#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:06:12 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179093 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/55/4305529.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4305529
loop_
_publ_author_name
'Yi Liu'
'Ling Chen'
'Long-Hua Li'
'Li-Ming Wu'
'Oksana Ya. Zelinska'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
Structures and Physical Properties of Rare-Earth Zinc Antimonides
Pr6Zn1+xSb14+yandRE6Zn1+xSb14 (RE= Sm, Gd-Ho)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11930
_journal_page_last               11941
_journal_paper_doi               10.1021/ic800524d
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'Sb28 Tb12 Zn2.92'
_chemical_formula_weight         5506.92
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           71
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-I 2 2'
_symmetry_space_group_name_H-M   'I m m m'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'by CrystalClear v1.3'
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   4.1412(4)
_cell_length_b                   14.9015(16)
_cell_length_c                   18.6780(17)
_cell_measurement_reflns_used    1695
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      2.1804
_cell_volume                     1152.6(2)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 14.6306
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0447
_diffrn_reflns_av_sigmaI/netI    0.0309
_diffrn_reflns_limit_h_max       5
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            4485
_diffrn_reflns_theta_full        27.47
_diffrn_reflns_theta_max         27.47
_diffrn_reflns_theta_min         2.18
_exptl_absorpt_coefficient_mu    35.681
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.2471
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    7.934
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2296
_exptl_crystal_size_max          0.2500
_exptl_crystal_size_mid          0.2000
_exptl_crystal_size_min          0.1800
_refine_diff_density_max         5.114
_refine_diff_density_min         -3.415
_refine_diff_density_rms         0.515
_refine_ls_extinction_coef       0.00144(7)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_matrix_type           full
_refine_ls_number_parameters     43
_refine_ls_number_reflns         805
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.0335
_refine_ls_R_factor_gt           0.0300
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0416P)²+18.2765P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0735
_refine_ls_wR_factor_ref         0.0758
_reflns_number_gt                728
_reflns_number_total             805
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic800524d_si_001_3.cif
_cod_data_source_block           Tb
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4305529
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.0000 0.0000 0.32259(4) 0.0088(2) Uani 1 4 d S . .
Tb2 Tb 0.0000 0.13845(3) 0.13642(3) 0.0068(2) Uani 1 2 d S . .
Zn1 Zn 0.0000 0.26233(18) 0.0000 0.0116(9) Uani 0.730(9) 4 d SP . .
Sb1 Sb 0.0000 0.0000 0.0000 0.0457(7) Uani 1 8 d S . .
Sb2 Sb 0.5000 0.5000 0.0000 0.0233(4) Uani 1 8 d S . .
Sb3 Sb 0.0000 0.36957(6) 0.10132(5) 0.0182(2) Uani 1 2 d S . .
Sb4 Sb 0.0000 0.21124(5) 0.30269(4) 0.0076(2) Uani 1 2 d S . .
Sb5 Sb 0.0000 0.34790(7) 0.5000 0.0099(3) Uani 1 4 d S . .
Sb6 Sb 0.5000 0.0000 0.19751(6) 0.0064(3) Uani 1 4 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Sb6 Tb1 Sb6 83.10(3) 1_455 . ?
Sb6 Tb1 Sb4 84.967(16) 1_455 . ?
Sb6 Tb1 Sb4 84.967(16) . . ?
Sb6 Tb1 Sb4 84.967(16) 1_455 2 ?
Sb6 Tb1 Sb4 84.967(16) . 2 ?
Sb4 Tb1 Sb4 166.54(4) . 2 ?
Sb6 Tb1 Sb3 140.12(2) 1_455 13 ?
Sb6 Tb1 Sb3 84.403(19) . 13 ?
Sb4 Tb1 Sb3 56.265(17) . 13 ?
Sb4 Tb1 Sb3 131.321(19) 2 13 ?
Sb6 Tb1 Sb3 84.403(19) 1_455 14_445 ?
Sb6 Tb1 Sb3 140.12(2) . 14_445 ?
Sb4 Tb1 Sb3 131.321(19) . 14_445 ?
Sb4 Tb1 Sb3 56.265(17) 2 14_445 ?
Sb3 Tb1 Sb3 126.83(4) 13 14_445 ?
Sb6 Tb1 Sb3 84.403(19) 1_455 13_455 ?
Sb6 Tb1 Sb3 140.12(2) . 13_455 ?
Sb4 Tb1 Sb3 56.265(17) . 13_455 ?
Sb4 Tb1 Sb3 131.321(19) 2 13_455 ?
Sb3 Tb1 Sb3 81.39(3) 13 13_455 ?
Sb3 Tb1 Sb3 75.47(3) 14_445 13_455 ?
Sb6 Tb1 Sb3 140.12(2) 1_455 14_545 ?
Sb6 Tb1 Sb3 84.403(19) . 14_545 ?
Sb4 Tb1 Sb3 131.321(19) . 14_545 ?
Sb4 Tb1 Sb3 56.265(17) 2 14_545 ?
Sb3 Tb1 Sb3 75.47(3) 13 14_545 ?
Sb3 Tb1 Sb3 81.39(3) 14_445 14_545 ?
Sb3 Tb1 Sb3 126.83(4) 13_455 14_545 ?
Sb6 Tb1 Sb2 138.449(17) 1_455 5_445 ?
Sb6 Tb1 Sb2 138.449(17) . 5_445 ?
Sb4 Tb1 Sb2 96.73(2) . 5_445 ?
Sb4 Tb1 Sb2 96.73(2) 2 5_445 ?
Sb3 Tb1 Sb2 63.41(2) 13 5_445 ?
Sb3 Tb1 Sb2 63.41(2) 14_445 5_445 ?
Sb3 Tb1 Sb2 63.41(2) 13_455 5_445 ?
Sb3 Tb1 Sb2 63.41(2) 14_545 5_445 ?
Sb6 Tb2 Sb6 82.582(19) 1_455 . ?
Sb6 Tb2 Zn1 132.86(2) 1_455 . ?
Sb6 Tb2 Zn1 132.86(2) . . ?
Sb6 Tb2 Sb4 138.17(3) 1_455 13 ?
Sb6 Tb2 Sb4 84.585(16) . 13 ?
Zn1 Tb2 Sb4 83.06(3) . 13 ?
Sb6 Tb2 Sb4 84.585(16) 1_455 13_455 ?
Sb6 Tb2 Sb4 138.17(3) . 13_455 ?
Zn1 Tb2 Sb4 83.06(3) . 13_455 ?
Sb4 Tb2 Sb4 79.00(2) 13 13_455 ?
Sb6 Tb2 Sb1 82.46(2) 1_455 . ?
Sb6 Tb2 Sb1 82.46(2) . . ?
Zn1 Tb2 Sb1 74.92(4) . . ?
Sb4 Tb2 Sb1 134.787(15) 13 . ?
Sb4 Tb2 Sb1 134.787(15) 13_455 . ?
Sb6 Tb2 Sb4 82.73(2) 1_455 . ?
Sb6 Tb2 Sb4 82.73(2) . . ?
Zn1 Tb2 Sb4 124.83(4) . . ?
Sb4 Tb2 Sb4 56.175(19) 13 . ?
Sb4 Tb2 Sb4 56.175(19) 13_455 . ?
Sb1 Tb2 Sb4 160.25(2) . . ?
Sb6 Tb2 Sb5 84.66(2) 1_455 13_455 ?
Sb6 Tb2 Sb5 137.53(3) . 13_455 ?
Zn1 Tb2 Sb5 48.43(3) . 13_455 ?
Sb4 Tb2 Sb5 128.93(3) 13 13_455 ?
Sb4 Tb2 Sb5 80.079(19) 13_455 13_455 ?
Sb1 Tb2 Sb5 55.730(18) . 13_455 ?
Sb4 Tb2 Sb5 135.308(16) . 13_455 ?
Sb6 Tb2 Sb5 137.53(3) 1_455 13 ?
Sb6 Tb2 Sb5 84.66(2) . 13 ?
Zn1 Tb2 Sb5 48.43(3) . 13 ?
Sb4 Tb2 Sb5 80.079(19) 13 13 ?
Sb4 Tb2 Sb5 128.93(3) 13_455 13 ?
Sb1 Tb2 Sb5 55.730(18) . 13 ?
Sb4 Tb2 Sb5 135.308(16) . 13 ?
Sb5 Tb2 Sb5 78.018(15) 13_455 13 ?
Sb6 Tb2 Sb3 135.555(11) 1_455 . ?
Sb6 Tb2 Sb3 135.555(11) . . ?
Zn1 Tb2 Sb3 43.30(4) . . ?
Sb4 Tb2 Sb3 52.369(17) 13 . ?
Sb4 Tb2 Sb3 52.369(17) 13_455 . ?
Sb1 Tb2 Sb3 118.22(2) . . ?
Sb4 Tb2 Sb3 81.53(2) . . ?
Sb5 Tb2 Sb3 78.14(3) 13_455 . ?
Sb5 Tb2 Sb3 78.14(3) 13 . ?
Sb3 Zn1 Sb3 99.64(10) . 10 ?
Sb3 Zn1 Sb5 113.639(15) . 13_455 ?
Sb3 Zn1 Sb5 113.639(15) 10 13_455 ?
Sb3 Zn1 Sb5 113.639(15) . 13 ?
Sb3 Zn1 Sb5 113.639(15) 10 13 ?
Sb5 Zn1 Sb5 103.15(10) 13_455 13 ?
Sb3 Zn1 Tb2 175.74(9) . 10 ?
Sb3 Zn1 Tb2 76.10(3) 10 10 ?
Sb5 Zn1 Tb2 68.62(4) 13_455 10 ?
Sb5 Zn1 Tb2 68.62(4) 13 10 ?
Sb3 Zn1 Tb2 76.10(3) . . ?
Sb3 Zn1 Tb2 175.74(9) 10 . ?
Sb5 Zn1 Tb2 68.62(4) 13_455 . ?
Sb5 Zn1 Tb2 68.62(4) 13 . ?
Tb2 Zn1 Tb2 108.16(8) 10 . ?
Sb5 Sb1 Sb5 180.00(3) 13 5_444 ?
Sb5 Sb1 Sb5 84.83(3) 13 13_455 ?
Sb5 Sb1 Sb5 95.17(3) 5_444 13_455 ?
Sb5 Sb1 Sb5 95.17(3) 13 5_544 ?
Sb5 Sb1 Sb5 84.83(3) 5_444 5_544 ?
Sb5 Sb1 Sb5 180.00(3) 13_455 5_544 ?
Sb5 Sb1 Tb2 117.684(10) 13 9 ?
Sb5 Sb1 Tb2 62.316(10) 5_444 9 ?
Sb5 Sb1 Tb2 117.684(10) 13_455 9 ?
Sb5 Sb1 Tb2 62.316(10) 5_544 9 ?
Sb5 Sb1 Tb2 62.316(10) 13 . ?
Sb5 Sb1 Tb2 117.684(10) 5_444 . ?
Sb5 Sb1 Tb2 62.316(10) 13_455 . ?
Sb5 Sb1 Tb2 117.684(10) 5_544 . ?
Tb2 Sb1 Tb2 180.000(19) 9 . ?
Sb5 Sb1 Tb2 117.684(10) 13 2 ?
Sb5 Sb1 Tb2 62.316(10) 5_444 2 ?
Sb5 Sb1 Tb2 117.684(10) 13_455 2 ?
Sb5 Sb1 Tb2 62.316(10) 5_544 2 ?
Tb2 Sb1 Tb2 102.01(2) 9 2 ?
Tb2 Sb1 Tb2 77.99(2) . 2 ?
Sb5 Sb1 Tb2 62.316(10) 13 10 ?
Sb5 Sb1 Tb2 117.684(10) 5_444 10 ?
Sb5 Sb1 Tb2 62.316(10) 13_455 10 ?
Sb5 Sb1 Tb2 117.684(10) 5_544 10 ?
Tb2 Sb1 Tb2 77.99(2) 9 10 ?
Tb2 Sb1 Tb2 102.01(2) . 10 ?
Tb2 Sb1 Tb2 180.000(14) 2 10 ?
Tb1 Sb2 Tb1 180.0 5_554 13 ?
Zn1 Sb3 Sb4 101.43(4) . 13 ?
Zn1 Sb3 Sb4 101.43(4) . 13_455 ?
Sb4 Sb3 Sb4 87.59(3) 13 13_455 ?
Zn1 Sb3 Tb1 137.46(2) . 13 ?
Sb4 Sb3 Tb1 61.76(2) 13 13 ?
Sb4 Sb3 Tb1 115.43(4) 13_455 13 ?
Zn1 Sb3 Tb1 137.46(2) . 13_455 ?
Sb4 Sb3 Tb1 115.43(4) 13 13_455 ?
Sb4 Sb3 Tb1 61.76(2) 13_455 13_455 ?
Tb1 Sb3 Tb1 81.39(3) 13 13_455 ?
Zn1 Sb3 Tb2 60.60(5) . . ?
Sb4 Sb3 Tb2 59.51(2) 13 . ?
Sb4 Sb3 Tb2 59.51(2) 13_455 . ?
Tb1 Sb3 Tb2 121.17(2) 13 . ?
Tb1 Sb3 Tb2 121.17(2) 13_455 . ?
Sb3 Sb4 Sb3 87.59(3) 13 13_455 ?
Sb3 Sb4 Sb4 177.01(4) 13 13_455 ?
Sb3 Sb4 Sb4 93.936(17) 13_455 13_455 ?
Sb3 Sb4 Sb4 93.936(17) 13 13 ?
Sb3 Sb4 Sb4 177.01(4) 13_455 13 ?
Sb4 Sb4 Sb4 84.43(4) 13_455 13 ?
Sb3 Sb4 Tb1 61.97(2) 13 . ?
Sb3 Sb4 Tb1 61.97(2) 13_455 . ?
Sb4 Sb4 Tb1 116.56(3) 13_455 . ?
Sb4 Sb4 Tb1 116.56(3) 13 . ?
Sb3 Sb4 Tb2 68.12(2) 13 13 ?
Sb3 Sb4 Tb2 120.51(3) 13_455 13 ?
Sb4 Sb4 Tb2 113.12(3) 13_455 13 ?
Sb4 Sb4 Tb2 62.47(2) 13 13 ?
Tb1 Sb4 Tb2 129.967(19) . 13 ?
Sb3 Sb4 Tb2 120.51(3) 13 13_455 ?
Sb3 Sb4 Tb2 68.12(2) 13_455 13_455 ?
Sb4 Sb4 Tb2 62.47(2) 13_455 13_455 ?
Sb4 Sb4 Tb2 113.12(3) 13 13_455 ?
Tb1 Sb4 Tb2 129.967(19) . 13_455 ?
Tb2 Sb4 Tb2 79.00(2) 13 13_455 ?
Sb3 Sb4 Tb2 115.66(3) 13 . ?
Sb3 Sb4 Tb2 115.66(3) 13_455 . ?
Sb4 Sb4 Tb2 61.35(3) 13_455 . ?
Sb4 Sb4 Tb2 61.35(3) 13 . ?
Tb1 Sb4 Tb2 77.48(2) . . ?
Tb2 Sb4 Tb2 123.825(19) 13 . ?
Tb2 Sb4 Tb2 123.825(19) 13_455 . ?
Zn1 Sb5 Zn1 103.15(10) 13_455 13 ?
Zn1 Sb5 Sb1 170.84(6) 13_455 5 ?
Zn1 Sb5 Sb1 86.01(5) 13 5 ?
Zn1 Sb5 Sb1 86.01(5) 13_455 5_455 ?
Zn1 Sb5 Sb1 170.84(6) 13 5_455 ?
Sb1 Sb5 Sb1 84.83(3) 5 5_455 ?
Zn1 Sb5 Tb2 122.11(3) 13_455 6 ?
Zn1 Sb5 Tb2 62.95(2) 13 6 ?
Sb1 Sb5 Tb2 61.954(13) 5 6 ?
Sb1 Sb5 Tb2 112.27(3) 5_455 6 ?
Zn1 Sb5 Tb2 62.95(2) 13_455 13_455 ?
Zn1 Sb5 Tb2 122.11(3) 13 13_455 ?
Sb1 Sb5 Tb2 112.27(3) 5 13_455 ?
Sb1 Sb5 Tb2 61.954(13) 5_455 13_455 ?
Tb2 Sb5 Tb2 172.91(4) 6 13_455 ?
Zn1 Sb5 Tb2 62.95(2) 13_455 6_455 ?
Zn1 Sb5 Tb2 122.11(3) 13 6_455 ?
Sb1 Sb5 Tb2 112.27(3) 5 6_455 ?
Sb1 Sb5 Tb2 61.954(13) 5_455 6_455 ?
Tb2 Sb5 Tb2 78.018(15) 6 6_455 ?
Tb2 Sb5 Tb2 101.535(15) 13_455 6_455 ?
Zn1 Sb5 Tb2 122.11(3) 13_455 13 ?
Zn1 Sb5 Tb2 62.95(2) 13 13 ?
Sb1 Sb5 Tb2 61.954(13) 5 13 ?
Sb1 Sb5 Tb2 112.27(3) 5_455 13 ?
Tb2 Sb5 Tb2 101.535(15) 6 13 ?
Tb2 Sb5 Tb2 78.018(15) 13_455 13 ?
Tb2 Sb5 Tb2 172.91(4) 6_455 13 ?
Tb1 Sb6 Tb1 83.10(3) 1_655 . ?
Tb1 Sb6 Tb2 135.22(2) 1_655 2 ?
Tb1 Sb6 Tb2 80.471(14) . 2 ?
Tb1 Sb6 Tb2 80.471(14) 1_655 2_655 ?
Tb1 Sb6 Tb2 135.22(2) . 2_655 ?
Tb2 Sb6 Tb2 82.582(19) 2 2_655 ?
Tb1 Sb6 Tb2 80.471(14) 1_655 1_655 ?
Tb1 Sb6 Tb2 135.22(2) . 1_655 ?
Tb2 Sb6 Tb2 137.35(4) 2 1_655 ?
Tb2 Sb6 Tb2 82.22(2) 2_655 1_655 ?
Tb1 Sb6 Tb2 135.22(2) 1_655 . ?
Tb1 Sb6 Tb2 80.471(14) . . ?
Tb2 Sb6 Tb2 82.22(2) 2 . ?
Tb2 Sb6 Tb2 137.35(4) 2_655 . ?
Tb2 Sb6 Tb2 82.582(19) 1_655 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Tb1 Sb6 3.1217(10) 1_455 ?
Tb1 Sb6 3.1217(10) . ?
Tb1 Sb4 3.1696(8) . ?
Tb1 Sb4 3.1696(8) 2 ?
Tb1 Sb3 3.1758(8) 13 ?
Tb1 Sb3 3.1758(8) 14_445 ?
Tb1 Sb3 3.1758(8) 13_455 ?
Tb1 Sb3 3.1758(8) 14_545 ?
Tb1 Sb2 3.3137(9) 5_445 ?
Tb2 Sb6 3.1378(6) 1_455 ?
Tb2 Sb6 3.1378(6) . ?
Tb2 Zn1 3.1464(16) . ?
Tb2 Sb4 3.2554(7) 13 ?
Tb2 Sb4 3.2554(7) 13_455 ?
Tb2 Sb1 3.2786(6) . ?
Tb2 Sb4 3.2896(10) . ?
Tb2 Sb5 3.2896(5) 13_455 ?
Tb2 Sb5 3.2896(5) 13 ?
Tb2 Sb3 3.5058(11) . ?
Zn1 Sb3 2.477(2) . ?
Zn1 Sb3 2.477(2) 10 ?
Zn1 Sb5 2.6430(18) 13_455 ?
Zn1 Sb5 2.6430(18) 13 ?
Zn1 Tb2 3.1464(16) 10 ?
Sb1 Sb5 3.0699(8) 13 ?
Sb1 Sb5 3.0699(8) 5_444 ?
Sb1 Sb5 3.0699(8) 13_455 ?
Sb1 Sb5 3.0699(8) 5_544 ?
Sb1 Tb2 3.2786(6) 9 ?
Sb1 Tb2 3.2786(6) 2 ?
Sb1 Tb2 3.2786(6) 10 ?
Sb2 Tb1 3.3137(9) 5_554 ?
Sb2 Tb1 3.3137(9) 13 ?
Sb3 Sb4 2.9919(9) 13 ?
Sb3 Sb4 2.9919(9) 13_455 ?
Sb3 Tb1 3.1758(8) 13 ?
Sb3 Tb1 3.1758(8) 13_455 ?
Sb4 Sb3 2.9919(9) 13 ?
Sb4 Sb3 2.9919(9) 13_455 ?
Sb4 Sb4 3.0817(11) 13_455 ?
Sb4 Sb4 3.0817(11) 13 ?
Sb4 Tb2 3.2554(7) 13 ?
Sb4 Tb2 3.2554(7) 13_455 ?
Sb5 Zn1 2.6430(18) 13_455 ?
Sb5 Zn1 2.6430(18) 13 ?
Sb5 Sb1 3.0699(8) 5 ?
Sb5 Sb1 3.0699(8) 5_455 ?
Sb5 Tb2 3.2896(5) 6 ?
Sb5 Tb2 3.2896(5) 13_455 ?
Sb5 Tb2 3.2896(5) 6_455 ?
Sb5 Tb2 3.2896(5) 13 ?
Sb6 Tb1 3.1217(10) 1_655 ?
Sb6 Tb2 3.1378(6) 2 ?
Sb6 Tb2 3.1378(6) 2_655 ?
Sb6 Tb2 3.1378(6) 1_655 ?
