#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:39:18 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179071 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/33/4303331.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4303331
loop_
_publ_author_name
'David V. Partyka'
'Nihal Deligonul'
_publ_section_title
;
Phosphine- and Carbene-Ligated Silver Acetate: Easily-Accessed Synthons for
Reactions with Silylated Nucleophiles
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              9463
_journal_page_last               9475
_journal_paper_doi               10.1021/ic901371g
_journal_volume                  48
_journal_year                    2009
_chemical_formula_moiety         'C80 H148 Ag4 N12 O2 P4'
_chemical_formula_sum            'C80 H148 Ag4 N12 O2 P4'
_chemical_formula_weight         1865.46
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.477(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   27.025(4)
_cell_length_b                   14.5163(16)
_cell_length_c                   23.243(3)
_cell_measurement_reflns_used    9863
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.82
_cell_measurement_theta_min      2.25
_cell_volume                     8648(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker AXS APES II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0245
_diffrn_reflns_av_sigmaI/netI    0.0177
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            51053
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.61
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.017
_exptl_absorpt_correction_T_max  0.8542
_exptl_absorpt_correction_T_min  0.8365
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'AXScale in APEX 2 (Bruker, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.433
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
_exptl_crystal_description       irregular
_exptl_crystal_F_000             3904
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.454
_refine_diff_density_min         -0.754
_refine_diff_density_rms         0.173
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         9923
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.083
_refine_ls_R_factor_all          0.0358
_refine_ls_R_factor_gt           0.0304
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0439P)²+28.4528P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0823
_refine_ls_wR_factor_ref         0.0908
_reflns_number_gt                8874
_reflns_number_total             9923
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic901371g_si_001_02.cif
_cod_data_source_block           nd031209_0m_
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        8648.1(18)
_cod_database_code               4303331
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.067611(7) 0.419341(12) 0.255398(8) 0.01691(6) Uani 1 1 d . . .
Ag2 Ag -0.011649(7) 0.585072(13) 0.167233(9) 0.02117(6) Uani 1 1 d . . .
P1 P 0.13749(2) 0.31834(4) 0.26044(3) 0.01458(12) Uani 1 1 d . . .
P2 P -0.02915(3) 0.69596(4) 0.08862(3) 0.01813(13) Uani 1 1 d . . .
C8 C 0.10330(10) 0.22429(17) 0.14892(11) 0.0202(5) Uani 1 1 d . . .
H8A H 0.0763 0.2726 0.1347 0.024 Uiso 1 1 calc R . .
H8B H 0.1351 0.2451 0.1403 0.024 Uiso 1 1 calc R . .
C11 C 0.04632(12) 0.08508(18) 0.19534(13) 0.0272(6) Uani 1 1 d . . .
H11A H 0.0725 0.0354 0.2094 0.033 Uiso 1 1 calc R . .
H11B H 0.0140 0.0655 0.2033 0.033 Uiso 1 1 calc R . .
C7 C 0.11557(9) 0.21040(16) 0.21737(11) 0.0169(4) Uani 1 1 d . . .
H7 H 0.1441 0.1637 0.2313 0.020 Uiso 1 1 calc R . .
C12 C 0.06692(10) 0.17339(18) 0.23082(12) 0.0225(5) Uani 1 1 d . . .
H12A H 0.0758 0.1608 0.2748 0.027 Uiso 1 1 calc R . .
H12B H 0.0392 0.2209 0.2200 0.027 Uiso 1 1 calc R . .
C9 C 0.08378(11) 0.13432(19) 0.11490(12) 0.0254(5) Uani 1 1 d . . .
H9A H 0.0760 0.1445 0.0708 0.031 Uiso 1 1 calc R . .
H9B H 0.1115 0.0870 0.1278 0.031 Uiso 1 1 calc R . .
C10 C 0.03485(12) 0.0997(2) 0.12728(13) 0.0291(6) Uani 1 1 d . . .
H10A H 0.0234 0.0410 0.1055 0.035 Uiso 1 1 calc R . .
H10B H 0.0064 0.1453 0.1123 0.035 Uiso 1 1 calc R . .
C18 C 0.23526(9) 0.30721(17) 0.23688(12) 0.0203(5) Uani 1 1 d . . .
H18A H 0.2533 0.2943 0.2803 0.024 Uiso 1 1 calc R . .
H18B H 0.2237 0.2478 0.2161 0.024 Uiso 1 1 calc R . .
C13 C 0.18746(9) 0.36822(16) 0.23076(11) 0.0164(4) Uani 1 1 d . . .
H13 H 0.1702 0.3790 0.1864 0.020 Uiso 1 1 calc R . .
C2 C 0.13940(10) 0.30096(18) 0.38072(11) 0.0193(5) Uani 1 1 d . . .
H2A H 0.1285 0.3664 0.3773 0.023 Uiso 1 1 calc R . .
H2B H 0.1076 0.2625 0.3669 0.023 Uiso 1 1 calc R . .
C1 C 0.17336(9) 0.28320(17) 0.33987(11) 0.0170(5) Uani 1 1 d . . .
H1 H 0.2044 0.3247 0.3545 0.020 Uiso 1 1 calc R . .
C6 C 0.19411(10) 0.18414(17) 0.34737(11) 0.0209(5) Uani 1 1 d . . .
H6A H 0.2180 0.1758 0.3232 0.025 Uiso 1 1 calc R . .
H6B H 0.1646 0.1408 0.3318 0.025 Uiso 1 1 calc R . .
C14 C 0.20442(10) 0.46312(17) 0.25980(12) 0.0205(5) Uani 1 1 d . . .
H14A H 0.1733 0.5031 0.2525 0.025 Uiso 1 1 calc R . .
H14B H 0.2204 0.4557 0.3042 0.025 Uiso 1 1 calc R . .
C15 C 0.24364(10) 0.50948(18) 0.23375(12) 0.0230(5) Uani 1 1 d . . .
H15A H 0.2261 0.5246 0.1905 0.028 Uiso 1 1 calc R . .
H15B H 0.2558 0.5678 0.2557 0.028 Uiso 1 1 calc R . .
C4 C 0.18857(11) 0.17907(19) 0.45379(12) 0.0255(5) Uani 1 1 d . . .
H4A H 0.2087 0.1668 0.4968 0.031 Uiso 1 1 calc R . .
H4B H 0.1584 0.1364 0.4418 0.031 Uiso 1 1 calc R . .
C16 C 0.29053(10) 0.4479(2) 0.23894(13) 0.0261(6) Uani 1 1 d . . .
H16A H 0.3106 0.4389 0.2823 0.031 Uiso 1 1 calc R . .
H16B H 0.3136 0.4783 0.2191 0.031 Uiso 1 1 calc R . .
C3 C 0.16901(10) 0.27864(19) 0.44697(11) 0.0231(5) Uani 1 1 d . . .
H3A H 0.1457 0.2881 0.4719 0.028 Uiso 1 1 calc R . .
H3B H 0.1991 0.3210 0.4620 0.028 Uiso 1 1 calc R . .
C5 C 0.22315(11) 0.1620(2) 0.41410(12) 0.0262(6) Uani 1 1 d . . .
H5A H 0.2343 0.0967 0.4178 0.031 Uiso 1 1 calc R . .
H5B H 0.2548 0.2009 0.4285 0.031 Uiso 1 1 calc R . .
C17 C 0.27333(10) 0.35419(19) 0.20926(13) 0.0249(5) Uani 1 1 d . . .
H17A H 0.3043 0.3144 0.2151 0.030 Uiso 1 1 calc R . .
H17B H 0.2562 0.3626 0.1651 0.030 Uiso 1 1 calc R . .
N1 N -0.01433(8) 0.42508(14) 0.17592(10) 0.0175(4) Uani 1 1 d . . .
N4 N 0.06125(8) 0.58041(14) 0.26046(10) 0.0191(4) Uani 1 1 d . . .
C19 C 0.03098(10) 0.73728(17) 0.07453(12) 0.0207(5) Uani 1 1 d . . .
H19 H 0.0384 0.6916 0.0461 0.025 Uiso 1 1 calc R . .
C30 C -0.04766(11) 0.57200(18) -0.00596(12) 0.0229(5) Uani 1 1 d . . .
H30A H -0.0141 0.5901 -0.0114 0.028 Uiso 1 1 calc R . .
H30B H -0.0401 0.5251 0.0266 0.028 Uiso 1 1 calc R . .
C25 C -0.07219(10) 0.65643(18) 0.01372(12) 0.0206(5) Uani 1 1 d . . .
H25 H -0.0754 0.7068 -0.0166 0.025 Uiso 1 1 calc R . .
C24 C 0.07796(11) 0.7332(2) 0.13256(13) 0.0289(6) Uani 1 1 d . . .
H24A H 0.0731 0.7781 0.1624 0.035 Uiso 1 1 calc R . .
H24B H 0.0804 0.6709 0.1506 0.035 Uiso 1 1 calc R . .
C32 C -0.09241(13) 0.8632(2) 0.06137(13) 0.0320(7) Uani 1 1 d . . .
H32A H -0.1118 0.8329 0.0226 0.038 Uiso 1 1 calc R . .
H32B H -0.0658 0.9042 0.0540 0.038 Uiso 1 1 calc R . .
C26 C -0.12667(11) 0.6323(2) 0.01637(14) 0.0297(6) Uani 1 1 d . . .
H26A H -0.1434 0.6886 0.0255 0.036 Uiso 1 1 calc R . .
H26B H -0.1234 0.5876 0.0496 0.036 Uiso 1 1 calc R . .
C31 C -0.06584(15) 0.7901(2) 0.10898(14) 0.0387(8) Uani 1 1 d . . .
H31 H -0.0957 0.7582 0.1172 0.046 Uiso 1 1 calc R . .
C20 C 0.02784(12) 0.8313(2) 0.04350(13) 0.0296(6) Uani 1 1 d . . .
H20A H 0.0211 0.8798 0.0700 0.036 Uiso 1 1 calc R . .
H20B H -0.0015 0.8312 0.0050 0.036 Uiso 1 1 calc R . .
N2 N -0.02142(8) 0.37851(14) 0.13063(9) 0.0185(4) Uani 1 1 d . . .
N3 N -0.02862(9) 0.33381(17) 0.08781(10) 0.0271(5) Uani 1 1 d . . .
N5 N 0.10024(9) 0.62685(15) 0.27285(12) 0.0277(5) Uani 1 1 d . . .
N6 N 0.13740(10) 0.67181(19) 0.28526(17) 0.0494(8) Uani 1 1 d . . .
C21 C 0.07878(13) 0.8528(2) 0.03039(14) 0.0380(7) Uani 1 1 d . . .
H21A H 0.0835 0.8082 0.0003 0.046 Uiso 1 1 calc R . .
H21B H 0.0766 0.9152 0.0126 0.046 Uiso 1 1 calc R . .
C33 C -0.13060(16) 0.9204(2) 0.08507(18) 0.0467(9) Uani 1 1 d . . .
H33A H -0.1467 0.9694 0.0555 0.056 Uiso 1 1 calc R . .
H33B H -0.1588 0.8799 0.0890 0.056 Uiso 1 1 calc R . .
C23 C 0.12856(12) 0.7552(2) 0.11903(16) 0.0365(7) Uani 1 1 d . . .
H23A H 0.1580 0.7557 0.1575 0.044 Uiso 1 1 calc R . .
H23B H 0.1354 0.7064 0.0927 0.044 Uiso 1 1 calc R . .
C27 C -0.16126(12) 0.5908(2) -0.04366(15) 0.0347(7) Uani 1 1 d . . .
H27A H -0.1956 0.5743 -0.0398 0.042 Uiso 1 1 calc R . .
H27B H -0.1670 0.6373 -0.0763 0.042 Uiso 1 1 calc R . .
C28 C -0.13629(12) 0.5054(2) -0.06061(15) 0.0357(7) Uani 1 1 d . . .
H28A H -0.1328 0.4570 -0.0295 0.043 Uiso 1 1 calc R . .
H28B H -0.1588 0.4811 -0.1001 0.043 Uiso 1 1 calc R . .
C29 C -0.08279(11) 0.52947(19) -0.06492(13) 0.0278(6) Uani 1 1 d . . .
H29A H -0.0869 0.5735 -0.0986 0.033 Uiso 1 1 calc R . .
H29B H -0.0661 0.4730 -0.0740 0.033 Uiso 1 1 calc R . .
C22 C 0.12560(13) 0.8479(2) 0.08780(15) 0.0366(7) Uani 1 1 d . . .
H22A H 0.1580 0.8580 0.0774 0.044 Uiso 1 1 calc R . .
H22B H 0.1230 0.8974 0.1160 0.044 Uiso 1 1 calc R . .
C35 C -0.07512(16) 0.8919(2) 0.19170(15) 0.0430(8) Uani 1 1 d . . .
H35A H -0.1010 0.8510 0.2008 0.052 Uiso 1 1 calc R . .
H35B H -0.0551 0.9237 0.2296 0.052 Uiso 1 1 calc R . .
C36 C -0.03691(14) 0.8325(2) 0.16784(15) 0.0389(7) Uani 1 1 d . . .
H36A H -0.0087 0.8722 0.1630 0.047 Uiso 1 1 calc R . .
H36B H -0.0208 0.7838 0.1977 0.047 Uiso 1 1 calc R . .
C34 C -0.10313(18) 0.9625(2) 0.14445(17) 0.0495(9) Uani 1 1 d . . .
H34A H -0.1287 0.9961 0.1591 0.059 Uiso 1 1 calc R . .
H34B H -0.0774 1.0077 0.1394 0.059 Uiso 1 1 calc R . .
O1 O 0.76098(9) 1.01551(16) 0.91795(11) 0.0393(5) Uani 1 1 d . . .
C73 C 0.79819(13) 0.9528(2) 0.90739(16) 0.0385(7) Uani 1 1 d . . .
H73A H 0.8309 0.9533 0.9421 0.046 Uiso 1 1 calc R . .
H73B H 0.8064 0.9704 0.8703 0.046 Uiso 1 1 calc R . .
C74 C 0.77326(15) 0.8585(3) 0.90004(19) 0.0468(9) Uani 1 1 d . . .
H74A H 0.7548 0.8448 0.8568 0.056 Uiso 1 1 calc R . .
H74B H 0.7996 0.8100 0.9169 0.056 Uiso 1 1 calc R . .
C76 C 0.71740(14) 0.9661(2) 0.92262(17) 0.0411(8) Uani 1 1 d . . .
H76A H 0.6880 0.9703 0.8843 0.049 Uiso 1 1 calc R . .
H76B H 0.7059 0.9909 0.9560 0.049 Uiso 1 1 calc R . .
C75 C 0.73564(16) 0.8660(2) 0.9356(2) 0.0486(9) Uani 1 1 d . . .
H75A H 0.7532 0.8555 0.9794 0.058 Uiso 1 1 calc R . .
H75B H 0.7063 0.8222 0.9206 0.058 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ag1 P1 133.19(5) . . ?
N4 Ag1 N1 86.54(7) . . ?
P1 Ag1 N1 126.08(5) . . ?
N4 Ag1 N1 82.36(7) . 2 ?
P1 Ag1 N1 127.57(5) . 2 ?
N1 Ag1 N1 84.91(7) . 2 ?
N1 Ag2 P2 137.65(6) . . ?
N1 Ag2 N4 86.20(7) . . ?
P2 Ag2 N4 128.01(5) . . ?
N1 Ag2 N4 82.82(7) . 2 ?
P2 Ag2 N4 121.80(5) . 2 ?
N4 Ag2 N4 81.55(8) . 2 ?
C13 P1 C7 106.02(11) . . ?
C13 P1 C1 105.35(11) . . ?
C7 P1 C1 106.30(11) . . ?
C13 P1 Ag1 113.91(8) . . ?
C7 P1 Ag1 112.59(8) . . ?
C1 P1 Ag1 112.04(8) . . ?
C31 P2 C25 104.08(14) . . ?
C31 P2 C19 112.29(15) . . ?
C25 P2 C19 104.98(11) . . ?
C31 P2 Ag2 107.41(10) . . ?
C25 P2 Ag2 115.29(8) . . ?
C19 P2 Ag2 112.58(9) . . ?
C9 C8 C7 110.5(2) . . ?
C9 C8 H8A 109.6 . . ?
C7 C8 H8A 109.6 . . ?
C9 C8 H8B 109.6 . . ?
C7 C8 H8B 109.6 . . ?
H8A C8 H8B 108.1 . . ?
C10 C11 C12 111.2(2) . . ?
C10 C11 H11A 109.4 . . ?
C12 C11 H11A 109.4 . . ?
C10 C11 H11B 109.4 . . ?
C12 C11 H11B 109.4 . . ?
H11A C11 H11B 108.0 . . ?
C8 C7 C12 109.8(2) . . ?
C8 C7 P1 112.13(16) . . ?
C12 C7 P1 109.42(17) . . ?
C8 C7 H7 108.5 . . ?
C12 C7 H7 108.5 . . ?
P1 C7 H7 108.5 . . ?
C11 C12 C7 111.8(2) . . ?
C11 C12 H12A 109.3 . . ?
C7 C12 H12A 109.3 . . ?
C11 C12 H12B 109.3 . . ?
C7 C12 H12B 109.3 . . ?
H12A C12 H12B 107.9 . . ?
C10 C9 C8 111.1(2) . . ?
C10 C9 H9A 109.4 . . ?
C8 C9 H9A 109.4 . . ?
C10 C9 H9B 109.4 . . ?
C8 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
C9 C10 C11 109.8(2) . . ?
C9 C10 H10A 109.7 . . ?
C11 C10 H10A 109.7 . . ?
C9 C10 H10B 109.7 . . ?
C11 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
C17 C18 C13 111.2(2) . . ?
C17 C18 H18A 109.4 . . ?
C13 C18 H18A 109.4 . . ?
C17 C18 H18B 109.4 . . ?
C13 C18 H18B 109.4 . . ?
H18A C18 H18B 108.0 . . ?
C18 C13 C14 110.5(2) . . ?
C18 C13 P1 115.62(17) . . ?
C14 C13 P1 109.79(16) . . ?
C18 C13 H13 106.8 . . ?
C14 C13 H13 106.8 . . ?
P1 C13 H13 106.8 . . ?
C3 C2 C1 111.3(2) . . ?
C3 C2 H2A 109.4 . . ?
C1 C2 H2A 109.4 . . ?
C3 C2 H2B 109.4 . . ?
C1 C2 H2B 109.4 . . ?
H2A C2 H2B 108.0 . . ?
C6 C1 C2 110.8(2) . . ?
C6 C1 P1 115.21(17) . . ?
C2 C1 P1 109.95(16) . . ?
C6 C1 H1 106.8 . . ?
C2 C1 H1 106.8 . . ?
P1 C1 H1 106.8 . . ?
C1 C6 C5 111.3(2) . . ?
C1 C6 H6A 109.4 . . ?
C5 C6 H6A 109.4 . . ?
C1 C6 H6B 109.4 . . ?
C5 C6 H6B 109.4 . . ?
H6A C6 H6B 108.0 . . ?
C15 C14 C13 111.5(2) . . ?
C15 C14 H14A 109.3 . . ?
C13 C14 H14A 109.3 . . ?
C15 C14 H14B 109.3 . . ?
C13 C14 H14B 109.3 . . ?
H14A C14 H14B 108.0 . . ?
C16 C15 C14 111.9(2) . . ?
C16 C15 H15A 109.2 . . ?
C14 C15 H15A 109.2 . . ?
C16 C15 H15B 109.2 . . ?
C14 C15 H15B 109.2 . . ?
H15A C15 H15B 107.9 . . ?
C5 C4 C3 110.4(2) . . ?
C5 C4 H4A 109.6 . . ?
C3 C4 H4A 109.6 . . ?
C5 C4 H4B 109.6 . . ?
C3 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C15 C16 C17 111.1(2) . . ?
C15 C16 H16A 109.4 . . ?
C17 C16 H16A 109.4 . . ?
C15 C16 H16B 109.4 . . ?
C17 C16 H16B 109.4 . . ?
H16A C16 H16B 108.0 . . ?
C2 C3 C4 111.0(2) . . ?
C2 C3 H3A 109.4 . . ?
C4 C3 H3A 109.4 . . ?
C2 C3 H3B 109.4 . . ?
C4 C3 H3B 109.4 . . ?
H3A C3 H3B 108.0 . . ?
C4 C5 C6 111.2(2) . . ?
C4 C5 H5A 109.4 . . ?
C6 C5 H5A 109.4 . . ?
C4 C5 H5B 109.4 . . ?
C6 C5 H5B 109.4 . . ?
H5A C5 H5B 108.0 . . ?
C16 C17 C18 110.8(2) . . ?
C16 C17 H17A 109.5 . . ?
C18 C17 H17A 109.5 . . ?
C16 C17 H17B 109.5 . . ?
C18 C17 H17B 109.5 . . ?
H17A C17 H17B 108.1 . . ?
N2 N1 Ag2 118.67(16) . . ?
N2 N1 Ag1 120.19(16) . . ?
Ag2 N1 Ag1 93.15(7) . . ?
N2 N1 Ag1 125.32(16) . 2 ?
Ag2 N1 Ag1 97.47(8) . 2 ?
Ag1 N1 Ag1 94.95(7) . 2 ?
N5 N4 Ag1 119.72(17) . . ?
N5 N4 Ag2 126.78(18) . . ?
Ag1 N4 Ag2 91.98(7) . . ?
N5 N4 Ag2 116.44(19) . 2 ?
Ag1 N4 Ag2 97.23(7) . 2 ?
Ag2 N4 Ag2 98.36(8) . 2 ?
C24 C19 C20 110.8(2) . . ?
C24 C19 P2 111.09(18) . . ?
C20 C19 P2 116.72(19) . . ?
C24 C19 H19 105.8 . . ?
C20 C19 H19 105.8 . . ?
P2 C19 H19 105.8 . . ?
C29 C30 C25 112.7(2) . . ?
C29 C30 H30A 109.0 . . ?
C25 C30 H30A 109.0 . . ?
C29 C30 H30B 109.0 . . ?
C25 C30 H30B 109.0 . . ?
H30A C30 H30B 107.8 . . ?
C30 C25 C26 109.9(2) . . ?
C30 C25 P2 109.06(17) . . ?
C26 C25 P2 110.99(19) . . ?
C30 C25 H25 108.9 . . ?
C26 C25 H25 108.9 . . ?
P2 C25 H25 108.9 . . ?
C23 C24 C19 110.9(2) . . ?
C23 C24 H24A 109.5 . . ?
C19 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
C19 C24 H24B 109.5 . . ?
H24A C24 H24B 108.1 . . ?
C31 C32 C33 108.9(2) . . ?
C31 C32 H32A 109.9 . . ?
C33 C32 H32A 109.9 . . ?
C31 C32 H32B 109.9 . . ?
C33 C32 H32B 109.9 . . ?
H32A C32 H32B 108.3 . . ?
C25 C26 C27 111.7(2) . . ?
C25 C26 H26A 109.3 . . ?
C27 C26 H26A 109.3 . . ?
C25 C26 H26B 109.3 . . ?
C27 C26 H26B 109.3 . . ?
H26A C26 H26B 107.9 . . ?
C36 C31 C32 111.6(3) . . ?
C36 C31 P2 112.2(2) . . ?
C32 C31 P2 119.7(2) . . ?
C36 C31 H31 103.8 . . ?
C32 C31 H31 103.8 . . ?
P2 C31 H31 103.8 . . ?
C19 C20 C21 110.8(3) . . ?
C19 C20 H20A 109.5 . . ?
C21 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C21 C20 H20B 109.5 . . ?
H20A C20 H20B 108.1 . . ?
N3 N2 N1 179.2(3) . . ?
N6 N5 N4 179.2(4) . . ?
C22 C21 C20 111.4(2) . . ?
C22 C21 H21A 109.3 . . ?
C20 C21 H21A 109.3 . . ?
C22 C21 H21B 109.3 . . ?
C20 C21 H21B 109.3 . . ?
H21A C21 H21B 108.0 . . ?
C34 C33 C32 111.0(3) . . ?
C34 C33 H33A 109.4 . . ?
C32 C33 H33A 109.4 . . ?
C34 C33 H33B 109.4 . . ?
C32 C33 H33B 109.4 . . ?
H33A C33 H33B 108.0 . . ?
C22 C23 C24 111.6(3) . . ?
C22 C23 H23A 109.3 . . ?
C24 C23 H23A 109.3 . . ?
C22 C23 H23B 109.3 . . ?
C24 C23 H23B 109.3 . . ?
H23A C23 H23B 108.0 . . ?
C28 C27 C26 111.3(3) . . ?
C28 C27 H27A 109.4 . . ?
C26 C27 H27A 109.4 . . ?
C28 C27 H27B 109.4 . . ?
C26 C27 H27B 109.4 . . ?
H27A C27 H27B 108.0 . . ?
C29 C28 C27 109.8(2) . . ?
C29 C28 H28A 109.7 . . ?
C27 C28 H28A 109.7 . . ?
C29 C28 H28B 109.7 . . ?
C27 C28 H28B 109.7 . . ?
H28A C28 H28B 108.2 . . ?
C28 C29 C30 111.5(2) . . ?
C28 C29 H29A 109.3 . . ?
C30 C29 H29A 109.3 . . ?
C28 C29 H29B 109.3 . . ?
C30 C29 H29B 109.3 . . ?
H29A C29 H29B 108.0 . . ?
C23 C22 C21 111.3(3) . . ?
C23 C22 H22A 109.4 . . ?
C21 C22 H22A 109.4 . . ?
C23 C22 H22B 109.4 . . ?
C21 C22 H22B 109.4 . . ?
H22A C22 H22B 108.0 . . ?
C34 C35 C36 110.3(3) . . ?
C34 C35 H35A 109.6 . . ?
C36 C35 H35A 109.6 . . ?
C34 C35 H35B 109.6 . . ?
C36 C35 H35B 109.6 . . ?
H35A C35 H35B 108.1 . . ?
C31 C36 C35 109.9(3) . . ?
C31 C36 H36A 109.7 . . ?
C35 C36 H36A 109.7 . . ?
C31 C36 H36B 109.7 . . ?
C35 C36 H36B 109.7 . . ?
H36A C36 H36B 108.2 . . ?
C33 C34 C35 112.6(3) . . ?
C33 C34 H34A 109.1 . . ?
C35 C34 H34A 109.1 . . ?
C33 C34 H34B 109.1 . . ?
C35 C34 H34B 109.1 . . ?
H34A C34 H34B 107.8 . . ?
C76 O1 C73 109.8(2) . . ?
O1 C73 C74 106.4(3) . . ?
O1 C73 H73A 110.5 . . ?
C74 C73 H73A 110.5 . . ?
O1 C73 H73B 110.5 . . ?
C74 C73 H73B 110.5 . . ?
H73A C73 H73B 108.6 . . ?
C75 C74 C73 103.2(3) . . ?
C75 C74 H74A 111.1 . . ?
C73 C74 H74A 111.1 . . ?
C75 C74 H74B 111.1 . . ?
C73 C74 H74B 111.1 . . ?
H74A C74 H74B 109.1 . . ?
O1 C76 C75 105.8(3) . . ?
O1 C76 H76A 110.6 . . ?
C75 C76 H76A 110.6 . . ?
O1 C76 H76B 110.6 . . ?
C75 C76 H76B 110.6 . . ?
H76A C76 H76B 108.7 . . ?
C74 C75 C76 101.0(3) . . ?
C74 C75 H75A 111.6 . . ?
C76 C75 H75A 111.6 . . ?
C74 C75 H75B 111.6 . . ?
C76 C75 H75B 111.6 . . ?
H75A C75 H75B 109.4 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N4 2.350(2) . ?
Ag1 P1 2.3642(6) . ?
Ag1 N1 2.394(2) . ?
Ag1 N1 2.467(2) 2 ?
Ag2 N1 2.334(2) . ?
Ag2 P2 2.3676(7) . ?
Ag2 N4 2.424(2) . ?
Ag2 N4 2.461(2) 2 ?
P1 C13 1.848(2) . ?
P1 C7 1.853(2) . ?
P1 C1 1.864(2) . ?
P2 C31 1.837(3) . ?
P2 C25 1.852(3) . ?
P2 C19 1.856(3) . ?
C8 C9 1.531(4) . ?
C8 C7 1.532(3) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C11 C10 1.528(4) . ?
C11 C12 1.530(4) . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C7 C12 1.541(3) . ?
C7 H7 1.0000 . ?
C12 H12A 0.9900 . ?
C12 H12B 0.9900 . ?
C9 C10 1.525(4) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C18 C17 1.534(3) . ?
C18 C13 1.535(3) . ?
C18 H18A 0.9900 . ?
C18 H18B 0.9900 . ?
C13 C14 1.539(3) . ?
C13 H13 1.0000 . ?
C2 C3 1.528(3) . ?
C2 C1 1.537(3) . ?
C2 H2A 0.9900 . ?
C2 H2B 0.9900 . ?
C1 C6 1.533(3) . ?
C1 H1 1.0000 . ?
C6 C5 1.534(3) . ?
C6 H6A 0.9900 . ?
C6 H6B 0.9900 . ?
C14 C15 1.533(3) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.524(4) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C4 C5 1.527(4) . ?
C4 C3 1.530(4) . ?
C4 H4A 0.9900 . ?
C4 H4B 0.9900 . ?
C16 C17 1.529(4) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C3 H3A 0.9900 . ?
C3 H3B 0.9900 . ?
C5 H5A 0.9900 . ?
C5 H5B 0.9900 . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
N1 N2 1.214(3) . ?
N1 Ag1 2.467(2) 2 ?
N4 N5 1.206(3) . ?
N4 Ag2 2.461(2) 2 ?
C19 C24 1.533(4) . ?
C19 C20 1.533(4) . ?
C19 H19 1.0000 . ?
C30 C29 1.528(4) . ?
C30 C25 1.531(4) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C25 C26 1.534(4) . ?
C25 H25 1.0000 . ?
C24 C23 1.531(4) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
C32 C31 1.537(4) . ?
C32 C33 1.555(4) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C26 C27 1.535(4) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C31 C36 1.478(5) . ?
C31 H31 1.0000 . ?
C20 C21 1.533(4) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
N2 N3 1.152(3) . ?
N5 N6 1.155(3) . ?
C21 C22 1.522(5) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C33 C34 1.476(5) . ?
C33 H33A 0.9900 . ?
C33 H33B 0.9900 . ?
C23 C22 1.519(5) . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
C27 C28 1.522(5) . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 C29 1.521(4) . ?
C28 H28A 0.9900 . ?
C28 H28B 0.9900 . ?
C29 H29A 0.9900 . ?
C29 H29B 0.9900 . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C35 C34 1.518(5) . ?
C35 C36 1.574(5) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9900 . ?
C36 H36B 0.9900 . ?
C34 H34A 0.9900 . ?
C34 H34B 0.9900 . ?
O1 C76 1.412(4) . ?
O1 C73 1.434(4) . ?
C73 C74 1.511(5) . ?
C73 H73A 0.9900 . ?
C73 H73B 0.9900 . ?
C74 C75 1.504(5) . ?
C74 H74A 0.9900 . ?
C74 H74B 0.9900 . ?
C76 C75 1.534(5) . ?
C76 H76A 0.9900 . ?
C76 H76B 0.9900 . ?
C75 H75A 0.9900 . ?
C75 H75B 0.9900 . ?
