#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:21:43 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179106 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/68/4306807.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4306807
loop_
_publ_author_name
'Cristina Tejel'
'Miguel A. Ciriano'
'Sonia Jiménez'
'Vincenzo Passarelli'
'José A. López'
_publ_contact_author
;
  Dr. José A. López
  Departamento de Química Inorgánica - I.C.M.A.
  Facultad de Ciencias
  Universidad de Zaragoza
  50009 Zaragoza, Spain
;
_publ_contact_author_email       lopez@unizar.es
_publ_section_title
;
Formation of a Bridging-Imido d6 Rhodium Compound by Nitrene Capture.
Insertion and Cycloaddition Reactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              10220
_journal_page_last               10222
_journal_paper_doi               10.1021/ic801703d
_journal_volume                  47
_journal_year                    2008
_chemical_formula_moiety         'C26 H29 N2 O6 Rh S2'
_chemical_formula_sum            'C26 H29 N2 O6 Rh S2'
_chemical_formula_weight         632.54
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.359(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   7.8460(8)
_cell_length_b                   21.966(2)
_cell_length_c                   8.2972(9)
_cell_measurement_reflns_used    3112
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.21
_cell_measurement_theta_min      2.69
_cell_volume                     1302.7(2)
_computing_cell_refinement       'SAINT+ v. 6.45 (Bruker AXS, 2003)'
_computing_data_collection       'SMART v. 5.611 (Bruker AXS, 2000)'
_computing_data_reduction        'SAINT+ v. 6.45 (Bruker AXS, 2003)'
_computing_molecular_graphics
;
ORTEP3 for Windows - L. J. Farrugia, 
J. Appl. Crystallogr. 1997, 30, 565.
;
_computing_structure_refinement
;
SHELX97 - Programs for Crystal Structure Analysis (Release 97-2). 
G. M. Sheldrick, Institut fur Anorganische Chemie der Universitat, 
Tammanstrasse 4, D-3400 Gottingen, Germany, 1998.
;
_computing_structure_solution
;
SHELX97 - Programs for Crystal Structure Analysis (Release 97-2). 
G. M. Sheldrick, Institut fur Anorganische Chemie der Universitat, 
Tammanstrasse 4, D-3400 Gottingen, Germany, 1998.
;
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART APEX CCD system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_sigmaI/netI    0.0361
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            11758
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         1.85
_diffrn_source                   'normal-focus sealed tube'
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    0.861
_exptl_absorpt_correction_T_max  0.9664
_exptl_absorpt_correction_T_min  0.7880
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
  SADABS: Area-Detector Absorption Correction.  v. 2.10 Bruker-AXS 
;
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.613
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       neddle
_exptl_crystal_F_000             648
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.862
_refine_diff_density_min         -0.382
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.155
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     181
_refine_ls_number_reflns         2912
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.155
_refine_ls_R_factor_all          0.0436
_refine_ls_R_factor_gt           0.0388
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0471P)²+0.8632P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0931
_refine_ls_wR_factor_ref         0.0954
_reflns_number_gt                2673
_reflns_number_total             2912
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic801703d_si_003_5.cif
_cod_data_source_block           cta150as
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               4306807
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh Rh 0.31029(4) 0.2500 0.45850(4) 0.01208(11) Uani 1 2 d S . .
S S 0.05587(11) 0.13495(3) 0.19766(9) 0.01637(17) Uani 1 1 d . . .
O1 O -0.1437(3) 0.14260(10) 0.1204(3) 0.0220(5) Uani 1 1 d . . .
O2 O 0.1403(3) 0.10460(10) 0.3659(3) 0.0237(5) Uani 1 1 d . . .
O3 O -0.0394(4) 0.2500 -0.0367(4) 0.0197(7) Uani 1 2 d S . .
O4 O 0.0113(5) 0.2500 0.6022(4) 0.0321(8) Uani 1 2 d S . .
N N 0.1615(4) 0.20037(11) 0.2240(3) 0.0164(5) Uani 1 1 d . . .
C1 C 0.1190(4) 0.09420(13) 0.0464(4) 0.0151(6) Uani 1 1 d . . .
C2 C 0.0690(4) 0.11648(14) -0.1242(4) 0.0183(6) Uani 1 1 d . . .
H2 H 0.0051 0.1542 -0.1588 0.022 Uiso 1 1 calc R . .
C3 C 0.1135(4) 0.08293(14) -0.2427(4) 0.0189(6) Uani 1 1 d . . .
H3 H 0.0798 0.0980 -0.3592 0.023 Uiso 1 1 calc R . .
C4 C 0.2072(4) 0.02729(14) -0.1943(4) 0.0171(6) Uani 1 1 d . . .
C5 C 0.2565(4) 0.00656(14) -0.0231(4) 0.0198(6) Uani 1 1 d . . .
H5 H 0.3217 -0.0310 0.0123 0.024 Uiso 1 1 calc R . .
C6 C 0.2130(4) 0.03931(14) 0.0980(4) 0.0178(6) Uani 1 1 d . . .
H6 H 0.2472 0.0243 0.2146 0.021 Uiso 1 1 calc R . .
C7 C 0.2519(5) -0.00999(14) -0.3256(4) 0.0215(7) Uani 1 1 d . . .
H7A H 0.2253 0.0141 -0.4327 0.032 Uiso 1 1 calc R . .
H7B H 0.1749 -0.0469 -0.3564 0.032 Uiso 1 1 calc R . .
H7C H 0.3845 -0.0213 -0.2728 0.032 Uiso 1 1 calc R . .
C8 C 0.0755(6) 0.2500 0.1155(5) 0.0167(8) Uani 1 2 d S . .
C9 C 0.1138(6) 0.2500 0.5396(5) 0.0190(9) Uani 1 2 d S . .
C10 C 0.5255(6) 0.2500 0.7294(5) 0.0239(10) Uani 1 2 d S . .
C11 C 0.5454(4) 0.19717(15) 0.6390(4) 0.0214(7) Uani 1 1 d . . .
C12 C 0.5904(4) 0.21776(14) 0.4955(4) 0.0189(6) Uani 1 1 d . . .
C13 C 0.4972(8) 0.2500 0.8982(6) 0.0417(15) Uani 1 2 d S . .
H13A H 0.4270 0.2136 0.9024 0.062 Uiso 1 1 d R . .
H13B H 0.6190 0.2500 0.9996 0.062 Uiso 1 2 d SR . .
C14 C 0.5440(5) 0.13213(17) 0.6916(5) 0.0376(10) Uani 1 1 d . . .
H14A H 0.6717 0.1194 0.7679 0.056 Uiso 1 1 calc R . .
H14B H 0.4951 0.1065 0.5854 0.056 Uiso 1 1 calc R . .
H14C H 0.4643 0.1279 0.7559 0.056 Uiso 1 1 calc R . .
C15 C 0.6284(5) 0.17634(17) 0.3713(5) 0.0318(8) Uani 1 1 d . . .
H15A H 0.6363 0.2003 0.2749 0.048 Uiso 1 1 calc R . .
H15B H 0.5269 0.1466 0.3222 0.048 Uiso 1 1 calc R . .
H15C H 0.7471 0.1550 0.4352 0.048 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C9 Rh N 95.98(13) . . ?
C9 Rh N 95.98(13) . 4_565 ?
N Rh N 62.14(13) . 4_565 ?
C9 Rh C11 109.58(13) . 4_565 ?
N Rh C11 154.23(11) . 4_565 ?
N Rh C11 110.42(11) 4_565 4_565 ?
C9 Rh C11 109.58(13) . . ?
N Rh C11 110.42(11) . . ?
N Rh C11 154.23(11) 4_565 . ?
C11 Rh C11 64.62(17) 4_565 . ?
C9 Rh C10 91.78(17) . . ?
N Rh C10 147.83(7) . . ?
N Rh C10 147.83(7) 4_565 . ?
C11 Rh C10 38.19(10) 4_565 . ?
C11 Rh C10 38.19(10) . . ?
C9 Rh C12 148.11(13) . 4_565 ?
N Rh C12 115.72(11) . 4_565 ?
N Rh C12 95.89(10) 4_565 4_565 ?
C11 Rh C12 38.58(11) 4_565 4_565 ?
C11 Rh C12 63.98(11) . 4_565 ?
C10 Rh C12 63.52(13) . 4_565 ?
C9 Rh C12 148.11(13) . . ?
N Rh C12 95.89(10) . . ?
N Rh C12 115.72(11) 4_565 . ?
C11 Rh C12 63.98(11) 4_565 . ?
C11 Rh C12 38.58(11) . . ?
C10 Rh C12 63.52(13) . . ?
C12 Rh C12 37.44(16) 4_565 . ?
O1 S O2 117.95(14) . . ?
O1 S N 110.96(13) . . ?
O2 S N 105.87(13) . . ?
O1 S C1 108.34(13) . . ?
O2 S C1 107.58(14) . . ?
N S C1 105.41(13) . . ?
C8 N S 121.2(2) . . ?
C8 N Rh 97.31(19) . . ?
S N Rh 129.53(14) . . ?
C6 C1 C2 120.7(3) . . ?
C6 C1 S 119.3(2) . . ?
C2 C1 S 119.9(2) . . ?
C3 C2 C1 119.2(3) . . ?
C2 C3 C4 121.2(3) . . ?
C5 C4 C3 118.3(3) . . ?
C5 C4 C7 120.7(3) . . ?
C3 C4 C7 121.1(3) . . ?
C4 C5 C6 121.6(3) . . ?
C1 C6 C5 119.1(3) . . ?
O3 C8 N 128.71(17) . 4_565 ?
O3 C8 N 128.71(17) . . ?
N C8 N 102.5(3) 4_565 . ?
O4 C9 Rh 173.7(4) . . ?
C11 C10 C11 109.0(4) . 4_565 ?
C11 C10 C13 125.46(19) . . ?
C11 C10 C13 125.46(19) 4_565 . ?
C11 C10 Rh 70.4(2) . . ?
C11 C10 Rh 70.4(2) 4_565 . ?
C13 C10 Rh 127.5(3) . . ?
C10 C11 C12 107.2(3) . . ?
C10 C11 C14 127.5(3) . . ?
C12 C11 C14 124.9(3) . . ?
C10 C11 Rh 71.4(2) . . ?
C12 C11 Rh 72.05(17) . . ?
C14 C11 Rh 127.3(2) . . ?
C12 C12 C11 108.22(18) 4_565 . ?
C12 C12 C15 127.52(19) 4_565 . ?
C11 C12 C15 124.3(3) . . ?
C12 C12 Rh 71.28(8) 4_565 . ?
C11 C12 Rh 69.37(17) . . ?
C15 C12 Rh 124.8(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh C9 1.920(5) . ?
Rh N 2.113(2) . ?
Rh N 2.113(2) 4_565 ?
Rh C11 2.171(3) 4_565 ?
Rh C11 2.171(3) . ?
Rh C10 2.185(4) . ?
Rh C12 2.207(3) 4_565 ?
Rh C12 2.207(3) . ?
S O1 1.436(2) . ?
S O2 1.438(2) . ?
S N 1.628(3) . ?
S C1 1.770(3) . ?
O3 C8 1.212(5) . ?
O4 C9 1.123(5) . ?
N C8 1.398(4) . ?
C1 C6 1.386(4) . ?
C1 C2 1.392(4) . ?
C2 C3 1.384(4) . ?
C3 C4 1.397(4) . ?
C4 C5 1.386(4) . ?
C4 C7 1.515(4) . ?
C5 C6 1.388(4) . ?
C8 N 1.398(4) 4_565 ?
C10 C11 1.425(4) . ?
C10 C11 1.425(4) 4_565 ?
C10 C13 1.506(6) . ?
C11 C12 1.447(4) . ?
C11 C14 1.495(5) . ?
C12 C12 1.416(6) 4_565 ?
C12 C15 1.494(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 S N C8 -26.9(3) . . . . ?
O2 S N C8 -156.0(3) . . . . ?
C1 S N C8 90.1(3) . . . . ?
O1 S N Rh 106.93(18) . . . . ?
O2 S N Rh -22.2(2) . . . . ?
C1 S N Rh -136.00(18) . . . . ?
C9 Rh N C8 88.2(2) . . . . ?
N Rh N C8 -5.5(2) 4_565 . . . ?
C11 Rh N C8 -84.7(3) 4_565 . . . ?
C11 Rh N C8 -158.3(2) . . . . ?
C10 Rh N C8 -168.8(3) . . . . ?
C12 Rh N C8 -88.2(2) 4_565 . . . ?
C12 Rh N C8 -121.5(2) . . . . ?
C9 Rh N S -53.40(19) . . . . ?
N Rh N S -147.02(14) 4_565 . . . ?
C11 Rh N S 133.8(2) 4_565 . . . ?
C11 Rh N S 60.1(2) . . . . ?
C10 Rh N S 49.6(3) . . . . ?
C12 Rh N S 130.20(18) 4_565 . . . ?
C12 Rh N S 96.95(19) . . . . ?
O1 S C1 C6 -121.2(2) . . . . ?
O2 S C1 C6 7.3(3) . . . . ?
N S C1 C6 119.9(2) . . . . ?
O1 S C1 C2 56.8(3) . . . . ?
O2 S C1 C2 -174.6(2) . . . . ?
N S C1 C2 -62.0(3) . . . . ?
C6 C1 C2 C3 0.3(5) . . . . ?
S C1 C2 C3 -177.7(2) . . . . ?
C1 C2 C3 C4 0.1(5) . . . . ?
C2 C3 C4 C5 -0.6(5) . . . . ?
C2 C3 C4 C7 178.6(3) . . . . ?
C3 C4 C5 C6 0.8(5) . . . . ?
C7 C4 C5 C6 -178.5(3) . . . . ?
C2 C1 C6 C5 -0.2(5) . . . . ?
S C1 C6 C5 177.8(2) . . . . ?
C4 C5 C6 C1 -0.4(5) . . . . ?
S N C8 O3 -29.1(6) . . . . ?
Rh N C8 O3 -175.0(4) . . . . ?
S N C8 N 153.38(15) . . . 4_565 ?
Rh N C8 N 7.5(3) . . . 4_565 ?
N Rh C9 O4 148.74(7) . . . . ?
N Rh C9 O4 -148.74(7) 4_565 . . . ?
C11 Rh C9 O4 -34.56(10) 4_565 . . . ?
C11 Rh C9 O4 34.56(10) . . . . ?
C10 Rh C9 O4 0.000(10) . . . . ?
C12 Rh C9 O4 -37.40(19) 4_565 . . . ?
C12 Rh C9 O4 37.40(19) . . . . ?
C9 Rh C10 C11 120.18(19) . . . . ?
N Rh C10 C11 16.0(4) . . . . ?
N Rh C10 C11 -135.6(2) 4_565 . . . ?
C11 Rh C10 C11 -119.6(4) 4_565 . . . ?
C12 Rh C10 C11 -80.8(2) 4_565 . . . ?
C12 Rh C10 C11 -38.81(19) . . . . ?
C9 Rh C10 C11 -120.18(19) . . . 4_565 ?
N Rh C10 C11 135.6(2) . . . 4_565 ?
N Rh C10 C11 -16.0(4) 4_565 . . 4_565 ?
C11 Rh C10 C11 119.6(4) . . . 4_565 ?
C12 Rh C10 C11 38.81(19) 4_565 . . 4_565 ?
C12 Rh C10 C11 80.8(2) . . . 4_565 ?
C9 Rh C10 C13 0.000(1) . . . . ?
N Rh C10 C13 -104.2(2) . . . . ?
N Rh C10 C13 104.2(2) 4_565 . . . ?
C11 Rh C10 C13 120.18(19) 4_565 . . . ?
C11 Rh C10 C13 -120.18(19) . . . . ?
C12 Rh C10 C13 158.99(9) 4_565 . . . ?
C12 Rh C10 C13 -158.99(9) . . . . ?
C11 C10 C11 C12 3.6(5) 4_565 . . . ?
C13 C10 C11 C12 -173.7(4) . . . . ?
Rh C10 C11 C12 63.6(2) . . . . ?
C11 C10 C11 C14 176.8(2) 4_565 . . . ?
C13 C10 C11 C14 -0.5(7) . . . . ?
Rh C10 C11 C14 -123.2(3) . . . . ?
C11 C10 C11 Rh -60.0(3) 4_565 . . . ?
C13 C10 C11 Rh 122.6(4) . . . . ?
C9 Rh C11 C10 -66.5(2) . . . . ?
N Rh C11 C10 -171.01(19) . . . . ?
N Rh C11 C10 121.1(3) 4_565 . . . ?
C11 Rh C11 C10 36.5(2) 4_565 . . . ?
C12 Rh C11 C10 79.5(2) 4_565 . . . ?
C12 Rh C11 C10 115.9(3) . . . . ?
C9 Rh C11 C12 177.59(17) . . . . ?
N Rh C11 C12 73.09(19) . . . . ?
N Rh C11 C12 5.2(3) 4_565 . . . ?
C11 Rh C11 C12 -79.41(18) 4_565 . . . ?
C10 Rh C11 C12 -115.9(3) . . . . ?
C12 Rh C11 C12 -36.39(19) 4_565 . . . ?
C9 Rh C11 C14 57.0(3) . . . . ?
N Rh C11 C14 -47.5(3) . . . . ?
N Rh C11 C14 -115.5(3) 4_565 . . . ?
C11 Rh C11 C14 160.0(3) 4_565 . . . ?
C10 Rh C11 C14 123.5(4) . . . . ?
C12 Rh C11 C14 -157.0(3) 4_565 . . . ?
C12 Rh C11 C14 -120.6(4) . . . . ?
C10 C11 C12 C12 -2.2(3) . . . 4_565 ?
C14 C11 C12 C12 -175.6(3) . . . 4_565 ?
Rh C11 C12 C12 61.00(9) . . . 4_565 ?
C10 C11 C12 C15 178.0(3) . . . . ?
C14 C11 C12 C15 4.6(5) . . . . ?
Rh C11 C12 C15 -118.7(3) . . . . ?
C10 C11 C12 Rh -63.2(2) . . . . ?
C14 C11 C12 Rh 123.4(3) . . . . ?
C9 Rh C12 C12 -123.0(2) . . . 4_565 ?
N Rh C12 C12 125.65(7) . . . 4_565 ?
N Rh C12 C12 63.79(8) 4_565 . . 4_565 ?
C11 Rh C12 C12 -37.50(11) 4_565 . . 4_565 ?
C11 Rh C12 C12 -118.70(17) . . . 4_565 ?
C10 Rh C12 C12 -80.28(7) . . . 4_565 ?
C9 Rh C12 C11 -4.3(3) . . . . ?
N Rh C12 C11 -115.65(18) . . . . ?
N Rh C12 C11 -177.51(17) 4_565 . . . ?
C11 Rh C12 C11 81.2(2) 4_565 . . . ?
C10 Rh C12 C11 38.42(17) . . . . ?
C12 Rh C12 C11 118.70(17) 4_565 . . . ?
C9 Rh C12 C15 113.8(3) . . . . ?
N Rh C12 C15 2.4(3) . . . . ?
N Rh C12 C15 -59.4(3) 4_565 . . . ?
C11 Rh C12 C15 -160.7(3) 4_565 . . . ?
C11 Rh C12 C15 118.1(4) . . . . ?
C10 Rh C12 C15 156.5(3) . . . . ?
C12 Rh C12 C15 -123.2(3) 4_565 . . . ?
