#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:32:08 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179065 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/27/4302733.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4302733
loop_
_publ_author_name
'Yue-Peng Cai'
'Xiu-Xia Zhou'
'Zheng-Yuan Zhou'
'Shi-Zheng Zhu'
'Praveen K. Thallapally'
'Jun Liu'
_publ_contact_author_address
;      
Energy and Environment Division
Pacific Northwest National Laboratory
Richland, WA 99352   USA
;
_publ_contact_author_email       praveen.thallapally@pnl.gov
_publ_contact_author_fax         '+1 (509)371 7249'
_publ_contact_author_name        'Praveen K. Thallapally'
_publ_contact_author_phone       '+1 (509)371 7183'
_publ_section_title
;
Single-Crystal-to-Single-Crystal Transformation in a One-Dimensional
Ag-Eu Helical System
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6341
_journal_page_last               6343
_journal_paper_doi               10.1021/ic9007125
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C14 H12 Ag Eu N2 O11, H2 O'
_chemical_formula_sum            'C14 H14 Ag Eu N2 O12'
_chemical_formula_weight         662.10
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.046(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.7248(6)
_cell_length_b                   7.4407(3)
_cell_length_c                   19.3497(8)
_cell_measurement_reflns_used    7227
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.53
_cell_measurement_theta_min      3.05
_cell_volume                     1925.03(14)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0207
_diffrn_reflns_av_sigmaI/netI    0.0213
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            12153
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.66
_exptl_absorpt_coefficient_mu    4.313
_exptl_absorpt_correction_T_max  0.5453
_exptl_absorpt_correction_T_min  0.3780
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.285
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1272
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.938
_refine_diff_density_min         -2.519
_refine_diff_density_rms         0.159
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     295
_refine_ls_number_reflns         3564
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0441
_refine_ls_R_factor_gt           0.0401
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0472P)²+18.0435P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0988
_refine_ls_wR_factor_ref         0.1019
_reflns_number_gt                3226
_reflns_number_total             3564
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic9007125_si_001_2.cif
_cod_data_source_block           compound_2_for_CCDC_#717401
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4302733
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.803543(10) 0.929188(19) 0.141883(7) 0.02066(4) Uani 1 1 d D . .
Ag1 Ag 0.88550(3) 1.46644(6) 0.01257(3) 0.10973(18) Uani 1 1 d . . .
O1 O 0.88245(16) 0.6643(3) 0.20358(12) 0.0313(6) Uani 1 1 d . . .
O2 O 0.9984(2) 0.4488(3) 0.21804(16) 0.0486(8) Uani 1 1 d . . .
O3 O 0.87825(17) 1.1466(3) 0.07434(12) 0.0350(6) Uani 1 1 d . . .
O4 O 0.7323(2) 0.6037(4) -0.06263(14) 0.0466(8) Uani 1 1 d . . .
O5 O 0.79905(17) 0.7153(3) 0.04381(12) 0.0330(6) Uani 1 1 d . . .
O6 O 1.0113(2) 1.2693(4) 0.04524(16) 0.0566(8) Uani 1 1 d . . .
O7 O 0.70244(17) 1.1954(3) 0.13929(11) 0.0317(6) Uani 1 1 d . . .
O8 O 0.5992(2) 1.4050(3) 0.08108(16) 0.0505(8) Uani 1 1 d . . .
O9 O 0.66458(16) 0.7241(3) 0.13936(10) 0.0304(6) Uani 1 1 d D . .
H9A H 0.6585(11) 0.709(3) 0.1813(3) 0.046 Uiso 1 1 d D . .
H9B H 0.654(2) 0.6324(9) 0.1133(4) 0.046 Uiso 1 1 d D . .
O10 O 0.74538(17) 0.9291(3) 0.25077(12) 0.0321(6) Uani 1 1 d D . .
H10A H 0.7835(7) 0.8789(14) 0.2850(4) 0.048 Uiso 1 1 d D . .
H10B H 0.7125(6) 1.0193(9) 0.2569(5) 0.048 Uiso 1 1 d D . .
O11 O 0.91626(17) 1.1228(3) 0.23183(12) 0.0363(7) Uani 1 1 d D . .
H11A H 0.9620(6) 1.0565(11) 0.2545(8) 0.055 Uiso 1 1 d D . .
H11B H 0.9346(10) 1.2252(8) 0.2214(9) 0.055 Uiso 1 1 d D . .
H1WB H 0.1091(5) 0.991(4) 0.3023(4) 0.055 Uiso 1 1 d D . .
O1W O 0.0656(4) 0.9735(7) 0.3269(2) 0.226(3) Uani 1 1 d D . .
H1WA H 0.0889(16) 0.963(6) 0.3708(3) 0.340 Uiso 1 1 d D . .
N1 N 0.98176(19) 0.8692(4) 0.13423(14) 0.0286(7) Uani 1 1 d . . .
N2 N 0.67940(18) 0.9918(3) 0.02637(13) 0.0250(6) Uani 1 1 d . . .
C1 C 0.9652(2) 0.5995(4) 0.19767(18) 0.0318(9) Uani 1 1 d . . .
C2 C 1.0280(2) 0.7191(5) 0.1620(2) 0.0381(9) Uani 1 1 d . . .
C3 C 1.1244(3) 0.6782(6) 0.1570(3) 0.0745(14) Uani 1 1 d . . .
H3 H 1.1545 0.5709 0.1750 0.089 Uiso 1 1 calc R . .
C4 C 1.1742(3) 0.8008(7) 0.1245(3) 0.1012(18) Uani 1 1 d . . .
H4 H 1.2392 0.7770 0.1202 0.121 Uiso 1 1 calc R . .
C5 C 1.1281(3) 0.9591(6) 0.0981(3) 0.0742(14) Uani 1 1 d . . .
H5 H 1.1624 1.0450 0.0779 0.089 Uiso 1 1 calc R . .
C6 C 1.0300(2) 0.9877(5) 0.10218(19) 0.0385(9) Uani 1 1 d . . .
C7 C 0.9705(3) 1.1471(5) 0.07255(19) 0.0369(9) Uani 1 1 d . . .
C8 C 0.7371(2) 0.7207(4) -0.01583(16) 0.0286(8) Uani 1 1 d . . .
C9 C 0.6693(2) 0.8817(4) -0.02945(16) 0.0282(8) Uani 1 1 d . . .
C10 C 0.6063(3) 0.9208(5) -0.09419(19) 0.0392(10) Uani 1 1 d . . .
H10 H 0.6014 0.8429 -0.1324 0.047 Uiso 1 1 calc R . .
C11 C 0.5506(3) 1.0780(5) -0.10122(19) 0.0451(11) Uani 1 1 d . . .
H11 H 0.5074 1.1070 -0.1441 0.054 Uiso 1 1 calc R . .
C12 C 0.5606(3) 1.1907(5) -0.04331(19) 0.0382(10) Uani 1 1 d . . .
H12 H 0.5240 1.2967 -0.0465 0.046 Uiso 1 1 calc R . .
C13 C 0.6256(2) 1.1434(4) 0.01913(17) 0.0271(8) Uani 1 1 d . . .
C14 C 0.6433(2) 1.2592(4) 0.08442(17) 0.0296(8) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Eu1 O10 73.54(7) . . ?
O7 Eu1 O1 150.12(8) . . ?
O10 Eu1 O1 76.68(7) . . ?
O7 Eu1 O9 94.02(8) . . ?
O10 Eu1 O9 66.78(7) . . ?
O1 Eu1 O9 76.20(7) . . ?
O7 Eu1 O3 75.78(8) . . ?
O10 Eu1 O3 136.65(7) . . ?
O1 Eu1 O3 127.25(8) . . ?
O9 Eu1 O3 145.58(7) . . ?
O7 Eu1 O5 126.83(7) . . ?
O10 Eu1 O5 135.64(8) . . ?
O1 Eu1 O5 77.61(7) . . ?
O9 Eu1 O5 72.34(8) . . ?
O3 Eu1 O5 87.50(8) . . ?
O7 Eu1 O11 78.73(7) . . ?
O10 Eu1 O11 70.62(8) . . ?
O1 Eu1 O11 89.33(7) . . ?
O9 Eu1 O11 137.07(7) . . ?
O3 Eu1 O11 73.94(8) . . ?
O5 Eu1 O11 144.03(8) . . ?
O7 Eu1 N1 134.79(8) . . ?
O10 Eu1 N1 124.52(8) . . ?
O1 Eu1 N1 63.56(8) . . ?
O9 Eu1 N1 130.79(8) . . ?
O3 Eu1 N1 63.69(8) . . ?
O5 Eu1 N1 72.36(8) . . ?
O11 Eu1 N1 71.81(8) . . ?
O7 Eu1 N2 63.95(8) . . ?
O10 Eu1 N2 118.78(8) . . ?
O1 Eu1 N2 136.10(8) . . ?
O9 Eu1 N2 74.30(8) . . ?
O3 Eu1 N2 71.70(8) . . ?
O5 Eu1 N2 62.88(8) . . ?
O11 Eu1 N2 134.02(8) . . ?
N1 Eu1 N2 116.70(8) . . ?
O7 Eu1 H9A 92.6(4) . . ?
O10 Eu1 H9A 50.9(2) . . ?
O1 Eu1 H9A 70.0(3) . . ?
O9 Eu1 H9A 16.52(16) . . ?
O3 Eu1 H9A 159.7(2) . . ?
O5 Eu1 H9A 86.4(3) . . ?
O11 Eu1 H9A 120.67(18) . . ?
N1 Eu1 H9A 131.9(4) . . ?
N2 Eu1 H9A 88.3(2) . . ?
O6 Ag1 O5 147.47(10) . 1_565 ?
O6 Ag1 O4 157.96(10) . 1_565 ?
O5 Ag1 O4 54.44(8) 1_565 1_565 ?
O6 Ag1 Ag1 56.42(7) . 3_785 ?
O5 Ag1 Ag1 117.91(6) 1_565 3_785 ?
O4 Ag1 Ag1 123.67(7) 1_565 3_785 ?
C1 O1 Eu1 125.2(2) . . ?
C7 O3 Eu1 123.7(2) . . ?
C8 O4 Ag1 87.86(19) . 1_545 ?
C8 O5 Ag1 93.70(19) . 1_545 ?
C8 O5 Eu1 125.0(2) . . ?
Ag1 O5 Eu1 141.23(9) 1_545 . ?
C7 O6 Ag1 101.8(2) . . ?
C14 O7 Eu1 125.3(2) . . ?
Eu1 O9 H9A 108.1(11) . . ?
Eu1 O9 H9B 123(2) . . ?
H9A O9 H9B 115.5(15) . . ?
Eu1 O10 H10A 114.9(7) . . ?
Eu1 O10 H10B 114.9(7) . . ?
H10A O10 H10B 120.7(10) . . ?
Eu1 O11 H11A 107.3(8) . . ?
Eu1 O11 H11B 121.6(11) . . ?
H11A O11 H11B 115.4(11) . . ?
H1WB O1W H1WA 115.0(16) . . ?
C6 N1 C2 119.9(3) . . ?
C6 N1 Eu1 119.9(2) . . ?
C2 N1 Eu1 120.2(2) . . ?
C9 N2 C13 118.5(3) . . ?
C9 N2 Eu1 121.8(2) . . ?
C13 N2 Eu1 119.58(19) . . ?
O2 C1 O1 126.1(3) . . ?
O2 C1 C2 118.1(3) . . ?
O1 C1 C2 115.7(3) . . ?
N1 C2 C3 122.1(4) . . ?
N1 C2 C1 114.1(3) . . ?
C3 C2 C1 123.8(3) . . ?
C4 C3 C2 118.0(4) . . ?
C4 C3 H3 121.0 . . ?
C2 C3 H3 121.0 . . ?
C3 C4 C5 120.1(4) . . ?
C3 C4 H4 119.9 . . ?
C5 C4 H4 119.9 . . ?
C4 C5 C6 118.8(4) . . ?
C4 C5 H5 120.6 . . ?
C6 C5 H5 120.6 . . ?
N1 C6 C5 121.0(3) . . ?
N1 C6 C7 114.9(3) . . ?
C5 C6 C7 124.0(4) . . ?
O6 C7 O3 123.9(3) . . ?
O6 C7 C6 119.2(3) . . ?
O3 C7 C6 116.8(3) . . ?
O4 C8 O5 123.5(3) . . ?
O4 C8 C9 120.0(3) . . ?
O5 C8 C9 116.5(3) . . ?
N2 C9 C10 122.2(3) . . ?
N2 C9 C8 113.5(3) . . ?
C10 C9 C8 124.2(3) . . ?
C9 C10 C11 118.9(3) . . ?
C9 C10 H10 120.5 . . ?
C11 C10 H10 120.5 . . ?
C12 C11 C10 118.7(3) . . ?
C12 C11 H11 120.6 . . ?
C10 C11 H11 120.6 . . ?
C13 C12 C11 118.9(3) . . ?
C13 C12 H12 120.6 . . ?
C11 C12 H12 120.6 . . ?
N2 C13 C12 122.7(3) . . ?
N2 C13 C14 114.5(3) . . ?
C12 C13 C14 122.8(3) . . ?
O8 C14 O7 125.6(3) . . ?
O8 C14 C13 118.3(3) . . ?
O7 C14 C13 116.0(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O7 2.413(2) . ?
Eu1 O10 2.416(2) . ?
Eu1 O1 2.429(2) . ?
Eu1 O9 2.435(2) . ?
Eu1 O3 2.446(2) . ?
Eu1 O5 2.467(2) . ?
Eu1 O11 2.506(2) . ?
Eu1 N1 2.523(3) . ?
Eu1 N2 2.529(2) . ?
Eu1 H9A 2.812(16) . ?
Ag1 O6 2.245(3) . ?
Ag1 O5 2.350(2) 1_565 ?
Ag1 O4 2.490(3) 1_565 ?
Ag1 Ag1 3.3247(10) 3_785 ?
O1 C1 1.263(4) . ?
O2 C1 1.241(4) . ?
O3 C7 1.275(4) . ?
O4 C8 1.247(4) . ?
O4 Ag1 2.490(3) 1_545 ?
O5 C8 1.270(4) . ?
O5 Ag1 2.350(2) 1_545 ?
O6 C7 1.246(5) . ?
O7 C14 1.273(4) . ?
O8 C14 1.237(4) . ?
O9 H9A 0.841(7) . ?
O9 H9B 0.842(6) . ?
O10 H10A 0.834(6) . ?
O10 H10B 0.832(6) . ?
O11 H11A 0.840(7) . ?
O11 H11B 0.842(7) . ?
O1W H1WB 0.854(8) . ?
O1W H1WA 0.840(7) . ?
N1 C6 1.336(5) . ?
N1 C2 1.336(4) . ?
N2 C9 1.337(4) . ?
N2 C13 1.338(4) . ?
C1 C2 1.510(5) . ?
C2 C3 1.382(6) . ?
C3 C4 1.375(7) . ?
C3 H3 0.9300 . ?
C4 C5 1.379(7) . ?
C4 H4 0.9300 . ?
C5 C6 1.384(6) . ?
C5 H5 0.9300 . ?
C6 C7 1.480(5) . ?
C8 C9 1.504(4) . ?
C9 C10 1.382(4) . ?
C10 C11 1.387(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.381(5) . ?
C11 H11 0.9300 . ?
C12 C13 1.376(4) . ?
C12 H12 0.9300 . ?
C13 C14 1.503(4) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1WA O4 0.840(7) 2.15(2) 2.815(5) 136(2) 4_576
O11 H11B O2 0.842(7) 1.888(8) 2.713(3) 166.5(15) 1_565
O11 H11A O1W 0.840(7) 1.862(10) 2.668(5) 160.4(14) 1_655
O10 H10B O9 0.832(6) 2.769(9) 3.111(3) 106.6(7) 2_655
O10 H10B O1 0.832(6) 1.974(8) 2.760(3) 157.4(10) 2_655
O10 H10A O7 0.834(6) 1.980(8) 2.715(3) 146.6(10) 2_645
O9 H9B O8 0.842(6) 1.898(12) 2.694(3) 157(2) 1_545
O9 H9A O11 0.841(7) 2.252(11) 3.043(3) 156.7(14) 2_645
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O7 Eu1 O1 C1 -145.9(2) . . . . ?
O10 Eu1 O1 C1 -150.5(3) . . . . ?
O9 Eu1 O1 C1 140.5(3) . . . . ?
O3 Eu1 O1 C1 -11.2(3) . . . . ?
O5 Eu1 O1 C1 65.9(2) . . . . ?
O11 Eu1 O1 C1 -80.3(2) . . . . ?
N1 Eu1 O1 C1 -10.3(2) . . . . ?
N2 Eu1 O1 C1 91.6(3) . . . . ?
O7 Eu1 O3 C7 150.8(3) . . . . ?
O10 Eu1 O3 C7 104.8(3) . . . . ?
O1 Eu1 O3 C7 -7.8(3) . . . . ?
O9 Eu1 O3 C7 -133.2(2) . . . . ?
O5 Eu1 O3 C7 -80.1(3) . . . . ?
O11 Eu1 O3 C7 68.7(3) . . . . ?
N1 Eu1 O3 C7 -8.6(2) . . . . ?
N2 Eu1 O3 C7 -142.4(3) . . . . ?
O7 Eu1 O5 C8 -5.3(3) . . . . ?
O10 Eu1 O5 C8 99.8(3) . . . . ?
O1 Eu1 O5 C8 155.6(3) . . . . ?
O9 Eu1 O5 C8 76.3(3) . . . . ?
O3 Eu1 O5 C8 -75.4(3) . . . . ?
O11 Eu1 O5 C8 -133.3(2) . . . . ?
N1 Eu1 O5 C8 -138.6(3) . . . . ?
N2 Eu1 O5 C8 -4.7(2) . . . . ?
O7 Eu1 O5 Ag1 171.25(14) . . . 1_545 ?
O10 Eu1 O5 Ag1 -83.7(2) . . . 1_545 ?
O1 Eu1 O5 Ag1 -27.91(16) . . . 1_545 ?
O9 Eu1 O5 Ag1 -107.17(18) . . . 1_545 ?
O3 Eu1 O5 Ag1 101.13(17) . . . 1_545 ?
O11 Eu1 O5 Ag1 43.2(2) . . . 1_545 ?
N1 Eu1 O5 Ag1 37.98(17) . . . 1_545 ?
N2 Eu1 O5 Ag1 171.8(2) . . . 1_545 ?
O5 Ag1 O6 C7 89.0(3) 1_565 . . . ?
O4 Ag1 O6 C7 -83.1(4) 1_565 . . . ?
Ag1 Ag1 O6 C7 179.3(3) 3_785 . . . ?
O10 Eu1 O7 C14 -142.1(3) . . . . ?
O1 Eu1 O7 C14 -146.8(2) . . . . ?
O9 Eu1 O7 C14 -77.8(3) . . . . ?
O3 Eu1 O7 C14 68.9(3) . . . . ?
O5 Eu1 O7 C14 -6.9(3) . . . . ?
O11 Eu1 O7 C14 145.0(3) . . . . ?
N1 Eu1 O7 C14 95.2(3) . . . . ?
N2 Eu1 O7 C14 -7.4(2) . . . . ?
O7 Eu1 N1 C6 -24.4(3) . . . . ?
O10 Eu1 N1 C6 -125.8(2) . . . . ?
O1 Eu1 N1 C6 -175.0(3) . . . . ?
O9 Eu1 N1 C6 146.4(2) . . . . ?
O3 Eu1 N1 C6 4.3(2) . . . . ?
O5 Eu1 N1 C6 100.4(3) . . . . ?
O11 Eu1 N1 C6 -76.4(2) . . . . ?
N2 Eu1 N1 C6 54.4(3) . . . . ?
O7 Eu1 N1 C2 155.7(2) . . . . ?
O10 Eu1 N1 C2 54.3(3) . . . . ?
O1 Eu1 N1 C2 5.2(2) . . . . ?
O9 Eu1 N1 C2 -33.5(3) . . . . ?
O3 Eu1 N1 C2 -175.6(3) . . . . ?
O5 Eu1 N1 C2 -79.5(3) . . . . ?
O11 Eu1 N1 C2 103.8(3) . . . . ?
N2 Eu1 N1 C2 -125.4(2) . . . . ?
O7 Eu1 N2 C9 -178.8(3) . . . . ?
O10 Eu1 N2 C9 -127.7(2) . . . . ?
O1 Eu1 N2 C9 -26.7(3) . . . . ?
O9 Eu1 N2 C9 -76.2(2) . . . . ?
O3 Eu1 N2 C9 98.5(3) . . . . ?
O5 Eu1 N2 C9 1.7(2) . . . . ?
O11 Eu1 N2 C9 142.0(2) . . . . ?
N1 Eu1 N2 C9 52.0(3) . . . . ?
O7 Eu1 N2 C13 4.6(2) . . . . ?
O10 Eu1 N2 C13 55.7(3) . . . . ?
O1 Eu1 N2 C13 156.8(2) . . . . ?
O9 Eu1 N2 C13 107.3(2) . . . . ?
O3 Eu1 N2 C13 -78.1(2) . . . . ?
O5 Eu1 N2 C13 -174.9(3) . . . . ?
O11 Eu1 N2 C13 -34.5(3) . . . . ?
N1 Eu1 N2 C13 -124.6(2) . . . . ?
Eu1 O1 C1 O2 -166.1(3) . . . . ?
Eu1 O1 C1 C2 13.6(4) . . . . ?
C6 N1 C2 C3 -2.0(6) . . . . ?
Eu1 N1 C2 C3 177.8(3) . . . . ?
C6 N1 C2 C1 178.9(3) . . . . ?
Eu1 N1 C2 C1 -1.2(4) . . . . ?
O2 C1 C2 N1 172.4(3) . . . . ?
O1 C1 C2 N1 -7.4(4) . . . . ?
O2 C1 C2 C3 -6.7(6) . . . . ?
O1 C1 C2 C3 173.6(4) . . . . ?
N1 C2 C3 C4 2.5(7) . . . . ?
C1 C2 C3 C4 -178.5(4) . . . . ?
C2 C3 C4 C5 0.0(8) . . . . ?
C3 C4 C5 C6 -2.9(9) . . . . ?
C2 N1 C6 C5 -1.0(5) . . . . ?
Eu1 N1 C6 C5 179.1(3) . . . . ?
C2 N1 C6 C7 179.1(3) . . . . ?
Eu1 N1 C6 C7 -0.8(4) . . . . ?
C4 C5 C6 N1 3.4(7) . . . . ?
C4 C5 C6 C7 -176.7(5) . . . . ?
Ag1 O6 C7 O3 3.4(4) . . . . ?
Ag1 O6 C7 C6 -179.5(3) . . . . ?
Eu1 O3 C7 O6 -171.2(3) . . . . ?
Eu1 O3 C7 C6 11.6(4) . . . . ?
N1 C6 C7 O6 176.0(3) . . . . ?
C5 C6 C7 O6 -3.9(6) . . . . ?
N1 C6 C7 O3 -6.7(5) . . . . ?
C5 C6 C7 O3 173.4(4) . . . . ?
Ag1 O4 C8 O5 -6.8(3) 1_545 . . . ?
Ag1 O4 C8 C9 171.3(3) 1_545 . . . ?
Ag1 O5 C8 O4 7.2(4) 1_545 . . . ?
Eu1 O5 C8 O4 -174.9(3) . . . . ?
Ag1 O5 C8 C9 -171.0(3) 1_545 . . . ?
Eu1 O5 C8 C9 6.8(4) . . . . ?
C13 N2 C9 C10 0.9(5) . . . . ?
Eu1 N2 C9 C10 -175.7(3) . . . . ?
C13 N2 C9 C8 177.2(3) . . . . ?
Eu1 N2 C9 C8 0.6(4) . . . . ?
O4 C8 C9 N2 177.1(3) . . . . ?
O5 C8 C9 N2 -4.6(4) . . . . ?
O4 C8 C9 C10 -6.6(5) . . . . ?
O5 C8 C9 C10 171.7(3) . . . . ?
N2 C9 C10 C11 -1.0(6) . . . . ?
C8 C9 C10 C11 -177.0(3) . . . . ?
C9 C10 C11 C12 0.4(6) . . . . ?
C10 C11 C12 C13 0.2(6) . . . . ?
C9 N2 C13 C12 -0.2(5) . . . . ?
Eu1 N2 C13 C12 176.5(3) . . . . ?
C9 N2 C13 C14 -179.2(3) . . . . ?
Eu1 N2 C13 C14 -2.5(4) . . . . ?
C11 C12 C13 N2 -0.4(6) . . . . ?
C11 C12 C13 C14 178.5(3) . . . . ?
Eu1 O7 C14 O8 -172.1(3) . . . . ?
Eu1 O7 C14 C13 9.0(4) . . . . ?
N2 C13 C14 O8 177.2(3) . . . . ?
C12 C13 C14 O8 -1.7(5) . . . . ?
N2 C13 C14 O7 -3.7(4) . . . . ?
C12 C13 C14 O7 177.3(3) . . . . ?
