#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:22:55 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179107 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/69/4306919.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4306919
loop_
_publ_author_name
'Sean E. Durran'
'Mark R. J. Elsegood'
'Shelly R. Hammond'
'Martin B. Smith'
_publ_section_title
;
Coordination Studies of a New Unsymmetrical
κ4-PNN'N''-Tetradentate Ligand: Stepwise Formation and
Structural Characterization
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2755
_journal_page_last               2766
_journal_paper_doi               10.1021/ic061196s
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C35 H30 N3 O4 P Pt'
_chemical_formula_weight         782.68
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   'geom except H4A & H4B coords freely refined'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.996(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.5410(7)
_cell_length_b                   12.7066(9)
_cell_length_c                   22.8534(16)
_cell_measurement_reflns_used    11627
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      28.82
_cell_measurement_theta_min      2.40
_cell_volume                     3049.4(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL and local programs'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.908
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD diffractometer'
_diffrn_measurement_method       'ω rotation with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0251
_diffrn_reflns_av_sigmaI/netI    0.0304
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            22959
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         28.89
_diffrn_reflns_theta_min         1.79
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.699
_exptl_absorpt_correction_T_max  0.655
_exptl_absorpt_correction_T_min  0.336
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS v2.03, Sheldrick, G.M., (2001)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.705
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1544
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.09
_refine_diff_density_max         0.712
_refine_diff_density_min         -0.592
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     403
_refine_ls_number_reflns         7304
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0352
_refine_ls_R_factor_gt           0.0215
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0157P)²+1.9215P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0407
_refine_ls_wR_factor_ref         0.0449
_reflns_number_gt                5921
_reflns_number_total             7304
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic061196ssi20060703_115123_6.cif
_cod_data_source_block           syn-6a'.H~2~O
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4306919
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.382010(10) 0.188557(8) 0.062381(4) 0.01745(3) Uani 1 1 d . . .
P1 P 0.42191(7) 0.27059(6) 0.14843(3) 0.01869(15) Uani 1 1 d . . .
N1 N 0.5685(2) 0.17434(16) 0.05076(9) 0.0189(5) Uani 1 1 d . . .
N2 N 0.3626(2) 0.11995(17) -0.01668(9) 0.0199(5) Uani 1 1 d . . .
N3 N 0.1903(2) 0.18075(18) 0.05180(9) 0.0213(5) Uani 1 1 d . . .
C1 C 0.5745(3) 0.2268(2) 0.18450(12) 0.0209(6) Uani 1 1 d . . .
C2 C 0.5976(3) 0.2325(2) 0.24542(12) 0.0284(7) Uani 1 1 d . . .
H2 H 0.5331 0.2595 0.2679 0.034 Uiso 1 1 calc R . .
C3 C 0.7122(3) 0.1999(3) 0.27407(13) 0.0354(8) Uani 1 1 d . . .
H3 H 0.7256 0.2049 0.3156 0.042 Uiso 1 1 calc R . .
C4 C 0.8066(3) 0.1606(3) 0.24243(13) 0.0352(8) Uani 1 1 d . . .
H4 H 0.8845 0.1369 0.2621 0.042 Uiso 1 1 calc R . .
C5 C 0.7878(3) 0.1555(2) 0.18198(13) 0.0288(7) Uani 1 1 d . . .
H5 H 0.8542 0.1300 0.1603 0.035 Uiso 1 1 calc R . .
C6 C 0.6722(3) 0.1875(2) 0.15197(11) 0.0212(6) Uani 1 1 d . . .
C7 C 0.6677(3) 0.1726(2) 0.08858(12) 0.0216(6) Uani 1 1 d . . .
H7 H 0.7470 0.1601 0.0731 0.026 Uiso 1 1 calc R . .
C8 C 0.5860(3) 0.1480(2) -0.01011(12) 0.0223(6) Uani 1 1 d . . .
C9 C 0.7025(3) 0.1531(2) -0.03398(13) 0.0276(7) Uani 1 1 d . . .
H9 H 0.7755 0.1787 -0.0110 0.033 Uiso 1 1 calc R . .
C10 C 0.7122(3) 0.1208(3) -0.09133(13) 0.0337(8) Uani 1 1 d . . .
H10 H 0.7916 0.1244 -0.1079 0.040 Uiso 1 1 calc R . .
C11 C 0.6055(3) 0.0834(2) -0.12431(13) 0.0316(7) Uani 1 1 d . . .
H11 H 0.6130 0.0598 -0.1633 0.038 Uiso 1 1 calc R . .
C12 C 0.4881(3) 0.0797(2) -0.10179(12) 0.0271(7) Uani 1 1 d . . .
H12 H 0.4158 0.0540 -0.1252 0.032 Uiso 1 1 calc R . .
C13 C 0.4763(3) 0.1139(2) -0.04426(11) 0.0217(6) Uani 1 1 d . . .
C14 C 0.2464(3) 0.0871(2) -0.03750(12) 0.0231(6) Uani 1 1 d . . .
O1 O 0.2188(2) 0.04281(16) -0.08539(8) 0.0299(5) Uani 1 1 d . . .
C15 C 0.1457(3) 0.1063(2) 0.00458(12) 0.0241(6) Uani 1 1 d . . .
H15A H 0.0683 0.1349 -0.0174 0.029 Uiso 1 1 calc R . .
H15B H 0.1229 0.0385 0.0223 0.029 Uiso 1 1 calc R . .
C16 C 0.0972(3) 0.2323(2) 0.07542(12) 0.0217(6) Uani 1 1 d . . .
O2 O -0.01749(19) 0.20970(16) 0.06928(9) 0.0305(5) Uani 1 1 d . . .
O3 O 0.14102(18) 0.31576(15) 0.10848(8) 0.0241(4) Uani 1 1 d . . .
C17 C 0.0489(3) 0.3669(2) 0.14239(12) 0.0293(7) Uani 1 1 d . . .
H17A H 0.0938 0.3985 0.1780 0.035 Uiso 1 1 calc R . .
H17B H -0.0110 0.3134 0.1553 0.035 Uiso 1 1 calc R . .
C18 C -0.0254(3) 0.4511(2) 0.10850(11) 0.0249(6) Uani 1 1 d . . .
C19 C -0.1556(3) 0.4429(3) 0.09675(13) 0.0321(7) Uani 1 1 d . . .
H19 H -0.1988 0.3825 0.1094 0.039 Uiso 1 1 calc R . .
C20 C -0.2242(3) 0.5224(3) 0.06655(14) 0.0403(9) Uani 1 1 d . . .
H20 H -0.3140 0.5167 0.0592 0.048 Uiso 1 1 calc R . .
C21 C -0.1622(4) 0.6088(3) 0.04729(14) 0.0420(9) Uani 1 1 d . . .
H21 H -0.2091 0.6630 0.0266 0.050 Uiso 1 1 calc R . .
C22 C -0.0329(4) 0.6172(3) 0.05774(15) 0.0450(9) Uani 1 1 d . . .
H22 H 0.0100 0.6768 0.0439 0.054 Uiso 1 1 calc R . .
C23 C 0.0356(3) 0.5390(3) 0.08845(14) 0.0359(8) Uani 1 1 d . . .
H23 H 0.1253 0.5457 0.0959 0.043 Uiso 1 1 calc R . .
C24 C 0.4448(3) 0.4110(2) 0.13807(12) 0.0212(6) Uani 1 1 d . . .
C25 C 0.5292(3) 0.4714(2) 0.17493(13) 0.0293(7) Uani 1 1 d . . .
H25 H 0.5742 0.4400 0.2083 0.035 Uiso 1 1 calc R . .
C26 C 0.5471(3) 0.5772(2) 0.16268(14) 0.0354(8) Uani 1 1 d . . .
H26 H 0.6042 0.6180 0.1879 0.042 Uiso 1 1 calc R . .
C27 C 0.4825(3) 0.6236(2) 0.11409(14) 0.0333(7) Uani 1 1 d . . .
H27 H 0.4953 0.6960 0.1060 0.040 Uiso 1 1 calc R . .
C28 C 0.3991(3) 0.5646(2) 0.07723(13) 0.0304(7) Uani 1 1 d . . .
H28 H 0.3540 0.5968 0.0441 0.036 Uiso 1 1 calc R . .
C29 C 0.3811(3) 0.4583(2) 0.08859(12) 0.0244(6) Uani 1 1 d . . .
H29 H 0.3254 0.4177 0.0626 0.029 Uiso 1 1 calc R . .
C30 C 0.3135(3) 0.2516(2) 0.20537(11) 0.0226(6) Uani 1 1 d . . .
C31 C 0.2976(3) 0.3252(3) 0.24902(12) 0.0315(7) Uani 1 1 d . . .
H31 H 0.3424 0.3901 0.2495 0.038 Uiso 1 1 calc R . .
C32 C 0.2155(3) 0.3036(3) 0.29234(13) 0.0428(9) Uani 1 1 d . . .
H32 H 0.2045 0.3537 0.3223 0.051 Uiso 1 1 calc R . .
C33 C 0.1507(3) 0.2094(3) 0.29148(14) 0.0449(10) Uani 1 1 d . . .
H33 H 0.0962 0.1944 0.3214 0.054 Uiso 1 1 calc R . .
C34 C 0.1642(3) 0.1366(3) 0.24762(14) 0.0384(8) Uani 1 1 d . . .
H34 H 0.1175 0.0726 0.2468 0.046 Uiso 1 1 calc R . .
C35 C 0.2456(3) 0.1570(2) 0.20499(13) 0.0276(7) Uani 1 1 d . . .
H35 H 0.2557 0.1065 0.1751 0.033 Uiso 1 1 calc R . .
O4 O -0.0261(3) 0.0092(2) -0.13307(12) 0.0579(7) Uani 1 1 d D . .
H4B H -0.048(4) -0.058(3) -0.1040(17) 0.087 Uiso 1 1 d D . .
H4A H 0.079(3) 0.021(3) -0.1133(17) 0.087 Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Pt1 N1 82.32(9) . . ?
N2 Pt1 N3 81.23(9) . . ?
N1 Pt1 N3 163.52(9) . . ?
N2 Pt1 P1 174.51(7) . . ?
N1 Pt1 P1 92.68(6) . . ?
N3 Pt1 P1 103.80(6) . . ?
C24 P1 C30 108.76(13) . . ?
C24 P1 C1 103.64(13) . . ?
C30 P1 C1 102.68(12) . . ?
C24 P1 Pt1 111.12(9) . . ?
C30 P1 Pt1 119.06(9) . . ?
C1 P1 Pt1 110.22(9) . . ?
C7 N1 C8 118.1(2) . . ?
C7 N1 Pt1 130.74(19) . . ?
C8 N1 Pt1 110.62(17) . . ?
C14 N2 C13 127.8(2) . . ?
C14 N2 Pt1 118.34(19) . . ?
C13 N2 Pt1 113.89(17) . . ?
C16 N3 C15 114.3(2) . . ?
C16 N3 Pt1 133.87(19) . . ?
C15 N3 Pt1 111.70(17) . . ?
C2 C1 C6 118.2(3) . . ?
C2 C1 P1 120.3(2) . . ?
C6 C1 P1 121.5(2) . . ?
C3 C2 C1 121.7(3) . . ?
C4 C3 C2 120.1(3) . . ?
C3 C4 C5 119.8(3) . . ?
C4 C5 C6 121.2(3) . . ?
C5 C6 C1 119.1(2) . . ?
C5 C6 C7 113.5(3) . . ?
C1 C6 C7 127.3(2) . . ?
N1 C7 C6 127.9(3) . . ?
C9 C8 C13 120.6(3) . . ?
C9 C8 N1 123.6(3) . . ?
C13 C8 N1 115.7(3) . . ?
C10 C9 C8 119.9(3) . . ?
C11 C10 C9 119.6(3) . . ?
C12 C11 C10 121.4(3) . . ?
C11 C12 C13 119.7(3) . . ?
C12 C13 N2 126.0(3) . . ?
C12 C13 C8 118.7(3) . . ?
N2 C13 C8 115.3(2) . . ?
O1 C14 N2 126.2(3) . . ?
O1 C14 C15 120.6(3) . . ?
N2 C14 C15 113.2(2) . . ?
N3 C15 C14 111.8(2) . . ?
O2 C16 N3 125.9(3) . . ?
O2 C16 O3 121.7(3) . . ?
N3 C16 O3 112.4(2) . . ?
C16 O3 C17 115.8(2) . . ?
O3 C17 C18 112.8(2) . . ?
C19 C18 C23 118.6(3) . . ?
C19 C18 C17 120.8(3) . . ?
C23 C18 C17 120.6(3) . . ?
C18 C19 C20 120.5(3) . . ?
C21 C20 C19 120.0(3) . . ?
C22 C21 C20 120.2(3) . . ?
C21 C22 C23 120.0(3) . . ?
C22 C23 C18 120.7(3) . . ?
C25 C24 C29 119.1(3) . . ?
C25 C24 P1 123.0(2) . . ?
C29 C24 P1 117.8(2) . . ?
C26 C25 C24 120.0(3) . . ?
C27 C26 C25 120.5(3) . . ?
C26 C27 C28 120.0(3) . . ?
C27 C28 C29 120.1(3) . . ?
C28 C29 C24 120.3(3) . . ?
C31 C30 C35 119.3(3) . . ?
C31 C30 P1 123.2(2) . . ?
C35 C30 P1 117.5(2) . . ?
C30 C31 C32 119.8(3) . . ?
C33 C32 C31 119.8(3) . . ?
C32 C33 C34 120.7(3) . . ?
C35 C34 C33 119.8(3) . . ?
C34 C35 C30 120.5(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N2 2.000(2) . ?
Pt1 N1 2.015(2) . ?
Pt1 N3 2.016(2) . ?
Pt1 P1 2.2330(7) . ?
P1 C24 1.819(3) . ?
P1 C30 1.821(3) . ?
P1 C1 1.829(3) . ?
N1 C7 1.297(3) . ?
N1 C8 1.458(3) . ?
N2 C14 1.341(3) . ?
N2 C13 1.404(4) . ?
N3 C16 1.333(4) . ?
N3 C15 1.481(3) . ?
C1 C2 1.394(4) . ?
C1 C6 1.413(4) . ?
C2 C3 1.387(4) . ?
C3 C4 1.374(4) . ?
C4 C5 1.380(4) . ?
C5 C6 1.405(4) . ?
C6 C7 1.458(4) . ?
C8 C9 1.388(4) . ?
C8 C13 1.406(4) . ?
C9 C10 1.385(4) . ?
C10 C11 1.382(4) . ?
C11 C12 1.381(4) . ?
C12 C13 1.401(4) . ?
C14 O1 1.243(3) . ?
C14 C15 1.512(4) . ?
C16 O2 1.238(3) . ?
C16 O3 1.359(3) . ?
O3 C17 1.449(3) . ?
C17 C18 1.500(4) . ?
C18 C19 1.380(4) . ?
C18 C23 1.387(4) . ?
C19 C20 1.389(4) . ?
C20 C21 1.370(5) . ?
C21 C22 1.367(5) . ?
C22 C23 1.383(4) . ?
C24 C25 1.400(4) . ?
C24 C29 1.399(4) . ?
C25 C26 1.389(4) . ?
C26 C27 1.383(4) . ?
C27 C28 1.384(4) . ?
C28 C29 1.391(4) . ?
C30 C31 1.388(4) . ?
C30 C35 1.398(4) . ?
C31 C32 1.398(4) . ?
C32 C33 1.377(5) . ?
C33 C34 1.381(5) . ?
C34 C35 1.378(4) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O4 H4B O2 1.12(3) 2.17(4) 3.155(4) 145(3) 3
O4 H4B N3 1.12(3) 2.53(3) 3.582(4) 156(3) 3
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pt1 P1 C24 84.57(11) . . . . ?
N3 Pt1 P1 C24 -95.68(12) . . . . ?
N1 Pt1 P1 C30 -147.91(12) . . . . ?
N3 Pt1 P1 C30 31.83(13) . . . . ?
N1 Pt1 P1 C1 -29.74(11) . . . . ?
N3 Pt1 P1 C1 150.01(12) . . . . ?
N2 Pt1 N1 C7 -157.7(2) . . . . ?
N3 Pt1 N1 C7 -154.6(3) . . . . ?
P1 Pt1 N1 C7 24.6(2) . . . . ?
N2 Pt1 N1 C8 13.14(16) . . . . ?
N3 Pt1 N1 C8 16.3(4) . . . . ?
P1 Pt1 N1 C8 -164.58(16) . . . . ?
N1 Pt1 N2 C14 170.4(2) . . . . ?
N3 Pt1 N2 C14 -8.68(19) . . . . ?
N1 Pt1 N2 C13 -10.51(17) . . . . ?
N3 Pt1 N2 C13 170.39(19) . . . . ?
N2 Pt1 N3 C16 -158.8(3) . . . . ?
N1 Pt1 N3 C16 -162.0(3) . . . . ?
P1 Pt1 N3 C16 18.9(3) . . . . ?
N2 Pt1 N3 C15 16.29(17) . . . . ?
N1 Pt1 N3 C15 13.1(4) . . . . ?
P1 Pt1 N3 C15 -165.97(16) . . . . ?
C24 P1 C1 C2 86.3(3) . . . . ?
C30 P1 C1 C2 -26.9(3) . . . . ?
Pt1 P1 C1 C2 -154.7(2) . . . . ?
C24 P1 C1 C6 -93.0(2) . . . . ?
C30 P1 C1 C6 153.8(2) . . . . ?
Pt1 P1 C1 C6 25.9(3) . . . . ?
C6 C1 C2 C3 -0.6(5) . . . . ?
P1 C1 C2 C3 180.0(3) . . . . ?
C1 C2 C3 C4 -0.1(5) . . . . ?
C2 C3 C4 C5 1.3(5) . . . . ?
C3 C4 C5 C6 -1.7(5) . . . . ?
C4 C5 C6 C1 0.9(4) . . . . ?
C4 C5 C6 C7 -177.6(3) . . . . ?
C2 C1 C6 C5 0.3(4) . . . . ?
P1 C1 C6 C5 179.6(2) . . . . ?
C2 C1 C6 C7 178.6(3) . . . . ?
P1 C1 C6 C7 -2.1(4) . . . . ?
C8 N1 C7 C6 -174.6(3) . . . . ?
Pt1 N1 C7 C6 -4.3(4) . . . . ?
C5 C6 C7 N1 165.1(3) . . . . ?
C1 C6 C7 N1 -13.3(5) . . . . ?
C7 N1 C8 C9 -20.8(4) . . . . ?
Pt1 N1 C8 C9 167.0(2) . . . . ?
C7 N1 C8 C13 157.9(2) . . . . ?
Pt1 N1 C8 C13 -14.3(3) . . . . ?
C13 C8 C9 C10 -2.3(4) . . . . ?
N1 C8 C9 C10 176.3(3) . . . . ?
C8 C9 C10 C11 -0.2(4) . . . . ?
C9 C10 C11 C12 1.5(5) . . . . ?
C10 C11 C12 C13 -0.3(4) . . . . ?
C11 C12 C13 N2 176.4(3) . . . . ?
C11 C12 C13 C8 -2.2(4) . . . . ?
C14 N2 C13 C12 5.8(4) . . . . ?
Pt1 N2 C13 C12 -173.2(2) . . . . ?
C14 N2 C13 C8 -175.6(2) . . . . ?
Pt1 N2 C13 C8 5.4(3) . . . . ?
C9 C8 C13 C12 3.5(4) . . . . ?
N1 C8 C13 C12 -175.2(2) . . . . ?
C9 C8 C13 N2 -175.2(2) . . . . ?
N1 C8 C13 N2 6.1(3) . . . . ?
C13 N2 C14 O1 1.5(4) . . . . ?
Pt1 N2 C14 O1 -179.6(2) . . . . ?
C13 N2 C14 C15 179.9(2) . . . . ?
Pt1 N2 C14 C15 -1.2(3) . . . . ?
C16 N3 C15 C14 154.9(2) . . . . ?
Pt1 N3 C15 C14 -21.3(3) . . . . ?
O1 C14 C15 N3 -166.7(2) . . . . ?
N2 C14 C15 N3 14.8(3) . . . . ?
C15 N3 C16 O2 14.1(4) . . . . ?
Pt1 N3 C16 O2 -170.9(2) . . . . ?
C15 N3 C16 O3 -166.0(2) . . . . ?
Pt1 N3 C16 O3 9.0(4) . . . . ?
O2 C16 O3 C17 8.3(4) . . . . ?
N3 C16 O3 C17 -171.6(2) . . . . ?
C16 O3 C17 C18 -87.4(3) . . . . ?
O3 C17 C18 C19 117.5(3) . . . . ?
O3 C17 C18 C23 -62.7(4) . . . . ?
C23 C18 C19 C20 -1.3(5) . . . . ?
C17 C18 C19 C20 178.5(3) . . . . ?
C18 C19 C20 C21 1.1(5) . . . . ?
C19 C20 C21 C22 -0.1(5) . . . . ?
C20 C21 C22 C23 -0.8(5) . . . . ?
C21 C22 C23 C18 0.6(5) . . . . ?
C19 C18 C23 C22 0.5(5) . . . . ?
C17 C18 C23 C22 -179.3(3) . . . . ?
C30 P1 C24 C25 80.8(3) . . . . ?
C1 P1 C24 C25 -27.9(3) . . . . ?
Pt1 P1 C24 C25 -146.3(2) . . . . ?
C30 P1 C24 C29 -103.6(2) . . . . ?
C1 P1 C24 C29 147.6(2) . . . . ?
Pt1 P1 C24 C29 29.3(2) . . . . ?
C29 C24 C25 C26 1.1(5) . . . . ?
P1 C24 C25 C26 176.6(2) . . . . ?
C24 C25 C26 C27 -0.3(5) . . . . ?
C25 C26 C27 C28 0.1(5) . . . . ?
C26 C27 C28 C29 -0.7(5) . . . . ?
C27 C28 C29 C24 1.6(5) . . . . ?
C25 C24 C29 C28 -1.7(4) . . . . ?
P1 C24 C29 C28 -177.5(2) . . . . ?
C24 P1 C30 C31 -25.2(3) . . . . ?
C1 P1 C30 C31 84.2(3) . . . . ?
Pt1 P1 C30 C31 -153.8(2) . . . . ?
C24 P1 C30 C35 156.0(2) . . . . ?
C1 P1 C30 C35 -94.6(2) . . . . ?
Pt1 P1 C30 C35 27.4(2) . . . . ?
C35 C30 C31 C32 0.8(4) . . . . ?
P1 C30 C31 C32 -178.0(2) . . . . ?
C30 C31 C32 C33 0.0(5) . . . . ?
C31 C32 C33 C34 -1.1(5) . . . . ?
C32 C33 C34 C35 1.6(5) . . . . ?
C33 C34 C35 C30 -0.8(5) . . . . ?
C31 C30 C35 C34 -0.3(4) . . . . ?
P1 C30 C35 C34 178.5(2) . . . . ?
