#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:42:41 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179124 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/86/4308656.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308656
loop_
_publ_author_name
'Matthias Weil'
'Ekkehart Tillmanns'
'Dmitry Yu. Pushcharovsky'
_publ_contact_author_address
;  
Institute for Chemical Technologies and Analytics
Division of Structural Chemistry
Vienna University of Technology
Getreidemarkt 9/164-SC
A-1060 Vienna
Austria       
;
_publ_contact_author_email       mweil@mail.zserv.tuwien.ac.at
_publ_contact_author_fax         '+43 1 58801 17199'
_publ_contact_author_name
;       
Matthias Weil       
;
_publ_contact_author_phone       '+43 1 58801 17122'
_publ_section_title
;
Hydrothermal Single-Crystal Growth in the Systems Ag/Hg/X/O (X = VV,
AsV): Crystal Structures of (Ag3Hg)VO4, (Ag2Hg2)3(VO4)4, and
(Ag2Hg2)2(HgO2)(AsO4)2 with the Unusual Tetrahedral Cluster Cations
(Ag3Hg)3+ and (Ag2Hg2)4+ and Crystal Structure of AgHgVO4
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1443
_journal_page_last               1451
_journal_paper_doi               10.1021/ic0484912
_journal_volume                  44
_journal_year                    2005
_chemical_formula_structural     '(Ag2 Hg2)(Hg O2)(As O4)2'
_chemical_formula_sum            'Ag4 As2 Hg5 O10'
_chemical_formula_weight         1744.27
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           159
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  'P 3 -2c'
_symmetry_space_group_name_H-M   'P 3 1 c'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   6.0261(9)
_cell_length_b                   6.0261(9)
_cell_length_c                   21.577(4)
_cell_measurement_reflns_used    3445
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.329
_cell_measurement_theta_min      3.778
_cell_volume                     678.57(19)
_computing_cell_refinement       SAINT
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'SMART (Siemens)'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0550
_diffrn_reflns_av_sigmaI/netI    0.0331
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       7
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            7466
_diffrn_reflns_theta_full        30.50
_diffrn_reflns_theta_max         30.50
_diffrn_reflns_theta_min         1.89
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    66.849
_exptl_absorpt_correction_T_max  0.4526
_exptl_absorpt_correction_T_min  0.0272
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Habitus (Herrendorf, 1993-1997)
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    8.537
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'hexagonal plate'
_exptl_crystal_F_000             1468
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.015
_refine_diff_density_max         7.963
_refine_diff_density_min         -4.577
_refine_diff_density_rms         0.867
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.47(15)
_refine_ls_extinction_coef       0.00030(15)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.132
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     50
_refine_ls_number_reflns         1362
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.132
_refine_ls_R_factor_all          0.0501
_refine_ls_R_factor_gt           0.0480
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0920P)²+16.8144P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1356
_refine_ls_wR_factor_ref         0.1368
_reflns_number_gt                1292
_reflns_number_total             1362
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic0484912si20041027_114324_1.cif
_cod_data_source_block           AgHgAsO
_cod_original_cell_volume        678.56(19)
_cod_database_code               4308656
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, z+1/2'
'-x, -x+y, z+1/2'
'x-y, -y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Hg1 Hg 0.0563(3) 0.4201(4) 0.34974(7) 0.0153(3) Uani 0.50 1 d P . .
Ag1 Ag 0.0563(3) 0.4201(4) 0.34974(7) 0.0153(3) Uani 0.50 1 d P . .
Hg2 Hg -0.3333 0.3333 0.20624(10) 0.0160(5) Uani 0.50 3 d SP . .
Ag2 Ag -0.3333 0.3333 0.20624(10) 0.0160(5) Uani 0.50 3 d SP . .
Hg3 Hg 0.3333 0.6667 0.45162(16) 0.0326(7) Uani 0.50 3 d SP . .
Ag3 Ag 0.3333 0.6667 0.45162(16) 0.0326(7) Uani 0.50 3 d SP . .
Hg4 Hg 0.4104(5) 0.3514(4) 0.10676(7) 0.0210(5) Uani 0.50 1 d P . .
Ag4 Ag 0.4104(5) 0.3514(4) 0.10676(7) 0.0210(5) Uani 0.50 1 d P . .
Hg5 Hg -0.3333 0.3333 0.48266(9) 0.0139(3) Uani 1 3 d S . .
As1 As 0.0000 0.0000 0.23840(18) 0.0038(6) Uiso 1 3 d S . .
As2 As 0.0000 0.0000 0.4803(2) 0.0074(7) Uiso 1 3 d S . .
O1 O 0.151(6) 0.295(4) 0.5081(10) 0.026(4) Uiso 1 1 d . . .
O2 O -0.3333 0.3333 0.3899(13) 0.006(5) Uiso 1 3 d S . .
O3 O -0.3333 0.3333 0.586(3) 0.043(12) Uiso 1 3 d S . .
O4 O 0.0000 0.0000 0.3979(14) 0.011(5) Uiso 1 3 d S . .
O5 O -0.136(4) 0.166(5) 0.2677(8) 0.015(3) Uiso 1 1 d . . .
O6 O 0.0000 0.0000 0.1567(16) 0.019(6) Uiso 1 3 d S . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Hg Hg -2.3894 9.2266 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O5 Hg1 O2 91.2(8) . . ?
O5 Hg1 O4 83.0(8) . . ?
O2 Hg1 O4 90.4(4) . . ?
O5 Hg1 Hg3 168.3(5) . . ?
O2 Hg1 Hg3 95.6(6) . . ?
O4 Hg1 Hg3 87.4(5) . . ?
O5 Hg1 Ag1 113.8(5) . 2_665 ?
O2 Hg1 Ag1 155.0(5) . 2_665 ?
O4 Hg1 Ag1 91.25(8) . 2_665 ?
Hg3 Hg1 Ag1 59.56(5) . 2_665 ?
O5 Hg1 Hg1 113.8(5) . 2_665 ?
O2 Hg1 Hg1 155.0(5) . 2_665 ?
O4 Hg1 Hg1 91.25(8) . 2_665 ?
Hg3 Hg1 Hg1 59.56(5) . 2_665 ?
Ag1 Hg1 Hg1 0.00(9) 2_665 2_665 ?
O5 Hg1 Ag1 127.3(6) . 3_565 ?
O2 Hg1 Ag1 106.62(13) . 3_565 ?
O4 Hg1 Ag1 143.5(4) . 3_565 ?
Hg3 Hg1 Ag1 59.56(5) . 3_565 ?
Ag1 Hg1 Ag1 60.000(1) 2_665 3_565 ?
Hg1 Hg1 Ag1 60.000(1) 2_665 3_565 ?
O5 Hg1 Hg1 127.3(6) . 3_565 ?
O2 Hg1 Hg1 106.62(13) . 3_565 ?
O4 Hg1 Hg1 143.5(4) . 3_565 ?
Hg3 Hg1 Hg1 59.56(5) . 3_565 ?
Ag1 Hg1 Hg1 60.000(1) 2_665 3_565 ?
Hg1 Hg1 Hg1 60.000(1) 2_665 3_565 ?
Ag1 Hg1 Hg1 0.00(7) 3_565 3_565 ?
O5 Hg2 O5 90.6(6) . 2_565 ?
O5 Hg2 O5 90.6(6) . 3_455 ?
O5 Hg2 O5 90.6(6) 2_565 3_455 ?
O5 Hg2 Hg4 93.5(5) . 2 ?
O5 Hg2 Hg4 155.0(5) 2_565 2 ?
O5 Hg2 Hg4 114.0(5) 3_455 2 ?
O5 Hg2 Ag4 93.5(5) . 2 ?
O5 Hg2 Ag4 155.0(5) 2_565 2 ?
O5 Hg2 Ag4 114.0(5) 3_455 2 ?
Hg4 Hg2 Ag4 0.00(9) 2 2 ?
O5 Hg2 Hg4 114.0(5) . 3_565 ?
O5 Hg2 Hg4 93.5(5) 2_565 3_565 ?
O5 Hg2 Hg4 155.0(5) 3_455 3_565 ?
Hg4 Hg2 Hg4 62.38(9) 2 3_565 ?
Ag4 Hg2 Hg4 62.38(9) 2 3_565 ?
O5 Hg2 Ag4 114.0(5) . 3_565 ?
O5 Hg2 Ag4 93.5(5) 2_565 3_565 ?
O5 Hg2 Ag4 155.0(5) 3_455 3_565 ?
Hg4 Hg2 Ag4 62.38(9) 2 3_565 ?
Ag4 Hg2 Ag4 62.38(9) 2 3_565 ?
Hg4 Hg2 Ag4 0.00(4) 3_565 3_565 ?
O5 Hg2 Ag4 155.0(5) . 1_455 ?
O5 Hg2 Ag4 114.0(5) 2_565 1_455 ?
O5 Hg2 Ag4 93.5(5) 3_455 1_455 ?
Hg4 Hg2 Ag4 62.38(9) 2 1_455 ?
Ag4 Hg2 Ag4 62.38(9) 2 1_455 ?
Hg4 Hg2 Ag4 62.38(9) 3_565 1_455 ?
Ag4 Hg2 Ag4 62.38(9) 3_565 1_455 ?
O5 Hg2 Hg4 155.0(5) . 1_455 ?
O5 Hg2 Hg4 114.0(5) 2_565 1_455 ?
O5 Hg2 Hg4 93.5(5) 3_455 1_455 ?
Hg4 Hg2 Hg4 62.38(9) 2 1_455 ?
Ag4 Hg2 Hg4 62.38(9) 2 1_455 ?
Hg4 Hg2 Hg4 62.38(9) 3_565 1_455 ?
Ag4 Hg2 Hg4 62.38(9) 3_565 1_455 ?
Ag4 Hg2 Hg4 0.00(10) 1_455 1_455 ?
O1 Hg3 O1 94.3(7) 3_565 2_665 ?
O1 Hg3 O1 94.3(7) 3_565 . ?
O1 Hg3 O1 94.3(7) 2_665 . ?
O1 Hg3 Hg1 112.2(7) 3_565 . ?
O1 Hg3 Hg1 152.3(6) 2_665 . ?
O1 Hg3 Hg1 91.8(6) . . ?
O1 Hg3 Hg1 91.8(6) 3_565 3_565 ?
O1 Hg3 Hg1 112.2(7) 2_665 3_565 ?
O1 Hg3 Hg1 152.3(6) . 3_565 ?
Hg1 Hg3 Hg1 60.88(9) . 3_565 ?
O1 Hg3 Ag1 91.8(6) 3_565 3_565 ?
O1 Hg3 Ag1 112.2(7) 2_665 3_565 ?
O1 Hg3 Ag1 152.3(6) . 3_565 ?
Hg1 Hg3 Ag1 60.88(9) . 3_565 ?
Hg1 Hg3 Ag1 0.00(9) 3_565 3_565 ?
O1 Hg3 Hg1 152.3(6) 3_565 2_665 ?
O1 Hg3 Hg1 91.8(6) 2_665 2_665 ?
O1 Hg3 Hg1 112.2(7) . 2_665 ?
Hg1 Hg3 Hg1 60.88(9) . 2_665 ?
Hg1 Hg3 Hg1 60.88(9) 3_565 2_665 ?
Ag1 Hg3 Hg1 60.88(9) 3_565 2_665 ?
O1 Hg3 Ag1 152.3(6) 3_565 2_665 ?
O1 Hg3 Ag1 91.8(6) 2_665 2_665 ?
O1 Hg3 Ag1 112.2(7) . 2_665 ?
Hg1 Hg3 Ag1 60.88(9) . 2_665 ?
Hg1 Hg3 Ag1 60.88(9) 3_565 2_665 ?
Ag1 Hg3 Ag1 60.88(9) 3_565 2_665 ?
Hg1 Hg3 Ag1 0.00(9) 2_665 2_665 ?
O3 Hg4 O1 97.2(16) 4_564 4_554 ?
O3 Hg4 O6 105.3(6) 4_564 . ?
O1 Hg4 O6 92.3(9) 4_554 . ?
O3 Hg4 Ag2 124.5(12) 4_564 1_655 ?
O1 Hg4 Ag2 136.5(8) 4_554 1_655 ?
O6 Hg4 Ag2 88.1(6) . 1_655 ?
O3 Hg4 Hg2 124.5(12) 4_564 1_655 ?
O1 Hg4 Hg2 136.5(8) 4_554 1_655 ?
O6 Hg4 Hg2 88.1(6) . 1_655 ?
Ag2 Hg4 Hg2 0.00(6) 1_655 1_655 ?
O3 Hg4 Hg4 103.76(15) 4_564 3_665 ?
O1 Hg4 Hg4 103.4(5) 4_554 3_665 ?
O6 Hg4 Hg4 144.8(5) . 3_665 ?
Ag2 Hg4 Hg4 58.81(4) 1_655 3_665 ?
Hg2 Hg4 Hg4 58.81(4) 1_655 3_665 ?
O3 Hg4 Ag4 103.76(15) 4_564 3_665 ?
O1 Hg4 Ag4 103.4(5) 4_554 3_665 ?
O6 Hg4 Ag4 144.8(5) . 3_665 ?
Ag2 Hg4 Ag4 58.81(4) 1_655 3_665 ?
Hg2 Hg4 Ag4 58.81(4) 1_655 3_665 ?
Hg4 Hg4 Ag4 0.00(5) 3_665 3_665 ?
O3 Hg4 Hg4 160.4(8) 4_564 2_655 ?
O1 Hg4 Hg4 77.8(7) 4_554 2_655 ?
O6 Hg4 Hg4 93.88(11) . 2_655 ?
Ag2 Hg4 Hg4 58.81(4) 1_655 2_655 ?
Hg2 Hg4 Hg4 58.81(4) 1_655 2_655 ?
Hg4 Hg4 Hg4 60.0 3_665 2_655 ?
Ag4 Hg4 Hg4 60.0 3_665 2_655 ?
O3 Hg4 Ag4 160.4(8) 4_564 2_655 ?
O1 Hg4 Ag4 77.8(7) 4_554 2_655 ?
O6 Hg4 Ag4 93.88(11) . 2_655 ?
Ag2 Hg4 Ag4 58.81(4) 1_655 2_655 ?
Hg2 Hg4 Ag4 58.81(4) 1_655 2_655 ?
Hg4 Hg4 Ag4 60.0 3_665 2_655 ?
Ag4 Hg4 Ag4 60.0 3_665 2_655 ?
Hg4 Hg4 Ag4 0.00(5) 2_655 2_655 ?
O3 Hg4 Hg5 39.5(15) 4_564 4_564 ?
O1 Hg4 Hg5 59.9(8) 4_554 4_564 ?
O6 Hg4 Hg5 116.3(5) . 4_564 ?
Ag2 Hg4 Hg5 152.18(9) 1_655 4_564 ?
Hg2 Hg4 Hg5 152.18(9) 1_655 4_564 ?
Hg4 Hg4 Hg5 98.79(8) 3_665 4_564 ?
Ag4 Hg4 Hg5 98.79(8) 3_665 4_564 ?
Hg4 Hg4 Hg5 127.25(4) 2_655 4_564 ?
Ag4 Hg4 Hg5 127.25(4) 2_655 4_564 ?
O2 Hg5 O3 180.000(12) . . ?
O2 Hg5 Hg4 140.98(4) . 6_565 ?
O3 Hg5 Hg4 39.02(4) . 6_565 ?
O2 Hg5 Hg4 140.98(4) . 5 ?
O3 Hg5 Hg4 39.02(4) . 5 ?
Hg4 Hg5 Hg4 66.08(7) 6_565 5 ?
O2 Hg5 Hg4 140.98(4) . 4_455 ?
O3 Hg5 Hg4 39.02(4) . 4_455 ?
Hg4 Hg5 Hg4 66.08(7) 6_565 4_455 ?
Hg4 Hg5 Hg4 66.08(7) 5 4_455 ?
O5 As1 O5 107.0(6) 3 . ?
O5 As1 O5 107.0(6) 3 2 ?
O5 As1 O5 107.0(7) . 2 ?
O5 As1 O6 111.9(6) 3 . ?
O5 As1 O6 111.9(6) . . ?
O5 As1 O6 111.9(6) 2 . ?
O1 As2 O1 107.6(8) . 2 ?
O1 As2 O1 107.6(8) . 3 ?
O1 As2 O1 107.6(8) 2 3 ?
O1 As2 O4 111.3(7) . . ?
O1 As2 O4 111.3(7) 2 . ?
O1 As2 O4 111.3(7) 3 . ?
As2 O1 Hg3 126.6(11) . . ?
As2 O1 Ag4 124.4(12) . 4 ?
Hg3 O1 Ag4 105.4(8) . 4 ?
As2 O1 Hg4 124.4(12) . 4 ?
Hg3 O1 Hg4 105.4(8) . 4 ?
Ag4 O1 Hg4 0.00(3) 4 4 ?
Hg5 O2 Ag1 112.1(6) . 3_455 ?
Hg5 O2 Hg1 112.1(6) . 3_455 ?
Ag1 O2 Hg1 0.00(10) 3_455 3_455 ?
Hg5 O2 Hg1 112.1(6) . . ?
Ag1 O2 Hg1 106.8(7) 3_455 . ?
Hg1 O2 Hg1 106.8(7) 3_455 . ?
Hg5 O2 Hg1 112.1(6) . 2_565 ?
Ag1 O2 Hg1 106.8(7) 3_455 2_565 ?
Hg1 O2 Hg1 106.8(7) 3_455 2_565 ?
Hg1 O2 Hg1 106.8(7) . 2_565 ?
Hg5 O2 Ag1 112.1(6) . 2_565 ?
Ag1 O2 Ag1 106.8(7) 3_455 2_565 ?
Hg1 O2 Ag1 106.8(7) 3_455 2_565 ?
Hg1 O2 Ag1 106.8(7) . 2_565 ?
Hg1 O2 Ag1 0.00(11) 2_565 2_565 ?
Ag4 O3 Hg4 0.00(7) 5 5 ?
Ag4 O3 Ag4 116.2(9) 5 6_565 ?
Hg4 O3 Ag4 116.2(9) 5 6_565 ?
Ag4 O3 Hg4 116.2(9) 5 6_565 ?
Hg4 O3 Hg4 116.2(9) 5 6_565 ?
Ag4 O3 Hg4 0.00(12) 6_565 6_565 ?
Ag4 O3 Hg4 116.2(9) 5 4_455 ?
Hg4 O3 Hg4 116.2(9) 5 4_455 ?
Ag4 O3 Hg4 116.2(9) 6_565 4_455 ?
Hg4 O3 Hg4 116.2(9) 6_565 4_455 ?
Ag4 O3 Ag4 116.2(9) 5 4_455 ?
Hg4 O3 Ag4 116.2(9) 5 4_455 ?
Ag4 O3 Ag4 116.2(9) 6_565 4_455 ?
Hg4 O3 Ag4 116.2(9) 6_565 4_455 ?
Hg4 O3 Ag4 0.00(8) 4_455 4_455 ?
Ag4 O3 Hg5 101.5(15) 5 . ?
Hg4 O3 Hg5 101.5(15) 5 . ?
Ag4 O3 Hg5 101.5(15) 6_565 . ?
Hg4 O3 Hg5 101.5(15) 6_565 . ?
Hg4 O3 Hg5 101.5(15) 4_455 . ?
Ag4 O3 Hg5 101.5(15) 4_455 . ?
As2 O4 Ag1 113.6(6) . 2 ?
As2 O4 Hg1 113.6(6) . 2 ?
Ag1 O4 Hg1 0.00(8) 2 2 ?
As2 O4 Ag1 113.6(6) . 3 ?
Ag1 O4 Ag1 105.0(7) 2 3 ?
Hg1 O4 Ag1 105.0(7) 2 3 ?
As2 O4 Hg1 113.6(6) . 3 ?
Ag1 O4 Hg1 105.0(7) 2 3 ?
Hg1 O4 Hg1 105.0(7) 2 3 ?
Ag1 O4 Hg1 0.00(9) 3 3 ?
As2 O4 Hg1 113.6(6) . . ?
Ag1 O4 Hg1 105.0(7) 2 . ?
Hg1 O4 Hg1 105.0(7) 2 . ?
Ag1 O4 Hg1 105.0(7) 3 . ?
Hg1 O4 Hg1 105.0(7) 3 . ?
As1 O5 Hg1 117.2(10) . . ?
As1 O5 Hg2 123.0(9) . . ?
Hg1 O5 Hg2 110.8(8) . . ?
As1 O6 Ag4 114.9(7) . 3 ?
As1 O6 Hg4 114.9(7) . 3 ?
Ag4 O6 Hg4 0.00(10) 3 3 ?
As1 O6 Ag4 114.9(7) . 2 ?
Ag4 O6 Ag4 103.5(8) 3 2 ?
Hg4 O6 Ag4 103.5(8) 3 2 ?
As1 O6 Hg4 114.9(7) . 2 ?
Ag4 O6 Hg4 103.5(8) 3 2 ?
Hg4 O6 Hg4 103.5(8) 3 2 ?
Ag4 O6 Hg4 0.00(8) 2 2 ?
As1 O6 Hg4 114.9(7) . . ?
Ag4 O6 Hg4 103.5(8) 3 . ?
Hg4 O6 Hg4 103.5(8) 3 . ?
Ag4 O6 Hg4 103.5(8) 2 . ?
Hg4 O6 Hg4 103.5(8) 2 . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Hg1 O5 2.25(2) . ?
Hg1 O2 2.304(10) . ?
Hg1 O4 2.597(12) . ?
Hg1 Hg3 2.710(3) . ?
Hg1 Ag1 2.746(3) 2_665 ?
Hg1 Hg1 2.746(3) 2_665 ?
Hg1 Ag1 2.746(3) 3_565 ?
Hg1 Hg1 2.746(3) 3_565 ?
Hg2 O5 2.322(18) . ?
Hg2 O5 2.322(18) 2_565 ?
Hg2 O5 2.322(18) 3_455 ?
Hg2 Hg4 2.678(3) 2 ?
Hg2 Ag4 2.678(3) 2 ?
Hg2 Hg4 2.678(3) 3_565 ?
Hg2 Ag4 2.678(3) 3_565 ?
Hg2 Ag4 2.678(3) 1_455 ?
Hg2 Hg4 2.678(3) 1_455 ?
Hg3 O1 2.29(2) 3_565 ?
Hg3 O1 2.29(2) 2_665 ?
Hg3 O1 2.29(2) . ?
Hg3 Hg1 2.710(3) 3_565 ?
Hg3 Ag1 2.710(3) 3_565 ?
Hg3 Hg1 2.710(3) 2_665 ?
Hg3 Ag1 2.710(3) 2_665 ?
Hg4 O3 2.214(12) 4_564 ?
Hg4 O1 2.37(2) 4_554 ?
Hg4 O6 2.554(15) . ?
Hg4 Ag2 2.678(3) 1_655 ?
Hg4 Hg2 2.678(3) 1_655 ?
Hg4 Hg4 2.774(4) 3_665 ?
Hg4 Ag4 2.774(4) 3_665 ?
Hg4 Hg4 2.774(4) 2_655 ?
Hg4 Ag4 2.774(4) 2_655 ?
Hg4 Hg5 3.446(2) 4_564 ?
Hg5 O2 2.00(3) . ?
Hg5 O3 2.24(6) . ?
Hg5 Hg4 3.446(2) 6_565 ?
Hg5 Hg4 3.446(2) 5 ?
Hg5 Hg4 3.446(2) 4_455 ?
As1 O5 1.700(17) 3 ?
As1 O5 1.700(17) . ?
As1 O5 1.700(18) 2 ?
As1 O6 1.76(4) . ?
As2 O1 1.65(2) . ?
As2 O1 1.65(2) 2 ?
As2 O1 1.65(2) 3 ?
As2 O4 1.78(3) . ?
O1 Ag4 2.37(2) 4 ?
O1 Hg4 2.37(2) 4 ?
O2 Ag1 2.304(10) 3_455 ?
O2 Hg1 2.304(10) 3_455 ?
O2 Hg1 2.304(10) 2_565 ?
O2 Ag1 2.304(10) 2_565 ?
O3 Ag4 2.214(12) 5 ?
O3 Hg4 2.214(12) 5 ?
O3 Ag4 2.214(12) 6_565 ?
O3 Hg4 2.214(12) 6_565 ?
O3 Hg4 2.214(12) 4_455 ?
O3 Ag4 2.214(12) 4_455 ?
O4 Ag1 2.597(12) 2 ?
O4 Hg1 2.597(12) 2 ?
O4 Ag1 2.597(12) 3 ?
O4 Hg1 2.597(12) 3 ?
O6 Ag4 2.554(15) 3 ?
O6 Hg4 2.554(15) 3 ?
O6 Ag4 2.554(15) 2 ?
O6 Hg4 2.554(15) 2 ?
