#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:30:56 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179064 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/26/4302614.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302614
loop_
_publ_author_name
'Liang Zhao'
'Thomas C. W. Mak'
_publ_section_title
;
Assembly of Silver(I) Two- and Three-Dimensional Coordination Networks with
Complementary Tridentate Heteroaryl Ethynide Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6480
_journal_page_last               6489
_journal_paper_doi               10.1021/ic900346p
_journal_volume                  48
_journal_year                    2009
_chemical_formula_sum            'C25 H3 Ag10 F24 N O26'
_chemical_formula_weight         2267.98
_chemical_name_common            ([2,6-(AgCC)2-Py])(8AgCF3CO2)(10H2O)
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.322(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.4365(15)
_cell_length_b                   16.7553(13)
_cell_length_c                   20.2441(16)
_cell_measurement_temperature    293(2)
_cell_volume                     5698.6(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0325
_diffrn_reflns_av_sigmaI/netI    0.0364
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            19334
_diffrn_reflns_theta_full        28.43
_diffrn_reflns_theta_max         28.43
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    3.509
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.675453
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    2.644
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Plate
_exptl_crystal_F_000             4216
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.110
_refine_diff_density_min         -1.202
_refine_diff_density_rms         0.124
_refine_ls_extinction_coef       0.000017(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     519
_refine_ls_number_reflns         7125
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0368
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0454P)²+22.4394P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0887
_refine_ls_wR_factor_ref         0.1076
_reflns_number_gt                4895
_reflns_number_total             7125
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic900346p_si_002_1.cif
_cod_data_source_block           Complex1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5698.5(8)
_cod_database_code               4302614
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.01880(3) 0.10457(2) 0.51264(3) 0.04990(13) Uani 1 1 d . . .
Ag2 Ag 0.17649(3) 0.14670(3) 0.53683(2) 0.05395(14) Uani 1 1 d . . .
Ag3 Ag 0.04207(3) 0.26572(3) 0.49238(3) 0.05693(14) Uani 1 1 d . . .
Ag4 Ag 0.13893(3) 0.25378(3) 0.40595(3) 0.05377(14) Uani 1 1 d . . .
Ag5 Ag 0.0000 0.2650(3) 0.2500 0.0510(15) Uani 0.80 2 d SP . 1
Ag5' Ag 0.0244(18) 0.2589(11) 0.247(2) 0.046(4) Uani 0.10 1 d P . 2
Ag6 Ag 0.0000 0.5000 0.5000 0.1338(6) Uani 1 2 d S . .
N1 N 0.0000 0.1308(3) 0.2500 0.0372(12) Uani 1 2 d S . .
C1 C 0.0671(3) 0.1623(3) 0.4375(3) 0.0431(12) Uani 1 1 d . . .
C2 C 0.0488(3) 0.1344(3) 0.3780(3) 0.0402(11) Uani 1 1 d . . .
C3 C 0.0231(3) 0.0892(3) 0.3115(3) 0.0405(11) Uani 1 1 d . . .
C4 C 0.0249(4) 0.0066(3) 0.3141(3) 0.0599(16) Uani 1 1 d . . .
H4A H 0.0425 -0.0202 0.3582 0.072 Uiso 1 1 calc R . .
C5 C 0.0000 -0.0347(5) 0.2500 0.077(3) Uani 1 2 d S . .
H5A H 0.0000 -0.0902 0.2500 0.092 Uiso 1 2 calc SR . .
O1 O 0.2098(2) 0.3495(3) 0.5014(2) 0.0591(11) Uani 1 1 d . . .
O2 O 0.1112(3) 0.3841(2) 0.5316(3) 0.0658(13) Uani 1 1 d . . .
C6 C 0.1779(4) 0.3905(4) 0.5326(3) 0.0528(14) Uani 1 1 d . . .
C7 C 0.2315(17) 0.4537(18) 0.5815(15) 0.102(15) Uani 0.529(17) 1 d PD . 1
F11 F 0.1915(15) 0.5035(15) 0.6058(13) 0.152(12) Uani 0.529(17) 1 d PD . 1
F12 F 0.2885(10) 0.4222(14) 0.6395(10) 0.118(6) Uani 0.529(17) 1 d PD . 1
F13 F 0.2655(17) 0.4977(15) 0.5479(16) 0.174(15) Uani 0.529(17) 1 d PD . 1
C7' C 0.2265(12) 0.4617(14) 0.5767(14) 0.074(12) Uani 0.471(17) 1 d PD . 2
F11' F 0.248(3) 0.449(3) 0.6413(14) 0.27(3) Uani 0.471(17) 1 d PD . 2
F12' F 0.1897(19) 0.5246(17) 0.567(3) 0.23(2) Uani 0.471(17) 1 d PD . 2
F13' F 0.2878(12) 0.4775(16) 0.570(2) 0.141(13) Uani 0.471(17) 1 d PD . 2
O3 O -0.0476(3) 0.1476(3) 0.5761(3) 0.0837(17) Uani 1 1 d . . .
O4 O -0.0336(3) 0.2767(3) 0.5594(3) 0.0767(15) Uani 1 1 d . . .
C8 C -0.0599(5) 0.2182(4) 0.5798(4) 0.0698(19) Uani 1 1 d . . .
C9 C -0.1142(6) 0.2382(5) 0.6186(6) 0.124(5) Uani 1 1 d D . .
F21 F -0.104(2) 0.192(2) 0.6717(19) 0.194(16) Uani 0.529(17) 1 d PD . 1
F22 F -0.1870(12) 0.234(3) 0.5753(14) 0.26(2) Uani 0.529(17) 1 d PD . 1
F23 F -0.104(3) 0.3085(15) 0.646(2) 0.245(19) Uani 0.529(17) 1 d PD . 1
F21' F -0.150(2) 0.3041(19) 0.595(2) 0.21(2) Uani 0.471(17) 1 d PD . 2
F22' F -0.0693(17) 0.245(3) 0.6859(13) 0.25(2) Uani 0.471(17) 1 d PD . 2
F23' F -0.1666(19) 0.1838(14) 0.609(2) 0.163(15) Uani 0.471(17) 1 d PD . 2
O5 O 0.0832(2) -0.0124(2) 0.5671(3) 0.0635(12) Uani 1 1 d . . .
O6 O 0.2090(2) 0.0242(3) 0.5980(3) 0.0622(11) Uani 1 1 d . . .
C10 C 0.1552(3) -0.0219(3) 0.5964(4) 0.0527(14) Uani 1 1 d . . .
C11 C 0.1835(4) -0.1000(4) 0.6400(5) 0.081(3) Uani 1 1 d D . .
F31 F 0.1432(11) -0.1253(14) 0.6704(17) 0.178(14) Uani 0.529(17) 1 d PD . 1
F32 F 0.2526(10) -0.0974(15) 0.6875(12) 0.124(9) Uani 0.529(17) 1 d PD . 1
F33 F 0.187(2) -0.1555(12) 0.5992(10) 0.196(12) Uani 0.529(17) 1 d PD . 1
F31' F 0.1401(13) -0.1593(9) 0.6059(15) 0.183(16) Uani 0.471(17) 1 d PD . 2
F32' F 0.2569(12) -0.1172(16) 0.657(2) 0.130(12) Uani 0.471(17) 1 d PD . 2
F33' F 0.175(2) -0.0898(16) 0.7009(12) 0.196(15) Uani 0.471(17) 1 d PD . 2
O7 O 0.1402(3) 0.2965(3) 0.2473(2) 0.0722(13) Uani 1 1 d . . .
O8 O 0.2267(2) 0.2915(3) 0.3615(2) 0.0555(10) Uani 1 1 d . . .
C12 C 0.2064(4) 0.3002(4) 0.2955(3) 0.0508(13) Uani 1 1 d . . .
C13 C 0.2750(4) 0.3154(5) 0.2721(4) 0.078(2) Uani 1 1 d D . .
F41 F 0.3398(7) 0.3349(10) 0.3228(6) 0.091(5) Uani 0.529(17) 1 d PD . 1
F42 F 0.2882(14) 0.2541(12) 0.2420(17) 0.218(17) Uani 0.529(17) 1 d PD . 1
F43 F 0.2571(10) 0.3730(17) 0.2260(13) 0.228(18) Uani 0.529(17) 1 d PD . 1
F41' F 0.2582(9) 0.2977(11) 0.2086(6) 0.081(5) Uani 0.471(17) 1 d PD . 2
F42' F 0.2976(19) 0.3853(12) 0.2793(18) 0.23(2) Uani 0.471(17) 1 d PD . 2
F43' F 0.3349(12) 0.274(2) 0.3074(11) 0.24(2) Uani 0.471(17) 1 d PD . 2
O1W O 0.0372(3) 0.3672(3) 0.3406(3) 0.0743(13) Uani 1 1 d . . .
O2W O -0.0354(5) 0.4365(4) 0.5800(4) 0.118(2) Uani 1 1 d . . .
O3W O -0.0796(3) 0.3424(4) 0.4021(3) 0.0875(16) Uani 1 1 d . . .
O4W O 0.1260(3) 0.4974(3) 0.3497(4) 0.0914(18) Uani 1 1 d . . .
O5W O 0.0903(8) 0.4725(14) 0.7036(8) 0.340(12) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Ag1 C1 135.11(19) . . ?
O3 Ag1 O5 107.11(18) . . ?
C1 Ag1 O5 114.37(18) . . ?
O3 Ag1 O5 97.4(2) . 5_556 ?
C1 Ag1 O5 103.46(18) . 5_556 ?
O5 Ag1 O5 83.36(15) . 5_556 ?
O3 Ag1 Ag3 85.73(12) . . ?
C1 Ag1 Ag3 50.45(14) . . ?
O5 Ag1 Ag3 143.83(10) . . ?
O5 Ag1 Ag3 129.39(10) 5_556 . ?
O3 Ag1 Ag2 126.03(16) . . ?
C1 Ag1 Ag2 49.57(14) . . ?
O5 Ag1 Ag2 80.83(10) . . ?
O5 Ag1 Ag2 136.40(11) 5_556 . ?
Ag3 Ag1 Ag2 64.858(17) . . ?
C1 Ag2 O8 146.33(18) . 7_556 ?
C1 Ag2 O6 121.70(17) . . ?
O8 Ag2 O6 89.22(16) 7_556 . ?
C1 Ag2 O1 106.38(17) . 7_556 ?
O8 Ag2 O1 80.14(14) 7_556 7_556 ?
O6 Ag2 O1 96.93(15) . 7_556 ?
C1 Ag2 Ag1 51.84(13) . . ?
O8 Ag2 Ag1 128.30(10) 7_556 . ?
O6 Ag2 Ag1 83.91(9) . . ?
O1 Ag2 Ag1 151.54(10) 7_556 . ?
C1 Ag2 Ag3 46.95(14) . . ?
O8 Ag2 Ag3 101.85(12) 7_556 . ?
O6 Ag2 Ag3 137.45(10) . . ?
O1 Ag2 Ag3 125.30(11) 7_556 . ?
Ag1 Ag2 Ag3 56.918(16) . . ?
C1 Ag2 Ag4 48.54(13) . . ?
O8 Ag2 Ag4 108.88(10) 7_556 . ?
O6 Ag2 Ag4 153.62(12) . . ?
O1 Ag2 Ag4 68.66(11) 7_556 . ?
Ag1 Ag2 Ag4 98.486(18) . . ?
Ag3 Ag2 Ag4 58.958(16) . . ?
C1 Ag3 O2 130.23(16) . . ?
C1 Ag3 O4 131.12(17) . . ?
O2 Ag3 O4 96.31(16) . . ?
C1 Ag3 O3W 109.6(2) . . ?
O2 Ag3 O3W 90.62(18) . . ?
O4 Ag3 O3W 79.48(19) . . ?
C1 Ag3 Ag1 52.48(13) . . ?
O2 Ag3 Ag1 151.08(13) . . ?
O4 Ag3 Ag1 79.93(11) . . ?
O3W Ag3 Ag1 116.42(14) . . ?
C1 Ag3 Ag4 49.54(13) . . ?
O2 Ag3 Ag4 83.13(11) . . ?
O4 Ag3 Ag4 179.27(11) . . ?
O3W Ag3 Ag4 100.04(13) . . ?
Ag1 Ag3 Ag4 100.786(18) . . ?
C1 Ag3 Ag2 46.70(14) . . ?
O2 Ag3 Ag2 101.31(11) . . ?
O4 Ag3 Ag2 119.77(13) . . ?
O3W Ag3 Ag2 155.44(13) . . ?
Ag1 Ag3 Ag2 58.224(15) . . ?
Ag4 Ag3 Ag2 60.845(16) . . ?
O8 Ag4 C1 154.08(18) . . ?
O8 Ag4 O1 83.83(14) . . ?
C1 Ag4 O1 113.83(17) . . ?
O8 Ag4 C2 130.82(16) . . ?
C1 Ag4 C2 28.57(17) . . ?
O1 Ag4 C2 142.40(16) . . ?
O8 Ag4 Ag3 157.47(11) . . ?
C1 Ag4 Ag3 47.41(14) . . ?
O1 Ag4 Ag3 75.25(9) . . ?
C2 Ag4 Ag3 71.63(12) . . ?
O8 Ag4 Ag5' 82.5(6) . . ?
C1 Ag4 Ag5' 94.8(6) . . ?
O1 Ag4 Ag5' 137.2(4) . . ?
C2 Ag4 Ag5' 71.1(5) . . ?
Ag3 Ag4 Ag5' 107.2(5) . . ?
O8 Ag4 Ag2 125.05(12) . . ?
C1 Ag4 Ag2 46.23(14) . . ?
O1 Ag4 Ag2 80.90(11) . . ?
C2 Ag4 Ag2 67.51(12) . . ?
Ag3 Ag4 Ag2 60.197(16) . . ?
Ag5' Ag4 Ag2 138.6(5) . . ?
O8 Ag4 Ag5 90.24(11) . . ?
C1 Ag4 Ag5 89.71(15) . . ?
O1 Ag4 Ag5 134.86(14) . . ?
C2 Ag4 Ag5 68.42(14) . . ?
Ag3 Ag4 Ag5 98.52(2) . . ?
Ag5' Ag4 Ag5 8.8(5) . . ?
Ag2 Ag4 Ag5 135.25(7) . . ?
O8 Ag4 Ag5' 98.3(5) . 2 ?
C1 Ag4 Ag5' 82.6(3) . 2 ?
O1 Ag4 Ag5' 135.1(4) . 2 ?
C2 Ag4 Ag5' 63.2(3) . 2 ?
Ag3 Ag4 Ag5' 90.9(5) . 2 ?
Ag5' Ag4 Ag5' 16.4(10) . 2 ?
Ag2 Ag4 Ag5' 128.7(3) . 2 ?
Ag5 Ag4 Ag5' 8.1(5) . 2 ?
N1 Ag5 O1W 135.68(15) . . ?
N1 Ag5 O1W 135.68(15) . 2 ?
O1W Ag5 O1W 88.6(3) . 2 ?
N1 Ag5 Ag4 86.57(8) . 2 ?
O1W Ag5 Ag4 132.02(18) . 2 ?
O1W Ag5 Ag4 54.29(13) 2 2 ?
N1 Ag5 Ag4 86.57(8) . . ?
O1W Ag5 Ag4 54.29(13) . . ?
O1W Ag5 Ag4 132.02(18) 2 . ?
Ag4 Ag5 Ag4 173.13(16) 2 . ?
Ag5' Ag5' N1 77.5(6) 2 . ?
Ag5' Ag5' O7 163(2) 2 . ?
N1 Ag5' O7 118.8(7) . . ?
Ag5' Ag5' O1W 85(3) 2 2 ?
N1 Ag5' O1W 134.3(17) . 2 ?
O7 Ag5' O1W 87.0(11) . 2 ?
Ag5' Ag5' O1W 74(3) 2 . ?
N1 Ag5' O1W 129.2(16) . . ?
O7 Ag5' O1W 90.2(11) . . ?
O1W Ag5' O1W 83.4(5) 2 . ?
Ag5' Ag5' Ag4 99(5) 2 . ?
N1 Ag5' Ag4 90.4(11) . . ?
O7 Ag5' Ag4 76.0(10) . . ?
O1W Ag5' Ag4 134.2(10) 2 . ?
O1W Ag5' Ag4 55.0(8) . . ?
Ag5' Ag5' Ag4 64(5) 2 2 ?
N1 Ag5' Ag4 83.2(10) . 2 ?
O7 Ag5' Ag4 120.5(15) . 2 ?
O1W Ag5' Ag4 51.2(7) 2 2 ?
O1W Ag5' Ag4 118.7(6) . 2 ?
Ag4 Ag5' Ag4 163.3(11) . 2 ?
O2W Ag6 O2W 180.000(1) 5_566 . ?
C3 N1 C3 117.0(6) 2 . ?
C3 N1 Ag5' 118.5(11) 2 . ?
C3 N1 Ag5' 122.9(11) . . ?
C3 N1 Ag5' 122.9(11) 2 2 ?
C3 N1 Ag5' 118.5(11) . 2 ?
Ag5' N1 Ag5' 24.9(13) . 2 ?
C3 N1 Ag5 121.5(3) 2 . ?
C3 N1 Ag5 121.5(3) . . ?
Ag5' N1 Ag5 12.5(6) . . ?
Ag5' N1 Ag5 12.5(6) 2 . ?
C2 C1 Ag2 130.0(4) . . ?
C2 C1 Ag3 141.1(5) . . ?
Ag2 C1 Ag3 86.34(19) . . ?
C2 C1 Ag1 118.6(4) . . ?
Ag2 C1 Ag1 78.59(17) . . ?
Ag3 C1 Ag1 77.06(16) . . ?
C2 C1 Ag4 86.4(4) . . ?
Ag2 C1 Ag4 85.23(18) . . ?
Ag3 C1 Ag4 83.05(18) . . ?
Ag1 C1 Ag4 155.0(3) . . ?
C1 C2 C3 170.4(5) . . ?
C1 C2 Ag4 65.1(3) . . ?
C3 C2 Ag4 124.1(3) . . ?
N1 C3 C4 123.4(5) . . ?
N1 C3 C2 116.9(5) . . ?
C4 C3 C2 119.6(5) . . ?
C5 C4 C3 118.3(6) . . ?
C4 C5 C4 119.4(8) 2 . ?
C6 O1 Ag4 124.0(4) . . ?
C6 O1 Ag2 140.9(4) . 7_556 ?
Ag4 O1 Ag2 90.90(14) . 7_556 ?
C6 O2 Ag3 119.2(4) . . ?
O2 C6 O1 129.0(6) . . ?
O2 C6 C7 117.0(7) . . ?
O1 C6 C7 113.9(7) . . ?
O2 C6 C7' 114.8(8) . . ?
O1 C6 C7' 116.2(8) . . ?
C7 C6 C7' 6.3(16) . . ?
F12 C7 F13 108(2) . . ?
F12 C7 F11 106(2) . . ?
F13 C7 F11 107(2) . . ?
F12 C7 C6 112(2) . . ?
F13 C7 C6 112(2) . . ?
F11 C7 C6 112(2) . . ?
F11' C7' F13' 104.5(18) . . ?
F11' C7' F12' 103.5(18) . . ?
F13' C7' F12' 105.8(18) . . ?
F11' C7' C6 110(2) . . ?
F13' C7' C6 117(2) . . ?
F12' C7' C6 115(2) . . ?
C8 O3 Ag1 120.9(4) . . ?
C8 O4 Ag3 123.1(4) . . ?
O3 C8 O4 129.9(6) . . ?
O3 C8 C9 114.9(6) . . ?
O4 C8 C9 115.1(6) . . ?
F22 C9 F21 107.5(13) . . ?
F22 C9 F22' 141.4(16) . . ?
F21 C9 F22' 49.1(13) . . ?
F22 C9 F21' 62.9(15) . . ?
F21 C9 F21' 135.5(15) . . ?
F22' C9 F21' 109.5(13) . . ?
F22 C9 F23 105.5(12) . . ?
F21 C9 F23 104.1(13) . . ?
F22' C9 F23 62.8(15) . . ?
F21' C9 F23 47.7(15) . . ?
F22 C9 F23' 49.1(13) . . ?
F21 C9 F23' 62.3(12) . . ?
F22' C9 F23' 109.7(13) . . ?
F21' C9 F23' 108.4(12) . . ?
F23 C9 F23' 132.8(16) . . ?
F22 C9 C8 111.2(13) . . ?
F21 C9 C8 113.5(10) . . ?
F22' C9 C8 106.9(13) . . ?
F21' C9 C8 110.1(13) . . ?
F23 C9 C8 114.4(13) . . ?
F23' C9 C8 112.2(12) . . ?
C10 O5 Ag1 125.6(4) . . ?
C10 O5 Ag1 128.5(4) . 5_556 ?
Ag1 O5 Ag1 96.64(15) . 5_556 ?
C10 O6 Ag2 120.0(4) . . ?
O5 C10 O6 128.8(6) . . ?
O5 C10 C11 115.6(5) . . ?
O6 C10 C11 115.6(5) . . ?
F31 C11 F32 105.4(12) . . ?
F31 C11 F33 106.1(13) . . ?
F32 C11 F33 102.8(11) . . ?
F31 C11 F32' 125.2(18) . . ?
F32 C11 F32' 33.5(14) . . ?
F33 C11 F32' 71.6(13) . . ?
F31 C11 F31' 68.2(13) . . ?
F32 C11 F31' 131.0(14) . . ?
F33 C11 F31' 42.7(13) . . ?
F32' C11 F31' 109.0(12) . . ?
F31 C11 F33' 40.7(13) . . ?
F32 C11 F33' 75.3(15) . . ?
F33 C11 F33' 139.9(15) . . ?
F32' C11 F33' 106.8(12) . . ?
F31' C11 F33' 108.5(13) . . ?
F31 C11 C10 116.8(10) . . ?
F32 C11 C10 114.2(12) . . ?
F33 C11 C10 110.3(11) . . ?
F32' C11 C10 114.6(15) . . ?
F31' C11 C10 111.2(10) . . ?
F33' C11 C10 106.5(11) . . ?
C12 O7 Ag5' 131.6(11) . . ?
C12 O8 Ag4 121.2(4) . . ?
C12 O8 Ag2 132.8(4) . 7_556 ?
Ag4 O8 Ag2 100.78(15) . 7_556 ?
O7 C12 O8 128.3(6) . . ?
O7 C12 C13 116.3(5) . . ?
O8 C12 C13 115.4(5) . . ?
F41' C13 F42' 106.2(12) . . ?
F41' C13 F43' 104.2(11) . . ?
F42' C13 F43' 106.4(12) . . ?
F41' C13 F41 131.4(10) . . ?
F42' C13 F41 59.6(15) . . ?
F43' C13 F41 50.0(14) . . ?
F41' C13 F42 46.9(12) . . ?
F42' C13 F42 134.7(14) . . ?
F43' C13 F42 61.7(12) . . ?
F41 C13 F42 107.2(11) . . ?
F41' C13 F43 62.8(12) . . ?
F42' C13 F43 49.2(13) . . ?
F43' C13 F43 137.0(16) . . ?
F41 C13 F43 105.7(10) . . ?
F42 C13 F43 107.5(11) . . ?
F41' C13 C12 113.4(8) . . ?
F42' C13 C12 113.7(11) . . ?
F43' C13 C12 112.2(12) . . ?
F41 C13 C12 114.7(7) . . ?
F42 C13 C12 111.0(10) . . ?
F43 C13 C12 110.4(11) . . ?
Ag5 O1W Ag5' 11.3(6) . 2 ?
Ag5 O1W Ag5' 10.6(6) . . ?
Ag5' O1W Ag5' 21.7(13) 2 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O3 2.228(5) . ?
Ag1 C1 2.271(5) . ?
Ag1 O5 2.321(4) . ?
Ag1 O5 2.455(4) 5_556 ?
Ag1 Ag3 2.7908(6) . ?
Ag1 Ag2 2.8315(6) . ?
Ag2 C1 2.199(6) . ?
Ag2 O8 2.339(4) 7_556 ?
Ag2 O6 2.345(4) . ?
Ag2 O1 2.516(4) 7_556 ?
Ag2 Ag3 3.0152(7) . ?
Ag2 Ag4 3.0345(7) . ?
Ag3 C1 2.208(5) . ?
Ag3 O2 2.314(4) . ?
Ag3 O4 2.319(4) . ?
Ag3 O3W 2.578(5) . ?
Ag3 Ag4 2.9771(6) . ?
Ag4 O8 2.242(4) . ?
Ag4 C1 2.282(5) . ?
Ag4 O1 2.436(4) . ?
Ag4 C2 2.512(5) . ?
Ag4 Ag5' 3.03(4) . ?
Ag4 Ag5 3.1468(6) . ?
Ag4 Ag5' 3.32(4) 2 ?
Ag5 N1 2.249(7) . ?
Ag5 O1W 2.394(6) . ?
Ag5 O1W 2.394(6) 2 ?
Ag5 Ag4 3.1468(6) 2 ?
Ag5' Ag5' 0.95(5) 2 ?
Ag5' N1 2.20(2) . ?
Ag5' O7 2.23(3) . ?
Ag5' O1W 2.47(3) 2 ?
Ag5' O1W 2.56(3) . ?
Ag5' Ag4 3.32(4) 2 ?
Ag6 O2W 2.248(6) 5_566 ?
Ag6 O2W 2.248(6) . ?
N1 C3 1.335(6) 2 ?
N1 C3 1.335(6) . ?
N1 Ag5' 2.20(2) 2 ?
C1 C2 1.204(7) . ?
C2 C3 1.443(7) . ?
C3 C4 1.384(7) . ?
C4 C5 1.373(7) . ?
C5 C4 1.373(7) 2 ?
O1 C6 1.235(7) . ?
O1 Ag2 2.516(4) 7_556 ?
O2 C6 1.226(7) . ?
C6 C7 1.51(4) . ?
C6 C7' 1.54(2) . ?
C7 F12 1.32(2) . ?
C7 F13 1.32(2) . ?
C7 F11 1.33(2) . ?
C7' F11' 1.22(2) . ?
C7' F13' 1.22(2) . ?
C7' F12' 1.22(2) . ?
O3 C8 1.212(8) . ?
O4 C8 1.239(8) . ?
C8 C9 1.542(11) . ?
C9 F22 1.268(18) . ?
C9 F21 1.271(16) . ?
C9 F22' 1.27(2) . ?
C9 F21' 1.27(2) . ?
C9 F23 1.284(19) . ?
C9 F23' 1.284(18) . ?
O5 C10 1.221(7) . ?
O5 Ag1 2.455(4) 5_556 ?
O6 C10 1.246(7) . ?
C10 C11 1.544(9) . ?
C11 F31 1.220(14) . ?
C11 F32 1.242(15) . ?
C11 F33 1.262(14) . ?
C11 F32' 1.285(17) . ?
C11 F31' 1.285(15) . ?
C11 F33' 1.314(16) . ?
O7 C12 1.211(7) . ?
O8 C12 1.239(7) . ?
O8 Ag2 2.339(4) 7_556 ?
C12 C13 1.542(9) . ?
C13 F41' 1.228(12) . ?
C13 F42' 1.232(14) . ?
C13 F43' 1.250(15) . ?
C13 F41 1.256(12) . ?
C13 F42 1.270(12) . ?
C13 F43 1.286(13) . ?
O1W Ag5' 2.47(3) 2 ?
