#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:37:04 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179119 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/81/4308144.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308144
loop_
_publ_author_name
'Silvia Del Piero'
'Rosalisa Fedele'
'Andrea Melchior'
'Roberto Portanova'
'Marilena Tolazzi'
'Ennio Zangrando'
_publ_section_title
;
Solvation Effects on the Stability of Silver(I) Complexes with
Pyridine-Containing Ligands Studied by Thermodynamic and DFT Methods
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4683
_journal_page_last               4691
_journal_paper_doi               10.1021/ic070124d
_journal_volume                  46
_journal_year                    2007
_chemical_formula_moiety         'C24 H26 Ag2 N6 2+, 2(Cl O4 1-)'
_chemical_formula_sum            'C24 H26 Ag2 Cl2 N6 O8'
_chemical_formula_weight         813.15
_chemical_name_systematic
;
 ?
 bis[bis(2-pyridylmethyl)amine-N,N')-silver(I)] diperchlorate
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 114.666(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   23.768(5)
_cell_length_b                   13.363(3)
_cell_length_c                   20.343(4)
_cell_measurement_temperature    293(2)
_cell_volume                     5872(2)
_computing_cell_refinement       'Denzo (Otwinowski & Minor 1997)'
_computing_data_collection       'Nonius Xpress'
_computing_data_reduction
'Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'Ortep3/windows (Farrugia,1997)'
_computing_publication_material  'Wingx 1.70.00 (Farrugia, 1999)'
_computing_structure_refinement  'SHELX97 (Sheldrick, 1998)'
_computing_structure_solution    'SHELX97 (Sheldrick, 1998)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'image plate dip1030'
_diffrn_measurement_method       'laser scanner'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           Mok\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0460
_diffrn_reflns_av_sigmaI/netI    0.0440
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            83587
_diffrn_reflns_theta_full        26.02
_diffrn_reflns_theta_max         26.02
_diffrn_reflns_theta_min         1.79
_exptl_absorpt_coefficient_mu    1.573
_exptl_absorpt_correction_T_max  0.6997
_exptl_absorpt_correction_T_min  0.5028
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details
;
Parkin S,Moezzi B & Hope H, (1995) J. Appl. Cryst. 28, 53-56
Cubic fit to sin(theta)/lambda - 24 parameters
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.840
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3232
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.278
_refine_diff_density_min         -0.540
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.984
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     380
_refine_ls_number_reflns         5711
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.985
_refine_ls_R_factor_all          0.0968
_refine_ls_R_factor_gt           0.0603
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1470P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1971
_refine_ls_wR_factor_ref         0.2199
_reflns_number_gt                3057
_reflns_number_total             5711
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic070124d-file003.cif
_cod_data_source_block           melc2c
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               4308144
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.48714(7) 0.64281(8) 0.46606(10) 0.0984(5) Uani 1 1 d . . .
Ag2 Ag 0.49444(6) 0.85150(11) 0.52183(5) 0.1001(4) Uani 1 1 d . . .
N1 N 0.5851(3) 0.6338(5) 0.4801(4) 0.0873(17) Uani 1 1 d . . .
N2 N 0.4869(3) 0.7178(7) 0.3569(3) 0.101(2) Uani 1 1 d . . .
H2 H 0.4525 0.6959 0.3187 0.121 Uiso 1 1 calc R . .
N3 N 0.4195(3) 0.8682(5) 0.4159(4) 0.0903(18) Uani 1 1 d . . .
N4 N 0.5904(3) 0.8436(5) 0.6066(3) 0.0889(17) Uani 1 1 d . . .
N5 N 0.4865(3) 0.7793(7) 0.6276(3) 0.106(2) Uani 1 1 d . . .
H5 H 0.4545 0.8101 0.6330 0.127 Uiso 1 1 calc R . .
N6 N 0.4077(3) 0.6414(5) 0.4926(4) 0.0888(17) Uani 1 1 d . . .
C1 C 0.6317(5) 0.6165(7) 0.5427(6) 0.111(3) Uani 1 1 d . . .
H1 H 0.6237 0.6024 0.5828 0.133 Uiso 1 1 calc R . .
C2 C 0.6930(5) 0.6190(7) 0.5507(6) 0.115(3) Uani 1 1 d . . .
H2A H 0.7254 0.6040 0.5949 0.138 Uiso 1 1 calc R . .
C3 C 0.7042(4) 0.6433(8) 0.4931(6) 0.119(3) Uani 1 1 d . . .
H3 H 0.7446 0.6464 0.4972 0.143 Uiso 1 1 calc R . .
C4 C 0.6544(4) 0.6638(8) 0.4271(6) 0.115(3) Uani 1 1 d . . .
H4 H 0.6611 0.6809 0.3867 0.138 Uiso 1 1 calc R . .
C5 C 0.5958(4) 0.6584(7) 0.4232(5) 0.094(2) Uani 1 1 d . . .
C6 C 0.3641(5) 0.8867(7) 0.4139(5) 0.112(3) Uani 1 1 d . . .
H6 H 0.3609 0.8921 0.4578 0.134 Uiso 1 1 calc R . .
C7 C 0.3119(5) 0.8984(8) 0.3531(7) 0.127(3) Uani 1 1 d . . .
H7 H 0.2738 0.9082 0.3548 0.152 Uiso 1 1 calc R . .
C8 C 0.3171(7) 0.8954(9) 0.2894(8) 0.151(5) Uani 1 1 d . . .
H8 H 0.2830 0.9084 0.2462 0.181 Uiso 1 1 calc R . .
C9 C 0.3743(7) 0.8724(8) 0.2894(5) 0.129(4) Uani 1 1 d . . .
H9 H 0.3785 0.8673 0.2461 0.155 Uiso 1 1 calc R . .
C10 C 0.4233(4) 0.8578(6) 0.3529(4) 0.094(2) Uani 1 1 d . . .
C11 C 0.4857(4) 0.8252(7) 0.3557(5) 0.103(3) Uani 1 1 d . . .
H11A H 0.4907 0.8499 0.3137 0.124 Uiso 1 1 calc R . .
H11B H 0.5191 0.8516 0.3988 0.124 Uiso 1 1 calc R . .
C12 C 0.5409(4) 0.6713(9) 0.3514(5) 0.118(3) Uani 1 1 d . . .
H12A H 0.5533 0.7122 0.3203 0.142 Uiso 1 1 calc R . .
H12B H 0.5289 0.6063 0.3287 0.142 Uiso 1 1 calc R . .
C13 C 0.6405(5) 0.8573(7) 0.5922(6) 0.109(3) Uani 1 1 d . . .
H13 H 0.6345 0.8744 0.5454 0.130 Uiso 1 1 calc R . .
C14 C 0.6989(5) 0.8472(8) 0.6434(6) 0.118(3) Uani 1 1 d . . .
H14 H 0.7326 0.8584 0.6322 0.142 Uiso 1 1 calc R . .
C15 C 0.7078(4) 0.8201(9) 0.7119(7) 0.134(4) Uani 1 1 d . . .
H15 H 0.7477 0.8131 0.7479 0.161 Uiso 1 1 calc R . .
C16 C 0.6568(4) 0.8031(9) 0.7277(5) 0.121(3) Uani 1 1 d . . .
H16 H 0.6620 0.7840 0.7739 0.145 Uiso 1 1 calc R . .
C17 C 0.5983(4) 0.8158(7) 0.6724(4) 0.092(2) Uani 1 1 d . . .
C18 C 0.3517(5) 0.6365(7) 0.4373(5) 0.104(3) Uani 1 1 d . . .
H18 H 0.3493 0.6336 0.3905 0.125 Uiso 1 1 calc R . .
C19 C 0.2980(5) 0.6356(7) 0.4464(7) 0.118(3) Uani 1 1 d . . .
H19 H 0.2600 0.6299 0.4067 0.141 Uiso 1 1 calc R . .
C20 C 0.3005(5) 0.6429(8) 0.5133(7) 0.125(3) Uani 1 1 d . . .
H20 H 0.2643 0.6437 0.5203 0.150 Uiso 1 1 calc R . .
C21 C 0.3591(5) 0.6492(7) 0.5735(6) 0.114(3) Uani 1 1 d . . .
H21 H 0.3625 0.6528 0.6207 0.137 Uiso 1 1 calc R . .
C22 C 0.4106(4) 0.6500(6) 0.5588(5) 0.089(2) Uani 1 1 d . . .
C23 C 0.4725(4) 0.6690(8) 0.6188(5) 0.109(3) Uani 1 1 d . . .
H23A H 0.5041 0.6349 0.6086 0.131 Uiso 1 1 calc R . .
H23B H 0.4734 0.6421 0.6635 0.131 Uiso 1 1 calc R . .
C24 C 0.5412(4) 0.8052(10) 0.6873(5) 0.123(3) Uani 1 1 d . . .
H24A H 0.5495 0.7547 0.7245 0.148 Uiso 1 1 calc R . .
H24B H 0.5345 0.8681 0.7067 0.148 Uiso 1 1 calc R . .
Cl1 Cl 0.37810(12) 0.9906(2) 0.61057(14) 0.1161(8) Uani 1 1 d . . .
O1 O 0.4137(7) 1.0005(9) 0.5672(5) 0.225(6) Uani 1 1 d . . .
O2 O 0.3524(7) 1.0777(13) 0.6131(9) 0.310(10) Uani 1 1 d . . .
O3 O 0.3581(6) 0.8952(9) 0.6046(10) 0.251(7) Uani 1 1 d . . .
O4 O 0.4285(5) 0.9868(10) 0.6792(6) 0.216(5) Uani 1 1 d . . .
Cl2 Cl 0.37556(12) 0.51123(19) 0.26677(13) 0.1104(7) Uani 1 1 d . . .
O5 O 0.4173(4) 0.5030(7) 0.3405(5) 0.169(3) Uani 1 1 d . . .
O6 O 0.3299(7) 0.4595(16) 0.2512(16) 0.51(2) Uani 1 1 d . . .
O7 O 0.4145(10) 0.4801(13) 0.2350(8) 0.319(11) Uani 1 1 d . . .
O8 O 0.3623(4) 0.6160(6) 0.2505(4) 0.144(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N6 Ag1 N1 159.9(3) . . ?
N6 Ag1 N2 124.1(3) . . ?
N1 Ag1 N2 75.1(2) . . ?
N6 Ag1 Ag2 80.35(17) . . ?
N1 Ag1 Ag2 96.30(17) . . ?
N2 Ag1 Ag2 86.6(2) . . ?
N3 Ag2 N4 159.2(3) . . ?
N3 Ag2 N5 125.9(3) . . ?
N4 Ag2 N5 74.2(2) . . ?
N3 Ag2 Ag1 79.89(18) . . ?
N4 Ag2 Ag1 97.41(18) . . ?
N5 Ag2 Ag1 87.3(2) . . ?
C1 N1 C5 119.9(8) . . ?
C1 N1 Ag1 123.2(6) . . ?
C5 N1 Ag1 116.5(5) . . ?
C11 N2 C12 115.7(8) . . ?
C11 N2 Ag1 114.7(6) . . ?
C12 N2 Ag1 103.0(5) . . ?
C6 N3 C10 117.1(8) . . ?
C6 N3 Ag2 116.5(6) . . ?
C10 N3 Ag2 126.3(6) . . ?
C17 N4 C13 119.4(7) . . ?
C17 N4 Ag2 117.8(5) . . ?
C13 N4 Ag2 122.6(6) . . ?
C24 N5 C23 115.1(8) . . ?
C24 N5 Ag2 106.3(6) . . ?
C23 N5 Ag2 112.2(5) . . ?
C22 N6 C18 118.1(8) . . ?
C22 N6 Ag1 124.8(6) . . ?
C18 N6 Ag1 117.0(6) . . ?
N1 C1 C2 121.7(10) . . ?
C3 C2 C1 118.7(10) . . ?
C2 C3 C4 119.2(10) . . ?
C5 C4 C3 118.7(9) . . ?
N1 C5 C4 121.7(8) . . ?
N1 C5 C12 118.1(7) . . ?
C4 C5 C12 120.0(8) . . ?
N3 C6 C7 125.0(11) . . ?
C6 C7 C8 117.4(13) . . ?
C7 C8 C9 119.1(11) . . ?
C10 C9 C8 119.0(11) . . ?
N3 C10 C9 122.1(10) . . ?
N3 C10 C11 116.8(7) . . ?
C9 C10 C11 121.1(9) . . ?
N2 C11 C10 107.4(7) . . ?
N2 C12 C5 113.8(7) . . ?
C14 C13 N4 122.3(9) . . ?
C13 C14 C15 118.9(10) . . ?
C14 C15 C16 119.9(9) . . ?
C17 C16 C15 117.8(9) . . ?
N4 C17 C16 121.7(8) . . ?
N4 C17 C24 117.9(7) . . ?
C16 C17 C24 120.3(8) . . ?
N6 C18 C19 122.9(9) . . ?
C20 C19 C18 119.3(11) . . ?
C19 C20 C21 119.5(10) . . ?
C22 C21 C20 117.0(9) . . ?
N6 C22 C21 123.1(9) . . ?
N6 C22 C23 117.5(7) . . ?
C21 C22 C23 119.2(8) . . ?
C22 C23 N5 111.0(7) . . ?
N5 C24 C17 115.7(7) . . ?
O2 Cl1 O3 133.1(12) . . ?
O2 Cl1 O4 101.9(9) . . ?
O3 Cl1 O4 100.2(10) . . ?
O2 Cl1 O1 109.6(11) . . ?
O3 Cl1 O1 107.6(8) . . ?
O4 Cl1 O1 97.8(7) . . ?
O6 Cl2 O7 113.8(18) . . ?
O6 Cl2 O5 112.8(14) . . ?
O7 Cl2 O5 99.3(8) . . ?
O6 Cl2 O8 114.0(11) . . ?
O7 Cl2 O8 107.9(9) . . ?
O5 Cl2 O8 107.9(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N6 2.169(6) . ?
Ag1 N1 2.227(6) . ?
Ag1 N2 2.435(7) . ?
Ag1 Ag2 2.9883(17) . ?
Ag2 N3 2.159(7) . ?
Ag2 N4 2.214(6) . ?
Ag2 N5 2.436(7) . ?
N1 C1 1.313(11) . ?
N1 C5 1.326(10) . ?
N2 C11 1.435(11) . ?
N2 C12 1.471(11) . ?
N3 C6 1.324(13) . ?
N3 C10 1.329(11) . ?
N4 C17 1.325(9) . ?
N4 C13 1.352(12) . ?
N5 C24 1.404(10) . ?
N5 C23 1.505(12) . ?
N6 C22 1.325(10) . ?
N6 C18 1.339(12) . ?
C1 C2 1.396(15) . ?
C2 C3 1.345(14) . ?
C3 C4 1.397(14) . ?
C4 C5 1.363(13) . ?
C5 C12 1.509(12) . ?
C6 C7 1.346(14) . ?
C7 C8 1.352(18) . ?
C8 C9 1.394(19) . ?
C9 C10 1.345(13) . ?
C10 C11 1.525(13) . ?
C13 C14 1.351(15) . ?
C14 C15 1.369(14) . ?
C15 C16 1.396(14) . ?
C16 C17 1.388(11) . ?
C17 C24 1.514(12) . ?
C18 C19 1.366(14) . ?
C19 C20 1.340(14) . ?
C20 C21 1.422(16) . ?
C21 C22 1.376(12) . ?
C22 C23 1.489(12) . ?
Cl1 O2 1.326(13) . ?
Cl1 O3 1.348(11) . ?
Cl1 O4 1.410(10) . ?
Cl1 O1 1.461(12) . ?
Cl2 O6 1.212(11) . ?
Cl2 O7 1.395(16) . ?
Cl2 O5 1.416(8) . ?
Cl2 O8 1.444(8) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N6 Ag1 Ag2 N3 -76.8(3) . . . . ?
N1 Ag1 Ag2 N3 123.2(3) . . . . ?
N2 Ag1 Ag2 N3 48.6(3) . . . . ?
N6 Ag1 Ag2 N4 124.1(3) . . . . ?
N1 Ag1 Ag2 N4 -35.9(3) . . . . ?
N2 Ag1 Ag2 N4 -110.5(2) . . . . ?
N6 Ag1 Ag2 N5 50.4(2) . . . . ?
N1 Ag1 Ag2 N5 -109.6(2) . . . . ?
N2 Ag1 Ag2 N5 175.8(2) . . . . ?
N6 Ag1 N1 C1 0.1(12) . . . . ?
N2 Ag1 N1 C1 163.9(7) . . . . ?
Ag2 Ag1 N1 C1 79.2(7) . . . . ?
N6 Ag1 N1 C5 -172.3(7) . . . . ?
N2 Ag1 N1 C5 -8.4(6) . . . . ?
Ag2 Ag1 N1 C5 -93.2(6) . . . . ?
N6 Ag1 N2 C11 71.7(6) . . . . ?
N1 Ag1 N2 C11 -101.6(6) . . . . ?
Ag2 Ag1 N2 C11 -4.2(6) . . . . ?
N6 Ag1 N2 C12 -161.6(5) . . . . ?
N1 Ag1 N2 C12 25.0(6) . . . . ?
Ag2 Ag1 N2 C12 122.5(6) . . . . ?
N4 Ag2 N3 C6 -162.9(7) . . . . ?
N5 Ag2 N3 C6 33.7(7) . . . . ?
Ag1 Ag2 N3 C6 112.8(6) . . . . ?
N4 Ag2 N3 C10 19.8(11) . . . . ?
N5 Ag2 N3 C10 -143.5(6) . . . . ?
Ag1 Ag2 N3 C10 -64.4(6) . . . . ?
N3 Ag2 N4 C17 -172.5(7) . . . . ?
N5 Ag2 N4 C17 -6.5(6) . . . . ?
Ag1 Ag2 N4 C17 -91.5(6) . . . . ?
N3 Ag2 N4 C13 1.6(11) . . . . ?
N5 Ag2 N4 C13 167.6(7) . . . . ?
Ag1 Ag2 N4 C13 82.6(6) . . . . ?
N3 Ag2 N5 C24 -166.0(6) . . . . ?
N4 Ag2 N5 C24 20.1(7) . . . . ?
Ag1 Ag2 N5 C24 118.6(7) . . . . ?
N3 Ag2 N5 C23 67.4(6) . . . . ?
N4 Ag2 N5 C23 -106.5(6) . . . . ?
Ag1 Ag2 N5 C23 -8.0(5) . . . . ?
N1 Ag1 N6 C22 16.8(11) . . . . ?
N2 Ag1 N6 C22 -144.2(6) . . . . ?
Ag2 Ag1 N6 C22 -65.1(6) . . . . ?
N1 Ag1 N6 C18 -166.7(7) . . . . ?
N2 Ag1 N6 C18 32.3(7) . . . . ?
Ag2 Ag1 N6 C18 111.4(6) . . . . ?
C5 N1 C1 C2 -2.9(13) . . . . ?
Ag1 N1 C1 C2 -175.0(7) . . . . ?
N1 C1 C2 C3 2.5(15) . . . . ?
C1 C2 C3 C4 -1.0(16) . . . . ?
C2 C3 C4 C5 -0.1(16) . . . . ?
C1 N1 C5 C4 1.8(13) . . . . ?
Ag1 N1 C5 C4 174.4(7) . . . . ?
C1 N1 C5 C12 176.3(8) . . . . ?
Ag1 N1 C5 C12 -11.1(10) . . . . ?
C3 C4 C5 N1 -0.3(15) . . . . ?
C3 C4 C5 C12 -174.7(9) . . . . ?
C10 N3 C6 C7 -1.9(14) . . . . ?
Ag2 N3 C6 C7 -179.4(8) . . . . ?
N3 C6 C7 C8 -3.1(17) . . . . ?
C6 C7 C8 C9 5.2(19) . . . . ?
C7 C8 C9 C10 -2.6(19) . . . . ?
C6 N3 C10 C9 4.7(13) . . . . ?
Ag2 N3 C10 C9 -178.1(7) . . . . ?
C6 N3 C10 C11 -173.5(8) . . . . ?
Ag2 N3 C10 C11 3.8(10) . . . . ?
C8 C9 C10 N3 -2.5(16) . . . . ?
C8 C9 C10 C11 175.5(10) . . . . ?
C12 N2 C11 C10 173.4(6) . . . . ?
Ag1 N2 C11 C10 -66.7(7) . . . . ?
N3 C10 C11 N2 87.5(9) . . . . ?
C9 C10 C11 N2 -90.7(10) . . . . ?
C11 N2 C12 C5 87.1(10) . . . . ?
Ag1 N2 C12 C5 -38.9(10) . . . . ?
N1 C5 C12 N2 37.2(13) . . . . ?
C4 C5 C12 N2 -148.2(9) . . . . ?
C17 N4 C13 C14 -2.4(13) . . . . ?
Ag2 N4 C13 C14 -176.4(7) . . . . ?
N4 C13 C14 C15 1.3(16) . . . . ?
C13 C14 C15 C16 0.3(18) . . . . ?
C14 C15 C16 C17 -0.7(18) . . . . ?
C13 N4 C17 C16 1.9(13) . . . . ?
Ag2 N4 C17 C16 176.2(8) . . . . ?
C13 N4 C17 C24 177.6(9) . . . . ?
Ag2 N4 C17 C24 -8.2(11) . . . . ?
C15 C16 C17 N4 -0.4(16) . . . . ?
C15 C16 C17 C24 -175.9(10) . . . . ?
C22 N6 C18 C19 -3.0(13) . . . . ?
Ag1 N6 C18 C19 -179.7(7) . . . . ?
N6 C18 C19 C20 2.1(15) . . . . ?
C18 C19 C20 C21 -1.4(16) . . . . ?
C19 C20 C21 C22 1.5(15) . . . . ?
C18 N6 C22 C21 3.2(12) . . . . ?
Ag1 N6 C22 C21 179.7(7) . . . . ?
C18 N6 C22 C23 -172.0(7) . . . . ?
Ag1 N6 C22 C23 4.4(10) . . . . ?
C20 C21 C22 N6 -2.5(14) . . . . ?
C20 C21 C22 C23 172.6(9) . . . . ?
N6 C22 C23 N5 86.9(9) . . . . ?
C21 C22 C23 N5 -88.5(10) . . . . ?
C24 N5 C23 C22 174.1(7) . . . . ?
Ag2 N5 C23 C22 -64.2(8) . . . . ?
C23 N5 C24 C17 93.9(11) . . . . ?
Ag2 N5 C24 C17 -30.9(11) . . . . ?
N4 C17 C24 N5 28.9(14) . . . . ?
C16 C17 C24 N5 -155.4(10) . . . . ?
