#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:30:56 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179064 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/26/4302607.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302607
loop_
_publ_author_name
'Branson A. Maynard'
'Philip A. Smith'
'Le Ann Ladner'
'Ayesha Jaleel'
'Nuquie Beedoe'
'Carlos Crawford'
'Zerihun Assefa'
'Richard E. Sykora'
_publ_contact_author_address
;University of South Alabama
Department of Chemistry
Chemistry Building, Room 223
Mobile  AL  36688-0002
;
_publ_contact_author_email       rsykora@jaguar1.usouthal.edu
_publ_contact_author_fax         1(251)4607359
_publ_contact_author_name        'Richard E. Sykora'
_publ_contact_author_phone       1(251)4607422
_publ_section_title
;
Emission Enhancement through Dual Donor Sensitization: Modulation of
Structural and Spectroscopic Properties in a Series of Europium
Tetracyanoplatinates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6425
_journal_page_last               6435
_journal_paper_doi               10.1021/ic900149v
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C42 H48 Eu2 N10 O15 Pt'
_chemical_formula_weight         1431.91
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.859(7)
_cell_angle_beta                 92.200(11)
_cell_angle_gamma                118.057(10)
_cell_formula_units_Z            2
_cell_length_a                   12.110(3)
_cell_length_b                   12.7273(11)
_cell_length_c                   18.7054(16)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    290(2)
_cell_measurement_theta_max      11.90
_cell_measurement_theta_min      8.04
_cell_volume                     2534.8(7)
_computing_cell_refinement       'CAD-4-PC Software'
_computing_data_collection
;
CAD-4-PC Software (Enraf-Nonius, 1993)
;
_computing_data_reduction        'XCAD4 (Harms & Wocadlo, 1996)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1998)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      290(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Enraf-Nonius CAD-4'
_diffrn_measurement_method       'θ/2θ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0305
_diffrn_reflns_av_sigmaI/netI    0.0434
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            9794
_diffrn_reflns_theta_full        25.37
_diffrn_reflns_theta_max         25.37
_diffrn_reflns_theta_min         2.05
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    5.270
_exptl_absorpt_correction_T_max  0.294
_exptl_absorpt_correction_T_min  0.250
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North et al., 1968)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.876
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             1388
_exptl_crystal_size_max          0.900
_exptl_crystal_size_mid          0.244
_exptl_crystal_size_min          0.232
_refine_diff_density_max         2.339
_refine_diff_density_min         -2.720
_refine_diff_density_rms         0.158
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     631
_refine_ls_number_reflns         9320
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0579
_refine_ls_R_factor_gt           0.0385
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0567P)²+10.8939P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1030
_refine_ls_wR_factor_ref         0.1123
_reflns_number_gt                7468
_reflns_number_total             9320
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic900149v_si_002_1.cif
_cod_data_source_block           3
_cod_database_code               4302607
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.88090(3) 0.74206(3) 0.398319(18) 0.02588(10) Uani 1 1 d . . .
Eu2 Eu 0.14472(3) 0.38864(3) 0.094301(19) 0.03178(10) Uani 1 1 d . . .
Pt1 Pt 0.51788(3) 0.04154(3) 0.260523(17) 0.03702(10) Uani 1 1 d . . .
O1 O 1.0257(5) 0.6733(5) 0.3597(3) 0.0442(13) Uani 1 1 d . . .
O2 O 0.9810(5) 0.7717(5) 0.2800(3) 0.0413(12) Uani 1 1 d . . .
O3 O 0.6813(5) 0.6928(5) 0.4470(3) 0.0468(14) Uani 1 1 d . . .
O4 O 0.8310(5) 0.8702(4) 0.4871(3) 0.0350(11) Uani 1 1 d . . .
O5 O 0.8195(6) 0.8693(5) 0.3339(3) 0.0474(14) Uani 1 1 d . . .
H5A H 0.8289 0.8619 0.2894 0.057 Uiso 1 1 d . . .
H5B H 0.7857 0.9085 0.3524 0.057 Uiso 1 1 d . . .
O6 O 1.0791(5) 0.9186(4) 0.4235(3) 0.0362(12) Uani 1 1 d . . .
H6A H 1.1370 0.9069 0.4066 0.043 Uiso 1 1 d . . .
H6B H 1.1027 0.9811 0.4515 0.043 Uiso 1 1 d . . .
O7 O -0.0067(5) 0.4736(5) 0.0900(3) 0.0437(13) Uani 1 1 d . . .
O8 O 0.0151(5) 0.3972(6) 0.1874(3) 0.0475(14) Uani 1 1 d . . .
O9 O 0.3484(6) 0.4212(7) 0.0624(4) 0.0643(19) Uani 1 1 d . . .
O10 O 0.1951(6) 0.2417(6) 0.0328(3) 0.0525(15) Uani 1 1 d . . .
O11 O 0.0939(6) 0.3836(6) -0.0318(3) 0.0489(14) Uani 1 1 d . . .
H11A H 0.0904 0.3215 -0.0532 0.059 Uiso 1 1 d . . .
H11B H 0.0527 0.4193 -0.0440 0.059 Uiso 1 1 d . . .
O12 O -0.0543(5) 0.2020(5) 0.0748(3) 0.0485(14) Uani 1 1 d . . .
H12B H -0.0557 0.1660 0.0350 0.058 Uiso 1 1 d . . .
H12C H -0.1120 0.1813 0.1038 0.058 Uiso 1 1 d . . .
O13 O 0.0480(9) 0.1927(9) 0.8676(4) 0.088(3) Uani 1 1 d . . .
O14 O 0.7921(7) 0.9001(7) 0.1902(4) 0.074(2) Uani 1 1 d . . .
O15 O 0.1392(8) 0.9825(9) 0.0423(5) 0.097(3) Uani 1 1 d . . .
N1 N 0.9481(6) 0.7091(6) 0.5232(3) 0.0374(14) Uani 1 1 d . . .
N2 N 0.7916(5) 0.5219(5) 0.4322(3) 0.0336(13) Uani 1 1 d . . .
N3 N 0.7206(6) 0.5781(6) 0.3062(3) 0.0355(14) Uani 1 1 d . . .
N4 N 0.2698(7) 0.6166(7) 0.0815(4) 0.056(2) Uani 1 1 d . . .
N5 N 0.2985(6) 0.5180(6) 0.2009(3) 0.0350(14) Uani 1 1 d . . .
N6 N 0.1752(6) 0.2771(6) 0.1968(3) 0.0385(15) Uani 1 1 d . . .
N7 N 0.7448(8) 0.1165(8) 0.1642(5) 0.068(2) Uani 1 1 d . . .
N8 N 0.3603(10) 0.0798(11) 0.1380(6) 0.087(3) Uani 1 1 d . . .
N9 N 0.2910(8) -0.0479(8) 0.3575(5) 0.073(3) Uani 1 1 d . . .
N10 N 0.6629(8) -0.0313(8) 0.3734(5) 0.060(2) Uani 1 1 d . . .
C1 C 1.0211(8) 0.8037(7) 0.5691(4) 0.0430(19) Uani 1 1 d . . .
H1 H 1.0442 0.8797 0.5546 0.052 Uiso 1 1 calc R . .
C2 C 1.0637(8) 0.7938(9) 0.6368(4) 0.051(2) Uani 1 1 d . . .
H2 H 1.1129 0.8612 0.6676 0.062 Uiso 1 1 calc R . .
C3 C 1.0308(9) 0.6812(9) 0.6572(5) 0.057(2) Uani 1 1 d . . .
H3 H 1.0578 0.6714 0.7024 0.068 Uiso 1 1 calc R . .
C4 C 0.9588(9) 0.5846(8) 0.6114(5) 0.051(2) Uani 1 1 d . . .
H4 H 0.9374 0.5084 0.6249 0.061 Uiso 1 1 calc R . .
C5 C 0.9168(7) 0.5989(7) 0.5443(4) 0.0359(16) Uani 1 1 d . . .
C6 C 0.8332(7) 0.4957(7) 0.4929(4) 0.0384(17) Uani 1 1 d . . .
C7 C 0.8002(9) 0.3791(8) 0.5080(5) 0.053(2) Uani 1 1 d . . .
H7 H 0.8295 0.3639 0.5508 0.064 Uiso 1 1 calc R . .
C8 C 0.7240(9) 0.2873(8) 0.4591(6) 0.058(3) Uani 1 1 d . . .
H8 H 0.7037 0.2089 0.4671 0.070 Uiso 1 1 calc R . .
C9 C 0.6785(8) 0.3126(7) 0.3984(5) 0.052(2) Uani 1 1 d . . .
H9 H 0.6247 0.2507 0.3653 0.062 Uiso 1 1 calc R . .
C10 C 0.7114(7) 0.4297(6) 0.3855(4) 0.0385(18) Uani 1 1 d . . .
C11 C 0.6650(6) 0.4605(7) 0.3197(4) 0.0371(17) Uani 1 1 d . . .
C12 C 0.5704(8) 0.3732(8) 0.2726(5) 0.052(2) Uani 1 1 d . . .
H12 H 0.5315 0.2936 0.2831 0.062 Uiso 1 1 calc R . .
C13 C 0.5359(9) 0.4064(10) 0.2112(5) 0.061(3) Uani 1 1 d . . .
H13 H 0.4734 0.3489 0.1794 0.073 Uiso 1 1 calc R . .
C14 C 0.5920(8) 0.5227(9) 0.1960(5) 0.054(2) Uani 1 1 d . . .
H14 H 0.5700 0.5455 0.1535 0.065 Uiso 1 1 calc R . .
C15 C 0.6830(8) 0.6067(8) 0.2455(4) 0.047(2) Uani 1 1 d . . .
H15 H 0.7196 0.6867 0.2359 0.056 Uiso 1 1 calc R . .
C16 C 1.0381(7) 0.7149(7) 0.3000(4) 0.0394(18) Uani 1 1 d . . .
C17 C 1.1307(9) 0.7054(10) 0.2498(6) 0.068(3) Uani 1 1 d . . .
H17A H 1.0940 0.6861 0.2014 0.102 Uiso 1 1 calc R . .
H17B H 1.1496 0.6438 0.2640 0.102 Uiso 1 1 calc R . .
H17C H 1.2065 0.7802 0.2526 0.102 Uiso 1 1 calc R . .
C18 C 0.7182(7) 0.7922(7) 0.4839(4) 0.0363(17) Uani 1 1 d . . .
C19 C 0.6210(8) 0.8128(9) 0.5202(5) 0.052(2) Uani 1 1 d . . .
H19A H 0.6499 0.8422 0.5692 0.078 Uiso 1 1 calc R . .
H19B H 0.5442 0.7390 0.5187 0.078 Uiso 1 1 calc R . .
H19C H 0.6067 0.8704 0.4959 0.078 Uiso 1 1 calc R . .
C20 C 0.2547(11) 0.6626(11) 0.0221(7) 0.085(4) Uani 1 1 d . . .
H20 H 0.1909 0.6131 -0.0121 0.102 Uiso 1 1 calc R . .
C21 C 0.3296(11) 0.7809(10) 0.0084(7) 0.074(3) Uani 1 1 d . . .
H21 H 0.3158 0.8106 -0.0335 0.089 Uiso 1 1 calc R . .
C22 C 0.4227(12) 0.8516(10) 0.0577(7) 0.079(3) Uani 1 1 d . . .
H22 H 0.4757 0.9309 0.0498 0.094 Uiso 1 1 calc R . .
C23 C 0.4386(11) 0.8051(9) 0.1201(6) 0.070(3) Uani 1 1 d . . .
H23 H 0.5026 0.8532 0.1545 0.084 Uiso 1 1 calc R . .
C24 C 0.3599(7) 0.6880(7) 0.1315(5) 0.0411(18) Uani 1 1 d . . .
C25 C 0.3683(8) 0.6375(7) 0.1982(4) 0.0415(18) Uani 1 1 d . . .
C26 C 0.4431(9) 0.7086(8) 0.2568(5) 0.056(2) Uani 1 1 d . . .
H26 H 0.4913 0.7903 0.2535 0.067 Uiso 1 1 calc R . .
C27 C 0.4471(10) 0.6601(9) 0.3199(6) 0.067(3) Uani 1 1 d . . .
H27 H 0.4966 0.7082 0.3597 0.081 Uiso 1 1 calc R . .
C28 C 0.3751(9) 0.5371(9) 0.3231(5) 0.056(2) Uani 1 1 d . . .
H28 H 0.3750 0.5017 0.3654 0.067 Uiso 1 1 calc R . .
C29 C 0.3029(7) 0.4675(7) 0.2614(4) 0.0401(18) Uani 1 1 d . . .
C30 C 0.2369(7) 0.3362(7) 0.2596(4) 0.0367(17) Uani 1 1 d . . .
C31 C 0.2402(10) 0.2754(9) 0.3170(5) 0.058(2) Uani 1 1 d . . .
H31 H 0.2830 0.3176 0.3599 0.070 Uiso 1 1 calc R . .
C32 C 0.1817(10) 0.1536(10) 0.3122(6) 0.068(3) Uani 1 1 d . . .
H32 H 0.1844 0.1127 0.3515 0.081 Uiso 1 1 calc R . .
C33 C 0.1182(9) 0.0919(8) 0.2481(5) 0.056(2) Uani 1 1 d . . .
H33 H 0.0766 0.0089 0.2430 0.067 Uiso 1 1 calc R . .
C34 C 0.1191(9) 0.1581(8) 0.1925(5) 0.053(2) Uani 1 1 d . . .
H34 H 0.0781 0.1175 0.1489 0.063 Uiso 1 1 calc R . .
C35 C -0.0409(7) 0.4397(7) 0.1512(4) 0.0382(17) Uani 1 1 d . . .
C36 C -0.1536(10) 0.4440(11) 0.1792(5) 0.064(3) Uani 1 1 d . . .
H36A H -0.1284 0.5217 0.2024 0.097 Uiso 1 1 calc R . .
H36B H -0.1902 0.3847 0.2130 0.097 Uiso 1 1 calc R . .
H36C H -0.2141 0.4285 0.1400 0.097 Uiso 1 1 calc R . .
C37 C 0.3077(9) 0.3181(11) 0.0325(5) 0.056(2) Uani 1 1 d . . .
C38 C 0.3960(12) 0.2848(14) -0.0046(8) 0.095(4) Uani 1 1 d . . .
H38A H 0.4003 0.2211 0.0186 0.143 Uiso 1 1 calc R . .
H38B H 0.4780 0.3528 -0.0022 0.143 Uiso 1 1 calc R . .
H38C H 0.3661 0.2591 -0.0539 0.143 Uiso 1 1 calc R . .
C39 C 0.6613(8) 0.0925(7) 0.1995(5) 0.0450(19) Uani 1 1 d . . .
C40 C 0.4182(9) 0.0692(9) 0.1836(6) 0.060(2) Uani 1 1 d . . .
C41 C 0.3752(8) -0.0134(8) 0.3215(5) 0.052(2) Uani 1 1 d . . .
C42 C 0.6116(8) 0.0015(8) 0.3349(5) 0.045(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O1 78.31(18) . . ?
O6 Eu1 O3 128.84(17) . . ?
O1 Eu1 O3 147.52(19) . . ?
O6 Eu1 O5 85.4(2) . . ?
O1 Eu1 O5 125.74(19) . . ?
O3 Eu1 O5 79.1(2) . . ?
O6 Eu1 O2 76.37(17) . . ?
O1 Eu1 O2 52.86(19) . . ?
O3 Eu1 O2 140.71(19) . . ?
O5 Eu1 O2 73.10(18) . . ?
O6 Eu1 O4 76.55(16) . . ?
O1 Eu1 O4 148.80(18) . . ?
O3 Eu1 O4 52.31(17) . . ?
O5 Eu1 O4 70.17(18) . . ?
O2 Eu1 O4 135.52(18) . . ?
O6 Eu1 N1 78.34(19) . . ?
O1 Eu1 N1 83.1(2) . . ?
O3 Eu1 N1 85.7(2) . . ?
O5 Eu1 N1 143.16(19) . . ?
O2 Eu1 N1 132.58(19) . . ?
O4 Eu1 N1 73.95(18) . . ?
O6 Eu1 N3 149.07(19) . . ?
O1 Eu1 N3 85.42(19) . . ?
O3 Eu1 N3 76.72(19) . . ?
O5 Eu1 N3 83.0(2) . . ?
O2 Eu1 N3 72.83(19) . . ?
O4 Eu1 N3 125.19(17) . . ?
N1 Eu1 N3 125.9(2) . . ?
O6 Eu1 N2 133.73(19) . . ?
O1 Eu1 N2 73.25(19) . . ?
O3 Eu1 N2 74.50(19) . . ?
O5 Eu1 N2 140.8(2) . . ?
O2 Eu1 N2 111.61(18) . . ?
O4 Eu1 N2 112.66(18) . . ?
N1 Eu1 N2 62.8(2) . . ?
N3 Eu1 N2 63.2(2) . . ?
O6 Eu1 C16 75.86(19) . . ?
O1 Eu1 C16 26.1(2) . . ?
O3 Eu1 C16 154.6(2) . . ?
O5 Eu1 C16 99.8(2) . . ?
O2 Eu1 C16 26.8(2) . . ?
O4 Eu1 C16 151.29(19) . . ?
N1 Eu1 C16 107.8(2) . . ?
N3 Eu1 C16 78.0(2) . . ?
N2 Eu1 C16 92.3(2) . . ?
O6 Eu1 C18 102.51(19) . . ?
O1 Eu1 C18 162.1(2) . . ?
O3 Eu1 C18 26.38(19) . . ?
O5 Eu1 C18 71.9(2) . . ?
O2 Eu1 C18 144.9(2) . . ?
O4 Eu1 C18 25.97(19) . . ?
N1 Eu1 C18 79.6(2) . . ?
N3 Eu1 C18 101.0(2) . . ?
N2 Eu1 C18 94.6(2) . . ?
C16 Eu1 C18 171.7(2) . . ?
O6 Eu1 H6A 16.6 . . ?
O1 Eu1 H6A 61.9 . . ?
O3 Eu1 H6A 144.9 . . ?
O5 Eu1 H6A 93.9 . . ?
O2 Eu1 H6A 65.4 . . ?
O4 Eu1 H6A 92.9 . . ?
N1 Eu1 H6A 79.7 . . ?
N3 Eu1 H6A 137.0 . . ?
N2 Eu1 H6A 124.1 . . ?
C16 Eu1 H6A 60.3 . . ?
C18 Eu1 H6A 118.8 . . ?
O11 Eu2 O9 86.9(2) . . ?
O11 Eu2 O8 123.91(19) . . ?
O9 Eu2 O8 147.6(2) . . ?
O11 Eu2 O12 78.0(2) . . ?
O9 Eu2 O12 127.1(2) . . ?
O8 Eu2 O12 74.3(2) . . ?
O11 Eu2 O10 73.0(2) . . ?
O9 Eu2 O10 53.2(2) . . ?
O8 Eu2 O10 139.0(2) . . ?
O12 Eu2 O10 73.9(2) . . ?
O11 Eu2 O7 76.04(18) . . ?
O9 Eu2 O7 144.0(2) . . ?
O8 Eu2 O7 52.00(18) . . ?
O12 Eu2 O7 80.4(2) . . ?
O10 Eu2 O7 143.04(19) . . ?
O11 Eu2 N6 146.7(2) . . ?
O9 Eu2 N6 85.4(2) . . ?
O8 Eu2 N6 73.6(2) . . ?
O12 Eu2 N6 81.1(2) . . ?
O10 Eu2 N6 76.5(2) . . ?
O7 Eu2 N6 125.43(19) . . ?
O11 Eu2 N5 143.8(2) . . ?
O9 Eu2 N5 74.3(2) . . ?
O8 Eu2 N5 74.3(2) . . ?
O12 Eu2 N5 137.82(19) . . ?
O10 Eu2 N5 115.61(19) . . ?
O7 Eu2 N5 101.29(19) . . ?
N6 Eu2 N5 63.4(2) . . ?
O11 Eu2 N4 82.6(2) . . ?
O9 Eu2 N4 75.4(3) . . ?
O8 Eu2 N4 97.1(2) . . ?
O12 Eu2 N4 148.7(2) . . ?
O10 Eu2 N4 123.2(2) . . ?
O7 Eu2 N4 71.1(2) . . ?
N6 Eu2 N4 126.1(2) . . ?
N5 Eu2 N4 63.0(2) . . ?
O11 Eu2 C37 77.9(2) . . ?
O9 Eu2 C37 26.7(3) . . ?
O8 Eu2 C37 154.4(2) . . ?
O12 Eu2 C37 100.5(3) . . ?
O10 Eu2 C37 26.6(3) . . ?
O7 Eu2 C37 153.1(2) . . ?
N6 Eu2 C37 80.9(2) . . ?
N5 Eu2 C37 95.9(2) . . ?
N4 Eu2 C37 99.1(3) . . ?
O11 Eu2 C35 99.6(2) . . ?
O9 Eu2 C35 158.8(3) . . ?
O8 Eu2 C35 25.9(2) . . ?
O12 Eu2 C35 74.1(2) . . ?
O10 Eu2 C35 148.0(2) . . ?
O7 Eu2 C35 26.3(2) . . ?
N6 Eu2 C35 99.2(2) . . ?
N5 Eu2 C35 89.1(2) . . ?
N4 Eu2 C35 85.3(3) . . ?
C37 Eu2 C35 174.5(3) . . ?
O11 Eu2 H11A 16.6 . . ?
O9 Eu2 H11A 80.9 . . ?
O8 Eu2 H11A 131.5 . . ?
O12 Eu2 H11A 70.4 . . ?
O10 Eu2 H11A 57.1 . . ?
O7 Eu2 H11A 89.6 . . ?
N6 Eu2 H11A 130.3 . . ?
N5 Eu2 H11A 150.7 . . ?
N4 Eu2 H11A 96.0 . . ?
C37 Eu2 H11A 66.0 . . ?
C35 Eu2 H11A 110.5 . . ?
C41 Pt1 C39 178.5(4) . . ?
C41 Pt1 C40 90.4(4) . . ?
C39 Pt1 C40 90.5(4) . . ?
C41 Pt1 C42 89.1(4) . . ?
C39 Pt1 C42 89.9(3) . . ?
C40 Pt1 C42 175.9(4) . . ?
C16 O1 Eu1 95.3(5) . . ?
C16 O2 Eu1 89.7(5) . . ?
C18 O3 Eu1 96.3(4) . . ?
C18 O4 Eu1 90.8(4) . . ?
Eu1 O5 H5A 109.5 . . ?
Eu1 O5 H5B 124.7 . . ?
H5A O5 H5B 125.4 . . ?
Eu1 O6 H6A 109.5 . . ?
Eu1 O6 H6B 132.9 . . ?
H6A O6 H6B 116.3 . . ?
C35 O7 Eu2 91.0(4) . . ?
C35 O8 Eu2 96.4(4) . . ?
C37 O9 Eu2 93.9(5) . . ?
C37 O10 Eu2 91.1(6) . . ?
Eu2 O11 H11A 109.6 . . ?
Eu2 O11 H11B 117.3 . . ?
H11A O11 H11B 126.6 . . ?
Eu2 O12 H12B 109.5 . . ?
Eu2 O12 H12C 122.8 . . ?
H12B O12 H12C 127.6 . . ?
C1 N1 C5 118.0(7) . . ?
C1 N1 Eu1 119.7(5) . . ?
C5 N1 Eu1 122.3(5) . . ?
C6 N2 C10 117.8(7) . . ?
C6 N2 Eu1 121.1(5) . . ?
C10 N2 Eu1 120.7(5) . . ?
C15 N3 C11 117.6(7) . . ?
C15 N3 Eu1 120.7(5) . . ?
C11 N3 Eu1 121.5(5) . . ?
C20 N4 C24 118.7(8) . . ?
C20 N4 Eu2 120.5(7) . . ?
C24 N4 Eu2 120.4(5) . . ?
C29 N5 C25 119.7(7) . . ?
C29 N5 Eu2 119.5(5) . . ?
C25 N5 Eu2 120.7(5) . . ?
C34 N6 C30 118.0(7) . . ?
C34 N6 Eu2 120.8(5) . . ?
C30 N6 Eu2 120.9(5) . . ?
N1 C1 C2 123.3(8) . . ?
N1 C1 H1 118.3 . . ?
C2 C1 H1 118.3 . . ?
C3 C2 C1 117.8(8) . . ?
C3 C2 H2 121.1 . . ?
C1 C2 H2 121.1 . . ?
C4 C3 C2 119.8(8) . . ?
C4 C3 H3 120.1 . . ?
C2 C3 H3 120.1 . . ?
C3 C4 C5 120.3(8) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
N1 C5 C4 120.8(8) . . ?
N1 C5 C6 116.7(7) . . ?
C4 C5 C6 122.6(7) . . ?
N2 C6 C7 122.5(8) . . ?
N2 C6 C5 116.4(6) . . ?
C7 C6 C5 121.1(8) . . ?
C8 C7 C6 119.2(9) . . ?
C8 C7 H7 120.4 . . ?
C6 C7 H7 120.4 . . ?
C9 C8 C7 118.8(8) . . ?
C9 C8 H8 120.6 . . ?
C7 C8 H8 120.6 . . ?
C8 C9 C10 120.6(8) . . ?
C8 C9 H9 119.7 . . ?
C10 C9 H9 119.7 . . ?
N2 C10 C9 121.0(8) . . ?
N2 C10 C11 116.9(7) . . ?
C9 C10 C11 122.0(7) . . ?
N3 C11 C12 121.3(8) . . ?
N3 C11 C10 116.9(6) . . ?
C12 C11 C10 121.7(8) . . ?
C13 C12 C11 119.0(9) . . ?
C13 C12 H12 120.5 . . ?
C11 C12 H12 120.5 . . ?
C14 C13 C12 120.6(8) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C13 C14 C15 118.2(9) . . ?
C13 C14 H14 120.9 . . ?
C15 C14 H14 120.9 . . ?
N3 C15 C14 123.2(9) . . ?
N3 C15 H15 118.4 . . ?
C14 C15 H15 118.4 . . ?
O1 C16 O2 122.1(7) . . ?
O1 C16 C17 119.9(8) . . ?
O2 C16 C17 117.8(8) . . ?
O1 C16 Eu1 58.6(4) . . ?
O2 C16 Eu1 63.5(4) . . ?
C17 C16 Eu1 176.3(6) . . ?
C16 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
C16 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
O4 C18 O3 120.4(7) . . ?
O4 C18 C19 121.9(7) . . ?
O3 C18 C19 117.6(7) . . ?
O4 C18 Eu1 63.2(4) . . ?
O3 C18 Eu1 57.3(4) . . ?
C19 C18 Eu1 172.5(6) . . ?
C18 C19 H19A 109.5 . . ?
C18 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C18 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
N4 C20 C21 123.1(11) . . ?
N4 C20 H20 118.5 . . ?
C21 C20 H20 118.5 . . ?
C22 C21 C20 118.1(11) . . ?
C22 C21 H21 120.9 . . ?
C20 C21 H21 120.9 . . ?
C21 C22 C23 119.3(10) . . ?
C21 C22 H22 120.3 . . ?
C23 C22 H22 120.3 . . ?
C24 C23 C22 120.1(11) . . ?
C24 C23 H23 120.0 . . ?
C22 C23 H23 120.0 . . ?
N4 C24 C23 120.6(9) . . ?
N4 C24 C25 117.4(7) . . ?
C23 C24 C25 121.9(9) . . ?
N5 C25 C26 121.1(8) . . ?
N5 C25 C24 117.6(7) . . ?
C26 C25 C24 121.3(8) . . ?
C27 C26 C25 120.6(9) . . ?
C27 C26 H26 119.7 . . ?
C25 C26 H26 119.7 . . ?
C26 C27 C28 118.5(8) . . ?
C26 C27 H27 120.8 . . ?
C28 C27 H27 120.8 . . ?
C27 C28 C29 119.0(9) . . ?
C27 C28 H28 120.5 . . ?
C29 C28 H28 120.5 . . ?
N5 C29 C28 121.1(8) . . ?
N5 C29 C30 117.9(7) . . ?
C28 C29 C30 120.9(8) . . ?
N6 C30 C31 120.7(8) . . ?
N6 C30 C29 116.5(7) . . ?
C31 C30 C29 122.7(8) . . ?
C30 C31 C32 120.9(9) . . ?
C30 C31 H31 119.6 . . ?
C32 C31 H31 119.6 . . ?
C31 C32 C33 119.0(9) . . ?
C31 C32 H32 120.5 . . ?
C33 C32 H32 120.5 . . ?
C34 C33 C32 117.3(8) . . ?
C34 C33 H33 121.4 . . ?
C32 C33 H33 121.4 . . ?
N6 C34 C33 124.2(9) . . ?
N6 C34 H34 117.9 . . ?
C33 C34 H34 117.9 . . ?
O8 C35 O7 120.1(7) . . ?
O8 C35 C36 119.7(7) . . ?
O7 C35 C36 120.1(7) . . ?
O8 C35 Eu2 57.7(4) . . ?
O7 C35 Eu2 62.8(4) . . ?
C36 C35 Eu2 170.2(7) . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
O10 C37 O9 121.6(8) . . ?
O10 C37 C38 118.8(11) . . ?
O9 C37 C38 119.6(10) . . ?
O10 C37 Eu2 62.3(5) . . ?
O9 C37 Eu2 59.4(4) . . ?
C38 C37 Eu2 176.5(8) . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N7 C39 Pt1 176.3(8) . . ?
N8 C40 Pt1 176.5(10) . . ?
N9 C41 Pt1 178.6(9) . . ?
N10 C42 Pt1 173.3(8) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.401(5) . ?
Eu1 O1 2.417(5) . ?
Eu1 O3 2.421(5) . ?
Eu1 O5 2.426(5) . ?
Eu1 O2 2.524(5) . ?
Eu1 O4 2.553(5) . ?
Eu1 N1 2.564(6) . ?
Eu1 N3 2.582(6) . ?
Eu1 N2 2.608(6) . ?
Eu1 C16 2.820(8) . ?
Eu1 C18 2.860(7) . ?
Eu1 H6A 2.8024 . ?
Eu2 O11 2.404(6) . ?
Eu2 O9 2.406(6) . ?
Eu2 O8 2.421(5) . ?
Eu2 O12 2.459(6) . ?
Eu2 O10 2.470(6) . ?
Eu2 O7 2.530(5) . ?
Eu2 N6 2.557(6) . ?
Eu2 N5 2.580(6) . ?
Eu2 N4 2.595(7) . ?
Eu2 C37 2.788(9) . ?
Eu2 C35 2.845(7) . ?
Eu2 H11A 2.8053 . ?
Pt1 C41 1.967(9) . ?
Pt1 C39 1.976(8) . ?
Pt1 C40 1.992(11) . ?
Pt1 C42 1.993(10) . ?
O1 C16 1.245(10) . ?
O2 C16 1.271(10) . ?
O3 C18 1.278(9) . ?
O4 C18 1.252(9) . ?
O5 H5A 0.8500 . ?
O5 H5B 0.8500 . ?
O6 H6A 0.8499 . ?
O6 H6B 0.8502 . ?
O7 C35 1.259(9) . ?
O8 C35 1.249(9) . ?
O9 C37 1.255(12) . ?
O10 C37 1.249(12) . ?
O11 H11A 0.8500 . ?
O11 H11B 0.8500 . ?
O12 H12B 0.8500 . ?
O12 H12C 0.8500 . ?
N1 C1 1.343(10) . ?
N1 C5 1.353(10) . ?
N2 C6 1.343(10) . ?
N2 C10 1.359(10) . ?
N3 C15 1.337(11) . ?
N3 C11 1.363(10) . ?
N4 C20 1.328(13) . ?
N4 C24 1.340(11) . ?
N5 C29 1.340(10) . ?
N5 C25 1.353(10) . ?
N6 C34 1.334(11) . ?
N6 C30 1.348(10) . ?
N7 C39 1.154(11) . ?
N8 C40 1.137(13) . ?
N9 C41 1.161(11) . ?
N10 C42 1.148(11) . ?
C1 C2 1.383(11) . ?
C1 H1 0.9300 . ?
C2 C3 1.373(14) . ?
C2 H2 0.9300 . ?
C3 C4 1.355(13) . ?
C3 H3 0.9300 . ?
C4 C5 1.389(11) . ?
C4 H4 0.9300 . ?
C5 C6 1.491(11) . ?
C6 C7 1.391(11) . ?
C7 C8 1.367(14) . ?
C7 H7 0.9300 . ?
C8 C9 1.361(14) . ?
C8 H8 0.9300 . ?
C9 C10 1.387(11) . ?
C9 H9 0.9300 . ?
C10 C11 1.479(12) . ?
C11 C12 1.397(11) . ?
C12 C13 1.359(14) . ?
C12 H12 0.9300 . ?
C13 C14 1.359(14) . ?
C13 H13 0.9300 . ?
C14 C15 1.390(12) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C16 C17 1.533(11) . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 C19 1.499(10) . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 C21 1.388(15) . ?
C20 H20 0.9300 . ?
C21 C22 1.347(16) . ?
C21 H21 0.9300 . ?
C22 C23 1.381(16) . ?
C22 H22 0.9300 . ?
C23 C24 1.374(12) . ?
C23 H23 0.9300 . ?
C24 C25 1.453(12) . ?
C25 C26 1.377(12) . ?
C26 C27 1.368(14) . ?
C26 H26 0.9300 . ?
C27 C28 1.395(14) . ?
C27 H27 0.9300 . ?
C28 C29 1.405(11) . ?
C28 H28 0.9300 . ?
C29 C30 1.473(11) . ?
C30 C31 1.364(12) . ?
C31 C32 1.364(14) . ?
C31 H31 0.9300 . ?
C32 C33 1.383(14) . ?
C32 H32 0.9300 . ?
C33 C34 1.367(12) . ?
C33 H33 0.9300 . ?
C34 H34 0.9300 . ?
C35 C36 1.504(11) . ?
C36 H36A 0.9600 . ?
C36 H36B 0.9600 . ?
C36 H36C 0.9600 . ?
C37 C38 1.503(13) . ?
C38 H38A 0.9600 . ?
C38 H38B 0.9600 . ?
C38 H38C 0.9600 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O5 H5A O14 0.85 2.03 2.766(9) 144.7 .
O5 H5B N10 0.85 2.01 2.832(10) 162.2 1_565
O6 H6A N9 0.85 1.96 2.749(9) 154.6 1_665
O6 H6B O4 0.85 1.96 2.804(7) 175.8 2_776
O11 H11A O13 0.85 2.01 2.820(10) 157.9 1_554
O11 H11B O7 0.85 1.92 2.742(8) 161.0 2_565
O12 H12B O15 0.85 2.12 2.900(10) 152.1 2_565
O12 H12C N7 0.85 1.97 2.811(10) 173.6 1_455
