#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/20/4302059.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302059
loop_
_publ_author_name
'Olena V. Zenkina'
'Leonid E. Konstantinovski'
'Linda J. W. Shimon'
'Yael Diskin-Posner'
'Mark A. Iron'
'Milko E. van der Boom'
_publ_section_title
;
Long-Range Through-Bond Heteronuclear Communication in Platinum Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4021
_journal_page_last               4030
_journal_paper_doi               10.1021/ic801940h
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C25 H40 F N P2 Pt'
_chemical_formula_sum            'C25 H40 F N P2 Pt'
_chemical_formula_weight         630.61
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.3960(16)
_cell_angle_beta                 95.855(2)
_cell_angle_gamma                104.263(2)
_cell_formula_units_Z            2
_cell_length_a                   8.6720(2)
_cell_length_b                   11.2167(5)
_cell_length_c                   14.6807(6)
_cell_measurement_reflns_used    5781
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.55
_cell_volume                     1312.73(9)
_computing_cell_refinement       HKL
_computing_data_collection       'Collect package Bruker-Nonius'
_computing_data_reduction        HKL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR-97 (Altomare et at, 1992)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       'Phi and Omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.084
_diffrn_reflns_av_sigmaI/netI    0.0557
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            5976
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.63
_exptl_absorpt_coefficient_mu    5.485
_exptl_absorpt_correction_T_max  0.8104
_exptl_absorpt_correction_T_min  0.2899
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SHELXL-97 (Sheldrick, 1997)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.595
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             628
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.814
_refine_diff_density_min         -0.814
_refine_diff_density_rms         0.156
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     280
_refine_ls_number_reflns         5354
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.015
_refine_ls_R_factor_all          0.0511
_refine_ls_R_factor_gt           0.0361
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0427P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0729
_refine_ls_wR_factor_ref         0.0765
_reflns_number_gt                4463
_reflns_number_total             5354
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic801940h_si_004.cif
_cod_data_source_block           v114a
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4302059
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.04094(2) 0.336879(19) 0.247948(15) 0.02122(8) Uani 1 1 d . . .
P2 P -0.16154(14) 0.15105(13) 0.17785(10) 0.0215(3) Uani 1 1 d . . .
P3 P -0.09540(14) 0.48922(13) 0.28000(10) 0.0210(3) Uani 1 1 d . . .
F1 F 0.3414(4) -0.0823(3) 0.4297(3) 0.0403(8) Uani 1 1 d . . .
N12 N 0.5064(5) 0.7206(5) 0.1712(4) 0.0362(12) Uani 1 1 d . . .
C1 C 0.2836(5) 0.1922(5) 0.2989(4) 0.0202(10) Uani 1 1 d . . .
C2 C 0.2943(6) 0.2174(5) 0.3982(4) 0.0298(12) Uani 1 1 d . . .
H2 H 0.2888 0.2989 0.4361 0.036 Uiso 1 1 calc R . .
C3 C 0.3130(6) 0.1243(5) 0.4430(4) 0.0296(12) Uani 1 1 d . . .
H3 H 0.3194 0.1415 0.5104 0.035 Uiso 1 1 calc R . .
C4 C 0.3218(6) 0.0080(5) 0.3868(4) 0.0288(13) Uani 1 1 d . . .
C5 C 0.3122(6) -0.0210(5) 0.2893(4) 0.0301(13) Uani 1 1 d . . .
H5 H 0.3167 -0.1030 0.2518 0.036 Uiso 1 1 calc R . .
C6 C 0.2956(6) 0.0734(5) 0.2471(4) 0.0274(12) Uani 1 1 d . . .
H6 H 0.2925 0.0556 0.1798 0.033 Uiso 1 1 calc R . .
C7 C 0.2605(5) 0.2868(5) 0.2470(4) 0.0223(11) Uani 1 1 d . . .
H7 H 0.2961 0.2803 0.1884 0.023(14) Uiso 1 1 d R . .
C8 C 0.2930(5) 0.4234(5) 0.2948(4) 0.0206(10) Uani 1 1 d . . .
H8 H 0.3145 0.4565 0.3600 0.000(10) Uiso 1 1 d R . .
C9 C 0.3635(5) 0.5212(5) 0.2493(4) 0.0222(11) Uani 1 1 d . . .
C10 C 0.4412(5) 0.6483(5) 0.3067(4) 0.0233(11) Uani 1 1 d . . .
H10 H 0.4468 0.6705 0.3743 0.028 Uiso 1 1 calc R . .
C11 C 0.5099(6) 0.7418(6) 0.2655(5) 0.0322(13) Uani 1 1 d . . .
H11 H 0.5629 0.8263 0.3069 0.039 Uiso 1 1 calc R . .
C13 C 0.4312(7) 0.6002(6) 0.1167(5) 0.0366(14) Uani 1 1 d . . .
H13 H 0.4256 0.5821 0.0492 0.044 Uiso 1 1 calc R . .
C14 C 0.3594(6) 0.4973(6) 0.1508(4) 0.0281(12) Uani 1 1 d . . .
H14 H 0.3092 0.4134 0.1076 0.034 Uiso 1 1 calc R . .
C21 C -0.3232(7) 0.1524(6) 0.0887(4) 0.0385(15) Uani 1 1 d . . .
H21A H -0.4035 0.0662 0.0659 0.046 Uiso 1 1 calc R . .
H21B H -0.3788 0.2157 0.1191 0.046 Uiso 1 1 calc R . .
C22 C -0.2748(6) 0.0861(5) 0.2612(4) 0.0302(12) Uani 1 1 d . . .
H22A H -0.3418 0.1427 0.2868 0.036 Uiso 1 1 calc R . .
H22B H -0.3486 -0.0004 0.2259 0.036 Uiso 1 1 calc R . .
C23 C -0.0893(6) 0.0171(5) 0.1151(4) 0.0268(12) Uani 1 1 d . . .
H23A H -0.0188 0.0478 0.0721 0.032 Uiso 1 1 calc R . .
H23B H -0.0204 -0.0029 0.1637 0.032 Uiso 1 1 calc R . .
C24 C -0.2603(9) 0.1868(7) 0.0027(5) 0.0519(18) Uani 1 1 d . . .
H24A H -0.1802 0.2719 0.0249 0.078 Uiso 1 1 calc R . .
H24B H -0.3505 0.1887 -0.0424 0.078 Uiso 1 1 calc R . .
H24C H -0.2098 0.1221 -0.0296 0.078 Uiso 1 1 calc R . .
C25 C -0.1650(7) 0.0756(6) 0.3448(4) 0.0367(14) Uani 1 1 d . . .
H25A H -0.1103 0.0099 0.3208 0.055 Uiso 1 1 calc R . .
H25B H -0.2298 0.0512 0.3914 0.055 Uiso 1 1 calc R . .
H25C H -0.0841 0.1590 0.3760 0.055 Uiso 1 1 calc R . .
C26 C -0.2134(7) -0.1084(6) 0.0555(5) 0.0393(14) Uani 1 1 d . . .
H26A H -0.2800 -0.1443 0.0972 0.059 Uiso 1 1 calc R . .
H26B H -0.1576 -0.1701 0.0248 0.059 Uiso 1 1 calc R . .
H26C H -0.2826 -0.0916 0.0061 0.059 Uiso 1 1 calc R . .
C31 C -0.2769(6) 0.4509(5) 0.3337(4) 0.0265(12) Uani 1 1 d . . .
H31A H -0.3240 0.5243 0.3442 0.032 Uiso 1 1 calc R . .
H31B H -0.3580 0.3746 0.2879 0.032 Uiso 1 1 calc R . .
C32 C 0.0262(6) 0.6476(5) 0.3607(4) 0.0263(11) Uani 1 1 d . . .
H32A H 0.0614 0.6368 0.4236 0.032 Uiso 1 1 calc R . .
H32B H 0.1248 0.6755 0.3342 0.032 Uiso 1 1 calc R . .
C33 C -0.1755(6) 0.5296(6) 0.1758(4) 0.0306(13) Uani 1 1 d . . .
H33A H -0.2535 0.4511 0.1305 0.037 Uiso 1 1 calc R . .
H33B H -0.2352 0.5937 0.1972 0.037 Uiso 1 1 calc R . .
C34 C -0.2430(7) 0.4234(6) 0.4285(4) 0.0352(13) Uani 1 1 d . . .
H34A H -0.1960 0.3510 0.4188 0.053 Uiso 1 1 calc R . .
H34B H -0.3443 0.4014 0.4526 0.053 Uiso 1 1 calc R . .
H34C H -0.1670 0.5000 0.4753 0.053 Uiso 1 1 calc R . .
C35 C -0.0552(7) 0.7562(6) 0.3782(4) 0.0348(13) Uani 1 1 d . . .
H35A H -0.0784 0.7763 0.3181 0.052 Uiso 1 1 calc R . .
H35B H 0.0170 0.8332 0.4267 0.052 Uiso 1 1 calc R . .
H35C H -0.1565 0.7287 0.4011 0.052 Uiso 1 1 calc R . .
C36 C -0.0474(7) 0.5833(6) 0.1238(4) 0.0420(15) Uani 1 1 d . . .
H36A H 0.0279 0.6632 0.1674 0.063 Uiso 1 1 calc R . .
H36B H -0.0985 0.6015 0.0683 0.063 Uiso 1 1 calc R . .
H36C H 0.0117 0.5202 0.1018 0.063 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 C8 40.00(19) . . ?
C7 Pt1 P2 106.76(14) . . ?
C8 Pt1 P2 146.70(13) . . ?
C7 Pt1 P3 150.39(14) . . ?
C8 Pt1 P3 110.51(13) . . ?
P2 Pt1 P3 102.78(5) . . ?
C21 P2 C23 103.6(3) . . ?
C21 P2 C22 102.1(3) . . ?
C23 P2 C22 103.1(2) . . ?
C21 P2 Pt1 118.2(2) . . ?
C23 P2 Pt1 113.09(17) . . ?
C22 P2 Pt1 114.94(19) . . ?
C33 P3 C32 102.5(3) . . ?
C33 P3 C31 101.4(2) . . ?
C32 P3 C31 104.0(2) . . ?
C33 P3 Pt1 115.37(19) . . ?
C32 P3 Pt1 114.68(16) . . ?
C31 P3 Pt1 116.90(17) . . ?
C13 N12 C11 115.2(5) . . ?
C6 C1 C2 117.3(5) . . ?
C6 C1 C7 119.2(5) . . ?
C2 C1 C7 123.5(5) . . ?
C1 C2 C3 121.1(5) . . ?
C1 C2 H2 119.4 . . ?
C3 C2 H2 119.4 . . ?
C4 C3 C2 118.2(5) . . ?
C4 C3 H3 120.9 . . ?
C2 C3 H3 120.9 . . ?
F1 C4 C5 118.6(5) . . ?
F1 C4 C3 118.6(5) . . ?
C5 C4 C3 122.8(5) . . ?
C4 C5 C6 117.7(5) . . ?
C4 C5 H5 121.1 . . ?
C6 C5 H5 121.1 . . ?
C1 C6 C5 122.8(5) . . ?
C1 C6 H6 118.6 . . ?
C5 C6 H6 118.6 . . ?
C8 C7 C1 123.1(5) . . ?
C8 C7 Pt1 70.1(3) . . ?
C1 C7 Pt1 117.3(3) . . ?
C8 C7 H7 106.0 . . ?
C1 C7 H7 118.4 . . ?
Pt1 C7 H7 112.6 . . ?
C7 C8 C9 121.8(5) . . ?
C7 C8 Pt1 69.9(3) . . ?
C9 C8 Pt1 114.3(3) . . ?
C7 C8 H8 121.9 . . ?
C9 C8 H8 111.1 . . ?
Pt1 C8 H8 109.4 . . ?
C14 C9 C10 116.0(5) . . ?
C14 C9 C8 124.4(5) . . ?
C10 C9 C8 119.5(5) . . ?
C11 C10 C9 120.5(5) . . ?
C11 C10 H10 119.7 . . ?
C9 C10 H10 119.7 . . ?
N12 C11 C10 124.2(5) . . ?
N12 C11 H11 117.9 . . ?
C10 C11 H11 117.9 . . ?
N12 C13 C14 125.4(6) . . ?
N12 C13 H13 117.3 . . ?
C14 C13 H13 117.3 . . ?
C9 C14 C13 118.6(6) . . ?
C9 C14 H14 120.7 . . ?
C13 C14 H14 120.7 . . ?
C24 C21 P2 112.3(4) . . ?
C24 C21 H21A 109.2 . . ?
P2 C21 H21A 109.2 . . ?
C24 C21 H21B 109.2 . . ?
P2 C21 H21B 109.2 . . ?
H21A C21 H21B 107.9 . . ?
C25 C22 P2 112.6(4) . . ?
C25 C22 H22A 109.1 . . ?
P2 C22 H22A 109.1 . . ?
C25 C22 H22B 109.1 . . ?
P2 C22 H22B 109.1 . . ?
H22A C22 H22B 107.8 . . ?
C26 C23 P2 118.5(4) . . ?
C26 C23 H23A 107.7 . . ?
P2 C23 H23A 107.7 . . ?
C26 C23 H23B 107.7 . . ?
P2 C23 H23B 107.7 . . ?
H23A C23 H23B 107.1 . . ?
C21 C24 H24A 109.5 . . ?
C21 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C21 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C22 C25 H25A 109.5 . . ?
C22 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C22 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C23 C26 H26A 109.5 . . ?
C23 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
C23 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
C34 C31 P3 113.3(3) . . ?
C34 C31 H31A 108.9 . . ?
P3 C31 H31A 108.9 . . ?
C34 C31 H31B 108.9 . . ?
P3 C31 H31B 108.9 . . ?
H31A C31 H31B 107.7 . . ?
C35 C32 P3 116.8(4) . . ?
C35 C32 H32A 108.1 . . ?
P3 C32 H32A 108.1 . . ?
C35 C32 H32B 108.1 . . ?
P3 C32 H32B 108.1 . . ?
H32A C32 H32B 107.3 . . ?
C36 C33 P3 113.7(4) . . ?
C36 C33 H33A 108.8 . . ?
P3 C33 H33A 108.8 . . ?
C36 C33 H33B 108.8 . . ?
P3 C33 H33B 108.8 . . ?
H33A C33 H33B 107.7 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
C32 C35 H35A 109.5 . . ?
C32 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C32 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
C33 C36 H36A 109.5 . . ?
C33 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C33 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 2.114(4) . ?
Pt1 C8 2.118(4) . ?
Pt1 P2 2.2750(13) . ?
Pt1 P3 2.2849(12) . ?
P2 C21 1.824(5) . ?
P2 C23 1.829(5) . ?
P2 C22 1.833(5) . ?
P3 C33 1.826(5) . ?
P3 C32 1.838(6) . ?
P3 C31 1.839(5) . ?
F1 C4 1.363(6) . ?
N12 C13 1.332(8) . ?
N12 C11 1.336(8) . ?
C1 C6 1.383(7) . ?
C1 C2 1.398(8) . ?
C1 C7 1.499(7) . ?
C2 C3 1.406(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.370(8) . ?
C3 H3 0.9500 . ?
C4 C5 1.370(8) . ?
C5 C6 1.390(7) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.447(7) . ?
C7 H7 0.9341 . ?
C8 C9 1.472(7) . ?
C8 H8 0.9113 . ?
C9 C14 1.393(7) . ?
C9 C10 1.403(7) . ?
C10 C11 1.387(8) . ?
C10 H10 0.9500 . ?
C11 H11 0.9500 . ?
C13 C14 1.410(8) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C21 C24 1.529(9) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 C25 1.523(8) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 C26 1.521(8) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C31 C34 1.520(7) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C35 1.531(7) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 C36 1.506(8) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 H35A 0.9800 . ?
C35 H35B 0.9800 . ?
C35 H35C 0.9800 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C7 Pt1 P2 C21 -134.4(3) . . . . ?
C8 Pt1 P2 C21 -137.2(3) . . . . ?
P3 Pt1 P2 C21 43.5(2) . . . . ?
C7 Pt1 P2 C23 -13.2(2) . . . . ?
C8 Pt1 P2 C23 -16.0(3) . . . . ?
P3 Pt1 P2 C23 164.68(19) . . . . ?
C7 Pt1 P2 C22 104.8(2) . . . . ?
C8 Pt1 P2 C22 102.1(3) . . . . ?
P3 Pt1 P2 C22 -77.3(2) . . . . ?
C7 Pt1 P3 C33 102.0(3) . . . . ?
C8 Pt1 P3 C33 106.5(2) . . . . ?
P2 Pt1 P3 C33 -73.9(2) . . . . ?
C7 Pt1 P3 C32 -16.8(4) . . . . ?
C8 Pt1 P3 C32 -12.3(2) . . . . ?
P2 Pt1 P3 C32 167.29(19) . . . . ?
C7 Pt1 P3 C31 -138.9(3) . . . . ?
C8 Pt1 P3 C31 -134.5(2) . . . . ?
P2 Pt1 P3 C31 45.1(2) . . . . ?
C6 C1 C2 C3 -1.3(7) . . . . ?
C7 C1 C2 C3 178.8(4) . . . . ?
C1 C2 C3 C4 0.5(7) . . . . ?
C2 C3 C4 F1 179.4(4) . . . . ?
C2 C3 C4 C5 -0.4(8) . . . . ?
F1 C4 C5 C6 -178.6(4) . . . . ?
C3 C4 C5 C6 1.1(8) . . . . ?
C2 C1 C6 C5 2.2(7) . . . . ?
C7 C1 C6 C5 -178.0(4) . . . . ?
C4 C5 C6 C1 -2.1(7) . . . . ?
C6 C1 C7 C8 -161.4(4) . . . . ?
C2 C1 C7 C8 18.4(7) . . . . ?
C6 C1 C7 Pt1 115.4(4) . . . . ?
C2 C1 C7 Pt1 -64.7(6) . . . . ?
P2 Pt1 C7 C8 -177.6(3) . . . . ?
P3 Pt1 C7 C8 6.5(5) . . . . ?
C8 Pt1 C7 C1 117.8(5) . . . . ?
P2 Pt1 C7 C1 -59.8(4) . . . . ?
P3 Pt1 C7 C1 124.3(3) . . . . ?
C1 C7 C8 C9 142.9(4) . . . . ?
Pt1 C7 C8 C9 -106.8(4) . . . . ?
C1 C7 C8 Pt1 -110.3(4) . . . . ?
P2 Pt1 C8 C7 4.1(4) . . . . ?
P3 Pt1 C8 C7 -176.6(2) . . . . ?
C7 Pt1 C8 C9 116.7(5) . . . . ?
P2 Pt1 C8 C9 120.8(3) . . . . ?
P3 Pt1 C8 C9 -59.8(4) . . . . ?
C7 C8 C9 C14 20.9(7) . . . . ?
Pt1 C8 C9 C14 -59.7(5) . . . . ?
C7 C8 C9 C10 -159.2(4) . . . . ?
Pt1 C8 C9 C10 120.3(4) . . . . ?
C14 C9 C10 C11 -0.6(7) . . . . ?
C8 C9 C10 C11 179.4(4) . . . . ?
C13 N12 C11 C10 -0.3(7) . . . . ?
C9 C10 C11 N12 1.0(8) . . . . ?
C11 N12 C13 C14 -0.7(8) . . . . ?
C10 C9 C14 C13 -0.3(7) . . . . ?
C8 C9 C14 C13 179.7(4) . . . . ?
N12 C13 C14 C9 1.0(8) . . . . ?
C23 P2 C21 C24 -65.6(5) . . . . ?
C22 P2 C21 C24 -172.5(4) . . . . ?
Pt1 P2 C21 C24 60.3(5) . . . . ?
C21 P2 C22 C25 -179.7(4) . . . . ?
C23 P2 C22 C25 73.1(5) . . . . ?
Pt1 P2 C22 C25 -50.5(5) . . . . ?
C21 P2 C23 C26 -43.9(5) . . . . ?
C22 P2 C23 C26 62.2(5) . . . . ?
Pt1 P2 C23 C26 -173.1(4) . . . . ?
C33 P3 C31 C34 -175.3(4) . . . . ?
C32 P3 C31 C34 -69.2(4) . . . . ?
Pt1 P3 C31 C34 58.4(5) . . . . ?
C33 P3 C32 C35 49.5(5) . . . . ?
C31 P3 C32 C35 -55.8(5) . . . . ?
Pt1 P3 C32 C35 175.3(3) . . . . ?
C32 P3 C33 C36 64.8(5) . . . . ?
C31 P3 C33 C36 172.2(4) . . . . ?
Pt1 P3 C33 C36 -60.5(5) . . . . ?
