#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:10:58 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179097 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/59/4305923.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4305923
loop_
_publ_author_name
'Colleen Munro-Leighton'
'Yuee Feng'
'Jubo Zhang'
'Nikki M. Alsop'
'T. Brent Gunnoe'
'Paul D. Boyle'
'Jeffrey L. Petersen'
_publ_contact_author_address
;Department of Chemistry
North Carolina State University
Raleigh, NC  27695-8204
;
_publ_contact_author_email       brent_gunnoe@ncsu.edu
_publ_contact_author_fax         '(919) 515-8909'
_publ_contact_author_name        'T. Brent Gunnoe'
_publ_contact_author_phone       '(919) 513-3704'
_publ_section_title
;
Preparation and Reactivity of a Monomeric Octahedral Platinum(IV) Amido
Complex
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6124
_journal_page_last               6126
_journal_paper_doi               10.1021/ic800843b
_journal_volume                  47
_journal_year                    2008
_chemical_formula_sum            'C31 H34 N5 Pt'
_chemical_formula_weight         671.72
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.2142(19)
_cell_angle_beta                 104.5609(17)
_cell_angle_gamma                107.6833(16)
_cell_formula_units_Z            2
_cell_length_a                   9.6908(3)
_cell_length_b                   12.7644(5)
_cell_length_c                   13.0869(5)
_cell_measurement_reflns_used    9981
_cell_measurement_temperature    110
_cell_measurement_theta_max      33.50
_cell_measurement_theta_min      2.37
_cell_volume                     1365.71(9)
_computing_cell_refinement       SAINT
_computing_data_collection       Apex2
_computing_data_reduction        SAINT
_computing_molecular_graphics    NRCVAX
_computing_publication_material  cif2tables.py
_computing_structure_refinement  XL
_computing_structure_solution    XS
_diffrn_ambient_temperature      110
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker-Nonius X8 Apex2'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0394
_diffrn_reflns_av_sigmaI/netI    0.0425
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            48861
_diffrn_reflns_theta_full        33.70
_diffrn_reflns_theta_max         33.70
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    5.166
_exptl_absorpt_correction_T_max  0.6261
_exptl_absorpt_correction_T_min  0.3063
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.633
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             666
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.087
_refine_diff_density_min         -1.217
_refine_diff_density_rms         0.142
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     336
_refine_ls_number_reflns         10669
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.064
_refine_ls_R_factor_all          0.0320
_refine_ls_R_factor_gt           0.0255
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0180P)²+0.2508P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0469
_refine_ls_wR_factor_ref         0.0486
_reflns_number_gt                9466
_reflns_number_total             10669
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic800843b-file003_4.cif
_cod_data_source_block           (NCN)PtMe2NHPh_(4)
_cod_database_code               4305923
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.086197(8) 0.708875(6) 0.296077(6) 0.01223(2) Uani 1 1 d . . .
N1 N 0.2481(2) 0.84263(15) 0.46285(15) 0.0173(3) Uani 1 1 d . . .
N2 N 0.2590(2) 0.95688(15) 0.49944(15) 0.0205(4) Uani 1 1 d . . .
N3 N 0.27185(19) 0.68116(14) 0.24954(14) 0.0142(3) Uani 1 1 d . . .
N4 N 0.29061(19) 0.69021(15) 0.15290(14) 0.0155(3) Uani 1 1 d . . .
N5 N 0.0577(2) 0.57870(15) 0.36424(15) 0.0179(3) Uani 1 1 d . . .
H5N H 0.0756 0.6062 0.4385 0.021 Uiso 1 1 calc R . .
C1 C 0.1337(2) 0.84599(17) 0.24187(17) 0.0142(4) Uani 1 1 d . . .
C2 C 0.1533(2) 0.96188(18) 0.30951(19) 0.0186(4) Uani 1 1 d . . .
C3 C 0.1837(3) 1.05414(19) 0.2718(2) 0.0221(4) Uani 1 1 d . . .
H3 H 0.1920 1.1305 0.3182 0.027 Uiso 1 1 calc R . .
C4 C 0.2020(3) 1.03639(19) 0.1674(2) 0.0224(5) Uani 1 1 d . . .
H4 H 0.2145 1.0975 0.1387 0.027 Uiso 1 1 calc R . .
C5 C 0.2018(2) 0.92735(18) 0.10544(18) 0.0186(4) Uani 1 1 d . . .
H5 H 0.2229 0.9160 0.0368 0.022 Uiso 1 1 calc R . .
C6 C 0.1710(2) 0.83464(17) 0.14275(17) 0.0154(4) Uani 1 1 d . . .
C7 C 0.1517(3) 0.99121(19) 0.42989(19) 0.0226(5) Uani 1 1 d . . .
H7A H 0.1815 1.0786 0.4685 0.027 Uiso 1 1 calc R . .
H7B H 0.0445 0.9485 0.4247 0.027 Uiso 1 1 calc R . .
C8 C 0.3754(3) 1.0253(2) 0.60332(19) 0.0273(5) Uani 1 1 d . . .
H8 H 0.4056 1.1084 0.6465 0.033 Uiso 1 1 calc R . .
C9 C 0.4423(3) 0.9545(2) 0.63576(19) 0.0285(5) Uani 1 1 d . . .
H9 H 0.5272 0.9777 0.7049 0.034 Uiso 1 1 calc R . .
C10 C 0.3595(2) 0.8410(2) 0.54585(18) 0.0207(4) Uani 1 1 d . . .
H10 H 0.3793 0.7721 0.5438 0.025 Uiso 1 1 calc R . .
C11 C 0.1861(2) 0.72219(18) 0.07726(17) 0.0162(4) Uani 1 1 d . . .
H11A H 0.0814 0.6547 0.0376 0.019 Uiso 1 1 calc R . .
H11B H 0.2268 0.7344 0.0176 0.019 Uiso 1 1 calc R . .
C12 C 0.4090(2) 0.66218(18) 0.13807(19) 0.0201(4) Uani 1 1 d . . .
H12 H 0.4442 0.6617 0.0765 0.024 Uiso 1 1 calc R . .
C13 C 0.4702(2) 0.63433(19) 0.22825(19) 0.0206(4) Uani 1 1 d . . .
H13 H 0.5553 0.6113 0.2416 0.025 Uiso 1 1 calc R . .
C14 C 0.3811(2) 0.64711(18) 0.29569(18) 0.0178(4) Uani 1 1 d . . .
H14 H 0.3957 0.6336 0.3645 0.021 Uiso 1 1 calc R . .
C15 C -0.0830(2) 0.58172(18) 0.14041(18) 0.0198(4) Uani 1 1 d . . .
H15A H -0.1300 0.6213 0.0973 0.030 Uiso 1 1 calc R . .
H15B H -0.1639 0.5256 0.1538 0.030 Uiso 1 1 calc R . .
H15C H -0.0359 0.5376 0.0959 0.030 Uiso 1 1 calc R . .
C16 C -0.0992(2) 0.7271(2) 0.3357(2) 0.0214(4) Uani 1 1 d . . .
H16A H -0.0650 0.7706 0.4192 0.032 Uiso 1 1 calc R . .
H16B H -0.1819 0.6474 0.3107 0.032 Uiso 1 1 calc R . .
H16C H -0.1394 0.7720 0.2960 0.032 Uiso 1 1 calc R . .
C17 C 0.0157(2) 0.45700(18) 0.31213(17) 0.0157(4) Uani 1 1 d . . .
C18 C 0.0625(2) 0.40587(18) 0.22251(17) 0.0157(4) Uani 1 1 d . . .
H18 H 0.1176 0.4559 0.1920 0.019 Uiso 1 1 calc R . .
C19 C 0.0297(2) 0.28491(18) 0.17847(18) 0.0180(4) Uani 1 1 d . . .
H19 H 0.0641 0.2537 0.1190 0.022 Uiso 1 1 calc R . .
C20 C -0.0519(2) 0.20775(19) 0.21871(19) 0.0210(4) Uani 1 1 d . . .
H20 H -0.0727 0.1247 0.1883 0.025 Uiso 1 1 calc R . .
C21 C -0.1026(2) 0.25492(19) 0.30453(19) 0.0217(4) Uani 1 1 d . . .
H21 H -0.1592 0.2035 0.3331 0.026 Uiso 1 1 calc R . .
C22 C -0.0717(2) 0.37604(19) 0.34914(18) 0.0185(4) Uani 1 1 d . . .
H22 H -0.1105 0.4055 0.4063 0.022 Uiso 1 1 calc R . .
C1S C 0.3048(3) 0.1178(2) 0.9003(2) 0.0324(6) Uani 1 1 d . . .
H1S H 0.2372 0.0594 0.8248 0.039 Uiso 1 1 calc R . .
C2S C 0.2676(3) 0.2101(2) 0.9528(2) 0.0313(6) Uani 1 1 d . . .
H2S H 0.1734 0.2142 0.9146 0.038 Uiso 1 1 calc R . .
C3S C 0.3671(3) 0.2959(2) 1.0602(3) 0.0364(6) Uani 1 1 d . . .
H3S H 0.3428 0.3605 1.0964 0.044 Uiso 1 1 calc R . .
C4S C 0.5042(3) 0.2882(3) 1.1165(2) 0.0407(7) Uani 1 1 d . . .
H4S H 0.5743 0.3480 1.1907 0.049 Uiso 1 1 calc R . .
C5S C 0.5372(3) 0.1926(3) 1.0630(2) 0.0374(7) Uani 1 1 d . . .
H5S H 0.6289 0.1855 1.1014 0.045 Uiso 1 1 calc R . .
C6S C 0.4382(3) 0.1095(2) 0.9560(2) 0.0338(6) Uani 1 1 d . . .
H6S H 0.4618 0.0448 0.9192 0.041 Uiso 1 1 calc R . .
C7S C 0.3460(3) 0.4171(2) 0.4546(2) 0.0244(5) Uani 1 1 d . . .
H7S H 0.2405 0.3603 0.4235 0.029 Uiso 1 1 calc R . .
C8S C 0.5536(3) 0.6016(2) 0.5999(2) 0.0267(5) Uani 1 1 d . . .
H8S H 0.5900 0.6714 0.6686 0.032 Uiso 1 1 calc R . .
C9S C 0.3996(3) 0.5187(2) 0.5545(2) 0.0269(5) Uani 1 1 d . . .
H9S H 0.3308 0.5319 0.5922 0.032 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Pt1 C16 96.38(8) . . ?
C1 Pt1 C15 95.38(8) . . ?
C16 Pt1 C15 84.19(9) . . ?
C1 Pt1 N5 174.65(7) . . ?
C16 Pt1 N5 85.76(8) . . ?
C15 Pt1 N5 89.71(8) . . ?
C1 Pt1 N3 85.17(7) . . ?
C16 Pt1 N3 177.25(7) . . ?
C15 Pt1 N3 93.41(8) . . ?
N5 Pt1 N3 92.90(7) . . ?
C1 Pt1 N1 85.49(7) . . ?
C16 Pt1 N1 91.32(8) . . ?
C15 Pt1 N1 175.49(8) . . ?
N5 Pt1 N1 89.56(7) . . ?
N3 Pt1 N1 91.07(6) . . ?
C10 N1 N2 106.00(17) . . ?
C10 N1 Pt1 132.26(15) . . ?
N2 N1 Pt1 121.60(13) . . ?
C8 N2 N1 110.35(19) . . ?
C8 N2 C7 128.65(19) . . ?
N1 N2 C7 121.00(17) . . ?
C14 N3 N4 106.32(16) . . ?
C14 N3 Pt1 132.23(14) . . ?
N4 N3 Pt1 121.32(12) . . ?
C12 N4 N3 110.56(17) . . ?
C12 N4 C11 127.96(18) . . ?
N3 N4 C11 121.44(16) . . ?
C17 N5 Pt1 130.60(14) . . ?
C17 N5 H5N 114.7 . . ?
Pt1 N5 H5N 114.7 . . ?
C2 C1 C6 115.71(18) . . ?
C2 C1 Pt1 121.97(15) . . ?
C6 C1 Pt1 121.71(14) . . ?
C3 C2 C1 121.7(2) . . ?
C3 C2 C7 117.92(18) . . ?
C1 C2 C7 120.23(19) . . ?
C4 C3 C2 120.8(2) . . ?
C4 C3 H3 119.6 . . ?
C2 C3 H3 119.6 . . ?
C3 C4 C5 118.5(2) . . ?
C3 C4 H4 120.7 . . ?
C5 C4 H4 120.7 . . ?
C4 C5 C6 120.6(2) . . ?
C4 C5 H5 119.7 . . ?
C6 C5 H5 119.7 . . ?
C5 C6 C1 121.65(18) . . ?
C5 C6 C11 117.99(18) . . ?
C1 C6 C11 120.29(18) . . ?
N2 C7 C2 112.02(17) . . ?
N2 C7 H7A 109.2 . . ?
C2 C7 H7A 109.2 . . ?
N2 C7 H7B 109.2 . . ?
C2 C7 H7B 109.2 . . ?
H7A C7 H7B 107.9 . . ?
N2 C8 C9 108.0(2) . . ?
N2 C8 H8 126.0 . . ?
C9 C8 H8 126.0 . . ?
C8 C9 C10 105.2(2) . . ?
C8 C9 H9 127.4 . . ?
C10 C9 H9 127.4 . . ?
N1 C10 C9 110.4(2) . . ?
N1 C10 H10 124.8 . . ?
C9 C10 H10 124.8 . . ?
N4 C11 C6 112.38(16) . . ?
N4 C11 H11A 109.1 . . ?
C6 C11 H11A 109.1 . . ?
N4 C11 H11B 109.1 . . ?
C6 C11 H11B 109.1 . . ?
H11A C11 H11B 107.9 . . ?
N4 C12 C13 107.63(19) . . ?
N4 C12 H12 126.2 . . ?
C13 C12 H12 126.2 . . ?
C12 C13 C14 105.43(18) . . ?
C12 C13 H13 127.3 . . ?
C14 C13 H13 127.3 . . ?
N3 C14 C13 110.06(19) . . ?
N3 C14 H14 125.0 . . ?
C13 C14 H14 125.0 . . ?
Pt1 C15 H15A 109.5 . . ?
Pt1 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
Pt1 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
Pt1 C16 H16A 109.5 . . ?
Pt1 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
Pt1 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N5 C17 C22 121.40(19) . . ?
N5 C17 C18 122.60(18) . . ?
C22 C17 C18 115.94(18) . . ?
C19 C18 C17 121.35(19) . . ?
C19 C18 H18 119.3 . . ?
C17 C18 H18 119.3 . . ?
C18 C19 C20 121.7(2) . . ?
C18 C19 H19 119.2 . . ?
C20 C19 H19 119.2 . . ?
C19 C20 C21 118.2(2) . . ?
C19 C20 H20 120.9 . . ?
C21 C20 H20 120.9 . . ?
C22 C21 C20 120.9(2) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C21 C22 C17 121.9(2) . . ?
C21 C22 H22 119.1 . . ?
C17 C22 H22 119.1 . . ?
C6S C1S C2S 120.4(2) . . ?
C6S C1S H1S 119.8 . . ?
C2S C1S H1S 119.8 . . ?
C3S C2S C1S 119.7(2) . . ?
C3S C2S H2S 120.1 . . ?
C1S C2S H2S 120.1 . . ?
C2S C3S C4S 119.8(2) . . ?
C2S C3S H3S 120.1 . . ?
C4S C3S H3S 120.1 . . ?
C5S C4S C3S 119.4(2) . . ?
C5S C4S H4S 120.3 . . ?
C3S C4S H4S 120.3 . . ?
C6S C5S C4S 119.8(2) . . ?
C6S C5S H5S 120.1 . . ?
C4S C5S H5S 120.1 . . ?
C5S C6S C1S 120.8(3) . . ?
C5S C6S H6S 119.6 . . ?
C1S C6S H6S 119.6 . . ?
C8S C7S C9S 119.7(2) 2_666 . ?
C8S C7S H7S 120.2 2_666 . ?
C9S C7S H7S 120.2 . . ?
C7S C8S C9S 120.1(2) 2_666 . ?
C7S C8S H8S 120.0 2_666 . ?
C9S C8S H8S 120.0 . . ?
C7S C9S C8S 120.2(2) . . ?
C7S C9S H9S 119.9 . . ?
C8S C9S H9S 119.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1 2.046(2) . ?
Pt1 C16 2.050(2) . ?
Pt1 C15 2.054(2) . ?
Pt1 N5 2.0869(17) . ?
Pt1 N3 2.1314(17) . ?
Pt1 N1 2.1414(17) . ?
N1 C10 1.335(3) . ?
N1 N2 1.355(2) . ?
N2 C8 1.346(3) . ?
N2 C7 1.462(3) . ?
N3 C14 1.337(3) . ?
N3 N4 1.355(2) . ?
N4 C12 1.343(3) . ?
N4 C11 1.469(3) . ?
N5 C17 1.376(3) . ?
N5 H5N 0.8800 . ?
C1 C2 1.406(3) . ?
C1 C6 1.411(3) . ?
C2 C3 1.387(3) . ?
C2 C7 1.513(3) . ?
C3 C4 1.383(3) . ?
C3 H3 0.9500 . ?
C4 C5 1.387(3) . ?
C4 H4 0.9500 . ?
C5 C6 1.389(3) . ?
C5 H5 0.9500 . ?
C6 C11 1.510(3) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.365(4) . ?
C8 H8 0.9500 . ?
C9 C10 1.392(3) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 C13 1.377(3) . ?
C12 H12 0.9500 . ?
C13 C14 1.391(3) . ?
C13 H13 0.9500 . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C22 1.411(3) . ?
C17 C18 1.415(3) . ?
C18 C19 1.379(3) . ?
C18 H18 0.9500 . ?
C19 C20 1.384(3) . ?
C19 H19 0.9500 . ?
C20 C21 1.386(3) . ?
C20 H20 0.9500 . ?
C21 C22 1.385(3) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C1S C6S 1.368(4) . ?
C1S C2S 1.375(4) . ?
C1S H1S 0.9500 . ?
C2S C3S 1.367(4) . ?
C2S H2S 0.9500 . ?
C3S C4S 1.395(4) . ?
C3S H3S 0.9500 . ?
C4S C5S 1.388(4) . ?
C4S H4S 0.9500 . ?
C5S C6S 1.354(4) . ?
C5S H5S 0.9500 . ?
C6S H6S 0.9500 . ?
C7S C8S 1.378(3) 2_666 ?
C7S C9S 1.381(3) . ?
C7S H7S 0.9500 . ?
C8S C7S 1.378(3) 2_666 ?
C8S C9S 1.387(3) . ?
C8S H8S 0.9500 . ?
C9S H9S 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Pt1 N1 C10 -139.2(2) . . . . ?
C16 Pt1 N1 C10 124.5(2) . . . . ?
C15 Pt1 N1 C10 119.5(9) . . . . ?
N5 Pt1 N1 C10 38.8(2) . . . . ?
N3 Pt1 N1 C10 -54.11(19) . . . . ?
C1 Pt1 N1 N2 35.85(15) . . . . ?
C16 Pt1 N1 N2 -60.45(16) . . . . ?
C15 Pt1 N1 N2 -65.5(10) . . . . ?
N5 Pt1 N1 N2 -146.20(15) . . . . ?
N3 Pt1 N1 N2 120.91(15) . . . . ?
C10 N1 N2 C8 0.2(2) . . . . ?
Pt1 N1 N2 C8 -176.01(14) . . . . ?
C10 N1 N2 C7 -178.99(19) . . . . ?
Pt1 N1 N2 C7 4.8(3) . . . . ?
C1 Pt1 N3 C14 144.50(19) . . . . ?
C16 Pt1 N3 C14 -91.2(16) . . . . ?
C15 Pt1 N3 C14 -120.38(18) . . . . ?
N5 Pt1 N3 C14 -30.49(18) . . . . ?
N1 Pt1 N3 C14 59.12(18) . . . . ?
C1 Pt1 N3 N4 -40.02(14) . . . . ?
C16 Pt1 N3 N4 84.3(16) . . . . ?
C15 Pt1 N3 N4 55.10(15) . . . . ?
N5 Pt1 N3 N4 144.98(14) . . . . ?
N1 Pt1 N3 N4 -125.40(14) . . . . ?
C14 N3 N4 C12 0.1(2) . . . . ?
Pt1 N3 N4 C12 -176.37(13) . . . . ?
C14 N3 N4 C11 177.92(17) . . . . ?
Pt1 N3 N4 C11 1.4(2) . . . . ?
C1 Pt1 N5 C17 -131.1(7) . . . . ?
C16 Pt1 N5 C17 115.12(19) . . . . ?
C15 Pt1 N5 C17 30.92(19) . . . . ?
N3 Pt1 N5 C17 -62.48(18) . . . . ?
N1 Pt1 N5 C17 -153.53(19) . . . . ?
C16 Pt1 C1 C2 51.50(17) . . . . ?
C15 Pt1 C1 C2 136.23(17) . . . . ?
N5 Pt1 C1 C2 -61.8(8) . . . . ?
N3 Pt1 C1 C2 -130.79(17) . . . . ?
N1 Pt1 C1 C2 -39.33(16) . . . . ?
C16 Pt1 C1 C6 -137.83(16) . . . . ?
C15 Pt1 C1 C6 -53.09(16) . . . . ?
N5 Pt1 C1 C6 108.9(7) . . . . ?
N3 Pt1 C1 C6 39.89(15) . . . . ?
N1 Pt1 C1 C6 131.35(16) . . . . ?
C6 C1 C2 C3 9.6(3) . . . . ?
Pt1 C1 C2 C3 -179.22(16) . . . . ?
C6 C1 C2 C7 -166.52(18) . . . . ?
Pt1 C1 C2 C7 4.7(3) . . . . ?
C1 C2 C3 C4 -2.6(3) . . . . ?
C7 C2 C3 C4 173.6(2) . . . . ?
C2 C3 C4 C5 -5.1(3) . . . . ?
C3 C4 C5 C6 5.2(3) . . . . ?
C4 C5 C6 C1 2.2(3) . . . . ?
C4 C5 C6 C11 -174.85(19) . . . . ?
C2 C1 C6 C5 -9.4(3) . . . . ?
Pt1 C1 C6 C5 179.38(15) . . . . ?
C2 C1 C6 C11 167.61(18) . . . . ?
Pt1 C1 C6 C11 -3.6(2) . . . . ?
C8 N2 C7 C2 125.3(2) . . . . ?
N1 N2 C7 C2 -55.8(3) . . . . ?
C3 C2 C7 N2 -125.1(2) . . . . ?
C1 C2 C7 N2 51.1(3) . . . . ?
N1 N2 C8 C9 -0.1(3) . . . . ?
C7 N2 C8 C9 179.0(2) . . . . ?
N2 C8 C9 C10 0.0(3) . . . . ?
N2 N1 C10 C9 -0.2(2) . . . . ?
Pt1 N1 C10 C9 175.41(15) . . . . ?
C8 C9 C10 N1 0.1(3) . . . . ?
C12 N4 C11 C6 -131.1(2) . . . . ?
N3 N4 C11 C6 51.6(2) . . . . ?
C5 C6 C11 N4 126.13(19) . . . . ?
C1 C6 C11 N4 -51.0(2) . . . . ?
N3 N4 C12 C13 -0.2(2) . . . . ?
C11 N4 C12 C13 -177.83(19) . . . . ?
N4 C12 C13 C14 0.2(2) . . . . ?
N4 N3 C14 C13 0.0(2) . . . . ?
Pt1 N3 C14 C13 175.98(14) . . . . ?
C12 C13 C14 N3 -0.2(2) . . . . ?
Pt1 N5 C17 C22 -147.25(16) . . . . ?
Pt1 N5 C17 C18 35.6(3) . . . . ?
N5 C17 C18 C19 174.49(19) . . . . ?
C22 C17 C18 C19 -2.8(3) . . . . ?
C17 C18 C19 C20 0.8(3) . . . . ?
C18 C19 C20 C21 0.8(3) . . . . ?
C19 C20 C21 C22 -0.3(3) . . . . ?
C20 C21 C22 C17 -1.8(3) . . . . ?
N5 C17 C22 C21 -174.03(19) . . . . ?
C18 C17 C22 C21 3.3(3) . . . . ?
C6S C1S C2S C3S 1.7(4) . . . . ?
C1S C2S C3S C4S -0.9(4) . . . . ?
C2S C3S C4S C5S -0.7(4) . . . . ?
C3S C4S C5S C6S 1.6(4) . . . . ?
C4S C5S C6S C1S -0.8(4) . . . . ?
C2S C1S C6S C5S -0.8(4) . . . . ?
C8S C7S C9S C8S 0.0(4) 2_666 . . . ?
C7S C8S C9S C7S 0.0(4) 2_666 . . . ?
