#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:24:52 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179109 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/71/4307181.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4307181
loop_
_publ_author_name
'Jie Zhang'
'Ruifang Cai'
'Zhenxia Chen'
'Xigeng Zhou'
_publ_section_title
;
Facile Construction of Lanthanide Metallomacrocycles with the Bridging
Imidazolate and Triazolate Ligands and Their Ring Expansions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              321
_journal_page_last               327
_journal_paper_doi               10.1021/ic061722f
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C72 H92 Dy4 N8 O5'
_chemical_formula_weight         1799.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.261(13)
_cell_angle_beta                 105.411(13)
_cell_angle_gamma                115.058(12)
_cell_formula_units_Z            2
_cell_length_a                   15.476(14)
_cell_length_b                   16.260(15)
_cell_length_c                   17.212(16)
_cell_measurement_reflns_used    907
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.889
_cell_measurement_theta_min      2.733
_cell_volume                     3511(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.970
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0303
_diffrn_reflns_av_sigmaI/netI    0.0798
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            14459
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.32
_diffrn_standards_decay_%        8.03
_exptl_absorpt_coefficient_mu    4.261
_exptl_absorpt_correction_T_max  0.6753
_exptl_absorpt_correction_T_min  0.5674
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_density_diffrn    1.702
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1768
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.940
_refine_diff_density_min         -1.430
_refine_diff_density_rms         0.222
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     752
_refine_ls_number_reflns         12025
_refine_ls_number_restraints     21
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.1086
_refine_ls_R_factor_gt           0.0587
_refine_ls_shift/su_max          0.688
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1261P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1608
_refine_ls_wR_factor_ref         0.2097
_reflns_number_gt                7446
_reflns_number_total             12025
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic061722fsi20060911_110221.cif
_cod_data_source_block           f41118a
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4307181
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.69059(5) 0.35318(4) 0.48526(4) 0.04223(19) Uani 1 1 d . . .
Dy2 Dy 0.36291(5) 0.34360(5) 0.13493(4) 0.0478(2) Uani 1 1 d . . .
Dy3 Dy 0.09870(5) 0.03116(5) 0.30457(4) 0.0513(2) Uani 1 1 d . . .
Dy4 Dy 0.41315(6) -0.08738(5) 0.17093(5) 0.0568(2) Uani 1 1 d D . .
N1 N 0.5414(8) 0.3577(8) 0.4008(7) 0.045(3) Uani 1 1 d . . .
N2 N 0.4407(8) 0.3694(8) 0.2826(7) 0.046(3) Uani 1 1 d . . .
N3 N 0.2475(9) 0.1880(9) 0.1462(8) 0.060(3) Uani 1 1 d . . .
N4 N 0.1534(8) 0.0855(8) 0.1967(7) 0.049(3) Uani 1 1 d . . .
N5 N 0.2443(10) 0.0016(9) 0.3169(8) 0.056(3) Uani 1 1 d . . .
N6 N 0.3343(10) -0.0565(9) 0.2651(8) 0.057(3) Uani 1 1 d . . .
N7 N 0.5302(9) 0.0857(9) 0.2360(8) 0.056(3) Uani 1 1 d . . .
N8 N 0.6306(9) 0.2343(8) 0.3459(7) 0.050(3) Uani 1 1 d . . .
O1 O 0.8113(8) 0.2768(8) 0.4906(8) 0.069(3) Uani 1 1 d . . .
O2 O 0.5363(9) 0.5284(8) 0.2197(7) 0.080(4) Uani 1 1 d . . .
O3 O -0.0190(11) 0.0987(11) 0.2298(10) 0.098(4) Uani 1 1 d . . .
O4 O 0.252(2) -0.257(2) 0.162(3) 0.34(2) Uiso 1 1 d D . .
O5 O 0.162(4) 0.436(3) 0.785(3) 0.35(2) Uiso 1 1 d D . .
C1 C 0.8824(14) 0.5109(12) 0.5702(14) 0.084(6) Uani 1 1 d . . .
H1A H 0.9407 0.5187 0.6175 0.101 Uiso 1 1 calc R . .
C2 C 0.8131(16) 0.5460(11) 0.5784(15) 0.088(6) Uani 1 1 d . . .
H2A H 0.8145 0.5802 0.6333 0.106 Uiso 1 1 calc R . .
C3 C 0.7578(13) 0.5398(12) 0.4965(15) 0.083(6) Uani 1 1 d . . .
H3A H 0.7124 0.5674 0.4862 0.099 Uiso 1 1 calc R . .
C4 C 0.7849(14) 0.5009(14) 0.4343(14) 0.079(5) Uani 1 1 d . . .
H4A H 0.7654 0.4992 0.3747 0.095 Uiso 1 1 calc R . .
C5 C 0.8624(13) 0.4819(13) 0.4780(14) 0.082(6) Uani 1 1 d . . .
H5A H 0.9054 0.4652 0.4527 0.098 Uiso 1 1 calc R . .
C6 C 0.7013(19) 0.3636(15) 0.6471(12) 0.091(6) Uani 1 1 d . . .
H6A H 0.7549 0.4162 0.7025 0.110 Uiso 1 1 calc R . .
C7 C 0.6047(19) 0.3510(16) 0.5985(13) 0.082(6) Uani 1 1 d . . .
H7A H 0.5795 0.3951 0.6154 0.098 Uiso 1 1 calc R . .
C8 C 0.5449(14) 0.261(2) 0.5382(13) 0.094(7) Uani 1 1 d . . .
H8A H 0.4701 0.2302 0.5043 0.112 Uiso 1 1 calc R . .
C9 C 0.5996(14) 0.2100(12) 0.5393(10) 0.066(5) Uani 1 1 d . . .
H9A H 0.5701 0.1400 0.5089 0.080 Uiso 1 1 calc R . .
C10 C 0.6935(14) 0.2726(14) 0.6062(11) 0.067(5) Uani 1 1 d . . .
H10A H 0.7453 0.2546 0.6290 0.081 Uiso 1 1 calc R . .
C11 C 0.5112(9) 0.3430(9) 0.3155(8) 0.037(3) Uani 1 1 d . . .
H11A H 0.5370 0.3163 0.2809 0.044 Uiso 1 1 calc R . .
C12 C 0.4834(11) 0.3980(10) 0.4236(9) 0.051(3) Uani 1 1 d . . .
H12A H 0.4858 0.4180 0.4793 0.061 Uiso 1 1 calc R . .
C13 C 0.4241(11) 0.4043(11) 0.3552(9) 0.053(4) Uani 1 1 d . . .
H13A H 0.3792 0.4281 0.3561 0.064 Uiso 1 1 calc R . .
C14 C 0.5159(14) 0.3321(17) 0.1015(12) 0.087(7) Uani 1 1 d . . .
H14A H 0.5892 0.3690 0.1422 0.105 Uiso 1 1 calc R . .
C15 C 0.4718(19) 0.3602(16) 0.0390(15) 0.092(7) Uani 1 1 d . . .
H15A H 0.5077 0.4173 0.0249 0.110 Uiso 1 1 calc R . .
C16 C 0.3699(15) 0.2710(18) -0.0169(10) 0.082(6) Uani 1 1 d . . .
H16A H 0.3238 0.2632 -0.0730 0.098 Uiso 1 1 calc R . .
C17 C 0.3560(19) 0.2009(15) 0.0105(14) 0.088(7) Uani 1 1 d . . .
H17A H 0.2988 0.1328 -0.0200 0.105 Uiso 1 1 calc R . .
C18 C 0.4464(18) 0.2369(15) 0.0863(13) 0.078(5) Uani 1 1 d . . .
H18A H 0.4623 0.1967 0.1160 0.094 Uiso 1 1 calc R . .
C19 C 0.3046(16) 0.4759(14) 0.1610(12) 0.079(5) Uani 1 1 d . . .
H19A H 0.3465 0.5414 0.2065 0.095 Uiso 1 1 calc R . .
C20 C 0.2969(16) 0.4528(14) 0.0765(14) 0.086(6) Uani 1 1 d . . .
H20A H 0.3324 0.4999 0.0524 0.103 Uiso 1 1 calc R . .
C21 C 0.2158(15) 0.3586(14) 0.0286(13) 0.082(6) Uani 1 1 d . . .
H21A H 0.1873 0.3287 -0.0349 0.098 Uiso 1 1 calc R . .
C22 C 0.1687(14) 0.3186(15) 0.0789(13) 0.077(5) Uani 1 1 d . . .
H22A H 0.1023 0.2577 0.0590 0.093 Uiso 1 1 calc R . .
C23 C 0.2282(17) 0.394(2) 0.1649(15) 0.098(7) Uani 1 1 d . . .
H23A H 0.2085 0.3921 0.2144 0.118 Uiso 1 1 calc R . .
C24 C 0.2350(10) 0.1689(10) 0.2107(9) 0.047(3) Uani 1 1 d . . .
H24A H 0.2820 0.2124 0.2669 0.057 Uiso 1 1 calc R . .
C25 C 0.1589(12) 0.1061(12) 0.0751(9) 0.069(5) Uani 1 1 d . . .
H25A H 0.1419 0.0971 0.0168 0.082 Uiso 1 1 calc R . .
C26 C 0.1046(13) 0.0445(12) 0.1068(11) 0.074(5) Uani 1 1 d . . .
H26A H 0.0441 -0.0160 0.0742 0.089 Uiso 1 1 calc R . .
C27 C 0.121(2) 0.1837(18) 0.4228(14) 0.100(7) Uani 1 1 d . . .
H27A H 0.0883 0.2227 0.4113 0.120 Uiso 1 1 calc R . .
C28 C 0.220(2) 0.2065(15) 0.4306(17) 0.130(12) Uani 1 1 d . . .
H28A H 0.2714 0.2652 0.4265 0.156 Uiso 1 1 calc R . .
C29 C 0.2419(17) 0.146(2) 0.4674(15) 0.102(9) Uani 1 1 d . . .
H29A H 0.3108 0.1532 0.4919 0.122 Uiso 1 1 calc R . .
C30 C 0.157(2) 0.0859(15) 0.4752(12) 0.089(6) Uani 1 1 d . . .
H30A H 0.1548 0.0424 0.5072 0.107 Uiso 1 1 calc R . .
C31 C 0.0862(17) 0.1100(17) 0.4513(15) 0.097(7) Uani 1 1 d . . .
H31A H 0.0225 0.0855 0.4621 0.117 Uiso 1 1 calc R . .
C32 C -0.0126(19) -0.1495(15) 0.1858(18) 0.115(10) Uani 1 1 d . . .
H32A H 0.0020 -0.1736 0.1365 0.138 Uiso 1 1 calc R . .
C33 C 0.0177(15) -0.1590(12) 0.2662(14) 0.085(6) Uani 1 1 d . . .
H33A H 0.0565 -0.1915 0.2824 0.102 Uiso 1 1 calc R . .
C34 C -0.037(2) -0.1344(13) 0.3104(17) 0.100(8) Uani 1 1 d . . .
H34A H -0.0398 -0.1448 0.3640 0.120 Uiso 1 1 calc R . .
C35 C -0.0970(16) -0.1087(15) 0.2632(18) 0.097(7) Uani 1 1 d . . .
H35A H -0.1521 -0.0996 0.2737 0.116 Uiso 1 1 calc R . .
C36 C -0.0812(16) -0.1220(14) 0.1829(14) 0.097(7) Uani 1 1 d . . .
H36A H -0.1234 -0.1195 0.1307 0.116 Uiso 1 1 calc R . .
C37 C 0.2698(13) -0.0207(12) 0.2537(10) 0.064(4) Uani 1 1 d . . .
H37A H 0.2448 -0.0123 0.2022 0.077 Uiso 1 1 calc R . .
C38 C 0.2956(13) -0.0215(12) 0.3757(10) 0.065(4) Uani 1 1 d . . .
H38A H 0.2930 -0.0153 0.4299 0.079 Uiso 1 1 calc R . .
C39 C 0.3517(13) -0.0553(12) 0.3464(11) 0.065(4) Uani 1 1 d . . .
H39A H 0.3945 -0.0742 0.3768 0.077 Uiso 1 1 calc R . .
C40 C 0.383(2) -0.0405(17) 0.0323(13) 0.106(8) Uani 1 1 d . . .
H40A H 0.4331 0.0158 0.0247 0.127 Uiso 1 1 calc R . .
C41 C 0.304(2) -0.0463(18) 0.0549(12) 0.097(7) Uani 1 1 d . . .
H41A H 0.2913 0.0080 0.0697 0.116 Uiso 1 1 calc R . .
C42 C 0.241(2) -0.1346(19) 0.0459(12) 0.099(7) Uani 1 1 d . . .
H42A H 0.1734 -0.1565 0.0502 0.118 Uiso 1 1 calc R . .
C43 C 0.2719(18) -0.1955(15) 0.0112(12) 0.093(7) Uani 1 1 d . . .
H43A H 0.2304 -0.2671 -0.0132 0.112 Uiso 1 1 calc R . .
C44 C 0.365(2) -0.139(2) 0.0048(13) 0.116(9) Uani 1 1 d . . .
H44A H 0.3995 -0.1622 -0.0270 0.139 Uiso 1 1 calc R . .
C45 C 0.594(2) -0.073(3) 0.236(2) 0.137(11) Uani 1 1 d . . .
H45A H 0.6611 -0.0169 0.2485 0.164 Uiso 1 1 calc R . .
C46 C 0.554(2) -0.096(2) 0.2978(18) 0.111(8) Uani 1 1 d . . .
H46A H 0.5864 -0.0571 0.3600 0.133 Uiso 1 1 calc R . .
C47 C 0.469(3) -0.189(2) 0.256(2) 0.121(10) Uani 1 1 d . . .
H47A H 0.4296 -0.2267 0.2849 0.145 Uiso 1 1 calc R . .
C48 C 0.453(4) -0.226(3) 0.165(2) 0.179(18) Uani 1 1 d . . .
H48A H 0.4081 -0.2945 0.1240 0.215 Uiso 1 1 calc R . .
C49 C 0.536(4) -0.157(4) 0.161(3) 0.19(2) Uani 1 1 d . . .
H49A H 0.5566 -0.1665 0.1122 0.227 Uiso 1 1 calc R . .
C50 C 0.5454(11) 0.1445(9) 0.3123(9) 0.051(3) Uani 1 1 d . . .
H50A H 0.5004 0.1245 0.3398 0.061 Uiso 1 1 calc R . .
C51 C 0.6726(13) 0.2334(12) 0.2855(10) 0.065(4) Uani 1 1 d . . .
H51A H 0.7327 0.2851 0.2887 0.078 Uiso 1 1 calc R . .
C52 C 0.6118(14) 0.1440(12) 0.2196(10) 0.068(5) Uani 1 1 d . . .
H52A H 0.6240 0.1255 0.1706 0.082 Uiso 1 1 calc R . .
C53 C 0.7755(17) 0.1746(14) 0.4583(19) 0.120(9) Uani 1 1 d . . .
H53A H 0.7332 0.1457 0.3964 0.144 Uiso 1 1 calc R . .
H53B H 0.7336 0.1417 0.4871 0.144 Uiso 1 1 calc R . .
C54 C 0.866(2) 0.165(2) 0.476(3) 0.201(19) Uani 1 1 d . . .
H54A H 0.8656 0.1260 0.5117 0.241 Uiso 1 1 calc R . .
H54B H 0.8662 0.1317 0.4217 0.241 Uiso 1 1 calc R . .
C55 C 0.954(2) 0.257(2) 0.518(2) 0.130(10) Uani 1 1 d . . .
H55A H 0.9895 0.2745 0.4802 0.156 Uiso 1 1 calc R . .
H55B H 1.0025 0.2599 0.5694 0.156 Uiso 1 1 calc R . .
C56 C 0.9179(16) 0.3216(18) 0.5416(18) 0.131(10) Uani 1 1 d . . .
H56A H 0.9296 0.3380 0.6025 0.157 Uiso 1 1 calc R . .
H56B H 0.9560 0.3816 0.5331 0.157 Uiso 1 1 calc R . .
C57 C 0.6037(17) 0.5761(17) 0.3027(16) 0.134(10) Uani 1 1 d . . .
H57A H 0.6367 0.5396 0.3189 0.161 Uiso 1 1 calc R . .
H57B H 0.5664 0.5805 0.3392 0.161 Uiso 1 1 calc R . .
C58 C 0.681(2) 0.6708(14) 0.3170(16) 0.139(11) Uani 1 1 d . . .
H58A H 0.6872 0.7177 0.3670 0.166 Uiso 1 1 calc R . .
H58B H 0.7472 0.6742 0.3293 0.166 Uiso 1 1 calc R . .
C59 C 0.655(2) 0.693(2) 0.2471(19) 0.178(16) Uani 1 1 d . . .
H59A H 0.7106 0.7122 0.2262 0.214 Uiso 1 1 calc R . .
H59B H 0.6402 0.7455 0.2593 0.214 Uiso 1 1 calc R . .
C60 C 0.565(3) 0.604(2) 0.1866(19) 0.25(3) Uani 1 1 d . . .
H60A H 0.5075 0.6151 0.1685 0.296 Uiso 1 1 calc R . .
H60B H 0.5773 0.5823 0.1357 0.296 Uiso 1 1 calc R . .
C61 C 0.021(3) 0.183(2) 0.203(3) 0.189(17) Uani 1 1 d . . .
H61A H 0.0917 0.2322 0.2446 0.226 Uiso 1 1 calc R . .
H61B H 0.0221 0.1627 0.1466 0.226 Uiso 1 1 calc R . .
C62 C -0.048(2) 0.224(2) 0.201(2) 0.167(14) Uani 1 1 d . . .
H62A H -0.0145 0.2844 0.2506 0.200 Uiso 1 1 calc R . .
H62B H -0.0643 0.2377 0.1484 0.200 Uiso 1 1 calc R . .
C63 C -0.140(3) 0.153(3) 0.203(2) 0.168(15) Uani 1 1 d . . .
H63A H -0.1992 0.1302 0.1493 0.201 Uiso 1 1 calc R . .
H63B H -0.1524 0.1812 0.2511 0.201 Uiso 1 1 calc R . .
C64 C -0.1246(18) 0.072(2) 0.2119(19) 0.144(11) Uani 1 1 d . . .
H64A H -0.1422 0.0558 0.2588 0.173 Uiso 1 1 calc R . .
H64B H -0.1702 0.0146 0.1587 0.173 Uiso 1 1 calc R . .
C69 C 0.216(3) 0.533(4) 0.852(3) 0.47(5) Uiso 1 1 d D . .
H69A H 0.2890 0.5687 0.8627 0.559 Uiso 1 1 calc R . .
H69B H 0.2097 0.5292 0.9063 0.559 Uiso 1 1 calc R . .
C70 C 0.158(4) 0.577(2) 0.812(3) 0.28(2) Uiso 1 1 d D . .
H70A H 0.1731 0.6375 0.8542 0.337 Uiso 1 1 calc R . .
H70B H 0.1716 0.5899 0.7630 0.337 Uiso 1 1 calc R . .
C71 C 0.048(3) 0.497(4) 0.785(4) 0.44(5) Uiso 1 1 d D . .
H71A H 0.0296 0.4943 0.8345 0.529 Uiso 1 1 calc R . .
H71B H -0.0014 0.5036 0.7428 0.529 Uiso 1 1 calc R . .
C72 C 0.053(3) 0.408(3) 0.746(4) 0.54(7) Uiso 1 1 d D . .
H72A H 0.0097 0.3537 0.7586 0.654 Uiso 1 1 calc R . .
H72B H 0.0292 0.3893 0.6833 0.654 Uiso 1 1 calc R . .
C65 C 0.160(4) -0.271(3) 0.179(3) 0.39(4) Uiso 1 1 d D . .
H65A H 0.1501 -0.2157 0.1810 0.466 Uiso 1 1 calc R . .
H65B H 0.1649 -0.2807 0.2337 0.466 Uiso 1 1 calc R . .
C68 C 0.232(4) -0.355(3) 0.119(7) 2.0(6) Uiso 1 1 d D . .
H68A H 0.2765 -0.3696 0.1573 2.400 Uiso 1 1 calc R . .
H68B H 0.2447 -0.3590 0.0668 2.400 Uiso 1 1 calc R . .
C66 C 0.073(2) -0.362(4) 0.103(3) 0.40(4) Uiso 1 1 d D . .
H66A H 0.0107 -0.3912 0.1151 0.482 Uiso 1 1 calc R . .
H66B H 0.0554 -0.3482 0.0510 0.482 Uiso 1 1 calc R . .
C67 C 0.120(4) -0.4248(19) 0.097(4) 0.35(3) Uiso 1 1 d D . .
H67A H 0.1135 -0.4574 0.1383 0.415 Uiso 1 1 calc R . .
H67B H 0.0871 -0.4737 0.0392 0.415 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N8 Dy1 N1 77.6(4) . . ?
N8 Dy1 C7 130.3(6) . . ?
N1 Dy1 C7 82.1(5) . . ?
N8 Dy1 O1 70.4(4) . . ?
N1 Dy1 O1 148.0(4) . . ?
C7 Dy1 O1 118.8(5) . . ?
N8 Dy1 C8 101.2(6) . . ?
N1 Dy1 C8 75.7(5) . . ?
C7 Dy1 C8 29.3(6) . . ?
O1 Dy1 C8 110.0(6) . . ?
N8 Dy1 C5 94.9(5) . . ?
N1 Dy1 C5 110.5(5) . . ?
C7 Dy1 C5 134.8(7) . . ?
O1 Dy1 C5 73.2(5) . . ?
C8 Dy1 C5 163.8(7) . . ?
N8 Dy1 C9 89.7(5) . . ?
N1 Dy1 C9 100.8(5) . . ?
C7 Dy1 C9 50.5(6) . . ?
O1 Dy1 C9 79.3(5) . . ?
C8 Dy1 C9 30.7(6) . . ?
C5 Dy1 C9 148.7(6) . . ?
N8 Dy1 C1 124.6(6) . . ?
N1 Dy1 C1 123.4(5) . . ?
C7 Dy1 C1 104.5(7) . . ?
O1 Dy1 C1 77.2(5) . . ?
C8 Dy1 C1 132.2(7) . . ?
C5 Dy1 C1 31.8(6) . . ?
C9 Dy1 C1 127.0(6) . . ?
N8 Dy1 C2 141.7(6) . . ?
N1 Dy1 C2 97.2(6) . . ?
C7 Dy1 C2 85.2(7) . . ?
O1 Dy1 C2 107.8(5) . . ?
C8 Dy1 C2 114.4(8) . . ?
C5 Dy1 C2 50.9(6) . . ?
C9 Dy1 C2 128.3(6) . . ?
C1 Dy1 C2 31.1(6) . . ?
N8 Dy1 C10 110.6(5) . . ?
N1 Dy1 C10 124.2(4) . . ?
C7 Dy1 C10 49.7(5) . . ?
O1 Dy1 C10 69.3(4) . . ?
C8 Dy1 C10 48.5(5) . . ?
C5 Dy1 C10 122.9(6) . . ?
C9 Dy1 C10 29.3(5) . . ?
C1 Dy1 C10 97.7(6) . . ?
C2 Dy1 C10 103.6(7) . . ?
N8 Dy1 C4 91.6(6) . . ?
N1 Dy1 C4 79.7(5) . . ?
C7 Dy1 C4 128.6(7) . . ?
O1 Dy1 C4 100.9(5) . . ?
C8 Dy1 C4 149.0(7) . . ?
C5 Dy1 C4 30.9(6) . . ?
C9 Dy1 C4 178.7(6) . . ?
C1 Dy1 C4 51.9(6) . . ?
C2 Dy1 C4 50.5(7) . . ?
C10 Dy1 C4 149.6(6) . . ?
N8 Dy1 C3 116.9(6) . . ?
N1 Dy1 C3 72.8(5) . . ?
C7 Dy1 C3 99.0(7) . . ?
O1 Dy1 C3 122.1(5) . . ?
C8 Dy1 C3 122.5(8) . . ?
C5 Dy1 C3 49.6(6) . . ?
C9 Dy1 C3 149.4(7) . . ?
C1 Dy1 C3 50.5(5) . . ?
C2 Dy1 C3 30.1(6) . . ?
C10 Dy1 C3 132.2(7) . . ?
C4 Dy1 C3 29.6(6) . . ?
N2 Dy2 N3 76.4(4) . . ?
N2 Dy2 C15 120.0(6) . . ?
N3 Dy2 C15 125.2(5) . . ?
N2 Dy2 C20 125.5(5) . . ?
N3 Dy2 C20 123.8(6) . . ?
C15 Dy2 C20 90.4(7) . . ?
N2 Dy2 C14 92.6(5) . . ?
N3 Dy2 C14 109.2(6) . . ?
C15 Dy2 C14 30.4(6) . . ?
C20 Dy2 C14 118.9(8) . . ?
N2 Dy2 C21 140.8(5) . . ?
N3 Dy2 C21 97.9(6) . . ?
C15 Dy2 C21 95.3(8) . . ?
C20 Dy2 C21 30.1(6) . . ?
C14 Dy2 C21 125.1(7) . . ?
N2 Dy2 C19 96.5(5) . . ?
N3 Dy2 C19 113.8(6) . . ?
C15 Dy2 C19 115.2(7) . . ?
C20 Dy2 C19 30.2(6) . . ?
C14 Dy2 C19 137.1(7) . . ?
C21 Dy2 C19 49.7(6) . . ?
N2 Dy2 C23 91.3(6) . . ?
N3 Dy2 C23 83.6(6) . . ?
C15 Dy2 C23 140.0(7) . . ?
C20 Dy2 C23 49.7(7) . . ?
C14 Dy2 C23 167.2(8) . . ?
C21 Dy2 C23 49.5(7) . . ?
C19 Dy2 C23 30.2(6) . . ?
N2 Dy2 C16 139.2(5) . . ?
N3 Dy2 C16 99.4(6) . . ?
C15 Dy2 C16 32.3(6) . . ?
C20 Dy2 C16 91.0(7) . . ?
C14 Dy2 C16 49.8(5) . . ?
C21 Dy2 C16 79.9(6) . . ?
C19 Dy2 C16 121.2(7) . . ?
C23 Dy2 C16 129.0(6) . . ?
N2 Dy2 C18 92.2(5) . . ?
N3 Dy2 C18 80.1(5) . . ?
C15 Dy2 C18 49.8(6) . . ?
C20 Dy2 C18 137.3(6) . . ?
C14 Dy2 C18 29.8(6) . . ?
C21 Dy2 C18 125.5(6) . . ?
C19 Dy2 C18 165.0(6) . . ?
C23 Dy2 C18 162.1(8) . . ?
C16 Dy2 C18 47.7(6) . . ?
N2 Dy2 C22 116.4(5) . . ?
N3 Dy2 C22 73.9(5) . . ?
C15 Dy2 C22 123.3(7) . . ?
C20 Dy2 C22 49.9(6) . . ?
C14 Dy2 C22 150.3(6) . . ?
C21 Dy2 C22 29.5(6) . . ?
C19 Dy2 C22 50.6(6) . . ?
C23 Dy2 C22 31.1(6) . . ?
C16 Dy2 C22 100.6(6) . . ?
C18 Dy2 C22 134.5(7) . . ?
N2 Dy2 C17 119.0(6) . . ?
N3 Dy2 C17 75.5(5) . . ?
C15 Dy2 C17 50.3(6) . . ?
C20 Dy2 C17 115.2(7) . . ?
C14 Dy2 C17 49.8(6) . . ?
C21 Dy2 C17 96.0(7) . . ?
C19 Dy2 C17 144.4(7) . . ?
C23 Dy2 C17 136.7(8) . . ?
C16 Dy2 C17 27.3(6) . . ?
C18 Dy2 C17 30.2(6) . . ?
C22 Dy2 C17 105.9(7) . . ?
N4 Dy3 N5 77.9(4) . . ?
N4 Dy3 C33 113.6(6) . . ?
N5 Dy3 C33 74.3(6) . . ?
N4 Dy3 C30 140.8(6) . . ?
N5 Dy3 C30 89.8(7) . . ?
C33 Dy3 C30 98.0(7) . . ?
N4 Dy3 C28 94.3(6) . . ?
N5 Dy3 C28 92.8(9) . . ?
C33 Dy3 C28 145.2(9) . . ?
C30 Dy3 C28 48.8(7) . . ?
N4 Dy3 C32 87.5(6) . . ?
N5 Dy3 C32 83.0(7) . . ?
C33 Dy3 C32 30.7(7) . . ?
C30 Dy3 C32 128.1(8) . . ?
C28 Dy3 C32 175.0(12) . . ?
N4 Dy3 C34 137.3(6) . . ?
N5 Dy3 C34 99.6(7) . . ?
C33 Dy3 C34 30.6(6) . . ?
C30 Dy3 C34 81.1(8) . . ?
C28 Dy3 C34 128.3(7) . . ?
C32 Dy3 C34 50.2(7) . . ?
N4 Dy3 C36 92.0(6) . . ?
N5 Dy3 C36 111.4(7) . . ?
C33 Dy3 C36 48.3(7) . . ?
C30 Dy3 C36 126.9(8) . . ?
C28 Dy3 C36 155.7(10) . . ?
C32 Dy3 C36 28.4(7) . . ?
C34 Dy3 C36 48.6(8) . . ?
N4 Dy3 C31 137.1(6) . . ?
N5 Dy3 C31 117.9(7) . . ?
C33 Dy3 C31 109.1(8) . . ?
C30 Dy3 C31 28.6(6) . . ?
C28 Dy3 C31 48.4(6) . . ?
C32 Dy3 C31 131.6(7) . . ?
C34 Dy3 C31 82.2(7) . . ?
C36 Dy3 C31 114.5(7) . . ?
N4 Dy3 C35 121.7(7) . . ?
N5 Dy3 C35 124.1(6) . . ?
C33 Dy3 C35 49.8(7) . . ?
C30 Dy3 C35 96.2(8) . . ?
C28 Dy3 C35 131.1(7) . . ?
C32 Dy3 C35 50.6(7) . . ?
C34 Dy3 C35 28.7(7) . . ?
C36 Dy3 C35 31.5(7) . . ?
C31 Dy3 C35 84.1(7) . . ?
N4 Dy3 C27 108.0(7) . . ?
N5 Dy3 C27 121.4(6) . . ?
C33 Dy3 C27 137.9(8) . . ?
C30 Dy3 C27 48.4(7) . . ?
C28 Dy3 C27 30.1(7) . . ?
C32 Dy3 C27 152.8(8) . . ?
C34 Dy3 C27 109.2(8) . . ?
C36 Dy3 C27 126.1(8) . . ?
C31 Dy3 C27 29.1(7) . . ?
C35 Dy3 C27 102.5(8) . . ?
N4 Dy3 C29 112.7(8) . . ?
N5 Dy3 C29 74.6(5) . . ?
C33 Dy3 C29 115.7(9) . . ?
C30 Dy3 C29 28.7(7) . . ?
C28 Dy3 C29 30.1(8) . . ?
C32 Dy3 C29 145.1(10) . . ?
C34 Dy3 C29 107.4(10) . . ?
C36 Dy3 C29 155.3(9) . . ?
C31 Dy3 C29 47.2(6) . . ?
C35 Dy3 C29 124.8(9) . . ?
C27 Dy3 C29 48.7(7) . . ?
N6 Dy4 N7 84.1(4) . . ?
N6 Dy4 C48 118.1(10) . . ?
N7 Dy4 C48 129.3(12) . . ?
N6 Dy4 C44 136.3(7) . . ?
N7 Dy4 C44 107.4(7) . . ?
C48 Dy4 C44 87.5(10) . . ?
N6 Dy4 C45 119.1(8) . . ?
N7 Dy4 C45 77.4(8) . . ?
C48 Dy4 C45 51.9(13) . . ?
C44 Dy4 C45 104.7(10) . . ?
N6 Dy4 C42 85.4(6) . . ?
N7 Dy4 C42 111.9(7) . . ?
C48 Dy4 C42 114.7(11) . . ?
C44 Dy4 C42 50.9(8) . . ?
C45 Dy4 C42 155.1(10) . . ?
N6 Dy4 C49 138.3(8) . . ?
N7 Dy4 C49 103.4(13) . . ?
C48 Dy4 C49 29.6(12) . . ?
C44 Dy4 C49 81.2(11) . . ?
C45 Dy4 C49 30.9(12) . . ?
C42 Dy4 C49 126.5(12) . . ?
N6 Dy4 C43 110.4(6) . . ?
N7 Dy4 C43 129.4(6) . . ?
C48 Dy4 C43 87.4(11) . . ?
C44 Dy4 C43 31.0(7) . . ?
C45 Dy4 C43 126.2(10) . . ?
C42 Dy4 C43 30.2(6) . . ?
C49 Dy4 C43 96.3(13) . . ?
N6 Dy4 C40 118.7(6) . . ?
N7 Dy4 C40 79.7(6) . . ?
C48 Dy4 C40 117.8(9) . . ?
C44 Dy4 C40 32.0(7) . . ?
C45 Dy4 C40 114.1(9) . . ?
C42 Dy4 C40 49.2(8) . . ?
C49 Dy4 C40 103.0(9) . . ?
C43 Dy4 C40 50.4(7) . . ?
N6 Dy4 C41 90.7(6) . . ?
N7 Dy4 C41 84.8(6) . . ?
C48 Dy4 C41 134.8(9) . . ?
C44 Dy4 C41 50.4(7) . . ?
C45 Dy4 C41 142.8(9) . . ?
C42 Dy4 C41 28.4(7) . . ?
C49 Dy4 C41 130.6(9) . . ?
C43 Dy4 C41 48.5(7) . . ?
C40 Dy4 C41 29.5(7) . . ?
N6 Dy4 C47 90.1(6) . . ?
N7 Dy4 C47 114.3(8) . . ?
C48 Dy4 C47 32.6(9) . . ?
C44 Dy4 C47 120.0(8) . . ?
C45 Dy4 C47 49.8(9) . . ?
C42 Dy4 C47 132.7(10) . . ?
C49 Dy4 C47 49.1(9) . . ?
C43 Dy4 C47 113.8(9) . . ?
C40 Dy4 C47 149.9(7) . . ?
C41 Dy4 C47 160.9(10) . . ?
N6 Dy4 C46 91.4(6) . . ?
N7 Dy4 C46 85.4(7) . . ?
C48 Dy4 C46 51.8(11) . . ?
C44 Dy4 C46 130.7(8) . . ?
C45 Dy4 C46 30.4(7) . . ?
C42 Dy4 C46 161.9(9) . . ?
C49 Dy4 C46 49.5(10) . . ?
C43 Dy4 C46 139.2(8) . . ?
C40 Dy4 C46 144.3(9) . . ?
C41 Dy4 C46 169.6(9) . . ?
C47 Dy4 C46 29.3(8) . . ?
C11 N1 C12 100.6(10) . . ?
C11 N1 Dy1 124.4(8) . . ?
C12 N1 Dy1 133.0(8) . . ?
C11 N2 C13 102.3(11) . . ?
C11 N2 Dy2 125.1(8) . . ?
C13 N2 Dy2 132.4(9) . . ?
C24 N3 C25 102.7(13) . . ?
C24 N3 Dy2 131.0(10) . . ?
C25 N3 Dy2 124.3(10) . . ?
C24 N4 C26 102.4(12) . . ?
C24 N4 Dy3 127.0(9) . . ?
C26 N4 Dy3 130.3(10) . . ?
C37 N5 C38 101.9(13) . . ?
C37 N5 Dy3 124.5(11) . . ?
C38 N5 Dy3 131.4(9) . . ?
C39 N6 C37 102.0(12) . . ?
C39 N6 Dy4 130.9(10) . . ?
C37 N6 Dy4 126.4(9) . . ?
C50 N7 C52 102.7(12) . . ?
C50 N7 Dy4 125.4(9) . . ?
C52 N7 Dy4 130.3(9) . . ?
C50 N8 C51 103.5(12) . . ?
C50 N8 Dy1 124.5(9) . . ?
C51 N8 Dy1 131.8(10) . . ?
C56 O1 C53 104.8(15) . . ?
C56 O1 Dy1 128.3(12) . . ?
C53 O1 Dy1 125.2(10) . . ?
C57 O2 C60 101.5(17) . . ?
C57 O2 Dy2 131.4(12) . . ?
C60 O2 Dy2 126.3(12) . . ?
C64 O3 C61 104.0(19) . . ?
C64 O3 Dy3 132.0(15) . . ?
C61 O3 Dy3 123.8(15) . . ?
C68 O4 C65 106.1(13) . . ?
C68 O4 Dy4 124(3) . . ?
C65 O4 Dy4 129(3) . . ?
C72 O5 C69 106.6(12) . . ?
C2 C1 C5 104.8(17) . . ?
C2 C1 Dy1 74.7(10) . . ?
C5 C1 Dy1 73.1(9) . . ?
C3 C2 C1 108.3(19) . . ?
C3 C2 Dy1 75.6(10) . . ?
C1 C2 Dy1 74.3(9) . . ?
C4 C3 C2 111.4(18) . . ?
C4 C3 Dy1 75.1(10) . . ?
C2 C3 Dy1 74.3(10) . . ?
C3 C4 C5 106.5(18) . . ?
C3 C4 Dy1 75.3(10) . . ?
C5 C4 Dy1 72.8(9) . . ?
C4 C5 C1 109.1(18) . . ?
C4 C5 Dy1 76.2(9) . . ?
C1 C5 Dy1 75.1(10) . . ?
C7 C6 C10 103.6(17) . . ?
C7 C6 Dy1 71.7(10) . . ?
C10 C6 Dy1 73.6(9) . . ?
C8 C7 C6 109.2(18) . . ?
C8 C7 Dy1 75.7(10) . . ?
C6 C7 Dy1 77.8(11) . . ?
C7 C8 C9 111.0(17) . . ?
C7 C8 Dy1 75.0(11) . . ?
C9 C8 Dy1 75.6(9) . . ?
C10 C9 C8 104.9(16) . . ?
C10 C9 Dy1 76.2(9) . . ?
C8 C9 Dy1 73.7(9) . . ?
C9 C10 C6 111.2(16) . . ?
C9 C10 Dy1 74.5(8) . . ?
C6 C10 Dy1 75.5(9) . . ?
N1 C11 N2 116.4(11) . . ?
C13 C12 N1 111.7(12) . . ?
C12 C13 N2 108.9(13) . . ?
C18 C14 C15 108.8(18) . . ?
C18 C14 Dy2 76.7(10) . . ?
C15 C14 Dy2 74.0(11) . . ?
C14 C15 C16 103.4(17) . . ?
C14 C15 Dy2 75.6(10) . . ?
C16 C15 Dy2 75.8(10) . . ?
C17 C16 C15 111.7(19) . . ?
C17 C16 Dy2 79.2(11) . . ?
C15 C16 Dy2 72.0(9) . . ?
C16 C17 C18 107(2) . . ?
C16 C17 Dy2 73.5(11) . . ?
C18 C17 Dy2 72.7(10) . . ?
C14 C18 C17 109.1(18) . . ?
C14 C18 Dy2 73.5(10) . . ?
C17 C18 Dy2 77.0(10) . . ?
C20 C19 C23 107.3(18) . . ?
C20 C19 Dy2 73.8(10) . . ?
C23 C19 Dy2 75.1(10) . . ?
C21 C20 C19 108(2) . . ?
C21 C20 Dy2 75.6(10) . . ?
C19 C20 Dy2 75.9(11) . . ?
C22 C21 C20 111.0(19) . . ?
C22 C21 Dy2 77.9(10) . . ?
C20 C21 Dy2 74.3(10) . . ?
C21 C22 C23 104.6(19) . . ?
C21 C22 Dy2 72.6(10) . . ?
C23 C22 Dy2 72.5(9) . . ?
C19 C23 C22 108.6(19) . . ?
C19 C23 Dy2 74.8(10) . . ?
C22 C23 Dy2 76.4(10) . . ?
N3 C24 N4 118.3(13) . . ?
C26 C25 N3 108.0(13) . . ?
C25 C26 N4 108.6(13) . . ?
C31 C27 C28 106(2) . . ?
C31 C27 Dy3 75.3(12) . . ?
C28 C27 Dy3 73.8(11) . . ?
C29 C28 C27 106(2) . . ?
C29 C28 Dy3 76.4(11) . . ?
C27 C28 Dy3 76.1(12) . . ?
C30 C29 C28 108(2) . . ?
C30 C29 Dy3 74.2(11) . . ?
C28 C29 Dy3 73.6(13) . . ?
C31 C30 C29 109(2) . . ?
C31 C30 Dy3 76.7(13) . . ?
C29 C30 Dy3 77.2(12) . . ?
C30 C31 C27 110(2) . . ?
C30 C31 Dy3 74.7(11) . . ?
C27 C31 Dy3 75.6(12) . . ?
C36 C32 C33 107(2) . . ?
C36 C32 Dy3 76.5(12) . . ?
C33 C32 Dy3 74.0(11) . . ?
C34 C33 C32 107(2) . . ?
C34 C33 Dy3 75.7(11) . . ?
C32 C33 Dy3 75.3(11) . . ?
C35 C34 C33 110(2) . . ?
C35 C34 Dy3 76.1(12) . . ?
C33 C34 Dy3 73.7(10) . . ?
C34 C35 C36 104(2) . . ?
C34 C35 Dy3 75.1(12) . . ?
C36 C35 Dy3 74.1(10) . . ?
C32 C36 C35 111(2) . . ?
C32 C36 Dy3 75.1(12) . . ?
C35 C36 Dy3 74.5(11) . . ?
N5 C37 N6 117.2(14) . . ?
N5 C37 C38 39.9(9) . . ?
N6 C37 C38 77.2(10) . . ?
N5 C38 C39 111.3(13) . . ?
N5 C38 C37 38.2(7) . . ?
C39 C38 C37 73.2(10) . . ?
N6 C39 C38 107.6(14) . . ?
C41 C40 C44 106(2) . . ?
C41 C40 Dy4 75.6(13) . . ?
C44 C40 Dy4 72.4(11) . . ?
C42 C41 C40 112(2) . . ?
C42 C41 Dy4 74.3(14) . . ?
C40 C41 Dy4 74.8(13) . . ?
C41 C42 C43 109(2) . . ?
C41 C42 Dy4 77.2(14) . . ?
C43 C42 Dy4 75.5(13) . . ?
C42 C43 C44 108(2) . . ?
C42 C43 Dy4 74.3(11) . . ?
C44 C43 Dy4 73.2(12) . . ?
C43 C44 C40 104(2) . . ?
C43 C44 Dy4 75.7(11) . . ?
C40 C44 Dy4 75.6(10) . . ?
C49 C45 C46 107(3) . . ?
C49 C45 Dy4 75.1(18) . . ?
C46 C45 Dy4 79.6(14) . . ?
C47 C46 C45 107(3) . . ?
C47 C46 Dy4 73.3(14) . . ?
C45 C46 Dy4 70.0(14) . . ?
C46 C47 C48 109(3) . . ?
C46 C47 Dy4 77.4(12) . . ?
C48 C47 Dy4 69.8(13) . . ?
C49 C48 C47 103(4) . . ?
C49 C48 Dy4 77.2(16) . . ?
C47 C48 Dy4 77.6(13) . . ?
C48 C49 C45 113(3) . . ?
C48 C49 Dy4 73.2(17) . . ?
C45 C49 Dy4 74.0(13) . . ?
N7 C50 N8 115.1(12) . . ?
C52 C51 N8 108.5(13) . . ?
C51 C52 N7 110.2(12) . . ?
O1 C53 C54 107(2) . . ?
C55 C54 C53 109(2) . . ?
C54 C55 C56 106(2) . . ?
O1 C56 C55 110(2) . . ?
O2 C57 C58 112(2) . . ?
C59 C58 C57 110(2) . . ?
C58 C59 C60 102(2) . . ?
O2 C60 C59 113.7(18) . . ?
C62 C61 O3 108(2) . . ?
C63 C62 C61 107(3) . . ?
C62 C63 C64 107(2) . . ?
O3 C64 C63 110(3) . . ?
O5 C69 C70 101.0(13) . . ?
C71 C70 C69 99.5(13) . . ?
C72 C71 C70 101.9(13) . . ?
O5 C72 C71 106.0(10) . . ?
O4 C65 C66 103.0(13) . . ?
O4 C68 C67 107.1(10) . . ?
C67 C66 C65 101.1(13) . . ?
C68 C67 C66 103.9(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 N8 2.383(11) . ?
Dy1 N1 2.419(11) . ?
Dy1 C7 2.633(18) . ?
Dy1 O1 2.639(10) . ?
Dy1 C8 2.642(16) . ?
Dy1 C5 2.653(15) . ?
Dy1 C9 2.666(14) . ?
Dy1 C1 2.680(17) . ?
Dy1 C2 2.685(15) . ?
Dy1 C10 2.686(13) . ?
Dy1 C4 2.698(16) . ?
Dy1 C3 2.701(17) . ?
Dy2 N2 2.362(11) . ?
Dy2 N3 2.489(13) . ?
Dy2 C15 2.630(17) . ?
Dy2 C20 2.637(18) . ?
Dy2 C14 2.651(16) . ?
Dy2 C21 2.653(15) . ?
Dy2 C19 2.663(18) . ?
Dy2 C23 2.667(17) . ?
Dy2 C16 2.681(16) . ?
Dy2 C18 2.690(16) . ?
Dy2 C22 2.718(17) . ?
Dy2 C17 2.746(17) . ?
Dy3 N4 2.417(11) . ?
Dy3 N5 2.462(12) . ?
Dy3 C33 2.642(17) . ?
Dy3 C30 2.651(18) . ?
Dy3 C28 2.652(19) . ?
Dy3 C32 2.658(19) . ?
Dy3 C34 2.668(18) . ?
Dy3 C36 2.674(18) . ?
Dy3 C31 2.675(19) . ?
Dy3 C35 2.680(19) . ?
Dy3 C27 2.680(19) . ?
Dy3 C29 2.687(19) . ?
Dy4 N6 2.365(11) . ?
Dy4 N7 2.392(12) . ?
Dy4 C48 2.57(2) . ?
Dy4 C44 2.600(18) . ?
Dy4 C45 2.61(3) . ?
Dy4 C42 2.62(2) . ?
Dy4 C49 2.62(2) . ?
Dy4 C43 2.632(18) . ?
Dy4 C40 2.64(2) . ?
Dy4 C41 2.65(2) . ?
Dy4 C47 2.68(2) . ?
Dy4 C46 2.73(2) . ?
N1 C11 1.351(16) . ?
N1 C12 1.403(16) . ?
N2 C11 1.368(15) . ?
N2 C13 1.393(18) . ?
N3 C24 1.256(17) . ?
N3 C25 1.421(18) . ?
N4 C24 1.319(17) . ?
N4 C26 1.387(19) . ?
N5 C37 1.285(17) . ?
N5 C38 1.34(2) . ?
N6 C39 1.346(19) . ?
N6 C37 1.347(18) . ?
N7 C50 1.342(17) . ?
N7 C52 1.364(18) . ?
N8 C50 1.345(17) . ?
N8 C51 1.366(18) . ?
O1 C56 1.40(2) . ?
O1 C53 1.43(2) . ?
O2 C57 1.33(2) . ?
O2 C60 1.41(2) . ?
O3 C64 1.42(2) . ?
O3 C61 1.47(3) . ?
O4 C68 1.456(10) . ?
O4 C65 1.467(10) . ?
O5 C72 1.454(10) . ?
O5 C69 1.459(10) . ?
C1 C2 1.44(3) . ?
C1 C5 1.46(3) . ?
C2 C3 1.40(3) . ?
C3 C4 1.38(3) . ?
C4 C5 1.43(3) . ?
C6 C7 1.41(3) . ?
C6 C10 1.44(2) . ?
C7 C8 1.34(3) . ?
C8 C9 1.41(3) . ?
C9 C10 1.35(2) . ?
C12 C13 1.339(19) . ?
C14 C18 1.37(3) . ?
C14 C15 1.38(3) . ?
C15 C16 1.48(3) . ?
C16 C17 1.28(3) . ?
C17 C18 1.42(3) . ?
C19 C20 1.38(3) . ?
C19 C23 1.39(3) . ?
C20 C21 1.37(3) . ?
C21 C22 1.37(3) . ?
C22 C23 1.44(3) . ?
C25 C26 1.33(2) . ?
C27 C31 1.35(3) . ?
C27 C28 1.38(3) . ?
C28 C29 1.39(4) . ?
C29 C30 1.32(3) . ?
C30 C31 1.32(3) . ?
C32 C36 1.31(3) . ?
C32 C33 1.40(3) . ?
C33 C34 1.40(3) . ?
C34 C35 1.33(3) . ?
C35 C36 1.45(3) . ?
C37 C38 2.04(2) . ?
C38 C39 1.35(2) . ?
C40 C41 1.35(3) . ?
C40 C44 1.45(3) . ?
C41 C42 1.29(3) . ?
C42 C43 1.37(3) . ?
C43 C44 1.40(3) . ?
C45 C49 1.39(5) . ?
C45 C46 1.40(3) . ?
C46 C47 1.37(4) . ?
C47 C48 1.48(4) . ?
C48 C49 1.33(5) . ?
C51 C52 1.36(2) . ?
C53 C54 1.44(3) . ?
C54 C55 1.39(3) . ?
C55 C56 1.42(3) . ?
C57 C58 1.41(3) . ?
C58 C59 1.34(3) . ?
C59 C60 1.42(3) . ?
C61 C62 1.48(3) . ?
C62 C63 1.41(4) . ?
C63 C64 1.47(4) . ?
C69 C70 1.502(10) . ?
C70 C71 1.499(11) . ?
C71 C72 1.496(10) . ?
C65 C66 1.502(10) . ?
C68 C67 1.494(10) . ?
C66 C67 1.495(10) . ?
