#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/54/4305476.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4305476
loop_
_publ_author_name
'D. B. Ambili Raj'
'S. Biju'
'M. L. P. Reddy'
_publ_section_title
;
One-, Two-, and Three-Dimensional Arrays of
Eu3+-4,4,5,5,5-pentafluoro-1-(naphthalen-2-yl)pentane-1,3-dione complexes:
Synthesis, Crystal Structure and Photophysical Properties
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8091
_journal_page_last               8100
_journal_paper_doi               10.1021/ic8004757
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C57 H36 Cl3 Eu F15 N2 O6.5'
_chemical_formula_weight         1396.19
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.238(19)
_cell_angle_beta                 93.336(18)
_cell_angle_gamma                96.523(19)
_cell_formula_units_Z            2
_cell_length_a                   10.338(4)
_cell_length_b                   14.784(6)
_cell_length_c                   19.431(7)
_cell_measurement_reflns_used    7906
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.1
_cell_measurement_theta_min      2.4
_cell_volume                     2926(2)
_computing_cell_refinement       'APEX2/SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        'SAINT/XPREP (Bruker, 2004)'
_computing_molecular_graphics    'ORTEP 32 (Farrugia, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Altomare etal., 1993)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker axs (Kappa apex2)'
_diffrn_measurement_method       'ω and φ scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0273
_diffrn_reflns_av_sigmaI/netI    0.0195
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            51395
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.06
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.308
_exptl_absorpt_correction_T_max  0.7922
_exptl_absorpt_correction_T_min  0.7211
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Blessing, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.585
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1386
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.016
_refine_diff_density_min         -0.613
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.111
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     825
_refine_ls_number_reflns         10300
_refine_ls_number_restraints     32
_refine_ls_restrained_S_all      1.122
_refine_ls_R_factor_all          0.0520
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0846P)²+4.0841P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1252
_refine_ls_wR_factor_ref         0.1400
_reflns_number_gt                9173
_reflns_number_total             10300
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic8004757_si_002.cif
_cod_data_source_block           bijubpy1
_cod_original_cell_volume        2925.7(18)
_cod_original_formula_sum        'C57 H36 Cl3 Eu F15 N2 O6.50'
_cod_database_code               4305476
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7795(7) 0.2811(4) 0.5364(3) 0.0723(16) Uani 1 1 d . . .
H1 H 0.8697 0.2957 0.5388 0.087 Uiso 1 1 calc R . .
C2 C 0.7101(9) 0.2865(5) 0.4752(3) 0.090(2) Uani 1 1 d . . .
H2 H 0.7522 0.3038 0.4368 0.108 Uiso 1 1 calc R . .
C3 C 0.5793(9) 0.2662(5) 0.4717(4) 0.096(2) Uani 1 1 d . . .
H3 H 0.5298 0.2702 0.4308 0.115 Uiso 1 1 calc R . .
C4 C 0.5190(7) 0.2394(4) 0.5288(4) 0.0811(19) Uani 1 1 d . . .
H4 H 0.4289 0.2241 0.5264 0.097 Uiso 1 1 calc R . .
C5 C 0.5943(5) 0.2354(3) 0.5906(3) 0.0603(13) Uani 1 1 d . . .
C6 C 0.5389(5) 0.2076(3) 0.6547(3) 0.0604(14) Uani 1 1 d . . .
C7 C 0.4068(6) 0.1813(5) 0.6582(4) 0.0827(19) Uani 1 1 d . . .
H7 H 0.3493 0.1810 0.6196 0.099 Uiso 1 1 calc R . .
C8 C 0.3614(6) 0.1558(6) 0.7185(5) 0.100(3) Uani 1 1 d . . .
H8 H 0.2725 0.1389 0.7212 0.120 Uiso 1 1 calc R . .
C9 C 0.4477(7) 0.1549(5) 0.7765(4) 0.087(2) Uani 1 1 d . . .
H9 H 0.4189 0.1370 0.8180 0.105 Uiso 1 1 calc R . .
C10 C 0.5784(6) 0.1819(5) 0.7690(4) 0.0734(16) Uani 1 1 d . . .
H10 H 0.6379 0.1820 0.8068 0.088 Uiso 1 1 calc R . .
C11 C 1.1283(6) 0.3969(4) 0.6620(3) 0.0693(15) Uani 1 1 d . . .
C12 C 1.2112(6) 0.3888(5) 0.7180(3) 0.0761(17) Uani 1 1 d . . .
H12 H 1.2929 0.4233 0.7225 0.091 Uiso 1 1 calc R . .
C13 C 1.1791(4) 0.3310(3) 0.7695(2) 0.0492(10) Uani 1 1 d . . .
C14 C 1.2668(4) 0.3327(3) 0.8334(2) 0.0496(10) Uani 1 1 d . . .
C15 C 1.3912(5) 0.3854(4) 0.8442(3) 0.0670(14) Uani 1 1 d . . .
H15 H 1.4243 0.4159 0.8085 0.080 Uiso 1 1 calc R . .
C16 C 1.4617(5) 0.3920(5) 0.9047(3) 0.0740(16) Uani 1 1 d . . .
H16 H 1.5428 0.4274 0.9102 0.089 Uiso 1 1 calc R . .
C17 C 1.4161(5) 0.3468(4) 0.9602(3) 0.0651(14) Uani 1 1 d . . .
C18 C 1.4850(7) 0.3556(5) 1.0263(4) 0.089(2) Uani 1 1 d . . .
H18 H 1.5666 0.3901 1.0332 0.107 Uiso 1 1 calc R . .
C19 C 1.4346(8) 0.3149(6) 1.0795(4) 0.097(2) Uani 1 1 d . . .
H19 H 1.4811 0.3227 1.1226 0.117 Uiso 1 1 calc R . .
C20 C 1.3122(9) 0.2608(6) 1.0702(4) 0.100(2) Uani 1 1 d . . .
H20 H 1.2782 0.2331 1.1071 0.120 Uiso 1 1 calc R . .
C21 C 1.2438(7) 0.2490(5) 1.0072(3) 0.0814(18) Uani 1 1 d . . .
H21 H 1.1634 0.2129 1.0012 0.098 Uiso 1 1 calc R . .
C24 C 1.1734(7) 0.4676(5) 0.6102(4) 0.0861(19) Uani 1 1 d . . .
C22 C 1.2939(5) 0.2913(4) 0.9509(3) 0.0566(12) Uani 1 1 d . . .
C23 C 1.2216(5) 0.2861(3) 0.8860(3) 0.0513(11) Uani 1 1 d . . .
H23 H 1.1411 0.2500 0.8790 0.062 Uiso 1 1 calc R . .
C25 C 1.2008(14) 0.4230(8) 0.5447(7) 0.136(4) Uani 1 1 d . . .
C30 C 1.1686(5) -0.0112(4) 0.5818(3) 0.0611(13) Uani 1 1 d . . .
H30 H 1.1609 -0.0489 0.6170 0.073 Uiso 1 1 calc R . .
C31 C 1.2510(6) -0.0273(4) 0.5310(4) 0.0728(16) Uani 1 1 d . . .
H31 H 1.2995 -0.0765 0.5324 0.087 Uiso 1 1 calc R . .
C32 C 1.2661(6) 0.0268(4) 0.4766(3) 0.0687(15) Uani 1 1 d . . .
C33 C 1.3509(7) 0.0110(5) 0.4241(4) 0.088(2) Uani 1 1 d . . .
H33 H 1.4020 -0.0368 0.4251 0.105 Uiso 1 1 calc R . .
C34 C 1.3590(8) 0.0645(5) 0.3720(4) 0.094(2) Uani 1 1 d . . .
H34 H 1.4157 0.0526 0.3376 0.113 Uiso 1 1 calc R . .
C35 C 1.2851(8) 0.1368(6) 0.3686(4) 0.088(2) Uani 1 1 d . . .
H35 H 1.2915 0.1724 0.3320 0.105 Uiso 1 1 calc R . .
C36 C 1.2036(6) 0.1551(4) 0.4190(3) 0.0723(16) Uani 1 1 d . . .
H36 H 1.1558 0.2045 0.4172 0.087 Uiso 1 1 calc R . .
C37 C 1.1895(5) 0.1012(3) 0.4740(3) 0.0575(12) Uani 1 1 d . . .
C38 C 1.1061(5) 0.1171(3) 0.5273(3) 0.0524(11) Uani 1 1 d . . .
H38 H 1.0567 0.1659 0.5265 0.063 Uiso 1 1 calc R . .
C29 C 1.0945(4) 0.0635(3) 0.5804(3) 0.0499(11) Uani 1 1 d . . .
C28 C 1.0078(4) 0.0882(3) 0.6368(3) 0.0473(10) Uani 1 1 d . . .
C27 C 0.9938(5) 0.0363(3) 0.6930(3) 0.0548(12) Uani 1 1 d . . .
H27 H 1.0379 -0.0150 0.6938 0.066 Uiso 1 1 calc R . .
C26 C 0.9181(5) 0.0579(3) 0.7465(3) 0.0506(11) Uani 1 1 d . . .
C39 C 0.8992(7) -0.0081(4) 0.8019(3) 0.0700(15) Uani 1 1 d . . .
C40 C 0.9745(12) 0.0248(6) 0.8696(4) 0.107(3) Uani 1 1 d . . .
C41 C 0.7541(7) 0.4661(4) 0.7488(3) 0.0740(17) Uani 1 1 d . . .
C42 C 0.7651(6) 0.4696(4) 0.8195(3) 0.0664(15) Uani 1 1 d . A .
H42 H 0.7429 0.5209 0.8463 0.080 Uiso 1 1 calc R . .
C43 C 0.8092(4) 0.3976(3) 0.8528(2) 0.0459(10) Uani 1 1 d . . .
C44 C 0.8261(4) 0.4053(3) 0.9296(2) 0.0458(10) Uani 1 1 d . A .
C45 C 0.8191(5) 0.4881(3) 0.9718(3) 0.0558(12) Uani 1 1 d . . .
H45 H 0.7999 0.5396 0.9515 0.067 Uiso 1 1 calc R A .
C46 C 0.8403(6) 0.4931(4) 1.0418(3) 0.0629(13) Uani 1 1 d . A .
H46 H 0.8343 0.5482 1.0688 0.075 Uiso 1 1 calc R . .
C47 C 0.8713(5) 0.4168(4) 1.0749(3) 0.0584(12) Uani 1 1 d . . .
C48 C 0.8983(7) 0.4206(5) 1.1474(3) 0.0770(17) Uani 1 1 d . A .
H48 H 0.8928 0.4747 1.1758 0.092 Uiso 1 1 calc R . .
C49 C 0.9318(8) 0.3468(6) 1.1758(3) 0.095(2) Uani 1 1 d . . .
H49 H 0.9519 0.3515 1.2235 0.114 Uiso 1 1 calc R A .
C50 C 0.9370(8) 0.2633(6) 1.1354(4) 0.095(2) Uani 1 1 d . A .
H50 H 0.9592 0.2127 1.1560 0.114 Uiso 1 1 calc R . .
C51 C 0.9095(7) 0.2569(5) 1.0660(3) 0.0771(17) Uani 1 1 d . . .
H51 H 0.9118 0.2010 1.0392 0.093 Uiso 1 1 calc R A .
C52 C 0.8771(5) 0.3333(4) 1.0328(3) 0.0547(11) Uani 1 1 d . A .
C53 C 0.8549(5) 0.3298(3) 0.9607(2) 0.0499(10) Uani 1 1 d . . .
H53 H 0.8596 0.2750 0.9331 0.060 Uiso 1 1 calc R A .
C54 C 0.7353(12) 0.5601(6) 0.7135(4) 0.104(4) Uani 0.770(10) 1 d PD A 1
C55 C 0.6167(12) 0.5459(6) 0.6747(5) 0.129(5) Uani 0.770(10) 1 d PD A 1
F11 F 0.8190(10) 0.5843(7) 0.6638(6) 0.189(7) Uani 0.770(10) 1 d PD A 1
F12 F 0.7408(9) 0.6341(4) 0.7598(3) 0.109(3) Uani 0.770(10) 1 d PD A 1
F13 F 0.5995(8) 0.4768(4) 0.6267(4) 0.147(4) Uani 0.770(10) 1 d PD A 1
F14 F 0.5966(10) 0.6205(5) 0.6440(4) 0.146(4) Uani 0.770(10) 1 d PD A 1
F15 F 0.5378(7) 0.5329(7) 0.7265(5) 0.154(4) Uani 0.770(10) 1 d PD A 1
C55' C 0.7129(18) 0.5699(12) 0.6609(10) 0.069(7) Uiso 0.230(10) 1 d PD A 2
C54' C 0.6563(17) 0.5297(11) 0.7201(9) 0.031(4) Uiso 0.230(10) 1 d PD A 2
F11' F 0.656(3) 0.6029(15) 0.7661(12) 0.115(9) Uiso 0.230(10) 1 d PD A 2
F12' F 0.534(3) 0.489(4) 0.711(3) 0.28(3) Uiso 0.230(10) 1 d PD A 2
F13' F 0.677(2) 0.4993(11) 0.6127(12) 0.113(8) Uiso 0.230(10) 1 d PD A 2
F14' F 0.6665(18) 0.6428(12) 0.6390(13) 0.096(7) Uiso 0.230(10) 1 d PD A 2
F15' F 0.8434(16) 0.5869(13) 0.6624(8) 0.055(5) Uiso 0.230(10) 1 d PD A 2
N1 N 0.7233(4) 0.2557(3) 0.5937(2) 0.0575(10) Uani 1 1 d . A .
N2 N 0.6230(4) 0.2076(3) 0.7103(2) 0.0603(11) Uani 1 1 d . A .
O1 O 1.0153(4) 0.3565(3) 0.6470(2) 0.0682(10) Uani 1 1 d . A .
O2 O 1.0738(3) 0.2791(2) 0.76577(18) 0.0576(8) Uani 1 1 d . A .
O3 O 0.8581(3) 0.1266(2) 0.75789(18) 0.0521(8) Uani 1 1 d . A .
O4 O 0.9508(3) 0.1574(2) 0.63074(17) 0.0531(8) Uani 1 1 d . A .
O5 O 0.7817(5) 0.4069(3) 0.70370(18) 0.0733(11) Uani 1 1 d . A .
O6 O 0.8340(4) 0.3250(2) 0.82031(17) 0.0544(8) Uani 1 1 d . A .
F1 F 1.0794(6) 0.5206(4) 0.5960(3) 0.141(2) Uani 1 1 d . . .
F2 F 1.2748(6) 0.5283(4) 0.6367(3) 0.135(2) Uani 1 1 d . . .
F3 F 1.1070(9) 0.3694(5) 0.5137(3) 0.182(4) Uani 1 1 d . . .
F4 F 1.2961(10) 0.3718(6) 0.5600(5) 0.219(5) Uani 1 1 d . . .
F5 F 1.2475(9) 0.4888(5) 0.5056(3) 0.183(3) Uani 1 1 d . . .
F6 F 0.7720(5) -0.0231(4) 0.8154(3) 0.1219(17) Uani 1 1 d . . .
F7 F 0.9312(6) -0.0915(2) 0.7816(2) 0.1101(16) Uani 1 1 d . . .
F8 F 0.9418(8) 0.1005(3) 0.8988(2) 0.143(2) Uani 1 1 d . . .
F9 F 0.9529(8) -0.0388(4) 0.9149(2) 0.143(2) Uani 1 1 d . . .
F10 F 1.0997(7) 0.0369(5) 0.8578(3) 0.150(2) Uani 1 1 d . . .
Eu1 Eu 0.86614(2) 0.265631(14) 0.706666(11) 0.04422(10) Uani 1 1 d . . .
Cl1 Cl 0.3924(6) 0.7242(3) 0.7317(2) 0.209(2) Uani 1 1 d D . .
C56 C 0.3571(10) 0.8161(7) 0.7859(6) 0.093(6) Uani 0.490(6) 1 d PD B 3
H56 H 0.3177 0.7987 0.8279 0.112 Uiso 0.490(6) 1 calc PR B 3
Cl2 Cl 0.5147(6) 0.8710(5) 0.8018(3) 0.154(3) Uani 0.490(6) 1 d PD B 3
Cl3 Cl 0.2639(10) 0.8797(9) 0.7389(8) 0.251(8) Uani 0.490(6) 1 d PD B 3
C56' C 0.2950(12) 0.8084(7) 0.7551(7) 0.139(10) Uani 0.510(6) 1 d PD B 4
H56' H 0.2615 0.7978 0.8001 0.166 Uiso 0.510(6) 1 calc PR B 4
Cl3' Cl 0.3493(12) 0.9238(5) 0.7576(6) 0.204(5) Uani 0.510(6) 1 d PD B 4
Cl2' Cl 0.1641(8) 0.7872(5) 0.6920(3) 0.151(3) Uani 0.510(6) 1 d PD B 4
C57 C 0.643(2) -0.0037(14) 1.0438(11) 0.126(6) Uiso 0.50 1 d PD . .
C58 C 0.567(3) 0.0171(15) 0.9795(12) 0.29(2) Uiso 0.50 1 d PD . .
O7 O 0.565(2) 0.1037(14) 0.9672(10) 0.140(9) Uiso 0.369(19) 1 d PD C 5
O7' O 0.468(4) 0.068(3) 0.985(2) 0.11(2) Uiso 0.133(19) 1 d PD . 6
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 123.2(7) . . ?
N1 C1 H1 118.4 . . ?
C2 C1 H1 118.4 . . ?
C3 C2 C1 118.5(7) . . ?
C3 C2 H2 120.8 . . ?
C1 C2 H2 120.8 . . ?
C2 C3 C4 119.8(6) . . ?
C2 C3 H3 120.1 . . ?
C4 C3 H3 120.1 . . ?
C3 C4 C5 119.6(6) . . ?
C3 C4 H4 120.2 . . ?
C5 C4 H4 120.2 . . ?
N1 C5 C4 120.2(6) . . ?
N1 C5 C6 116.1(4) . . ?
C4 C5 C6 123.7(6) . . ?
N2 C6 C7 120.5(6) . . ?
N2 C6 C5 117.2(5) . . ?
C7 C6 C5 122.4(6) . . ?
C8 C7 C6 119.8(7) . . ?
C8 C7 H7 120.1 . . ?
C6 C7 H7 120.1 . . ?
C7 C8 C9 120.3(6) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 H8 119.8 . . ?
C10 C9 C8 116.6(7) . . ?
C10 C9 H9 121.7 . . ?
C8 C9 H9 121.7 . . ?
N2 C10 C9 123.3(7) . . ?
N2 C10 H10 118.4 . . ?
C9 C10 H10 118.4 . . ?
O1 C11 C12 127.6(5) . . ?
O1 C11 C24 113.9(5) . . ?
C12 C11 C24 118.5(5) . . ?
C11 C12 C13 123.6(5) . . ?
C11 C12 H12 118.2 . . ?
C13 C12 H12 118.2 . . ?
O2 C13 C12 122.3(5) . . ?
O2 C13 C14 116.4(4) . . ?
C12 C13 C14 121.2(5) . . ?
C23 C14 C15 118.4(5) . . ?
C23 C14 C13 118.4(4) . . ?
C15 C14 C13 123.0(5) . . ?
C16 C15 C14 121.3(6) . . ?
C16 C15 H15 119.3 . . ?
C14 C15 H15 119.3 . . ?
C15 C16 C17 121.5(5) . . ?
C15 C16 H16 119.3 . . ?
C17 C16 H16 119.3 . . ?
C16 C17 C22 119.0(5) . . ?
C16 C17 C18 123.3(6) . . ?
C22 C17 C18 117.7(6) . . ?
C19 C18 C17 121.5(7) . . ?
C19 C18 H18 119.3 . . ?
C17 C18 H18 119.3 . . ?
C18 C19 C20 120.6(6) . . ?
C18 C19 H19 119.7 . . ?
C20 C19 H19 119.7 . . ?
C21 C20 C19 119.9(7) . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 120.6(7) . . ?
C20 C21 H21 119.7 . . ?
C22 C21 H21 119.7 . . ?
F2 C24 F1 103.5(7) . . ?
F2 C24 C25 110.5(8) . . ?
F1 C24 C25 105.6(8) . . ?
F2 C24 C11 113.0(6) . . ?
F1 C24 C11 111.6(6) . . ?
C25 C24 C11 112.1(7) . . ?
C21 C22 C17 119.7(5) . . ?
C21 C22 C23 122.2(5) . . ?
C17 C22 C23 117.9(5) . . ?
C14 C23 C22 121.9(5) . . ?
C14 C23 H23 119.1 . . ?
C22 C23 H23 119.1 . . ?
F3 C25 F4 107.2(11) . . ?
F3 C25 F5 112.5(12) . . ?
F4 C25 F5 109.5(11) . . ?
F3 C25 C24 114.8(10) . . ?
F4 C25 C24 104.6(11) . . ?
F5 C25 C24 107.9(9) . . ?
C31 C30 C29 119.3(5) . . ?
C31 C30 H30 120.3 . . ?
C29 C30 H30 120.3 . . ?
C30 C31 C32 122.8(5) . . ?
C30 C31 H31 118.6 . . ?
C32 C31 H31 118.6 . . ?
C31 C32 C33 123.3(6) . . ?
C31 C32 C37 118.2(5) . . ?
C33 C32 C37 118.4(7) . . ?
C34 C33 C32 120.6(7) . . ?
C34 C33 H33 119.7 . . ?
C32 C33 H33 119.7 . . ?
C33 C34 C35 121.8(6) . . ?
C33 C34 H34 119.1 . . ?
C35 C34 H34 119.1 . . ?
C36 C35 C34 119.3(7) . . ?
C36 C35 H35 120.4 . . ?
C34 C35 H35 120.4 . . ?
C35 C36 C37 121.7(7) . . ?
C35 C36 H36 119.2 . . ?
C37 C36 H36 119.2 . . ?
C38 C37 C36 123.8(5) . . ?
C38 C37 C32 118.0(5) . . ?
C36 C37 C32 118.2(5) . . ?
C29 C38 C37 122.5(5) . . ?
C29 C38 H38 118.7 . . ?
C37 C38 H38 118.7 . . ?
C38 C29 C30 119.1(5) . . ?
C38 C29 C28 118.8(4) . . ?
C30 C29 C28 122.0(5) . . ?
O4 C28 C27 123.0(4) . . ?
O4 C28 C29 115.8(4) . . ?
C27 C28 C29 121.1(4) . . ?
C26 C27 C28 123.0(4) . . ?
C26 C27 H27 118.5 . . ?
C28 C27 H27 118.5 . . ?
O3 C26 C27 128.7(5) . . ?
O3 C26 C39 112.3(4) . . ?
C27 C26 C39 118.9(4) . . ?
F7 C39 F6 104.4(5) . . ?
F7 C39 C40 106.9(6) . . ?
F6 C39 C40 106.9(7) . . ?
F7 C39 C26 112.8(5) . . ?
F6 C39 C26 110.9(5) . . ?
C40 C39 C26 114.1(6) . . ?
F8 C40 F10 109.0(9) . . ?
F8 C40 F9 106.8(7) . . ?
F10 C40 F9 110.3(8) . . ?
F8 C40 C39 113.2(7) . . ?
F10 C40 C39 107.8(7) . . ?
F9 C40 C39 109.7(8) . . ?
O5 C41 C42 130.1(5) . . ?
O5 C41 C54' 112.9(7) . . ?
C42 C41 C54' 114.4(7) . . ?
O5 C41 C54 109.2(5) . . ?
C42 C41 C54 119.1(5) . . ?
C54' C41 C54 32.7(6) . . ?
C41 C42 C43 121.6(5) . . ?
C41 C42 H42 119.2 . . ?
C43 C42 H42 119.2 . . ?
O6 C43 C42 122.7(4) . . ?
O6 C43 C44 116.9(4) . . ?
C42 C43 C44 120.3(4) . . ?
C53 C44 C45 118.7(4) . . ?
C53 C44 C43 118.9(4) . . ?
C45 C44 C43 122.3(4) . . ?
C46 C45 C44 120.4(5) . . ?
C46 C45 H45 119.8 . . ?
C44 C45 H45 119.8 . . ?
C45 C46 C47 121.9(5) . . ?
C45 C46 H46 119.1 . . ?
C47 C46 H46 119.1 . . ?
C52 C47 C48 118.8(5) . . ?
C52 C47 C46 117.9(5) . . ?
C48 C47 C46 123.3(5) . . ?
C49 C48 C47 120.7(6) . . ?
C49 C48 H48 119.6 . . ?
C47 C48 H48 119.6 . . ?
C48 C49 C50 121.5(6) . . ?
C48 C49 H49 119.3 . . ?
C50 C49 H49 119.3 . . ?
C51 C50 C49 119.3(7) . . ?
C51 C50 H50 120.4 . . ?
C49 C50 H50 120.4 . . ?
C50 C51 C52 121.7(6) . . ?
C50 C51 H51 119.1 . . ?
C52 C51 H51 119.1 . . ?
C53 C52 C47 119.2(5) . . ?
C53 C52 C51 122.8(5) . . ?
C47 C52 C51 117.9(5) . . ?
C44 C53 C52 121.9(4) . . ?
C44 C53 H53 119.1 . . ?
C52 C53 H53 119.1 . . ?
F12 C54 F11 105.7(8) . . ?
F12 C54 C55 110.6(9) . . ?
F11 C54 C55 100.9(9) . . ?
F12 C54 C41 113.4(7) . . ?
F11 C54 C41 117.8(8) . . ?
C55 C54 C41 107.8(8) . . ?
F13 C55 F14 107.1(8) . . ?
F13 C55 F15 111.5(9) . . ?
F14 C55 F15 112.5(8) . . ?
F13 C55 C54 116.9(8) . . ?
F14 C55 C54 110.4(9) . . ?
F15 C55 C54 98.5(8) . . ?
F14' C55' F13' 107.6(11) . . ?
F14' C55' F15' 106.2(10) . . ?
F13' C55' F15' 106.9(10) . . ?
F14' C55' C54' 119.3(17) . . ?
F13' C55' C54' 97.9(16) . . ?
F15' C55' C54' 117.6(17) . . ?
F11' C54' F12' 106.7(11) . . ?
F11' C54' C55' 102.2(17) . . ?
F12' C54' C55' 118(4) . . ?
F11' C54' C41 108.9(17) . . ?
F12' C54' C41 113(3) . . ?
C55' C54' C41 108.1(13) . . ?
C5 N1 C1 118.6(5) . . ?
C5 N1 Eu1 122.5(4) . . ?
C1 N1 Eu1 118.5(4) . . ?
C10 N2 C6 119.6(5) . . ?
C10 N2 Eu1 119.6(4) . . ?
C6 N2 Eu1 120.7(4) . . ?
C11 O1 Eu1 134.3(3) . . ?
C13 O2 Eu1 137.8(3) . . ?
C26 O3 Eu1 131.5(3) . . ?
C28 O4 Eu1 135.6(3) . . ?
C41 O5 Eu1 134.0(3) . . ?
C43 O6 Eu1 139.4(3) . . ?
O4 Eu1 O6 149.53(11) . . ?
O4 Eu1 O2 83.79(13) . . ?
O6 Eu1 O2 75.49(13) . . ?
O4 Eu1 O5 138.62(12) . . ?
O6 Eu1 O5 71.24(12) . . ?
O2 Eu1 O5 113.47(14) . . ?
O4 Eu1 O1 76.80(14) . . ?
O6 Eu1 O1 115.98(14) . . ?
O2 Eu1 O1 71.32(12) . . ?
O5 Eu1 O1 74.30(16) . . ?
O4 Eu1 O3 71.92(12) . . ?
O6 Eu1 O3 81.92(12) . . ?
O2 Eu1 O3 77.85(12) . . ?
O5 Eu1 O3 146.13(14) . . ?
O1 Eu1 O3 137.90(13) . . ?
O4 Eu1 N1 75.36(13) . . ?
O6 Eu1 N1 131.35(13) . . ?
O2 Eu1 N1 150.18(15) . . ?
O5 Eu1 N1 72.37(13) . . ?
O1 Eu1 N1 83.17(14) . . ?
O3 Eu1 N1 114.39(13) . . ?
O4 Eu1 N2 105.94(14) . . ?
O6 Eu1 N2 80.62(14) . . ?
O2 Eu1 N2 145.03(14) . . ?
O5 Eu1 N2 81.62(16) . . ?
O1 Eu1 N2 143.23(14) . . ?
O3 Eu1 N2 73.79(13) . . ?
N1 Eu1 N2 63.03(15) . . ?
C56 Cl1 C56' 28.3(5) . . ?
Cl1 C56 Cl3 108.3(8) . . ?
Cl1 C56 Cl2 97.5(6) . . ?
Cl3 C56 Cl2 110.1(8) . . ?
Cl1 C56 H56 113.3 . . ?
Cl3 C56 H56 113.3 . . ?
Cl2 C56 H56 113.3 . . ?
Cl1 C56' Cl3' 122.2(8) . . ?
Cl1 C56' Cl2' 103.7(6) . . ?
Cl3' C56' Cl2' 105.3(8) . . ?
Cl1 C56' H56' 108.3 . . ?
Cl3' C56' H56' 108.3 . . ?
Cl2' C56' H56' 108.3 . . ?
O7' C57 C58 61(2) 2_657 . ?
O7' C58 O7 52(2) . . ?
O7' C58 O7' 108(3) . 2_657 ?
O7 C58 O7' 156(4) . 2_657 ?
O7' C58 C57 120.6(13) . . ?
O7 C58 C57 119.5(13) . . ?
O7' C58 C57 57.1(19) 2_657 . ?
O7' C58 C58 59(2) . 2_657 ?
O7 C58 C58 110(3) . 2_657 ?
O7' C58 C58 48.8(18) 2_657 2_657 ?
C57 C58 C58 85.1(18) . 2_657 ?
C58 O7' C57 103(3) . 2_657 ?
C58 O7' C58 72(3) . 2_657 ?
C57 O7' C58 62(2) 2_657 2_657 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.355(8) . ?
C1 C2 1.368(8) . ?
C1 H1 0.9300 . ?
C2 C3 1.348(11) . ?
C2 H2 0.9300 . ?
C3 C4 1.377(11) . ?
C3 H3 0.9300 . ?
C4 C5 1.404(8) . ?
C4 H4 0.9300 . ?
C5 N1 1.330(7) . ?
C5 C6 1.478(9) . ?
C6 N2 1.348(7) . ?
C6 C7 1.384(8) . ?
C7 C8 1.362(11) . ?
C7 H7 0.9300 . ?
C8 C9 1.398(11) . ?
C8 H8 0.9300 . ?
C9 C10 1.385(9) . ?
C9 H9 0.9300 . ?
C10 N2 1.330(8) . ?
C10 H10 0.9300 . ?
C11 O1 1.253(7) . ?
C11 C12 1.371(8) . ?
C11 C24 1.578(9) . ?
C12 C13 1.416(8) . ?
C12 H12 0.9300 . ?
C13 O2 1.252(6) . ?
C13 C14 1.490(7) . ?
C14 C23 1.368(7) . ?
C14 C15 1.418(7) . ?
C15 C16 1.333(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.407(9) . ?
C16 H16 0.9300 . ?
C17 C22 1.416(8) . ?
C17 C18 1.417(8) . ?
C18 C19 1.352(11) . ?
C18 H18 0.9300 . ?
C19 C20 1.409(11) . ?
C19 H19 0.9300 . ?
C20 C21 1.362(9) . ?
C20 H20 0.9300 . ?
C21 C22 1.413(8) . ?
C21 H21 0.9300 . ?
C24 F2 1.339(8) . ?
C24 F1 1.351(9) . ?
C24 C25 1.427(14) . ?
C22 C23 1.419(7) . ?
C23 H23 0.9300 . ?
C25 F3 1.260(14) . ?
C25 F4 1.346(15) . ?
C25 F5 1.361(12) . ?
C30 C31 1.361(8) . ?
C30 C29 1.416(7) . ?
C30 H30 0.9300 . ?
C31 C32 1.398(9) . ?
C31 H31 0.9300 . ?
C32 C33 1.402(9) . ?
C32 C37 1.430(8) . ?
C33 C34 1.350(11) . ?
C33 H33 0.9300 . ?
C34 C35 1.388(12) . ?
C34 H34 0.9300 . ?
C35 C36 1.355(9) . ?
C35 H35 0.9300 . ?
C36 C37 1.405(8) . ?
C36 H36 0.9300 . ?
C37 C38 1.402(7) . ?
C38 C29 1.371(7) . ?
C38 H38 0.9300 . ?
C29 C28 1.497(7) . ?
C28 O4 1.250(6) . ?
C28 C27 1.406(7) . ?
C27 C26 1.369(7) . ?
C27 H27 0.9300 . ?
C26 O3 1.256(6) . ?
C26 C39 1.535(7) . ?
C39 F7 1.337(7) . ?
C39 F6 1.354(8) . ?
C39 C40 1.492(11) . ?
C40 F8 1.288(9) . ?
C40 F10 1.323(12) . ?
C40 F9 1.365(9) . ?
C41 O5 1.237(7) . ?
C41 C42 1.368(8) . ?
C41 C54' 1.575(19) . ?
C41 C54 1.641(11) . ?
C42 C43 1.410(7) . ?
C42 H42 0.9300 . ?
C43 O6 1.244(5) . ?
C43 C44 1.483(7) . ?
C44 C53 1.379(7) . ?
C44 C45 1.409(7) . ?
C45 C46 1.359(8) . ?
C45 H45 0.9300 . ?
C46 C47 1.415(8) . ?
C46 H46 0.9300 . ?
C47 C52 1.414(7) . ?
C47 C48 1.414(8) . ?
C48 C49 1.346(11) . ?
C48 H48 0.9300 . ?
C49 C50 1.398(11) . ?
C49 H49 0.9300 . ?
C50 C51 1.353(9) . ?
C50 H50 0.9300 . ?
C51 C52 1.423(8) . ?
C51 H51 0.9300 . ?
C52 C53 1.400(7) . ?
C53 H53 0.9300 . ?
C54 F12 1.332(8) . ?
C54 F11 1.383(9) . ?
C54 C55 1.384(17) . ?
C55 F13 1.294(9) . ?
C55 F14 1.340(8) . ?
C55 F15 1.349(9) . ?
C55' F14' 1.328(10) . ?
C55' F13' 1.328(10) . ?
C55' F15' 1.342(10) . ?
C55' C54' 1.47(3) . ?
C54' F11' 1.327(10) . ?
C54' F12' 1.335(10) . ?
N1 Eu1 2.554(4) . ?
N2 Eu1 2.570(4) . ?
O1 Eu1 2.367(4) . ?
O2 Eu1 2.352(3) . ?
O3 Eu1 2.374(3) . ?
O4 Eu1 2.336(3) . ?
O5 Eu1 2.359(4) . ?
O6 Eu1 2.343(3) . ?
Cl1 C56 1.713(9) . ?
Cl1 C56' 1.728(9) . ?
C56 Cl3 1.714(9) . ?
C56 Cl2 1.730(9) . ?
C56 H56 0.9800 . ?
C56' Cl3' 1.729(9) . ?
C56' Cl2' 1.749(10) . ?
C56' H56' 0.9800 . ?
C57 O7' 1.45(5) 2_657 ?
C57 C58 1.516(10) . ?
C58 O7' 1.331(10) . ?
C58 O7 1.331(10) . ?
C58 O7' 1.51(6) 2_657 ?
C58 C58 1.69(7) 2_657 ?
O7' C57 1.45(5) 2_657 ?
O7' C58 1.51(6) 2_657 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 0.5(11) . . . . ?
C1 C2 C3 C4 -0.9(11) . . . . ?
C2 C3 C4 C5 1.3(11) . . . . ?
C3 C4 C5 N1 -1.2(9) . . . . ?
C3 C4 C5 C6 180.0(6) . . . . ?
N1 C5 C6 N2 1.6(6) . . . . ?
C4 C5 C6 N2 -179.5(5) . . . . ?
N1 C5 C6 C7 -177.5(5) . . . . ?
C4 C5 C6 C7 1.3(8) . . . . ?
N2 C6 C7 C8 0.5(9) . . . . ?
C5 C6 C7 C8 179.6(6) . . . . ?
C6 C7 C8 C9 -0.9(11) . . . . ?
C7 C8 C9 C10 0.8(11) . . . . ?
C8 C9 C10 N2 -0.1(11) . . . . ?
O1 C11 C12 C13 -0.1(12) . . . . ?
C24 C11 C12 C13 177.1(6) . . . . ?
C11 C12 C13 O2 3.5(10) . . . . ?
C11 C12 C13 C14 -173.0(6) . . . . ?
O2 C13 C14 C23 -6.8(7) . . . . ?
C12 C13 C14 C23 169.9(5) . . . . ?
O2 C13 C14 C15 177.7(5) . . . . ?
C12 C13 C14 C15 -5.6(8) . . . . ?
C23 C14 C15 C16 -1.9(9) . . . . ?
C13 C14 C15 C16 173.6(6) . . . . ?
C14 C15 C16 C17 0.3(10) . . . . ?
C15 C16 C17 C22 1.5(10) . . . . ?
C15 C16 C17 C18 -176.8(7) . . . . ?
C16 C17 C18 C19 176.4(7) . . . . ?
C22 C17 C18 C19 -2.0(11) . . . . ?
C17 C18 C19 C20 1.2(13) . . . . ?
C18 C19 C20 C21 0.1(14) . . . . ?
C19 C20 C21 C22 -0.6(13) . . . . ?
O1 C11 C24 F2 161.7(7) . . . . ?
C12 C11 C24 F2 -15.9(10) . . . . ?
O1 C11 C24 F1 45.5(9) . . . . ?
C12 C11 C24 F1 -132.1(7) . . . . ?
O1 C11 C24 C25 -72.7(10) . . . . ?
C12 C11 C24 C25 109.7(10) . . . . ?
C20 C21 C22 C17 -0.3(10) . . . . ?
C20 C21 C22 C23 -175.4(7) . . . . ?
C16 C17 C22 C21 -176.9(6) . . . . ?
C18 C17 C22 C21 1.5(9) . . . . ?
C16 C17 C22 C23 -1.6(8) . . . . ?
C18 C17 C22 C23 176.8(6) . . . . ?
C15 C14 C23 C22 1.7(8) . . . . ?
C13 C14 C23 C22 -174.0(5) . . . . ?
C21 C22 C23 C14 175.2(6) . . . . ?
C17 C22 C23 C14 0.0(8) . . . . ?
F2 C24 C25 F3 -175.1(10) . . . . ?
F1 C24 C25 F3 -63.8(12) . . . . ?
C11 C24 C25 F3 57.9(14) . . . . ?
F2 C24 C25 F4 67.7(10) . . . . ?
F1 C24 C25 F4 179.0(8) . . . . ?
C11 C24 C25 F4 -59.3(11) . . . . ?
F2 C24 C25 F5 -48.8(13) . . . . ?
F1 C24 C25 F5 62.5(12) . . . . ?
C11 C24 C25 F5 -175.8(9) . . . . ?
C29 C30 C31 C32 -0.2(9) . . . . ?
C30 C31 C32 C33 179.9(6) . . . . ?
C30 C31 C32 C37 -1.1(9) . . . . ?
C31 C32 C33 C34 178.5(7) . . . . ?
C37 C32 C33 C34 -0.5(10) . . . . ?
C32 C33 C34 C35 0.3(11) . . . . ?
C33 C34 C35 C36 0.7(11) . . . . ?
C34 C35 C36 C37 -1.6(10) . . . . ?
C35 C36 C37 C38 -179.7(5) . . . . ?
C35 C36 C37 C32 1.3(8) . . . . ?
C31 C32 C37 C38 1.7(7) . . . . ?
C33 C32 C37 C38 -179.3(5) . . . . ?
C31 C32 C37 C36 -179.4(5) . . . . ?
C33 C32 C37 C36 -0.3(8) . . . . ?
C36 C37 C38 C29 -179.8(5) . . . . ?
C32 C37 C38 C29 -0.9(7) . . . . ?
C37 C38 C29 C30 -0.4(7) . . . . ?
C37 C38 C29 C28 177.2(4) . . . . ?
C31 C30 C29 C38 1.0(8) . . . . ?
C31 C30 C29 C28 -176.5(5) . . . . ?
C38 C29 C28 O4 0.3(6) . . . . ?
C30 C29 C28 O4 177.8(4) . . . . ?
C38 C29 C28 C27 -179.2(4) . . . . ?
C30 C29 C28 C27 -1.6(7) . . . . ?
O4 C28 C27 C26 -1.1(8) . . . . ?
C29 C28 C27 C26 178.3(5) . . . . ?
C28 C27 C26 O3 -5.2(9) . . . . ?
C28 C27 C26 C39 174.4(5) . . . . ?
O3 C26 C39 F7 162.9(5) . . . . ?
C27 C26 C39 F7 -16.8(8) . . . . ?
O3 C26 C39 F6 46.1(7) . . . . ?
C27 C26 C39 F6 -133.6(6) . . . . ?
O3 C26 C39 C40 -74.7(7) . . . . ?
C27 C26 C39 C40 105.6(7) . . . . ?
F7 C39 C40 F8 -172.8(8) . . . . ?
F6 C39 C40 F8 -61.4(9) . . . . ?
C26 C39 C40 F8 61.7(10) . . . . ?
F7 C39 C40 F10 66.5(8) . . . . ?
F6 C39 C40 F10 177.9(6) . . . . ?
C26 C39 C40 F10 -59.0(8) . . . . ?
F7 C39 C40 F9 -53.6(9) . . . . ?
F6 C39 C40 F9 57.8(9) . . . . ?
C26 C39 C40 F9 -179.1(7) . . . . ?
O5 C41 C42 C43 -2.5(13) . . . . ?
C54' C41 C42 C43 157.5(8) . . . . ?
C54 C41 C42 C43 -166.0(7) . . . . ?
C41 C42 C43 O6 -3.9(9) . . . . ?
C41 C42 C43 C44 177.1(6) . . . . ?
O6 C43 C44 C53 -6.5(7) . . . . ?
C42 C43 C44 C53 172.6(5) . . . . ?
O6 C43 C44 C45 170.9(5) . . . . ?
C42 C43 C44 C45 -10.0(7) . . . . ?
C53 C44 C45 C46 0.0(8) . . . . ?
C43 C44 C45 C46 -177.4(5) . . . . ?
C44 C45 C46 C47 0.7(9) . . . . ?
C45 C46 C47 C52 -1.3(8) . . . . ?
C45 C46 C47 C48 177.8(6) . . . . ?
C52 C47 C48 C49 1.5(10) . . . . ?
C46 C47 C48 C49 -177.6(7) . . . . ?
C47 C48 C49 C50 -2.1(12) . . . . ?
C48 C49 C50 C51 0.9(13) . . . . ?
C49 C50 C51 C52 0.9(12) . . . . ?
C48 C47 C52 C53 -177.9(5) . . . . ?
C46 C47 C52 C53 1.3(8) . . . . ?
C48 C47 C52 C51 0.3(8) . . . . ?
C46 C47 C52 C51 179.4(5) . . . . ?
C50 C51 C52 C53 176.6(7) . . . . ?
C50 C51 C52 C47 -1.5(10) . . . . ?
C45 C44 C53 C52 0.0(7) . . . . ?
C43 C44 C53 C52 177.4(4) . . . . ?
C47 C52 C53 C44 -0.6(8) . . . . ?
C51 C52 C53 C44 -178.7(5) . . . . ?
O5 C41 C54 F12 -162.7(8) . . . . ?
C42 C41 C54 F12 4.0(12) . . . . ?
C54' C41 C54 F12 94.5(14) . . . . ?
O5 C41 C54 F11 -38.6(12) . . . . ?
C42 C41 C54 F11 128.1(9) . . . . ?
C54' C41 C54 F11 -141.4(16) . . . . ?
O5 C41 C54 C55 74.5(9) . . . . ?
C42 C41 C54 C55 -118.8(8) . . . . ?
C54' C41 C54 C55 -28.3(12) . . . . ?
F12 C54 C55 F13 178.7(8) . . . . ?
F11 C54 C55 F13 67.2(11) . . . . ?
C41 C54 C55 F13 -56.8(10) . . . . ?
F12 C54 C55 F14 56.1(11) . . . . ?
F11 C54 C55 F14 -55.4(10) . . . . ?
C41 C54 C55 F14 -179.4(7) . . . . ?
F12 C54 C55 F15 -61.9(9) . . . . ?
F11 C54 C55 F15 -173.4(8) . . . . ?
C41 C54 C55 F15 62.6(8) . . . . ?
F14' C55' C54' F11' -48(2) . . . . ?
F13' C55' C54' F11' -163.6(17) . . . . ?
F15' C55' C54' F11' 83(2) . . . . ?
F14' C55' C54' F12' 68(3) . . . . ?
F13' C55' C54' F12' -47(3) . . . . ?
F15' C55' C54' F12' -161(3) . . . . ?
F14' C55' C54' C41 -163.1(13) . . . . ?
F13' C55' C54' C41 81.6(14) . . . . ?
F15' C55' C54' C41 -32.2(18) . . . . ?
O5 C41 C54' F11' -165.5(16) . . . . ?
C42 C41 C54' F11' 31.0(19) . . . . ?
C54 C41 C54' F11' -75.4(18) . . . . ?
O5 C41 C54' F12' 76(2) . . . . ?
C42 C41 C54' F12' -87(3) . . . . ?
C54 C41 C54' F12' 166(3) . . . . ?
O5 C41 C54' C55' -55.3(15) . . . . ?
C42 C41 C54' C55' 141.2(11) . . . . ?
C54 C41 C54' C55' 34.8(11) . . . . ?
C4 C5 N1 C1 0.8(7) . . . . ?
C6 C5 N1 C1 179.7(5) . . . . ?
C4 C5 N1 Eu1 173.8(4) . . . . ?
C6 C5 N1 Eu1 -7.3(6) . . . . ?
C2 C1 N1 C5 -0.4(9) . . . . ?
C2 C1 N1 Eu1 -173.8(5) . . . . ?
C9 C10 N2 C6 -0.3(9) . . . . ?
C9 C10 N2 Eu1 176.1(5) . . . . ?
C7 C6 N2 C10 0.2(8) . . . . ?
C5 C6 N2 C10 -179.0(5) . . . . ?
C7 C6 N2 Eu1 -176.3(4) . . . . ?
C5 C6 N2 Eu1 4.6(6) . . . . ?
C12 C11 O1 Eu1 10.8(11) . . . . ?
C24 C11 O1 Eu1 -166.5(4) . . . . ?
C12 C13 O2 Eu1 -19.0(8) . . . . ?
C14 C13 O2 Eu1 157.6(4) . . . . ?
C27 C26 O3 Eu1 -10.9(8) . . . . ?
C39 C26 O3 Eu1 169.4(3) . . . . ?
C27 C28 O4 Eu1 25.3(7) . . . . ?
C29 C28 O4 Eu1 -154.1(3) . . . . ?
C42 C41 O5 Eu1 0.6(13) . . . . ?
C54' C41 O5 Eu1 -159.7(7) . . . . ?
C54 C41 O5 Eu1 165.4(6) . . . . ?
C42 C43 O6 Eu1 13.5(8) . . . . ?
C44 C43 O6 Eu1 -167.4(3) . . . . ?
C28 O4 Eu1 O6 4.3(6) . . . . ?
C28 O4 Eu1 O2 51.3(4) . . . . ?
C28 O4 Eu1 O5 170.2(4) . . . . ?
C28 O4 Eu1 O1 123.5(5) . . . . ?
C28 O4 Eu1 O3 -27.9(4) . . . . ?
C28 O4 Eu1 N1 -150.2(5) . . . . ?
C28 O4 Eu1 N2 -94.4(5) . . . . ?
C43 O6 Eu1 O4 158.8(4) . . . . ?
C43 O6 Eu1 O2 110.1(5) . . . . ?
C43 O6 Eu1 O5 -11.4(5) . . . . ?
C43 O6 Eu1 O1 49.7(5) . . . . ?
C43 O6 Eu1 O3 -170.4(5) . . . . ?
C43 O6 Eu1 N1 -54.9(6) . . . . ?
C43 O6 Eu1 N2 -95.6(5) . . . . ?
C13 O2 Eu1 O4 97.9(5) . . . . ?
C13 O2 Eu1 O6 -104.6(5) . . . . ?
C13 O2 Eu1 O5 -42.9(5) . . . . ?
C13 O2 Eu1 O1 19.8(5) . . . . ?
C13 O2 Eu1 O3 170.7(5) . . . . ?
C13 O2 Eu1 N1 52.5(6) . . . . ?
C13 O2 Eu1 N2 -153.0(4) . . . . ?
C41 O5 Eu1 O4 -168.7(6) . . . . ?
C41 O5 Eu1 O6 3.8(7) . . . . ?
C41 O5 Eu1 O2 -60.4(7) . . . . ?
C41 O5 Eu1 O1 -121.4(7) . . . . ?
C41 O5 Eu1 O3 43.2(8) . . . . ?
C41 O5 Eu1 N1 150.9(7) . . . . ?
C41 O5 Eu1 N2 86.7(7) . . . . ?
C11 O1 Eu1 O4 -102.6(6) . . . . ?
C11 O1 Eu1 O6 47.9(6) . . . . ?
C11 O1 Eu1 O2 -14.8(6) . . . . ?
C11 O1 Eu1 O5 107.3(6) . . . . ?
C11 O1 Eu1 O3 -59.9(7) . . . . ?
C11 O1 Eu1 N1 -179.1(6) . . . . ?
C11 O1 Eu1 N2 158.3(5) . . . . ?
C26 O3 Eu1 O4 19.5(4) . . . . ?
C26 O3 Eu1 O6 -144.6(4) . . . . ?
C26 O3 Eu1 O2 -67.8(4) . . . . ?
C26 O3 Eu1 O5 178.0(4) . . . . ?
C26 O3 Eu1 O1 -24.5(5) . . . . ?
C26 O3 Eu1 N1 83.4(4) . . . . ?
C26 O3 Eu1 N2 132.8(4) . . . . ?
C5 N1 Eu1 O4 123.6(4) . . . . ?
C1 N1 Eu1 O4 -63.3(4) . . . . ?
C5 N1 Eu1 O6 -39.5(4) . . . . ?
C1 N1 Eu1 O6 133.6(4) . . . . ?
C5 N1 Eu1 O2 170.8(3) . . . . ?
C1 N1 Eu1 O2 -16.2(5) . . . . ?
C5 N1 Eu1 O5 -82.6(4) . . . . ?
C1 N1 Eu1 O5 90.4(4) . . . . ?
C5 N1 Eu1 O1 -158.3(4) . . . . ?
C1 N1 Eu1 O1 14.8(4) . . . . ?
C5 N1 Eu1 O3 61.7(4) . . . . ?
C1 N1 Eu1 O3 -125.2(4) . . . . ?
C5 N1 Eu1 N2 6.8(3) . . . . ?
C1 N1 Eu1 N2 179.8(4) . . . . ?
C10 N2 Eu1 O4 114.1(4) . . . . ?
C6 N2 Eu1 O4 -69.5(4) . . . . ?
C10 N2 Eu1 O6 -35.4(4) . . . . ?
C6 N2 Eu1 O6 141.0(4) . . . . ?
C10 N2 Eu1 O2 11.8(6) . . . . ?
C6 N2 Eu1 O2 -171.8(3) . . . . ?
C10 N2 Eu1 O5 -107.6(4) . . . . ?
C6 N2 Eu1 O5 68.8(4) . . . . ?
C10 N2 Eu1 O1 -156.8(4) . . . . ?
C6 N2 Eu1 O1 19.6(5) . . . . ?
C10 N2 Eu1 O3 48.8(4) . . . . ?
C6 N2 Eu1 O3 -134.7(4) . . . . ?
C10 N2 Eu1 N1 177.9(5) . . . . ?
C6 N2 Eu1 N1 -5.6(3) . . . . ?
C56' Cl1 C56 Cl3 -25.7(11) . . . . ?
C56' Cl1 C56 Cl2 -139.9(18) . . . . ?
C56 Cl1 C56' Cl3' 64.0(14) . . . . ?
C56 Cl1 C56' Cl2' -177.7(19) . . . . ?
O7' C57 C58 O7' 92(4) 2_657 . . . ?
O7' C57 C58 O7 153(5) 2_657 . . . ?
O7' C57 C58 C58 43(2) 2_657 . . 2_657 ?
O7 C58 O7' C57 139(3) . . . 2_657 ?
O7' C58 O7' C57 -54(2) 2_657 . . 2_657 ?
C57 C58 O7' C57 -116(3) . . . 2_657 ?
C58 C58 O7' C57 -54(2) 2_657 . . 2_657 ?
O7 C58 O7' C58 -167(3) . . . 2_657 ?
O7' C58 O7' C58 0.000(6) 2_657 . . 2_657 ?
C57 C58 O7' C58 -62(3) . . . 2_657 ?
