#------------------------------------------------------------------------------
#$Date: 2016-03-22 23:46:46 +0200 (Tue, 22 Mar 2016) $
#$Revision: 179077 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/39/4303951.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4303951
loop_
_publ_author_name
'Taro Tsubomura'
'Yasuhiro Ito'
'Satoshi Inoue'
'Yu Tanaka'
'Kenji Matsumoto'
'Toshiaki Tsukuda'
_publ_section_title
;
Strongly Luminescent Palladium(0) and Platinum(0) Diphosphine Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              481
_journal_page_last               486
_journal_paper_doi               10.1021/ic700475z
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         'C72 H56 P4 Pd (C7 H8)3'
_chemical_formula_sum            'C93 H77 P4 Pt'
_chemical_formula_weight         1513.61
_chemical_name_common            '[Pt(biphep)2] (C6H5CH3)3'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.870(17)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.818(8)
_cell_length_b                   14.219(3)
_cell_length_c                   26.677(2)
_cell_measurement_reflns_used    24
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      12.4
_cell_measurement_theta_min      10.0
_cell_volume                     7447(3)
_computing_cell_refinement       teXsan
_computing_data_collection       teXsan
_computing_data_reduction        teXsan
_computing_molecular_graphics    ortepIII
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      295(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  AFC-5S
_diffrn_measurement_method       'profile data from θ/2θ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0821
_diffrn_reflns_av_sigmaI/netI    0.1936
_diffrn_reflns_limit_h_max       0
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            6760
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.75
_diffrn_standards_decay_%        1.5
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.017
_exptl_absorpt_correction_T_max  0.91
_exptl_absorpt_correction_T_min  0.68
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.346
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3072
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.039
_refine_diff_density_min         -1.157
_refine_diff_density_rms         0.151
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     456
_refine_ls_number_reflns         6556
_refine_ls_number_restraints     11
_refine_ls_restrained_S_all      1.325
_refine_ls_R_factor_all          0.1617
_refine_ls_R_factor_gt           0.0782
_refine_ls_shift/su_max          0.013
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0500P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1313
_refine_ls_wR_factor_ref         0.1618
_reflns_number_gt                3779
_reflns_number_total             6556
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic700475z-file003.cif
_cod_data_source_block           ptbiphep
_cod_original_cell_volume        7446(3)
_cod_database_code               4303951
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.0000 -0.04983(6) 0.7500 0.0326(3) Uani 1 2 d S . .
P1 P -0.05077(18) 0.0309(3) 0.81076(13) 0.0359(10) Uani 1 1 d . . .
P2 P 0.07539(19) -0.1311(3) 0.80912(13) 0.0350(10) Uani 1 1 d . . .
C1 C 0.0105(7) 0.0656(10) 0.8667(5) 0.036(4) Uani 1 1 d . . .
C2 C 0.0318(8) 0.1590(11) 0.8712(5) 0.044(4) Uani 1 1 d . . .
H2 H 0.0129 0.2031 0.8476 0.053 Uiso 1 1 calc R . .
C3 C 0.0812(9) 0.1871(12) 0.9106(6) 0.060(5) Uani 1 1 d . . .
H3 H 0.0951 0.2496 0.9129 0.072 Uiso 1 1 calc R . .
C4 C 0.1092(8) 0.1239(13) 0.9459(6) 0.055(5) Uani 1 1 d . . .
H4 H 0.1420 0.1422 0.9724 0.065 Uiso 1 1 calc R . .
C5 C 0.0873(8) 0.0322(11) 0.9411(5) 0.049(4) Uani 1 1 d . . .
H5 H 0.1056 -0.0104 0.9658 0.058 Uiso 1 1 calc R . .
C6 C 0.0398(8) -0.0015(12) 0.9019(5) 0.043(4) Uani 1 1 d . . .
C7 C 0.0382(7) -0.1677(10) 0.8659(5) 0.033(4) Uani 1 1 d . . .
C8 C 0.0188(8) -0.2629(11) 0.8708(6) 0.046(4) Uani 1 1 d . . .
H8 H 0.0285 -0.3067 0.8469 0.055 Uiso 1 1 calc R . .
C9 C -0.0141(8) -0.2915(12) 0.9105(6) 0.056(5) Uani 1 1 d . . .
H9 H -0.0274 -0.3540 0.9126 0.067 Uiso 1 1 calc R . .
C10 C -0.0272(8) -0.2281(12) 0.9470(6) 0.059(5) Uani 1 1 d . . .
H10 H -0.0488 -0.2470 0.9741 0.071 Uiso 1 1 calc R . .
C11 C -0.0077(8) -0.1362(11) 0.9422(5) 0.049(4) Uani 1 1 d . . .
H11 H -0.0150 -0.0942 0.9676 0.059 Uiso 1 1 calc R . .
C12 C 0.0222(8) -0.1023(11) 0.9018(5) 0.039(4) Uani 1 1 d . . .
C13 C -0.0930(7) 0.1440(12) 0.7949(6) 0.050(4) Uani 1 1 d . . .
C14 C -0.1315(9) 0.1934(14) 0.8254(7) 0.074(6) Uani 1 1 d . . .
H14 H -0.1351 0.1702 0.8576 0.088 Uiso 1 1 calc R . .
C15 C -0.1644(9) 0.2748(15) 0.8103(8) 0.079(6) Uani 1 1 d . . .
H15 H -0.1893 0.3064 0.8321 0.095 Uiso 1 1 calc R . .
C16 C -0.1610(11) 0.3100(14) 0.7633(9) 0.091(7) Uani 1 1 d . . .
H16 H -0.1851 0.3639 0.7524 0.110 Uiso 1 1 calc R . .
C17 C -0.1218(11) 0.2653(13) 0.7325(8) 0.089(7) Uani 1 1 d . . .
H17 H -0.1164 0.2916 0.7013 0.106 Uiso 1 1 calc R . .
C18 C -0.0902(8) 0.1822(11) 0.7469(6) 0.053(5) Uani 1 1 d . . .
H18 H -0.0664 0.1505 0.7243 0.064 Uiso 1 1 calc R . .
C19 C -0.1171(7) -0.0279(9) 0.8420(5) 0.035(4) Uani 1 1 d . . .
C20 C -0.1551(8) -0.0976(11) 0.8177(6) 0.048(4) Uani 1 1 d . . .
H20 H -0.1481 -0.1137 0.7851 0.057 Uiso 1 1 calc R . .
C21 C -0.2046(9) -0.1464(14) 0.8402(7) 0.078(6) Uani 1 1 d . . .
H21 H -0.2286 -0.1959 0.8234 0.094 Uiso 1 1 calc R . .
C22 C -0.2170(9) -0.1202(14) 0.8867(7) 0.067(5) Uani 1 1 d . . .
H22 H -0.2509 -0.1506 0.9015 0.081 Uiso 1 1 calc R . .
C23 C -0.1806(8) -0.0504(14) 0.9123(5) 0.061(5) Uani 1 1 d . . .
H23 H -0.1896 -0.0329 0.9444 0.074 Uiso 1 1 calc R . .
C24 C -0.1301(8) -0.0052(12) 0.8905(5) 0.053(4) Uani 1 1 d . . .
H24 H -0.1043 0.0414 0.9086 0.063 Uiso 1 1 calc R . .
C25 C 0.1543(7) -0.0718(9) 0.8396(5) 0.036(4) Uani 1 1 d . . .
C26 C 0.1794(9) 0.0032(11) 0.8162(6) 0.056(5) Uani 1 1 d . . .
H26 H 0.1572 0.0217 0.7848 0.067 Uiso 1 1 calc R . .
C27 C 0.2355(8) 0.0521(14) 0.8368(6) 0.075(6) Uani 1 1 d . . .
H27 H 0.2506 0.1033 0.8197 0.090 Uiso 1 1 calc R . .
C28 C 0.2701(9) 0.0254(14) 0.8831(7) 0.072(6) Uani 1 1 d . . .
H28 H 0.3087 0.0579 0.8975 0.087 Uiso 1 1 calc R . .
C29 C 0.2464(8) -0.0492(14) 0.9071(6) 0.065(5) Uani 1 1 d . . .
H29 H 0.2696 -0.0686 0.9380 0.078 Uiso 1 1 calc R . .
C30 C 0.1880(8) -0.0974(10) 0.8862(5) 0.044(4) Uani 1 1 d . . .
H30 H 0.1717 -0.1470 0.9038 0.053 Uiso 1 1 calc R . .
C31 C 0.1130(7) -0.2418(11) 0.7911(5) 0.046(4) Uani 1 1 d . . .
C32 C 0.1605(8) -0.2939(12) 0.8220(6) 0.056(5) Uani 1 1 d . . .
H32 H 0.1744 -0.2728 0.8548 0.068 Uiso 1 1 calc R . .
C33 C 0.1881(10) -0.3756(14) 0.8063(8) 0.078(6) Uani 1 1 d . . .
H33 H 0.2224 -0.4070 0.8271 0.094 Uiso 1 1 calc R . .
C34 C 0.1632(10) -0.4107(13) 0.7581(9) 0.082(7) Uani 1 1 d . . .
H34 H 0.1806 -0.4668 0.7473 0.099 Uiso 1 1 calc R . .
C35 C 0.1145(11) -0.3646(15) 0.7269(8) 0.091(7) Uani 1 1 d . . .
H35 H 0.0978 -0.3889 0.6953 0.110 Uiso 1 1 calc R . .
C36 C 0.0898(10) -0.2790(12) 0.7436(6) 0.071(6) Uani 1 1 d . . .
H36 H 0.0570 -0.2462 0.7222 0.085 Uiso 1 1 calc R . .
C37 C 0.1201(18) 0.446(2) 0.9799(13) 0.202(14) Uani 1 1 d . . .
H37A H 0.0983 0.4266 1.0082 0.303 Uiso 1 1 calc R . .
H37B H 0.1385 0.5079 0.9859 0.303 Uiso 1 1 calc R . .
H37C H 0.1562 0.4028 0.9757 0.303 Uiso 1 1 calc R . .
C38 C 0.0740(15) 0.446(2) 0.9375(9) 0.144(14) Uani 1 1 d D . .
C39 C 0.0926(12) 0.4719(14) 0.8913(9) 0.090(7) Uani 1 1 d D . .
H39 H 0.1361 0.4920 0.8872 0.107 Uiso 1 1 calc R . .
C40 C 0.0413(16) 0.465(2) 0.8530(9) 0.131(11) Uani 1 1 d D . .
H40 H 0.0546 0.4943 0.8247 0.158 Uiso 1 1 calc R . .
C41 C -0.022(2) 0.431(5) 0.840(2) 0.52(8) Uani 1 1 d D . .
H41 H -0.0490 0.4183 0.8099 0.627 Uiso 1 1 calc R . .
C42 C -0.0293(18) 0.423(4) 0.890(2) 0.25(3) Uani 1 1 d D . .
H42 H -0.0756 0.4198 0.8924 0.297 Uiso 1 1 calc R . .
C43 C 0.0073(14) 0.4188(14) 0.9393(12) 0.103(10) Uani 1 1 d D . .
H43 H -0.0105 0.4004 0.9683 0.123 Uiso 1 1 calc R . .
C44 C 0.229(2) 0.3032(16) 0.4684(8) 0.109(11) Uani 1 1 d D . .
C45 C 0.348(2) 0.265(3) 0.4785(19) 0.20(3) Uani 1 1 d D . .
C46 C 0.294(3) 0.319(4) 0.458(2) 0.26(7) Uani 0.50 1 d PD . .
C47 C 0.2850(18) 0.258(3) 0.4917(18) 0.086(15) Uani 0.50 1 d PD . .
C48 C 0.164(3) 0.298(5) 0.479(3) 0.15(4) Uani 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Pt1 P1 120.80(19) . 2_556 ?
P1 Pt1 P2 114.78(13) . 2_556 ?
P1 Pt1 P2 94.12(12) 2_556 2_556 ?
P1 Pt1 P2 94.12(12) . . ?
P1 Pt1 P2 114.78(13) 2_556 . ?
P2 Pt1 P2 120.40(19) 2_556 . ?
C13 P1 C19 99.8(7) . . ?
C13 P1 C1 100.4(6) . . ?
C19 P1 C1 100.7(6) . . ?
C13 P1 Pt1 119.9(5) . . ?
C19 P1 Pt1 119.5(5) . . ?
C1 P1 Pt1 113.1(4) . . ?
C31 P2 C7 101.3(6) . . ?
C31 P2 C25 99.0(7) . . ?
C7 P2 C25 100.1(6) . . ?
C31 P2 Pt1 119.7(5) . . ?
C7 P2 Pt1 113.9(4) . . ?
C25 P2 Pt1 119.6(4) . . ?
C2 C1 C6 119.8(14) . . ?
C2 C1 P1 118.7(11) . . ?
C6 C1 P1 121.4(11) . . ?
C1 C2 C3 120.8(15) . . ?
C4 C3 C2 120.6(16) . . ?
C3 C4 C5 117.9(15) . . ?
C4 C5 C6 124.6(15) . . ?
C5 C6 C1 116.2(15) . . ?
C5 C6 C12 118.1(15) . . ?
C1 C6 C12 125.6(15) . . ?
C12 C7 C8 118.7(13) . . ?
C12 C7 P2 121.7(11) . . ?
C8 C7 P2 119.3(11) . . ?
C9 C8 C7 121.1(15) . . ?
C8 C9 C10 120.2(16) . . ?
C11 C10 C9 118.3(15) . . ?
C10 C11 C12 124.0(15) . . ?
C11 C12 C7 117.5(14) . . ?
C11 C12 C6 117.6(14) . . ?
C7 C12 C6 124.8(14) . . ?
C14 C13 C18 115.9(16) . . ?
C14 C13 P1 125.4(14) . . ?
C18 C13 P1 118.6(12) . . ?
C15 C14 C13 122.4(19) . . ?
C16 C15 C14 120.3(19) . . ?
C15 C16 C17 119(2) . . ?
C16 C17 C18 121(2) . . ?
C17 C18 C13 121.3(18) . . ?
C20 C19 C24 117.0(14) . . ?
C20 C19 P1 119.8(11) . . ?
C24 C19 P1 123.2(12) . . ?
C19 C20 C21 122.2(15) . . ?
C22 C21 C20 118.9(17) . . ?
C21 C22 C23 121.0(16) . . ?
C22 C23 C24 119.5(15) . . ?
C23 C24 C19 121.4(15) . . ?
C26 C25 C30 117.3(14) . . ?
C26 C25 P2 119.4(11) . . ?
C30 C25 P2 123.3(11) . . ?
C27 C26 C25 122.9(14) . . ?
C26 C27 C28 119.9(16) . . ?
C29 C28 C27 118.4(16) . . ?
C28 C29 C30 121.2(15) . . ?
C25 C30 C29 120.3(15) . . ?
C32 C31 C36 117.0(16) . . ?
C32 C31 P2 124.9(12) . . ?
C36 C31 P2 118.0(12) . . ?
C33 C32 C31 122.6(17) . . ?
C32 C33 C34 118.4(18) . . ?
C35 C34 C33 121.5(18) . . ?
C34 C35 C36 118.3(19) . . ?
C31 C36 C35 122.1(18) . . ?
C37 C38 C39 121(3) . . ?
C37 C38 C43 120(3) . . ?
C39 C38 C43 119(2) . . ?
C40 C39 C38 113(2) . . ?
C41 C40 C39 143(4) . . ?
C41 C40 C42 45.2(19) . . ?
C39 C40 C42 99(2) . . ?
C40 C41 C42 90(4) . . ?
C41 C42 C43 143(4) . . ?
C41 C42 C40 44(2) . . ?
C43 C42 C40 100(2) . . ?
C38 C43 C42 109(3) . . ?
C47 C44 C46 56(4) . . ?
C47 C44 C48 128(4) . . ?
C46 C44 C48 174(5) . . ?
C47 C44 C47 67(3) . 7_556 ?
C46 C44 C47 122(4) . 7_556 ?
C48 C44 C47 62(4) . 7_556 ?
C47 C45 C46 56(4) . . ?
C47 C45 C48 61(3) . 7_556 ?
C46 C45 C48 116(4) . 7_556 ?
C47 C46 C44 62(2) . . ?
C47 C46 C45 61(2) . . ?
C44 C46 C45 123(5) . . ?
C46 C47 C45 63(2) . . ?
C46 C47 C44 63(2) . . ?
C45 C47 C44 125(4) . . ?
C46 C47 C48 127(4) . 7_556 ?
C45 C47 C48 65(3) . 7_556 ?
C44 C47 C48 170(4) . 7_556 ?
C46 C47 C44 174(4) . 7_556 ?
C45 C47 C44 121(4) . 7_556 ?
C44 C47 C44 113(3) . 7_556 ?
C48 C47 C44 57(2) 7_556 7_556 ?
C46 C47 C47 122(4) . 7_556 ?
C45 C47 C47 175(5) . 7_556 ?
C44 C47 C47 59(2) . 7_556 ?
C48 C47 C47 111(4) 7_556 7_556 ?
C44 C47 C47 54(3) 7_556 7_556 ?
C44 C48 C47 62(3) . 7_556 ?
C44 C48 C45 116(6) . 7_556 ?
C47 C48 C45 55(3) 7_556 7_556 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 P1 2.325(4) . ?
Pt1 P1 2.325(4) 2_556 ?
Pt1 P2 2.326(4) 2_556 ?
Pt1 P2 2.326(4) . ?
P1 C13 1.835(17) . ?
P1 C19 1.851(14) . ?
P1 C1 1.857(14) . ?
P2 C31 1.834(16) . ?
P2 C7 1.848(13) . ?
P2 C25 1.863(14) . ?
C1 C2 1.393(19) . ?
C1 C6 1.408(19) . ?
C2 C3 1.394(19) . ?
C3 C4 1.36(2) . ?
C4 C5 1.37(2) . ?
C5 C6 1.393(19) . ?
C6 C12 1.475(19) . ?
C7 C12 1.402(18) . ?
C7 C8 1.417(19) . ?
C8 C9 1.378(19) . ?
C9 C10 1.38(2) . ?
C10 C11 1.37(2) . ?
C11 C12 1.386(18) . ?
C13 C14 1.38(2) . ?
C13 C18 1.40(2) . ?
C14 C15 1.36(2) . ?
C15 C16 1.36(3) . ?
C16 C17 1.36(3) . ?
C17 C18 1.37(2) . ?
C19 C20 1.355(18) . ?
C19 C24 1.390(18) . ?
C20 C21 1.40(2) . ?
C21 C22 1.35(2) . ?
C22 C23 1.36(2) . ?
C23 C24 1.38(2) . ?
C25 C26 1.363(18) . ?
C25 C30 1.377(17) . ?
C26 C27 1.363(19) . ?
C27 C28 1.38(2) . ?
C28 C29 1.36(2) . ?
C29 C30 1.39(2) . ?
C31 C32 1.380(18) . ?
C31 C36 1.391(19) . ?
C32 C33 1.37(2) . ?
C33 C34 1.41(2) . ?
C34 C35 1.35(2) . ?
C35 C36 1.41(2) . ?
C37 C38 1.35(3) . ?
C38 C39 1.38(2) . ?
C38 C43 1.39(2) . ?
C39 C40 1.34(2) . ?
C40 C41 1.34(3) . ?
C40 C42 1.91(5) . ?
C41 C42 1.36(3) . ?
C42 C43 1.42(4) . ?
C44 C47 1.35(2) . ?
C44 C46 1.36(3) . ?
C44 C48 1.36(3) . ?
C44 C47 1.44(5) 7_556 ?
C45 C47 1.34(2) . ?
C45 C46 1.36(3) . ?
C45 C48 1.49(8) 7_556 ?
C46 C47 1.27(8) . ?
C47 C48 1.43(8) 7_556 ?
C47 C44 1.44(5) 7_556 ?
C47 C47 1.53(8) 7_556 ?
C48 C47 1.43(8) 7_556 ?
C48 C45 1.49(8) 7_556 ?
