#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:43:47 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179125 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/87/4308705.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308705
loop_
_publ_author_name
'Nicola Oberbeckmann-Winter'
'Xavier Morise'
'Pierre Braunstein'
'Richard Welter'
_publ_contact_author_address
;
Institut Le Bel, rue Blaise Pascal,
67000 STRASBOURG, FRANCE
;
_publ_contact_author_email       braunst@chimie.u-strasbg.fr
_publ_contact_author_fax         0390241322
_publ_contact_author_name        'Pierre Braunstein'
_publ_contact_author_phone       0390241308
_publ_section_title
;
Synthesis and Structure of Pt(II) Phosphonato-Phosphine Complexes and of a
P,O-Stabilized Metal-Metal-Bonded Pt2Ag2 Complex
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1391
_journal_page_last               1403
_journal_paper_doi               10.1021/ic0485559
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C96 H110 Ag2 F6 O18 P8 Pt2 S2, 2(C F3 S O3)'
_chemical_formula_sum            'C98 H110 Ag2 F12 O24 P8 Pt2 S4'
_chemical_formula_weight         2881.78
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.958(5)
_cell_angle_beta                 109.643(5)
_cell_angle_gamma                94.520(5)
_cell_formula_units_Z            1
_cell_length_a                   13.550(5)
_cell_length_b                   14.827(5)
_cell_length_c                   15.009(5)
_cell_measurement_reflns_used    63025
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.034
_cell_measurement_theta_min      0.998
_cell_volume                     2828.1(17)
_computing_cell_refinement       'Denzo (Nonius B.V., 1998)'
_computing_data_collection       'Collect (Nonius B.V., 1998)'
_computing_data_reduction        'Denzo (Nonius B.V., 1998)'
_computing_molecular_graphics    'PLATON 98 (Spek, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'π scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.038
_diffrn_reflns_av_sigmaI/netI    0.0925
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            16465
_diffrn_reflns_theta_full        30.04
_diffrn_reflns_theta_max         30.04
_diffrn_reflns_theta_min         1.38
_exptl_absorpt_coefficient_mu    3.081
_exptl_absorpt_correction_T_max  0.547
_exptl_absorpt_correction_T_min  0.498
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
multi-scan from symmetry-related measurements
Sortav (Blessing 1995)
;
_exptl_crystal_colour            Off-white
_exptl_crystal_density_diffrn    1.692
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1432
_exptl_crystal_size_max          0.13
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.829
_refine_diff_density_min         -1.848
_refine_diff_density_rms         0.313
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.124
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     658
_refine_ls_number_reflns         16464
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.124
_refine_ls_R_factor_all          0.0711
_refine_ls_R_factor_gt           0.0499
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0558P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1175
_refine_ls_wR_factor_ref         0.1381
_reflns_number_gt                13584
_reflns_number_total             16464
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0485559si20041211_103736_1.cif
_cod_data_source_block           complex_8
_cod_database_code               4308705
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt Pt 0.381858(14) 0.195146(12) 0.828172(12) 0.02088(6) Uani 1 1 d . . .
Ag Ag 0.43889(4) 0.38053(3) 0.88010(4) 0.04383(12) Uani 1 1 d . . .
P1 P 0.33271(10) 0.17749(8) 0.95870(9) 0.0225(2) Uani 1 1 d . . .
P3 P 0.42792(10) 0.20200(8) 0.69292(9) 0.0233(2) Uani 1 1 d . . .
P2 P 0.14980(10) 0.22957(9) 0.80595(9) 0.0264(3) Uani 1 1 d . . .
P4 P 0.39918(13) 0.40162(9) 0.64228(11) 0.0348(3) Uani 1 1 d . . .
S1 S 0.67674(12) 0.46635(9) 1.01161(11) 0.0389(3) Uani 1 1 d . . .
S2 S 0.00199(14) 0.23824(12) 0.48877(11) 0.0467(4) Uani 1 1 d . . .
C1 C 0.2153(4) 0.2429(3) 0.9333(3) 0.0250(9) Uani 1 1 d . . .
H1 H 0.2447 0.3077 0.9446 0.030 Uiso 1 1 calc . . .
O1 O 0.2290(3) 0.2463(3) 0.7575(2) 0.0308(8) Uani 1 1 d . . .
O2 O 0.0924(3) 0.1325(3) 0.7914(3) 0.0343(8) Uani 1 1 d . . .
O3 O 0.0607(3) 0.2942(3) 0.7744(3) 0.0339(8) Uani 1 1 d . . .
C42 C 0.2145(6) -0.0098(5) 0.5640(5) 0.0507(17) Uani 1 1 d . . .
H42 H 0.1400 -0.0192 0.5373 0.061 Uiso 1 1 calc . . .
C25 C 0.3620(4) 0.2832(3) 0.6030(3) 0.0269(10) Uani 1 1 d . . .
H25 H 0.2859 0.2735 0.5964 0.032 Uiso 1 1 calc . . .
C41 C 0.2736(7) -0.0814(5) 0.5692(6) 0.062(2) Uani 1 1 d . . .
H41 H 0.2406 -0.1399 0.5451 0.074 Uiso 1 1 calc . . .
C14 C 0.2956(4) 0.0628(3) 0.9805(4) 0.0300(11) Uani 1 1 d . . .
C7 C 0.0880(4) 0.1507(4) 0.9959(4) 0.0325(11) Uani 1 1 d . . .
H7 H 0.0851 0.1018 0.9531 0.039 Uiso 1 1 calc . . .
C15 C 0.2842(5) 0.0418(4) 1.0679(4) 0.0369(12) Uani 1 1 d . . .
H15 H 0.3000 0.0873 1.1171 0.044 Uiso 1 1 calc . . .
C38 C 0.3715(4) 0.0905(3) 0.6364(4) 0.0305(11) Uani 1 1 d . . .
C32 C 0.5673(4) 0.2142(4) 0.7067(4) 0.0288(10) Uani 1 1 d . . .
O5 O 0.5149(3) 0.4183(3) 0.6448(3) 0.0425(10) Uani 1 1 d . . .
C17 C 0.2267(5) -0.1114(4) 1.0104(6) 0.0504(18) Uani 1 1 d . . .
H17 H 0.2030 -0.1712 1.0203 0.060 Uiso 1 1 calc . . .
C27 C 0.4540(5) 0.2808(4) 0.4800(4) 0.0376(12) Uani 1 1 d . . .
H27 H 0.5169 0.3075 0.5261 0.045 Uiso 1 1 calc . . .
C8 C 0.4286(4) 0.2213(4) 1.0699(4) 0.0316(11) Uani 1 1 d . . .
O4 O 0.3813(4) 0.4253(3) 0.7314(3) 0.0533(12) Uani 1 1 d . . .
C11 C 0.5996(6) 0.2911(8) 1.2245(5) 0.072(3) Uani 1 1 d . . .
H11 H 0.6585 0.3155 1.2766 0.087 Uiso 1 1 calc . . .
O7 O 0.5868(5) 0.4069(4) 1.0078(4) 0.070 Uiso 1 1 d . . .
C39 C 0.4308(6) 0.0174(4) 0.6442(5) 0.0476(15) Uani 1 1 d . . .
H39 H 0.5052 0.0254 0.6730 0.057 Uiso 1 1 calc . . .
C26 C 0.3643(5) 0.2625(3) 0.5040(4) 0.0315(11) Uani 1 1 d . . .
C2 C 0.1486(4) 0.2313(4) 0.9958(3) 0.0274(10) Uani 1 1 d . . .
C47 C 0.2549(9) 0.5943(8) 0.5199(8) 0.100 Uiso 1 1 d . . .
H47A H 0.1923 0.6260 0.5134 0.150 Uiso 1 1 calc . . .
H47B H 0.2673 0.5927 0.4593 0.150 Uiso 1 1 calc . . .
H47C H 0.3160 0.6262 0.5684 0.150 Uiso 1 1 calc . . .
O11 O -0.0812(4) 0.2465(4) 0.5269(3) 0.0569(12) Uani 1 1 d . . .
C31 C 0.2736(5) 0.2242(5) 0.4350(4) 0.0474(15) Uani 1 1 d . . .
H31 H 0.2111 0.2118 0.4498 0.057 Uiso 1 1 calc . . .
C33 C 0.6347(4) 0.2688(4) 0.7806(4) 0.0360(12) Uani 1 1 d . . .
H33 H 0.6078 0.2979 0.8233 0.043 Uiso 1 1 calc . . .
O6 O 0.3364(4) 0.4576(3) 0.5581(4) 0.0538(12) Uani 1 1 d . . .
C5 C 0.0332(5) 0.2124(6) 1.1175(5) 0.0539(18) Uani 1 1 d . . .
H5 H -0.0068 0.2063 1.1587 0.065 Uiso 1 1 calc . . .
C3 C 0.1495(5) 0.3026(4) 1.0579(4) 0.0404(13) Uani 1 1 d . . .
H3 H 0.1898 0.3582 1.0588 0.048 Uiso 1 1 calc . . .
C13 C 0.5071(5) 0.1655(5) 1.1184(4) 0.0453(15) Uani 1 1 d . . .
H13 H 0.5027 0.1038 1.0984 0.054 Uiso 1 1 calc . . .
C37 C 0.6069(5) 0.1721(4) 0.6432(4) 0.0411(13) Uani 1 1 d . . .
H37 H 0.5612 0.1350 0.5912 0.049 Uiso 1 1 calc . . .
C43 C 0.2614(5) 0.0765(4) 0.5970(4) 0.0383(13) Uani 1 1 d . . .
H43 H 0.2194 0.1256 0.5930 0.046 Uiso 1 1 calc . . .
O10 O 0.0954(4) 0.2958(5) 0.5322(4) 0.0759(18) Uani 1 1 d . . .
C28 C 0.4524(6) 0.2602(4) 0.3889(5) 0.0489(16) Uani 1 1 d . . .
H28 H 0.5146 0.2723 0.3735 0.059 Uiso 1 1 calc . . .
C6 C 0.0324(5) 0.1414(5) 1.0574(4) 0.0416(14) Uani 1 1 d . . .
H6 H -0.0067 0.0856 1.0582 0.050 Uiso 1 1 calc . . .
C46 C 0.2376(7) 0.4948(7) 0.5500(9) 0.100(4) Uani 1 1 d . . .
H46A H 0.2249 0.4945 0.6112 0.120 Uiso 1 1 calc . . .
H46B H 0.1775 0.4603 0.5012 0.120 Uiso 1 1 calc . . .
C18 C 0.2374(5) -0.0916(4) 0.9243(5) 0.0472(16) Uani 1 1 d . . .
H18 H 0.2219 -0.1378 0.8757 0.057 Uiso 1 1 calc . . .
C20 C 0.0249(5) 0.0918(5) 0.6986(4) 0.0469(15) Uani 1 1 d . . .
H20A H -0.0247 0.1351 0.6638 0.056 Uiso 1 1 calc . . .
H20B H 0.0684 0.0760 0.6602 0.056 Uiso 1 1 calc . . .
C40 C 0.3809(8) -0.0679(5) 0.6096(7) 0.069(2) Uani 1 1 d . . .
H40 H 0.4220 -0.1177 0.6141 0.083 Uiso 1 1 calc . . .
C19 C 0.2707(4) -0.0043(4) 0.9091(4) 0.0342(12) Uani 1 1 d . . .
H19 H 0.2766 0.0096 0.8494 0.041 Uiso 1 1 calc . . .
C9 C 0.4369(5) 0.3111(4) 1.1010(4) 0.0397(13) Uani 1 1 d . . .
H9 H 0.3839 0.3494 1.0699 0.048 Uiso 1 1 calc . . .
C4 C 0.0922(6) 0.2926(5) 1.1179(5) 0.0530(17) Uani 1 1 d . . .
H4 H 0.0933 0.3414 1.1601 0.064 Uiso 1 1 calc . . .
C29 C 0.3621(7) 0.2226(5) 0.3208(5) 0.062(2) Uani 1 1 d . . .
H29 H 0.3613 0.2098 0.2583 0.074 Uiso 1 1 calc . . .
F4 F 0.0175(5) 0.2813(5) 0.3261(3) 0.104(2) Uani 1 1 d . . .
F6 F -0.0761(6) 0.3636(4) 0.3735(4) 0.116(2) Uani 1 1 d . . .
C34 C 0.7418(5) 0.2821(4) 0.7940(5) 0.0472(15) Uani 1 1 d . . .
H34 H 0.7875 0.3202 0.8452 0.057 Uiso 1 1 calc . . .
C22 C 0.0762(5) 0.3839(4) 0.7381(5) 0.0422(14) Uani 1 1 d . . .
H22A H 0.1385 0.4191 0.7835 0.051 Uiso 1 1 calc . . .
H22B H 0.0882 0.3771 0.6769 0.051 Uiso 1 1 calc . . .
C23 C -0.0177(6) 0.4311(5) 0.7255(6) 0.060 Uiso 1 1 d . . .
H23A H -0.0083 0.4914 0.7021 0.090 Uiso 1 1 calc . . .
H23B H -0.0292 0.4372 0.7863 0.090 Uiso 1 1 calc . . .
H23C H -0.0787 0.3965 0.6796 0.090 Uiso 1 1 calc . . .
C12 C 0.5916(6) 0.2021(7) 1.1965(5) 0.066(2) Uani 1 1 d . . .
H12 H 0.6439 0.1645 1.2304 0.079 Uiso 1 1 calc . . .
O9 O 0.6870(5) 0.4807(4) 0.9211(4) 0.0654(14) Uani 1 1 d . . .
C35 C 0.7811(5) 0.2392(5) 0.7320(6) 0.059(2) Uani 1 1 d . . .
H35 H 0.8542 0.2471 0.7414 0.070 Uiso 1 1 calc . . .
C49 C -0.0512(7) 0.2795(6) 0.3707(5) 0.064(2) Uani 1 1 d . . .
C16 C 0.2497(5) -0.0461(4) 1.0817(5) 0.0464(16) Uani 1 1 d . . .
H16 H 0.2421 -0.0607 1.1406 0.056 Uiso 1 1 calc . . .
F5 F -0.1366(5) 0.2316(6) 0.3190(4) 0.118(2) Uani 1 1 d . . .
O12 O 0.0202(5) 0.1473(4) 0.4716(5) 0.0810(18) Uani 1 1 d . . .
C10 C 0.5241(7) 0.3449(6) 1.1785(5) 0.063(2) Uani 1 1 d . . .
H10 H 0.5304 0.4067 1.1991 0.075 Uiso 1 1 calc . . .
C30 C 0.2735(7) 0.2038(6) 0.3436(5) 0.065(2) Uani 1 1 d . . .
H30 H 0.2112 0.1767 0.2971 0.078 Uiso 1 1 calc . . .
C21 C -0.0333(8) 0.0099(6) 0.7159(6) 0.089(3) Uani 1 1 d . . .
H21A H -0.0799 -0.0183 0.6553 0.133 Uiso 1 1 calc . . .
H21B H -0.0754 0.0263 0.7546 0.133 Uiso 1 1 calc . . .
H21C H 0.0165 -0.0328 0.7494 0.133 Uiso 1 1 calc . . .
C36 C 0.7147(6) 0.1853(6) 0.6571(5) 0.0560(18) Uani 1 1 d . . .
H36 H 0.7421 0.1568 0.6144 0.067 Uiso 1 1 calc . . .
C44 C 0.5677(8) 0.5091(5) 0.6537(9) 0.097(4) Uani 1 1 d . . .
H44A H 0.5459 0.5354 0.5905 0.117 Uiso 1 1 calc . . .
H44B H 0.5434 0.5471 0.6957 0.117 Uiso 1 1 calc . . .
C45 C 0.6771(7) 0.5135(6) 0.6893(7) 0.081(3) Uani 1 1 d . . .
H45A H 0.7061 0.5766 0.6929 0.121 Uiso 1 1 calc . . .
H45B H 0.7023 0.4775 0.6473 0.121 Uiso 1 1 calc . . .
H45C H 0.6998 0.4893 0.7527 0.121 Uiso 1 1 calc . . .
C24 C 0.5181(5) 0.1402(4) 0.8978(4) 0.0384(13) Uani 1 1 d . . .
H24A H 0.5050 0.0943 0.9397 0.058 Uiso 1 1 calc . . .
H24B H 0.5705 0.1878 0.9355 0.058 Uiso 1 1 calc . . .
H24C H 0.5445 0.1119 0.8518 0.058 Uiso 1 1 calc . . .
C48 C 0.7839(10) 0.4014(6) 1.0741(8) 0.094(4) Uani 1 1 d . . .
F3 F 0.7923(6) 0.3934(4) 1.1629(4) 0.119(3) Uani 1 1 d . . .
F1 F 0.7757(9) 0.3240(5) 1.0330(7) 0.246(7) Uani 1 1 d . . .
F2 F 0.8744(6) 0.4451(7) 1.0746(5) 0.142(3) Uani 1 1 d . . .
O8 O 0.6948(4) 0.5467(3) 1.0724(3) 0.0517(12) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C24 Pt O1 175.62(19) . . ?
C24 Pt P1 89.05(16) . . ?
O1 Pt P1 87.72(10) . . ?
C24 Pt P3 90.20(16) . . ?
O1 Pt P3 92.81(10) . . ?
P1 Pt P3 175.84(4) . . ?
C24 Pt Ag 101.50(19) . . ?
O1 Pt Ag 81.45(11) . . ?
P1 Pt Ag 89.72(3) . . ?
P3 Pt Ag 94.44(3) . . ?
O4 Ag O7 136.5(2) . . ?
O4 Ag O8 94.57(17) . 2_667 ?
O7 Ag O8 103.54(18) . 2_667 ?
O4 Ag Pt 94.47(11) . . ?
O7 Ag Pt 113.51(15) . . ?
O8 Ag Pt 112.74(11) 2_667 . ?
C14 P1 C8 104.8(3) . . ?
C14 P1 C1 108.3(2) . . ?
C8 P1 C1 108.3(2) . . ?
C14 P1 Pt 115.68(18) . . ?
C8 P1 Pt 115.84(17) . . ?
C1 P1 Pt 103.68(16) . . ?
C32 P3 C38 108.5(2) . . ?
C32 P3 C25 107.0(2) . . ?
C38 P3 C25 104.0(2) . . ?
C32 P3 Pt 118.33(17) . . ?
C38 P3 Pt 100.38(17) . . ?
C25 P3 Pt 117.10(16) . . ?
O1 P2 O3 112.3(2) . . ?
O1 P2 O2 116.2(2) . . ?
O3 P2 O2 105.3(2) . . ?
O1 P2 C1 109.4(2) . . ?
O3 P2 C1 109.6(2) . . ?
O2 P2 C1 103.6(2) . . ?
O4 P4 O5 115.4(3) . . ?
O4 P4 O6 112.6(3) . . ?
O5 P4 O6 103.8(3) . . ?
O4 P4 C25 113.7(2) . . ?
O5 P4 C25 104.3(2) . . ?
O6 P4 C25 105.9(3) . . ?
O9 S1 O7 113.8(3) . . ?
O9 S1 O8 115.1(3) . . ?
O7 S1 O8 115.1(3) . . ?
O9 S1 C48 105.7(5) . . ?
O7 S1 C48 102.1(5) . . ?
O8 S1 C48 102.9(4) . . ?
O10 S2 O12 113.8(4) . . ?
O10 S2 O11 116.0(3) . . ?
O12 S2 O11 114.3(4) . . ?
O10 S2 C49 104.1(4) . . ?
O12 S2 C49 103.1(4) . . ?
O11 S2 C49 103.4(3) . . ?
C2 C1 P2 118.0(4) . . ?
C2 C1 P1 118.3(3) . . ?
P2 C1 P1 105.2(2) . . ?
C2 C1 H1 104.6 . . ?
P2 C1 H1 104.6 . . ?
P1 C1 H1 104.6 . . ?
P2 O1 Pt 115.33(19) . . ?
C20 O2 P2 123.8(4) . . ?
C22 O3 P2 122.3(4) . . ?
C41 C42 C43 121.2(7) . . ?
C41 C42 H42 119.4 . . ?
C43 C42 H42 119.4 . . ?
C26 C25 P4 113.4(3) . . ?
C26 C25 P3 114.4(3) . . ?
P4 C25 P3 113.9(3) . . ?
C26 C25 H25 104.6 . . ?
P4 C25 H25 104.6 . . ?
P3 C25 H25 104.6 . . ?
C42 C41 C40 119.2(6) . . ?
C42 C41 H41 120.4 . . ?
C40 C41 H41 120.4 . . ?
C19 C14 C15 119.2(5) . . ?
C19 C14 P1 120.3(4) . . ?
C15 C14 P1 120.4(4) . . ?
C6 C7 C2 120.6(5) . . ?
C6 C7 H7 119.7 . . ?
C2 C7 H7 119.7 . . ?
C16 C15 C14 119.7(6) . . ?
C16 C15 H15 120.2 . . ?
C14 C15 H15 120.2 . . ?
C39 C38 C43 119.3(5) . . ?
C39 C38 P3 122.6(5) . . ?
C43 C38 P3 117.4(4) . . ?
C33 C32 C37 119.4(5) . . ?
C33 C32 P3 118.3(4) . . ?
C37 C32 P3 122.2(4) . . ?
C44 O5 P4 121.9(5) . . ?
C16 C17 C18 121.0(6) . . ?
C16 C17 H17 119.5 . . ?
C18 C17 H17 119.5 . . ?
C28 C27 C26 120.4(6) . . ?
C28 C27 H27 119.8 . . ?
C26 C27 H27 119.8 . . ?
C9 C8 C13 119.1(5) . . ?
C9 C8 P1 122.3(4) . . ?
C13 C8 P1 117.8(4) . . ?
P4 O4 Ag 135.6(3) . . ?
C10 C11 C12 120.3(7) . . ?
C10 C11 H11 119.9 . . ?
C12 C11 H11 119.9 . . ?
S1 O7 Ag 125.2(3) . . ?
C38 C39 C40 119.5(7) . . ?
C38 C39 H39 120.2 . . ?
C40 C39 H39 120.2 . . ?
C31 C26 C27 118.5(5) . . ?
C31 C26 C25 119.0(5) . . ?
C27 C26 C25 122.5(5) . . ?
C3 C2 C7 118.4(5) . . ?
C3 C2 C1 119.1(5) . . ?
C7 C2 C1 122.5(5) . . ?
C46 C47 H47A 109.5 . . ?
C46 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
C46 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C26 C31 C30 120.3(7) . . ?
C26 C31 H31 119.8 . . ?
C30 C31 H31 119.8 . . ?
C32 C33 C34 121.1(6) . . ?
C32 C33 H33 119.4 . . ?
C34 C33 H33 119.4 . . ?
C46 O6 P4 124.5(6) . . ?
C6 C5 C4 119.7(6) . . ?
C6 C5 H5 120.1 . . ?
C4 C5 H5 120.1 . . ?
C4 C3 C2 120.2(6) . . ?
C4 C3 H3 119.9 . . ?
C2 C3 H3 119.9 . . ?
C12 C13 C8 119.2(7) . . ?
C12 C13 H13 120.4 . . ?
C8 C13 H13 120.4 . . ?
C36 C37 C32 119.3(6) . . ?
C36 C37 H37 120.3 . . ?
C32 C37 H37 120.3 . . ?
C42 C43 C38 119.4(6) . . ?
C42 C43 H43 120.3 . . ?
C38 C43 H43 120.3 . . ?
C29 C28 C27 120.8(6) . . ?
C29 C28 H28 119.6 . . ?
C27 C28 H28 119.6 . . ?
C5 C6 C7 120.3(6) . . ?
C5 C6 H6 119.8 . . ?
C7 C6 H6 119.8 . . ?
O6 C46 C47 103.0(8) . . ?
O6 C46 H46A 111.2 . . ?
C47 C46 H46A 111.2 . . ?
O6 C46 H46B 111.2 . . ?
C47 C46 H46B 111.2 . . ?
H46A C46 H46B 109.1 . . ?
C17 C18 C19 119.8(6) . . ?
C17 C18 H18 120.1 . . ?
C19 C18 H18 120.1 . . ?
C21 C20 O2 107.5(5) . . ?
C21 C20 H20A 110.2 . . ?
O2 C20 H20A 110.2 . . ?
C21 C20 H20B 110.2 . . ?
O2 C20 H20B 110.2 . . ?
H20A C20 H20B 108.5 . . ?
C41 C40 C39 121.3(7) . . ?
C41 C40 H40 119.3 . . ?
C39 C40 H40 119.3 . . ?
C18 C19 C14 120.3(6) . . ?
C18 C19 H19 119.8 . . ?
C14 C19 H19 119.8 . . ?
C8 C9 C10 119.5(7) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 H9 120.3 . . ?
C3 C4 C5 120.7(6) . . ?
C3 C4 H4 119.6 . . ?
C5 C4 H4 119.6 . . ?
C30 C29 C28 119.4(6) . . ?
C30 C29 H29 120.3 . . ?
C28 C29 H29 120.3 . . ?
C35 C34 C33 119.4(6) . . ?
C35 C34 H34 120.3 . . ?
C33 C34 H34 120.3 . . ?
C23 C22 O3 108.4(5) . . ?
C23 C22 H22A 110.0 . . ?
O3 C22 H22A 110.0 . . ?
C23 C22 H22B 110.0 . . ?
O3 C22 H22B 110.0 . . ?
H22A C22 H22B 108.4 . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C11 C12 C13 120.8(7) . . ?
C11 C12 H12 119.6 . . ?
C13 C12 H12 119.6 . . ?
C36 C35 C34 120.3(6) . . ?
C36 C35 H35 119.9 . . ?
C34 C35 H35 119.9 . . ?
F5 C49 F4 108.7(7) . . ?
F5 C49 F6 106.5(8) . . ?
F4 C49 F6 105.8(8) . . ?
F5 C49 S2 112.4(6) . . ?
F4 C49 S2 111.9(6) . . ?
F6 C49 S2 111.2(6) . . ?
C17 C16 C15 119.9(6) . . ?
C17 C16 H16 120.0 . . ?
C15 C16 H16 120.0 . . ?
C11 C10 C9 121.1(7) . . ?
C11 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C29 C30 C31 120.6(7) . . ?
C29 C30 H30 119.7 . . ?
C31 C30 H30 119.7 . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C35 C36 C37 120.5(6) . . ?
C35 C36 H36 119.8 . . ?
C37 C36 H36 119.8 . . ?
C45 C44 O5 114.8(8) . . ?
C45 C44 H44A 108.6 . . ?
O5 C44 H44A 108.6 . . ?
C45 C44 H44B 108.6 . . ?
O5 C44 H44B 108.6 . . ?
H44A C44 H44B 107.5 . . ?
C44 C45 H45A 109.5 . . ?
C44 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
C44 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
Pt C24 H24A 109.5 . . ?
Pt C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
Pt C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
F1 C48 F3 110.8(10) . . ?
F1 C48 F2 107.3(13) . . ?
F3 C48 F2 106.2(8) . . ?
F1 C48 S1 111.2(7) . . ?
F3 C48 S1 112.2(9) . . ?
F2 C48 S1 108.9(8) . . ?
S1 O8 Ag 126.3(3) . 2_667 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt C24 2.033(5) . ?
Pt O1 2.188(3) . ?
Pt P1 2.2840(14) . ?
Pt P3 2.3172(14) . ?
Pt Ag 2.8193(10) . ?
Ag O4 2.234(5) . ?
Ag O7 2.261(6) . ?
Ag O8 2.471(5) 2_667 ?
P1 C14 1.801(5) . ?
P1 C8 1.808(5) . ?
P1 C1 1.861(5) . ?
P3 C32 1.824(5) . ?
P3 C38 1.832(5) . ?
P3 C25 1.867(5) . ?
P2 O1 1.493(4) . ?
P2 O3 1.554(4) . ?
P2 O2 1.556(4) . ?
P2 C1 1.816(5) . ?
P4 O4 1.479(4) . ?
P4 O5 1.556(5) . ?
P4 O6 1.560(5) . ?
P4 C25 1.819(5) . ?
S1 O9 1.429(5) . ?
S1 O7 1.431(6) . ?
S1 O8 1.441(4) . ?
S1 C48 1.803(10) . ?
S2 O10 1.419(6) . ?
S2 O12 1.425(6) . ?
S2 O11 1.438(5) . ?
S2 C49 1.811(8) . ?
C1 C2 1.509(7) . ?
C1 H1 1.0000 . ?
O2 C20 1.473(7) . ?
O3 C22 1.472(7) . ?
C42 C41 1.367(11) . ?
C42 C43 1.387(8) . ?
C42 H42 0.9500 . ?
C25 C26 1.523(7) . ?
C25 H25 1.0000 . ?
C41 C40 1.371(12) . ?
C41 H41 0.9500 . ?
C14 C19 1.387(8) . ?
C14 C15 1.409(8) . ?
C7 C6 1.376(8) . ?
C7 C2 1.396(7) . ?
C7 H7 0.9500 . ?
C15 C16 1.391(8) . ?
C15 H15 0.9500 . ?
C38 C39 1.382(8) . ?
C38 C43 1.405(8) . ?
C32 C33 1.377(8) . ?
C32 C37 1.401(7) . ?
O5 C44 1.456(9) . ?
C17 C16 1.369(10) . ?
C17 C18 1.381(10) . ?
C17 H17 0.9500 . ?
C27 C28 1.389(8) . ?
C27 C26 1.389(8) . ?
C27 H27 0.9500 . ?
C8 C9 1.386(8) . ?
C8 C13 1.408(8) . ?
C11 C10 1.354(13) . ?
C11 C12 1.363(13) . ?
C11 H11 0.9500 . ?
C39 C40 1.390(10) . ?
C39 H39 0.9500 . ?
C26 C31 1.385(8) . ?
C2 C3 1.393(7) . ?
C47 C46 1.573(15) . ?
C47 H47A 0.9800 . ?
C47 H47B 0.9800 . ?
C47 H47C 0.9800 . ?
C31 C30 1.399(9) . ?
C31 H31 0.9500 . ?
C33 C34 1.394(8) . ?
C33 H33 0.9500 . ?
O6 C46 1.457(10) . ?
C5 C6 1.372(10) . ?
C5 C4 1.378(10) . ?
C5 H5 0.9500 . ?
C3 C4 1.376(8) . ?
C3 H3 0.9500 . ?
C13 C12 1.399(10) . ?
C13 H13 0.9500 . ?
C37 C36 1.400(9) . ?
C37 H37 0.9500 . ?
C43 H43 0.9500 . ?
C28 C29 1.373(11) . ?
C28 H28 0.9500 . ?
C6 H6 0.9500 . ?
C46 H46A 0.9900 . ?
C46 H46B 0.9900 . ?
C18 C19 1.385(8) . ?
C18 H18 0.9500 . ?
C20 C21 1.470(11) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C40 H40 0.9500 . ?
C19 H19 0.9500 . ?
C9 C10 1.402(9) . ?
C9 H9 0.9500 . ?
C4 H4 0.9500 . ?
C29 C30 1.366(11) . ?
C29 H29 0.9500 . ?
F4 C49 1.315(9) . ?
F6 C49 1.322(10) . ?
C34 C35 1.385(10) . ?
C34 H34 0.9500 . ?
C22 C23 1.459(10) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C12 H12 0.9500 . ?
C35 C36 1.375(11) . ?
C35 H35 0.9500 . ?
C49 F5 1.301(10) . ?
C16 H16 0.9500 . ?
C10 H10 0.9500 . ?
C30 H30 0.9500 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C36 H36 0.9500 . ?
C44 C45 1.392(13) . ?
C44 H44A 0.9900 . ?
C44 H44B 0.9900 . ?
C45 H45A 0.9800 . ?
C45 H45B 0.9800 . ?
C45 H45C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C48 F1 1.273(10) . ?
C48 F3 1.308(13) . ?
C48 F2 1.338(14) . ?
O8 Ag 2.471(5) 2_667 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C24 Pt Ag O4 128.7(2) . . . . ?
O1 Pt Ag O4 -54.60(16) . . . . ?
P1 Pt Ag O4 -142.34(14) . . . . ?
P3 Pt Ag O4 37.58(14) . . . . ?
C24 Pt Ag O7 -17.1(2) . . . . ?
O1 Pt Ag O7 159.59(19) . . . . ?
P1 Pt Ag O7 71.85(17) . . . . ?
P3 Pt Ag O7 -108.23(17) . . . . ?
C24 Pt Ag O8 -134.5(2) . . . 2_667 ?
O1 Pt Ag O8 42.26(15) . . . 2_667 ?
P1 Pt Ag O8 -45.48(12) . . . 2_667 ?
P3 Pt Ag O8 134.43(12) . . . 2_667 ?
C24 Pt P1 C14 -72.4(3) . . . . ?
O1 Pt P1 C14 104.6(2) . . . . ?
P3 Pt P1 C14 7.2(7) . . . . ?
Ag Pt P1 C14 -173.95(19) . . . . ?
C24 Pt P1 C8 50.7(3) . . . . ?
O1 Pt P1 C8 -132.2(2) . . . . ?
P3 Pt P1 C8 130.4(6) . . . . ?
Ag Pt P1 C8 -50.8(2) . . . . ?
C24 Pt P1 C1 169.1(3) . . . . ?
O1 Pt P1 C1 -13.82(19) . . . . ?
P3 Pt P1 C1 -111.2(6) . . . . ?
Ag Pt P1 C1 67.64(16) . . . . ?
C24 Pt P3 C32 -28.6(3) . . . . ?
O1 Pt P3 C32 154.6(2) . . . . ?
P1 Pt P3 C32 -108.3(6) . . . . ?
Ag Pt P3 C32 72.9(2) . . . . ?
C24 Pt P3 C38 89.1(3) . . . . ?
O1 Pt P3 C38 -87.7(2) . . . . ?
P1 Pt P3 C38 9.5(7) . . . . ?
Ag Pt P3 C38 -169.34(18) . . . . ?
C24 Pt P3 C25 -159.1(3) . . . . ?
O1 Pt P3 C25 24.1(2) . . . . ?
P1 Pt P3 C25 121.2(6) . . . . ?
Ag Pt P3 C25 -57.56(19) . . . . ?
O1 P2 C1 C2 178.4(4) . . . . ?
O3 P2 C1 C2 54.8(4) . . . . ?
O2 P2 C1 C2 -57.2(4) . . . . ?
O1 P2 C1 P1 -47.2(3) . . . . ?
O3 P2 C1 P1 -170.7(2) . . . . ?
O2 P2 C1 P1 77.3(3) . . . . ?
C14 P1 C1 C2 44.7(4) . . . . ?
C8 P1 C1 C2 -68.4(4) . . . . ?
Pt P1 C1 C2 168.1(3) . . . . ?
C14 P1 C1 P2 -89.6(3) . . . . ?
C8 P1 C1 P2 157.4(2) . . . . ?
Pt P1 C1 P2 33.8(2) . . . . ?
O3 P2 O1 Pt 159.9(2) . . . . ?
O2 P2 O1 Pt -78.9(3) . . . . ?
C1 P2 O1 Pt 37.9(3) . . . . ?
C24 Pt O1 P2 29(3) . . . . ?
P1 Pt O1 P2 -13.8(2) . . . . ?
P3 Pt O1 P2 162.0(2) . . . . ?
Ag Pt O1 P2 -103.9(2) . . . . ?
O1 P2 O2 C20 -62.1(5) . . . . ?
O3 P2 O2 C20 62.8(5) . . . . ?
C1 P2 O2 C20 177.9(5) . . . . ?
O1 P2 O3 C22 -25.9(5) . . . . ?
O2 P2 O3 C22 -153.1(4) . . . . ?
C1 P2 O3 C22 96.0(4) . . . . ?
O4 P4 C25 C26 170.9(4) . . . . ?
O5 P4 C25 C26 -62.4(4) . . . . ?
O6 P4 C25 C26 46.8(4) . . . . ?
O4 P4 C25 P3 -55.9(4) . . . . ?
O5 P4 C25 P3 70.8(3) . . . . ?
O6 P4 C25 P3 180.0(3) . . . . ?
C32 P3 C25 C26 64.9(4) . . . . ?
C38 P3 C25 C26 -49.8(4) . . . . ?
Pt P3 C25 C26 -159.5(3) . . . . ?
C32 P3 C25 P4 -67.8(3) . . . . ?
C38 P3 C25 P4 177.5(3) . . . . ?
Pt P3 C25 P4 67.8(3) . . . . ?
C43 C42 C41 C40 1.4(11) . . . . ?
C8 P1 C14 C19 -146.0(4) . . . . ?
C1 P1 C14 C19 98.6(5) . . . . ?
Pt P1 C14 C19 -17.2(5) . . . . ?
C8 P1 C14 C15 38.5(5) . . . . ?
C1 P1 C14 C15 -76.8(5) . . . . ?
Pt P1 C14 C15 167.4(4) . . . . ?
C19 C14 C15 C16 0.9(8) . . . . ?
P1 C14 C15 C16 176.4(4) . . . . ?
C32 P3 C38 C39 26.6(6) . . . . ?
C25 P3 C38 C39 140.3(5) . . . . ?
Pt P3 C38 C39 -98.2(5) . . . . ?
C32 P3 C38 C43 -163.6(4) . . . . ?
C25 P3 C38 C43 -49.9(5) . . . . ?
Pt P3 C38 C43 71.6(4) . . . . ?
C38 P3 C32 C33 -151.2(4) . . . . ?
C25 P3 C32 C33 97.1(4) . . . . ?
Pt P3 C32 C33 -37.8(5) . . . . ?
C38 P3 C32 C37 30.8(5) . . . . ?
C25 P3 C32 C37 -81.0(5) . . . . ?
Pt P3 C32 C37 144.1(4) . . . . ?
O4 P4 O5 C44 -67.5(8) . . . . ?
O6 P4 O5 C44 56.3(7) . . . . ?
C25 P4 O5 C44 167.0(7) . . . . ?
C14 P1 C8 C9 -145.7(5) . . . . ?
C1 P1 C8 C9 -30.3(5) . . . . ?
Pt P1 C8 C9 85.5(5) . . . . ?
C14 P1 C8 C13 44.3(5) . . . . ?
C1 P1 C8 C13 159.7(4) . . . . ?
Pt P1 C8 C13 -84.4(5) . . . . ?
O5 P4 O4 Ag -60.5(5) . . . . ?
O6 P4 O4 Ag -179.5(4) . . . . ?
C25 P4 O4 Ag 60.1(5) . . . . ?
O7 Ag O4 P4 78.2(5) . . . . ?
O8 Ag O4 P4 -166.6(4) 2_667 . . . ?
Pt Ag O4 P4 -53.4(4) . . . . ?
O9 S1 O7 Ag -24.2(5) . . . . ?
O8 S1 O7 Ag 111.8(4) . . . . ?
C48 S1 O7 Ag -137.6(5) . . . . ?
O4 Ag O7 S1 1.4(6) . . . . ?
O8 Ag O7 S1 -110.5(4) 2_667 . . . ?
Pt Ag O7 S1 126.9(4) . . . . ?
C43 C38 C39 C40 2.4(10) . . . . ?
P3 C38 C39 C40 172.0(6) . . . . ?
C28 C27 C26 C31 -0.5(8) . . . . ?
C28 C27 C26 C25 179.6(5) . . . . ?
P4 C25 C26 C31 -122.7(5) . . . . ?
P3 C25 C26 C31 104.3(5) . . . . ?
P4 C25 C26 C27 57.1(6) . . . . ?
P3 C25 C26 C27 -75.8(6) . . . . ?
C6 C7 C2 C3 -1.4(8) . . . . ?
C6 C7 C2 C1 176.7(5) . . . . ?
P2 C1 C2 C3 -121.7(5) . . . . ?
P1 C1 C2 C3 109.8(5) . . . . ?
P2 C1 C2 C7 60.2(6) . . . . ?
P1 C1 C2 C7 -68.3(6) . . . . ?
C27 C26 C31 C30 0.6(10) . . . . ?
C25 C26 C31 C30 -179.5(6) . . . . ?
C37 C32 C33 C34 -0.8(9) . . . . ?
P3 C32 C33 C34 -178.9(5) . . . . ?
O4 P4 O6 C46 -27.8(7) . . . . ?
O5 P4 O6 C46 -153.4(7) . . . . ?
C25 P4 O6 C46 97.1(7) . . . . ?
C7 C2 C3 C4 0.4(9) . . . . ?
C1 C2 C3 C4 -177.7(6) . . . . ?
C9 C8 C13 C12 -0.2(9) . . . . ?
P1 C8 C13 C12 170.1(5) . . . . ?
C33 C32 C37 C36 1.1(9) . . . . ?
P3 C32 C37 C36 179.1(5) . . . . ?
C41 C42 C43 C38 0.0(10) . . . . ?
C39 C38 C43 C42 -2.0(9) . . . . ?
P3 C38 C43 C42 -172.1(5) . . . . ?
C26 C27 C28 C29 0.8(10) . . . . ?
C4 C5 C6 C7 -1.7(11) . . . . ?
C2 C7 C6 C5 2.0(9) . . . . ?
P4 O6 C46 C47 134.2(7) . . . . ?
C16 C17 C18 C19 -0.7(9) . . . . ?
P2 O2 C20 C21 -167.3(6) . . . . ?
C42 C41 C40 C39 -0.9(13) . . . . ?
C38 C39 C40 C41 -1.0(12) . . . . ?
C17 C18 C19 C14 1.4(9) . . . . ?
C15 C14 C19 C18 -1.4(8) . . . . ?
P1 C14 C19 C18 -177.0(4) . . . . ?
C13 C8 C9 C10 1.4(8) . . . . ?
P1 C8 C9 C10 -168.5(5) . . . . ?
C2 C3 C4 C5 -0.1(11) . . . . ?
C6 C5 C4 C3 0.7(12) . . . . ?
C27 C28 C29 C30 -1.2(11) . . . . ?
C32 C33 C34 C35 -0.3(10) . . . . ?
P2 O3 C22 C23 -173.5(5) . . . . ?
C10 C11 C12 C13 1.8(12) . . . . ?
C8 C13 C12 C11 -1.4(11) . . . . ?
C33 C34 C35 C36 1.1(11) . . . . ?
O10 S2 C49 F5 177.7(7) . . . . ?
O12 S2 C49 F5 58.7(7) . . . . ?
O11 S2 C49 F5 -60.7(7) . . . . ?
O10 S2 C49 F4 55.1(8) . . . . ?
O12 S2 C49 F4 -64.0(8) . . . . ?
O11 S2 C49 F4 176.7(7) . . . . ?
O10 S2 C49 F6 -63.0(7) . . . . ?
O12 S2 C49 F6 178.0(7) . . . . ?
O11 S2 C49 F6 58.6(7) . . . . ?
C18 C17 C16 C15 0.1(10) . . . . ?
C14 C15 C16 C17 -0.2(9) . . . . ?
C12 C11 C10 C9 -0.6(12) . . . . ?
C8 C9 C10 C11 -1.0(10) . . . . ?
C28 C29 C30 C31 1.3(13) . . . . ?
C26 C31 C30 C29 -1.0(12) . . . . ?
C34 C35 C36 C37 -0.8(12) . . . . ?
C32 C37 C36 C35 -0.3(11) . . . . ?
P4 O5 C44 C45 157.4(8) . . . . ?
O9 S1 C48 F1 -63.6(13) . . . . ?
O7 S1 C48 F1 55.6(13) . . . . ?
O8 S1 C48 F1 175.2(11) . . . . ?
O9 S1 C48 F3 171.6(7) . . . . ?
O7 S1 C48 F3 -69.1(8) . . . . ?
O8 S1 C48 F3 50.5(8) . . . . ?
O9 S1 C48 F2 54.4(8) . . . . ?
O7 S1 C48 F2 173.7(7) . . . . ?
O8 S1 C48 F2 -66.7(9) . . . . ?
O9 S1 O8 Ag 111.0(4) . . . 2_667 ?
O7 S1 O8 Ag -24.4(5) . . . 2_667 ?
C48 S1 O8 Ag -134.6(6) . . . 2_667 ?
