#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:01:45 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179089 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/51/4305119.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4305119
loop_
_publ_author_name
'H. V. Rasika Dias'
'Shreeyukta Singh'
'Charles F. Campana'
_publ_contact_author_address
;Department of Chemistry and Biochemistry
The University of Texas at Arlington
Arlington, Texas 76019-0065, USA
;
_publ_contact_author_email       dias@uta.edu
_publ_contact_author_fax         817-272-3808
_publ_contact_author_name        'Prof. H. V. R. Dias'
_publ_contact_author_phone       817-272-3813
_publ_section_title
;
Toluene-Sandwiched Trinuclear Copper(I) and Silver(I) Triazolates and
Phosphine Adducts of Dinuclear Copper(I) and Silver(I) Triazolates
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3943
_journal_page_last               3945
_journal_paper_doi               10.1021/ic800396t
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C52 H30 Ag2 F28 N6 P2'
_chemical_formula_weight         1548.50
_chemical_name_common            '[(3,5-(C3F7)2Tz)AgPPh3]2'
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.550(1)
_cell_angle_beta                 100.380(1)
_cell_angle_gamma                107.485(1)
_cell_formula_units_Z            2
_cell_length_a                   12.6918(5)
_cell_length_b                   14.1546(6)
_cell_length_c                   17.2029(7)
_cell_measurement_reflns_used    7862
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.30
_cell_measurement_theta_min      2.20
_cell_volume                     2842.2(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0240
_diffrn_reflns_av_sigmaI/netI    0.0342
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            21406
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.73
_exptl_absorpt_coefficient_mu    0.881
_exptl_absorpt_correction_T_max  0.9656
_exptl_absorpt_correction_T_min  0.8647
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.809
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rods
_exptl_crystal_F_000             1520
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.190
_refine_diff_density_min         -0.898
_refine_diff_density_rms         0.106
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.028
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     897
_refine_ls_number_reflns         9966
_refine_ls_number_restraints     1457
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.0575
_refine_ls_R_factor_gt           0.0493
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0692P)²+8.6596P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1254
_refine_ls_wR_factor_ref         0.1328
_reflns_number_gt                8503
_reflns_number_total             9966
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic800396t-file003_1.cif
_cod_data_source_block           cfc99s
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4305119
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.00061(3) 0.79360(3) 0.28990(2) 0.02725(12) Uani 1 1 d U . .
Ag2 Ag 0.72711(3) 0.78115(3) 0.26484(2) 0.03228(13) Uani 1 1 d U . .
P1 P 1.12679(10) 0.89121(10) 0.22349(7) 0.0256(3) Uani 1 1 d U . .
C1 C 1.2735(4) 0.9435(4) 0.2811(3) 0.0311(11) Uani 1 1 d U . .
C2 C 1.3098(5) 0.8902(5) 0.3360(3) 0.0383(12) Uani 1 1 d U . .
H2A H 1.2576 0.8299 0.3433 0.035(15) Uiso 1 1 calc R . .
C3 C 1.4208(5) 0.9230(6) 0.3803(4) 0.0509(15) Uani 1 1 d U . .
H3 H 1.4447 0.8860 0.4181 0.09(3) Uiso 1 1 calc R . .
C4 C 1.4967(5) 1.0102(6) 0.3690(4) 0.0555(17) Uani 1 1 d U . .
H4 H 1.5736 1.0325 0.3984 0.026(13) Uiso 1 1 calc R . .
C5 C 1.4621(5) 1.0650(5) 0.3159(4) 0.0514(16) Uani 1 1 d U . .
H5 H 1.5150 1.1252 0.3090 0.08(3) Uiso 1 1 calc R . .
C6 C 1.3500(5) 1.0330(4) 0.2718(3) 0.0392(13) Uani 1 1 d U . .
H6 H 1.3259 1.0718 0.2357 0.040(16) Uiso 1 1 calc R . .
C7 C 1.1331(4) 0.8325(4) 0.1242(3) 0.0268(10) Uani 1 1 d U . .
C8 C 1.0421(4) 0.7487(4) 0.0807(3) 0.0335(11) Uani 1 1 d U . .
H8 H 0.9790 0.7221 0.1032 0.018(12) Uiso 1 1 calc R . .
C9 C 1.0435(5) 0.7037(4) 0.0040(3) 0.0369(12) Uani 1 1 d U . .
H9 H 0.9816 0.6461 -0.0253 0.037(15) Uiso 1 1 calc R . .
C10 C 1.1347(5) 0.7424(4) -0.0296(3) 0.0345(12) Uani 1 1 d U . .
H10 H 1.1359 0.7109 -0.0816 0.032(14) Uiso 1 1 calc R . .
C11 C 1.2243(4) 0.8275(4) 0.0130(3) 0.0310(11) Uani 1 1 d U . .
H11 H 1.2863 0.8551 -0.0102 0.030(14) Uiso 1 1 calc R . .
C12 C 1.2236(4) 0.8722(4) 0.0894(3) 0.0283(10) Uani 1 1 d U . .
H12 H 1.2852 0.9304 0.1183 0.035(15) Uiso 1 1 calc R . .
C13 C 1.0817(4) 0.9985(4) 0.2053(3) 0.0292(10) Uani 1 1 d U . .
C14 C 1.0990(5) 1.0747(4) 0.2706(3) 0.0406(13) Uani 1 1 d U . .
H14 H 1.1380 1.0723 0.3225 0.040(16) Uiso 1 1 calc R . .
C15 C 1.0594(6) 1.1538(5) 0.2600(4) 0.0474(15) Uani 1 1 d U . .
H15 H 1.0719 1.2061 0.3048 0.052(18) Uiso 1 1 calc R . .
C16 C 1.0019(5) 1.1578(4) 0.1851(3) 0.0400(13) Uani 1 1 d U . .
H16 H 0.9764 1.2134 0.1781 0.042(16) Uiso 1 1 calc R . .
C17 C 0.9815(5) 1.0809(4) 0.1204(3) 0.0368(12) Uani 1 1 d U . .
H17 H 0.9403 1.0825 0.0690 0.050(18) Uiso 1 1 calc R . .
C18 C 1.0214(4) 1.0011(4) 0.1307(3) 0.0322(11) Uani 1 1 d U . .
H18 H 1.0072 0.9480 0.0862 0.030(14) Uiso 1 1 calc R . .
P2 P 0.63279(10) 0.82897(10) 0.15411(7) 0.0267(3) Uani 1 1 d U . .
C19 C 0.6876(4) 0.8065(4) 0.0653(3) 0.0288(10) Uani 1 1 d U . .
C20 C 0.7157(4) 0.8774(4) 0.0178(3) 0.0323(11) Uani 1 1 d U . .
H20 H 0.7065 0.9413 0.0309 0.040(16) Uiso 1 1 calc R . .
C21 C 0.7576(5) 0.8550(5) -0.0494(3) 0.0411(13) Uani 1 1 d U . .
H21 H 0.7763 0.9036 -0.0823 0.06(2) Uiso 1 1 calc R . .
C22 C 0.7719(5) 0.7631(5) -0.0683(3) 0.0446(14) Uani 1 1 d U . .
H22 H 0.8009 0.7486 -0.1139 0.052(18) Uiso 1 1 calc R . .
C23 C 0.7443(5) 0.6919(5) -0.0213(4) 0.0438(13) Uani 1 1 d U . .
H23 H 0.7529 0.6279 -0.0352 0.053(19) Uiso 1 1 calc R . .
C24 C 0.7039(5) 0.7135(4) 0.0460(3) 0.0353(12) Uani 1 1 d U . .
H24 H 0.6872 0.6650 0.0793 0.030(14) Uiso 1 1 calc R . .
C25 C 0.6300(4) 0.9576(4) 0.1615(3) 0.0271(10) Uani 1 1 d U . .
C26 C 0.5423(4) 0.9800(4) 0.1144(3) 0.0324(11) Uani 1 1 d U . .
H26 H 0.4797 0.9269 0.0800 0.044(17) Uiso 1 1 calc R . .
C27 C 0.5462(5) 1.0788(4) 0.1178(3) 0.0368(12) Uani 1 1 d U . .
H27A H 0.4857 1.0934 0.0861 0.045(17) Uiso 1 1 calc R . .
C28 C 0.6376(5) 1.1571(4) 0.1671(3) 0.0390(12) Uani 1 1 d U . .
H28 H 0.6403 1.2252 0.1688 0.044(17) Uiso 1 1 calc R . .
C29 C 0.7250(5) 1.1356(4) 0.2139(3) 0.0412(13) Uani 1 1 d U . .
H29 H 0.7878 1.1890 0.2479 0.043(16) Uiso 1 1 calc R . .
C30 C 0.7209(5) 1.0359(4) 0.2113(3) 0.0346(11) Uani 1 1 d U . .
H30 H 0.7807 1.0215 0.2439 0.033(14) Uiso 1 1 calc R . .
C31 C 0.4848(4) 0.7477(4) 0.1260(3) 0.0302(10) Uani 1 1 d U . .
C32 C 0.4250(5) 0.7410(5) 0.1873(4) 0.0429(13) Uani 1 1 d U . .
H32 H 0.4603 0.7810 0.2397 0.048(18) Uiso 1 1 calc R . .
C33 C 0.3146(5) 0.6758(5) 0.1711(5) 0.0513(15) Uani 1 1 d U . .
H33 H 0.2739 0.6719 0.2125 0.07(2) Uiso 1 1 calc R . .
C34 C 0.2633(5) 0.6167(4) 0.0960(5) 0.0528(16) Uani 1 1 d U . .
H34 H 0.1879 0.5709 0.0859 0.055(19) Uiso 1 1 calc R . .
C35 C 0.3207(5) 0.6235(4) 0.0352(4) 0.0483(15) Uani 1 1 d U . .
H35 H 0.2844 0.5834 -0.0171 0.031(14) Uiso 1 1 calc R . .
C36 C 0.4319(4) 0.6891(4) 0.0499(3) 0.0364(12) Uani 1 1 d U . .
H36 H 0.4714 0.6936 0.0079 0.030(14) Uiso 1 1 calc R . .
N1 N 0.9391(4) 0.8274(3) 0.4021(2) 0.0304(9) Uani 1 1 d U . .
N2 N 0.8255(4) 0.8131(3) 0.3897(2) 0.0318(9) Uani 1 1 d U . .
C37 C 0.9769(5) 0.8479(4) 0.4820(3) 0.0359(12) Uani 1 1 d U . .
N3 N 0.8965(4) 0.8472(4) 0.5235(3) 0.0395(11) Uani 1 1 d U . .
C38 C 0.8055(5) 0.8264(4) 0.4628(3) 0.0348(11) Uani 1 1 d U . .
C41 C 1.0979(5) 0.8656(5) 0.5209(3) 0.0502(15) Uani 1 1 d DU . .
F1 F 1.1673(3) 0.9104(3) 0.4765(2) 0.0575(10) Uani 1 1 d DU . .
F2 F 1.1290(4) 0.9317(5) 0.5923(3) 0.104(2) Uani 1 1 d DU . .
C42 C 1.1251(6) 0.7801(6) 0.5473(6) 0.088(2) Uani 1 1 d DU . .
F3 F 1.0695(5) 0.7457(6) 0.6136(3) 0.115(2) Uani 1 1 d DU . .
F4 F 1.2411(4) 0.8046(4) 0.5731(4) 0.1023(18) Uani 1 1 d DU . .
C43 C 1.0887(8) 0.6864(7) 0.4940(6) 0.099(3) Uani 1 1 d DU . .
F5 F 1.1280(4) 0.7134(4) 0.4273(3) 0.0793(13) Uani 1 1 d DU . .
F6 F 0.9748(5) 0.6438(3) 0.4774(4) 0.108(2) Uani 1 1 d DU . .
F7 F 1.1243(5) 0.6143(4) 0.5266(4) 0.108(2) Uani 1 1 d DU . .
C44 C 0.6887(5) 0.8132(4) 0.4747(3) 0.0399(12) Uani 1 1 d DU . .
F8 F 0.6231(4) 0.8229(5) 0.4077(3) 0.0927(18) Uani 1 1 d DU . .
F9 F 0.6901(4) 0.8857(3) 0.5350(3) 0.0723(13) Uani 1 1 d DU . .
C45 C 0.6290(6) 0.7124(5) 0.4936(4) 0.0606(17) Uani 1 1 d DU . .
F10 F 0.6810(4) 0.7134(5) 0.5708(4) 0.109(2) Uani 1 1 d DU . .
F11 F 0.6469(4) 0.6404(3) 0.4449(5) 0.126(3) Uani 1 1 d DU . .
C46 C 0.5034(6) 0.6820(5) 0.4886(5) 0.073(2) Uani 1 1 d DU . .
F12 F 0.4645(5) 0.5970(4) 0.5136(6) 0.149(3) Uani 1 1 d DU . .
F13 F 0.4455(4) 0.6693(6) 0.4139(3) 0.128(2) Uani 1 1 d DU . .
F14 F 0.4779(4) 0.7514(4) 0.5320(3) 0.0881(16) Uani 1 1 d DU . .
N4 N 0.8712(3) 0.6353(3) 0.2454(2) 0.0309(9) Uani 1 1 d U A .
N5 N 0.7585(4) 0.6225(3) 0.2353(3) 0.0368(10) Uani 1 1 d U A .
C39 C 0.8756(5) 0.5447(4) 0.2190(3) 0.0349(11) Uani 1 1 d U . .
N6 N 0.7746(4) 0.4710(4) 0.1930(3) 0.0411(11) Uani 1 1 d U A .
C40 C 0.7062(5) 0.5247(4) 0.2037(4) 0.0408(12) Uani 1 1 d U . .
C47 C 0.9847(5) 0.5247(4) 0.2204(4) 0.0515(14) Uani 0.564(6) 1 d PDU A 1
F15 F 0.9831(18) 0.4913(9) 0.1410(6) 0.062(3) Uani 0.564(6) 1 d PDU A 1
F16 F 1.0662(15) 0.6201(10) 0.2406(16) 0.047(3) Uani 0.564(6) 1 d PDU A 1
C48 C 1.0185(10) 0.4594(9) 0.2720(7) 0.058(2) Uani 0.564(6) 1 d PDU A 1
F17 F 0.9418(11) 0.3656(7) 0.2402(6) 0.051(2) Uani 0.564(6) 1 d PDU A 1
F18 F 1.0034(11) 0.4911(9) 0.3465(7) 0.0549(19) Uani 0.564(6) 1 d PDU A 1
C49 C 1.1371(9) 0.4579(8) 0.2790(8) 0.060(3) Uani 0.564(6) 1 d PDU A 1
F19 F 1.1540(8) 0.4282(7) 0.2061(6) 0.080(2) Uani 0.564(6) 1 d PDU A 1
F20 F 1.2150(8) 0.5462(7) 0.3134(7) 0.072(3) Uani 0.564(6) 1 d PDU A 1
F21 F 1.1512(7) 0.3922(6) 0.3248(7) 0.075(2) Uani 0.564(6) 1 d PDU A 1
C47' C 0.9847(5) 0.5247(4) 0.2204(4) 0.0515(14) Uani 0.436(6) 1 d PDU A 2
F15' F 0.990(2) 0.4628(13) 0.1545(9) 0.062(3) Uani 0.436(6) 1 d PDU A 2
F16' F 1.080(2) 0.6100(14) 0.233(2) 0.047(3) Uani 0.436(6) 1 d PDU A 2
C48' C 1.0114(12) 0.4708(12) 0.2902(9) 0.058(2) Uani 0.436(6) 1 d PDU A 2
F17' F 0.9407(15) 0.3705(10) 0.2731(8) 0.051(2) Uani 0.436(6) 1 d PDU A 2
F18' F 0.9836(16) 0.5127(12) 0.3582(9) 0.0549(19) Uani 0.436(6) 1 d PDU A 2
C49' C 1.1264(11) 0.4641(10) 0.3229(9) 0.060(3) Uani 0.436(6) 1 d PDU A 2
F19' F 1.1632(11) 0.4270(10) 0.2610(9) 0.080(2) Uani 0.436(6) 1 d PDU A 2
F20' F 1.2016(11) 0.5537(9) 0.3583(8) 0.072(3) Uani 0.436(6) 1 d PDU A 2
F21' F 1.1342(10) 0.4027(8) 0.3759(8) 0.075(2) Uani 0.436(6) 1 d PDU A 2
C50 C 0.5797(5) 0.4821(5) 0.1828(4) 0.0609(16) Uani 0.688(4) 1 d PDU A 1
F22 F 0.5367(6) 0.5239(4) 0.1237(4) 0.0570(15) Uani 0.688(4) 1 d PDU A 1
F23 F 0.5498(4) 0.3764(3) 0.1412(3) 0.0447(11) Uani 0.688(4) 1 d PDU A 1
C51 C 0.5111(8) 0.4801(6) 0.2398(6) 0.066(2) Uani 0.688(4) 1 d PDU A 1
F24 F 0.5405(4) 0.5784(4) 0.2788(4) 0.0546(13) Uani 0.688(4) 1 d PDU A 1
F25 F 0.3905(6) 0.4430(6) 0.1994(6) 0.086(2) Uani 0.688(4) 1 d PDU A 1
C52 C 0.5212(9) 0.4198(8) 0.3018(6) 0.072(2) Uani 0.688(4) 1 d PDU A 1
F26 F 0.6264(7) 0.4564(6) 0.3377(5) 0.0746(19) Uani 0.688(4) 1 d PDU A 1
F27 F 0.4814(11) 0.3235(5) 0.2687(6) 0.138(4) Uani 0.688(4) 1 d PDU A 1
F28 F 0.4533(11) 0.4381(10) 0.3499(6) 0.139(5) Uani 0.688(4) 1 d PDU A 1
C50' C 0.5797(5) 0.4821(5) 0.1828(4) 0.0609(16) Uani 0.312(4) 1 d PDU A 2
F22' F 0.5225(15) 0.4801(10) 0.1139(8) 0.0570(15) Uani 0.312(4) 1 d PDU A 2
F23' F 0.5416(9) 0.5731(7) 0.2289(8) 0.0447(11) Uani 0.312(4) 1 d PDU A 2
C51' C 0.5296(13) 0.4174(11) 0.2373(9) 0.066(2) Uani 0.312(4) 1 d PDU A 2
F24' F 0.6012(12) 0.4210(11) 0.3113(8) 0.0546(13) Uani 0.312(4) 1 d PDU A 2
F25' F 0.5226(13) 0.3282(11) 0.1857(10) 0.086(2) Uani 0.312(4) 1 d PDU A 2
C52' C 0.4173(14) 0.4059(13) 0.2549(11) 0.072(2) Uani 0.312(4) 1 d PDU A 2
F26' F 0.3451(15) 0.4201(14) 0.1946(10) 0.0746(19) Uani 0.312(4) 1 d PDU A 2
F27' F 0.377(2) 0.3100(11) 0.2613(14) 0.138(4) Uani 0.312(4) 1 d PDU A 2
F28' F 0.403(3) 0.458(2) 0.3206(13) 0.139(5) Uani 0.312(4) 1 d PDU A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N4 95.33(15) . . ?
N1 Ag1 P1 134.22(12) . . ?
N4 Ag1 P1 129.50(11) . . ?
N1 Ag1 Ag2 62.82(11) . . ?
N4 Ag1 Ag2 64.92(11) . . ?
P1 Ag1 Ag2 123.11(3) . . ?
N2 Ag2 P2 152.08(12) . . ?
N2 Ag2 N5 92.15(16) . . ?
P2 Ag2 N5 115.23(12) . . ?
N2 Ag2 Ag1 63.60(11) . . ?
P2 Ag2 Ag1 122.13(3) . . ?
N5 Ag2 Ag1 64.24(10) . . ?
C1 P1 C13 106.4(2) . . ?
C1 P1 C7 105.4(2) . . ?
C13 P1 C7 104.2(2) . . ?
C1 P1 Ag1 114.45(17) . . ?
C13 P1 Ag1 107.75(16) . . ?
C7 P1 Ag1 117.68(17) . . ?
C2 C1 C6 119.2(5) . . ?
C2 C1 P1 117.5(4) . . ?
C6 C1 P1 123.3(4) . . ?
C1 C2 C3 121.2(6) . . ?
C4 C3 C2 119.2(7) . . ?
C5 C4 C3 120.6(6) . . ?
C4 C5 C6 120.5(6) . . ?
C1 C6 C5 119.3(6) . . ?
C8 C7 C12 119.3(4) . . ?
C8 C7 P1 118.7(4) . . ?
C12 C7 P1 121.9(4) . . ?
C7 C8 C9 120.0(5) . . ?
C10 C9 C8 120.5(5) . . ?
C9 C10 C11 119.6(5) . . ?
C12 C11 C10 120.2(5) . . ?
C11 C12 C7 120.4(5) . . ?
C18 C13 C14 119.5(5) . . ?
C18 C13 P1 122.0(4) . . ?
C14 C13 P1 118.2(4) . . ?
C15 C14 C13 119.8(5) . . ?
C14 C15 C16 120.7(5) . . ?
C17 C16 C15 119.8(5) . . ?
C16 C17 C18 119.7(5) . . ?
C13 C18 C17 120.4(5) . . ?
C25 P2 C19 104.6(2) . . ?
C25 P2 C31 105.8(2) . . ?
C19 P2 C31 104.9(2) . . ?
C25 P2 Ag2 120.27(16) . . ?
C19 P2 Ag2 111.56(16) . . ?
C31 P2 Ag2 108.61(17) . . ?
C20 C19 C24 119.3(5) . . ?
C20 C19 P2 123.0(4) . . ?
C24 C19 P2 117.7(4) . . ?
C19 C20 C21 119.9(5) . . ?
C22 C21 C20 120.4(5) . . ?
C21 C22 C23 120.3(5) . . ?
C22 C23 C24 120.0(6) . . ?
C23 C24 C19 120.2(5) . . ?
C30 C25 C26 119.2(5) . . ?
C30 C25 P2 119.0(4) . . ?
C26 C25 P2 121.7(4) . . ?
C27 C26 C25 120.3(5) . . ?
C26 C27 C28 120.5(5) . . ?
C29 C28 C27 119.6(5) . . ?
C28 C29 C30 120.1(5) . . ?
C25 C30 C29 120.3(5) . . ?
C36 C31 C32 119.4(5) . . ?
C36 C31 P2 123.6(4) . . ?
C32 C31 P2 116.9(4) . . ?
C33 C32 C31 119.7(6) . . ?
C34 C33 C32 120.7(6) . . ?
C33 C34 C35 120.1(6) . . ?
C34 C35 C36 120.2(6) . . ?
C31 C36 C35 119.9(6) . . ?
C37 N1 N2 104.8(4) . . ?
C37 N1 Ag1 139.4(4) . . ?
N2 N1 Ag1 115.2(3) . . ?
C38 N2 N1 105.5(4) . . ?
C38 N2 Ag2 136.7(4) . . ?
N1 N2 Ag2 117.8(3) . . ?
N1 C37 N3 114.6(5) . . ?
N1 C37 C41 121.9(5) . . ?
N3 C37 C41 123.5(5) . . ?
C38 N3 C37 100.4(4) . . ?
N2 C38 N3 114.8(5) . . ?
N2 C38 C44 121.7(5) . . ?
N3 C38 C44 123.5(5) . . ?
F1 C41 F2 104.9(5) . . ?
F1 C41 C42 112.3(6) . . ?
F2 C41 C42 100.6(6) . . ?
F1 C41 C37 111.0(5) . . ?
F2 C41 C37 109.9(5) . . ?
C42 C41 C37 117.0(6) . . ?
F4 C42 C43 105.4(7) . . ?
F4 C42 C41 110.1(6) . . ?
C43 C42 C41 120.1(7) . . ?
F4 C42 F3 109.2(6) . . ?
C43 C42 F3 98.3(7) . . ?
C41 C42 F3 112.9(7) . . ?
F6 C43 F7 101.9(7) . . ?
F6 C43 F5 112.6(7) . . ?
F7 C43 F5 116.3(8) . . ?
F6 C43 C42 111.2(7) . . ?
F7 C43 C42 113.3(7) . . ?
F5 C43 C42 101.9(8) . . ?
F8 C44 F9 106.5(5) . . ?
F8 C44 C38 109.7(4) . . ?
F9 C44 C38 111.0(5) . . ?
F8 C44 C45 107.1(5) . . ?
F9 C44 C45 107.4(5) . . ?
C38 C44 C45 114.7(5) . . ?
F11 C45 F10 107.6(7) . . ?
F11 C45 C46 107.6(5) . . ?
F10 C45 C46 107.3(6) . . ?
F11 C45 C44 108.4(6) . . ?
F10 C45 C44 106.6(5) . . ?
C46 C45 C44 118.9(6) . . ?
F14 C46 F12 107.5(7) . . ?
F14 C46 F13 106.5(7) . . ?
F12 C46 F13 107.3(7) . . ?
F14 C46 C45 111.4(6) . . ?
F12 C46 C45 112.4(7) . . ?
F13 C46 C45 111.4(6) . . ?
C39 N4 N5 105.1(4) . . ?
C39 N4 Ag1 135.4(3) . . ?
N5 N4 Ag1 119.3(3) . . ?
C40 N5 N4 104.6(4) . . ?
C40 N5 Ag2 143.3(4) . . ?
N4 N5 Ag2 111.5(3) . . ?
N4 C39 N6 115.2(5) . . ?
N4 C39 C47 122.7(5) . . ?
N6 C39 C47 122.1(5) . . ?
C40 N6 C39 99.7(5) . . ?
N5 C40 N6 115.4(5) . . ?
N5 C40 C50 120.2(5) . . ?
N6 C40 C50 124.4(5) . . ?
F15 C47 F16 103.8(11) . . ?
F15 C47 C48 111.2(7) . . ?
F16 C47 C48 109.9(12) . . ?
F15 C47 C39 105.8(9) . . ?
F16 C47 C39 104.1(10) . . ?
C48 C47 C39 120.6(7) . . ?
F17 C48 F18 108.6(10) . . ?
F17 C48 C47 104.9(9) . . ?
F18 C48 C47 106.4(9) . . ?
F17 C48 C49 110.7(10) . . ?
F18 C48 C49 109.9(10) . . ?
C47 C48 C49 116.0(10) . . ?
F20 C49 F21 107.5(10) . . ?
F20 C49 F19 108.8(10) . . ?
F21 C49 F19 108.8(10) . . ?
F20 C49 C48 113.0(10) . . ?
F21 C49 C48 107.8(10) . . ?
F19 C49 C48 110.7(10) . . ?
F17' C48' F18' 103.4(12) . . ?
F17' C48' C49' 103.1(12) . . ?
F18' C48' C49' 103.4(11) . . ?
F20' C49' F19' 107.8(13) . . ?
F20' C49' F21' 106.0(12) . . ?
F19' C49' F21' 104.2(12) . . ?
F20' C49' C48' 112.0(12) . . ?
F19' C49' C48' 108.3(12) . . ?
F21' C49' C48' 117.9(12) . . ?
F22 C50 C51 106.0(7) . . ?
F22 C50 F23 101.9(6) . . ?
C51 C50 F23 106.1(5) . . ?
F22 C50 C40 110.0(5) . . ?
C51 C50 C40 124.3(7) . . ?
F23 C50 C40 106.4(5) . . ?
F24 C51 C50 105.6(7) . . ?
F24 C51 C52 107.1(8) . . ?
C50 C51 C52 118.6(8) . . ?
F24 C51 F25 109.4(7) . . ?
C50 C51 F25 110.9(8) . . ?
C52 C51 F25 105.0(8) . . ?
F26 C52 F27 117.2(11) . . ?
F26 C52 F28 112.2(10) . . ?
F27 C52 F28 108.0(10) . . ?
F26 C52 C51 103.5(8) . . ?
F27 C52 C51 109.9(9) . . ?
F28 C52 C51 105.3(10) . . ?
F24' C51' F25' 105.9(13) . . ?
F24' C51' C52' 105.3(12) . . ?
F25' C51' C52' 108.8(13) . . ?
F27' C52' F26' 107.3(17) . . ?
F27' C52' F28' 104.5(18) . . ?
F26' C52' F28' 103.5(17) . . ?
F27' C52' C51' 104.5(15) . . ?
F26' C52' C51' 112.6(14) . . ?
F28' C52' C51' 123.4(18) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.255(4) . ?
Ag1 N4 2.278(4) . ?
Ag1 P1 2.3502(13) . ?
Ag1 Ag2 3.3674(5) . ?
Ag2 N2 2.195(4) . ?
Ag2 P2 2.3503(13) . ?
Ag2 N5 2.402(5) . ?
P1 C1 1.819(5) . ?
P1 C13 1.821(5) . ?
P1 C7 1.825(5) . ?
C1 C2 1.383(8) . ?
C1 C6 1.395(8) . ?
C2 C3 1.381(8) . ?
C3 C4 1.380(10) . ?
C4 C5 1.369(10) . ?
C5 C6 1.392(8) . ?
C7 C8 1.390(7) . ?
C7 C12 1.392(7) . ?
C8 C9 1.392(7) . ?
C9 C10 1.385(8) . ?
C10 C11 1.388(8) . ?
C11 C12 1.384(7) . ?
C13 C18 1.381(7) . ?
C13 C14 1.387(7) . ?
C14 C15 1.377(8) . ?
C15 C16 1.380(8) . ?
C16 C17 1.378(8) . ?
C17 C18 1.388(8) . ?
P2 C25 1.819(5) . ?
P2 C19 1.819(5) . ?
P2 C31 1.820(5) . ?
C19 C20 1.380(7) . ?
C19 C24 1.400(7) . ?
C20 C21 1.396(7) . ?
C21 C22 1.371(9) . ?
C22 C23 1.377(9) . ?
C23 C24 1.382(8) . ?
C25 C30 1.386(7) . ?
C25 C26 1.396(7) . ?
C26 C27 1.378(8) . ?
C27 C28 1.385(8) . ?
C28 C29 1.384(8) . ?
C29 C30 1.390(8) . ?
C31 C36 1.384(8) . ?
C31 C32 1.402(8) . ?
C32 C33 1.381(8) . ?
C33 C34 1.371(10) . ?
C34 C35 1.377(10) . ?
C35 C36 1.393(8) . ?
N1 C37 1.334(7) . ?
N1 N2 1.367(6) . ?
N2 C38 1.327(6) . ?
C37 N3 1.345(7) . ?
C37 C41 1.491(8) . ?
N3 C38 1.339(7) . ?
C38 C44 1.493(7) . ?
C41 F1 1.341(7) . ?
C41 F2 1.357(7) . ?
C41 C42 1.459(9) . ?
C42 F4 1.380(8) . ?
C42 C43 1.404(11) . ?
C42 F3 1.504(9) . ?
C43 F6 1.348(10) . ?
C43 F7 1.378(9) . ?
C43 F5 1.385(10) . ?
C44 F8 1.343(6) . ?
C44 F9 1.353(6) . ?
C44 C45 1.508(8) . ?
C45 F11 1.332(8) . ?
C45 F10 1.369(8) . ?
C45 C46 1.504(9) . ?
C46 F14 1.309(8) . ?
C46 F12 1.316(9) . ?
C46 F13 1.319(9) . ?
N4 C39 1.324(7) . ?
N4 N5 1.362(6) . ?
N5 C40 1.331(7) . ?
C39 N6 1.341(7) . ?
C39 C47 1.491(8) . ?
N6 C40 1.335(8) . ?
C40 C50 1.492(8) . ?
C47 F15 1.380(11) . ?
C47 F16 1.386(11) . ?
C47 C48 1.463(12) . ?
C48 F17 1.361(11) . ?
C48 F18 1.367(12) . ?
C48 C49 1.496(12) . ?
C49 F20 1.320(11) . ?
C49 F21 1.325(12) . ?
C49 F19 1.345(13) . ?
C48' F17' 1.392(13) . ?
C48' F18' 1.392(13) . ?
C48' C49' 1.503(14) . ?
C49' F20' 1.323(13) . ?
C49' F19' 1.345(14) . ?
C49' F21' 1.350(14) . ?
C50 F22 1.355(9) . ?
C50 C51 1.420(10) . ?
C50 F23 1.475(7) . ?
C51 F24 1.370(9) . ?
C51 C52 1.463(12) . ?
C51 F25 1.463(11) . ?
C52 F26 1.279(11) . ?
C52 F27 1.309(11) . ?
C52 F28 1.352(12) . ?
C51' F24' 1.410(15) . ?
C51' F25' 1.413(14) . ?
C51' C52' 1.476(15) . ?
C52' F27' 1.327(15) . ?
C52' F26' 1.334(16) . ?
C52' F28' 1.341(15) . ?
