#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:07:27 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179094 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/56/4305680.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4305680
loop_
_publ_author_name
'Philip W. Miller'
'Mark Nieuwenhuyzen'
'Jonathan P. H. Charmant'
'Stuart L. James'
_publ_section_title
;
The Cyclic "Silver-Diphos" Motif [Ag2(μ-diphosphine)2]2+ as a Synthon
for Building up Larger Structures
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              8367
_journal_page_last               8379
_journal_paper_doi               10.1021/ic800664f
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety
'C124 H92 Ag4 F12 O12 P8 S4 Sn, C H3 N O2, 4(C H Cl3)'
_chemical_formula_sum            'C129 H99 Ag4 Cl12 F12 N O14 P8 S4 Sn'
_chemical_formula_weight         3466.66
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.920(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.3377(10)
_cell_length_b                   20.4212(12)
_cell_length_c                   32.4782(15)
_cell_measurement_reflns_used    18246
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      70.04
_cell_measurement_theta_min      2.56
_cell_volume                     14133.7(12)
_computing_cell_refinement       'SAINT v6.22 (Bruker, 2001)'
_computing_data_collection       'SMART v5.625 (Bruker, 2001)'
_computing_data_reduction        'SAINT v6.22 (Bruker, 2001)'
_computing_molecular_graphics    'XSHELL v4.02 (Bruker, 2000)'
_computing_publication_material  'SHELXTL v6.10 (Bruker, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.602
_diffrn_detector_type            'Bruker-AXS SMART 6000'
_diffrn_measured_fraction_theta_full 0.938
_diffrn_measured_fraction_theta_max 0.938
_diffrn_measurement_details      'frames, 0.3° width'
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker-AXS D8'
_diffrn_measurement_method       'ω scans'
_diffrn_measurement_specimen_support 'glass fibre'
_diffrn_radiation_collimation    'Osmic CMF12-38Cu6 (blue) mirror optics'
_diffrn_radiation_monochromator  'Osmic CMF12-38Cu6 (blue) mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.5418
_diffrn_reflns_av_R_equivalents  0.0609
_diffrn_reflns_av_sigmaI/netI    0.0521
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -36
_diffrn_reflns_number            108137
_diffrn_reflns_theta_full        70.15
_diffrn_reflns_theta_max         70.15
_diffrn_reflns_theta_min         2.07
_diffrn_source                   rotating-anode
_diffrn_source_current           120
_diffrn_source_power             4.8
_diffrn_source_size              '3 x 0.3mm'
_diffrn_source_target            Cu
_diffrn_source_type              'MAC Science M18XCE'
_diffrn_source_voltage           40
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    9.885
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.457
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2002)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.629
_exptl_crystal_density_method    none
_exptl_crystal_description       block
_exptl_crystal_F_000             6904
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.319
_refine_diff_density_min         -1.275
_refine_diff_density_rms         0.152
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1595
_refine_ls_number_reflns         25179
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0851
_refine_ls_R_factor_gt           0.0661
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1360P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1854
_refine_ls_wR_factor_ref         0.1981
_reflns_number_gt                18668
_reflns_number_total             25179
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic800664f-file002_2.cif
_cod_data_source_block           pm2_505s
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_diffrn_radiation_probe' value 'X-ray' changed to 'x-ray'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4305680
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1695(3) 0.9792(3) 0.72378(17) 0.0265(12) Uani 1 1 d . . .
C2 C 0.1711(3) 1.0061(3) 0.68421(19) 0.0286(13) Uani 1 1 d . . .
H2 H 0.2044 1.0346 0.6777 0.034 Uiso 1 1 calc R . .
C3 C 0.1240(3) 0.9913(3) 0.65436(19) 0.0292(13) Uani 1 1 d . . .
C4 C 0.0749(3) 0.9508(3) 0.6646(2) 0.0331(14) Uani 1 1 d . . .
H4 H 0.0431 0.9396 0.6443 0.040 Uiso 1 1 calc R . .
C5 C 0.0720(3) 0.9263(3) 0.7047(2) 0.0320(14) Uani 1 1 d . . .
C6 C 0.1191(3) 0.9412(3) 0.73348(19) 0.0274(12) Uani 1 1 d . . .
H6 H 0.1169 0.9249 0.7608 0.033 Uiso 1 1 calc R . .
C7 C 0.2629(3) 1.0605(3) 0.80757(18) 0.0282(12) Uani 1 1 d . . .
C8 C 0.3000(3) 1.1147(3) 0.7998(2) 0.0331(14) Uani 1 1 d . . .
H8 H 0.3149 1.1208 0.7730 0.040 Uiso 1 1 calc R . .
C9 C 0.3156(3) 1.1599(3) 0.8305(2) 0.0352(14) Uani 1 1 d . . .
C10 C 0.2940(3) 1.1514(3) 0.8702(2) 0.0369(15) Uani 1 1 d . . .
H10 H 0.3052 1.1816 0.8916 0.044 Uiso 1 1 calc R . .
C11 C 0.2559(3) 1.0980(3) 0.87782(19) 0.0320(13) Uani 1 1 d . . .
C12 C 0.2407(3) 1.0534(3) 0.84686(19) 0.0323(14) Uani 1 1 d . . .
H12 H 0.2145 1.0172 0.8525 0.039 Uiso 1 1 calc R . .
C13 C 0.2503(3) 0.8956(3) 0.80130(19) 0.0291(13) Uani 1 1 d . . .
C14 C 0.2160(3) 0.8406(3) 0.78765(19) 0.0299(13) Uani 1 1 d . . .
H14 H 0.1989 0.8393 0.7601 0.036 Uiso 1 1 calc R . .
C15 C 0.2065(3) 0.7872(3) 0.8140(2) 0.0344(14) Uani 1 1 d . . .
C16 C 0.2331(3) 0.7903(3) 0.8542(2) 0.0362(15) Uani 1 1 d . . .
H16 H 0.2266 0.7552 0.8726 0.043 Uiso 1 1 calc R . .
C17 C 0.2679(3) 0.8423(3) 0.8674(2) 0.0341(14) Uani 1 1 d . . .
C18 C 0.2760(3) 0.8956(3) 0.8414(2) 0.0326(14) Uani 1 1 d . . .
H18 H 0.2996 0.9323 0.8512 0.039 Uiso 1 1 calc R . .
C19 C 0.3295(3) 0.9920(3) 0.72480(18) 0.0257(12) Uani 1 1 d . . .
C20 C 0.3843(3) 1.0222(3) 0.74003(18) 0.0265(12) Uani 1 1 d . . .
H20 H 0.3896 1.0316 0.7686 0.032 Uiso 1 1 calc R . .
C21 C 0.4311(3) 1.0387(3) 0.71399(18) 0.0272(12) Uani 1 1 d . . .
C22 C 0.4244(3) 1.0247(3) 0.67231(19) 0.0303(13) Uani 1 1 d . . .
H22 H 0.4563 1.0368 0.6545 0.036 Uiso 1 1 calc R . .
C23 C 0.3711(3) 0.9929(3) 0.6567(2) 0.0331(14) Uani 1 1 d . . .
C24 C 0.3239(3) 0.9760(3) 0.68360(19) 0.0285(13) Uani 1 1 d . . .
H24 H 0.2876 0.9532 0.6732 0.034 Uiso 1 1 calc R . .
C25 C 0.1156(3) 1.1075(3) 0.6028(2) 0.0347(14) Uani 1 1 d . . .
C26 C 0.0955(3) 1.1393(4) 0.6374(2) 0.0440(17) Uani 1 1 d . . .
H26 H 0.0887 1.1153 0.6618 0.053 Uiso 1 1 calc R . .
C27 C 0.0851(4) 1.2063(4) 0.6363(3) 0.059(2) Uani 1 1 d . . .
H27 H 0.0710 1.2282 0.6600 0.071 Uiso 1 1 calc R . .
C28 C 0.0953(5) 1.2408(4) 0.6011(3) 0.067(3) Uani 1 1 d . . .
H28 H 0.0891 1.2869 0.6008 0.081 Uiso 1 1 calc R . .
C29 C 0.1138(5) 1.2107(5) 0.5668(3) 0.067(3) Uani 1 1 d . . .
H29 H 0.1188 1.2350 0.5423 0.080 Uiso 1 1 calc R . .
C30 C 0.1254(4) 1.1441(4) 0.5678(2) 0.0480(19) Uani 1 1 d . . .
H30 H 0.1403 1.1230 0.5442 0.058 Uiso 1 1 calc R . .
C31 C 0.0788(3) 0.9799(3) 0.5694(2) 0.0341(14) Uani 1 1 d . . .
C32 C 0.0158(3) 0.9941(4) 0.5696(2) 0.0452(17) Uani 1 1 d . . .
H32 H 0.0018 1.0287 0.5864 0.054 Uiso 1 1 calc R . .
C33 C -0.0277(3) 0.9579(4) 0.5452(2) 0.0503(19) Uani 1 1 d . . .
H33 H -0.0711 0.9682 0.5451 0.060 Uiso 1 1 calc R . .
C34 C -0.0072(4) 0.9080(5) 0.5217(2) 0.059(2) Uani 1 1 d . . .
H34 H -0.0367 0.8823 0.5058 0.071 Uiso 1 1 calc R . .
C35 C 0.0565(4) 0.8940(5) 0.5206(3) 0.064(2) Uani 1 1 d . . .
H35 H 0.0706 0.8598 0.5035 0.077 Uiso 1 1 calc R . .
C36 C 0.0982(4) 0.9296(4) 0.5440(2) 0.0489(18) Uani 1 1 d . . .
H36 H 0.1417 0.9201 0.5432 0.059 Uiso 1 1 calc R . .
C37 C -0.0318(3) 0.9050(4) 0.7589(2) 0.0413(16) Uani 1 1 d . . .
C38 C -0.0726(4) 0.8643(4) 0.7791(3) 0.053(2) Uani 1 1 d . . .
H38 H -0.0768 0.8195 0.7716 0.064 Uiso 1 1 calc R . .
C39 C -0.1072(4) 0.8906(5) 0.8106(3) 0.072(3) Uani 1 1 d . . .
H39 H -0.1366 0.8639 0.8239 0.086 Uiso 1 1 calc R . .
C40 C -0.0991(4) 0.9549(5) 0.8225(3) 0.066(3) Uani 1 1 d . . .
H40 H -0.1210 0.9716 0.8449 0.079 Uiso 1 1 calc R . .
C41 C -0.0590(4) 0.9950(5) 0.8020(3) 0.060(2) Uani 1 1 d . . .
H41 H -0.0548 1.0398 0.8095 0.072 Uiso 1 1 calc R . .
C42 C -0.0254(3) 0.9702(4) 0.7708(3) 0.0501(19) Uani 1 1 d . . .
H42 H 0.0027 0.9979 0.7571 0.060 Uiso 1 1 calc R . .
C43 C -0.0402(3) 0.8572(4) 0.6751(2) 0.0464(19) Uani 1 1 d . . .
C44 C -0.0769(3) 0.9095(5) 0.6624(3) 0.055(2) Uani 1 1 d . . .
H44 H -0.0740 0.9496 0.6772 0.067 Uiso 1 1 calc R . .
C45 C -0.1182(4) 0.9043(6) 0.6281(3) 0.070(3) Uani 1 1 d . . .
H45 H -0.1444 0.9399 0.6194 0.084 Uiso 1 1 calc R . .
C46 C -0.1199(5) 0.8450(5) 0.6068(4) 0.086(4) Uani 1 1 d . . .
H46 H -0.1473 0.8404 0.5830 0.103 Uiso 1 1 calc R . .
C47 C -0.0826(6) 0.7931(6) 0.6195(4) 0.094(4) Uani 1 1 d . . .
H47 H -0.0846 0.7529 0.6048 0.113 Uiso 1 1 calc R . .
C48 C -0.0415(5) 0.8002(5) 0.6543(3) 0.074(3) Uani 1 1 d . . .
H48 H -0.0150 0.7650 0.6632 0.089 Uiso 1 1 calc R . .
C49 C 0.2508(4) 1.1454(4) 0.9616(2) 0.0475(18) Uani 1 1 d . . .
C50 C 0.2163(4) 1.2019(5) 0.9602(3) 0.061(2) Uani 1 1 d . . .
H50 H 0.1795 1.2049 0.9426 0.073 Uiso 1 1 calc R . .
C51 C 0.2354(4) 1.2555(5) 0.9847(3) 0.058(2) Uani 1 1 d . . .
H51 H 0.2096 1.2934 0.9851 0.070 Uiso 1 1 calc R . .
C52 C 0.2884(6) 1.2540(6) 1.0073(4) 0.099(4) Uani 1 1 d . . .
H52 H 0.3022 1.2920 1.0221 0.118 Uiso 1 1 calc R . .
C53 C 0.3237(10) 1.1979(9) 1.0096(9) 0.237(16) Uani 1 1 d . . .
H53 H 0.3604 1.1960 1.0274 0.284 Uiso 1 1 calc R . .
C54 C 0.3051(7) 1.1423(7) 0.9850(5) 0.151(8) Uani 1 1 d . . .
H54 H 0.3304 1.1040 0.9852 0.181 Uiso 1 1 calc R . .
C55 C 0.1457(4) 1.0728(4) 0.9222(2) 0.0465(18) Uani 1 1 d . . .
C56 C 0.1123(4) 1.1081(4) 0.8916(2) 0.0494(18) Uani 1 1 d . . .
H56 H 0.1341 1.1370 0.8744 0.059 Uiso 1 1 calc R . .
C57 C 0.0480(4) 1.1018(5) 0.8859(3) 0.063(2) Uani 1 1 d . . .
H57 H 0.0266 1.1263 0.8647 0.076 Uiso 1 1 calc R . .
C58 C 0.0146(5) 1.0614(6) 0.9098(4) 0.080(3) Uani 1 1 d . . .
H58 H -0.0295 1.0570 0.9054 0.096 Uiso 1 1 calc R . .
C59 C 0.0471(5) 1.0265(6) 0.9412(4) 0.090(4) Uani 1 1 d . . .
H59 H 0.0245 0.9988 0.9587 0.108 Uiso 1 1 calc R . .
C60 C 0.1124(5) 1.0318(5) 0.9474(3) 0.073(3) Uani 1 1 d . . .
H60 H 0.1338 1.0075 0.9688 0.088 Uiso 1 1 calc R . .
C61 C 0.3191(3) 1.2941(4) 0.8017(3) 0.0502(19) Uani 1 1 d . . .
C62 C 0.2547(4) 1.2911(5) 0.8065(3) 0.064(2) Uani 1 1 d . . .
H62 H 0.2367 1.2535 0.8185 0.077 Uiso 1 1 calc R . .
C63 C 0.2168(5) 1.3437(6) 0.7937(4) 0.086(3) Uani 1 1 d . . .
H63 H 0.1731 1.3424 0.7978 0.103 Uiso 1 1 calc R . .
C64 C 0.2427(5) 1.3988(5) 0.7746(4) 0.084(3) Uani 1 1 d . . .
H64 H 0.2171 1.4344 0.7652 0.101 Uiso 1 1 calc R . .
C65 C 0.3068(5) 1.3991(5) 0.7701(4) 0.078(3) Uani 1 1 d . . .
H65 H 0.3255 1.4362 0.7580 0.094 Uiso 1 1 calc R . .
C66 C 0.3439(4) 1.3480(4) 0.7824(3) 0.064(2) Uani 1 1 d . . .
H66 H 0.3875 1.3492 0.7777 0.077 Uiso 1 1 calc R . .
C67 C 0.4078(4) 1.2486(4) 0.8664(3) 0.051(2) Uani 1 1 d . . .
C68 C 0.4507(5) 1.2018(6) 0.8835(3) 0.077(3) Uani 1 1 d . . .
H68 H 0.4588 1.1629 0.8686 0.092 Uiso 1 1 calc R . .
C69 C 0.4813(6) 1.2121(7) 0.9220(4) 0.094(4) Uani 1 1 d . . .
H69 H 0.5088 1.1802 0.9342 0.113 Uiso 1 1 calc R . .
C70 C 0.4699(6) 1.2710(7) 0.9417(4) 0.095(4) Uani 1 1 d . . .
H70 H 0.4909 1.2792 0.9677 0.115 Uiso 1 1 calc R . .
C71 C 0.4302(6) 1.3170(7) 0.9257(4) 0.104(5) Uani 1 1 d . . .
H71 H 0.4239 1.3570 0.9399 0.125 Uiso 1 1 calc R . .
C72 C 0.3978(5) 1.3041(6) 0.8865(4) 0.093(4) Uani 1 1 d . . .
H72 H 0.3690 1.3354 0.8750 0.112 Uiso 1 1 calc R . .
C73 C 0.2056(4) 0.6703(4) 0.7643(3) 0.0470(18) Uani 1 1 d . . .
C74 C 0.2698(4) 0.6805(4) 0.7603(3) 0.052(2) Uani 1 1 d . . .
H74 H 0.2894 0.7164 0.7745 0.062 Uiso 1 1 calc R . .
C75 C 0.3047(4) 0.6421(5) 0.7375(3) 0.066(3) Uani 1 1 d . . .
H75 H 0.3474 0.6528 0.7340 0.080 Uiso 1 1 calc R . .
C76 C 0.2799(4) 0.5883(5) 0.7195(3) 0.070(3) Uani 1 1 d . . .
H76 H 0.3054 0.5600 0.7042 0.083 Uiso 1 1 calc R . .
C77 C 0.2162(4) 0.5741(5) 0.7233(4) 0.081(3) Uani 1 1 d . . .
H77 H 0.1981 0.5366 0.7101 0.097 Uiso 1 1 calc R . .
C78 C 0.1790(4) 0.6151(5) 0.7468(3) 0.068(3) Uani 1 1 d . . .
H78 H 0.1362 0.6049 0.7504 0.081 Uiso 1 1 calc R . .
C79 C 0.1375(3) 0.6736(4) 0.8382(2) 0.0473(18) Uani 1 1 d . . .
C80 C 0.1778(4) 0.6258(5) 0.8530(3) 0.061(2) Uani 1 1 d . . .
H80 H 0.2147 0.6167 0.8389 0.073 Uiso 1 1 calc R . .
C81 C 0.1654(5) 0.5909(6) 0.8881(3) 0.084(4) Uani 1 1 d . . .
H81 H 0.1933 0.5574 0.8979 0.100 Uiso 1 1 calc R . .
C82 C 0.1127(5) 0.6049(7) 0.9085(3) 0.090(4) Uani 1 1 d . . .
H82 H 0.1048 0.5822 0.9332 0.109 Uiso 1 1 calc R . .
C83 C 0.0722(5) 0.6501(6) 0.8942(3) 0.080(3) Uani 1 1 d . . .
H83 H 0.0351 0.6583 0.9083 0.097 Uiso 1 1 calc R . .
C84 C 0.0841(4) 0.6864(5) 0.8576(3) 0.058(2) Uani 1 1 d . . .
H84 H 0.0554 0.7187 0.8472 0.070 Uiso 1 1 calc R . .
C85 C 0.3821(3) 0.8395(4) 0.9204(2) 0.0463(18) Uani 1 1 d . . .
C86 C 0.4143(4) 0.8325(4) 0.8837(3) 0.055(2) Uani 1 1 d . . .
H86 H 0.3913 0.8328 0.8579 0.066 Uiso 1 1 calc R . .
C87 C 0.4776(4) 0.8253(5) 0.8846(3) 0.071(3) Uani 1 1 d . . .
H87 H 0.4983 0.8213 0.8595 0.085 Uiso 1 1 calc R . .
C88 C 0.5126(5) 0.8239(7) 0.9221(4) 0.098(4) Uani 1 1 d . . .
H88 H 0.5569 0.8190 0.9229 0.118 Uiso 1 1 calc R . .
C89 C 0.4816(5) 0.8296(8) 0.9578(4) 0.110(5) Uani 1 1 d . . .
H89 H 0.5048 0.8267 0.9835 0.132 Uiso 1 1 calc R . .
C90 C 0.4165(4) 0.8397(7) 0.9575(3) 0.093(4) Uani 1 1 d . . .
H90 H 0.3965 0.8466 0.9826 0.112 Uiso 1 1 calc R . .
C91 C 0.2687(3) 0.7842(4) 0.9482(2) 0.0418(17) Uani 1 1 d . . .
C92 C 0.2943(5) 0.7227(4) 0.9437(2) 0.055(2) Uani 1 1 d . . .
H92 H 0.3304 0.7174 0.9281 0.066 Uiso 1 1 calc R . .
C93 C 0.2683(5) 0.6693(4) 0.9615(2) 0.060(2) Uani 1 1 d . . .
H93 H 0.2857 0.6270 0.9581 0.072 Uiso 1 1 calc R . .
C94 C 0.2151(4) 0.6780(5) 0.9849(3) 0.066(3) Uani 1 1 d . . .
H94 H 0.1959 0.6412 0.9969 0.080 Uiso 1 1 calc R . .
C95 C 0.1911(4) 0.7391(5) 0.9904(3) 0.068(3) Uani 1 1 d . . .
H95 H 0.1563 0.7448 1.0072 0.081 Uiso 1 1 calc R . .
C96 C 0.2176(4) 0.7932(5) 0.9715(3) 0.059(2) Uani 1 1 d . . .
H96 H 0.2004 0.8357 0.9748 0.071 Uiso 1 1 calc R . .
C97 C 0.5302(3) 1.0454(3) 0.7791(2) 0.0351(15) Uani 1 1 d . . .
C98 C 0.5342(3) 0.9778(4) 0.7791(2) 0.0415(17) Uani 1 1 d . . .
H98 H 0.5165 0.9530 0.7566 0.050 Uiso 1 1 calc R . .
C99 C 0.5650(4) 0.9469(5) 0.8129(3) 0.056(2) Uani 1 1 d . . .
H99 H 0.5676 0.9004 0.8135 0.067 Uiso 1 1 calc R . .
C100 C 0.5916(4) 0.9824(5) 0.8455(3) 0.065(2) Uani 1 1 d . . .
H100 H 0.6135 0.9609 0.8678 0.078 Uiso 1 1 calc R . .
C101 C 0.5858(4) 1.0494(5) 0.8449(3) 0.067(3) Uani 1 1 d . . .
H101 H 0.6030 1.0740 0.8676 0.081 Uiso 1 1 calc R . .
C102 C 0.5560(3) 1.0820(4) 0.8124(2) 0.0478(18) Uani 1 1 d . . .
H102 H 0.5529 1.1284 0.8126 0.057 Uiso 1 1 calc R . .
C103 C 0.5501(3) 1.0973(4) 0.6975(2) 0.0403(16) Uani 1 1 d . . .
C104 C 0.5876(4) 1.0440(5) 0.6887(3) 0.057(2) Uani 1 1 d . . .
H104 H 0.5835 1.0043 0.7035 0.068 Uiso 1 1 calc R . .
C105 C 0.6314(4) 1.0485(5) 0.6582(3) 0.062(2) Uani 1 1 d . . .
H105 H 0.6573 1.0122 0.6524 0.074 Uiso 1 1 calc R . .
C106 C 0.6365(4) 1.1048(5) 0.6372(3) 0.058(2) Uani 1 1 d . . .
H106 H 0.6661 1.1082 0.6165 0.070 Uiso 1 1 calc R . .
C107 C 0.5994(5) 1.1570(5) 0.6454(3) 0.070(3) Uani 1 1 d . . .
H107 H 0.6039 1.1965 0.6303 0.084 Uiso 1 1 calc R . .
C108 C 0.5551(4) 1.1538(4) 0.6753(2) 0.053(2) Uani 1 1 d . . .
H108 H 0.5287 1.1901 0.6801 0.063 Uiso 1 1 calc R . .
C109 C 0.4148(4) 1.0173(6) 0.5764(2) 0.068(3) Uani 1 1 d . . .
C110 C 0.4059(5) 1.0829(7) 0.5652(4) 0.098(4) Uani 1 1 d . . .
H110 H 0.3669 1.1037 0.5694 0.118 Uiso 1 1 calc R . .
C111 C 0.4541(7) 1.1179(10) 0.5477(4) 0.133(7) Uani 1 1 d . . .
H111 H 0.4481 1.1622 0.5396 0.160 Uiso 1 1 calc R . .
C112 C 0.5090(7) 1.0879(13) 0.5426(4) 0.138(8) Uani 1 1 d . . .
H112 H 0.5423 1.1121 0.5317 0.166 Uiso 1 1 calc R . .
C113 C 0.5184(8) 1.0242(12) 0.5523(7) 0.160(9) Uani 1 1 d . . .
H113 H 0.5573 1.0042 0.5467 0.192 Uiso 1 1 calc R . .
C114 C 0.4717(6) 0.9869(9) 0.5708(5) 0.134(7) Uani 1 1 d . . .
H114 H 0.4791 0.9428 0.5790 0.161 Uiso 1 1 calc R . .
C115 C 0.3633(4) 0.8875(5) 0.5973(3) 0.059(2) Uani 1 1 d . . .
C116 C 0.3337(5) 0.8575(5) 0.5629(3) 0.087(4) Uani 1 1 d . . .
H116 H 0.3128 0.8834 0.5422 0.104 Uiso 1 1 calc R . .
C117 C 0.3346(8) 0.7901(6) 0.5591(4) 0.116(6) Uani 1 1 d . . .
H117 H 0.3140 0.7696 0.5359 0.139 Uiso 1 1 calc R . .
C118 C 0.3661(8) 0.7521(7) 0.5897(5) 0.142(8) Uani 1 1 d . . .
H118 H 0.3674 0.7058 0.5870 0.170 Uiso 1 1 calc R . .
C119 C 0.3948(8) 0.7818(7) 0.6232(4) 0.128(7) Uani 1 1 d . . .
H119 H 0.4155 0.7560 0.6440 0.153 Uiso 1 1 calc R . .
C120 C 0.3939(5) 0.8501(5) 0.6270(3) 0.079(3) Uani 1 1 d . . .
H120 H 0.4144 0.8705 0.6503 0.095 Uiso 1 1 calc R . .
Ag1 Ag 0.24510(2) 1.00728(3) 0.584481(14) 0.03400(13) Uani 1 1 d . . .
Ag2 Ag 0.06796(2) 0.76988(2) 0.751165(15) 0.03610(13) Uani 1 1 d . . .
Ag3 Ag 0.27027(3) 0.96411(3) 0.945886(17) 0.05315(16) Uani 1 1 d . . .
Ag4 Ag 0.44238(2) 1.18845(3) 0.766845(16) 0.03986(14) Uani 1 1 d . . .
P1 P 0.13709(7) 1.02180(8) 0.60238(5) 0.0291(3) Uani 1 1 d . . .
P2 P 0.01461(7) 0.86508(9) 0.71968(6) 0.0362(4) Uani 1 1 d . . .
P3 P 0.23094(9) 1.07484(10) 0.92907(5) 0.0412(4) Uani 1 1 d . . .
P4 P 0.36915(8) 1.22614(9) 0.81678(6) 0.0374(4) Uani 1 1 d . . .
P5 P 0.15502(8) 0.72272(8) 0.79297(6) 0.0359(4) Uani 1 1 d . . .
P6 P 0.29827(8) 0.85520(10) 0.92122(5) 0.0396(4) Uani 1 1 d . . .
P7 P 0.49268(7) 1.09206(9) 0.73672(5) 0.0347(4) Uani 1 1 d . . .
P8 P 0.35268(8) 0.97647(10) 0.60220(5) 0.0403(4) Uani 1 1 d . . .
Sn1 Sn 0.252017(16) 0.982158(19) 0.764014(11) 0.02506(11) Uani 1 1 d . . .
C121 C -0.1048(3) 0.6392(4) 0.7280(2) 0.0448(17) Uani 1 1 d . . .
F1 F -0.1203(2) 0.6867(3) 0.70106(15) 0.0630(13) Uani 1 1 d . . .
F2 F -0.1085(2) 0.5815(2) 0.70756(14) 0.0556(12) Uani 1 1 d . . .
F3 F -0.14851(19) 0.6384(2) 0.75594(14) 0.0562(12) Uani 1 1 d . . .
O1 O -0.0318(2) 0.7128(2) 0.77250(17) 0.0493(13) Uani 1 1 d . . .
O2 O 0.0130(2) 0.6528(3) 0.71704(17) 0.0505(13) Uani 1 1 d . . .
O3 O -0.0197(2) 0.5958(2) 0.77839(16) 0.0464(12) Uani 1 1 d . . .
S1 S -0.02699(7) 0.65050(8) 0.75175(5) 0.0380(4) Uani 1 1 d . . .
C122 C 0.6012(3) 1.3309(4) 0.7382(2) 0.0386(16) Uani 1 1 d . . .
F4 F 0.6176(2) 1.2829(2) 0.71231(14) 0.0510(11) Uani 1 1 d . . .
F5 F 0.59377(18) 1.3849(2) 0.71605(13) 0.0455(10) Uani 1 1 d . . .
F6 F 0.64864(18) 1.3386(2) 0.76592(14) 0.0504(10) Uani 1 1 d . . .
O4 O 0.5478(2) 1.2499(3) 0.78493(18) 0.0515(13) Uani 1 1 d . . .
O5 O 0.5173(2) 1.3643(3) 0.78753(16) 0.0477(12) Uani 1 1 d . . .
O6 O 0.4850(2) 1.2961(3) 0.72865(17) 0.0482(12) Uani 1 1 d . . .
S2 S 0.52967(7) 1.30843(9) 0.76284(6) 0.0394(4) Uani 1 1 d . . .
C123 C 0.2962(5) 1.0514(6) 0.4524(3) 0.074(3) Uani 1 1 d . . .
F7 F 0.3519(3) 1.0525(6) 0.4706(3) 0.139(3) Uani 1 1 d . . .
F8 F 0.2954(5) 1.0072(4) 0.4235(2) 0.130(3) Uani 1 1 d . . .
F9 F 0.2898(4) 1.1100(4) 0.4336(2) 0.110(2) Uani 1 1 d . . .
O7 O 0.2466(5) 0.9753(3) 0.5028(2) 0.087(2) Uani 1 1 d . . .
O8 O 0.1803(3) 1.0506(6) 0.4640(3) 0.131(4) Uani 1 1 d . . .
O9 O 0.2504(3) 1.0875(3) 0.51971(19) 0.0695(17) Uani 1 1 d . . .
S3 S 0.23535(8) 1.03975(10) 0.48768(5) 0.0439(4) Uani 1 1 d . . .
C124 C 0.2402(11) 0.9067(10) 1.0852(4) 0.148(8) Uani 1 1 d . . .
F10 F 0.1907(8) 0.9455(7) 1.0985(3) 0.203(7) Uani 1 1 d . . .
F11 F 0.2729(6) 0.8839(6) 1.1184(3) 0.177(5) Uani 1 1 d . . .
F12 F 0.2082(6) 0.8549(5) 1.0690(3) 0.157(4) Uani 1 1 d . . .
O10 O 0.2394(5) 0.9618(5) 1.0176(2) 0.116(3) Uani 1 1 d . . .
O11 O 0.3108(9) 0.9998(6) 1.0731(5) 0.206(8) Uani 1 1 d . . .
O12 O 0.3299(8) 0.8923(10) 1.0376(4) 0.226(9) Uani 1 1 d . . .
S4 S 0.2862(2) 0.9444(2) 1.05014(11) 0.1216(14) Uani 1 1 d . . .
C125 C 0.1899(13) 0.7675(11) 0.6381(4) 0.184(10) Uani 1 1 d . . .
H125 H 0.2217 0.7413 0.6237 0.221 Uiso 1 1 calc R . .
Cl1 Cl 0.2246(3) 0.8162(3) 0.67468(17) 0.183(2) Uani 1 1 d . . .
Cl2 Cl 0.1453(4) 0.8139(3) 0.60368(16) 0.221(4) Uani 1 1 d . . .
Cl3 Cl 0.1324(3) 0.7128(3) 0.66303(14) 0.1484(17) Uani 1 1 d . . .
C126 C 0.4496(10) 1.0028(12) 0.9302(6) 0.160(8) Uani 1 1 d . . .
H126 H 0.4563 0.9545 0.9283 0.192 Uiso 1 1 calc R . .
Cl4 Cl 0.5264(7) 1.0321(9) 0.9414(4) 0.412(9) Uani 1 1 d . . .
Cl5 Cl 0.4169(4) 1.0200(4) 0.8849(4) 0.276(5) Uani 1 1 d . . .
Cl6 Cl 0.4074(5) 1.0093(10) 0.9710(6) 0.496(14) Uani 1 1 d . . .
C127 C 0.0445(7) 0.8748(8) 0.8678(6) 0.145(7) Uani 1 1 d . . .
H12A H 0.0406 0.8497 0.8421 0.217 Uiso 1 1 calc R . .
H12B H 0.0120 0.9087 0.8675 0.217 Uiso 1 1 calc R . .
H12C H 0.0393 0.8453 0.8912 0.217 Uiso 1 1 calc R . .
N1 N 0.1025(5) 0.9035(6) 0.8714(4) 0.099(3) Uani 1 1 d . . .
O13 O 0.1361(6) 0.8944(6) 0.9060(4) 0.150(5) Uani 1 1 d . . .
O14 O 0.1197(4) 0.9392(5) 0.8452(3) 0.105(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn 0.0259 5.4591 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C2 119.2(5) . . ?
C6 C1 Sn1 120.3(4) . . ?
C2 C1 Sn1 119.4(4) . . ?
C3 C2 C1 120.1(5) . . ?
C3 C2 H2 119.9 . . ?
C1 C2 H2 119.9 . . ?
C4 C3 C2 119.3(6) . . ?
C4 C3 P1 125.1(5) . . ?
C2 C3 P1 115.4(5) . . ?
C3 C4 C5 120.4(6) . . ?
C3 C4 H4 119.8 . . ?
C5 C4 H4 119.8 . . ?
C6 C5 C4 119.2(6) . . ?
C6 C5 P2 116.5(5) . . ?
C4 C5 P2 123.6(5) . . ?
C5 C6 C1 121.6(5) . . ?
C5 C6 H6 119.2 . . ?
C1 C6 H6 119.2 . . ?
C12 C7 C8 118.1(6) . . ?
C12 C7 Sn1 119.9(5) . . ?
C8 C7 Sn1 121.2(4) . . ?
C9 C8 C7 121.2(6) . . ?
C9 C8 H8 119.4 . . ?
C7 C8 H8 119.4 . . ?
C8 C9 C10 120.0(6) . . ?
C8 C9 P4 116.4(5) . . ?
C10 C9 P4 123.6(5) . . ?
C11 C10 C9 119.0(6) . . ?
C11 C10 H10 120.5 . . ?
C9 C10 H10 120.5 . . ?
C12 C11 C10 120.4(6) . . ?
C12 C11 P3 114.9(5) . . ?
C10 C11 P3 124.3(5) . . ?
C11 C12 C7 121.4(6) . . ?
C11 C12 H12 119.3 . . ?
C7 C12 H12 119.3 . . ?
C18 C13 C14 118.2(6) . . ?
C18 C13 Sn1 120.9(5) . . ?
C14 C13 Sn1 120.4(4) . . ?
C13 C14 C15 121.2(6) . . ?
C13 C14 H14 119.4 . . ?
C15 C14 H14 119.4 . . ?
C16 C15 C14 117.9(6) . . ?
C16 C15 P5 126.1(5) . . ?
C14 C15 P5 115.8(5) . . ?
C17 C16 C15 121.4(6) . . ?
C17 C16 H16 119.3 . . ?
C15 C16 H16 119.3 . . ?
C16 C17 C18 120.3(6) . . ?
C16 C17 P6 124.8(5) . . ?
C18 C17 P6 114.4(5) . . ?
C13 C18 C17 120.9(6) . . ?
C13 C18 H18 119.5 . . ?
C17 C18 H18 119.5 . . ?
C24 C19 C20 118.8(5) . . ?
C24 C19 Sn1 121.5(4) . . ?
C20 C19 Sn1 119.3(4) . . ?
C21 C20 C19 120.8(6) . . ?
C21 C20 H20 119.6 . . ?
C19 C20 H20 119.6 . . ?
C22 C21 C20 120.3(5) . . ?
C22 C21 P7 123.7(5) . . ?
C20 C21 P7 115.1(4) . . ?
C23 C22 C21 119.9(6) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C22 C23 C24 119.2(6) . . ?
C22 C23 P8 125.1(5) . . ?
C24 C23 P8 115.5(5) . . ?
C19 C24 C23 121.0(6) . . ?
C19 C24 H24 119.5 . . ?
C23 C24 H24 119.5 . . ?
C30 C25 C26 118.6(7) . . ?
C30 C25 P1 117.8(5) . . ?
C26 C25 P1 123.3(5) . . ?
C27 C26 C25 119.9(7) . . ?
C27 C26 H26 120.0 . . ?
C25 C26 H26 120.0 . . ?
C28 C27 C26 119.8(8) . . ?
C28 C27 H27 120.1 . . ?
C26 C27 H27 120.1 . . ?
C29 C28 C27 121.3(9) . . ?
C29 C28 H28 119.3 . . ?
C27 C28 H28 119.3 . . ?
C28 C29 C30 119.3(8) . . ?
C28 C29 H29 120.4 . . ?
C30 C29 H29 120.4 . . ?
C29 C30 C25 121.0(7) . . ?
C29 C30 H30 119.5 . . ?
C25 C30 H30 119.5 . . ?
C32 C31 C36 118.6(7) . . ?
C32 C31 P1 122.6(6) . . ?
C36 C31 P1 118.8(5) . . ?
C31 C32 C33 120.4(7) . . ?
C31 C32 H32 119.8 . . ?
C33 C32 H32 119.8 . . ?
C34 C33 C32 119.4(7) . . ?
C34 C33 H33 120.3 . . ?
C32 C33 H33 120.3 . . ?
C33 C34 C35 120.8(8) . . ?
C33 C34 H34 119.6 . . ?
C35 C34 H34 119.6 . . ?
C36 C35 C34 119.3(8) . . ?
C36 C35 H35 120.3 . . ?
C34 C35 H35 120.3 . . ?
C35 C36 C31 121.5(8) . . ?
C35 C36 H36 119.2 . . ?
C31 C36 H36 119.2 . . ?
C38 C37 C42 119.6(7) . . ?
C38 C37 P2 115.7(6) . . ?
C42 C37 P2 124.5(5) . . ?
C37 C38 C39 118.9(8) . . ?
C37 C38 H38 120.6 . . ?
C39 C38 H38 120.6 . . ?
C40 C39 C38 120.4(8) . . ?
C40 C39 H39 119.8 . . ?
C38 C39 H39 119.8 . . ?
C39 C40 C41 120.2(9) . . ?
C39 C40 H40 119.9 . . ?
C41 C40 H40 119.9 . . ?
C42 C41 C40 120.0(9) . . ?
C42 C41 H41 120.0 . . ?
C40 C41 H41 120.0 . . ?
C41 C42 C37 120.8(7) . . ?
C41 C42 H42 119.6 . . ?
C37 C42 H42 119.6 . . ?
C48 C43 C44 121.5(8) . . ?
C48 C43 P2 118.1(7) . . ?
C44 C43 P2 120.3(7) . . ?
C43 C44 C45 120.7(9) . . ?
C43 C44 H44 119.6 . . ?
C45 C44 H44 119.6 . . ?
C44 C45 C46 117.6(9) . . ?
C44 C45 H45 121.2 . . ?
C46 C45 H45 121.2 . . ?
C47 C46 C45 121.4(9) . . ?
C47 C46 H46 119.3 . . ?
C45 C46 H46 119.3 . . ?
C46 C47 C48 119.4(11) . . ?
C46 C47 H47 120.3 . . ?
C48 C47 H47 120.3 . . ?
C43 C48 C47 119.4(10) . . ?
C43 C48 H48 120.3 . . ?
C47 C48 H48 120.3 . . ?
C54 C49 C50 120.0(9) . . ?
C54 C49 P3 117.1(8) . . ?
C50 C49 P3 122.7(6) . . ?
C49 C50 C51 120.1(8) . . ?
C49 C50 H50 120.0 . . ?
C51 C50 H50 120.0 . . ?
C52 C51 C50 121.0(10) . . ?
C52 C51 H51 119.5 . . ?
C50 C51 H51 119.5 . . ?
C51 C52 C53 120.2(11) . . ?
C51 C52 H52 119.9 . . ?
C53 C52 H52 119.9 . . ?
C52 C53 C54 119.8(12) . . ?
C52 C53 H53 120.1 . . ?
C54 C53 H53 120.1 . . ?
C49 C54 C53 118.7(11) . . ?
C49 C54 H54 120.6 . . ?
C53 C54 H54 120.6 . . ?
C60 C55 C56 118.2(8) . . ?
C60 C55 P3 118.6(7) . . ?
C56 C55 P3 123.2(6) . . ?
C57 C56 C55 121.1(8) . . ?
C57 C56 H56 119.5 . . ?
C55 C56 H56 119.5 . . ?
C58 C57 C56 121.7(10) . . ?
C58 C57 H57 119.1 . . ?
C56 C57 H57 119.1 . . ?
C57 C58 C59 118.2(10) . . ?
C57 C58 H58 120.9 . . ?
C59 C58 H58 120.9 . . ?
C58 C59 C60 121.1(10) . . ?
C58 C59 H59 119.4 . . ?
C60 C59 H59 119.4 . . ?
C55 C60 C59 119.7(10) . . ?
C55 C60 H60 120.2 . . ?
C59 C60 H60 120.2 . . ?
C66 C61 C62 119.3(8) . . ?
C66 C61 P4 120.0(6) . . ?
C62 C61 P4 120.6(7) . . ?
C61 C62 C63 119.5(9) . . ?
C61 C62 H62 120.3 . . ?
C63 C62 H62 120.3 . . ?
C62 C63 C64 120.8(9) . . ?
C62 C63 H63 119.6 . . ?
C64 C63 H63 119.6 . . ?
C65 C64 C63 117.4(9) . . ?
C65 C64 H64 121.3 . . ?
C63 C64 H64 121.3 . . ?
C66 C65 C64 122.1(9) . . ?
C66 C65 H65 119.0 . . ?
C64 C65 H65 119.0 . . ?
C65 C66 C61 120.9(8) . . ?
C65 C66 H66 119.6 . . ?
C61 C66 H66 119.6 . . ?
C72 C67 C68 119.9(9) . . ?
C72 C67 P4 124.7(8) . . ?
C68 C67 P4 115.4(7) . . ?
C69 C68 C67 120.8(10) . . ?
C69 C68 H68 119.6 . . ?
C67 C68 H68 119.6 . . ?
C70 C69 C68 117.3(12) . . ?
C70 C69 H69 121.4 . . ?
C68 C69 H69 121.4 . . ?
C71 C70 C69 123.1(12) . . ?
C71 C70 H70 118.4 . . ?
C69 C70 H70 118.4 . . ?
C70 C71 C72 118.3(11) . . ?
C70 C71 H71 120.8 . . ?
C72 C71 H71 120.8 . . ?
C67 C72 C71 120.5(11) . . ?
C67 C72 H72 119.7 . . ?
C71 C72 H72 119.7 . . ?
C78 C73 C74 118.1(8) . . ?
C78 C73 P5 116.9(6) . . ?
C74 C73 P5 124.9(6) . . ?
C75 C74 C73 122.8(8) . . ?
C75 C74 H74 118.6 . . ?
C73 C74 H74 118.6 . . ?
C74 C75 C76 120.4(9) . . ?
C74 C75 H75 119.8 . . ?
C76 C75 H75 119.8 . . ?
C75 C76 C77 119.6(9) . . ?
C75 C76 H76 120.2 . . ?
C77 C76 H76 120.2 . . ?
C76 C77 C78 120.1(8) . . ?
C76 C77 H77 119.9 . . ?
C78 C77 H77 119.9 . . ?
C73 C78 C77 118.7(8) . . ?
C73 C78 H78 120.6 . . ?
C77 C78 H78 120.6 . . ?
C84 C79 C80 120.0(8) . . ?
C84 C79 P5 118.6(6) . . ?
C80 C79 P5 121.4(7) . . ?
C79 C80 C81 121.0(10) . . ?
C79 C80 H80 119.5 . . ?
C81 C80 H80 119.5 . . ?
C82 C81 C80 119.3(10) . . ?
C82 C81 H81 120.4 . . ?
C80 C81 H81 120.4 . . ?
C83 C82 C81 120.8(9) . . ?
C83 C82 H82 119.6 . . ?
C81 C82 H82 119.6 . . ?
C82 C83 C84 120.5(11) . . ?
C82 C83 H83 119.7 . . ?
C84 C83 H83 119.7 . . ?
C79 C84 C83 118.4(10) . . ?
C79 C84 H84 120.8 . . ?
C83 C84 H84 120.8 . . ?
C90 C85 C86 118.5(8) . . ?
C90 C85 P6 117.9(7) . . ?
C86 C85 P6 123.4(6) . . ?
C87 C86 C85 121.3(8) . . ?
C87 C86 H86 119.4 . . ?
C85 C86 H86 119.4 . . ?
C86 C87 C88 120.6(10) . . ?
C86 C87 H87 119.7 . . ?
C88 C87 H87 119.7 . . ?
C89 C88 C87 118.5(10) . . ?
C89 C88 H88 120.8 . . ?
C87 C88 H88 120.8 . . ?
C88 C89 C90 121.9(10) . . ?
C88 C89 H89 119.0 . . ?
C90 C89 H89 119.0 . . ?
C85 C90 C89 119.2(10) . . ?
C85 C90 H90 120.4 . . ?
C89 C90 H90 120.4 . . ?
C96 C91 C92 120.6(7) . . ?
C96 C91 P6 117.6(6) . . ?
C92 C91 P6 121.6(6) . . ?
C93 C92 C91 120.7(8) . . ?
C93 C92 H92 119.6 . . ?
C91 C92 H92 119.6 . . ?
C92 C93 C94 119.0(9) . . ?
C92 C93 H93 120.5 . . ?
C94 C93 H93 120.5 . . ?
C95 C94 C93 120.3(9) . . ?
C95 C94 H94 119.9 . . ?
C93 C94 H94 119.9 . . ?
C94 C95 C96 120.2(9) . . ?
C94 C95 H95 119.9 . . ?
C96 C95 H95 119.9 . . ?
C91 C96 C95 119.1(9) . . ?
C91 C96 H96 120.4 . . ?
C95 C96 H96 120.4 . . ?
C98 C97 C102 120.8(7) . . ?
C98 C97 P7 123.0(5) . . ?
C102 C97 P7 116.3(6) . . ?
C97 C98 C99 118.3(7) . . ?
C97 C98 H98 120.8 . . ?
C99 C98 H98 120.8 . . ?
C100 C99 C98 121.5(9) . . ?
C100 C99 H99 119.3 . . ?
C98 C99 H99 119.3 . . ?
C101 C100 C99 118.6(9) . . ?
C101 C100 H100 120.7 . . ?
C99 C100 H100 120.7 . . ?
C100 C101 C102 122.0(8) . . ?
C100 C101 H101 119.0 . . ?
C102 C101 H101 119.0 . . ?
C101 C102 C97 118.7(8) . . ?
C101 C102 H102 120.7 . . ?
C97 C102 H102 120.7 . . ?
C108 C103 C104 119.5(7) . . ?
C108 C103 P7 119.6(6) . . ?
C104 C103 P7 120.9(6) . . ?
C103 C104 C105 120.4(8) . . ?
C103 C104 H104 119.8 . . ?
C105 C104 H104 119.8 . . ?
C106 C105 C104 119.3(9) . . ?
C106 C105 H105 120.3 . . ?
C104 C105 H105 120.3 . . ?
C105 C106 C107 120.6(7) . . ?
C105 C106 H106 119.7 . . ?
C107 C106 H106 119.7 . . ?
C106 C107 C108 121.4(9) . . ?
C106 C107 H107 119.3 . . ?
C108 C107 H107 119.3 . . ?
C103 C108 C107 118.8(8) . . ?
C103 C108 H108 120.6 . . ?
C107 C108 H108 120.6 . . ?
C114 C109 C110 120.2(11) . . ?
C114 C109 P8 121.6(12) . . ?
C110 C109 P8 117.9(7) . . ?
C111 C110 C109 120.1(14) . . ?
C111 C110 H110 119.9 . . ?
C109 C110 H110 119.9 . . ?
C112 C111 C110 118.9(18) . . ?
C112 C111 H111 120.5 . . ?
C110 C111 H111 120.5 . . ?
C111 C112 C113 122.2(14) . . ?
C111 C112 H112 118.9 . . ?
C113 C112 H112 118.9 . . ?
C112 C113 C114 121.2(15) . . ?
C112 C113 H113 119.4 . . ?
C114 C113 H113 119.4 . . ?
C109 C114 C113 117.2(18) . . ?
C109 C114 H114 121.4 . . ?
C113 C114 H114 121.4 . . ?
C120 C115 C116 120.0(9) . . ?
C120 C115 P8 123.1(7) . . ?
C116 C115 P8 116.7(7) . . ?
C117 C116 C115 120.1(10) . . ?
C117 C116 H116 120.0 . . ?
C115 C116 H116 120.0 . . ?
C116 C117 C118 119.7(11) . . ?
C116 C117 H117 120.2 . . ?
C118 C117 H117 120.2 . . ?
C119 C118 C117 119.9(12) . . ?
C119 C118 H118 120.1 . . ?
C117 C118 H118 120.1 . . ?
C118 C119 C120 120.4(11) . . ?
C118 C119 H119 119.8 . . ?
C120 C119 H119 119.8 . . ?
C115 C120 C119 120.0(9) . . ?
C115 C120 H120 120.0 . . ?
C119 C120 H120 120.0 . . ?
P8 Ag1 P1 151.22(6) . . ?
P8 Ag1 O9 105.57(17) . . ?
P1 Ag1 O9 101.12(16) . . ?
P8 Ag1 O7 96.4(2) . . ?
P1 Ag1 O7 108.7(2) . . ?
O9 Ag1 O7 51.68(19) . . ?
P5 Ag2 P2 150.35(6) . . ?
P5 Ag2 O1 106.86(14) . . ?
P2 Ag2 O1 95.71(13) . . ?
P6 Ag3 O10 112.0(2) . . ?
P6 Ag3 P3 147.92(6) . . ?
O10 Ag3 P3 97.1(2) . . ?
P4 Ag4 P7 145.42(6) . . ?
P4 Ag4 O4 105.82(14) . . ?
P7 Ag4 O4 94.88(13) . . ?
P4 Ag4 O6 106.89(12) . . ?
P7 Ag4 O6 107.68(12) . . ?
O4 Ag4 O6 53.70(16) . . ?
C25 P1 C31 107.2(3) . . ?
C25 P1 C3 105.7(3) . . ?
C31 P1 C3 104.6(3) . . ?
C25 P1 Ag1 111.4(2) . . ?
C31 P1 Ag1 115.6(2) . . ?
C3 P1 Ag1 111.71(19) . . ?
C43 P2 C5 105.0(3) . . ?
C43 P2 C37 104.0(4) . . ?
C5 P2 C37 105.8(3) . . ?
C43 P2 Ag2 121.9(3) . . ?
C5 P2 Ag2 110.5(2) . . ?
C37 P2 Ag2 108.5(2) . . ?
C55 P3 C49 106.9(4) . . ?
C55 P3 C11 103.2(3) . . ?
C49 P3 C11 104.6(3) . . ?
C55 P3 Ag3 109.4(3) . . ?
C49 P3 Ag3 122.0(3) . . ?
C11 P3 Ag3 109.0(2) . . ?
C61 P4 C67 106.3(4) . . ?
C61 P4 C9 105.4(3) . . ?
C67 P4 C9 103.1(3) . . ?
C61 P4 Ag4 117.0(3) . . ?
C67 P4 Ag4 113.0(3) . . ?
C9 P4 Ag4 110.9(2) . . ?
C73 P5 C15 104.8(3) . . ?
C73 P5 C79 103.9(4) . . ?
C15 P5 C79 103.8(3) . . ?
C73 P5 Ag2 113.8(3) . . ?
C15 P5 Ag2 110.5(2) . . ?
C79 P5 Ag2 118.7(2) . . ?
C85 P6 C91 103.4(3) . . ?
C85 P6 C17 105.0(3) . . ?
C91 P6 C17 103.2(3) . . ?
C85 P6 Ag3 114.9(3) . . ?
C91 P6 Ag3 117.9(3) . . ?
C17 P6 Ag3 111.0(2) . . ?
C103 P7 C97 105.9(3) . . ?
C103 P7 C21 104.4(3) . . ?
C97 P7 C21 105.8(3) . . ?
C103 P7 Ag4 123.6(3) . . ?
C97 P7 Ag4 107.5(2) . . ?
C21 P7 Ag4 108.5(2) . . ?
C109 P8 C23 103.8(3) . . ?
C109 P8 C115 108.6(5) . . ?
C23 P8 C115 104.1(3) . . ?
C109 P8 Ag1 118.6(4) . . ?
C23 P8 Ag1 109.7(2) . . ?
C115 P8 Ag1 110.8(3) . . ?
C7 Sn1 C1 118.9(2) . . ?
C7 Sn1 C13 104.3(2) . . ?
C1 Sn1 C13 106.5(2) . . ?
C7 Sn1 C19 105.1(2) . . ?
C1 Sn1 C19 106.0(2) . . ?
C13 Sn1 C19 116.6(2) . . ?
F3 C121 F1 107.2(6) . . ?
F3 C121 F2 107.3(6) . . ?
F1 C121 F2 107.8(6) . . ?
F3 C121 S1 111.6(5) . . ?
F1 C121 S1 112.2(5) . . ?
F2 C121 S1 110.5(5) . . ?
S1 O1 Ag2 101.2(3) . . ?
O3 S1 O1 114.7(3) . . ?
O3 S1 O2 116.7(3) . . ?
O1 S1 O2 113.2(3) . . ?
O3 S1 C121 103.3(3) . . ?
O1 S1 C121 103.0(3) . . ?
O2 S1 C121 103.7(3) . . ?
F5 C122 F6 109.7(5) . . ?
F5 C122 F4 107.2(6) . . ?
F6 C122 F4 107.2(6) . . ?
F5 C122 S2 111.7(5) . . ?
F6 C122 S2 111.0(5) . . ?
F4 C122 S2 109.9(4) . . ?
S2 O4 Ag4 94.6(3) . . ?
S2 O6 Ag4 90.7(3) . . ?
O5 S2 O4 115.9(3) . . ?
O5 S2 O6 115.8(3) . . ?
O4 S2 O6 112.9(3) . . ?
O5 S2 C122 103.2(3) . . ?
O4 S2 C122 102.7(3) . . ?
O6 S2 C122 104.0(3) . . ?
F7 C123 F8 108.5(10) . . ?
F7 C123 F9 105.2(10) . . ?
F8 C123 F9 107.0(9) . . ?
F7 C123 S3 112.7(8) . . ?
F8 C123 S3 112.6(8) . . ?
F9 C123 S3 110.3(7) . . ?
S3 O7 Ag1 96.0(3) . . ?
S3 O9 Ag1 97.8(3) . . ?
O8 S3 O7 117.5(6) . . ?
O8 S3 O9 116.2(6) . . ?
O7 S3 O9 110.3(4) . . ?
O8 S3 C123 104.1(5) . . ?
O7 S3 C123 103.3(5) . . ?
O9 S3 C123 103.2(5) . . ?
F11 C124 F12 105.8(15) . . ?
F11 C124 F10 108.5(13) . . ?
F12 C124 F10 100.9(19) . . ?
F11 C124 S4 113.4(16) . . ?
F12 C124 S4 112.7(11) . . ?
F10 C124 S4 114.5(13) . . ?
S4 O10 Ag3 119.1(6) . . ?
O11 S4 O10 113.7(8) . . ?
O11 S4 O12 119.2(12) . . ?
O10 S4 O12 112.9(7) . . ?
O11 S4 C124 102.4(10) . . ?
O10 S4 C124 101.3(8) . . ?
O12 S4 C124 104.3(11) . . ?
Cl1 C125 Cl2 110.0(13) . . ?
Cl1 C125 Cl3 108.7(8) . . ?
Cl2 C125 Cl3 104.9(14) . . ?
Cl1 C125 H125 111.0 . . ?
Cl2 C125 H125 111.0 . . ?
Cl3 C125 H125 111.0 . . ?
Cl5 C126 Cl6 118.8(17) . . ?
Cl5 C126 Cl4 117.6(15) . . ?
Cl6 C126 Cl4 110.3(13) . . ?
Cl5 C126 H126 102.3 . . ?
Cl6 C126 H126 102.3 . . ?
Cl4 C126 H126 102.3 . . ?
N1 C127 H12A 109.5 . . ?
N1 C127 H12B 109.5 . . ?
H12A C127 H12B 109.5 . . ?
N1 C127 H12C 109.5 . . ?
H12A C127 H12C 109.5 . . ?
H12B C127 H12C 109.5 . . ?
O14 N1 O13 121.3(14) . . ?
O14 N1 C127 120.7(14) . . ?
O13 N1 C127 117.8(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.375(8) . ?
C1 C2 1.400(8) . ?
C1 Sn1 2.140(5) . ?
C2 C3 1.394(8) . ?
C2 H2 0.9500 . ?
C3 C4 1.389(9) . ?
C3 P1 1.834(6) . ?
C4 C5 1.399(9) . ?
C4 H4 0.9500 . ?
C5 C6 1.373(9) . ?
C5 P2 1.832(7) . ?
C6 H6 0.9500 . ?
C7 C12 1.391(8) . ?
C7 C8 1.391(9) . ?
C7 Sn1 2.140(6) . ?
C8 C9 1.388(9) . ?
C8 H8 0.9500 . ?
C9 C10 1.402(9) . ?
C9 P4 1.840(7) . ?
C10 C11 1.389(9) . ?
C10 H10 0.9500 . ?
C11 C12 1.383(9) . ?
C11 P3 1.835(6) . ?
C12 H12 0.9500 . ?
C13 C18 1.386(9) . ?
C13 C14 1.400(9) . ?
C13 Sn1 2.144(6) . ?
C14 C15 1.406(9) . ?
C14 H14 0.9500 . ?
C15 C16 1.399(10) . ?
C15 P5 1.825(7) . ?
C16 C17 1.352(10) . ?
C16 H16 0.9500 . ?
C17 C18 1.393(9) . ?
C17 P6 1.853(7) . ?
C18 H18 0.9500 . ?
C19 C24 1.377(8) . ?
C19 C20 1.389(8) . ?
C19 Sn1 2.148(6) . ?
C20 C21 1.384(8) . ?
C20 H20 0.9500 . ?
C21 C22 1.384(9) . ?
C21 P7 1.832(6) . ?
C22 C23 1.383(9) . ?
C22 H22 0.9500 . ?
C23 C24 1.409(9) . ?
C23 P8 1.824(7) . ?
C24 H24 0.9500 . ?
C25 C30 1.384(10) . ?
C25 C26 1.385(10) . ?
C25 P1 1.810(7) . ?
C26 C27 1.384(12) . ?
C26 H26 0.9500 . ?
C27 C28 1.372(12) . ?
C27 H27 0.9500 . ?
C28 C29 1.348(13) . ?
C28 H28 0.9500 . ?
C29 C30 1.383(12) . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C31 C32 1.374(10) . ?
C31 C36 1.392(10) . ?
C31 P1 1.815(7) . ?
C32 C33 1.400(11) . ?
C32 H32 0.9500 . ?
C33 C34 1.361(13) . ?
C33 H33 0.9500 . ?
C34 C35 1.390(13) . ?
C34 H34 0.9500 . ?
C35 C36 1.353(11) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C38 1.390(10) . ?
C37 C42 1.394(11) . ?
C37 P2 1.842(8) . ?
C38 C39 1.402(12) . ?
C38 H38 0.9500 . ?
C39 C40 1.376(14) . ?
C39 H39 0.9500 . ?
C40 C41 1.381(12) . ?
C40 H40 0.9500 . ?
C41 C42 1.366(12) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 C48 1.346(13) . ?
C43 C44 1.377(11) . ?
C43 P2 1.820(7) . ?
C44 C45 1.388(12) . ?
C44 H44 0.9500 . ?
C45 C46 1.393(16) . ?
C45 H45 0.9500 . ?
C46 C47 1.377(16) . ?
C46 H46 0.9500 . ?
C47 C48 1.402(13) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
C49 C54 1.357(13) . ?
C49 C50 1.368(12) . ?
C49 P3 1.823(8) . ?
C50 C51 1.401(12) . ?
C50 H50 0.9500 . ?
C51 C52 1.318(14) . ?
C51 H51 0.9500 . ?
C52 C53 1.372(19) . ?
C52 H52 0.9500 . ?
C53 C54 1.433(19) . ?
C53 H53 0.9500 . ?
C54 H54 0.9500 . ?
C55 C60 1.393(12) . ?
C55 C56 1.395(11) . ?
C55 P3 1.821(8) . ?
C56 C57 1.380(11) . ?
C56 H56 0.9500 . ?
C57 C58 1.360(14) . ?
C57 H57 0.9500 . ?
C58 C59 1.398(16) . ?
C58 H58 0.9500 . ?
C59 C60 1.402(15) . ?
C59 H59 0.9500 . ?
C60 H60 0.9500 . ?
C61 C66 1.384(12) . ?
C61 C62 1.392(11) . ?
C61 P4 1.804(9) . ?
C62 C63 1.397(14) . ?
C62 H62 0.9500 . ?
C63 C64 1.411(15) . ?
C63 H63 0.9500 . ?
C64 C65 1.384(14) . ?
C64 H64 0.9500 . ?
C65 C66 1.358(13) . ?
C65 H65 0.9500 . ?
C66 H66 0.9500 . ?
C67 C72 1.330(13) . ?
C67 C68 1.417(13) . ?
C67 P4 1.832(8) . ?
C68 C69 1.396(15) . ?
C68 H68 0.9500 . ?
C69 C70 1.390(18) . ?
C69 H69 0.9500 . ?
C70 C71 1.351(18) . ?
C70 H70 0.9500 . ?
C71 C72 1.442(16) . ?
C71 H71 0.9500 . ?
C72 H72 0.9500 . ?
C73 C78 1.374(11) . ?
C73 C74 1.397(11) . ?
C73 P5 1.811(8) . ?
C74 C75 1.333(12) . ?
C74 H74 0.9500 . ?
C75 C76 1.340(13) . ?
C75 H75 0.9500 . ?
C76 C77 1.403(13) . ?
C76 H76 0.9500 . ?
C77 C78 1.405(13) . ?
C77 H77 0.9500 . ?
C78 H78 0.9500 . ?
C79 C84 1.355(12) . ?
C79 C80 1.372(12) . ?
C79 P5 1.832(8) . ?
C80 C81 1.381(12) . ?
C80 H80 0.9500 . ?
C81 C82 1.365(17) . ?
C81 H81 0.9500 . ?
C82 C83 1.332(17) . ?
C82 H82 0.9500 . ?
C83 C84 1.435(12) . ?
C83 H83 0.9500 . ?
C84 H84 0.9500 . ?
C85 C90 1.379(12) . ?
C85 C86 1.413(11) . ?
C85 P6 1.819(7) . ?
C86 C87 1.357(12) . ?
C86 H86 0.9500 . ?
C87 C88 1.396(15) . ?
C87 H87 0.9500 . ?
C88 C89 1.367(17) . ?
C88 H88 0.9500 . ?
C89 C90 1.403(14) . ?
C89 H89 0.9500 . ?
C90 H90 0.9500 . ?
C91 C96 1.371(11) . ?
C91 C92 1.381(12) . ?
C91 P6 1.823(7) . ?
C92 C93 1.364(12) . ?
C92 H92 0.9500 . ?
C93 C94 1.409(14) . ?
C93 H93 0.9500 . ?
C94 C95 1.363(14) . ?
C94 H94 0.9500 . ?
C95 C96 1.398(13) . ?
C95 H95 0.9500 . ?
C96 H96 0.9500 . ?
C97 C98 1.382(10) . ?
C97 C102 1.404(10) . ?
C97 P7 1.827(7) . ?
C98 C99 1.403(11) . ?
C98 H98 0.9500 . ?
C99 C100 1.379(13) . ?
C99 H99 0.9500 . ?
C100 C101 1.375(14) . ?
C100 H100 0.9500 . ?
C101 C102 1.375(12) . ?
C101 H101 0.9500 . ?
C102 H102 0.9500 . ?
C103 C108 1.367(11) . ?
C103 C104 1.389(11) . ?
C103 P7 1.816(7) . ?
C104 C105 1.399(11) . ?
C104 H104 0.9500 . ?
C105 C106 1.344(13) . ?
C105 H105 0.9500 . ?
C106 C107 1.361(13) . ?
C106 H106 0.9500 . ?
C107 C108 1.391(11) . ?
C107 H107 0.9500 . ?
C108 H108 0.9500 . ?
C109 C114 1.383(16) . ?
C109 C110 1.401(17) . ?
C109 P8 1.808(9) . ?
C110 C111 1.395(15) . ?
C110 H110 0.9500 . ?
C111 C112 1.34(3) . ?
C111 H111 0.9500 . ?
C112 C113 1.35(3) . ?
C112 H112 0.9500 . ?
C113 C114 1.41(2) . ?
C113 H113 0.9500 . ?
C114 H114 0.9500 . ?
C115 C120 1.369(12) . ?
C115 C116 1.396(12) . ?
C115 P8 1.840(9) . ?
C116 C117 1.382(15) . ?
C116 H116 0.9500 . ?
C117 C118 1.405(16) . ?
C117 H117 0.9500 . ?
C118 C119 1.363(17) . ?
C118 H118 0.9500 . ?
C119 C120 1.401(17) . ?
C119 H119 0.9500 . ?
C120 H120 0.9500 . ?
Ag1 P8 2.4211(17) . ?
Ag1 P1 2.4236(15) . ?
Ag1 O9 2.674(6) . ?
Ag1 O7 2.733(7) . ?
Ag2 P5 2.4423(17) . ?
Ag2 P2 2.4500(18) . ?
Ag2 O1 2.555(5) . ?
Ag3 P6 2.448(2) . ?
Ag3 O10 2.452(8) . ?
Ag3 P3 2.464(2) . ?
Ag4 P4 2.4337(17) . ?
Ag4 P7 2.4680(18) . ?
Ag4 O4 2.616(5) . ?
Ag4 O6 2.705(5) . ?
C121 F3 1.335(8) . ?
C121 F1 1.336(9) . ?
C121 F2 1.352(9) . ?
C121 S1 1.810(8) . ?
O1 S1 1.445(5) . ?
O2 S1 1.449(5) . ?
O3 S1 1.416(5) . ?
C122 F5 1.321(9) . ?
C122 F6 1.329(8) . ?
C122 F4 1.349(8) . ?
C122 S2 1.819(7) . ?
O4 S2 1.437(6) . ?
O5 S2 1.427(6) . ?
O6 S2 1.448(5) . ?
C123 F7 1.300(12) . ?
C123 F8 1.301(12) . ?
C123 F9 1.347(14) . ?
C123 S3 1.792(10) . ?
O7 S3 1.421(7) . ?
O8 S3 1.390(7) . ?
O9 S3 1.450(7) . ?
C124 F11 1.337(17) . ?
C124 F12 1.35(2) . ?
C124 F10 1.41(2) . ?
C124 S4 1.722(18) . ?
O10 S4 1.460(10) . ?
O11 S4 1.440(12) . ?
O12 S4 1.486(14) . ?
C125 Cl1 1.69(2) . ?
C125 Cl2 1.72(2) . ?
C125 Cl3 1.87(2) . ?
C125 H125 1.0000 . ?
C126 Cl5 1.63(2) . ?
C126 Cl6 1.65(2) . ?
C126 Cl4 1.76(2) . ?
C126 H126 1.0000 . ?
C127 N1 1.369(17) . ?
C127 H12A 0.9800 . ?
C127 H12B 0.9800 . ?
C127 H12C 0.9800 . ?
N1 O14 1.193(13) . ?
N1 O13 1.314(14) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C6 C1 C2 C3 -3.8(9) . . . . ?
Sn1 C1 C2 C3 164.6(5) . . . . ?
C1 C2 C3 C4 1.4(9) . . . . ?
C1 C2 C3 P1 -172.9(5) . . . . ?
C2 C3 C4 C5 1.4(9) . . . . ?
P1 C3 C4 C5 175.2(5) . . . . ?
C3 C4 C5 C6 -1.8(10) . . . . ?
C3 C4 C5 P2 -172.5(5) . . . . ?
C4 C5 C6 C1 -0.6(10) . . . . ?
P2 C5 C6 C1 170.7(5) . . . . ?
C2 C1 C6 C5 3.4(9) . . . . ?
Sn1 C1 C6 C5 -164.9(5) . . . . ?
C12 C7 C8 C9 1.3(9) . . . . ?
Sn1 C7 C8 C9 -169.1(5) . . . . ?
C7 C8 C9 C10 0.1(10) . . . . ?
C7 C8 C9 P4 176.1(5) . . . . ?
C8 C9 C10 C11 -1.3(10) . . . . ?
P4 C9 C10 C11 -177.1(5) . . . . ?
C9 C10 C11 C12 1.2(10) . . . . ?
C9 C10 C11 P3 173.0(5) . . . . ?
C10 C11 C12 C7 0.1(10) . . . . ?
P3 C11 C12 C7 -172.3(5) . . . . ?
C8 C7 C12 C11 -1.4(9) . . . . ?
Sn1 C7 C12 C11 169.1(5) . . . . ?
C18 C13 C14 C15 1.5(9) . . . . ?
Sn1 C13 C14 C15 -170.4(5) . . . . ?
C13 C14 C15 C16 -0.8(9) . . . . ?
C13 C14 C15 P5 174.7(5) . . . . ?
C14 C15 C16 C17 -1.2(10) . . . . ?
P5 C15 C16 C17 -176.1(5) . . . . ?
C15 C16 C17 C18 2.4(10) . . . . ?
C15 C16 C17 P6 173.4(5) . . . . ?
C14 C13 C18 C17 -0.2(9) . . . . ?
Sn1 C13 C18 C17 171.6(5) . . . . ?
C16 C17 C18 C13 -1.7(10) . . . . ?
P6 C17 C18 C13 -173.6(5) . . . . ?
C24 C19 C20 C21 3.0(9) . . . . ?
Sn1 C19 C20 C21 -169.6(5) . . . . ?
C19 C20 C21 C22 -0.8(9) . . . . ?
C19 C20 C21 P7 168.5(5) . . . . ?
C20 C21 C22 C23 -1.1(9) . . . . ?
P7 C21 C22 C23 -169.5(5) . . . . ?
C21 C22 C23 C24 0.8(9) . . . . ?
C21 C22 C23 P8 175.2(5) . . . . ?
C20 C19 C24 C23 -3.4(9) . . . . ?
Sn1 C19 C24 C23 169.1(5) . . . . ?
C22 C23 C24 C19 1.5(9) . . . . ?
P8 C23 C24 C19 -173.4(5) . . . . ?
C30 C25 C26 C27 0.4(11) . . . . ?
P1 C25 C26 C27 174.4(6) . . . . ?
C25 C26 C27 C28 -0.4(14) . . . . ?
C26 C27 C28 C29 1.6(16) . . . . ?
C27 C28 C29 C30 -2.8(17) . . . . ?
C28 C29 C30 C25 2.9(15) . . . . ?
C26 C25 C30 C29 -1.7(12) . . . . ?
P1 C25 C30 C29 -176.0(7) . . . . ?
C36 C31 C32 C33 1.0(11) . . . . ?
P1 C31 C32 C33 -176.5(6) . . . . ?
C31 C32 C33 C34 0.8(11) . . . . ?
C32 C33 C34 C35 -2.2(13) . . . . ?
C33 C34 C35 C36 1.7(14) . . . . ?
C34 C35 C36 C31 0.1(14) . . . . ?
C32 C31 C36 C35 -1.5(12) . . . . ?
P1 C31 C36 C35 176.1(7) . . . . ?
C42 C37 C38 C39 1.2(12) . . . . ?
P2 C37 C38 C39 177.0(7) . . . . ?
C37 C38 C39 C40 -2.7(15) . . . . ?
C38 C39 C40 C41 3.4(16) . . . . ?
C39 C40 C41 C42 -2.6(16) . . . . ?
C40 C41 C42 C37 1.2(14) . . . . ?
C38 C37 C42 C41 -0.5(12) . . . . ?
P2 C37 C42 C41 -175.9(7) . . . . ?
C48 C43 C44 C45 1.9(13) . . . . ?
P2 C43 C44 C45 179.1(6) . . . . ?
C43 C44 C45 C46 -1.4(13) . . . . ?
C44 C45 C46 C47 0.8(17) . . . . ?
C45 C46 C47 C48 -1(2) . . . . ?
C44 C43 C48 C47 -1.8(15) . . . . ?
P2 C43 C48 C47 -179.0(9) . . . . ?
C46 C47 C48 C43 1.2(18) . . . . ?
C54 C49 C50 C51 -3.5(17) . . . . ?
P3 C49 C50 C51 -177.3(7) . . . . ?
C49 C50 C51 C52 4.5(16) . . . . ?
C50 C51 C52 C53 -5(3) . . . . ?
C51 C52 C53 C54 4(4) . . . . ?
C50 C49 C54 C53 3(3) . . . . ?
P3 C49 C54 C53 177(2) . . . . ?
C52 C53 C54 C49 -3(4) . . . . ?
C60 C55 C56 C57 -1.3(13) . . . . ?
P3 C55 C56 C57 175.9(7) . . . . ?
C55 C56 C57 C58 0.4(14) . . . . ?
C56 C57 C58 C59 0.9(16) . . . . ?
C57 C58 C59 C60 -1.4(18) . . . . ?
C56 C55 C60 C59 0.8(14) . . . . ?
P3 C55 C60 C59 -176.5(9) . . . . ?
C58 C59 C60 C55 0.5(18) . . . . ?
C66 C61 C62 C63 -3.0(15) . . . . ?
P4 C61 C62 C63 -178.4(9) . . . . ?
C61 C62 C63 C64 2.2(18) . . . . ?
C62 C63 C64 C65 -1.5(19) . . . . ?
C63 C64 C65 C66 2(2) . . . . ?
C64 C65 C66 C61 -2.7(19) . . . . ?
C62 C61 C66 C65 3.3(16) . . . . ?
P4 C61 C66 C65 178.7(9) . . . . ?
C72 C67 C68 C69 2.1(17) . . . . ?
P4 C67 C68 C69 -177.5(10) . . . . ?
C67 C68 C69 C70 -2.7(19) . . . . ?
C68 C69 C70 C71 1(2) . . . . ?
C69 C70 C71 C72 1(2) . . . . ?
C68 C67 C72 C71 -0.1(18) . . . . ?
P4 C67 C72 C71 179.5(10) . . . . ?
C70 C71 C72 C67 -1(2) . . . . ?
C78 C73 C74 C75 5.8(14) . . . . ?
P5 C73 C74 C75 -177.2(8) . . . . ?
C73 C74 C75 C76 -4.8(16) . . . . ?
C74 C75 C76 C77 2.6(17) . . . . ?
C75 C76 C77 C78 -1.5(18) . . . . ?
C74 C73 C78 C77 -4.4(15) . . . . ?
P5 C73 C78 C77 178.3(9) . . . . ?
C76 C77 C78 C73 2.5(18) . . . . ?
C84 C79 C80 C81 -1.0(14) . . . . ?
P5 C79 C80 C81 177.3(8) . . . . ?
C79 C80 C81 C82 -1.0(16) . . . . ?
C80 C81 C82 C83 2.5(17) . . . . ?
C81 C82 C83 C84 -2.0(17) . . . . ?
C80 C79 C84 C83 1.5(13) . . . . ?
P5 C79 C84 C83 -176.9(7) . . . . ?
C82 C83 C84 C79 0.0(15) . . . . ?
C90 C85 C86 C87 0.7(15) . . . . ?
P6 C85 C86 C87 175.4(8) . . . . ?
C85 C86 C87 C88 0.8(16) . . . . ?
C86 C87 C88 C89 0(2) . . . . ?
C87 C88 C89 C90 -3(2) . . . . ?
C86 C85 C90 C89 -3.2(18) . . . . ?
P6 C85 C90 C89 -178.2(11) . . . . ?
C88 C89 C90 C85 4(2) . . . . ?
C96 C91 C92 C93 1.8(13) . . . . ?
P6 C91 C92 C93 -174.7(7) . . . . ?
C91 C92 C93 C94 -0.7(13) . . . . ?
C92 C93 C94 C95 -1.5(14) . . . . ?
C93 C94 C95 C96 2.5(15) . . . . ?
C92 C91 C96 C95 -0.8(13) . . . . ?
P6 C91 C96 C95 175.8(7) . . . . ?
C94 C95 C96 C91 -1.4(14) . . . . ?
C102 C97 C98 C99 -0.4(10) . . . . ?
P7 C97 C98 C99 178.9(5) . . . . ?
C97 C98 C99 C100 -0.9(12) . . . . ?
C98 C99 C100 C101 2.0(13) . . . . ?
C99 C100 C101 C102 -1.8(14) . . . . ?
C100 C101 C102 C97 0.6(13) . . . . ?
C98 C97 C102 C101 0.6(11) . . . . ?
P7 C97 C102 C101 -178.8(6) . . . . ?
C108 C103 C104 C105 1.8(13) . . . . ?
P7 C103 C104 C105 179.5(7) . . . . ?
C103 C104 C105 C106 -0.6(14) . . . . ?
C104 C105 C106 C107 0.0(15) . . . . ?
C105 C106 C107 C108 -0.5(16) . . . . ?
C104 C103 C108 C107 -2.4(13) . . . . ?
P7 C103 C108 C107 179.9(7) . . . . ?
C106 C107 C108 C103 1.8(15) . . . . ?
C114 C109 C110 C111 0.8(18) . . . . ?
P8 C109 C110 C111 175.6(10) . . . . ?
C109 C110 C111 C112 -1(2) . . . . ?
C110 C111 C112 C113 2(3) . . . . ?
C111 C112 C113 C114 -4(3) . . . . ?
C110 C109 C114 C113 -2(2) . . . . ?
P8 C109 C114 C113 -176.5(13) . . . . ?
C112 C113 C114 C109 3(3) . . . . ?
C120 C115 C116 C117 0.6(19) . . . . ?
P8 C115 C116 C117 -174.0(12) . . . . ?
C115 C116 C117 C118 -1(2) . . . . ?
C116 C117 C118 C119 1(3) . . . . ?
C117 C118 C119 C120 -1(3) . . . . ?
C116 C115 C120 C119 -0.7(19) . . . . ?
P8 C115 C120 C119 173.6(11) . . . . ?
C118 C119 C120 C115 1(3) . . . . ?
C30 C25 P1 C31 -73.5(6) . . . . ?
C26 C25 P1 C31 112.5(6) . . . . ?
C30 C25 P1 C3 175.4(6) . . . . ?
C26 C25 P1 C3 1.4(7) . . . . ?
C30 C25 P1 Ag1 53.9(6) . . . . ?
C26 C25 P1 Ag1 -120.1(6) . . . . ?
C32 C31 P1 C25 -40.7(7) . . . . ?
C36 C31 P1 C25 141.9(6) . . . . ?
C32 C31 P1 C3 71.3(6) . . . . ?
C36 C31 P1 C3 -106.2(6) . . . . ?
C32 C31 P1 Ag1 -165.5(5) . . . . ?
C36 C31 P1 Ag1 17.1(6) . . . . ?
C4 C3 P1 C25 106.5(6) . . . . ?
C2 C3 P1 C25 -79.5(5) . . . . ?
C4 C3 P1 C31 -6.4(6) . . . . ?
C2 C3 P1 C31 167.6(5) . . . . ?
C4 C3 P1 Ag1 -132.2(5) . . . . ?
C2 C3 P1 Ag1 41.8(5) . . . . ?
P8 Ag1 P1 C25 111.9(3) . . . . ?
O9 Ag1 P1 C25 -45.9(3) . . . . ?
O7 Ag1 P1 C25 -99.0(3) . . . . ?
P8 Ag1 P1 C31 -125.5(3) . . . . ?
O9 Ag1 P1 C31 76.7(3) . . . . ?
O7 Ag1 P1 C31 23.6(3) . . . . ?
P8 Ag1 P1 C3 -6.1(3) . . . . ?
O9 Ag1 P1 C3 -163.9(3) . . . . ?
O7 Ag1 P1 C3 143.0(3) . . . . ?
C48 C43 P2 C5 113.0(7) . . . . ?
C44 C43 P2 C5 -64.3(7) . . . . ?
C48 C43 P2 C37 -136.1(7) . . . . ?
C44 C43 P2 C37 46.7(7) . . . . ?
C48 C43 P2 Ag2 -13.4(8) . . . . ?
C44 C43 P2 Ag2 169.3(5) . . . . ?
C6 C5 P2 C43 180.0(5) . . . . ?
C4 C5 P2 C43 -9.1(7) . . . . ?
C6 C5 P2 C37 70.4(6) . . . . ?
C4 C5 P2 C37 -118.8(6) . . . . ?
C6 C5 P2 Ag2 -46.9(5) . . . . ?
C4 C5 P2 Ag2 124.0(5) . . . . ?
C38 C37 P2 C43 78.5(7) . . . . ?
C42 C37 P2 C43 -105.9(7) . . . . ?
C38 C37 P2 C5 -171.1(6) . . . . ?
C42 C37 P2 C5 4.5(7) . . . . ?
C38 C37 P2 Ag2 -52.5(6) . . . . ?
C42 C37 P2 Ag2 123.0(6) . . . . ?
P5 Ag2 P2 C43 157.4(3) . . . . ?
O1 Ag2 P2 C43 -62.7(3) . . . . ?
P5 Ag2 P2 C5 33.5(3) . . . . ?
O1 Ag2 P2 C5 173.4(3) . . . . ?
P5 Ag2 P2 C37 -82.1(3) . . . . ?
O1 Ag2 P2 C37 57.8(3) . . . . ?
C60 C55 P3 C49 -97.2(8) . . . . ?
C56 C55 P3 C49 85.7(7) . . . . ?
C60 C55 P3 C11 152.8(7) . . . . ?
C56 C55 P3 C11 -24.3(8) . . . . ?
C60 C55 P3 Ag3 36.8(8) . . . . ?
C56 C55 P3 Ag3 -140.3(6) . . . . ?
C54 C49 P3 C55 152.5(12) . . . . ?
C50 C49 P3 C55 -33.5(8) . . . . ?
C54 C49 P3 C11 -98.4(12) . . . . ?
C50 C49 P3 C11 75.5(8) . . . . ?
C54 C49 P3 Ag3 25.7(13) . . . . ?
C50 C49 P3 Ag3 -160.3(6) . . . . ?
C12 C11 P3 C55 -63.3(6) . . . . ?
C10 C11 P3 C55 124.6(6) . . . . ?
C12 C11 P3 C49 -175.0(5) . . . . ?
C10 C11 P3 C49 12.9(7) . . . . ?
C12 C11 P3 Ag3 53.0(5) . . . . ?
C10 C11 P3 Ag3 -119.1(5) . . . . ?
P6 Ag3 P3 C55 80.3(3) . . . . ?
O10 Ag3 P3 C55 -75.2(4) . . . . ?
P6 Ag3 P3 C49 -154.0(3) . . . . ?
O10 Ag3 P3 C49 50.5(4) . . . . ?
P6 Ag3 P3 C11 -31.9(3) . . . . ?
O10 Ag3 P3 C11 172.6(4) . . . . ?
C66 C61 P4 C67 82.7(8) . . . . ?
C62 C61 P4 C67 -102.0(8) . . . . ?
C66 C61 P4 C9 -168.3(8) . . . . ?
C62 C61 P4 C9 7.0(9) . . . . ?
C66 C61 P4 Ag4 -44.5(9) . . . . ?
C62 C61 P4 Ag4 130.8(7) . . . . ?
C72 C67 P4 C61 1.7(10) . . . . ?
C68 C67 P4 C61 -178.7(7) . . . . ?
C72 C67 P4 C9 -108.9(9) . . . . ?
C68 C67 P4 C9 70.7(7) . . . . ?
C72 C67 P4 Ag4 131.2(9) . . . . ?
C68 C67 P4 Ag4 -49.2(8) . . . . ?
C8 C9 P4 C61 95.5(6) . . . . ?
C10 C9 P4 C61 -88.7(7) . . . . ?
C8 C9 P4 C67 -153.3(5) . . . . ?
C10 C9 P4 C67 22.6(7) . . . . ?
C8 C9 P4 Ag4 -32.0(6) . . . . ?
C10 C9 P4 Ag4 143.8(5) . . . . ?
P7 Ag4 P4 C61 -141.5(3) . . . . ?
O4 Ag4 P4 C61 93.9(3) . . . . ?
O6 Ag4 P4 C61 37.8(3) . . . . ?
P7 Ag4 P4 C67 94.6(3) . . . . ?
O4 Ag4 P4 C67 -30.0(3) . . . . ?
O6 Ag4 P4 C67 -86.1(3) . . . . ?
P7 Ag4 P4 C9 -20.6(3) . . . . ?
O4 Ag4 P4 C9 -145.2(3) . . . . ?
O6 Ag4 P4 C9 158.6(3) . . . . ?
C78 C73 P5 C15 176.7(7) . . . . ?
C74 C73 P5 C15 -0.3(8) . . . . ?
C78 C73 P5 C79 68.0(8) . . . . ?
C74 C73 P5 C79 -109.0(8) . . . . ?
C78 C73 P5 Ag2 -62.5(8) . . . . ?
C74 C73 P5 Ag2 120.5(7) . . . . ?
C16 C15 P5 C73 -99.8(6) . . . . ?
C14 C15 P5 C73 85.2(6) . . . . ?
C16 C15 P5 C79 8.9(7) . . . . ?
C14 C15 P5 C79 -166.1(5) . . . . ?
C16 C15 P5 Ag2 137.3(6) . . . . ?
C14 C15 P5 Ag2 -37.8(5) . . . . ?
C84 C79 P5 C73 -155.5(7) . . . . ?
C80 C79 P5 C73 26.1(8) . . . . ?
C84 C79 P5 C15 95.2(7) . . . . ?
C80 C79 P5 C15 -83.2(8) . . . . ?
C84 C79 P5 Ag2 -27.9(8) . . . . ?
C80 C79 P5 Ag2 153.7(6) . . . . ?
P2 Ag2 P5 C73 -113.4(3) . . . . ?
O1 Ag2 P5 C73 108.6(3) . . . . ?
P2 Ag2 P5 C15 4.1(3) . . . . ?
O1 Ag2 P5 C15 -133.8(3) . . . . ?
P2 Ag2 P5 C79 123.8(3) . . . . ?
O1 Ag2 P5 C79 -14.1(3) . . . . ?
C90 C85 P6 C91 -66.4(9) . . . . ?
C86 C85 P6 C91 118.9(7) . . . . ?
C90 C85 P6 C17 -174.3(9) . . . . ?
C86 C85 P6 C17 11.0(8) . . . . ?
C90 C85 P6 Ag3 63.5(9) . . . . ?
C86 C85 P6 Ag3 -111.2(7) . . . . ?
C96 C91 P6 C85 148.4(7) . . . . ?
C92 C91 P6 C85 -35.1(7) . . . . ?
C96 C91 P6 C17 -102.4(7) . . . . ?
C92 C91 P6 C17 74.2(7) . . . . ?
C96 C91 P6 Ag3 20.3(7) . . . . ?
C92 C91 P6 Ag3 -163.1(6) . . . . ?
C16 C17 P6 C85 107.1(6) . . . . ?
C18 C17 P6 C85 -81.4(6) . . . . ?
C16 C17 P6 C91 -0.9(7) . . . . ?
C18 C17 P6 C91 170.6(5) . . . . ?
C16 C17 P6 Ag3 -128.1(6) . . . . ?
C18 C17 P6 Ag3 43.3(5) . . . . ?
O10 Ag3 P6 C85 -101.2(4) . . . . ?
P3 Ag3 P6 C85 105.1(3) . . . . ?
O10 Ag3 P6 C91 21.2(4) . . . . ?
P3 Ag3 P6 C91 -132.5(3) . . . . ?
O10 Ag3 P6 C17 139.8(4) . . . . ?
P3 Ag3 P6 C17 -13.8(3) . . . . ?
C108 C103 P7 C97 -142.1(6) . . . . ?
C104 C103 P7 C97 40.1(7) . . . . ?
C108 C103 P7 C21 106.5(6) . . . . ?
C104 C103 P7 C21 -71.3(7) . . . . ?
C108 C103 P7 Ag4 -17.8(7) . . . . ?
C104 C103 P7 Ag4 164.5(6) . . . . ?
C98 C97 P7 C103 -80.4(6) . . . . ?
C102 C97 P7 C103 99.1(5) . . . . ?
C98 C97 P7 C21 30.0(6) . . . . ?
C102 C97 P7 C21 -150.5(5) . . . . ?
C98 C97 P7 Ag4 145.7(5) . . . . ?
C102 C97 P7 Ag4 -34.8(5) . . . . ?
C22 C21 P7 C103 -17.0(6) . . . . ?
C20 C21 P7 C103 174.1(5) . . . . ?
C22 C21 P7 C97 -128.5(5) . . . . ?
C20 C21 P7 C97 62.6(5) . . . . ?
C22 C21 P7 Ag4 116.5(5) . . . . ?
C20 C21 P7 Ag4 -52.4(5) . . . . ?
P4 Ag4 P7 C103 -178.4(3) . . . . ?
O4 Ag4 P7 C103 -51.1(3) . . . . ?
O6 Ag4 P7 C103 2.3(3) . . . . ?
P4 Ag4 P7 C97 -54.7(2) . . . . ?
O4 Ag4 P7 C97 72.6(2) . . . . ?
O6 Ag4 P7 C97 126.0(2) . . . . ?
P4 Ag4 P7 C21 59.2(2) . . . . ?
O4 Ag4 P7 C21 -173.5(2) . . . . ?
O6 Ag4 P7 C21 -120.1(2) . . . . ?
C114 C109 P8 C23 85.8(10) . . . . ?
C110 C109 P8 C23 -89.0(8) . . . . ?
C114 C109 P8 C115 -24.6(10) . . . . ?
C110 C109 P8 C115 160.7(8) . . . . ?
C114 C109 P8 Ag1 -152.3(8) . . . . ?
C110 C109 P8 Ag1 33.0(9) . . . . ?
C22 C23 P8 C109 -5.1(7) . . . . ?
C24 C23 P8 C109 169.5(6) . . . . ?
C22 C23 P8 C115 108.5(6) . . . . ?
C24 C23 P8 C115 -76.9(6) . . . . ?
C22 C23 P8 Ag1 -132.8(5) . . . . ?
C24 C23 P8 Ag1 41.8(5) . . . . ?
C120 C115 P8 C109 95.5(10) . . . . ?
C116 C115 P8 C109 -90.1(9) . . . . ?
C120 C115 P8 C23 -14.6(10) . . . . ?
C116 C115 P8 C23 159.8(9) . . . . ?
C120 C115 P8 Ag1 -132.6(9) . . . . ?
C116 C115 P8 Ag1 41.9(9) . . . . ?
P1 Ag1 P8 C109 -149.4(4) . . . . ?
O9 Ag1 P8 C109 7.9(4) . . . . ?
O7 Ag1 P8 C109 59.9(4) . . . . ?
P1 Ag1 P8 C23 -30.5(3) . . . . ?
O9 Ag1 P8 C23 126.9(3) . . . . ?
O7 Ag1 P8 C23 178.8(3) . . . . ?
P1 Ag1 P8 C115 84.0(3) . . . . ?
O9 Ag1 P8 C115 -118.7(3) . . . . ?
O7 Ag1 P8 C115 -66.7(3) . . . . ?
C12 C7 Sn1 C1 90.6(5) . . . . ?
C8 C7 Sn1 C1 -99.2(5) . . . . ?
C12 C7 Sn1 C13 -27.8(5) . . . . ?
C8 C7 Sn1 C13 142.4(5) . . . . ?
C12 C7 Sn1 C19 -151.0(5) . . . . ?
C8 C7 Sn1 C19 19.2(5) . . . . ?
C6 C1 Sn1 C7 -96.5(5) . . . . ?
C2 C1 Sn1 C7 95.2(5) . . . . ?
C6 C1 Sn1 C13 20.7(6) . . . . ?
C2 C1 Sn1 C13 -147.5(5) . . . . ?
C6 C1 Sn1 C19 145.5(5) . . . . ?
C2 C1 Sn1 C19 -22.7(6) . . . . ?
C18 C13 Sn1 C7 -22.0(5) . . . . ?
C14 C13 Sn1 C7 149.7(5) . . . . ?
C18 C13 Sn1 C1 -148.5(5) . . . . ?
C14 C13 Sn1 C1 23.1(5) . . . . ?
C18 C13 Sn1 C19 93.4(5) . . . . ?
C14 C13 Sn1 C19 -94.9(5) . . . . ?
C24 C19 Sn1 C7 -146.3(5) . . . . ?
C20 C19 Sn1 C7 26.1(5) . . . . ?
C24 C19 Sn1 C1 -19.5(6) . . . . ?
C20 C19 Sn1 C1 152.9(5) . . . . ?
C24 C19 Sn1 C13 98.8(5) . . . . ?
C20 C19 Sn1 C13 -88.8(5) . . . . ?
P5 Ag2 O1 S1 -76.8(3) . . . . ?
P2 Ag2 O1 S1 122.7(3) . . . . ?
Ag2 O1 S1 O3 115.0(3) . . . . ?
Ag2 O1 S1 O2 -22.2(4) . . . . ?
Ag2 O1 S1 C121 -133.5(3) . . . . ?
F3 C121 S1 O3 60.1(6) . . . . ?
F1 C121 S1 O3 -179.6(5) . . . . ?
F2 C121 S1 O3 -59.3(5) . . . . ?
F3 C121 S1 O1 -59.6(6) . . . . ?
F1 C121 S1 O1 60.8(6) . . . . ?
F2 C121 S1 O1 -178.9(5) . . . . ?
F3 C121 S1 O2 -177.7(5) . . . . ?
F1 C121 S1 O2 -57.3(6) . . . . ?
F2 C121 S1 O2 63.0(5) . . . . ?
P4 Ag4 O4 S2 -82.9(3) . . . . ?
P7 Ag4 O4 S2 125.0(3) . . . . ?
O6 Ag4 O4 S2 16.7(2) . . . . ?
P4 Ag4 O6 S2 81.0(2) . . . . ?
P7 Ag4 O6 S2 -99.4(2) . . . . ?
O4 Ag4 O6 S2 -16.5(2) . . . . ?
Ag4 O4 S2 O5 109.1(3) . . . . ?
Ag4 O4 S2 O6 -27.9(3) . . . . ?
Ag4 O4 S2 C122 -139.2(3) . . . . ?
Ag4 O6 S2 O5 -110.2(3) . . . . ?
Ag4 O6 S2 O4 26.8(3) . . . . ?
Ag4 O6 S2 C122 137.3(3) . . . . ?
F5 C122 S2 O5 -58.9(5) . . . . ?
F6 C122 S2 O5 63.8(6) . . . . ?
F4 C122 S2 O5 -177.8(5) . . . . ?
F5 C122 S2 O4 -179.8(5) . . . . ?
F6 C122 S2 O4 -57.1(6) . . . . ?
F4 C122 S2 O4 61.3(6) . . . . ?
F5 C122 S2 O6 62.4(5) . . . . ?
F6 C122 S2 O6 -174.9(5) . . . . ?
F4 C122 S2 O6 -56.5(6) . . . . ?
P8 Ag1 O7 S3 -117.2(4) . . . . ?
P1 Ag1 O7 S3 77.2(4) . . . . ?
O9 Ag1 O7 S3 -12.4(3) . . . . ?
P8 Ag1 O9 S3 98.0(3) . . . . ?
P1 Ag1 O9 S3 -92.9(3) . . . . ?
O7 Ag1 O9 S3 12.2(3) . . . . ?
Ag1 O7 S3 O8 -117.0(5) . . . . ?
Ag1 O7 S3 O9 19.4(5) . . . . ?
Ag1 O7 S3 C123 129.1(4) . . . . ?
Ag1 O9 S3 O8 117.1(4) . . . . ?
Ag1 O9 S3 O7 -19.9(5) . . . . ?
Ag1 O9 S3 C123 -129.7(4) . . . . ?
F7 C123 S3 O8 170.7(10) . . . . ?
F8 C123 S3 O8 -66.1(11) . . . . ?
F9 C123 S3 O8 53.4(10) . . . . ?
F7 C123 S3 O7 -66.0(11) . . . . ?
F8 C123 S3 O7 57.2(10) . . . . ?
F9 C123 S3 O7 176.7(7) . . . . ?
F7 C123 S3 O9 48.9(11) . . . . ?
F8 C123 S3 O9 172.2(9) . . . . ?
F9 C123 S3 O9 -68.3(8) . . . . ?
P6 Ag3 O10 S4 65.6(7) . . . . ?
P3 Ag3 O10 S4 -128.2(6) . . . . ?
Ag3 O10 S4 O11 102.5(11) . . . . ?
Ag3 O10 S4 O12 -37.4(11) . . . . ?
Ag3 O10 S4 C124 -148.5(9) . . . . ?
F11 C124 S4 O11 -64.2(17) . . . . ?
F12 C124 S4 O11 175.6(15) . . . . ?
F10 C124 S4 O11 61.0(16) . . . . ?
F11 C124 S4 O10 178.1(14) . . . . ?
F12 C124 S4 O10 57.9(17) . . . . ?
F10 C124 S4 O10 -56.7(15) . . . . ?
F11 C124 S4 O12 60.7(17) . . . . ?
F12 C124 S4 O12 -59.6(18) . . . . ?
F10 C124 S4 O12 -174.1(14) . . . . ?
