#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:37:04 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179119 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/81/4308161.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308161
loop_
_publ_author_name
'Jenni Meiners'
'Jost-Steffen Herrmann'
'Peter W. Roesky'
_publ_contact_author
;
      Prof. Dr. Peter Roesky
      Freie Universität Berlin
      Fabeckstr. 34-36
      14195 Berlin
      Bundesrepublik Deutschland
;
_publ_contact_author_email       roesky@chemie.fu-berlin.de
_publ_contact_author_fax         +49/(0)3083852440
_publ_contact_author_phone       +49/(0)3083854004
_publ_section_title
;
Three-Coordinated Aminotroponiminate and Aminotroponate Complexes of Gold(I)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4599
_journal_page_last               4604
_journal_paper_doi               10.1021/ic0701662
_journal_volume                  46
_journal_year                    2007
_chemical_formula_sum            'C37 H42 Au N2 P'
_chemical_formula_weight         742.66
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.540(6)
_cell_angle_beta                 110.119(6)
_cell_angle_gamma                101.708(6)
_cell_formula_units_Z            2
_cell_length_a                   11.1572(8)
_cell_length_b                   13.0802(10)
_cell_length_c                   13.3000(10)
_cell_measurement_temperature    200(2)
_cell_volume                     1602.9(3)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_molecular_graphics    'Diamond 2.1e'
_computing_publication_material  'X-STEP32, Microsoft Word'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0597
_diffrn_reflns_av_sigmaI/netI    0.0738
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            11137
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.69
_exptl_absorpt_coefficient_mu    4.667
_exptl_absorpt_correction_T_max  0.8920
_exptl_absorpt_correction_T_min  0.5513
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'STOE X-RED & X-SHAPE'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.539
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.191
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.029
_refine_diff_density_max         1.053
_refine_diff_density_min         -1.002
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         5600
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0618
_refine_ls_R_factor_gt           0.0422
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0350P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0779
_refine_ls_wR_factor_ref         0.0831
_reflns_number_gt                4570
_reflns_number_total             5600
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0701662-file001_2.cif
_cod_data_source_block           2
_cod_original_cell_volume        1602.9(2)
_cod_database_code               4308161
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.9575(7) 0.5922(5) 0.3060(5) 0.0294(14) Uani 1 1 d . . .
C2 C 1.0059(8) 0.5196(7) 0.2352(7) 0.0450(18) Uani 1 1 d . . .
H2 H 1.0905 0.5161 0.2809 0.054 Uiso 1 1 calc R . .
C3 C 0.9552(9) 0.4536(8) 0.1145(7) 0.057(2) Uani 1 1 d . . .
H3 H 1.0115 0.4141 0.0927 0.069 Uiso 1 1 calc R . .
C4 C 0.8377(10) 0.4345(8) 0.0196(7) 0.056(2) Uani 1 1 d . . .
H4 H 0.8216 0.3844 -0.0581 0.067 Uiso 1 1 calc R . .
C5 C 0.7420(10) 0.4835(8) 0.0304(7) 0.059(2) Uani 1 1 d . . .
H5 H 0.6664 0.4634 -0.0429 0.071 Uiso 1 1 calc R . .
C6 C 0.7383(9) 0.5568(8) 0.1299(7) 0.054(2) Uani 1 1 d . . .
H6 H 0.6613 0.5799 0.1104 0.065 Uiso 1 1 calc R . .
C7 C 0.8210(7) 0.6068(6) 0.2552(6) 0.0303(15) Uani 1 1 d . . .
C8 C 1.1735(8) 0.6655(8) 0.4842(6) 0.049(2) Uani 1 1 d . . .
H8 H 1.2073 0.6357 0.4237 0.058 Uiso 1 1 calc R . .
C9 C 1.2645(8) 0.7914(8) 0.5692(9) 0.063(3) Uani 1 1 d . . .
H9A H 1.2290 0.8229 0.6269 0.075 Uiso 1 1 calc R . .
H9B H 1.2624 0.8379 0.5236 0.075 Uiso 1 1 calc R . .
C10 C 1.4129(8) 0.8024(9) 0.6372(9) 0.067(3) Uani 1 1 d . . .
H10A H 1.4498 0.7737 0.5799 0.080 Uiso 1 1 calc R . .
H10B H 1.4700 0.8852 0.6914 0.080 Uiso 1 1 calc R . .
C11 C 1.4194(8) 0.7347(8) 0.7072(7) 0.048(2) Uani 1 1 d . . .
H11A H 1.3883 0.7667 0.7682 0.058 Uiso 1 1 calc R . .
H11B H 1.5152 0.7410 0.7487 0.058 Uiso 1 1 calc R . .
C12 C 1.3292(9) 0.6073(8) 0.6255(10) 0.076(3) Uani 1 1 d . . .
H12A H 1.3667 0.5731 0.5703 0.091 Uiso 1 1 calc R . .
H12B H 1.3298 0.5640 0.6740 0.091 Uiso 1 1 calc R . .
C13 C 1.1824(8) 0.5947(8) 0.5535(9) 0.067(3) Uani 1 1 d . . .
H13A H 1.1284 0.5118 0.4975 0.081 Uiso 1 1 calc R . .
H13B H 1.1415 0.6193 0.6085 0.081 Uiso 1 1 calc R . .
C14 C 0.6714(7) 0.7050(6) 0.2973(6) 0.0326(15) Uani 1 1 d . . .
H14 H 0.5984 0.6395 0.2205 0.039 Uiso 1 1 calc R . .
C15 C 0.6156(7) 0.7278(7) 0.3884(7) 0.0427(18) Uani 1 1 d . . .
H15A H 0.6879 0.7898 0.4664 0.051 Uiso 1 1 calc R . .
H15B H 0.5874 0.6565 0.3984 0.051 Uiso 1 1 calc R . .
C16 C 0.4924(8) 0.7651(9) 0.3476(8) 0.057(2) Uani 1 1 d . . .
H16A H 0.4179 0.7008 0.2725 0.069 Uiso 1 1 calc R . .
H16B H 0.4584 0.7817 0.4087 0.069 Uiso 1 1 calc R . .
C17 C 0.5312(9) 0.8720(9) 0.3281(10) 0.068(3) Uani 1 1 d . . .
H17A H 0.4495 0.8929 0.2998 0.081 Uiso 1 1 calc R . .
H17B H 0.6006 0.9379 0.4047 0.081 Uiso 1 1 calc R . .
C18 C 0.5872(10) 0.8521(10) 0.2387(10) 0.072(3) Uani 1 1 d . . .
H18A H 0.6179 0.9251 0.2321 0.087 Uiso 1 1 calc R . .
H18B H 0.5145 0.7926 0.1595 0.087 Uiso 1 1 calc R . .
C19 C 0.7069(8) 0.8116(8) 0.2760(8) 0.048(2) Uani 1 1 d . . .
H19A H 0.7383 0.7939 0.2131 0.058 Uiso 1 1 calc R . .
H19B H 0.7836 0.8756 0.3500 0.058 Uiso 1 1 calc R . .
C20 C 0.9059(6) 0.9608(6) 0.7245(5) 0.0282(14) Uani 1 1 d . . .
C21 C 0.8525(8) 1.0073(7) 0.8007(7) 0.0430(18) Uani 1 1 d . . .
H21 H 0.8259 0.9661 0.8409 0.052 Uiso 1 1 calc R . .
C22 C 0.8374(9) 1.1138(7) 0.8190(8) 0.050(2) Uani 1 1 d . . .
H22 H 0.8011 1.1452 0.8722 0.060 Uiso 1 1 calc R . .
C23 C 0.8748(9) 1.1745(7) 0.7606(7) 0.0482(19) Uani 1 1 d . . .
H23 H 0.8666 1.2483 0.7750 0.058 Uiso 1 1 calc R . .
C24 C 0.9246(8) 1.1266(6) 0.6807(7) 0.0412(17) Uani 1 1 d . . .
H24 H 0.9480 1.1666 0.6383 0.049 Uiso 1 1 calc R . .
C25 C 0.9399(7) 1.0205(6) 0.6630(6) 0.0371(16) Uani 1 1 d . . .
H25 H 0.9740 0.9880 0.6083 0.044 Uiso 1 1 calc R . .
C26 C 0.8385(7) 0.7409(6) 0.7436(6) 0.0308(14) Uani 1 1 d . . .
C27 C 0.8623(7) 0.7700(6) 0.8619(6) 0.0377(16) Uani 1 1 d . . .
H27 H 0.9343 0.8394 0.9248 0.045 Uiso 1 1 calc R . .
C28 C 0.7799(8) 0.6967(8) 0.8868(7) 0.046(2) Uani 1 1 d . . .
H28 H 0.7951 0.7161 0.9668 0.056 Uiso 1 1 calc R . .
C29 C 0.6751(8) 0.5950(7) 0.7942(8) 0.049(2) Uani 1 1 d . . .
H29 H 0.6202 0.5444 0.8117 0.059 Uiso 1 1 calc R . .
C30 C 0.6502(8) 0.5669(7) 0.6787(7) 0.049(2) Uani 1 1 d . . .
H30 H 0.5770 0.4982 0.6159 0.059 Uiso 1 1 calc R . .
C31 C 0.7330(7) 0.6396(6) 0.6535(7) 0.0394(17) Uani 1 1 d . . .
H31 H 0.7168 0.6193 0.5731 0.047 Uiso 1 1 calc R . .
C32 C 1.1153(6) 0.8846(6) 0.8326(5) 0.0291(14) Uani 1 1 d . . .
C33 C 1.1904(7) 1.0012(7) 0.9045(6) 0.0431(18) Uani 1 1 d . . .
H33 H 1.1558 1.0579 0.8894 0.052 Uiso 1 1 calc R . .
C34 C 1.3170(8) 1.0351(8) 0.9993(7) 0.053(2) Uani 1 1 d . . .
H34 H 1.3694 1.1155 1.0485 0.064 Uiso 1 1 calc R . .
C35 C 1.3667(8) 0.9548(9) 1.0224(7) 0.054(2) Uani 1 1 d . . .
H35 H 1.4528 0.9795 1.0885 0.065 Uiso 1 1 calc R . .
C36 C 1.2938(8) 0.8381(8) 0.9510(7) 0.051(2) Uani 1 1 d . . .
H36 H 1.3291 0.7821 0.9672 0.061 Uiso 1 1 calc R . .
C37 C 1.1686(8) 0.8031(7) 0.8555(6) 0.0425(17) Uani 1 1 d . . .
H37 H 1.1184 0.7226 0.8050 0.051 Uiso 1 1 calc R . .
N1 N 1.0309(6) 0.6555(5) 0.4218(5) 0.0394(14) Uani 1 1 d . . .
N2 N 0.7913(5) 0.6718(5) 0.3344(5) 0.0312(12) Uani 1 1 d . . .
P1 P 0.94661(16) 0.82963(15) 0.70479(14) 0.0271(4) Uani 1 1 d . . .
Au1 Au 0.93358(3) 0.73674(3) 0.52705(2) 0.02915(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 C1 C2 122.1(6) . . ?
N1 C1 C7 114.1(6) . . ?
C2 C1 C7 123.7(6) . . ?
C3 C2 C1 133.2(8) . . ?
C4 C3 C2 131.6(8) . . ?
C3 C4 C5 124.1(8) . . ?
C6 C5 C4 130.3(8) . . ?
C5 C6 C7 136.0(8) . . ?
N2 C7 C6 124.2(6) . . ?
N2 C7 C1 114.8(5) . . ?
C6 C7 C1 120.9(6) . . ?
N1 C8 C13 110.7(7) . . ?
N1 C8 C9 110.8(7) . . ?
C13 C8 C9 108.9(6) . . ?
C8 C9 C10 111.3(8) . . ?
C11 C10 C9 110.6(7) . . ?
C10 C11 C12 110.3(7) . . ?
C13 C12 C11 111.1(8) . . ?
C8 C13 C12 112.8(8) . . ?
N2 C14 C19 110.2(6) . . ?
N2 C14 C15 111.8(5) . . ?
C19 C14 C15 109.9(6) . . ?
C14 C15 C16 110.1(6) . . ?
C17 C16 C15 111.0(7) . . ?
C18 C17 C16 111.4(8) . . ?
C17 C18 C19 110.4(7) . . ?
C14 C19 C18 113.1(7) . . ?
C21 C20 C25 119.0(7) . . ?
C21 C20 P1 124.4(5) . . ?
C25 C20 P1 116.5(5) . . ?
C20 C21 C22 120.5(7) . . ?
C23 C22 C21 120.5(7) . . ?
C22 C23 C24 119.5(7) . . ?
C25 C24 C23 119.9(6) . . ?
C24 C25 C20 120.7(7) . . ?
C31 C26 C27 119.2(6) . . ?
C31 C26 P1 118.7(5) . . ?
C27 C26 P1 122.1(5) . . ?
C28 C27 C26 119.7(7) . . ?
C29 C28 C27 119.8(7) . . ?
C30 C29 C28 120.8(7) . . ?
C29 C30 C31 119.5(7) . . ?
C26 C31 C30 121.0(7) . . ?
C33 C32 C37 119.3(6) . . ?
C33 C32 P1 123.3(6) . . ?
C37 C32 P1 117.4(5) . . ?
C32 C33 C34 119.5(8) . . ?
C35 C34 C33 120.8(8) . . ?
C34 C35 C36 120.6(7) . . ?
C35 C36 C37 119.3(8) . . ?
C36 C37 C32 120.6(8) . . ?
C1 N1 C8 121.9(6) . . ?
C1 N1 Au1 119.1(5) . . ?
C8 N1 Au1 118.8(4) . . ?
C7 N2 C14 120.4(5) . . ?
C7 N2 Au1 118.0(4) . . ?
C14 N2 Au1 121.5(4) . . ?
C20 P1 C26 107.5(3) . . ?
C20 P1 C32 102.2(3) . . ?
C26 P1 C32 102.1(3) . . ?
C20 P1 Au1 113.4(2) . . ?
C26 P1 Au1 113.9(2) . . ?
C32 P1 Au1 116.5(2) . . ?
N1 Au1 P1 147.87(16) . . ?
N1 Au1 N2 72.2(2) . . ?
P1 Au1 N2 139.90(15) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 N1 1.316(8) . ?
C1 C2 1.428(10) . ?
C1 C7 1.520(9) . ?
C2 C3 1.376(11) . ?
C3 C4 1.375(12) . ?
C4 C5 1.376(12) . ?
C5 C6 1.370(12) . ?
C6 C7 1.422(10) . ?
C7 N2 1.303(9) . ?
C8 N1 1.473(9) . ?
C8 C13 1.505(12) . ?
C8 C9 1.519(12) . ?
C9 C10 1.538(11) . ?
C10 C11 1.479(12) . ?
C11 C12 1.525(12) . ?
C12 C13 1.527(11) . ?
C14 N2 1.465(8) . ?
C14 C19 1.516(10) . ?
C14 C15 1.516(10) . ?
C15 C16 1.535(11) . ?
C16 C17 1.512(13) . ?
C17 C18 1.498(14) . ?
C18 C19 1.522(11) . ?
C20 C21 1.380(10) . ?
C20 C25 1.394(9) . ?
C20 P1 1.821(7) . ?
C21 C22 1.387(11) . ?
C22 C23 1.382(11) . ?
C23 C24 1.390(11) . ?
C24 C25 1.384(10) . ?
C26 C31 1.382(10) . ?
C26 C27 1.400(9) . ?
C26 P1 1.825(6) . ?
C27 C28 1.393(10) . ?
C28 C29 1.392(12) . ?
C29 C30 1.364(11) . ?
C30 C31 1.393(10) . ?
C32 C33 1.377(10) . ?
C32 C37 1.391(10) . ?
C32 P1 1.838(6) . ?
C33 C34 1.389(10) . ?
C34 C35 1.357(13) . ?
C35 C36 1.375(13) . ?
C36 C37 1.380(10) . ?
N1 Au1 2.188(6) . ?
N2 Au1 2.237(5) . ?
P1 Au1 2.2037(17) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 C1 C2 C3 -174.2(9) . . . . ?
C7 C1 C2 C3 3.7(14) . . . . ?
C1 C2 C3 C4 -0.6(18) . . . . ?
C2 C3 C4 C5 0.5(17) . . . . ?
C3 C4 C5 C6 -0.8(17) . . . . ?
C4 C5 C6 C7 -2.7(19) . . . . ?
C5 C6 C7 N2 -176.6(10) . . . . ?
C5 C6 C7 C1 6.7(15) . . . . ?
N1 C1 C7 N2 -5.6(8) . . . . ?
C2 C1 C7 N2 176.5(6) . . . . ?
N1 C1 C7 C6 171.5(7) . . . . ?
C2 C1 C7 C6 -6.5(10) . . . . ?
N1 C8 C9 C10 178.5(7) . . . . ?
C13 C8 C9 C10 56.5(10) . . . . ?
C8 C9 C10 C11 -59.6(11) . . . . ?
C9 C10 C11 C12 57.8(11) . . . . ?
C10 C11 C12 C13 -55.4(12) . . . . ?
N1 C8 C13 C12 -176.9(8) . . . . ?
C9 C8 C13 C12 -54.7(11) . . . . ?
C11 C12 C13 C8 54.7(13) . . . . ?
N2 C14 C15 C16 178.7(6) . . . . ?
C19 C14 C15 C16 55.9(8) . . . . ?
C14 C15 C16 C17 -57.7(10) . . . . ?
C15 C16 C17 C18 57.5(10) . . . . ?
C16 C17 C18 C19 -55.1(11) . . . . ?
N2 C14 C19 C18 -179.2(7) . . . . ?
C15 C14 C19 C18 -55.5(9) . . . . ?
C17 C18 C19 C14 54.9(12) . . . . ?
C25 C20 C21 C22 -2.3(11) . . . . ?
P1 C20 C21 C22 173.5(6) . . . . ?
C20 C21 C22 C23 0.4(13) . . . . ?
C21 C22 C23 C24 1.7(13) . . . . ?
C22 C23 C24 C25 -1.9(12) . . . . ?
C23 C24 C25 C20 0.0(11) . . . . ?
C21 C20 C25 C24 2.0(10) . . . . ?
P1 C20 C25 C24 -174.0(6) . . . . ?
C31 C26 C27 C28 0.1(11) . . . . ?
P1 C26 C27 C28 -177.5(6) . . . . ?
C26 C27 C28 C29 0.3(11) . . . . ?
C27 C28 C29 C30 -1.2(12) . . . . ?
C28 C29 C30 C31 1.6(12) . . . . ?
C27 C26 C31 C30 0.3(11) . . . . ?
P1 C26 C31 C30 178.0(6) . . . . ?
C29 C30 C31 C26 -1.2(12) . . . . ?
C37 C32 C33 C34 -0.8(10) . . . . ?
P1 C32 C33 C34 180.0(6) . . . . ?
C32 C33 C34 C35 -0.6(12) . . . . ?
C33 C34 C35 C36 1.2(12) . . . . ?
C34 C35 C36 C37 -0.3(12) . . . . ?
C35 C36 C37 C32 -1.1(12) . . . . ?
C33 C32 C37 C36 1.7(11) . . . . ?
P1 C32 C37 C36 -179.0(6) . . . . ?
C2 C1 N1 C8 6.7(10) . . . . ?
C7 C1 N1 C8 -171.4(6) . . . . ?
C2 C1 N1 Au1 -168.2(5) . . . . ?
C7 C1 N1 Au1 13.8(7) . . . . ?
C13 C8 N1 C1 -105.2(8) . . . . ?
C9 C8 N1 C1 133.9(7) . . . . ?
C13 C8 N1 Au1 69.7(8) . . . . ?
C9 C8 N1 Au1 -51.3(8) . . . . ?
C6 C7 N2 C14 -4.6(10) . . . . ?
C1 C7 N2 C14 172.4(5) . . . . ?
C6 C7 N2 Au1 178.2(6) . . . . ?
C1 C7 N2 Au1 -4.9(7) . . . . ?
C19 C14 N2 C7 -84.6(8) . . . . ?
C15 C14 N2 C7 152.9(6) . . . . ?
C19 C14 N2 Au1 92.6(6) . . . . ?
C15 C14 N2 Au1 -30.0(7) . . . . ?
C21 C20 P1 C26 25.4(7) . . . . ?
C25 C20 P1 C26 -158.7(5) . . . . ?
C21 C20 P1 C32 -81.6(6) . . . . ?
C25 C20 P1 C32 94.2(5) . . . . ?
C21 C20 P1 Au1 152.3(5) . . . . ?
C25 C20 P1 Au1 -31.9(6) . . . . ?
C31 C26 P1 C20 108.8(6) . . . . ?
C27 C26 P1 C20 -73.6(6) . . . . ?
C31 C26 P1 C32 -144.1(6) . . . . ?
C27 C26 P1 C32 33.5(7) . . . . ?
C31 C26 P1 Au1 -17.7(6) . . . . ?
C27 C26 P1 Au1 159.8(5) . . . . ?
C33 C32 P1 C20 -10.3(6) . . . . ?
C37 C32 P1 C20 170.5(5) . . . . ?
C33 C32 P1 C26 -121.4(6) . . . . ?
C37 C32 P1 C26 59.3(6) . . . . ?
C33 C32 P1 Au1 113.8(6) . . . . ?
C37 C32 P1 Au1 -65.4(6) . . . . ?
C1 N1 Au1 P1 168.9(4) . . . . ?
C8 N1 Au1 P1 -6.1(8) . . . . ?
C1 N1 Au1 N2 -12.3(5) . . . . ?
C8 N1 Au1 N2 172.7(6) . . . . ?
C20 P1 Au1 N1 129.6(4) . . . . ?
C26 P1 Au1 N1 -107.0(4) . . . . ?
C32 P1 Au1 N1 11.4(4) . . . . ?
C20 P1 Au1 N2 -48.7(3) . . . . ?
C26 P1 Au1 N2 74.7(3) . . . . ?
C32 P1 Au1 N2 -166.8(3) . . . . ?
C7 N2 Au1 N1 8.8(5) . . . . ?
C14 N2 Au1 N1 -168.4(5) . . . . ?
C7 N2 Au1 P1 -172.1(4) . . . . ?
C14 N2 Au1 P1 10.6(6) . . . . ?
