#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:04:11 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179091 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/53/4305332.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4305332
loop_
_publ_author_name
'Meisu Zhou'
'Yanping Song'
'Tao Gong'
'Hongbo Tong'
'Jianping Guo'
'Linhong Weng'
'Diansheng Liu'
_publ_section_title
;
Synthesis and Structures of Selected Triazapentadienate of Li, Mn, Fe, Co,
Ni, Cu(I), and Cu(II) using 2,4-N,N'-Disubstituted
1,3,5-Triazapentadienate Anions as Ancillary Ligands:
[N(Ar)C(NMe2)NC(NMe2)N(R)]- (Ar = Ph, 2,6-iPr2-C6H3; R = H, SiMe3)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6692
_journal_page_last               6700
_journal_paper_doi               10.1021/ic800320e
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C30 H52 Co N10 Si2'
_chemical_formula_weight         667.93
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.522(3)
_cell_angle_beta                 107.442(3)
_cell_angle_gamma                115.851(2)
_cell_formula_units_Z            2
_cell_length_a                   11.163(2)
_cell_length_b                   11.961(3)
_cell_length_c                   16.070(3)
_cell_measurement_temperature    213(2)
_cell_volume                     1817.6(7)
_computing_cell_refinement       SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      213(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_measurement_device_type  'CCD AREA DETECTOR'
_diffrn_measurement_method       Ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0219
_diffrn_reflns_av_sigmaI/netI    0.0525
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            7545
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.92
_exptl_absorpt_coefficient_mu    0.573
_exptl_absorpt_correction_T_max  0.8941
_exptl_absorpt_correction_T_min  0.8470
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Purple
_exptl_crystal_density_diffrn    1.220
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             714
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.501
_refine_diff_density_min         -0.327
_refine_diff_density_rms         0.057
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     402
_refine_ls_number_reflns         6283
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0620
_refine_ls_R_factor_gt           0.0535
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0529P)²+0.9682P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1174
_refine_ls_wR_factor_ref         0.1222
_reflns_number_gt                5545
_reflns_number_total             6283
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic800320e-file001_5.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4305332
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.50063(4) 0.74181(3) 0.73410(2) 0.02338(13) Uani 1 1 d . . .
N1 N 0.5225(3) 0.5866(2) 0.75551(16) 0.0269(6) Uani 1 1 d . . .
N2 N 0.3696(3) 0.3697(2) 0.72655(17) 0.0371(7) Uani 1 1 d . . .
N3 N 0.3677(3) 0.4772(2) 0.61092(16) 0.0289(6) Uani 1 1 d . . .
N4 N 0.3307(3) 0.5469(2) 0.47977(16) 0.0371(7) Uani 1 1 d . . .
N5 N 0.3782(3) 0.6792(2) 0.60795(15) 0.0254(5) Uani 1 1 d . . .
N6 N 0.6596(3) 0.9156(2) 0.77450(15) 0.0253(5) Uani 1 1 d . . .
N7 N 0.7891(3) 1.0913(2) 0.88803(17) 0.0343(6) Uani 1 1 d . . .
N8 N 0.5512(3) 0.9740(2) 0.86261(17) 0.0314(6) Uani 1 1 d . . .
N9 N 0.3186(3) 0.9098(3) 0.8421(2) 0.0443(7) Uani 1 1 d . . .
N10 N 0.3875(3) 0.7618(2) 0.80275(16) 0.0278(6) Uani 1 1 d . . .
Si1 Si 0.66550(10) 0.59742(8) 0.84365(6) 0.0326(2) Uani 1 1 d . . .
Si2 Si 0.76696(10) 0.99293(8) 0.71183(6) 0.0341(2) Uani 1 1 d . . .
C1 C 0.4220(3) 0.4841(3) 0.6983(2) 0.0275(7) Uani 1 1 d . . .
C2 C 0.3491(4) 0.3617(3) 0.8123(2) 0.0475(9) Uani 1 1 d . . .
H2A H 0.3932 0.4448 0.8455 0.071 Uiso 1 1 calc R . .
H2B H 0.3908 0.3127 0.8441 0.071 Uiso 1 1 calc R . .
H2C H 0.2497 0.3222 0.8036 0.071 Uiso 1 1 calc R . .
C3 C 0.2776(4) 0.2546(3) 0.6627(2) 0.0534(11) Uani 1 1 d . . .
H3A H 0.1826 0.2440 0.6432 0.080 Uiso 1 1 calc R . .
H3B H 0.2799 0.1841 0.6899 0.080 Uiso 1 1 calc R . .
H3C H 0.3094 0.2597 0.6130 0.080 Uiso 1 1 calc R . .
C4 C 0.3611(3) 0.5700(3) 0.56826(19) 0.0278(7) Uani 1 1 d . . .
C5 C 0.2904(5) 0.4223(3) 0.4356(2) 0.0511(10) Uani 1 1 d . . .
H5A H 0.3724 0.4199 0.4300 0.077 Uiso 1 1 calc R . .
H5B H 0.2217 0.4052 0.3780 0.077 Uiso 1 1 calc R . .
H5C H 0.2505 0.3600 0.4699 0.077 Uiso 1 1 calc R . .
C6 C 0.3564(4) 0.6447(3) 0.4247(2) 0.0455(9) Uani 1 1 d . . .
H6A H 0.4048 0.7258 0.4613 0.068 Uiso 1 1 calc R . .
H6B H 0.2679 0.6341 0.3840 0.068 Uiso 1 1 calc R . .
H6C H 0.4136 0.6388 0.3923 0.068 Uiso 1 1 calc R . .
C7 C 0.2868(3) 0.7314(3) 0.57076(19) 0.0276(7) Uani 1 1 d . . .
C8 C 0.1468(3) 0.6595(3) 0.5157(2) 0.0338(7) Uani 1 1 d . . .
H8 H 0.1141 0.5746 0.4962 0.041 Uiso 1 1 calc R . .
C9 C 0.0560(4) 0.7126(3) 0.4897(2) 0.0429(9) Uani 1 1 d . . .
H9 H -0.0371 0.6628 0.4534 0.052 Uiso 1 1 calc R . .
C10 C 0.1024(4) 0.8386(4) 0.5170(2) 0.0484(10) Uani 1 1 d . . .
H10 H 0.0411 0.8740 0.4997 0.058 Uiso 1 1 calc R . .
C11 C 0.2413(4) 0.9114(3) 0.5705(2) 0.0454(9) Uani 1 1 d . . .
H11 H 0.2741 0.9967 0.5889 0.055 Uiso 1 1 calc R . .
C12 C 0.3318(4) 0.8581(3) 0.5968(2) 0.0353(8) Uani 1 1 d . . .
H12 H 0.4250 0.9085 0.6327 0.042 Uiso 1 1 calc R . .
C13 C 0.8292(4) 0.7161(3) 0.8281(2) 0.0449(9) Uani 1 1 d . . .
H13A H 0.8364 0.6880 0.7744 0.067 Uiso 1 1 calc R . .
H13B H 0.9098 0.7266 0.8772 0.067 Uiso 1 1 calc R . .
H13C H 0.8263 0.7949 0.8245 0.067 Uiso 1 1 calc R . .
C14 C 0.6590(4) 0.6555(4) 0.9500(2) 0.0566(11) Uani 1 1 d . . .
H14A H 0.6553 0.7341 0.9462 0.085 Uiso 1 1 calc R . .
H14B H 0.7419 0.6675 0.9976 0.085 Uiso 1 1 calc R . .
H14C H 0.5763 0.5947 0.9607 0.085 Uiso 1 1 calc R . .
C15 C 0.6840(4) 0.4497(4) 0.8470(3) 0.0581(11) Uani 1 1 d . . .
H15A H 0.6229 0.3936 0.8756 0.087 Uiso 1 1 calc R . .
H15B H 0.7802 0.4695 0.8792 0.087 Uiso 1 1 calc R . .
H15C H 0.6583 0.4101 0.7877 0.087 Uiso 1 1 calc R . .
C16 C 0.6579(3) 0.9846(3) 0.83985(19) 0.0275(7) Uani 1 1 d . . .
C17 C 0.8932(4) 1.0567(3) 0.9433(2) 0.0489(10) Uani 1 1 d . . .
H17A H 0.8716 1.0329 0.9959 0.073 Uiso 1 1 calc R . .
H17B H 0.9857 1.1272 0.9590 0.073 Uiso 1 1 calc R . .
H17C H 0.8909 0.9872 0.9113 0.073 Uiso 1 1 calc R . .
C18 C 0.7797(4) 1.1874(3) 0.9386(2) 0.0506(10) Uani 1 1 d . . .
H18A H 0.7130 1.2113 0.9008 0.076 Uiso 1 1 calc R . .
H18B H 0.8709 1.2598 0.9612 0.076 Uiso 1 1 calc R . .
H18C H 0.7492 1.1544 0.9869 0.076 Uiso 1 1 calc R . .
C19 C 0.4182(3) 0.8780(3) 0.8335(2) 0.0309(7) Uani 1 1 d . . .
C20 C 0.3635(5) 1.0360(3) 0.8860(3) 0.0610(12) Uani 1 1 d . . .
H20A H 0.4430 1.0578 0.9390 0.092 Uiso 1 1 calc R . .
H20B H 0.2870 1.0375 0.9009 0.092 Uiso 1 1 calc R . .
H20C H 0.3898 1.0956 0.8471 0.092 Uiso 1 1 calc R . .
C21 C 0.1723(4) 0.8425(4) 0.7837(3) 0.0614(12) Uani 1 1 d . . .
H21A H 0.1666 0.7924 0.7342 0.092 Uiso 1 1 calc R . .
H21B H 0.1385 0.9019 0.7628 0.092 Uiso 1 1 calc R . .
H21C H 0.1153 0.7887 0.8154 0.092 Uiso 1 1 calc R . .
C22 C 0.2707(3) 0.6552(3) 0.8116(2) 0.0303(7) Uani 1 1 d . . .
C23 C 0.2520(4) 0.6386(3) 0.8929(2) 0.0402(8) Uani 1 1 d . . .
H23 H 0.3153 0.6996 0.9422 0.048 Uiso 1 1 calc R . .
C24 C 0.1409(4) 0.5326(3) 0.9014(2) 0.0505(10) Uani 1 1 d . . .
H24 H 0.1295 0.5237 0.9564 0.061 Uiso 1 1 calc R . .
C25 C 0.0464(4) 0.4394(3) 0.8299(2) 0.0484(9) Uani 1 1 d . . .
H25 H -0.0288 0.3684 0.8359 0.058 Uiso 1 1 calc R . .
C26 C 0.0660(4) 0.4540(3) 0.7494(2) 0.0481(10) Uani 1 1 d . . .
H26 H 0.0040 0.3915 0.7006 0.058 Uiso 1 1 calc R . .
C27 C 0.1764(4) 0.5599(3) 0.7401(2) 0.0396(8) Uani 1 1 d . . .
H27 H 0.1881 0.5678 0.6852 0.048 Uiso 1 1 calc R . .
C28 C 0.9632(4) 1.0634(4) 0.7643(3) 0.0571(11) Uani 1 1 d . . .
H28A H 0.9966 1.1377 0.8056 0.086 Uiso 1 1 calc R . .
H28B H 1.0065 1.0851 0.7195 0.086 Uiso 1 1 calc R . .
H28C H 0.9874 1.0035 0.7949 0.086 Uiso 1 1 calc R . .
C29 C 0.7251(4) 1.1200(3) 0.6692(3) 0.0521(10) Uani 1 1 d . . .
H29A H 0.6285 1.0838 0.6308 0.078 Uiso 1 1 calc R . .
H29B H 0.7862 1.1651 0.6370 0.078 Uiso 1 1 calc R . .
H29C H 0.7391 1.1767 0.7179 0.078 Uiso 1 1 calc R . .
C30 C 0.7209(4) 0.8733(3) 0.6179(3) 0.0548(11) Uani 1 1 d . . .
H30A H 0.7352 0.8042 0.6402 0.082 Uiso 1 1 calc R . .
H30B H 0.7801 0.9105 0.5830 0.082 Uiso 1 1 calc R . .
H30C H 0.6236 0.8431 0.5820 0.082 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N5 Co1 N6 121.93(10) . . ?
N5 Co1 N10 108.59(10) . . ?
N6 Co1 N10 96.26(10) . . ?
N5 Co1 N1 95.94(10) . . ?
N6 Co1 N1 123.87(10) . . ?
N10 Co1 N1 109.91(10) . . ?
C1 N1 Si1 127.3(2) . . ?
C1 N1 Co1 113.97(19) . . ?
Si1 N1 Co1 118.73(13) . . ?
C1 N2 C3 120.3(3) . . ?
C1 N2 C2 120.5(3) . . ?
C3 N2 C2 113.8(3) . . ?
C4 N3 C1 126.8(3) . . ?
C4 N4 C6 123.7(3) . . ?
C4 N4 C5 120.8(3) . . ?
C6 N4 C5 114.8(3) . . ?
C4 N5 C7 121.6(2) . . ?
C4 N5 Co1 118.40(19) . . ?
C7 N5 Co1 118.11(18) . . ?
C16 N6 Si2 118.6(2) . . ?
C16 N6 Co1 115.8(2) . . ?
Si2 N6 Co1 123.15(13) . . ?
C16 N7 C17 113.0(3) . . ?
C16 N7 C18 116.0(3) . . ?
C17 N7 C18 110.4(3) . . ?
C16 N8 C19 127.1(3) . . ?
C19 N9 C21 120.9(3) . . ?
C19 N9 C20 119.2(3) . . ?
C21 N9 C20 116.2(3) . . ?
C19 N10 C22 121.6(3) . . ?
C19 N10 Co1 117.8(2) . . ?
C22 N10 Co1 120.45(19) . . ?
N1 Si1 C13 107.70(15) . . ?
N1 Si1 C15 113.65(15) . . ?
C13 Si1 C15 104.76(19) . . ?
N1 Si1 C14 110.05(16) . . ?
C13 Si1 C14 107.55(18) . . ?
C15 Si1 C14 112.7(2) . . ?
N6 Si2 C29 108.89(16) . . ?
N6 Si2 C30 106.44(15) . . ?
C29 Si2 C30 109.65(19) . . ?
N6 Si2 C28 119.01(16) . . ?
C29 Si2 C28 107.45(18) . . ?
C30 Si2 C28 105.14(19) . . ?
N1 C1 N3 126.3(3) . . ?
N1 C1 N2 120.1(3) . . ?
N3 C1 N2 113.5(3) . . ?
N2 C2 H2A 109.5 . . ?
N2 C2 H2B 109.5 . . ?
H2A C2 H2B 109.5 . . ?
N2 C2 H2C 109.5 . . ?
H2A C2 H2C 109.5 . . ?
H2B C2 H2C 109.5 . . ?
N2 C3 H3A 109.5 . . ?
N2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
N2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
N3 C4 N4 115.0(3) . . ?
N3 C4 N5 123.8(3) . . ?
N4 C4 N5 121.1(3) . . ?
N4 C5 H5A 109.5 . . ?
N4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
N4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
N4 C6 H6A 109.5 . . ?
N4 C6 H6B 109.5 . . ?
H6A C6 H6B 109.5 . . ?
N4 C6 H6C 109.5 . . ?
H6A C6 H6C 109.5 . . ?
H6B C6 H6C 109.5 . . ?
C12 C7 C8 117.5(3) . . ?
C12 C7 N5 118.9(3) . . ?
C8 C7 N5 123.3(3) . . ?
C9 C8 C7 121.1(3) . . ?
C9 C8 H8 119.5 . . ?
C7 C8 H8 119.5 . . ?
C10 C9 C8 120.6(3) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C11 C10 C9 119.0(3) . . ?
C11 C10 H10 120.5 . . ?
C9 C10 H10 120.5 . . ?
C10 C11 C12 120.3(3) . . ?
C10 C11 H11 119.8 . . ?
C12 C11 H11 119.8 . . ?
C11 C12 C7 121.5(3) . . ?
C11 C12 H12 119.2 . . ?
C7 C12 H12 119.2 . . ?
Si1 C13 H13A 109.5 . . ?
Si1 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
Si1 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
Si1 C14 H14A 109.5 . . ?
Si1 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
Si1 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
Si1 C15 H15A 109.5 . . ?
Si1 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Si1 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
N8 C16 N6 129.3(3) . . ?
N8 C16 N7 114.3(3) . . ?
N6 C16 N7 116.2(3) . . ?
N7 C17 H17A 109.5 . . ?
N7 C17 H17B 109.5 . . ?
H17A C17 H17B 109.5 . . ?
N7 C17 H17C 109.5 . . ?
H17A C17 H17C 109.5 . . ?
H17B C17 H17C 109.5 . . ?
N7 C18 H18A 109.5 . . ?
N7 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N7 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N10 C19 N8 123.3(3) . . ?
N10 C19 N9 122.7(3) . . ?
N8 C19 N9 113.9(3) . . ?
N9 C20 H20A 109.5 . . ?
N9 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
N9 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
N9 C21 H21A 109.5 . . ?
N9 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
N9 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C23 C22 C27 117.8(3) . . ?
C23 C22 N10 121.1(3) . . ?
C27 C22 N10 120.9(3) . . ?
C24 C23 C22 120.8(3) . . ?
C24 C23 H23 119.6 . . ?
C22 C23 H23 119.6 . . ?
C25 C24 C23 121.1(3) . . ?
C25 C24 H24 119.5 . . ?
C23 C24 H24 119.5 . . ?
C24 C25 C26 118.5(3) . . ?
C24 C25 H25 120.8 . . ?
C26 C25 H25 120.8 . . ?
C25 C26 C27 120.8(3) . . ?
C25 C26 H26 119.6 . . ?
C27 C26 H26 119.6 . . ?
C26 C27 C22 121.0(3) . . ?
C26 C27 H27 119.5 . . ?
C22 C27 H27 119.5 . . ?
Si2 C28 H28A 109.5 . . ?
Si2 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
Si2 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
Si2 C29 H29A 109.5 . . ?
Si2 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
Si2 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
Si2 C30 H30A 109.5 . . ?
Si2 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
Si2 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 N5 1.989(2) . ?
Co1 N6 1.990(2) . ?
Co1 N10 1.991(2) . ?
Co1 N1 1.996(2) . ?
N1 C1 1.330(4) . ?
N1 Si1 1.741(3) . ?
N2 C1 1.376(4) . ?
N2 C3 1.453(4) . ?
N2 C2 1.460(4) . ?
N3 C4 1.327(4) . ?
N3 C1 1.338(4) . ?
N4 C4 1.355(4) . ?
N4 C6 1.454(4) . ?
N4 C5 1.459(4) . ?
N5 C4 1.358(4) . ?
N5 C7 1.409(4) . ?
N6 C16 1.339(4) . ?
N6 Si2 1.755(3) . ?
N7 C16 1.431(4) . ?
N7 C17 1.455(4) . ?
N7 C18 1.460(4) . ?
N8 C16 1.303(4) . ?
N8 C19 1.352(4) . ?
N9 C19 1.363(4) . ?
N9 C21 1.455(5) . ?
N9 C20 1.462(4) . ?
N10 C19 1.329(4) . ?
N10 C22 1.418(4) . ?
Si1 C13 1.854(4) . ?
Si1 C15 1.865(4) . ?
Si1 C14 1.872(4) . ?
Si2 C29 1.855(4) . ?
Si2 C30 1.856(4) . ?
Si2 C28 1.868(4) . ?
C2 H2A 0.9600 . ?
C2 H2B 0.9600 . ?
C2 H2C 0.9600 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C6 H6A 0.9600 . ?
C6 H6B 0.9600 . ?
C6 H6C 0.9600 . ?
C7 C12 1.387(4) . ?
C7 C8 1.396(4) . ?
C8 C9 1.384(5) . ?
C8 H8 0.9300 . ?
C9 C10 1.380(5) . ?
C9 H9 0.9300 . ?
C10 C11 1.383(5) . ?
C10 H10 0.9300 . ?
C11 C12 1.385(5) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C13 H13A 0.9600 . ?
C13 H13B 0.9600 . ?
C13 H13C 0.9600 . ?
C14 H14A 0.9600 . ?
C14 H14B 0.9600 . ?
C14 H14C 0.9600 . ?
C15 H15A 0.9600 . ?
C15 H15B 0.9600 . ?
C15 H15C 0.9600 . ?
C17 H17A 0.9600 . ?
C17 H17B 0.9600 . ?
C17 H17C 0.9600 . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C21 H21A 0.9600 . ?
C21 H21B 0.9600 . ?
C21 H21C 0.9600 . ?
C22 C23 1.386(4) . ?
C22 C27 1.390(4) . ?
C23 C24 1.378(5) . ?
C23 H23 0.9300 . ?
C24 C25 1.378(5) . ?
C24 H24 0.9300 . ?
C25 C26 1.376(5) . ?
C25 H25 0.9300 . ?
C26 C27 1.378(5) . ?
C26 H26 0.9300 . ?
C27 H27 0.9300 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C29 H29A 0.9600 . ?
C29 H29B 0.9600 . ?
C29 H29C 0.9600 . ?
C30 H30A 0.9600 . ?
C30 H30B 0.9600 . ?
C30 H30C 0.9600 . ?
