#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:29:17 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179113 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/75/4307582.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4307582
loop_
_publ_author_name
'Samuel J. Mugavero'
'Mark D. Smith'
'Hans-Conrad zur Loye'
_publ_contact_author_address
;
Department of Chemistry and Biochemistry
University of South Carolina
Columbia, SC  29208
USA
;
_publ_contact_author_email       zurloye@sc.edu
_publ_contact_author_fax         '803 777 8508'
_publ_contact_author_name        'Professor Hans-Conrad zur Loye'
_publ_contact_author_phone       '803 777 6916'
_publ_section_title
;
Crystal Growth and Structural Characterization of the New Ordered
Palladates LnKPdO3 (Ln = La, Pr, Nd, Sm-Gd) and the Isostructural,
Partially Cu-Substituted Palladate PrK(Cu0.14Pd0.86)O3
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3116
_journal_page_last               3122
_journal_paper_doi               10.1021/ic062066m
_journal_volume                  46
_journal_year                    2007
_chemical_formula_moiety         'Eu K O3 Pd'
_chemical_formula_sum            'Eu K O3 Pd'
_chemical_formula_weight         345.46
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 104.5620(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.0582(5)
_cell_length_b                   3.9198(2)
_cell_length_c                   7.3298(3)
_cell_measurement_reflns_used    2748
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      32.524
_cell_measurement_theta_min      2.871
_cell_volume                     363.13(3)
_computing_cell_refinement       'SAINT+ NT V6.22 (Bruker, 2001)'
_computing_data_collection       'SMART NT V5.625 (Bruker, 1998)'
_computing_data_reduction        'SAINT+ NT V6.22'
_computing_molecular_graphics    'SHELXTL V6.1 (Sheldrick, 2000)'
_computing_publication_material  'SHELXTL V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD diffractometer'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0303
_diffrn_reflns_av_sigmaI/netI    0.0207
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       5
_diffrn_reflns_limit_k_min       -5
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            4069
_diffrn_reflns_theta_full        32.57
_diffrn_reflns_theta_max         32.57
_diffrn_reflns_theta_min         2.87
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    23.030
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.4766
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS, Bruker, 2001)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    6.319
_exptl_crystal_density_meas      6.32
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.958
_refine_diff_density_min         -2.974
_refine_diff_density_rms         0.379
_refine_ls_extinction_coef       0.0023(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.148
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     38
_refine_ls_number_reflns         743
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.148
_refine_ls_R_factor_all          0.0248
_refine_ls_R_factor_gt           0.0239
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0382P)²+0.9027P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0602
_refine_ls_wR_factor_ref         0.0607
_reflns_number_gt                724
_reflns_number_total             743
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic062066msi20061029_032921.cif
_cod_data_source_block           EuKPdO3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4307582
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.650419(19) 0.0000 0.07738(3) 0.00924(12) Uani 1 2 d S . .
Pd1 Pd 0.00700(3) 0.0000 0.77922(6) 0.00811(12) Uani 1 2 d S . .
K1 K 0.35653(10) 0.0000 0.43613(17) 0.0153(2) Uani 1 2 d S . .
O1 O 0.8305(3) 0.0000 0.1310(6) 0.0119(7) Uani 1 2 d S . .
O2 O 0.4938(3) 0.0000 0.1946(6) 0.0135(7) Uani 1 2 d S . .
O3 O 0.1523(3) 0.0000 0.2740(6) 0.0115(7) Uani 1 2 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O2 135.18(14) . 5_655 ?
O1 Eu1 O2 150.24(14) . . ?
O2 Eu1 O2 74.59(16) 5_655 . ?
O1 Eu1 O3 92.37(11) . 3 ?
O2 Eu1 O3 112.71(10) 5_655 3 ?
O2 Eu1 O3 70.82(10) . 3 ?
O1 Eu1 O3 92.37(11) . 3_545 ?
O2 Eu1 O3 112.71(10) 5_655 3_545 ?
O2 Eu1 O3 70.82(10) . 3_545 ?
O3 Eu1 O3 107.56(16) 3 3_545 ?
O1 Eu1 O1 81.42(11) . 7_645 ?
O2 Eu1 O1 70.80(10) 5_655 7_645 ?
O2 Eu1 O1 115.82(10) . 7_645 ?
O3 Eu1 O1 173.35(12) 3 7_645 ?
O3 Eu1 O1 75.28(12) 3_545 7_645 ?
O1 Eu1 O1 81.42(11) . 7_655 ?
O2 Eu1 O1 70.80(10) 5_655 7_655 ?
O2 Eu1 O1 115.82(10) . 7_655 ?
O3 Eu1 O1 75.28(12) 3 7_655 ?
O3 Eu1 O1 173.35(12) 3_545 7_655 ?
O1 Eu1 O1 101.27(14) 7_645 7_655 ?
O1 Eu1 Pd1 121.48(7) . 3_544 ?
O2 Eu1 Pd1 38.291(10) 5_655 3_544 ?
O2 Eu1 Pd1 80.71(8) . 3_544 ?
O3 Eu1 Pd1 145.42(9) 3 3_544 ?
O3 Eu1 Pd1 80.02(8) 3_545 3_544 ?
O1 Eu1 Pd1 40.34(8) 7_645 3_544 ?
O1 Eu1 Pd1 101.12(8) 7_655 3_544 ?
O1 Eu1 Pd1 121.48(7) . 3_554 ?
O2 Eu1 Pd1 38.291(9) 5_655 3_554 ?
O2 Eu1 Pd1 80.71(8) . 3_554 ?
O3 Eu1 Pd1 80.02(8) 3 3_554 ?
O3 Eu1 Pd1 145.42(9) 3_545 3_554 ?
O1 Eu1 Pd1 101.12(8) 7_645 3_554 ?
O1 Eu1 Pd1 40.34(8) 7_655 3_554 ?
Pd1 Eu1 Pd1 76.299(10) 3_544 3_554 ?
O1 Eu1 Pd1 131.41(6) . 7_546 ?
O2 Eu1 Pd1 80.60(8) 5_655 7_546 ?
O2 Eu1 Pd1 37.867(10) . 7_546 ?
O3 Eu1 Pd1 102.16(8) 3 7_546 ?
O3 Eu1 Pd1 39.04(9) 3_545 7_546 ?
O1 Eu1 Pd1 83.85(8) 7_645 7_546 ?
O1 Eu1 Pd1 147.05(9) 7_655 7_546 ?
Pd1 Eu1 Pd1 62.073(13) 3_544 7_546 ?
Pd1 Eu1 Pd1 106.718(9) 3_554 7_546 ?
O1 Eu1 Pd1 131.41(6) . 7_556 ?
O2 Eu1 Pd1 80.60(8) 5_655 7_556 ?
O2 Eu1 Pd1 37.867(10) . 7_556 ?
O3 Eu1 Pd1 39.04(9) 3 7_556 ?
O3 Eu1 Pd1 102.16(8) 3_545 7_556 ?
O1 Eu1 Pd1 147.05(9) 7_645 7_556 ?
O1 Eu1 Pd1 83.85(8) 7_655 7_556 ?
Pd1 Eu1 Pd1 106.718(9) 3_544 7_556 ?
Pd1 Eu1 Pd1 62.073(13) 3_554 7_556 ?
Pd1 Eu1 Pd1 75.460(11) 7_546 7_556 ?
O1 Eu1 K1 96.39(10) . 5_656 ?
O2 Eu1 K1 128.44(10) 5_655 5_656 ?
O2 Eu1 K1 53.85(10) . 5_656 ?
O3 Eu1 K1 53.82(8) 3 5_656 ?
O3 Eu1 K1 53.82(8) 3_545 5_656 ?
O1 Eu1 K1 128.99(7) 7_645 5_656 ?
O1 Eu1 K1 128.99(7) 7_655 5_656 ?
Pd1 Eu1 K1 121.754(15) 3_544 5_656 ?
Pd1 Eu1 K1 121.754(15) 3_554 5_656 ?
Pd1 Eu1 K1 59.696(15) 7_546 5_656 ?
Pd1 Eu1 K1 59.696(15) 7_556 5_656 ?
O2 Pd1 O2 168.7(2) 7_556 7_546 ?
O2 Pd1 O3 89.35(12) 7_556 5_556 ?
O2 Pd1 O3 89.35(12) 7_546 5_556 ?
O2 Pd1 O1 89.93(12) 7_556 5_656 ?
O2 Pd1 O1 89.93(12) 7_546 5_656 ?
O3 Pd1 O1 172.75(18) 5_556 5_656 ?
O2 Pd1 Eu1 48.30(12) 7_556 3_456 ?
O2 Pd1 Eu1 124.34(13) 7_546 3_456 ?
O3 Pd1 Eu1 122.31(8) 5_556 3_456 ?
O1 Pd1 Eu1 52.91(7) 5_656 3_456 ?
O2 Pd1 Eu1 124.34(13) 7_556 3_446 ?
O2 Pd1 Eu1 48.30(12) 7_546 3_446 ?
O3 Pd1 Eu1 122.31(8) 5_556 3_446 ?
O1 Pd1 Eu1 52.91(7) 5_656 3_446 ?
Eu1 Pd1 Eu1 76.298(10) 3_456 3_446 ?
O2 Pd1 Eu1 123.89(12) 7_556 7_546 ?
O2 Pd1 Eu1 48.68(12) 7_546 7_546 ?
O3 Pd1 Eu1 49.31(7) 5_556 7_546 ?
O1 Pd1 Eu1 126.18(8) 5_656 7_546 ?
Eu1 Pd1 Eu1 117.928(13) 3_456 7_546 ?
Eu1 Pd1 Eu1 73.283(9) 3_446 7_546 ?
O2 Pd1 Eu1 48.68(12) 7_556 7_556 ?
O2 Pd1 Eu1 123.89(12) 7_546 7_556 ?
O3 Pd1 Eu1 49.31(7) 5_556 7_556 ?
O1 Pd1 Eu1 126.18(8) 5_656 7_556 ?
Eu1 Pd1 Eu1 73.283(9) 3_456 7_556 ?
Eu1 Pd1 Eu1 117.928(13) 3_446 7_556 ?
Eu1 Pd1 Eu1 75.459(11) 7_546 7_556 ?
O2 Pd1 K1 58.19(12) 7_556 7_556 ?
O2 Pd1 K1 130.78(12) 7_546 7_556 ?
O3 Pd1 K1 124.13(9) 5_556 7_556 ?
O1 Pd1 K1 61.07(9) 5_656 7_556 ?
Eu1 Pd1 K1 70.54(2) 3_456 7_556 ?
Eu1 Pd1 K1 113.55(2) 3_446 7_556 ?
Eu1 Pd1 K1 170.84(3) 7_546 7_556 ?
Eu1 Pd1 K1 105.158(14) 7_556 7_556 ?
O2 Pd1 K1 130.78(12) 7_556 7_546 ?
O2 Pd1 K1 58.19(12) 7_546 7_546 ?
O3 Pd1 K1 124.13(9) 5_556 7_546 ?
O1 Pd1 K1 61.07(9) 5_656 7_546 ?
Eu1 Pd1 K1 113.55(2) 3_456 7_546 ?
Eu1 Pd1 K1 70.54(2) 3_446 7_546 ?
Eu1 Pd1 K1 105.158(14) 7_546 7_546 ?
Eu1 Pd1 K1 170.84(3) 7_556 7_546 ?
K1 Pd1 K1 72.74(3) 7_556 7_546 ?
O2 Pd1 K1 129.06(13) 7_556 3_445 ?
O2 Pd1 K1 58.80(12) 7_546 3_445 ?
O3 Pd1 K1 58.70(9) 5_556 3_445 ?
O1 Pd1 K1 126.50(8) 5_656 3_445 ?
Eu1 Pd1 K1 176.046(19) 3_456 3_445 ?
Eu1 Pd1 K1 106.553(13) 3_446 3_445 ?
Eu1 Pd1 K1 65.822(19) 7_546 3_445 ?
Eu1 Pd1 K1 107.25(2) 7_556 3_445 ?
K1 Pd1 K1 105.64(2) 7_556 3_445 ?
K1 Pd1 K1 65.50(4) 7_546 3_445 ?
O2 Pd1 K1 58.80(12) 7_556 3_455 ?
O2 Pd1 K1 129.06(13) 7_546 3_455 ?
O3 Pd1 K1 58.70(9) 5_556 3_455 ?
O1 Pd1 K1 126.50(8) 5_656 3_455 ?
Eu1 Pd1 K1 106.553(13) 3_456 3_455 ?
Eu1 Pd1 K1 176.046(19) 3_446 3_455 ?
Eu1 Pd1 K1 107.25(2) 7_546 3_455 ?
Eu1 Pd1 K1 65.822(19) 7_556 3_455 ?
K1 Pd1 K1 65.50(4) 7_556 3_455 ?
K1 Pd1 K1 105.64(2) 7_546 3_455 ?
K1 Pd1 K1 70.47(2) 3_445 3_455 ?
O3 K1 O2 116.65(13) . . ?
O3 K1 O2 141.85(13) . 5_656 ?
O2 K1 O2 101.51(11) . 5_656 ?
O3 K1 O3 96.18(10) . 7_556 ?
O2 K1 O3 127.31(8) . 7_556 ?
O2 K1 O3 57.52(8) 5_656 7_556 ?
O3 K1 O3 96.18(10) . 7_546 ?
O2 K1 O3 127.31(8) . 7_546 ?
O2 K1 O3 57.52(8) 5_656 7_546 ?
O3 K1 O3 84.54(11) 7_556 7_546 ?
O3 K1 O1 75.26(11) . 3_445 ?
O2 K1 O1 59.34(9) . 3_445 ?
O2 K1 O1 129.15(8) 5_656 3_445 ?
O3 K1 O1 171.35(11) 7_556 3_445 ?
O3 K1 O1 95.07(9) 7_546 3_445 ?
O3 K1 O1 75.26(11) . 3_455 ?
O2 K1 O1 59.34(9) . 3_455 ?
O2 K1 O1 129.15(8) 5_656 3_455 ?
O3 K1 O1 95.07(9) 7_556 3_455 ?
O3 K1 O1 171.35(11) 7_546 3_455 ?
O1 K1 O1 84.01(11) 3_445 3_455 ?
O3 K1 Pd1 113.02(8) . 7_556 ?
O2 K1 Pd1 36.440(14) . 7_556 ?
O2 K1 Pd1 97.31(7) 5_656 7_556 ?
O3 K1 Pd1 94.26(6) 7_556 7_556 ?
O3 K1 Pd1 150.70(9) 7_546 7_556 ?
O1 K1 Pd1 90.29(7) 3_445 7_556 ?
O1 K1 Pd1 37.94(7) 3_455 7_556 ?
O3 K1 Pd1 113.02(8) . 7_546 ?
O2 K1 Pd1 36.440(14) . 7_546 ?
O2 K1 Pd1 97.31(7) 5_656 7_546 ?
O3 K1 Pd1 150.70(9) 7_556 7_546 ?
O3 K1 Pd1 94.26(6) 7_546 7_546 ?
O1 K1 Pd1 37.94(7) 3_445 7_546 ?
O1 K1 Pd1 90.29(7) 3_455 7_546 ?
Pd1 K1 Pd1 72.74(3) 7_556 7_546 ?
O3 K1 Pd1 131.75(6) . 3 ?
O2 K1 Pd1 97.14(8) . 3 ?
O2 K1 Pd1 35.327(13) 5_656 3 ?
O3 K1 Pd1 36.28(7) 7_556 3 ?
O3 K1 Pd1 88.28(7) 7_546 3 ?
O1 K1 Pd1 152.35(9) 3_445 3 ?
O1 K1 Pd1 96.53(6) 3_455 3 ?
Pd1 K1 Pd1 74.36(2) 7_556 3 ?
Pd1 K1 Pd1 114.50(4) 7_546 3 ?
O3 K1 Pd1 131.75(6) . 3_545 ?
O2 K1 Pd1 97.14(8) . 3_545 ?
O2 K1 Pd1 35.327(13) 5_656 3_545 ?
O3 K1 Pd1 88.28(7) 7_556 3_545 ?
O3 K1 Pd1 36.28(7) 7_546 3_545 ?
O1 K1 Pd1 96.53(6) 3_445 3_545 ?
O1 K1 Pd1 152.35(9) 3_455 3_545 ?
Pd1 K1 Pd1 114.50(4) 7_556 3_545 ?
Pd1 K1 Pd1 74.36(2) 7_546 3_545 ?
Pd1 K1 Pd1 70.47(2) 3 3_545 ?
O3 K1 Eu1 99.94(10) . 5_656 ?
O2 K1 Eu1 143.41(10) . 5_656 ?
O2 K1 Eu1 41.91(8) 5_656 5_656 ?
O3 K1 Eu1 42.29(6) 7_556 5_656 ?
O3 K1 Eu1 42.29(6) 7_546 5_656 ?
O1 K1 Eu1 137.02(6) 3_445 5_656 ?
O1 K1 Eu1 137.02(6) 3_455 5_656 ?
Pd1 K1 Eu1 128.74(3) 7_556 5_656 ?
Pd1 K1 Eu1 128.74(3) 7_546 5_656 ?
Pd1 K1 Eu1 54.482(18) 3 5_656 ?
Pd1 K1 Eu1 54.482(18) 3_545 5_656 ?
Pd1 O1 Eu1 171.5(2) 5_656 . ?
Pd1 O1 Eu1 86.75(11) 5_656 7_645 ?
Eu1 O1 Eu1 98.58(11) . 7_645 ?
Pd1 O1 Eu1 86.75(11) 5_656 7_655 ?
Eu1 O1 Eu1 98.58(11) . 7_655 ?
Eu1 O1 Eu1 101.27(14) 7_645 7_655 ?
Pd1 O1 K1 80.99(10) 5_656 3 ?
Eu1 O1 K1 92.75(11) . 3 ?
Eu1 O1 K1 165.32(15) 7_645 3 ?
Eu1 O1 K1 86.14(3) 7_655 3 ?
Pd1 O1 K1 80.99(10) 5_656 3_545 ?
Eu1 O1 K1 92.75(11) . 3_545 ?
Eu1 O1 K1 86.14(3) 7_645 3_545 ?
Eu1 O1 K1 165.32(15) 7_655 3_545 ?
K1 O1 K1 84.01(11) 3 3_545 ?
Pd1 O2 Pd1 168.7(2) 7_556 7_546 ?
Pd1 O2 Eu1 93.41(12) 7_556 5_655 ?
Pd1 O2 Eu1 93.41(12) 7_546 5_655 ?
Pd1 O2 Eu1 93.45(12) 7_556 . ?
Pd1 O2 Eu1 93.45(12) 7_546 . ?
Eu1 O2 Eu1 105.41(16) 5_655 . ?
Pd1 O2 K1 85.37(12) 7_556 . ?
Pd1 O2 K1 85.37(12) 7_546 . ?
Eu1 O2 K1 91.85(13) 5_655 . ?
Eu1 O2 K1 162.74(19) . . ?
Pd1 O2 K1 85.88(12) 7_556 5_656 ?
Pd1 O2 K1 85.88(12) 7_546 5_656 ?
Eu1 O2 K1 170.34(18) 5_655 5_656 ?
Eu1 O2 K1 84.25(12) . 5_656 ?
K1 O2 K1 78.49(11) . 5_656 ?
Pd1 O3 Eu1 91.66(11) 5_556 3_445 ?
Pd1 O3 Eu1 91.66(11) 5_556 3_455 ?
Eu1 O3 Eu1 107.56(16) 3_445 3_455 ?
Pd1 O3 K1 164.9(2) 5_556 . ?
Eu1 O3 K1 97.24(10) 3_445 . ?
Eu1 O3 K1 97.24(10) 3_455 . ?
Pd1 O3 K1 85.01(11) 5_556 7_556 ?
Eu1 O3 K1 168.19(14) 3_445 7_556 ?
Eu1 O3 K1 83.89(3) 3_455 7_556 ?
K1 O3 K1 83.82(10) . 7_556 ?
Pd1 O3 K1 85.01(11) 5_556 7_546 ?
Eu1 O3 K1 83.89(3) 3_445 7_546 ?
Eu1 O3 K1 168.19(14) 3_455 7_546 ?
K1 O3 K1 83.82(10) . 7_546 ?
K1 O3 K1 84.53(11) 7_556 7_546 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.285(4) . ?
Eu1 O2 2.373(4) 5_655 ?
Eu1 O2 2.410(4) . ?
Eu1 O3 2.429(2) 3 ?
Eu1 O3 2.429(2) 3_545 ?
Eu1 O1 2.535(3) 7_645 ?
Eu1 O1 2.535(3) 7_655 ?
Eu1 Pd1 3.1728(4) 3_544 ?
Eu1 Pd1 3.1728(4) 3_554 ?
Eu1 Pd1 3.2028(4) 7_546 ?
Eu1 Pd1 3.2028(4) 7_556 ?
Eu1 K1 3.5897(12) 5_656 ?
Pd1 O2 1.9695(4) 7_556 ?
Pd1 O2 1.9695(4) 7_546 ?
Pd1 O3 2.018(4) 5_556 ?
Pd1 O1 2.057(4) 5_656 ?
Pd1 Eu1 3.1728(4) 3_456 ?
Pd1 Eu1 3.1728(4) 3_446 ?
Pd1 Eu1 3.2028(4) 7_546 ?
Pd1 Eu1 3.2028(4) 7_556 ?
Pd1 K1 3.3050(10) 7_556 ?
Pd1 K1 3.3050(10) 7_546 ?
Pd1 K1 3.3973(10) 3_445 ?
Pd1 K1 3.3973(10) 3_455 ?
K1 O3 2.632(4) . ?
K1 O2 2.818(4) . ?
K1 O2 2.913(4) 5_656 ?
K1 O3 2.914(3) 7_556 ?
K1 O3 2.914(3) 7_546 ?
K1 O1 2.929(3) 3_445 ?
K1 O1 2.929(3) 3_455 ?
K1 Pd1 3.3050(10) 7_556 ?
K1 Pd1 3.3050(10) 7_546 ?
K1 Pd1 3.3972(10) 3 ?
K1 Pd1 3.3972(10) 3_545 ?
K1 Eu1 3.5897(12) 5_656 ?
O1 Pd1 2.057(4) 5_656 ?
O1 Eu1 2.535(3) 7_645 ?
O1 Eu1 2.535(3) 7_655 ?
O1 K1 2.929(3) 3 ?
O1 K1 2.929(3) 3_545 ?
O2 Pd1 1.9695(4) 7_556 ?
O2 Pd1 1.9695(4) 7_546 ?
O2 Eu1 2.373(4) 5_655 ?
O2 K1 2.913(4) 5_656 ?
O3 Pd1 2.018(4) 5_556 ?
O3 Eu1 2.429(2) 3_445 ?
O3 Eu1 2.429(2) 3_455 ?
O3 K1 2.914(3) 7_556 ?
O3 K1 2.914(3) 7_546 ?
