#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:20:41 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179105 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/67/4306713.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4306713
loop_
_publ_author_name
'Bayrammurad Saparov'
'Sheng-qing Xia'
'Svilen Bobev'
_publ_section_title
;
Synthesis, Structure, and Bonding of the Zintl Phase Ba3Cd2Sb4
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11237
_journal_page_last               11244
_journal_paper_doi               10.1021/ic801530d
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         'Ba2.58 Cd2 Eu0.42 Sb4'
_chemical_formula_sum            'Ba2.58 Cd2 Eu0.42 Sb4'
_chemical_formula_weight         1129.96
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.6800(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   17.6492(16)
_cell_length_b                   4.8793(5)
_cell_length_c                   7.5676(7)
_cell_measurement_reflns_used    700
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.37
_cell_measurement_theta_min      2.48
_cell_volume                     605.59(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0201
_diffrn_reflns_av_sigmaI/netI    0.0148
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            3633
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.48
_exptl_absorpt_coefficient_mu    22.525
_exptl_absorpt_correction_T_max  0.6742
_exptl_absorpt_correction_T_min  0.3096
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
SADABS (Sheldrick, 2003) 
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    6.197
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             942
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.682
_refine_diff_density_min         -0.806
_refine_diff_density_rms         0.214
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.126
_refine_ls_matrix_type           full
_refine_ls_number_parameters     30
_refine_ls_number_reflns         700
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.126
_refine_ls_R_factor_all          0.0159
_refine_ls_R_factor_gt           0.0146
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0191P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0348
_refine_ls_wR_factor_ref         0.0354
_reflns_number_gt                675
_reflns_number_total             700
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic801530d_si_002_4.cif
_cod_data_source_block           Ba3Cd2Sb4:Eu
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4306713
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ba1 Ba 0.142244(19) 0.0000 0.59345(5) 0.01079(10) Uani 1 2 d S . .
Ba2 Ba 0.0000 0.0000 0.0000 0.01014(16) Uani 0.579(14) 4 d SP . .
Eu2 Eu 0.0000 0.0000 0.0000 0.01014(16) Uani 0.421(14) 4 d SP . .
Sb1 Sb 0.20639(2) 0.0000 0.19609(5) 0.01061(11) Uani 1 2 d S . .
Sb2 Sb 0.49967(2) 0.0000 0.31282(5) 0.01246(11) Uani 1 2 d S . .
Cd1 Cd 0.33333(2) 0.0000 0.02686(6) 0.01153(11) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ba Ba -0.3244 2.2819 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Sb1 Ba1 Sb1 87.346(13) 7_556 7_546 ?
Sb1 Ba1 Sb1 87.571(11) 7_556 . ?
Sb1 Ba1 Sb1 87.571(11) 7_546 . ?
Sb1 Ba1 Sb2 170.272(14) 7_556 3_445 ?
Sb1 Ba1 Sb2 92.610(9) 7_546 3_445 ?
Sb1 Ba1 Sb2 82.709(11) . 3_445 ?
Sb1 Ba1 Sb2 92.610(9) 7_556 3_455 ?
Sb1 Ba1 Sb2 170.272(14) 7_546 3_455 ?
Sb1 Ba1 Sb2 82.709(11) . 3_455 ?
Sb2 Ba1 Sb2 85.795(13) 3_445 3_455 ?
Sb1 Ba1 Cd1 48.522(9) 7_556 7_556 ?
Sb1 Ba1 Cd1 104.799(12) 7_546 7_556 ?
Sb1 Ba1 Cd1 132.426(9) . 7_556 ?
Sb2 Ba1 Cd1 140.337(13) 3_445 7_556 ?
Sb2 Ba1 Cd1 82.251(10) 3_455 7_556 ?
Sb1 Ba1 Cd1 104.799(12) 7_556 7_546 ?
Sb1 Ba1 Cd1 48.522(9) 7_546 7_546 ?
Sb1 Ba1 Cd1 132.426(9) . 7_546 ?
Sb2 Ba1 Cd1 82.251(10) 3_445 7_546 ?
Sb2 Ba1 Cd1 140.337(13) 3_455 7_546 ?
Cd1 Ba1 Cd1 83.290(13) 7_556 7_546 ?
Sb1 Ba1 Cd1 46.940(7) 7_556 1_556 ?
Sb1 Ba1 Cd1 46.940(7) 7_546 1_556 ?
Sb1 Ba1 Cd1 105.912(14) . 1_556 ?
Sb2 Ba1 Cd1 136.773(7) 3_445 1_556 ?
Sb2 Ba1 Cd1 136.773(7) 3_455 1_556 ?
Cd1 Ba1 Cd1 60.396(10) 7_556 1_556 ?
Cd1 Ba1 Cd1 60.396(10) 7_546 1_556 ?
Sb1 Ba1 Sb2 144.217(14) 7_556 7_546 ?
Sb1 Ba1 Sb2 84.954(10) 7_546 7_546 ?
Sb1 Ba1 Sb2 126.824(9) . 7_546 ?
Sb2 Ba1 Sb2 45.324(13) 3_445 7_546 ?
Sb2 Ba1 Sb2 100.560(11) 3_455 7_546 ?
Cd1 Ba1 Sb2 100.251(12) 7_556 7_546 ?
Cd1 Ba1 Sb2 46.578(9) 7_546 7_546 ?
Cd1 Ba1 Sb2 106.470(12) 1_556 7_546 ?
Sb1 Ba1 Sb2 84.954(10) 7_556 7_556 ?
Sb1 Ba1 Sb2 144.217(14) 7_546 7_556 ?
Sb1 Ba1 Sb2 126.824(9) . 7_556 ?
Sb2 Ba1 Sb2 100.560(11) 3_445 7_556 ?
Sb2 Ba1 Sb2 45.324(13) 3_455 7_556 ?
Cd1 Ba1 Sb2 46.578(9) 7_556 7_556 ?
Cd1 Ba1 Sb2 100.251(12) 7_546 7_556 ?
Cd1 Ba1 Sb2 106.470(12) 1_556 7_556 ?
Sb2 Ba1 Sb2 81.247(12) 7_546 7_556 ?
Sb1 Ba1 Ba2 121.894(9) 7_556 . ?
Sb1 Ba1 Ba2 121.894(9) 7_546 . ?
Sb1 Ba1 Ba2 50.284(9) . . ?
Sb2 Ba1 Ba2 50.499(7) 3_445 . ?
Sb2 Ba1 Ba2 50.499(7) 3_455 . ?
Cd1 Ba1 Ba2 132.710(8) 7_556 . ?
Cd1 Ba1 Ba2 132.710(8) 7_546 . ?
Cd1 Ba1 Ba2 156.196(12) 1_556 . ?
Sb2 Ba1 Ba2 91.419(9) 7_546 . ?
Sb2 Ba1 Ba2 91.419(10) 7_556 . ?
Sb1 Ba2 Sb1 180.0 . 5 ?
Sb1 Ba2 Sb2 91.536(8) . 7_545 ?
Sb1 Ba2 Sb2 88.464(8) 5 7_545 ?
Sb1 Ba2 Sb2 88.464(8) . 3_455 ?
Sb1 Ba2 Sb2 91.536(8) 5 3_455 ?
Sb2 Ba2 Sb2 180.000(13) 7_545 3_455 ?
Sb1 Ba2 Sb2 91.536(8) . 7 ?
Sb1 Ba2 Sb2 88.464(8) 5 7 ?
Sb2 Ba2 Sb2 91.671(12) 7_545 7 ?
Sb2 Ba2 Sb2 88.329(12) 3_455 7 ?
Sb1 Ba2 Sb2 88.464(8) . 3_445 ?
Sb1 Ba2 Sb2 91.536(8) 5 3_445 ?
Sb2 Ba2 Sb2 88.329(12) 7_545 3_445 ?
Sb2 Ba2 Sb2 91.671(12) 3_455 3_445 ?
Sb2 Ba2 Sb2 180.000(19) 7 3_445 ?
Sb1 Ba2 Cd1 46.402(7) . 7 ?
Sb1 Ba2 Cd1 133.598(7) 5 7 ?
Sb2 Ba2 Cd1 102.593(9) 7_545 7 ?
Sb2 Ba2 Cd1 77.407(9) 3_455 7 ?
Sb2 Ba2 Cd1 46.917(9) 7 7 ?
Sb2 Ba2 Cd1 133.083(8) 3_445 7 ?
Sb1 Ba2 Cd1 133.598(7) . 3_445 ?
Sb1 Ba2 Cd1 46.402(7) 5 3_445 ?
Sb2 Ba2 Cd1 77.407(9) 7_545 3_445 ?
Sb2 Ba2 Cd1 102.593(9) 3_455 3_445 ?
Sb2 Ba2 Cd1 133.083(8) 7 3_445 ?
Sb2 Ba2 Cd1 46.917(9) 3_445 3_445 ?
Cd1 Ba2 Cd1 180.0 7 3_445 ?
Sb1 Ba2 Cd1 46.402(7) . 7_545 ?
Sb1 Ba2 Cd1 133.598(7) 5 7_545 ?
Sb2 Ba2 Cd1 46.917(9) 7_545 7_545 ?
Sb2 Ba2 Cd1 133.083(9) 3_455 7_545 ?
Sb2 Ba2 Cd1 102.593(9) 7 7_545 ?
Sb2 Ba2 Cd1 77.407(9) 3_445 7_545 ?
Cd1 Ba2 Cd1 77.816(11) 7 7_545 ?
Cd1 Ba2 Cd1 102.184(11) 3_445 7_545 ?
Sb1 Ba2 Cd1 133.598(7) . 3_455 ?
Sb1 Ba2 Cd1 46.402(7) 5 3_455 ?
Sb2 Ba2 Cd1 133.083(9) 7_545 3_455 ?
Sb2 Ba2 Cd1 46.917(9) 3_455 3_455 ?
Sb2 Ba2 Cd1 77.407(9) 7 3_455 ?
Sb2 Ba2 Cd1 102.593(9) 3_445 3_455 ?
Cd1 Ba2 Cd1 102.184(11) 7 3_455 ?
Cd1 Ba2 Cd1 77.816(11) 3_445 3_455 ?
Cd1 Ba2 Cd1 180.000(8) 7_545 3_455 ?
Sb1 Ba2 Ba1 125.550(8) . 5 ?
Sb1 Ba2 Ba1 54.451(8) 5 5 ?
Sb2 Ba2 Ba1 54.407(7) 7_545 5 ?
Sb2 Ba2 Ba1 125.593(7) 3_455 5 ?
Sb2 Ba2 Ba1 54.407(7) 7 5 ?
Sb2 Ba2 Ba1 125.593(7) 3_445 5 ?
Cd1 Ba2 Ba1 96.177(8) 7 5 ?
Cd1 Ba2 Ba1 83.823(8) 3_445 5 ?
Cd1 Ba2 Ba1 96.177(8) 7_545 5 ?
Cd1 Ba2 Ba1 83.823(8) 3_455 5 ?
Sb1 Ba2 Ba1 54.450(8) . . ?
Sb1 Ba2 Ba1 125.549(8) 5 . ?
Sb2 Ba2 Ba1 125.593(7) 7_545 . ?
Sb2 Ba2 Ba1 54.407(7) 3_455 . ?
Sb2 Ba2 Ba1 125.593(7) 7 . ?
Sb2 Ba2 Ba1 54.407(7) 3_445 . ?
Cd1 Ba2 Ba1 83.823(8) 7 . ?
Cd1 Ba2 Ba1 96.177(8) 3_445 . ?
Cd1 Ba2 Ba1 83.823(8) 7_545 . ?
Cd1 Ba2 Ba1 96.177(8) 3_455 . ?
Ba1 Ba2 Ba1 180.0 5 . ?
Cd1 Sb1 Cd1 114.48(2) 7_545 7 ?
Cd1 Sb1 Cd1 78.899(12) 7_545 . ?
Cd1 Sb1 Cd1 78.899(12) 7 . ?
Cd1 Sb1 Ba2 75.852(10) 7_545 . ?
Cd1 Sb1 Ba2 75.852(10) 7 . ?
Cd1 Sb1 Ba2 132.301(15) . . ?
Cd1 Sb1 Ba1 145.376(15) 7_545 7_556 ?
Cd1 Sb1 Ba1 70.214(11) 7 7_556 ?
Cd1 Sb1 Ba1 68.178(11) . 7_556 ?
Ba2 Sb1 Ba1 135.161(7) . 7_556 ?
Cd1 Sb1 Ba1 70.214(11) 7_545 7_546 ?
Cd1 Sb1 Ba1 145.376(15) 7 7_546 ?
Cd1 Sb1 Ba1 68.178(11) . 7_546 ?
Ba2 Sb1 Ba1 135.161(7) . 7_546 ?
Ba1 Sb1 Ba1 87.345(13) 7_556 7_546 ?
Cd1 Sb1 Ba1 113.872(11) 7_545 . ?
Cd1 Sb1 Ba1 113.872(11) 7 . ?
Cd1 Sb1 Ba1 152.434(16) . . ?
Ba2 Sb1 Ba1 75.265(10) . . ?
Ba1 Sb1 Ba1 92.429(11) 7_556 . ?
Ba1 Sb1 Ba1 92.430(11) 7_546 . ?
Sb2 Sb2 Cd1 111.81(2) 5_656 . ?
Sb2 Sb2 Eu2 134.163(6) 5_656 3_545 ?
Cd1 Sb2 Eu2 75.234(10) . 3_545 ?
Sb2 Sb2 Ba2 134.163(6) 5_656 3_545 ?
Cd1 Sb2 Ba2 75.234(10) . 3_545 ?
Eu2 Sb2 Ba2 0.0 3_545 3_545 ?
Sb2 Sb2 Eu2 134.163(6) 5_656 3 ?
Cd1 Sb2 Eu2 75.234(10) . 3 ?
Eu2 Sb2 Eu2 91.672(13) 3_545 3 ?
Ba2 Sb2 Eu2 91.672(13) 3_545 3 ?
Sb2 Sb2 Ba2 134.163(6) 5_656 3 ?
Cd1 Sb2 Ba2 75.234(10) . 3 ?
Eu2 Sb2 Ba2 91.672(13) 3_545 3 ?
Ba2 Sb2 Ba2 91.672(13) 3_545 3 ?
Eu2 Sb2 Ba2 0.0 3 3 ?
Sb2 Sb2 Ba1 70.385(12) 5_656 3 ?
Cd1 Sb2 Ba1 136.823(7) . 3 ?
Eu2 Sb2 Ba1 136.001(13) 3_545 3 ?
Ba2 Sb2 Ba1 136.001(13) 3_545 3 ?
Eu2 Sb2 Ba1 75.094(9) 3 3 ?
Ba2 Sb2 Ba1 75.094(9) 3 3 ?
Sb2 Sb2 Ba1 70.385(12) 5_656 3_545 ?
Cd1 Sb2 Ba1 136.823(7) . 3_545 ?
Eu2 Sb2 Ba1 75.094(8) 3_545 3_545 ?
Ba2 Sb2 Ba1 75.094(8) 3_545 3_545 ?
Eu2 Sb2 Ba1 136.001(13) 3 3_545 ?
Ba2 Sb2 Ba1 136.001(13) 3 3_545 ?
Ba1 Sb2 Ba1 85.795(13) 3 3_545 ?
Sb2 Sb2 Ba1 64.290(11) 5_656 7_546 ?
Cd1 Sb2 Ba1 65.353(11) . 7_546 ?
Eu2 Sb2 Ba1 80.670(8) 3_545 7_546 ?
Ba2 Sb2 Ba1 80.670(8) 3_545 7_546 ?
Eu2 Sb2 Ba1 140.532(12) 3 7_546 ?
Ba2 Sb2 Ba1 140.532(12) 3 7_546 ?
Ba1 Sb2 Ba1 134.676(12) 3 7_546 ?
Ba1 Sb2 Ba1 79.439(11) 3_545 7_546 ?
Sb2 Sb2 Ba1 64.290(11) 5_656 7_556 ?
Cd1 Sb2 Ba1 65.353(11) . 7_556 ?
Eu2 Sb2 Ba1 140.532(12) 3_545 7_556 ?
Ba2 Sb2 Ba1 140.532(12) 3_545 7_556 ?
Eu2 Sb2 Ba1 80.670(8) 3 7_556 ?
Ba2 Sb2 Ba1 80.670(8) 3 7_556 ?
Ba1 Sb2 Ba1 79.439(11) 3 7_556 ?
Ba1 Sb2 Ba1 134.676(12) 3_545 7_556 ?
Ba1 Sb2 Ba1 81.246(12) 7_546 7_556 ?
Sb1 Cd1 Sb1 114.48(2) 7_545 7 ?
Sb1 Cd1 Sb2 112.952(11) 7_545 . ?
Sb1 Cd1 Sb2 112.952(11) 7 . ?
Sb1 Cd1 Sb1 101.098(12) 7_545 . ?
Sb1 Cd1 Sb1 101.098(12) 7 . ?
Sb2 Cd1 Sb1 113.050(19) . . ?
Sb1 Cd1 Ba1 161.311(15) 7_545 7_556 ?
Sb1 Cd1 Ba1 80.190(11) 7 7_556 ?
Sb2 Cd1 Ba1 68.069(10) . 7_556 ?
Sb1 Cd1 Ba1 63.298(10) . 7_556 ?
Sb1 Cd1 Ba1 80.190(11) 7_545 7_546 ?
Sb1 Cd1 Ba1 161.311(15) 7 7_546 ?
Sb2 Cd1 Ba1 68.069(10) . 7_546 ?
Sb1 Cd1 Ba1 63.298(10) . 7_546 ?
Ba1 Cd1 Ba1 83.290(14) 7_556 7_546 ?
Sb1 Cd1 Ba1 62.846(10) 7_545 1_554 ?
Sb1 Cd1 Ba1 62.846(10) 7 1_554 ?
Sb2 Cd1 Ba1 168.606(17) . 1_554 ?
Sb1 Cd1 Ba1 78.344(15) . 1_554 ?
Ba1 Cd1 Ba1 119.603(10) 7_556 1_554 ?
Ba1 Cd1 Ba1 119.603(10) 7_546 1_554 ?
Sb1 Cd1 Ba2 121.516(15) 7_545 3 ?
Sb1 Cd1 Ba2 57.748(9) 7 3 ?
Sb2 Cd1 Ba2 57.849(9) . 3 ?
Sb1 Cd1 Ba2 136.951(8) . 3 ?
Ba1 Cd1 Ba2 75.602(7) 7_556 3 ?
Ba1 Cd1 Ba2 125.880(12) 7_546 3 ?
Ba1 Cd1 Ba2 114.174(11) 1_554 3 ?
Sb1 Cd1 Eu2 121.516(15) 7_545 3 ?
Sb1 Cd1 Eu2 57.748(9) 7 3 ?
Sb2 Cd1 Eu2 57.849(9) . 3 ?
Sb1 Cd1 Eu2 136.951(8) . 3 ?
Ba1 Cd1 Eu2 75.602(7) 7_556 3 ?
Ba1 Cd1 Eu2 125.880(12) 7_546 3 ?
Ba1 Cd1 Eu2 114.174(11) 1_554 3 ?
Ba2 Cd1 Eu2 0.0 3 3 ?
Sb1 Cd1 Eu2 57.748(9) 7_545 3_545 ?
Sb1 Cd1 Eu2 121.516(15) 7 3_545 ?
Sb2 Cd1 Eu2 57.849(9) . 3_545 ?
Sb1 Cd1 Eu2 136.951(8) . 3_545 ?
Ba1 Cd1 Eu2 125.880(12) 7_556 3_545 ?
Ba1 Cd1 Eu2 75.602(7) 7_546 3_545 ?
Ba1 Cd1 Eu2 114.174(11) 1_554 3_545 ?
Ba2 Cd1 Eu2 77.817(11) 3 3_545 ?
Eu2 Cd1 Eu2 77.817(11) 3 3_545 ?
Sb1 Cd1 Ba2 57.748(9) 7_545 3_545 ?
Sb1 Cd1 Ba2 121.516(15) 7 3_545 ?
Sb2 Cd1 Ba2 57.849(9) . 3_545 ?
Sb1 Cd1 Ba2 136.951(8) . 3_545 ?
Ba1 Cd1 Ba2 125.880(12) 7_556 3_545 ?
Ba1 Cd1 Ba2 75.602(7) 7_546 3_545 ?
Ba1 Cd1 Ba2 114.174(11) 1_554 3_545 ?
Ba2 Cd1 Ba2 77.817(11) 3 3_545 ?
Eu2 Cd1 Ba2 77.817(11) 3 3_545 ?
Eu2 Cd1 Ba2 0.0 3_545 3_545 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ba1 Sb1 3.5330(4) 7_556 ?
Ba1 Sb1 3.5330(4) 7_546 ?
Ba1 Sb1 3.5832(6) . ?
Ba1 Sb2 3.5841(4) 3_445 ?
Ba1 Sb2 3.5841(4) 3_455 ?
Ba1 Cd1 3.6713(5) 7_556 ?
Ba1 Cd1 3.6713(5) 7_546 ?
Ba1 Cd1 3.7361(6) 1_556 ?
Ba1 Sb2 3.7471(4) 7_546 ?
Ba1 Sb2 3.7471(4) 7_556 ?
Ba1 Ba2 4.2593(5) . ?
Ba2 Sb1 3.3877(5) . ?
Ba2 Sb1 3.3878(5) 5 ?
Ba2 Sb2 3.4009(4) 7_545 ?
Ba2 Sb2 3.4009(4) 3_455 ?
Ba2 Sb2 3.4009(4) 7 ?
Ba2 Sb2 3.4009(4) 3_445 ?
Ba2 Cd1 3.8844(4) 7 ?
Ba2 Cd1 3.8844(4) 3_445 ?
Ba2 Cd1 3.8844(4) 7_545 ?
Ba2 Cd1 3.8844(4) 3_455 ?
Ba2 Ba1 4.2592(5) 5 ?
Sb1 Cd1 2.9010(4) 7_545 ?
Sb1 Cd1 2.9010(4) 7 ?
Sb1 Cd1 2.9630(6) . ?
Sb1 Ba1 3.5330(4) 7_556 ?
Sb1 Ba1 3.5330(4) 7_546 ?
Sb2 Sb2 2.8287(8) 5_656 ?
Sb2 Cd1 2.9338(6) . ?
Sb2 Eu2 3.4009(4) 3_545 ?
Sb2 Ba2 3.4009(4) 3_545 ?
Sb2 Eu2 3.4009(4) 3 ?
Sb2 Ba2 3.4009(4) 3 ?
Sb2 Ba1 3.5841(4) 3 ?
Sb2 Ba1 3.5841(4) 3_545 ?
Sb2 Ba1 3.7471(4) 7_546 ?
Sb2 Ba1 3.7471(4) 7_556 ?
Cd1 Sb1 2.9010(4) 7_545 ?
Cd1 Sb1 2.9010(4) 7 ?
Cd1 Ba1 3.6714(5) 7_556 ?
Cd1 Ba1 3.6714(5) 7_546 ?
Cd1 Ba1 3.7362(6) 1_554 ?
Cd1 Ba2 3.8843(4) 3 ?
Cd1 Eu2 3.8843(4) 3 ?
Cd1 Eu2 3.8843(4) 3_545 ?
Cd1 Ba2 3.8843(4) 3_545 ?
