1 O10 76.1(5) . . ?
O14 Eu1 O10 82.7(5) . . ?
O3 Eu1 O8 125.6(5) . . ?
O5 Eu1 O8 87.9(4) . . ?
O16 Eu1 O8 76.5(4) . . ?
O13 Eu1 O8 71.2(5) . . ?
O14 Eu1 O8 76.3(5) . . ?
O10 Eu1 O8 147.3(5) . . ?
O3 Eu1 O7 76.3(5) . . ?
O5 Eu1 O7 80.9(4) . . ?
O16 Eu1 O7 70.7(4) . . ?
O13 Eu1 O7 114.2(4) . . ?
O14 Eu1 O7 121.2(5) . . ?
O10 Eu1 O7 155.8(5) . . ?
O8 Eu1 O7 49.3(4) . . ?
O3 Eu1 O11 76.6(5) . . ?
O5 Eu1 O11 129.2(5) . . ?
O16 Eu1 O11 73.5(5) . . ?
O13 Eu1 O11 106.9(5) . . ?
O14 Eu1 O11 73.3(5) . . ?
O10 Eu1 O11 49.6(5) . . ?
O8 Eu1 O11 141.0(5) . . ?
O7 Eu1 O11 136.0(5) . . ?
O3 Eu1 H16 70.5 . . ?
O5 Eu1 H16 140.2 . . ?
O16 Eu1 H16 16.1 . . ?
O13 Eu1 H16 140.4 . . ?
O14 Eu1 H16 92.9 . . ?
O10 Eu1 H16 122.7 . . ?
O8 Eu1 H16 83.6 . . ?
O7 Eu1 H16 64.2 . . ?
O11 Eu1 H16 74.3 . . ?
C15 N1 C22 124(2) . . ?
C15 N1 H1 118.1 . . ?
C22 N1 H1 118.1 . . ?
C31 N2 C38 122.2(17) . . ?
C31 N2 H2 118.9 . . ?
C38 N2 H2 118.9 . . ?
O8 N3 O9 128(2) . . ?
O8 N3 O7 116(2) . . ?
O9 N3 O7 116(2) . . ?
O10 N4 O11 119(3) . . ?
O10 N4 O12 120(3) . . ?
O11 N4 O12 120(3) . . ?
O14 N5 O13 115(2) . . ?
O14 N5 O15 126(2) . . ?
O13 N5 O15 117(2) . . ?
C1 O1 C13 116.3(17) . . ?
C8 O2 C29 121.0(18) 2_656 . ?
C15 O3 Eu1 172.0(15) . . ?
C17 O4 C14 123.3(18) . . ?
C31 O5 Eu1 167.9(12) . . ?
C30 O6 C33 119.6(16) . . ?
N3 O7 Eu1 94.4(12) . . ?
N3 O8 Eu1 100.2(14) . . ?
N4 O10 Eu1 98.6(17) . . ?
N4 O11 Eu1 92.3(16) . . ?
N5 O13 Eu1 95.5(13) . . ?
N5 O14 Eu1 96.9(15) . . ?
C45 O16 Eu1 136.7(15) . . ?
C45 O16 H16 106.9 . . ?
Eu1 O16 H16 110.6 . . ?
O1 C1 C2 127(2) . . ?
O1 C1 C6 114(2) . . ?
C2 C1 C6 119(2) . . ?
C1 C2 C3 118(2) . . ?
C1 C2 H2A 121.2 . . ?
C3 C2 H2A 121.2 . . ?
C4 C3 C2 127(2) . . ?
C4 C3 H3 116.7 . . ?
C2 C3 H3 116.7 . . ?
C3 C4 C5 114(2) . . ?
C3 C4 Br1 123(2) . . ?
C5 C4 Br1 123.2(19) . . ?
C6 C5 C4 125(2) . . ?
C6 C5 H5 117.7 . . ?
C4 C5 H5 117.7 . . ?
C5 C6 C1 119(2) . . ?
C5 C6 C7 122(2) . . ?
C1 C6 C7 119(2) . . ?
C12 C7 C8 119(2) . . ?
C12 C7 C6 120(2) . . ?
C8 C7 C6 121(2) . . ?
O2 C8 C7 120(2) 2_646 . ?
O2 C8 C9 123(2) 2_646 . ?
C7 C8 C9 117(2) . . ?
C10 C9 C8 122(2) . . ?
C10 C9 H9 118.9 . . ?
C8 C9 H9 118.9 . . ?
C11 C10 C9 118(2) . . ?
C11 C10 H10 120.9 . . ?
C9 C10 H10 120.9 . . ?
C12 C11 C10 116(2) . . ?
C12 C11 Br2 127(2) . . ?
C10 C11 Br2 116(2) . . ?
C7 C12 C11 128(2) . . ?
C7 C12 H12 116.2 . . ?
C11 C12 H12 116.2 . . ?
C14 C13 O1 107.7(19) . . ?
C14 C13 H13A 110.2 . . ?
O1 C13 H13A 110.2 . . ?
C14 C13 H13B 110.2 . . ?
O1 C13 H13B 110.2 . . ?
H13A C13 H13B 108.5 . . ?
C13 C14 O4 105.6(18) . . ?
C13 C14 H14A 110.6 . . ?
O4 C14 H14A 110.6 . . ?
C13 C14 H14B 110.6 . . ?
O4 C14 H14B 110.6 . . ?
H14A C14 H14B 108.8 . . ?
O3 C15 N1 114(2) . . ?
O3 C15 C16 127(3) . . ?
N1 C15 C16 119(2) . . ?
C21 C16 C17 126(2) . . ?
C21 C16 C15 112(3) . . ?
C17 C16 C15 122(2) . . ?
C16 C17 O4 123(2) . . ?
C16 C17 C18 117(2) . . ?
O4 C17 C18 120(2) . . ?
C19 C18 C17 121(2) . . ?
C19 C18 H18 119.5 . . ?
C17 C18 H18 119.5 . . ?
C18 C19 C20 119(2) . . ?
C18 C19 H19 120.3 . . ?
C20 C19 H19 120.3 . . ?
C21 C20 C19 120(2) . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C16 C21 C20 117(2) . . ?
C16 C21 H21 121.6 . . ?
C20 C21 H21 121.6 . . ?
N1 C22 C23 108.2(19) . . ?
N1 C22 H22A 110.1 . . ?
C23 C22 H22A 110.1 . . ?
N1 C22 H22B 110.1 . . ?
C23 C22 H22B 110.1 . . ?
H22A C22 H22B 108.4 . . ?
C28 C23 C24 122(3) . . ?
C28 C23 C22 121(4) . . ?
C24 C23 C22 117(4) . . ?
C23 C24 C25 117(3) . . ?
C23 C24 H24 121.4 . . ?
C25 C24 H24 121.4 . . ?
C26 C25 C24 119(3) . . ?
C26 C25 H25 120.3 . . ?
C24 C25 H25 120.3 . . ?
C25 C26 C27 124(3) . . ?
C25 C26 H26 118.1 . . ?
C27 C26 H26 118.1 . . ?
C26 C27 C28 116(3) . . ?
C26 C27 H27 122.0 . . ?
C28 C27 H27 122.0 . . ?
C23 C28 C27 122(3) . . ?
C23 C28 H28 119.1 . . ?
C27 C28 H28 119.1 . . ?
O2 C29 C30 105.7(16) . . ?
O2 C29 H29A 110.6 . . ?
C30 C29 H29A 110.6 . . ?
O2 C29 H29B 110.6 . . ?
C30 C29 H29B 110.6 . . ?
H29A C29 H29B 108.7 . . ?
O6 C30 C29 108.0(17) . . ?
O6 C30 H30A 110.1 . . ?
C29 C30 H30A 110.1 . . ?
O6 C30 H30B 110.1 . . ?
C29 C30 H30B 110.1 . . ?
H30A C30 H30B 108.4 . . ?
O5 C31 N2 122.6(19) . . ?
O5 C31 C32 119(2) . . ?
N2 C31 C32 118(2) . . ?
C37 C32 C33 115(2) . . ?
C37 C32 C31 117(2) . . ?
C33 C32 C31 128(2) . . ?
C34 C33 C32 123(2) . . ?
C34 C33 O6 122(2) . . ?
C32 C33 O6 115(2) . . ?
C33 C34 C35 119(2) . . ?
C33 C34 H34 120.3 . . ?
C35 C34 H34 120.3 . . ?
C36 C35 C34 122(2) . . ?
C36 C35 H35 118.8 . . ?
C34 C35 H35 118.8 . . ?
C35 C36 C37 112(2) . . ?
C35 C36 H36 124.0 . . ?
C37 C36 H36 124.0 . . ?
C32 C37 C36 127(2) . . ?
C32 C37 H37 116.4 . . ?
C36 C37 H37 116.4 . . ?
N2 C38 C39 114.9(16) . . ?
N2 C38 H38A 108.5 . . ?
C39 C38 H38A 108.5 . . ?
N2 C38 H38B 108.5 . . ?
C39 C38 H38B 108.5 . . ?
H38A C38 H38B 107.5 . . ?
O16 C45 C46' 125(4) . . ?
O16 C45 C46 123(4) . . ?
C46' C45 C46 111(4) . . ?
O16 C45 H45A 106.5 . . ?
C46' C45 H45A 58.9 . . ?
C46 C45 H45A 106.5 . . ?
O16 C45 H45B 106.5 . . ?
C46' C45 H45B 48.2 . . ?
C46 C45 H45B 106.5 . . ?
H45A C45 H45B 106.5 . . ?
O16 C45 H45C 102.3 . . ?
C46' C45 H45C 117.1 . . ?
C46 C45 H45C 40.2 . . ?
H45A C45 H45C 145.6 . . ?
H45B C45 H45C 82.6 . . ?
O16 C45 H45D 106.4 . . ?
C46' C45 H45D 98.6 . . ?
C46 C45 H45D 67.3 . . ?
H45A C45 H45D 47.9 . . ?
H45B C45 H45D 143.2 . . ?
H45C C45 H45D 105.8 . . ?
C45 C46 H45C 38.8 . . ?
C45 C46 H45D 38.0 . . ?
H45C C46 H45D 75.8 . . ?
C45 C46 H46A 109.5 . . ?
H45C C46 H46A 114.2 . . ?
H45D C46 H46A 87.2 . . ?
C45 C46 H46B 109.5 . . ?
H45C C46 H46B 132.8 . . ?
H45D C46 H46B 89.6 . . ?
H46A C46 H46B 109.5 . . ?
C45 C46 H46C 109.5 . . ?
H45C C46 H46C 71.9 . . ?
H45D C46 H46C 147.4 . . ?
H46A C46 H46C 109.5 . . ?
H46B C46 H46C 109.5 . . ?
C45 C46' H46D 109.5 . . ?
C45 C46' H46E 109.5 . . ?
H46D C46' H46E 109.5 . . ?
C45 C46' H46F 109.5 . . ?
H46D C46' H46F 109.5 . . ?
H46E C46' H46F 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C39 C40 1.3900 . ?
C39 C44 1.3900 . ?
C39 C38 1.44(2) . ?
C40 C41 1.3900 . ?
C40 H40 0.9300 . ?
C41 C42 1.3900 . ?
C41 H41 0.9300 . ?
C42 C43 1.3900 . ?
C42 H42 0.9300 . ?
C43 C44 1.3900 . ?
C43 H43 0.9300 . ?
C44 H44 0.9300 . ?
Eu1 O3 2.236(16) . ?
Eu1 O5 2.266(12) . ?
Eu1 O16 2.374(12) . ?
Eu1 O13 2.380(13) . ?
Eu1 O14 2.381(15) . ?
Eu1 O10 2.391(16) . ?
Eu1 O8 2.458(12) . ?
Eu1 O7 2.511(12) . ?
Eu1 O11 2.513(14) . ?
Eu1 H16 2.7704 . ?
Br1 C4 1.81(2) . ?
Br2 C11 1.79(2) . ?
N1 C15 1.31(2) . ?
N1 C22 1.40(2) . ?
N1 H1 0.8600 . ?
N2 C31 1.27(2) . ?
N2 C38 1.39(2) . ?
N2 H2 0.8600 . ?
N3 O8 1.17(2) . ?
N3 O9 1.181(19) . ?
N3 O7 1.27(2) . ?
N4 O10 1.19(2) . ?
N4 O11 1.20(2) . ?
N4 O12 1.24(2) . ?
N5 O14 1.218(19) . ?
N5 O13 1.27(2) . ?
N5 O15 1.27(2) . ?
O1 C1 1.32(2) . ?
O1 C13 1.45(2) . ?
O2 C8 1.32(2) 2_656 ?
O2 C29 1.369(19) . ?
O3 C15 1.23(2) . ?
O4 C17 1.33(2) . ?
O4 C14 1.45(2) . ?
O5 C31 1.245(19) . ?
O6 C30 1.372(16) . ?
O6 C33 1.39(2) . ?
O16 C45 1.43(3) . ?
O16 H16 0.8200 . ?
C1 C2 1.37(3) . ?
C1 C6 1.40(2) . ?
C2 C3 1.37(2) . ?
C2 H2A 0.9300 . ?
C3 C4 1.29(2) . ?
C3 H3 0.9300 . ?
C4 C5 1.40(2) . ?
C5 C6 1.33(2) . ?
C5 H5 0.9300 . ?
C6 C7 1.47(3) . ?
C7 C12 1.30(2) . ?
C7 C8 1.37(2) . ?
C8 O2 1.32(2) 2_646 ?
C8 C9 1.44(3) . ?
C9 C10 1.39(2) . ?
C9 H9 0.9300 . ?
C10 C11 1.37(3) . ?
C10 H10 0.9300 . ?
C11 C12 1.37(3) . ?
C12 H12 0.9300 . ?
C13 C14 1.40(2) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.46(3) . ?
C16 C21 1.32(2) . ?
C16 C17 1.32(3) . ?
C17 C18 1.40(2) . ?
C18 C19 1.28(2) . ?
C18 H18 0.9300 . ?
C19 C20 1.43(3) . ?
C19 H19 0.9300 . ?
C20 C21 1.35(2) . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
C22 C23 1.58(3) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C28 1.36(3) . ?
C23 C24 1.39(3) . ?
C24 C25 1.40(3) . ?
C24 H24 0.9300 . ?
C25 C26 1.36(3) . ?
C25 H25 0.9300 . ?
C26 C27 1.38(3) . ?
C26 H26 0.9300 . ?
C27 C28 1.38(3) . ?
C27 H27 0.9300 . ?
C28 H28 0.9300 . ?
C29 C30 1.46(2) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 C32 1.47(2) . ?
C32 C37 1.30(2) . ?
C32 C33 1.37(2) . ?
C33 C34 1.32(2) . ?
C34 C35 1.39(2) . ?
C34 H34 0.9300 . ?
C35 C36 1.36(2) . ?
C35 H35 0.9300 . ?
C36 C37 1.43(2) . ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C45 C46' 1.51(7) . ?
C45 C46 1.52(5) . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C45 H45C 0.9700 . ?
C45 H45D 0.9700 . ?
C46 H45C 0.9988 . ?
C46 H45D 1.4530 . ?
C46 H46A 0.9600 . ?
C46 H46B 0.9600 . ?
C46 H46C 0.9600 . ?
C46' H46D 0.9600 . ?
C46' H46E 0.9600 . ?
C46' H46F 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C44 C39 C40 C41 0.0 . . . . ?
C38 C39 C40 C41 178.0(14) . . . . ?
C39 C40 C41 C42 0.0 . . . . ?
C40 C41 C42 C43 0.0 . . . . ?
C41 C42 C43 C44 0.0 . . . . ?
C42 C43 C44 C39 0.0 . . . . ?
C40 C39 C44 C43 0.0 . . . . ?
C38 C39 C44 C43 -178.1(14) . . . . ?
O5 Eu1 O3 C15 115(12) . . . . ?
O16 Eu1 O3 C15 -38(12) . . . . ?
O13 Eu1 O3 C15 147(12) . . . . ?
O14 Eu1 O3 C15 -96(12) . . . . ?
O10 Eu1 O3 C15 -162(12) . . . . ?
O8 Eu1 O3 C15 32(12) . . . . ?
O7 Eu1 O3 C15 33(12) . . . . ?
O11 Eu1 O3 C15 -112(12) . . . . ?
O3 Eu1 O5 C31 -168(6) . . . . ?
O16 Eu1 O5 C31 -98(6) . . . . ?
O13 Eu1 O5 C31 29(6) . . . . ?
O14 Eu1 O5 C31 31(7) . . . . ?
O10 Eu1 O5 C31 107(6) . . . . ?
O8 Eu1 O5 C31 -42(6) . . . . ?
O7 Eu1 O5 C31 -91(6) . . . . ?
O11 Eu1 O5 C31 125(6) . . . . ?
O8 N3 O7 Eu1 0.9(18) . . . . ?
O9 N3 O7 Eu1 179.9(15) . . . . ?
O3 Eu1 O7 N3 -179.8(10) . . . . ?
O5 Eu1 O7 N3 94.6(10) . . . . ?
O16 Eu1 O7 N3 -89.1(11) . . . . ?
O13 Eu1 O7 N3 31.1(11) . . . . ?
O14 Eu1 O7 N3 -28.1(12) . . . . ?
O10 Eu1 O7 N3 142.1(13) . . . . ?
O8 Eu1 O7 N3 -0.5(10) . . . . ?
O11 Eu1 O7 N3 -126.3(10) . . . . ?
O9 N3 O8 Eu1 -179.7(19) . . . . ?
O7 N3 O8 Eu1 -0.9(19) . . . . ?
O3 Eu1 O8 N3 1.4(14) . . . . ?
O5 Eu1 O8 N3 -79.3(12) . . . . ?
O16 Eu1 O8 N3 76.5(13) . . . . ?
O13 Eu1 O8 N3 -149.1(13) . . . . ?
O14 Eu1 O8 N3 156.4(13) . . . . ?
O10 Eu1 O8 N3 -152.0(12) . . . . ?
O7 Eu1 O8 N3 0.5(11) . . . . ?
O11 Eu1 O8 N3 117.0(13) . . . . ?
O11 N4 O10 Eu1 3(2) . . . . ?
O12 N4 O10 Eu1 -180(2) . . . . ?
O3 Eu1 O10 N4 75.8(13) . . . . ?
O5 Eu1 O10 N4 160.1(13) . . . . ?
O16 Eu1 O10 N4 -5.9(15) . . . . ?
O13 Eu1 O10 N4 -128.5(14) . . . . ?
O14 Eu1 O10 N4 -75.6(14) . . . . ?
O8 Eu1 O10 N4 -125.7(13) . . . . ?
O7 Eu1 O10 N4 112.8(15) . . . . ?
O11 Eu1 O10 N4 -1.4(13) . . . . ?
O10 N4 O11 Eu1 -2(2) . . . . ?
O12 N4 O11 Eu1 180(2) . . . . ?
O3 Eu1 O11 N4 -92.8(14) . . . . ?
O5 Eu1 O11 N4 -22.7(16) . . . . ?
O16 Eu1 O11 N4 177.3(15) . . . . ?
O13 Eu1 O11 N4 55.3(14) . . . . ?
O14 Eu1 O11 N4 96.1(14) . . . . ?
O10 Eu1 O11 N4 1.3(13) . . . . ?
O8 Eu1 O11 N4 136.2(13) . . . . ?
O7 Eu1 O11 N4 -146.1(13) . . . . ?
O14 N5 O13 Eu1 0.0(19) . . . . ?
O15 N5 O13 Eu1 167.1(18) . . . . ?
O3 Eu1 O13 N5 144.1(12) . . . . ?
O5 Eu1 O13 N5 178.5(12) . . . . ?
O16 Eu1 O13 N5 -29.2(13) . . . . ?
O14 Eu1 O13 N5 0.0(11) . . . . ?
O10 Eu1 O13 N5 91.5(12) . . . . ?
O8 Eu1 O13 N5 -86.9(11) . . . . ?
O7 Eu1 O13 N5 -111.7(11) . . . . ?
O11 Eu1 O13 N5 52.1(12) . . . . ?
O13 N5 O14 Eu1 0.0(19) . . . . ?
O15 N5 O14 Eu1 -166(2) . . . . ?
O3 Eu1 O14 N5 -144.6(12) . . . . ?
O5 Eu1 O14 N5 -1.7(15) . . . . ?
O16 Eu1 O14 N5 155.7(13) . . . . ?
O13 Eu1 O14 N5 0.0(12) . . . . ?
O10 Eu1 O14 N5 -78.0(13) . . . . ?
O8 Eu1 O14 N5 76.7(13) . . . . ?
O7 Eu1 O14 N5 97.9(13) . . . . ?
O11 Eu1 O14 N5 -127.9(14) . . . . ?
O3 Eu1 O16 C45 -135(3) . . . . ?
O5 Eu1 O16 C45 156(3) . . . . ?
O13 Eu1 O16 C45 42(3) . . . . ?
O14 Eu1 O16 C45 18(3) . . . . ?
O10 Eu1 O16 C45 -54(3) . . . . ?
O8 Eu1 O16 C45 97(3) . . . . ?
O7 Eu1 O16 C45 148(3) . . . . ?
O11 Eu1 O16 C45 -58(3) . . . . ?
C13 O1 C1 C2 3(3) . . . . ?
C13 O1 C1 C6 -177.8(16) . . . . ?
O1 C1 C2 C3 177.8(17) . . . . ?
C6 C1 C2 C3 -2(3) . . . . ?
C1 C2 C3 C4 1(3) . . . . ?
C2 C3 C4 C5 1(3) . . . . ?
C2 C3 C4 Br1 178.0(15) . . . . ?
C3 C4 C5 C6 -1(3) . . . . ?
Br1 C4 C5 C6 -178.2(14) . . . . ?
C4 C5 C6 C1 0(3) . . . . ?
C4 C5 C6 C7 179.6(19) . . . . ?
O1 C1 C6 C5 -178.2(16) . . . . ?
C2 C1 C6 C5 1(3) . . . . ?
O1 C1 C6 C7 2(3) . . . . ?
C2 C1 C6 C7 -178.2(19) . . . . ?
C5 C6 C7 C12 -123(2) . . . . ?
C1 C6 C7 C12 57(3) . . . . ?
C5 C6 C7 C8 48(3) . . . . ?
C1 C6 C7 C8 -133(2) . . . . ?
C12 C7 C8 O2 178.1(17) . . . 2_646 ?
C6 C7 C8 O2 8(3) . . . 2_646 ?
C12 C7 C8 C9 -2(3) . . . . ?
C6 C7 C8 C9 -172.3(17) . . . . ?
O2 C8 C9 C10 179.9(17) 2_646 . . . ?
C7 C8 C9 C10 0(3) . . . . ?
C8 C9 C10 C11 3(3) . . . . ?
C9 C10 C11 C12 -3(3) . . . . ?
C9 C10 C11 Br2 176.6(13) . . . . ?
C8 C7 C12 C11 1(3) . . . . ?
C6 C7 C12 C11 172(2) . . . . ?
C10 C11 C12 C7 1(3) . . . . ?
Br2 C11 C12 C7 -178.6(16) . . . . ?
C1 O1 C13 C14 -173.6(17) . . . . ?
O1 C13 C14 O4 -72.7(19) . . . . ?
C17 O4 C14 C13 173.7(17) . . . . ?
Eu1 O3 C15 N1 -97(12) . . . . ?
Eu1 O3 C15 C16 84(12) . . . . ?
C22 N1 C15 O3 12(3) . . . . ?
C22 N1 C15 C16 -168.4(19) . . . . ?
O3 C15 C16 C21 -18(3) . . . . ?
N1 C15 C16 C21 162(2) . . . . ?
O3 C15 C16 C17 160(2) . . . . ?
N1 C15 C16 C17 -20(3) . . . . ?
C21 C16 C17 O4 -177.6(19) . . . . ?
C15 C16 C17 O4 5(3) . . . . ?
C21 C16 C17 C18 -3(3) . . . . ?
C15 C16 C17 C18 179.9(18) . . . . ?
C14 O4 C17 C16 172(2) . . . . ?
C14 O4 C17 C18 -3(3) . . . . ?
C16 C17 C18 C19 -3(3) . . . . ?
O4 C17 C18 C19 172(2) . . . . ?
C17 C18 C19 C20 8(3) . . . . ?
C18 C19 C20 C21 -8(3) . . . . ?
C17 C16 C21 C20 2(3) . . . . ?
C15 C16 C21 C20 179.9(18) . . . . ?
C19 C20 C21 C16 3(3) . . . . ?
C15 N1 C22 C23 -156(3) . . . . ?
N1 C22 C23 C28 68(3) . . . . ?
N1 C22 C23 C24 -108(3) . . . . ?
C28 C23 C24 C25 0(4) . . . . ?
C22 C23 C24 C25 175(2) . . . . ?
C23 C24 C25 C26 -1(4) . . . . ?
C24 C25 C26 C27 2(4) . . . . ?
C25 C26 C27 C28 -2(4) . . . . ?
C24 C23 C28 C27 1(4) . . . . ?
C22 C23 C28 C27 -175(2) . . . . ?
C26 C27 C28 C23 1(4) . . . . ?
C8 O2 C29 C30 176.8(16) 2_656 . . . ?
C33 O6 C30 C29 -167.5(15) . . . . ?
O2 C29 C30 O6 -71.5(17) . . . . ?
Eu1 O5 C31 N2 75(7) . . . . ?
Eu1 O5 C31 C32 -106(6) . . . . ?
C38 N2 C31 O5 -1(3) . . . . ?
C38 N2 C31 C32 179.6(17) . . . . ?
O5 C31 C32 C37 -8(3) . . . . ?
N2 C31 C32 C37 171.0(17) . . . . ?
O5 C31 C32 C33 173.8(17) . . . . ?
N2 C31 C32 C33 -7(3) . . . . ?
C37 C32 C33 C34 6(3) . . . . ?
C31 C32 C33 C34 -176.2(19) . . . . ?
C37 C32 C33 O6 -172.4(17) . . . . ?
C31 C32 C33 O6 6(3) . . . . ?
C30 O6 C33 C34 2(3) . . . . ?
C30 O6 C33 C32 -179.8(15) . . . . ?
C32 C33 C34 C35 0(3) . . . . ?
O6 C33 C34 C35 178.1(16) . . . . ?
C33 C34 C35 C36 -1(3) . . . . ?
C34 C35 C36 C37 -3(3) . . . . ?
C33 C32 C37 C36 -11(3) . . . . ?
C31 C32 C37 C36 170.4(19) . . . . ?
C35 C36 C37 C32 10(3) . . . . ?
C31 N2 C38 C39 162.3(17) . . . . ?
C40 C39 C38 N2 128.9(14) . . . . ?
C44 C39 C38 N2 -53.1(19) . . . . ?
Eu1 O16 C45 C46' 73(5) . . . . ?
Eu1 O16 C45 C46 -100(4) . . . . ?
