#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:33:25 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179116 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/78/4307878.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4307878
loop_
_publ_author_name
'Kieran Norton'
'Thomas J. Emge'
'John G. Brennan'
_publ_section_title
;
Lanthanide Compounds with Fluorinated OC6F5 Ligands: Homo- and
Heterovalent Complexes of Eu(II) and Eu(III)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4060
_journal_page_last               4066
_journal_paper_doi               10.1021/ic062395e
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C26 H20 Eu F15 O7'
_chemical_formula_weight         881.38
_chemical_name_systematic
; 

 ? 

;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.058(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.4086(5)
_cell_length_b                   12.8244(6)
_cell_length_c                   23.4796(11)
_cell_measurement_reflns_used    7891
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.54
_cell_measurement_theta_min      2.36
_cell_volume                     3116.6(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0180
_diffrn_reflns_av_sigmaI/netI    0.0195
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            31618
_diffrn_reflns_theta_full        30.56
_diffrn_reflns_theta_max         30.56
_diffrn_reflns_theta_min         1.81
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.145
_exptl_absorpt_correction_T_max  0.9999
_exptl_absorpt_correction_T_min  0.8815
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SAINT (SADABS)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.878
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       lathe
_exptl_crystal_F_000             1720
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.889
_refine_diff_density_min         -0.799
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.001
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     446
_refine_ls_number_reflns         9519
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.001
_refine_ls_R_factor_all          0.0237
_refine_ls_R_factor_gt           0.0212
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0250P)²+2.6000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0512
_refine_ls_wR_factor_ref         0.0524
_reflns_number_gt                8764
_reflns_number_total             9519
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic062395e-file003.cif
_cod_data_source_block           kieran
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4307878
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.321103(7) 0.802685(6) 0.065927(3) 0.01480(3) Uani 1 1 d . . .
O1 O 0.47822(13) 0.88869(10) 0.11590(5) 0.0270(3) Uani 1 1 d . . .
F1 F 0.35771(11) 1.01360(11) 0.18934(6) 0.0405(3) Uani 1 1 d . . .
F2 F 0.49525(14) 1.14095(11) 0.26355(6) 0.0441(3) Uani 1 1 d . . .
F3 F 0.75902(14) 1.13954(10) 0.27255(5) 0.0398(3) Uani 1 1 d . . .
F4 F 0.88095(11) 1.01252(11) 0.20307(5) 0.0357(3) Uani 1 1 d . . .
F5 F 0.74531(12) 0.88995(10) 0.12534(5) 0.0346(3) Uani 1 1 d . . .
C1 C 0.54543(16) 0.94878(13) 0.15321(7) 0.0203(3) Uani 1 1 d . . .
C2 C 0.48768(16) 1.01411(14) 0.19075(8) 0.0243(3) Uani 1 1 d . . .
C3 C 0.55711(19) 1.07816(14) 0.22993(8) 0.0265(4) Uani 1 1 d . . .
C4 C 0.68992(19) 1.07766(14) 0.23444(7) 0.0258(4) Uani 1 1 d . . .
C5 C 0.75106(16) 1.01373(15) 0.19878(7) 0.0235(3) Uani 1 1 d . . .
C6 C 0.68060(17) 0.95134(14) 0.15892(7) 0.0217(3) Uani 1 1 d . . .
O2 O 0.37262(11) 0.81942(9) -0.02410(5) 0.0196(2) Uani 1 1 d . . .
F6 F 0.12151(10) 0.87187(8) -0.05999(4) 0.0250(2) Uani 1 1 d . . .
F7 F 0.00006(11) 0.79495(9) -0.15817(5) 0.0285(2) Uani 1 1 d . . .
F8 F 0.12712(12) 0.66487(10) -0.22514(5) 0.0347(3) Uani 1 1 d . . .
F9 F 0.38009(13) 0.61739(11) -0.19313(5) 0.0400(3) Uani 1 1 d . . .
F10 F 0.50232(11) 0.69398(10) -0.09542(5) 0.0327(3) Uani 1 1 d . . .
C7 C 0.31660(15) 0.78609(12) -0.07346(7) 0.0177(3) Uani 1 1 d . . .
C8 C 0.18818(16) 0.81038(12) -0.09308(7) 0.0184(3) Uani 1 1 d . . .
C9 C 0.12474(16) 0.77081(13) -0.14298(7) 0.0210(3) Uani 1 1 d . . .
C10 C 0.18854(19) 0.70525(14) -0.17691(8) 0.0242(3) Uani 1 1 d . . .
C11 C 0.31647(19) 0.68123(15) -0.16036(8) 0.0260(3) Uani 1 1 d . . .
C12 C 0.37861(16) 0.72143(14) -0.11027(8) 0.0229(3) Uani 1 1 d . . .
O3 O 0.16377(12) 0.69186(9) 0.03486(5) 0.0218(2) Uani 1 1 d . . .
F11 F -0.09472(10) 0.73551(9) 0.00438(5) 0.0290(2) Uani 1 1 d . . .
F12 F -0.22374(10) 0.64236(11) -0.08703(6) 0.0369(3) Uani 1 1 d . . .
F13 F -0.10343(12) 0.49993(10) -0.15017(5) 0.0363(3) Uani 1 1 d . . .
F14 F 0.14866(12) 0.45117(10) -0.11863(5) 0.0355(3) Uani 1 1 d . . .
F15 F 0.27978(10) 0.54542(9) -0.02693(5) 0.0306(2) Uani 1 1 d . . .
C13 C 0.09805(15) 0.64335(12) -0.00776(7) 0.0183(3) Uani 1 1 d . . .
C14 C -0.03280(15) 0.66409(13) -0.02495(7) 0.0200(3) Uani 1 1 d . . .
C15 C -0.09945(16) 0.61676(14) -0.07193(8) 0.0236(3) Uani 1 1 d . . .
C16 C -0.03979(17) 0.54484(14) -0.10375(8) 0.0242(3) Uani 1 1 d . . .
C17 C 0.08806(17) 0.52030(14) -0.08767(8) 0.0235(3) Uani 1 1 d . . .
C18 C 0.15375(15) 0.56811(13) -0.04072(7) 0.0206(3) Uani 1 1 d . . .
O4 O 0.14018(12) 0.86228(9) 0.11946(5) 0.0219(2) Uani 1 1 d . . .
O5 O 0.24341(11) 0.97986(9) 0.04225(5) 0.0213(2) Uani 1 1 d . . .
C19 C 0.0577(2) 0.78878(16) 0.14472(9) 0.0323(4) Uani 1 1 d . . .
H19A H 0.0216 0.8211 0.1763 0.048 Uiso 1 1 calc R . .
H19B H 0.1075 0.7289 0.1581 0.048 Uiso 1 1 calc R . .
H19C H -0.0107 0.7674 0.1165 0.048 Uiso 1 1 calc R . .
C20 C 0.06564(18) 0.94754(15) 0.09397(8) 0.0279(4) Uani 1 1 d . . .
H20A H 0.0107 0.9759 0.1211 0.033 Uiso 1 1 calc R . .
H20B H 0.0111 0.9237 0.0604 0.033 Uiso 1 1 calc R . .
C21 C 0.15725(17) 1.02977(14) 0.07728(8) 0.0236(3) Uani 1 1 d . . .
H21A H 0.1101 1.0852 0.0561 0.028 Uiso 1 1 calc R . .
H21B H 0.2051 1.0595 0.1111 0.028 Uiso 1 1 calc R . .
C22 C 0.32490(19) 1.05369(15) 0.01747(10) 0.0333(4) Uani 1 1 d . . .
H22A H 0.2724 1.1057 -0.0032 0.050 Uiso 1 1 calc R . .
H22B H 0.3759 1.0183 -0.0083 0.050 Uiso 1 1 calc R . .
H22C H 0.3809 1.0865 0.0473 0.050 Uiso 1 1 calc R . .
O6 O 0.49121(11) 0.66767(10) 0.06331(5) 0.0217(2) Uani 1 1 d . . .
O7 O 0.33763(13) 0.68107(10) 0.14891(5) 0.0251(3) Uani 1 1 d . . .
C23 C 0.60931(18) 0.69009(15) 0.03865(9) 0.0280(4) Uani 1 1 d . . .
H23A H 0.6741 0.7127 0.0682 0.042 Uiso 1 1 calc R . .
H23B H 0.5939 0.7441 0.0105 0.042 Uiso 1 1 calc R . .
H23C H 0.6386 0.6283 0.0208 0.042 Uiso 1 1 calc R . .
C24 C 0.51020(19) 0.59137(16) 0.10768(9) 0.0303(4) Uani 1 1 d . . .
H24A H 0.5763 0.6141 0.1373 0.036 Uiso 1 1 calc R . .
H24B H 0.5366 0.5254 0.0924 0.036 Uiso 1 1 calc R . .
C25 C 0.38303(19) 0.58021(15) 0.13133(9) 0.0289(4) Uani 1 1 d . . .
H25A H 0.3203 0.5504 0.1024 0.035 Uiso 1 1 calc R . .
H25B H 0.3922 0.5334 0.1639 0.035 Uiso 1 1 calc R . .
C26 C 0.3870(3) 0.7097(2) 0.20588(9) 0.0440(6) Uani 1 1 d . . .
H26A H 0.3621 0.6583 0.2323 0.066 Uiso 1 1 calc R . .
H26B H 0.3527 0.7763 0.2151 0.066 Uiso 1 1 calc R . .
H26C H 0.4796 0.7137 0.2085 0.066 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O3 165.87(5) . . ?
O1 Eu1 O2 102.46(5) . . ?
O3 Eu1 O2 89.60(5) . . ?
O1 Eu1 O5 82.28(5) . . ?
O3 Eu1 O5 107.61(4) . . ?
O2 Eu1 O5 78.70(4) . . ?
O1 Eu1 O6 82.60(5) . . ?
O3 Eu1 O6 92.77(4) . . ?
O2 Eu1 O6 78.55(4) . . ?
O5 Eu1 O6 149.16(4) . . ?
O1 Eu1 O7 84.88(5) . . ?
O3 Eu1 O7 81.05(4) . . ?
O2 Eu1 O7 142.53(4) . . ?
O5 Eu1 O7 138.71(4) . . ?
O6 Eu1 O7 65.88(4) . . ?
O1 Eu1 O4 97.80(5) . . ?
O3 Eu1 O4 78.03(4) . . ?
O2 Eu1 O4 135.55(4) . . ?
O5 Eu1 O4 65.30(4) . . ?
O6 Eu1 O4 143.66(4) . . ?
O7 Eu1 O4 77.92(4) . . ?
C1 O1 Eu1 164.22(12) . . ?
O1 C1 C2 122.61(16) . . ?
O1 C1 C6 122.52(16) . . ?
C2 C1 C6 114.87(15) . . ?
F1 C2 C3 118.19(17) . . ?
F1 C2 C1 118.59(16) . . ?
C3 C2 C1 123.21(16) . . ?
F2 C3 C4 119.96(17) . . ?
F2 C3 C2 120.03(17) . . ?
C4 C3 C2 120.01(17) . . ?
F3 C4 C5 120.48(17) . . ?
F3 C4 C3 120.71(17) . . ?
C5 C4 C3 118.81(16) . . ?
F4 C5 C4 119.17(16) . . ?
F4 C5 C6 120.10(17) . . ?
C4 C5 C6 120.73(16) . . ?
F5 C6 C5 118.26(16) . . ?
F5 C6 C1 119.40(15) . . ?
C5 C6 C1 122.34(16) . . ?
C7 O2 Eu1 132.23(10) . . ?
O2 C7 C8 122.47(15) . . ?
O2 C7 C12 123.09(15) . . ?
C8 C7 C12 114.42(15) . . ?
F6 C8 C9 118.35(14) . . ?
F6 C8 C7 118.10(14) . . ?
C9 C8 C7 123.47(15) . . ?
F7 C9 C10 119.87(15) . . ?
F7 C9 C8 120.16(15) . . ?
C10 C9 C8 119.97(15) . . ?
F8 C10 C9 120.49(17) . . ?
F8 C10 C11 120.64(16) . . ?
C9 C10 C11 118.87(16) . . ?
F9 C11 C12 120.00(17) . . ?
F9 C11 C10 119.52(16) . . ?
C12 C11 C10 120.47(16) . . ?
F10 C12 C11 118.21(15) . . ?
F10 C12 C7 119.01(15) . . ?
C11 C12 C7 122.73(16) . . ?
C13 O3 Eu1 149.21(11) . . ?
O3 C13 C18 122.47(14) . . ?
O3 C13 C14 122.86(15) . . ?
C18 C13 C14 114.66(15) . . ?
F11 C14 C15 118.64(15) . . ?
F11 C14 C13 118.86(15) . . ?
C15 C14 C13 122.47(16) . . ?
F12 C15 C16 119.80(16) . . ?
F12 C15 C14 119.45(16) . . ?
C16 C15 C14 120.75(15) . . ?
F13 C16 C15 121.04(16) . . ?
F13 C16 C17 120.16(16) . . ?
C15 C16 C17 118.79(16) . . ?
F14 C17 C18 120.28(16) . . ?
F14 C17 C16 119.73(16) . . ?
C18 C17 C16 119.98(16) . . ?
F15 C18 C17 118.92(15) . . ?
F15 C18 C13 117.70(14) . . ?
C17 C18 C13 123.31(15) . . ?
C20 O4 C19 110.50(14) . . ?
C20 O4 Eu1 115.32(10) . . ?
C19 O4 Eu1 121.37(10) . . ?
C21 O5 C22 111.79(14) . . ?
C21 O5 Eu1 119.69(10) . . ?
C22 O5 Eu1 120.51(10) . . ?
O4 C20 C21 108.29(14) . . ?
O5 C21 C20 106.86(14) . . ?
C24 O6 C23 111.80(13) . . ?
C24 O6 Eu1 120.29(11) . . ?
C23 O6 Eu1 120.76(10) . . ?
C26 O7 C25 113.52(16) . . ?
C26 O7 Eu1 124.08(13) . . ?
C25 O7 Eu1 109.48(10) . . ?
O6 C24 C25 106.07(14) . . ?
O7 C25 C24 110.35(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.2051(12) . ?
Eu1 O3 2.2320(12) . ?
Eu1 O2 2.2451(12) . ?
Eu1 O5 2.4558(12) . ?
Eu1 O6 2.4819(12) . ?
Eu1 O7 2.4875(13) . ?
Eu1 O4 2.4919(12) . ?
O1 C1 1.3121(19) . ?
F1 C2 1.350(2) . ?
F2 C3 1.339(2) . ?
F3 C4 1.3461(19) . ?
F4 C5 1.345(2) . ?
F5 C6 1.344(2) . ?
C1 C2 1.397(2) . ?
C1 C6 1.400(2) . ?
C2 C3 1.379(2) . ?
C3 C4 1.375(3) . ?
C4 C5 1.375(3) . ?
C5 C6 1.382(2) . ?
O2 C7 1.3128(19) . ?
F6 C8 1.3493(18) . ?
F7 C9 1.3452(19) . ?
F8 C10 1.344(2) . ?
F9 C11 1.345(2) . ?
F10 C12 1.345(2) . ?
C7 C8 1.402(2) . ?
C7 C12 1.403(2) . ?
C8 C9 1.380(2) . ?
C9 C10 1.376(3) . ?
C10 C11 1.382(3) . ?
C11 C12 1.381(2) . ?
O3 C13 1.3085(19) . ?
F11 C14 1.350(2) . ?
F12 C15 1.3456(19) . ?
F13 C16 1.344(2) . ?
F14 C17 1.345(2) . ?
F15 C18 1.3494(19) . ?
C13 C18 1.400(2) . ?
C13 C14 1.404(2) . ?
C14 C15 1.380(2) . ?
C15 C16 1.376(3) . ?
C16 C17 1.381(2) . ?
C17 C18 1.378(2) . ?
O4 C20 1.434(2) . ?
O4 C19 1.444(2) . ?
O5 C21 1.430(2) . ?
O5 C22 1.435(2) . ?
C20 C21 1.501(3) . ?
O6 C24 1.428(2) . ?
O6 C23 1.442(2) . ?
O7 C26 1.429(2) . ?
O7 C25 1.452(2) . ?
C24 C25 1.495(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O3 Eu1 O1 C1 -72.6(5) . . . . ?
O2 Eu1 O1 C1 139.3(4) . . . . ?
O5 Eu1 O1 C1 62.8(4) . . . . ?
O6 Eu1 O1 C1 -144.2(4) . . . . ?
O7 Eu1 O1 C1 -77.9(4) . . . . ?
O4 Eu1 O1 C1 -0.8(4) . . . . ?
Eu1 O1 C1 C2 -7.4(5) . . . . ?
Eu1 O1 C1 C6 171.8(3) . . . . ?
O1 C1 C2 F1 1.5(3) . . . . ?
C6 C1 C2 F1 -177.78(16) . . . . ?
O1 C1 C2 C3 -179.56(17) . . . . ?
C6 C1 C2 C3 1.2(3) . . . . ?
F1 C2 C3 F2 -2.9(3) . . . . ?
C1 C2 C3 F2 178.16(17) . . . . ?
F1 C2 C3 C4 177.21(17) . . . . ?
C1 C2 C3 C4 -1.8(3) . . . . ?
F2 C3 C4 F3 0.2(3) . . . . ?
C2 C3 C4 F3 -179.84(17) . . . . ?
F2 C3 C4 C5 -178.95(17) . . . . ?
C2 C3 C4 C5 1.0(3) . . . . ?
F3 C4 C5 F4 1.1(3) . . . . ?
C3 C4 C5 F4 -179.76(16) . . . . ?
F3 C4 C5 C6 -178.92(16) . . . . ?
C3 C4 C5 C6 0.3(3) . . . . ?
F4 C5 C6 F5 0.3(2) . . . . ?
C4 C5 C6 F5 -179.68(16) . . . . ?
F4 C5 C6 C1 179.21(16) . . . . ?
C4 C5 C6 C1 -0.8(3) . . . . ?
O1 C1 C6 F5 -0.3(3) . . . . ?
C2 C1 C6 F5 178.95(15) . . . . ?
O1 C1 C6 C5 -179.15(16) . . . . ?
C2 C1 C6 C5 0.1(2) . . . . ?
O1 Eu1 O2 C7 -179.53(13) . . . . ?
O3 Eu1 O2 C7 7.89(14) . . . . ?
O5 Eu1 O2 C7 -100.16(14) . . . . ?
O6 Eu1 O2 C7 100.80(14) . . . . ?
O7 Eu1 O2 C7 82.54(15) . . . . ?
O4 Eu1 O2 C7 -64.47(15) . . . . ?
Eu1 O2 C7 C8 56.5(2) . . . . ?
Eu1 O2 C7 C12 -121.86(16) . . . . ?
O2 C7 C8 F6 1.2(2) . . . . ?
C12 C7 C8 F6 179.69(15) . . . . ?
O2 C7 C8 C9 -175.65(16) . . . . ?
C12 C7 C8 C9 2.9(2) . . . . ?
F6 C8 C9 F7 1.0(2) . . . . ?
C7 C8 C9 F7 177.85(15) . . . . ?
F6 C8 C9 C10 -178.02(15) . . . . ?
C7 C8 C9 C10 -1.2(3) . . . . ?
F7 C9 C10 F8 -0.2(3) . . . . ?
C8 C9 C10 F8 178.91(16) . . . . ?
F7 C9 C10 C11 -179.76(16) . . . . ?
C8 C9 C10 C11 -0.7(3) . . . . ?
F8 C10 C11 F9 0.5(3) . . . . ?
C9 C10 C11 F9 -179.91(17) . . . . ?
F8 C10 C11 C12 -178.87(17) . . . . ?
C9 C10 C11 C12 0.7(3) . . . . ?
F9 C11 C12 F10 -0.7(3) . . . . ?
C10 C11 C12 F10 178.63(17) . . . . ?
F9 C11 C12 C7 -178.22(17) . . . . ?
C10 C11 C12 C7 1.1(3) . . . . ?
O2 C7 C12 F10 -1.8(3) . . . . ?
C8 C7 C12 F10 179.71(15) . . . . ?
O2 C7 C12 C11 175.70(17) . . . . ?
C8 C7 C12 C11 -2.8(3) . . . . ?
O1 Eu1 O3 C13 -151.9(2) . . . . ?
O2 Eu1 O3 C13 -3.0(2) . . . . ?
O5 Eu1 O3 C13 75.0(2) . . . . ?
O6 Eu1 O3 C13 -81.5(2) . . . . ?
O7 Eu1 O3 C13 -146.6(2) . . . . ?
O4 Eu1 O3 C13 134.0(2) . . . . ?
Eu1 O3 C13 C18 66.2(3) . . . . ?
Eu1 O3 C13 C14 -112.3(2) . . . . ?
O3 C13 C14 F11 -1.5(2) . . . . ?
C18 C13 C14 F11 179.92(15) . . . . ?
O3 C13 C14 C15 176.30(16) . . . . ?
C18 C13 C14 C15 -2.3(2) . . . . ?
F11 C14 C15 F12 -0.4(3) . . . . ?
C13 C14 C15 F12 -178.11(16) . . . . ?
F11 C14 C15 C16 178.87(16) . . . . ?
C13 C14 C15 C16 1.1(3) . . . . ?
F12 C15 C16 F13 0.5(3) . . . . ?
C14 C15 C16 F13 -178.74(16) . . . . ?
F12 C15 C16 C17 179.57(17) . . . . ?
C14 C15 C16 C17 0.4(3) . . . . ?
F13 C16 C17 F14 -0.1(3) . . . . ?
C15 C16 C17 F14 -179.15(17) . . . . ?
F13 C16 C17 C18 178.68(16) . . . . ?
C15 C16 C17 C18 -0.4(3) . . . . ?
F14 C17 C18 F15 0.9(3) . . . . ?
C16 C17 C18 F15 -177.86(16) . . . . ?
F14 C17 C18 C13 177.75(16) . . . . ?
C16 C17 C18 C13 -1.0(3) . . . . ?
O3 C13 C18 F15 0.6(2) . . . . ?
C14 C13 C18 F15 179.19(15) . . . . ?
O3 C13 C18 C17 -176.36(16) . . . . ?
C14 C13 C18 C17 2.3(2) . . . . ?
O1 Eu1 O4 C20 97.75(12) . . . . ?
O3 Eu1 O4 C20 -95.96(12) . . . . ?
O2 Eu1 O4 C20 -19.03(14) . . . . ?
O5 Eu1 O4 C20 20.00(12) . . . . ?
O6 Eu1 O4 C20 -174.16(11) . . . . ?
O7 Eu1 O4 C20 -179.23(13) . . . . ?
O1 Eu1 O4 C19 -124.33(14) . . . . ?
O3 Eu1 O4 C19 41.96(14) . . . . ?
O2 Eu1 O4 C19 118.90(14) . . . . ?
O5 Eu1 O4 C19 157.93(15) . . . . ?
O6 Eu1 O4 C19 -36.23(17) . . . . ?
O7 Eu1 O4 C19 -41.30(14) . . . . ?
O1 Eu1 O5 C21 -90.77(12) . . . . ?
O3 Eu1 O5 C21 78.87(12) . . . . ?
O2 Eu1 O5 C21 164.81(12) . . . . ?
O6 Eu1 O5 C21 -152.04(11) . . . . ?
O7 Eu1 O5 C21 -17.68(15) . . . . ?
O4 Eu1 O5 C21 11.53(11) . . . . ?
O1 Eu1 O5 C22 55.54(14) . . . . ?
O3 Eu1 O5 C22 -134.83(14) . . . . ?
O2 Eu1 O5 C22 -48.89(14) . . . . ?
O6 Eu1 O5 C22 -5.74(18) . . . . ?
O7 Eu1 O5 C22 128.63(14) . . . . ?
O4 Eu1 O5 C22 157.84(15) . . . . ?
C19 O4 C20 C21 170.63(16) . . . . ?
Eu1 O4 C20 C21 -47.01(18) . . . . ?
C22 O5 C21 C20 172.35(16) . . . . ?
Eu1 O5 C21 C20 -38.62(17) . . . . ?
O4 C20 C21 O5 53.81(19) . . . . ?
O1 Eu1 O6 C24 88.78(13) . . . . ?
O3 Eu1 O6 C24 -77.81(13) . . . . ?
O2 Eu1 O6 C24 -166.85(13) . . . . ?
O5 Eu1 O6 C24 149.98(13) . . . . ?
O7 Eu1 O6 C24 1.10(12) . . . . ?
O4 Eu1 O6 C24 -4.33(16) . . . . ?
O1 Eu1 O6 C23 -59.23(13) . . . . ?
O3 Eu1 O6 C23 134.18(13) . . . . ?
O2 Eu1 O6 C23 45.15(13) . . . . ?
O5 Eu1 O6 C23 1.97(17) . . . . ?
O7 Eu1 O6 C23 -146.91(14) . . . . ?
O4 Eu1 O6 C23 -152.34(12) . . . . ?
O1 Eu1 O7 C26 24.66(17) . . . . ?
O3 Eu1 O7 C26 -154.03(17) . . . . ?
O2 Eu1 O7 C26 128.50(16) . . . . ?
O5 Eu1 O7 C26 -47.49(18) . . . . ?
O6 Eu1 O7 C26 108.83(17) . . . . ?
O4 Eu1 O7 C26 -74.46(17) . . . . ?
O1 Eu1 O7 C25 -113.96(11) . . . . ?
O3 Eu1 O7 C25 67.34(11) . . . . ?
O2 Eu1 O7 C25 -10.13(14) . . . . ?
O5 Eu1 O7 C25 173.88(10) . . . . ?
O6 Eu1 O7 C25 -29.79(10) . . . . ?
O4 Eu1 O7 C25 146.92(11) . . . . ?
C23 O6 C24 C25 176.96(16) . . . . ?
Eu1 O6 C24 C25 26.3(2) . . . . ?
C26 O7 C25 C24 -85.9(2) . . . . ?
Eu1 O7 C25 C24 57.41(16) . . . . ?
O6 C24 C25 O7 -54.5(2) . . . . ?
