#------------------------------------------------------------------------------
#$Date: 2018-09-02 04:56:57 +0300 (Sun, 02 Sep 2018) $
#$Revision: 210349 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/30/21/4302162.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302162
loop_
_publ_author_name
'Dinelli, Luis R.'
'Von Poelhsitz, Gustavo'
'Castellano, Eduardo E.'
'Ellena, Javier'
'Galembeck, Sérgio E.'
'Batista, Alzir A.'
_publ_section_title
;
 On an Electrode Modified by a Supramolecular Ruthenium Mixed Valence
 (RuII/RuIII) Diphosphine-Porphyrin Assembly
;
_journal_coden_ASTM              INOCAJ
_journal_issue                   11
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4692
_journal_page_last               4700
_journal_paper_doi               10.1021/ic702471d
_journal_volume                  48
_journal_year                    2009
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C33 H33 Cl3 N P2 Ru'
_chemical_formula_sum            'C33 H33 Cl3 N P2 Ru'
_chemical_formula_weight         712.96
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/cifdics/cif_core2.1beta.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.1beta3
_audit_creation_date             1999-06-01T16:39:44-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 103.259(6)
_cell_angle_gamma                90
_cell_formula_units_Z            16
_cell_length_a                   32.194(3)
_cell_length_b                   11.0531(9)
_cell_length_c                   35.705(3)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      30.1
_cell_measurement_theta_min      20.0
_cell_measurement_wavelength     1.54184
_cell_volume                     12366.7(19)
_computing_cell_refinement       'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_collection       'CAD4 Express (Enraf Nonius, 1994)'
_computing_data_reduction        'XCAD4 (Harms & Wocadlo, 1995)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX publication routines (Farrugia, 1998)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'scintillation LiI'
_diffrn_detector_dtime           1.195
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Enraf Nonius CAD4'
_diffrn_measurement_method       'non-profiled omega/2theta scans'
_diffrn_orient_matrix_type
;
  x-axis points to radiation source
  the matrix is specified in reciprocal space
;
_diffrn_orient_matrix_UB_11      0.15022E-1
_diffrn_orient_matrix_UB_12      -0.13033E-1
_diffrn_orient_matrix_UB_13      -0.02127
_diffrn_orient_matrix_UB_21      0.28056E-1
_diffrn_orient_matrix_UB_22      0.14518E-1
_diffrn_orient_matrix_UB_23      0.18375E-1
_diffrn_orient_matrix_UB_31      0.00237
_diffrn_orient_matrix_UB_32      -0.88344E-1
_diffrn_orient_matrix_UB_33      0.6156E-2
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0211
_diffrn_reflns_av_sigmaI/netI    0.0309
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -42
_diffrn_reflns_number            10917
_diffrn_reflns_theta_full        66.94
_diffrn_reflns_theta_max         66.94
_diffrn_reflns_theta_min         2.82
_diffrn_source                   'Enraf Nonius FR590'
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  30
_diffrn_standards_number         1
_exptl_absorpt_coefficient_mu    7.652
_exptl_absorpt_correction_T_max  0.5973
_exptl_absorpt_correction_T_min  0.3263
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
        (see. N.W. Alcock (1970). Cryst. Computing, p271)
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.532
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             5808
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.114
_exptl_crystal_size_min          0.086
_refine_diff_density_max         0.911
_refine_diff_density_min         -0.662
_refine_diff_density_rms         0.084
_refine_ls_extinction_coef       0.000070(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.03
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     722
_refine_ls_number_reflns         10727
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.03
_refine_ls_R_factor_all          0.0486
_refine_ls_R_factor_gt           0.0322
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0842
_refine_ls_wR_factor_ref         0.0924
_reflns_number_gt                8442
_reflns_number_total             10727
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic702471d_si_002.cif
_cod_data_source_block           s93
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4302162
#BEGIN Tags that were not found in dictionaries:
_exptl_absorpt_correction_t_ave  0.4835
_diffrn_standards_decay_corr_max 1
_diffrn_standards_decay_corr_min 1
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.144019(7) 0.46656(2) 0.196906(6) 0.02777(8) Uani 1 1 d . . .
Cl11 Cl 0.17219(3) 0.48698(8) 0.26280(2) 0.0415(2) Uani 1 1 d . . .
Cl12 Cl 0.11606(3) 0.45366(8) 0.12978(2) 0.03936(19) Uani 1 1 d . . .
Cl13 Cl 0.18298(3) 0.28354(8) 0.19679(3) 0.0441(2) Uani 1 1 d . . .
P11 P 0.10913(3) 0.66249(7) 0.19296(2) 0.02990(18) Uani 1 1 d . . .
P12 P 0.08513(2) 0.35989(8) 0.20722(2) 0.02931(18) Uani 1 1 d . . .
N1 N 0.20216(9) 0.5526(3) 0.18749(8) 0.0387(7) Uani 1 1 d . . .
C11 C 0.06097(11) 0.6804(3) 0.15363(9) 0.0373(8) Uani 1 1 d . . .
H11A H 0.0576 0.766 0.1477 0.045 Uiso 1 1 calc R . .
H11B H 0.0665 0.6407 0.131 0.045 Uiso 1 1 calc R . .
C12 C 0.01849(11) 0.6335(3) 0.15953(11) 0.0424(8) Uani 1 1 d . . .
H12A H -0.0037 0.658 0.1376 0.051 Uiso 1 1 calc R . .
H12B H 0.0127 0.6726 0.1821 0.051 Uiso 1 1 calc R . .
C13 C 0.01528(12) 0.4973(4) 0.16448(11) 0.0450(9) Uani 1 1 d . . .
H13A H 0.0282 0.4573 0.1458 0.054 Uiso 1 1 calc R . .
H13B H -0.0146 0.4749 0.1588 0.054 Uiso 1 1 calc R . .
C14 C 0.03678(10) 0.4497(3) 0.20489(10) 0.0370(8) Uani 1 1 d . . .
H14A H 0.0163 0.4006 0.2142 0.044 Uiso 1 1 calc R . .
H14B H 0.044 0.5183 0.2221 0.044 Uiso 1 1 calc R . .
C111 C 0.21592(12) 0.5245(4) 0.15580(12) 0.0497(10) Uani 1 1 d . . .
H111 H 0.2014 0.4657 0.1392 0.06 Uiso 1 1 calc R . .
C112 C 0.25077(13) 0.5798(5) 0.14703(14) 0.0631(13) Uani 1 1 d . . .
H112 H 0.2596 0.5583 0.1249 0.076 Uiso 1 1 calc R . .
C113 C 0.27260(13) 0.6676(5) 0.17135(15) 0.0706(15) Uani 1 1 d . . .
H113 H 0.2956 0.7081 0.1654 0.085 Uiso 1 1 calc R . .
C114 C 0.25961(13) 0.6937(5) 0.20442(15) 0.0660(13) Uani 1 1 d . . .
H114 H 0.2743 0.7504 0.2217 0.079 Uiso 1 1 calc R . .
C115 C 0.22465(12) 0.6349(4) 0.21165(12) 0.0500(10) Uani 1 1 d . . .
H115 H 0.2162 0.6528 0.2342 0.06 Uiso 1 1 calc R . .
C121 C 0.14290(12) 0.7801(3) 0.17982(10) 0.0384(8) Uani 1 1 d . . .
C122 C 0.15032(13) 0.7799(4) 0.14295(11) 0.0493(9) Uani 1 1 d . . .
H122 H 0.1374 0.7213 0.1254 0.059 Uiso 1 1 calc R . .
C123 C 0.17643(16) 0.8650(4) 0.13198(15) 0.0674(13) Uani 1 1 d . . .
H123 H 0.1813 0.8631 0.1073 0.081 Uiso 1 1 calc R . .
C124 C 0.19512(19) 0.9522(5) 0.15740(18) 0.0825(17) Uani 1 1 d . . .
H124 H 0.2126 1.0101 0.1499 0.099 Uiso 1 1 calc R . .
C125 C 0.18834(18) 0.9550(4) 0.19399(18) 0.0766(15) Uani 1 1 d . . .
H125 H 0.2011 1.0147 0.2112 0.092 Uiso 1 1 calc R . .
C126 C 0.16242(14) 0.8686(4) 0.20534(13) 0.0553(10) Uani 1 1 d . . .
H126 H 0.1581 0.8702 0.2302 0.066 Uiso 1 1 calc R . .
C131 C 0.09100(11) 0.7307(3) 0.23330(9) 0.0347(7) Uani 1 1 d . . .
C132 C 0.07190(13) 0.8452(3) 0.22758(11) 0.0461(9) Uani 1 1 d . . .
H132 H 0.0705 0.8859 0.2045 0.055 Uiso 1 1 calc R . .
C133 C 0.05514(13) 0.8980(4) 0.25599(12) 0.0524(10) Uani 1 1 d . . .
H133 H 0.0424 0.9738 0.2519 0.063 Uiso 1 1 calc R . .
C134 C 0.05730(14) 0.8386(4) 0.29017(12) 0.0582(11) Uani 1 1 d . . .
H134 H 0.0461 0.8742 0.3093 0.07 Uiso 1 1 calc R . .
C135 C 0.07606(14) 0.7267(4) 0.29594(11) 0.0553(11) Uani 1 1 d . . .
H135 H 0.0774 0.6867 0.3191 0.066 Uiso 1 1 calc R . .
C136 C 0.09300(11) 0.6726(4) 0.26798(10) 0.0415(8) Uani 1 1 d . . .
H136 H 0.1058 0.5969 0.2724 0.05 Uiso 1 1 calc R . .
C141 C 0.06415(10) 0.2291(3) 0.17676(9) 0.0332(7) Uani 1 1 d . . .
C142 C 0.02440(11) 0.1835(3) 0.17928(11) 0.0423(8) Uani 1 1 d . . .
H142 H 0.009 0.2216 0.195 0.051 Uiso 1 1 calc R . .
C143 C 0.00764(13) 0.0813(4) 0.15841(12) 0.0502(10) Uani 1 1 d . . .
H143 H -0.0191 0.0525 0.1598 0.06 Uiso 1 1 calc R . .
C144 C 0.03040(13) 0.0231(3) 0.13588(11) 0.0491(10) Uani 1 1 d . . .
H144 H 0.0191 -0.0452 0.122 0.059 Uiso 1 1 calc R . .
C145 C 0.06978(14) 0.0654(4) 0.13380(12) 0.0503(10) Uani 1 1 d . . .
H145 H 0.0854 0.0243 0.1189 0.06 Uiso 1 1 calc R . .
C146 C 0.08671(12) 0.1692(3) 0.15364(11) 0.0428(8) Uani 1 1 d . . .
H146 H 0.1131 0.1984 0.1514 0.051 Uiso 1 1 calc R . .
C151 C 0.09366(10) 0.2879(3) 0.25443(9) 0.0341(7) Uani 1 1 d . . .
C152 C 0.07734(13) 0.3343(4) 0.28415(10) 0.0461(9) Uani 1 1 d . . .
H152 H 0.0621 0.4064 0.2808 0.055 Uiso 1 1 calc R . .
C153 C 0.08375(14) 0.2730(5) 0.31907(11) 0.0581(11) Uani 1 1 d . . .
H153 H 0.0726 0.304 0.3389 0.07 Uiso 1 1 calc R . .
C154 C 0.10655(14) 0.1670(4) 0.32436(12) 0.0600(12) Uani 1 1 d . . .
H154 H 0.1106 0.1258 0.3476 0.072 Uiso 1 1 calc R . .
C155 C 0.12324(14) 0.1222(4) 0.29551(13) 0.0591(11) Uani 1 1 d . . .
H155 H 0.1392 0.0513 0.2994 0.071 Uiso 1 1 calc R . .
C156 C 0.11681(12) 0.1808(4) 0.26040(11) 0.0478(9) Uani 1 1 d . . .
H156 H 0.128 0.1484 0.2408 0.057 Uiso 1 1 calc R . .
Ru2 Ru 0.347310(7) 0.42745(2) 0.055034(6) 0.02609(8) Uani 1 1 d . . .
Cl21 Cl 0.28488(3) 0.40334(9) 0.00692(2) 0.0429(2) Uani 1 1 d . . .
Cl22 Cl 0.40942(2) 0.42692(7) 0.10431(2) 0.03420(17) Uani 1 1 d . . .
Cl23 Cl 0.32222(2) 0.60699(7) 0.07908(2) 0.03561(18) Uani 1 1 d . . .
P21 P 0.37157(3) 0.23866(8) 0.03439(2) 0.03226(18) Uani 1 1 d . . .
P22 P 0.37896(2) 0.54463(7) 0.01507(2) 0.02767(17) Uani 1 1 d . . .
N2 N 0.31447(9) 0.3354(3) 0.09538(8) 0.0351(6) Uani 1 1 d . . .
C21 C 0.34936(13) 0.1953(3) -0.01584(10) 0.0450(9) Uani 1 1 d . . .
H21A H 0.3535 0.1088 -0.0179 0.054 Uiso 1 1 calc R . .
H21B H 0.3188 0.2092 -0.0212 0.054 Uiso 1 1 calc R . .
C22 C 0.36625(14) 0.2563(4) -0.04780(11) 0.0510(10) Uani 1 1 d . . .
H22A H 0.3521 0.2199 -0.0721 0.061 Uiso 1 1 calc R . .
H22B H 0.3964 0.2378 -0.0437 0.061 Uiso 1 1 calc R . .
C23 C 0.36100(13) 0.3937(4) -0.05183(9) 0.0445(9) Uani 1 1 d . . .
H23A H 0.3334 0.416 -0.0473 0.053 Uiso 1 1 calc R . .
H23B H 0.3611 0.4163 -0.0781 0.053 Uiso 1 1 calc R . .
C24 C 0.39599(11) 0.4667(3) -0.02410(9) 0.0365(7) Uani 1 1 d . . .
H24A H 0.4073 0.5264 -0.039 0.044 Uiso 1 1 calc R . .
H24B H 0.4191 0.412 -0.0129 0.044 Uiso 1 1 calc R . .
C211 C 0.32717(13) 0.3547(4) 0.13333(10) 0.0485(10) Uani 1 1 d . . .
H211 H 0.3504 0.4055 0.1421 0.058 Uiso 1 1 calc R . .
C212 C 0.30777(16) 0.3035(4) 0.15998(13) 0.0632(12) Uani 1 1 d . . .
H212 H 0.3181 0.3181 0.1861 0.076 Uiso 1 1 calc R . .
C213 C 0.27296(16) 0.2304(5) 0.14743(15) 0.0718(14) Uani 1 1 d . . .
H213 H 0.2589 0.1957 0.1648 0.086 Uiso 1 1 calc R . .
C214 C 0.25943(15) 0.2100(5) 0.10895(15) 0.0700(14) Uani 1 1 d . . .
H214 H 0.2359 0.1609 0.0997 0.084 Uiso 1 1 calc R . .
C215 C 0.28072(12) 0.2624(4) 0.08364(12) 0.0509(10) Uani 1 1 d . . .
H215 H 0.2713 0.2464 0.0575 0.061 Uiso 1 1 calc R . .
C221 C 0.35580(11) 0.1140(3) 0.06146(10) 0.0381(8) Uani 1 1 d . . .
C222 C 0.32432(14) 0.0307(4) 0.04539(13) 0.0553(11) Uani 1 1 d . . .
H222 H 0.3105 0.0364 0.0195 0.066 Uiso 1 1 calc R . .
C223 C 0.31371(17) -0.0601(4) 0.06783(16) 0.0731(14) Uani 1 1 d . . .
H223 H 0.2933 -0.117 0.0568 0.088 Uiso 1 1 calc R . .
C224 C 0.33274(18) -0.0679(4) 0.10614(16) 0.0738(15) Uani 1 1 d . . .
H224 H 0.3247 -0.1286 0.1211 0.089 Uiso 1 1 calc R . .
C225 C 0.36390(17) 0.0143(4) 0.12265(14) 0.0668(13) Uani 1 1 d . . .
H225 H 0.377 0.009 0.1487 0.08 Uiso 1 1 calc R . .
C226 C 0.37530(14) 0.1038(4) 0.10044(11) 0.0515(10) Uani 1 1 d . . .
H226 H 0.3964 0.1588 0.1116 0.062 Uiso 1 1 calc R . .
C231 C 0.42888(11) 0.2059(3) 0.04042(10) 0.0374(8) Uani 1 1 d . . .
C232 C 0.44023(14) 0.0870(4) 0.03440(12) 0.0528(10) Uani 1 1 d . . .
H232 H 0.4193 0.0279 0.0279 0.063 Uiso 1 1 calc R . .
C233 C 0.48296(16) 0.0569(4) 0.03818(14) 0.0635(13) Uani 1 1 d . . .
H233 H 0.4905 -0.0227 0.0344 0.076 Uiso 1 1 calc R . .
C234 C 0.51407(14) 0.1435(4) 0.04740(13) 0.0587(12) Uani 1 1 d . . .
H234 H 0.5425 0.123 0.0496 0.07 Uiso 1 1 calc R . .
C235 C 0.50303(13) 0.2606(4) 0.05332(11) 0.0511(10) Uani 1 1 d . . .
H235 H 0.5242 0.3191 0.0599 0.061 Uiso 1 1 calc R . .
C236 C 0.46077(11) 0.2925(3) 0.04963(10) 0.0394(8) Uani 1 1 d . . .
H236 H 0.4537 0.3725 0.0533 0.047 Uiso 1 1 calc R . .
C241 C 0.42701(10) 0.6255(3) 0.04001(9) 0.0313(7) Uani 1 1 d . . .
C242 C 0.46685(11) 0.6075(3) 0.03217(10) 0.0405(8) Uani 1 1 d . . .
H242 H 0.4704 0.5478 0.0148 0.049 Uiso 1 1 calc R . .
C243 C 0.50161(11) 0.6781(4) 0.05007(12) 0.0477(9) Uani 1 1 d . . .
H243 H 0.5282 0.6654 0.0446 0.057 Uiso 1 1 calc R . .
C244 C 0.49657(12) 0.7663(4) 0.07569(11) 0.0468(9) Uani 1 1 d . . .
H244 H 0.5198 0.8132 0.0877 0.056 Uiso 1 1 calc R . .
C245 C 0.45724(12) 0.7854(4) 0.08367(11) 0.0459(9) Uani 1 1 d . . .
H245 H 0.4539 0.8458 0.1009 0.055 Uiso 1 1 calc R . .
C246 C 0.42238(11) 0.7147(3) 0.06604(10) 0.0403(8) Uani 1 1 d . . .
H246 H 0.396 0.7273 0.0718 0.048 Uiso 1 1 calc R . .
C251 C 0.34959(10) 0.6730(3) -0.01108(9) 0.0330(7) Uani 1 1 d . . .
C252 C 0.37278(12) 0.7579(3) -0.02722(11) 0.0442(9) Uani 1 1 d . . .
H252 H 0.4019 0.7468 -0.0248 0.053 Uiso 1 1 calc R . .
C253 C 0.35292(13) 0.8582(4) -0.04676(11) 0.0479(9) Uani 1 1 d . . .
H253 H 0.3688 0.9141 -0.0571 0.058 Uiso 1 1 calc R . .
C254 C 0.31017(14) 0.8749(4) -0.05086(11) 0.0514(10) Uani 1 1 d . . .
H254 H 0.2969 0.9423 -0.0639 0.062 Uiso 1 1 calc R . .
C255 C 0.28649(13) 0.7919(4) -0.03567(12) 0.0543(10) Uani 1 1 d . . .
H255 H 0.2573 0.8033 -0.0387 0.065 Uiso 1 1 calc R . .
C256 C 0.30619(11) 0.6913(4) -0.01579(10) 0.0420(8) Uani 1 1 d . . .
H256 H 0.29 0.6359 -0.0056 0.05 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru 0.0552 3.296 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
11 1 10
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
1 0 -1 0.043
-1 0 1 0.043
0 1 0 0.175
0 -1 0 0.175
0 0 1 0.057
0 0 -1 0.057
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ru1 Cl11 87.97(8) . . ?
N1 Ru1 P12 175.30(8) . . ?
Cl11 Ru1 P12 91.82(3) . . ?
N1 Ru1 Cl12 90.61(8) . . ?
Cl11 Ru1 Cl12 177.83(3) . . ?
P12 Ru1 Cl12 89.73(3) . . ?
N1 Ru1 Cl13 84.25(8) . . ?
Cl11 Ru1 Cl13 90.05(3) . . ?
P12 Ru1 Cl13 91.05(3) . . ?
Cl12 Ru1 Cl13 91.45(3) . . ?
N1 Ru1 P11 90.23(8) . . ?
Cl11 Ru1 P11 92.29(3) . . ?
P12 Ru1 P11 94.47(3) . . ?
Cl12 Ru1 P11 86.07(3) . . ?
Cl13 Ru1 P11 173.93(3) . . ?
C121 P11 C131 102.98(16) . . ?
C121 P11 C11 100.02(16) . . ?
C131 P11 C11 100.95(16) . . ?
C121 P11 Ru1 110.81(12) . . ?
C131 P11 Ru1 123.16(11) . . ?
C11 P11 Ru1 115.82(12) . . ?
C151 P12 C14 102.96(16) . . ?
C151 P12 C141 99.21(15) . . ?
C14 P12 C141 101.89(16) . . ?
C151 P12 Ru1 114.22(10) . . ?
C14 P12 Ru1 115.58(12) . . ?
C141 P12 Ru1 120.32(11) . . ?
C111 N1 C115 117.6(3) . . ?
C111 N1 Ru1 119.1(3) . . ?
C115 N1 Ru1 123.2(3) . . ?
C12 C11 P11 118.8(2) . . ?
C12 C11 H11A 107.6 . . ?
P11 C11 H11A 107.6 . . ?
C12 C11 H11B 107.6 . . ?
P11 C11 H11B 107.6 . . ?
H11A C11 H11B 107.0 . . ?
C11 C12 C13 116.1(3) . . ?
C11 C12 H12A 108.3 . . ?
C13 C12 H12A 108.3 . . ?
C11 C12 H12B 108.3 . . ?
C13 C12 H12B 108.3 . . ?
H12A C12 H12B 107.4 . . ?
C12 C13 C14 114.7(3) . . ?
C12 C13 H13A 108.6 . . ?
C14 C13 H13A 108.6 . . ?
C12 C13 H13B 108.6 . . ?
C14 C13 H13B 108.6 . . ?
H13A C13 H13B 107.6 . . ?
C13 C14 P12 114.9(3) . . ?
C13 C14 H14A 108.5 . . ?
P12 C14 H14A 108.5 . . ?
C13 C14 H14B 108.5 . . ?
P12 C14 H14B 108.5 . . ?
H14A C14 H14B 107.5 . . ?
N1 C111 C112 122.2(4) . . ?
N1 C111 H111 118.9 . . ?
C112 C111 H111 118.9 . . ?
C111 C112 C113 119.5(4) . . ?
C111 C112 H112 120.2 . . ?
C113 C112 H112 120.2 . . ?
C114 C113 C112 118.5(4) . . ?
C114 C113 H113 120.8 . . ?
C112 C113 H113 120.8 . . ?
C113 C114 C115 119.2(5) . . ?
C113 C114 H114 120.4 . . ?
C115 C114 H114 120.4 . . ?
N1 C115 C114 122.9(4) . . ?
N1 C115 H115 118.6 . . ?
C114 C115 H115 118.6 . . ?
C126 C121 C122 118.2(4) . . ?
C126 C121 P11 122.8(3) . . ?
C122 C121 P11 119.0(3) . . ?
C123 C122 C121 121.1(4) . . ?
C123 C122 H122 119.4 . . ?
C121 C122 H122 119.4 . . ?
C124 C123 C122 119.9(5) . . ?
C124 C123 H123 120.1 . . ?
C122 C123 H123 120.1 . . ?
C123 C124 C125 120.4(4) . . ?
C123 C124 H124 119.8 . . ?
C125 C124 H124 119.8 . . ?
C124 C125 C126 120.0(5) . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C121 C126 C125 120.4(4) . . ?
C121 C126 H126 119.8 . . ?
C125 C126 H126 119.8 . . ?
C136 C131 C132 118.6(3) . . ?
C136 C131 P11 123.6(3) . . ?
C132 C131 P11 117.7(3) . . ?
C133 C132 C131 120.4(4) . . ?
C133 C132 H132 119.8 . . ?
C131 C132 H132 119.8 . . ?
C134 C133 C132 120.1(4) . . ?
C134 C133 H133 119.9 . . ?
C132 C133 H133 119.9 . . ?
C135 C134 C133 119.7(4) . . ?
C135 C134 H134 120.2 . . ?
C133 C134 H134 120.2 . . ?
C134 C135 C136 121.1(4) . . ?
C134 C135 H135 119.4 . . ?
C136 C135 H135 119.4 . . ?
C135 C136 C131 120.1(4) . . ?
C135 C136 H136 120.0 . . ?
C131 C136 H136 120.0 . . ?
C146 C141 C142 118.6(3) . . ?
C146 C141 P12 123.7(3) . . ?
C142 C141 P12 117.6(3) . . ?
C143 C142 C141 120.4(4) . . ?
C143 C142 H142 119.8 . . ?
C141 C142 H142 119.8 . . ?
C144 C143 C142 120.2(4) . . ?
C144 C143 H143 119.9 . . ?
C142 C143 H143 119.9 . . ?
C143 C144 C145 119.9(4) . . ?
C143 C144 H144 120.0 . . ?
C145 C144 H144 120.0 . . ?
C144 C145 C146 120.9(4) . . ?
C144 C145 H145 119.6 . . ?
C146 C145 H145 119.6 . . ?
C141 C146 C145 119.9(4) . . ?
C141 C146 H146 120.0 . . ?
C145 C146 H146 120.0 . . ?
C152 C151 C156 118.8(3) . . ?
C152 C151 P12 122.8(3) . . ?
C156 C151 P12 118.3(3) . . ?
C151 C152 C153 120.1(4) . . ?
C151 C152 H152 120.0 . . ?
C153 C152 H152 120.0 . . ?
C154 C153 C152 120.2(4) . . ?
C154 C153 H153 119.9 . . ?
C152 C153 H153 119.9 . . ?
C155 C154 C153 119.9(4) . . ?
C155 C154 H154 120.1 . . ?
C153 C154 H154 120.1 . . ?
C154 C155 C156 120.9(4) . . ?
C154 C155 H155 119.6 . . ?
C156 C155 H155 119.6 . . ?
C155 C156 C151 120.1(4) . . ?
C155 C156 H156 120.0 . . ?
C151 C156 H156 120.0 . . ?
N2 Ru2 P22 173.46(8) . . ?
N2 Ru2 Cl21 88.14(8) . . ?
P22 Ru2 Cl21 92.08(3) . . ?
N2 Ru2 Cl22 87.88(7) . . ?
P22 Ru2 Cl22 92.50(3) . . ?
Cl21 Ru2 Cl22 173.24(3) . . ?
N2 Ru2 Cl23 84.06(8) . . ?
P22 Ru2 Cl23 89.40(3) . . ?
Cl21 Ru2 Cl23 93.12(3) . . ?
Cl22 Ru2 Cl23 91.90(3) . . ?
N2 Ru2 P21 92.16(8) . . ?
P22 Ru2 P21 94.38(3) . . ?
Cl21 Ru2 P21 87.76(3) . . ?
Cl22 Ru2 P21 86.94(3) . . ?
Cl23 Ru2 P21 176.08(3) . . ?
C221 P21 C21 103.15(17) . . ?
C221 P21 C231 100.54(16) . . ?
C21 P21 C231 102.59(17) . . ?
C221 P21 Ru2 110.15(12) . . ?
C21 P21 Ru2 116.44(13) . . ?
C231 P21 Ru2 121.45(12) . . ?
C24 P22 C241 103.49(16) . . ?
C24 P22 C251 100.64(15) . . ?
C241 P22 C251 98.58(15) . . ?
C24 P22 Ru2 117.17(12) . . ?
C241 P22 Ru2 114.40(10) . . ?
C251 P22 Ru2 119.66(11) . . ?
C211 N2 C215 116.7(3) . . ?
C211 N2 Ru2 120.2(2) . . ?
C215 N2 Ru2 123.1(2) . . ?
C22 C21 P21 119.2(3) . . ?
C22 C21 H21A 107.5 . . ?
P21 C21 H21A 107.5 . . ?
C22 C21 H21B 107.5 . . ?
P21 C21 H21B 107.5 . . ?
H21A C21 H21B 107.0 . . ?
C21 C22 C23 117.2(3) . . ?
C21 C22 H22A 108.0 . . ?
C23 C22 H22A 108.0 . . ?
C21 C22 H22B 108.0 . . ?
C23 C22 H22B 108.0 . . ?
H22A C22 H22B 107.2 . . ?
C22 C23 C24 114.2(3) . . ?
C22 C23 H23A 108.7 . . ?
C24 C23 H23A 108.7 . . ?
C22 C23 H23B 108.7 . . ?
C24 C23 H23B 108.7 . . ?
H23A C23 H23B 107.6 . . ?
C23 C24 P22 115.6(2) . . ?
C23 C24 H24A 108.4 . . ?
P22 C24 H24A 108.4 . . ?
C23 C24 H24B 108.4 . . ?
P22 C24 H24B 108.4 . . ?
H24A C24 H24B 107.4 . . ?
N2 C211 C212 123.6(4) . . ?
N2 C211 H211 118.2 . . ?
C212 C211 H211 118.2 . . ?
C213 C212 C211 118.9(4) . . ?
C213 C212 H212 120.5 . . ?
C211 C212 H212 120.5 . . ?
C214 C213 C212 118.4(4) . . ?
C214 C213 H213 120.8 . . ?
C212 C213 H213 120.8 . . ?
C213 C214 C215 120.0(4) . . ?
C213 C214 H214 120.0 . . ?
C215 C214 H214 120.0 . . ?
N2 C215 C214 122.4(4) . . ?
N2 C215 H215 118.8 . . ?
C214 C215 H215 118.8 . . ?
C222 C221 C226 118.5(4) . . ?
C222 C221 P21 123.2(3) . . ?
C226 C221 P21 118.3(3) . . ?
C223 C222 C221 119.8(4) . . ?
C223 C222 H222 120.1 . . ?
C221 C222 H222 120.1 . . ?
C224 C223 C222 121.0(4) . . ?
C224 C223 H223 119.5 . . ?
C222 C223 H223 119.5 . . ?
C223 C224 C225 120.0(4) . . ?
C223 C224 H224 120.0 . . ?
C225 C224 H224 120.0 . . ?
C226 C225 C224 119.5(4) . . ?
C226 C225 H225 120.2 . . ?
C224 C225 H225 120.2 . . ?
C225 C226 C221 121.2(4) . . ?
C225 C226 H226 119.4 . . ?
C221 C226 H226 119.4 . . ?
C236 C231 C232 118.8(3) . . ?
C236 C231 P21 124.0(3) . . ?
C232 C231 P21 117.2(3) . . ?
C233 C232 C231 119.9(4) . . ?
C233 C232 H232 120.0 . . ?
C231 C232 H232 120.0 . . ?
C234 C233 C232 120.5(4) . . ?
C234 C233 H233 119.7 . . ?
C232 C233 H233 119.7 . . ?
C233 C234 C235 119.7(4) . . ?
C233 C234 H234 120.1 . . ?
C235 C234 H234 120.1 . . ?
C234 C235 C236 120.7(4) . . ?
C234 C235 H235 119.7 . . ?
C236 C235 H235 119.7 . . ?
C235 C236 C231 120.4(4) . . ?
C235 C236 H236 119.8 . . ?
C231 C236 H236 119.8 . . ?
C246 C241 C242 118.9(3) . . ?
C246 C241 P22 117.7(2) . . ?
C242 C241 P22 123.3(3) . . ?
C241 C242 C243 120.6(3) . . ?
C241 C242 H242 119.7 . . ?
C243 C242 H242 119.7 . . ?
C244 C243 C242 119.9(3) . . ?
C244 C243 H243 120.0 . . ?
C242 C243 H243 120.1 . . ?
C243 C244 C245 120.2(3) . . ?
C243 C244 H244 119.9 . . ?
C245 C244 H244 119.9 . . ?
C244 C245 C246 120.2(4) . . ?
C244 C245 H245 119.9 . . ?
C246 C245 H245 119.9 . . ?
C241 C246 C245 120.2(3) . . ?
C241 C246 H246 119.9 . . ?
C245 C246 H246 119.9 . . ?
C256 C251 C252 118.0(3) . . ?
C256 C251 P22 124.2(3) . . ?
C252 C251 P22 117.7(3) . . ?
C253 C252 C251 121.0(4) . . ?
C253 C252 H252 119.5 . . ?
C251 C252 H252 119.5 . . ?
C254 C253 C252 120.0(4) . . ?
C254 C253 H253 120.0 . . ?
C252 C253 H253 120.0 . . ?
C253 C254 C255 120.2(4) . . ?
C253 C254 H254 119.9 . . ?
C255 C254 H254 119.9 . . ?
C254 C255 C256 120.2(4) . . ?
C254 C255 H255 119.9 . . ?
C256 C255 H255 119.9 . . ?
C251 C256 C255 120.6(4) . . ?
C251 C256 H256 119.7 . . ?
C255 C256 H256 119.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N1 2.193(3) . ?
Ru1 Cl11 2.3304(8) . ?
Ru1 P12 2.3325(8) . ?
Ru1 Cl12 2.3632(8) . ?
Ru1 Cl13 2.3807(9) . ?
Ru1 P11 2.4289(9) . ?
P11 C121 1.824(4) . ?
P11 C131 1.836(3) . ?
P11 C11 1.848(3) . ?
P12 C151 1.827(3) . ?
P12 C14 1.832(3) . ?
P12 C141 1.842(3) . ?
N1 C111 1.343(5) . ?
N1 C115 1.345(5) . ?
C11 C12 1.522(5) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 C13 1.522(5) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.542(5) . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C111 C112 1.376(5) . ?
C111 H111 0.9300 . ?
C112 C113 1.382(7) . ?
C112 H112 0.9300 . ?
C113 C114 1.371(7) . ?
C113 H113 0.9300 . ?
C114 C115 1.374(6) . ?
C114 H114 0.9300 . ?
C115 H115 0.9300 . ?
C121 C126 1.386(5) . ?
C121 C122 1.391(5) . ?
C122 C123 1.377(6) . ?
C122 H122 0.9300 . ?
C123 C124 1.366(7) . ?
C123 H123 0.9300 . ?
C124 C125 1.374(8) . ?
C124 H124 0.9300 . ?
C125 C126 1.388(6) . ?
C125 H125 0.9300 . ?
C126 H126 0.9300 . ?
C131 C136 1.384(5) . ?
C131 C132 1.401(5) . ?
C132 C133 1.383(5) . ?
C132 H132 0.9300 . ?
C133 C134 1.373(6) . ?
C133 H133 0.9300 . ?
C134 C135 1.371(6) . ?
C134 H134 0.9300 . ?
C135 C136 1.379(5) . ?
C135 H135 0.9300 . ?
C136 H136 0.9300 . ?
C141 C146 1.386(5) . ?
C141 C142 1.398(5) . ?
C142 C143 1.392(5) . ?
C142 H142 0.9300 . ?
C143 C144 1.367(6) . ?
C143 H143 0.9300 . ?
C144 C145 1.370(6) . ?
C144 H144 0.9300 . ?
C145 C146 1.392(5) . ?
C145 H145 0.9300 . ?
C146 H146 0.9300 . ?
C151 C152 1.386(5) . ?
C151 C156 1.389(5) . ?
C152 C153 1.392(5) . ?
C152 H152 0.9300 . ?
C153 C154 1.373(7) . ?
C153 H153 0.9300 . ?
C154 C155 1.360(7) . ?
C154 H154 0.9300 . ?
C155 C156 1.383(5) . ?
C155 H155 0.9300 . ?
C156 H156 0.9300 . ?
Ru2 N2 2.220(3) . ?
Ru2 P22 2.3278(8) . ?
Ru2 Cl21 2.3405(8) . ?
Ru2 Cl22 2.3410(8) . ?
Ru2 Cl23 2.3760(8) . ?
Ru2 P21 2.4025(9) . ?
P21 C221 1.821(4) . ?
P21 C21 1.836(3) . ?
P21 C231 1.843(4) . ?
P22 C24 1.830(3) . ?
P22 C241 1.831(3) . ?
P22 C251 1.837(3) . ?
N2 C211 1.340(5) . ?
N2 C215 1.341(4) . ?
C21 C22 1.529(5) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.531(6) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.545(5) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C211 C212 1.374(5) . ?
C211 H211 0.9300 . ?
C212 C213 1.370(6) . ?
C212 H212 0.9300 . ?
C213 C214 1.362(7) . ?
C213 H213 0.9300 . ?
C214 C215 1.380(6) . ?
C214 H214 0.9300 . ?
C215 H215 0.9300 . ?
C221 C222 1.392(5) . ?
C221 C226 1.394(5) . ?
C222 C223 1.376(6) . ?
C222 H222 0.9300 . ?
C223 C224 1.367(7) . ?
C223 H223 0.9300 . ?
C224 C225 1.382(7) . ?
C224 H224 0.9300 . ?
C225 C226 1.370(6) . ?
C225 H225 0.9300 . ?
C226 H226 0.9300 . ?
C231 C236 1.387(5) . ?
C231 C232 1.394(5) . ?
C232 C233 1.392(6) . ?
C232 H232 0.9300 . ?
C233 C234 1.370(7) . ?
C233 H233 0.9300 . ?
C234 C235 1.371(6) . ?
C234 H234 0.9300 . ?
C235 C236 1.382(5) . ?
C235 H235 0.9300 . ?
C236 H236 0.9300 . ?
C241 C246 1.386(5) . ?
C241 C242 1.388(5) . ?
C242 C243 1.393(5) . ?
C242 H242 0.9300 . ?
C243 C244 1.372(6) . ?
C243 H243 0.9300 . ?
C244 C245 1.376(5) . ?
C244 H244 0.9300 . ?
C245 C246 1.394(5) . ?
C245 H245 0.9300 . ?
C246 H246 0.9300 . ?
C251 C256 1.383(5) . ?
C251 C252 1.403(5) . ?
C252 C253 1.385(5) . ?
C252 H252 0.9300 . ?
C253 C254 1.363(6) . ?
C253 H253 0.9300 . ?
C254 C255 1.380(6) . ?
C254 H254 0.9300 . ?
C255 C256 1.391(5) . ?
C255 H255 0.9300 . ?
C256 H256 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ru1 P11 C121 5.68(15) . . . . ?
Cl11 Ru1 P11 C121 93.66(13) . . . . ?
P12 Ru1 P11 C121 -174.33(13) . . . . ?
Cl12 Ru1 P11 C121 -84.91(13) . . . . ?
Cl13 Ru1 P11 C121 -18.9(3) . . . . ?
N1 Ru1 P11 C131 -116.69(15) . . . . ?
Cl11 Ru1 P11 C131 -28.71(13) . . . . ?
P12 Ru1 P11 C131 63.30(13) . . . . ?
Cl12 Ru1 P11 C131 152.72(13) . . . . ?
Cl13 Ru1 P11 C131 -141.3(3) . . . . ?
N1 Ru1 P11 C11 118.68(15) . . . . ?
Cl11 Ru1 P11 C11 -153.34(13) . . . . ?
P12 Ru1 P11 C11 -61.33(13) . . . . ?
Cl12 Ru1 P11 C11 28.09(13) . . . . ?
Cl13 Ru1 P11 C11 94.1(3) . . . . ?
N1 Ru1 P12 C151 65.2(10) . . . . ?
Cl11 Ru1 P12 C151 -22.24(13) . . . . ?
Cl12 Ru1 P12 C151 159.28(13) . . . . ?
Cl13 Ru1 P12 C151 67.84(13) . . . . ?
P11 Ru1 P12 C151 -114.68(13) . . . . ?
N1 Ru1 P12 C14 -176(9) . . . . ?
Cl11 Ru1 P12 C14 96.97(13) . . . . ?
Cl12 Ru1 P12 C14 -81.50(13) . . . . ?
Cl13 Ru1 P12 C14 -172.95(13) . . . . ?
P11 Ru1 P12 C14 4.53(13) . . . . ?
N1 Ru1 P12 C141 -52.6(10) . . . . ?
Cl11 Ru1 P12 C141 -140.03(12) . . . . ?
Cl12 Ru1 P12 C141 41.49(12) . . . . ?
Cl13 Ru1 P12 C141 -49.95(13) . . . . ?
P11 Ru1 P12 C141 127.53(12) . . . . ?
Cl11 Ru1 N1 C111 151.0(3) . . . . ?
P12 Ru1 N1 C111 63.4(11) . . . . ?
Cl12 Ru1 N1 C111 -30.7(3) . . . . ?
Cl13 Ru1 N1 C111 60.7(3) . . . . ?
P11 Ru1 N1 C111 -116.8(3) . . . . ?
Cl11 Ru1 N1 C115 -30.4(3) . . . . ?
P12 Ru1 N1 C115 -118.0(9) . . . . ?
Cl12 Ru1 N1 C115 148.0(3) . . . . ?
Cl13 Ru1 N1 C115 -120.6(3) . . . . ?
P11 Ru1 N1 C115 61.9(3) . . . . ?
C121 P11 C11 C12 -158.4(3) . . . . ?
C131 P11 C11 C12 -53.0(3) . . . . ?
Ru1 P11 C11 C12 82.5(3) . . . . ?
P11 C11 C12 C13 -64.5(4) . . . . ?
C11 C12 C13 C14 78.5(4) . . . . ?
C12 C13 C14 P12 -110.3(3) . . . . ?
C151 P12 C14 C13 -165.9(3) . . . . ?
C141 P12 C14 C13 -63.4(3) . . . . ?
Ru1 P12 C14 C13 68.8(3) . . . . ?
C115 N1 C111 C112 -2.3(6) . . . . ?
Ru1 N1 C111 C112 176.4(3) . . . . ?
N1 C111 C112 C113 -0.1(7) . . . . ?
C111 C112 C113 C114 2.4(7) . . . . ?
C112 C113 C114 C115 -2.1(7) . . . . ?
C111 N1 C115 C114 2.6(6) . . . . ?
Ru1 N1 C115 C114 -176.1(3) . . . . ?
C113 C114 C115 N1 -0.4(7) . . . . ?
C131 P11 C121 C126 23.7(4) . . . . ?
C11 P11 C121 C126 127.6(3) . . . . ?
Ru1 P11 C121 C126 -109.7(3) . . . . ?
C131 P11 C121 C122 -157.8(3) . . . . ?
C11 P11 C121 C122 -53.9(3) . . . . ?
Ru1 P11 C121 C122 68.8(3) . . . . ?
C126 C121 C122 C123 0.2(6) . . . . ?
P11 C121 C122 C123 -178.4(3) . . . . ?
C121 C122 C123 C124 -0.7(7) . . . . ?
C122 C123 C124 C125 0.6(9) . . . . ?
C123 C124 C125 C126 0.1(9) . . . . ?
C122 C121 C126 C125 0.5(7) . . . . ?
P11 C121 C126 C125 179.0(4) . . . . ?
C124 C125 C126 C121 -0.7(8) . . . . ?
C121 P11 C131 C136 -130.7(3) . . . . ?
C11 P11 C131 C136 126.2(3) . . . . ?
Ru1 P11 C131 C136 -4.8(4) . . . . ?
C121 P11 C131 C132 53.1(3) . . . . ?
C11 P11 C131 C132 -50.0(3) . . . . ?
Ru1 P11 C131 C132 179.0(2) . . . . ?
C136 C131 C132 C133 -0.5(6) . . . . ?
P11 C131 C132 C133 175.8(3) . . . . ?
C131 C132 C133 C134 0.3(6) . . . . ?
C132 C133 C134 C135 -0.1(7) . . . . ?
C133 C134 C135 C136 0.2(7) . . . . ?
C134 C135 C136 C131 -0.4(6) . . . . ?
C132 C131 C136 C135 0.6(6) . . . . ?
P11 C131 C136 C135 -175.6(3) . . . . ?
C151 P12 C141 C146 -108.8(3) . . . . ?
C14 P12 C141 C146 145.8(3) . . . . ?
Ru1 P12 C141 C146 16.4(3) . . . . ?
C151 P12 C141 C142 66.8(3) . . . . ?
C14 P12 C141 C142 -38.6(3) . . . . ?
Ru1 P12 C141 C142 -168.0(2) . . . . ?
C146 C141 C142 C143 -1.1(5) . . . . ?
P12 C141 C142 C143 -177.0(3) . . . . ?
C141 C142 C143 C144 1.4(6) . . . . ?
C142 C143 C144 C145 -0.1(6) . . . . ?
C143 C144 C145 C146 -1.6(6) . . . . ?
C142 C141 C146 C145 -0.5(5) . . . . ?
P12 C141 C146 C145 175.0(3) . . . . ?
C144 C145 C146 C141 1.9(6) . . . . ?
C14 P12 C151 C152 -22.8(3) . . . . ?
C141 P12 C151 C152 -127.4(3) . . . . ?
Ru1 P12 C151 C152 103.3(3) . . . . ?
C14 P12 C151 C156 155.9(3) . . . . ?
C141 P12 C151 C156 51.3(3) . . . . ?
Ru1 P12 C151 C156 -78.0(3) . . . . ?
C156 C151 C152 C153 -0.9(5) . . . . ?
P12 C151 C152 C153 177.9(3) . . . . ?
C151 C152 C153 C154 0.6(6) . . . . ?
C152 C153 C154 C155 0.6(6) . . . . ?
C153 C154 C155 C156 -1.4(7) . . . . ?
C154 C155 C156 C151 1.1(6) . . . . ?
C152 C151 C156 C155 0.0(6) . . . . ?
P12 C151 C156 C155 -178.7(3) . . . . ?
N2 Ru2 P21 C221 -3.16(14) . . . . ?
P22 Ru2 P21 C221 176.87(12) . . . . ?
Cl21 Ru2 P21 C221 -91.22(12) . . . . ?
Cl22 Ru2 P21 C221 84.60(12) . . . . ?
Cl23 Ru2 P21 C221 11.8(5) . . . . ?
N2 Ru2 P21 C21 113.78(16) . . . . ?
P22 Ru2 P21 C21 -66.18(15) . . . . ?
Cl21 Ru2 P21 C21 25.73(15) . . . . ?
Cl22 Ru2 P21 C21 -158.46(15) . . . . ?
Cl23 Ru2 P21 C21 128.8(4) . . . . ?
N2 Ru2 P21 C231 -120.10(15) . . . . ?
P22 Ru2 P21 C231 59.94(13) . . . . ?
Cl21 Ru2 P21 C231 151.85(13) . . . . ?
Cl22 Ru2 P21 C231 -32.34(13) . . . . ?
Cl23 Ru2 P21 C231 -105.1(5) . . . . ?
N2 Ru2 P22 C24 -163.8(7) . . . . ?
Cl21 Ru2 P22 C24 -72.08(13) . . . . ?
Cl22 Ru2 P22 C24 102.95(13) . . . . ?
Cl23 Ru2 P22 C24 -165.18(13) . . . . ?
P21 Ru2 P22 C24 15.83(13) . . . . ?
N2 Ru2 P22 C241 74.8(7) . . . . ?
Cl21 Ru2 P22 C241 166.54(12) . . . . ?
Cl22 Ru2 P22 C241 -18.44(12) . . . . ?
Cl23 Ru2 P22 C241 73.44(12) . . . . ?
P21 Ru2 P22 C241 -105.56(12) . . . . ?
N2 Ru2 P22 C251 -41.8(7) . . . . ?
Cl21 Ru2 P22 C251 50.00(13) . . . . ?
Cl22 Ru2 P22 C251 -134.97(12) . . . . ?
Cl23 Ru2 P22 C251 -43.10(12) . . . . ?
P21 Ru2 P22 C251 137.91(12) . . . . ?
P22 Ru2 N2 C211 -63.9(8) . . . . ?
Cl21 Ru2 N2 C211 -155.9(3) . . . . ?
Cl22 Ru2 N2 C211 29.6(3) . . . . ?
Cl23 Ru2 N2 C211 -62.6(3) . . . . ?
P21 Ru2 N2 C211 116.4(3) . . . . ?
P22 Ru2 N2 C215 113.8(7) . . . . ?
Cl21 Ru2 N2 C215 21.8(3) . . . . ?
Cl22 Ru2 N2 C215 -152.8(3) . . . . ?
Cl23 Ru2 N2 C215 115.1(3) . . . . ?
P21 Ru2 N2 C215 -65.9(3) . . . . ?
C221 P21 C21 C22 -162.2(3) . . . . ?
C231 P21 C21 C22 -58.1(3) . . . . ?
Ru2 P21 C21 C22 77.0(3) . . . . ?
P21 C21 C22 C23 -60.6(5) . . . . ?
C21 C22 C23 C24 82.7(5) . . . . ?
C22 C23 C24 P22 -108.7(3) . . . . ?
C241 P22 C24 C23 -177.4(3) . . . . ?
C251 P22 C24 C23 -75.8(3) . . . . ?
Ru2 P22 C24 C23 55.6(3) . . . . ?
C215 N2 C211 C212 0.5(6) . . . . ?
Ru2 N2 C211 C212 178.3(4) . . . . ?
N2 C211 C212 C213 -1.4(7) . . . . ?
C211 C212 C213 C214 1.1(8) . . . . ?
C212 C213 C214 C215 0.1(8) . . . . ?
C211 N2 C215 C214 0.7(6) . . . . ?
Ru2 N2 C215 C214 -177.0(4) . . . . ?
C213 C214 C215 N2 -1.0(8) . . . . ?
C21 P21 C221 C222 -16.0(4) . . . . ?
C231 P21 C221 C222 -121.7(4) . . . . ?
Ru2 P21 C221 C222 109.0(3) . . . . ?
C21 P21 C221 C226 166.0(3) . . . . ?
C231 P21 C221 C226 60.3(3) . . . . ?
Ru2 P21 C221 C226 -69.0(3) . . . . ?
C226 C221 C222 C223 -1.1(7) . . . . ?
P21 C221 C222 C223 -179.1(4) . . . . ?
C221 C222 C223 C224 2.0(8) . . . . ?
C222 C223 C224 C225 -1.6(9) . . . . ?
C223 C224 C225 C226 0.4(9) . . . . ?
C224 C225 C226 C221 0.4(8) . . . . ?
C222 C221 C226 C225 -0.1(7) . . . . ?
P21 C221 C226 C225 178.0(4) . . . . ?
C221 P21 C231 C236 -134.9(3) . . . . ?
C21 P21 C231 C236 118.9(3) . . . . ?
Ru2 P21 C231 C236 -13.3(3) . . . . ?
C221 P21 C231 C232 46.6(3) . . . . ?
C21 P21 C231 C232 -59.6(3) . . . . ?
Ru2 P21 C231 C232 168.3(3) . . . . ?
C236 C231 C232 C233 0.9(6) . . . . ?
P21 C231 C232 C233 179.4(3) . . . . ?
C231 C232 C233 C234 -0.7(7) . . . . ?
C232 C233 C234 C235 0.7(7) . . . . ?
C233 C234 C235 C236 -0.8(6) . . . . ?
C234 C235 C236 C231 1.0(6) . . . . ?
C232 C231 C236 C235 -1.0(5) . . . . ?
P21 C231 C236 C235 -179.5(3) . . . . ?
C24 P22 C241 C246 166.0(3) . . . . ?
C251 P22 C241 C246 62.8(3) . . . . ?
Ru2 P22 C241 C246 -65.3(3) . . . . ?
C24 P22 C241 C242 -9.4(3) . . . . ?
C251 P22 C241 C242 -112.6(3) . . . . ?
Ru2 P22 C241 C242 119.2(3) . . . . ?
C246 C241 C242 C243 -0.2(5) . . . . ?
P22 C241 C242 C243 175.2(3) . . . . ?
C241 C242 C243 C244 0.0(6) . . . . ?
C242 C243 C244 C245 -0.2(6) . . . . ?
C243 C244 C245 C246 0.6(6) . . . . ?
C242 C241 C246 C245 0.6(5) . . . . ?
P22 C241 C246 C245 -175.1(3) . . . . ?
C244 C245 C246 C241 -0.8(6) . . . . ?
C24 P22 C251 C256 115.0(3) . . . . ?
C241 P22 C251 C256 -139.4(3) . . . . ?
Ru2 P22 C251 C256 -14.9(3) . . . . ?
C24 P22 C251 C252 -65.1(3) . . . . ?
C241 P22 C251 C252 40.5(3) . . . . ?
Ru2 P22 C251 C252 165.0(2) . . . . ?
C256 C251 C252 C253 1.0(5) . . . . ?
P22 C251 C252 C253 -178.9(3) . . . . ?
C251 C252 C253 C254 -0.6(6) . . . . ?
C252 C253 C254 C255 -0.2(6) . . . . ?
C253 C254 C255 C256 0.5(6) . . . . ?
C252 C251 C256 C255 -0.7(5) . . . . ?
P22 C251 C256 C255 179.2(3) . . . . ?
C254 C255 C256 C251 -0.1(6) . . . . ?
