#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:43:47 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179125 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/87/4308710.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308710
loop_
_publ_author_name
'Jiangbo Yu'
'Liang Zhou'
'Hongjie Zhang'
'Youxuan Zheng'
'Huanrong Li'
'Ruiping Deng'
'Zeping Peng'
'Zhefeng Li'
_publ_section_title
;
Efficient Electroluminescence from New Lanthanide (Eu3+, Sm3+) Complexes
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1611
_journal_page_last               1618
_journal_paper_doi               10.1021/ic0485561
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C60 H32 Eu F21 N2 O6'
_chemical_formula_weight         1427.84
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                76.39(3)
_cell_angle_beta                 86.47(3)
_cell_angle_gamma                88.36(3)
_cell_formula_units_Z            4
_cell_length_a                   11.700(3)
_cell_length_b                   21.111(8)
_cell_length_c                   24.369(9)
_cell_measurement_reflns_used    22
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      7.08
_cell_measurement_theta_min      4.84
_cell_volume                     5838(4)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Siemens P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0390
_diffrn_reflns_av_sigmaI/netI    0.2758
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -1
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            24133
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         1.72
_diffrn_standards_decay_%        3
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.194
_exptl_absorpt_correction_T_max  0.5394
_exptl_absorpt_correction_T_min  0.4983
_exptl_absorpt_correction_type   psi-scan
_exptl_crystal_density_diffrn    1.624
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2824
_exptl_crystal_size_max          0.48
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.162
_refine_diff_density_min         -0.713
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.961
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1354
_refine_ls_number_reflns         20488
_refine_ls_number_restraints     386
_refine_ls_restrained_S_all      0.977
_refine_ls_R_factor_all          0.2250
_refine_ls_R_factor_gt           0.0830
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0400P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1525
_refine_ls_wR_factor_ref         0.1814
_reflns_number_gt                6637
_reflns_number_total             20488
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic0485561si20041221_101051.cif
_cod_data_source_block           m156
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        5839(3)
_cod_database_code               4308710
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu -0.37005(6) 0.58636(3) 0.23476(3) 0.0531(3) Uani 1 1 d . . .
O1 O -0.4243(8) 0.4770(4) 0.2665(4) 0.065(3) Uani 1 1 d . . .
O2 O -0.4635(8) 0.5531(5) 0.1615(4) 0.067(3) Uani 1 1 d . . .
O3 O -0.1957(8) 0.5314(4) 0.2568(4) 0.058(3) Uani 1 1 d . . .
O4 O -0.2407(9) 0.6171(4) 0.1561(4) 0.068(3) Uani 1 1 d . . .
O5 O -0.2741(7) 0.6776(4) 0.2494(4) 0.064(3) Uani 1 1 d . . .
O6 O -0.3668(9) 0.5808(4) 0.3323(4) 0.072(3) Uani 1 1 d . . .
N1 N -0.5843(9) 0.5952(5) 0.2656(5) 0.056(3) Uani 1 1 d . . .
N2 N -0.4799(12) 0.6885(5) 0.1790(5) 0.066(3) Uani 1 1 d . . .
C1 C -0.4892(12) 0.3693(6) 0.2886(6) 0.055(4) Uani 1 1 d D . .
C2 C -0.4678(12) 0.3621(7) 0.3456(8) 0.082(5) Uani 1 1 d . . .
H2 H -0.4468 0.3987 0.3574 0.082 Uiso 1 1 calc R . .
C3 C -0.4759(15) 0.3056(9) 0.3838(8) 0.083(5) Uani 1 1 d . . .
C4 C -0.4516(16) 0.3010(10) 0.4401(10) 0.116(7) Uani 1 1 d . . .
H4 H -0.4253 0.3372 0.4509 0.116 Uiso 1 1 calc R . .
C5 C -0.4667(17) 0.2420(13) 0.4803(9) 0.131(8) Uani 1 1 d . . .
H5 H -0.4550 0.2389 0.5183 0.131 Uiso 1 1 calc R . .
C6 C -0.5006(17) 0.1870(12) 0.4613(10) 0.123(8) Uani 1 1 d . . .
H6 H -0.5078 0.1468 0.4869 0.123 Uiso 1 1 calc R . .
C7 C -0.5216(16) 0.1918(8) 0.4088(9) 0.103(6) Uani 1 1 d . . .
H7 H -0.5461 0.1556 0.3975 0.103 Uiso 1 1 calc R . .
C8 C -0.5082(15) 0.2497(9) 0.3701(8) 0.086(6) Uani 1 1 d . . .
C9 C -0.5326(14) 0.2566(9) 0.3122(10) 0.111(7) Uani 1 1 d . . .
H9 H -0.5563 0.2203 0.3007 0.111 Uiso 1 1 calc R . .
C10 C -0.5225(13) 0.3146(7) 0.2730(6) 0.078(5) Uani 1 1 d . . .
H10 H -0.5382 0.3170 0.2356 0.078 Uiso 1 1 calc R . .
C11 C -0.4799(12) 0.4344(7) 0.2500(7) 0.064(4) Uani 1 1 d D . .
C12 C -0.5286(12) 0.4483(8) 0.1959(7) 0.082(5) Uani 1 1 d . . .
H12 H -0.5743 0.4170 0.1875 0.082 Uiso 1 1 calc R . .
C13 C -0.5119(12) 0.5044(7) 0.1566(6) 0.059(4) Uani 1 1 d D . .
C14 C -0.5707(12) 0.5102(7) 0.1002(6) 0.182(7) Uani 1 1 d D . .
C15 C -0.6452(12) 0.5716(7) 0.0831(6) 0.182(7) Uani 1 1 d D . .
C16 C -0.7183(12) 0.5793(7) 0.0304(6) 0.182(7) Uani 1 1 d D . .
F1 F -0.6348(11) 0.4602(6) 0.1005(5) 0.186(5) Uiso 1 1 d D . .
F2 F -0.4883(9) 0.5162(5) 0.0586(5) 0.147(4) Uiso 1 1 d D . .
F3 F -0.5755(10) 0.6247(5) 0.0668(5) 0.167(5) Uiso 1 1 d D . .
F4 F -0.7108(9) 0.5765(5) 0.1278(4) 0.145(4) Uiso 1 1 d D . .
F5 F -0.8004(11) 0.5388(6) 0.0483(6) 0.206(6) Uiso 1 1 d D . .
F6 F -0.7603(11) 0.6397(5) 0.0161(5) 0.198(6) Uiso 1 1 d D . .
F7 F -0.6502(11) 0.5698(6) -0.0108(6) 0.219(6) Uiso 1 1 d D . .
C17 C -0.0143(13) 0.4796(6) 0.2673(6) 0.058(4) Uani 1 1 d . . .
C18 C -0.0381(12) 0.4510(7) 0.3197(6) 0.068(4) Uani 1 1 d . . .
H18 H -0.1075 0.4618 0.3361 0.068 Uiso 1 1 calc R . .
C19 C 0.0340(13) 0.4040(7) 0.3543(7) 0.066(4) Uani 1 1 d . . .
C20 C 0.0053(14) 0.3748(9) 0.4109(7) 0.106(7) Uani 1 1 d . . .
H20 H -0.0606 0.3877 0.4290 0.106 Uiso 1 1 calc R . .
C21 C 0.0743(19) 0.3279(9) 0.4387(8) 0.120(7) Uani 1 1 d . . .
H21 H 0.0555 0.3075 0.4762 0.120 Uiso 1 1 calc R . .
C22 C 0.1744(17) 0.3093(9) 0.4117(9) 0.112(7) Uani 1 1 d . . .
H22 H 0.2204 0.2766 0.4321 0.112 Uiso 1 1 calc R . .
C23 C 0.2069(16) 0.3362(8) 0.3582(7) 0.099(6) Uani 1 1 d . . .
H23 H 0.2752 0.3237 0.3419 0.099 Uiso 1 1 calc R . .
C24 C 0.1325(14) 0.3857(8) 0.3259(7) 0.075(5) Uani 1 1 d . . .
C25 C 0.1574(13) 0.4140(7) 0.2700(7) 0.072(5) Uani 1 1 d . . .
H25 H 0.2228 0.4012 0.2516 0.072 Uiso 1 1 calc R . .
C26 C 0.0880(13) 0.4600(7) 0.2419(6) 0.067(4) Uani 1 1 d . . .
H26 H 0.1077 0.4798 0.2044 0.067 Uiso 1 1 calc R . .
C27 C -0.0936(13) 0.5294(6) 0.2335(6) 0.057(4) Uani 1 1 d . . .
C28 C -0.0589(13) 0.5691(7) 0.1826(6) 0.073(5) Uani 1 1 d . . .
H28 H 0.0181 0.5690 0.1706 0.073 Uiso 1 1 calc R . .
C29 C -0.1358(14) 0.6100(7) 0.1479(5) 0.054(4) Uani 1 1 d D . .
C30 C -0.0852(11) 0.6524(6) 0.0914(5) 0.089(5) Uani 1 1 d D . .
C31 C -0.0986(14) 0.6279(7) 0.0396(6) 0.227(12) Uani 1 1 d D . .
C32 C -0.2237(15) 0.6148(8) 0.0260(7) 0.227(12) Uani 1 1 d D . .
F8 F -0.1324(8) 0.7114(5) 0.0840(4) 0.115(3) Uiso 1 1 d D . .
F9 F 0.0306(9) 0.6602(5) 0.0924(4) 0.124(3) Uiso 1 1 d D . .
F10 F -0.0486(11) 0.5676(6) 0.0425(6) 0.182(6) Uiso 1 1 d D . .
F11 F -0.0553(8) 0.6718(4) -0.0052(4) 0.121(3) Uiso 1 1 d D . .
F12 F -0.2505(10) 0.5601(5) 0.0600(5) 0.155(4) Uiso 1 1 d D . .
F13 F -0.2099(11) 0.6035(6) -0.0258(5) 0.198(5) Uiso 1 1 d D . .
F14 F -0.2809(12) 0.6665(7) 0.0287(7) 0.214(7) Uiso 1 1 d D . .
C33 C -0.1228(13) 0.7404(7) 0.2681(6) 0.063(4) Uani 1 1 d . . .
C34 C -0.1237(12) 0.7769(6) 0.2121(6) 0.064(4) Uani 1 1 d . . .
H34 H -0.1799 0.7703 0.1887 0.064 Uiso 1 1 calc R . .
C35 C -0.0380(12) 0.8239(6) 0.1914(6) 0.056(4) Uani 1 1 d . . .
C36 C -0.0344(12) 0.8618(7) 0.1366(7) 0.073(4) Uani 1 1 d . . .
H36 H -0.0894 0.8559 0.1123 0.073 Uiso 1 1 calc R . .
C37 C 0.0504(15) 0.9090(8) 0.1167(8) 0.105(6) Uani 1 1 d . . .
H37 H 0.0522 0.9327 0.0794 0.105 Uiso 1 1 calc R . .
C38 C 0.1303(15) 0.9203(7) 0.1519(8) 0.078(5) Uani 1 1 d . . .
H38 H 0.1849 0.9522 0.1385 0.078 Uiso 1 1 calc R . .
C39 C 0.1303(14) 0.8857(7) 0.2056(7) 0.078(5) Uani 1 1 d . . .
H39 H 0.1863 0.8926 0.2289 0.078 Uiso 1 1 calc R . .
C40 C 0.0446(12) 0.8383(7) 0.2267(6) 0.058(4) Uani 1 1 d . . .
C41 C 0.0396(12) 0.8002(7) 0.2824(6) 0.069(4) Uani 1 1 d . . .
H41 H 0.0940 0.8072 0.3065 0.069 Uiso 1 1 calc R . .
C42 C -0.0423(12) 0.7524(7) 0.3039(6) 0.066(4) Uani 1 1 d . . .
H42 H -0.0429 0.7290 0.3413 0.066 Uiso 1 1 calc R . .
C43 C -0.2092(14) 0.6874(8) 0.2874(7) 0.070(5) Uani 1 1 d . . .
C44 C -0.2127(17) 0.6480(10) 0.3380(7) 0.131(8) Uani 1 1 d . . .
H44 H -0.1551 0.6532 0.3612 0.131 Uiso 1 1 calc R . .
C45 C -0.2922(18) 0.5990(9) 0.3615(7) 0.102(6) Uani 1 1 d D . .
C46 C -0.2616(17) 0.5496(9) 0.4157(8) 0.274(10) Uiso 1 1 d D . .
C47 C -0.3246(16) 0.5800(8) 0.4589(8) 0.274(10) Uiso 1 1 d D . .
C48 C -0.3145(17) 0.5422(9) 0.5219(8) 0.274(10) Uiso 1 1 d D . .
F15 F -0.2984(12) 0.4891(7) 0.4279(6) 0.229(2) Uiso 1 1 d D . .
F16 F -0.1522(12) 0.5426(7) 0.4341(6) 0.229(2) Uiso 1 1 d D . .
F17 F -0.2873(12) 0.6394(7) 0.4592(6) 0.229(2) Uiso 1 1 d D . .
F18 F -0.4300(12) 0.5909(7) 0.4469(6) 0.229(2) Uiso 1 1 d D . .
F19 F -0.3610(12) 0.4875(7) 0.5294(6) 0.229(2) Uiso 1 1 d D . .
F20 F -0.2114(12) 0.5225(7) 0.5332(6) 0.229(2) Uiso 1 1 d D . .
F21 F -0.3507(12) 0.5778(7) 0.5553(6) 0.229(2) Uiso 1 1 d D . .
C49 C -0.6338(13) 0.5547(7) 0.3074(6) 0.066(4) Uani 1 1 d . . .
H49 H -0.5886 0.5241 0.3308 0.066 Uiso 1 1 calc R . .
C50 C -0.7530(16) 0.5543(7) 0.3196(7) 0.080(5) Uani 1 1 d . . .
H50 H -0.7864 0.5240 0.3499 0.080 Uiso 1 1 calc R . .
C51 C -0.8186(13) 0.6004(8) 0.2848(7) 0.073(5) Uani 1 1 d . . .
H51 H -0.8979 0.6005 0.2911 0.073 Uiso 1 1 calc R . .
C52 C -0.7698(16) 0.6446(8) 0.2426(7) 0.074(5) Uani 1 1 d . . .
C53 C -0.6484(14) 0.6423(7) 0.2334(6) 0.057(4) Uani 1 1 d . . .
C54 C -0.5968(15) 0.6906(7) 0.1880(7) 0.065(4) Uani 1 1 d . . .
C55 C -0.6601(14) 0.7390(8) 0.1540(7) 0.070(5) Uani 1 1 d . . .
C56 C -0.6012(17) 0.7837(8) 0.1118(7) 0.097(6) Uani 1 1 d . . .
H56 H -0.6438 0.8161 0.0889 0.097 Uiso 1 1 calc R . .
C57 C -0.4824(16) 0.7836(7) 0.1012(7) 0.097(6) Uani 1 1 d . . .
H57 H -0.4433 0.8135 0.0726 0.097 Uiso 1 1 calc R . .
C58 C -0.4301(13) 0.7325(7) 0.1394(6) 0.069(4) Uani 1 1 d . . .
H58 H -0.3506 0.7299 0.1358 0.069 Uiso 1 1 calc R . .
C59 C -0.8337(15) 0.6952(9) 0.2039(8) 0.088(6) Uani 1 1 d . . .
H59 H -0.9131 0.6972 0.2083 0.088 Uiso 1 1 calc R . .
C60 C -0.7811(16) 0.7366(9) 0.1644(9) 0.109(7) Uani 1 1 d . . .
H60 H -0.8252 0.7675 0.1407 0.109 Uiso 1 1 calc R . .
Eu2 Eu 1.31863(6) 0.07802(3) 0.23853(3) 0.0530(3) Uani 1 1 d . . .
O7 O 1.1407(8) 0.0290(4) 0.2587(4) 0.061(3) Uani 1 1 d . . .
O8 O 1.2118(9) 0.1144(4) 0.1597(4) 0.067(3) Uani 1 1 d . . .
O9 O 1.2157(8) 0.1669(4) 0.2610(4) 0.070(3) Uani 1 1 d . . .
O10 O 1.2957(8) 0.0635(4) 0.3388(4) 0.070(3) Uani 1 1 d . . .
O11 O 1.3652(8) -0.0338(4) 0.2689(4) 0.070(3) Uani 1 1 d . . .
O12 O 1.4340(9) 0.0437(5) 0.1663(4) 0.079(3) Uani 1 1 d . . .
N3 N 1.4359(12) 0.1794(6) 0.1851(5) 0.070(4) Uani 1 1 d . . .
N4 N 1.5211(10) 0.0876(6) 0.2722(5) 0.063(3) Uani 1 1 d . . .
C61 C 0.9527(12) -0.0183(7) 0.2681(6) 0.060(4) Uani 1 1 d . . .
C62 C 0.9643(12) -0.0480(6) 0.3227(6) 0.060(4) Uani 1 1 d . . .
H62 H 1.0269 -0.0385 0.3409 0.060 Uiso 1 1 calc R . .
C63 C 0.8842(14) -0.0931(7) 0.3528(7) 0.068(4) Uani 1 1 d . . .
C64 C 0.8923(17) -0.1260(8) 0.4082(7) 0.105(7) Uani 1 1 d . . .
H64 H 0.9536 -0.1166 0.4274 0.105 Uiso 1 1 calc R . .
C65 C 0.8193(19) -0.1698(9) 0.4358(8) 0.109(7) Uani 1 1 d . . .
H65 H 0.8305 -0.1902 0.4733 0.109 Uiso 1 1 calc R . .
C66 C 0.7279(18) -0.1858(9) 0.4107(9) 0.105(7) Uani 1 1 d . . .
H66 H 0.6759 -0.2167 0.4303 0.105 Uiso 1 1 calc R . .
C67 C 0.7148(14) -0.1551(9) 0.3563(9) 0.098(6) Uani 1 1 d . . .
H67 H 0.6509 -0.1647 0.3391 0.098 Uiso 1 1 calc R . .
C68 C 0.7915(15) -0.1101(8) 0.3247(8) 0.071(5) Uani 1 1 d . . .
C69 C 0.7806(13) -0.0790(8) 0.2688(8) 0.085(6) Uani 1 1 d . . .
H69 H 0.7189 -0.0893 0.2503 0.085 Uiso 1 1 calc R . .
C70 C 0.8586(12) -0.0325(8) 0.2384(6) 0.073(5) Uani 1 1 d . . .
H70 H 0.8496 -0.0119 0.2008 0.073 Uiso 1 1 calc R . .
C71 C 1.0473(14) 0.0298(7) 0.2357(6) 0.063(4) Uani 1 1 d . . .
C72 C 1.0203(12) 0.0755(6) 0.1840(6) 0.064(4) Uani 1 1 d . . .
H72 H 0.9455 0.0797 0.1727 0.064 Uiso 1 1 calc R . .
C73 C 1.1040(14) 0.1120(6) 0.1521(5) 0.053(4) Uani 1 1 d D . .
C74 C 1.0664(11) 0.1579(7) 0.0966(5) 0.087(5) Uani 1 1 d D . .
C75 C 1.1014(11) 0.1335(5) 0.0443(5) 0.082(5) Uani 1 1 d D . .
C76 C 1.2295(13) 0.1241(8) 0.0286(7) 0.149(8) Uiso 1 1 d D . .
F22 F 0.9528(8) 0.1666(4) 0.0945(4) 0.112(3) Uiso 1 1 d D . .
F23 F 1.1122(8) 0.2171(4) 0.0900(4) 0.099(3) Uiso 1 1 d D . .
F24 F 1.0577(7) 0.1780(4) -0.0010(4) 0.106(3) Uiso 1 1 d D . .
F25 F 1.0477(8) 0.0786(4) 0.0458(4) 0.105(3) Uiso 1 1 d D . .
F26 F 1.2345(9) 0.1154(5) -0.0235(4) 0.151(4) Uiso 1 1 d D . .
F27 F 1.2627(8) 0.0697(4) 0.0620(4) 0.122(3) Uiso 1 1 d D . .
F28 F 1.2871(9) 0.1736(5) 0.0319(4) 0.155(4) Uiso 1 1 d D . .
C77 C 1.0587(12) 0.2292(6) 0.2838(6) 0.053(4) Uani 1 1 d . . .
C78 C 1.0629(12) 0.2650(6) 0.2289(6) 0.061(4) Uani 1 1 d . . .
H78 H 1.1223 0.2567 0.2042 0.061 Uiso 1 1 calc R . .
C79 C 0.9796(14) 0.3147(7) 0.2079(8) 0.071(5) Uani 1 1 d . . .
C80 C 0.9861(14) 0.3528(8) 0.1533(7) 0.086(5) Uani 1 1 d . . .
H80 H 1.0485 0.3478 0.1290 0.086 Uiso 1 1 calc R . .
C81 C 0.9053(18) 0.3959(9) 0.1351(9) 0.112(7) Uani 1 1 d . . .
H81 H 0.9061 0.4176 0.0971 0.112 Uiso 1 1 calc R . .
C82 C 0.819(2) 0.4087(9) 0.1728(10) 0.112(8) Uani 1 1 d . . .
H82 H 0.7658 0.4419 0.1606 0.112 Uiso 1 1 calc R . .
C83 C 0.8111(14) 0.3741(8) 0.2264(10) 0.095(6) Uani 1 1 d . . .
H83 H 0.7483 0.3811 0.2497 0.095 Uiso 1 1 calc R . .
C84 C 0.8950(15) 0.3274(7) 0.2488(8) 0.075(5) Uani 1 1 d . . .
C85 C 0.8878(14) 0.2866(10) 0.3026(7) 0.096(6) Uani 1 1 d . . .
H85 H 0.8249 0.2903 0.3269 0.096 Uiso 1 1 calc R . .
C86 C 0.9709(14) 0.2412(7) 0.3204(6) 0.073(5) Uani 1 1 d . . .
H86 H 0.9684 0.2180 0.3579 0.073 Uiso 1 1 calc R . .
C87 C 1.1436(12) 0.1756(7) 0.2997(6) 0.053(4) Uani 1 1 d . . .
C88 C 1.1497(13) 0.1353(7) 0.3547(6) 0.075(5) Uani 1 1 d . . .
H88 H 1.0987 0.1445 0.3826 0.075 Uiso 1 1 calc R . .
C89 C 1.2235(15) 0.0842(9) 0.3703(6) 0.110(5) Uani 1 1 d D . .
C90 C 1.2441(12) 0.0528(7) 0.4333(6) 0.110(5) Uani 1 1 d D . .
C91 C 1.1929(16) -0.0138(7) 0.4517(6) 0.275(15) Uani 1 1 d D . .
C92 C 1.2003(17) -0.0504(8) 0.5151(6) 0.275(15) Uani 1 1 d D . .
F29 F 1.1893(11) 0.0842(6) 0.4677(5) 0.189(5) Uiso 1 1 d D . .
F30 F 1.3562(11) 0.0451(6) 0.4467(5) 0.174(5) Uiso 1 1 d D . .
F31 F 1.0791(14) 0.0047(9) 0.4426(8) 0.292(9) Uiso 1 1 d D . .
F32 F 1.2124(11) -0.0492(6) 0.4180(5) 0.182(5) Uiso 1 1 d D . .
F33 F 1.3048(13) -0.0641(9) 0.5241(7) 0.275(9) Uiso 1 1 d D . .
F34 F 1.1497(14) -0.1049(7) 0.5201(7) 0.266(8) Uiso 1 1 d D . .
F35 F 1.1564(12) -0.0190(6) 0.5477(5) 0.196(6) Uiso 1 1 d D . .
C93 C 1.4059(12) -0.1426(7) 0.2880(7) 0.066(4) Uani 1 1 d . . .
C94 C 1.3293(13) -0.1503(7) 0.3366(6) 0.065(4) Uani 1 1 d . . .
H94 H 1.2931 -0.1139 0.3454 0.065 Uiso 1 1 calc R . .
C95 C 1.3079(16) -0.2125(8) 0.3714(7) 0.078(5) Uani 1 1 d . . .
C96 C 1.2231(17) -0.2171(9) 0.4204(9) 0.120(8) Uani 1 1 d . . .
H96 H 1.1849 -0.1798 0.4263 0.120 Uiso 1 1 calc R . .
C97 C 1.2017(18) -0.2757(11) 0.4564(10) 0.138(9) Uani 1 1 d . . .
H97 H 1.1527 -0.2797 0.4885 0.138 Uiso 1 1 calc R . .
C98 C 1.258(3) -0.3306(11) 0.4423(9) 0.167(13) Uani 1 1 d . . .
H98 H 1.2351 -0.3715 0.4628 0.167 Uiso 1 1 calc R . .
C99 C 1.3455(18) -0.3288(9) 0.4005(9) 0.119(8) Uani 1 1 d . . .
H99 H 1.3874 -0.3660 0.3974 0.119 Uiso 1 1 calc R . .
C100 C 1.3676(15) -0.2672(8) 0.3628(8) 0.075(5) Uani 1 1 d . . .
C101 C 1.4482(15) -0.2607(7) 0.3169(7) 0.076(5) Uani 1 1 d . . .
H101 H 1.4910 -0.2966 0.3113 0.076 Uiso 1 1 calc R . .
C102 C 1.4639(13) -0.1988(7) 0.2790(6) 0.073(4) Uani 1 1 d . . .
H102 H 1.5140 -0.1954 0.2473 0.073 Uiso 1 1 calc R . .
C103 C 1.4186(13) -0.0782(7) 0.2509(7) 0.063(4) Uani 1 1 d . . .
C104 C 1.4854(13) -0.0673(8) 0.1980(7) 0.075(5) Uani 1 1 d . . .
H104 H 1.5270 -0.1013 0.1877 0.075 Uiso 1 1 calc R . .
C105 C 1.4869(12) -0.0081(9) 0.1642(7) 0.065(4) Uani 1 1 d D . .
C106 C 1.5623(12) -0.0036(8) 0.1080(6) 0.163(12) Uani 1 1 d D . .
C107 C 1.6285(12) 0.0591(7) 0.0885(5) 0.113(7) Uani 1 1 d D . .
C108 C 1.7263(15) 0.0637(8) 0.0420(7) 0.152(9) Uani 1 1 d D . .
F36 F 1.6399(9) -0.0508(5) 0.1135(4) 0.137(4) Uiso 1 1 d D . .
F37 F 1.4924(9) -0.0053(5) 0.0674(4) 0.140(4) Uiso 1 1 d D . .
F38 F 1.6794(8) 0.0685(4) 0.1355(4) 0.107(3) Uiso 1 1 d D . .
F39 F 1.5589(10) 0.1118(5) 0.0708(4) 0.142(4) Uiso 1 1 d D . .
F40 F 1.8038(11) 0.0208(6) 0.0606(5) 0.170(5) Uiso 1 1 d D . .
F41 F 1.6826(10) 0.0457(5) -0.0004(5) 0.152(4) Uiso 1 1 d D . .
F42 F 1.7562(11) 0.1233(6) 0.0241(5) 0.167(5) Uiso 1 1 d D . .
C109 C 1.3917(14) 0.2225(7) 0.1430(6) 0.080(5) Uani 1 1 d . . .
H109 H 1.3152 0.2202 0.1353 0.080 Uiso 1 1 calc R . .
C110 C 1.4611(18) 0.2714(8) 0.1102(7) 0.102(6) Uani 1 1 d . . .
H110 H 1.4308 0.3023 0.0807 0.102 Uiso 1 1 calc R . .
C111 C 1.5720(19) 0.2740(10) 0.1213(9) 0.102(6) Uani 1 1 d . . .
H111 H 1.6176 0.3073 0.0999 0.102 Uiso 1 1 calc R . .
C112 C 1.6191(17) 0.2269(10) 0.1648(8) 0.087(6) Uani 1 1 d . . .
C113 C 1.5468(15) 0.1803(8) 0.1953(7) 0.061(4) Uani 1 1 d . . .
C114 C 1.5937(14) 0.1329(8) 0.2426(7) 0.064(4) Uani 1 1 d . . .
C115 C 1.7064(17) 0.1352(11) 0.2571(9) 0.087(6) Uani 1 1 d . . .
C116 C 1.7478(16) 0.0908(10) 0.3024(10) 0.100(7) Uani 1 1 d . . .
H116 H 1.8244 0.0905 0.3108 0.100 Uiso 1 1 calc R . .
C117 C 1.6730(18) 0.0475(9) 0.3345(8) 0.101(7) Uani 1 1 d . . .
H117 H 1.6955 0.0198 0.3678 0.101 Uiso 1 1 calc R . .
C118 C 1.5624(15) 0.0448(8) 0.3172(8) 0.089(5) Uani 1 1 d . . .
H118 H 1.5146 0.0120 0.3376 0.089 Uiso 1 1 calc R . .
C119 C 1.7358(18) 0.2277(11) 0.1771(9) 0.107(7) Uani 1 1 d . . .
H119 H 1.7831 0.2590 0.1541 0.107 Uiso 1 1 calc R . .
C120 C 1.7794(18) 0.1864(11) 0.2193(11) 0.121(9) Uani 1 1 d . . .
H120 H 1.8564 0.1889 0.2260 0.121 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Eu1 O1 76.8(3) . . ?
O3 Eu1 O4 71.9(3) . . ?
O1 Eu1 O4 119.9(3) . . ?
O3 Eu1 O6 78.3(3) . . ?
O1 Eu1 O6 82.9(3) . . ?
O4 Eu1 O6 135.6(3) . . ?
O3 Eu1 O5 84.3(3) . . ?
O1 Eu1 O5 149.7(3) . . ?
O4 Eu1 O5 74.8(3) . . ?
O6 Eu1 O5 70.1(3) . . ?
O3 Eu1 O2 113.5(3) . . ?
O1 Eu1 O2 70.5(3) . . ?
O4 Eu1 O2 77.0(3) . . ?
O6 Eu1 O2 146.5(3) . . ?
O5 Eu1 O2 139.5(3) . . ?
O3 Eu1 N2 149.0(4) . . ?
O1 Eu1 N2 131.3(4) . . ?
O4 Eu1 N2 80.9(4) . . ?
O6 Eu1 N2 113.7(4) . . ?
O5 Eu1 N2 74.3(3) . . ?
O2 Eu1 N2 73.1(3) . . ?
O3 Eu1 N1 145.5(3) . . ?
O1 Eu1 N1 76.9(3) . . ?
O4 Eu1 N1 141.6(4) . . ?
O6 Eu1 N1 76.8(4) . . ?
O5 Eu1 N1 108.7(3) . . ?
O2 Eu1 N1 77.6(3) . . ?
N2 Eu1 N1 64.4(4) . . ?
C11 O1 Eu1 139.4(9) . . ?
C13 O2 Eu1 136.4(9) . . ?
C27 O3 Eu1 138.0(8) . . ?
C29 O4 Eu1 134.2(9) . . ?
C43 O5 Eu1 134.8(9) . . ?
C45 O6 Eu1 131.6(11) . . ?
C49 N1 C53 118.8(13) . . ?
C49 N1 Eu1 123.3(10) . . ?
C53 N1 Eu1 117.8(10) . . ?
C58 N2 C54 119.6(14) . . ?
C58 N2 Eu1 122.3(11) . . ?
C54 N2 Eu1 117.6(10) . . ?
C2 C1 C10 116.7(13) . . ?
C2 C1 C11 119.0(14) . . ?
C10 C1 C11 124.2(15) . . ?
C3 C2 C1 123.4(17) . . ?
C2 C3 C8 122.0(18) . . ?
C2 C3 C4 121(2) . . ?
C8 C3 C4 117.1(17) . . ?
C5 C4 C3 120(2) . . ?
C6 C5 C4 118(2) . . ?
C7 C6 C5 121(2) . . ?
C6 C7 C8 121(2) . . ?
C7 C8 C9 122(2) . . ?
C7 C8 C3 123.1(19) . . ?
C9 C8 C3 115.2(16) . . ?
C10 C9 C8 122.5(16) . . ?
C9 C10 C1 120.3(15) . . ?
O1 C11 C12 121.8(13) . . ?
O1 C11 C1 116.9(14) . . ?
C12 C11 C1 121.3(15) . . ?
C13 C12 C11 123.6(14) . . ?
O2 C13 C12 127.7(14) . . ?
O2 C13 C14 115.9(12) . . ?
C12 C13 C14 116.1(13) . . ?
F1 C14 F2 109.9(13) . . ?
F1 C14 C15 107.3(12) . . ?
F2 C14 C15 104.4(11) . . ?
F1 C14 C13 113.1(13) . . ?
F2 C14 C13 107.8(12) . . ?
C15 C14 C13 114.0(12) . . ?
F4 C15 F3 109.8(12) . . ?
F4 C15 C14 107.4(11) . . ?
F3 C15 C14 108.9(11) . . ?
F4 C15 C16 110.5(11) . . ?
F3 C15 C16 101.4(11) . . ?
C14 C15 C16 118.6(11) . . ?
F5 C16 F7 118.0(14) . . ?
F5 C16 F6 110.0(12) . . ?
F7 C16 F6 108.3(12) . . ?
F5 C16 C15 103.3(11) . . ?
F7 C16 C15 107.1(12) . . ?
F6 C16 C15 109.7(13) . . ?
C18 C17 C26 116.8(14) . . ?
C18 C17 C27 122.4(14) . . ?
C26 C17 C27 120.7(14) . . ?
C17 C18 C19 125.2(15) . . ?
C20 C19 C18 123.2(16) . . ?
C20 C19 C24 122.0(15) . . ?
C18 C19 C24 114.6(15) . . ?
C21 C20 C19 118.8(17) . . ?
C20 C21 C22 120.6(18) . . ?
C23 C22 C21 123.1(19) . . ?
C22 C23 C24 118.1(18) . . ?
C25 C24 C19 120.8(17) . . ?
C25 C24 C23 121.9(17) . . ?
C19 C24 C23 117.3(15) . . ?
C26 C25 C24 120.2(15) . . ?
C25 C26 C17 122.2(14) . . ?
O3 C27 C28 123.5(14) . . ?
O3 C27 C17 114.4(12) . . ?
C28 C27 C17 122.1(15) . . ?
C27 C28 C29 122.1(14) . . ?
O4 C29 C28 128.9(13) . . ?
O4 C29 C30 114.3(13) . . ?
C28 C29 C30 116.9(13) . . ?
F8 C30 F9 106.6(12) . . ?
F8 C30 C31 108.6(11) . . ?
F9 C30 C31 104.3(10) . . ?
F8 C30 C29 108.2(11) . . ?
F9 C30 C29 111.9(11) . . ?
C31 C30 C29 116.8(12) . . ?
F11 C31 F10 111.0(13) . . ?
F11 C31 C30 108.6(11) . . ?
F10 C31 C30 112.9(13) . . ?
F11 C31 C32 106.4(12) . . ?
F10 C31 C32 100.8(11) . . ?
C30 C31 C32 116.8(12) . . ?
F14 C32 F12 120.0(16) . . ?
F14 C32 F13 114.8(16) . . ?
F12 C32 F13 106.7(14) . . ?
F14 C32 C31 105.4(13) . . ?
F12 C32 C31 105.1(13) . . ?
F13 C32 C31 102.9(13) . . ?
C34 C33 C42 120.5(14) . . ?
C34 C33 C43 118.0(14) . . ?
C42 C33 C43 121.5(14) . . ?
C33 C34 C35 119.3(14) . . ?
C36 C35 C40 115.9(14) . . ?
C36 C35 C34 122.1(14) . . ?
C40 C35 C34 121.9(14) . . ?
C37 C36 C35 121.5(15) . . ?
C36 C37 C38 120.7(16) . . ?
C39 C38 C37 120.5(17) . . ?
C38 C39 C40 119.9(16) . . ?
C41 C40 C35 115.5(14) . . ?
C41 C40 C39 122.9(14) . . ?
C35 C40 C39 121.5(14) . . ?
C40 C41 C42 124.0(14) . . ?
C41 C42 C33 118.7(13) . . ?
O5 C43 C44 120.3(16) . . ?
O5 C43 C33 116.0(14) . . ?
C44 C43 C33 123.3(17) . . ?
C43 C44 C45 128.3(18) . . ?
O6 C45 C44 122.5(15) . . ?
O6 C45 C46 116.1(18) . . ?
C44 C45 C46 117.5(18) . . ?
F15 C46 F16 102.9(15) . . ?
F15 C46 C47 104.1(15) . . ?
F16 C46 C47 102.5(14) . . ?
F15 C46 C45 122.0(18) . . ?
F16 C46 C45 122.3(18) . . ?
C47 C46 C45 99.7(14) . . ?
F18 C47 F17 103.0(14) . . ?
F18 C47 C46 110.3(15) . . ?
F17 C47 C46 113.7(15) . . ?
F18 C47 C48 111.2(15) . . ?
F17 C47 C48 102.4(13) . . ?
C46 C47 C48 115.4(13) . . ?
F19 C48 F21 116.0(19) . . ?
F19 C48 F20 98.7(15) . . ?
F21 C48 F20 109.4(17) . . ?
F19 C48 C47 109.1(15) . . ?
F21 C48 C47 110.4(14) . . ?
F20 C48 C47 112.9(16) . . ?
N1 C49 C50 123.2(15) . . ?
C51 C50 C49 117.7(15) . . ?
C52 C51 C50 120.6(17) . . ?
C51 C52 C59 123.9(19) . . ?
C51 C52 C53 118.3(17) . . ?
C59 C52 C53 117.8(17) . . ?
N1 C53 C54 121.0(15) . . ?
N1 C53 C52 121.2(15) . . ?
C54 C53 C52 117.7(17) . . ?
N2 C54 C55 119.6(16) . . ?
N2 C54 C53 117.9(15) . . ?
C55 C54 C53 122.5(16) . . ?
C56 C55 C60 125.9(18) . . ?
C56 C55 C54 117.6(16) . . ?
C60 C55 C54 116.5(17) . . ?
C55 C56 C57 124.8(16) . . ?
C56 C57 C58 111.1(15) . . ?
N2 C58 C57 127.3(15) . . ?
C60 C59 C52 120.6(19) . . ?
C59 C60 C55 125(2) . . ?
O8 Eu2 O7 72.5(3) . . ?
O8 Eu2 O9 77.9(3) . . ?
O7 Eu2 O9 82.3(3) . . ?
O8 Eu2 O11 120.0(3) . . ?
O7 Eu2 O11 76.7(3) . . ?
O9 Eu2 O11 145.5(3) . . ?
O8 Eu2 O10 138.7(3) . . ?
O7 Eu2 O10 78.1(3) . . ?
O9 Eu2 O10 69.9(3) . . ?
O11 Eu2 O10 79.2(3) . . ?
O8 Eu2 O12 77.7(3) . . ?
O7 Eu2 O12 114.6(3) . . ?
O9 Eu2 O12 144.0(3) . . ?
O11 Eu2 O12 70.4(3) . . ?
O10 Eu2 O12 142.2(3) . . ?
O8 Eu2 N4 140.5(4) . . ?
O7 Eu2 N4 146.9(4) . . ?
O9 Eu2 N4 104.2(3) . . ?
O11 Eu2 N4 80.7(4) . . ?
O10 Eu2 N4 74.1(4) . . ?
O12 Eu2 N4 79.2(3) . . ?
O8 Eu2 N3 79.3(4) . . ?
O7 Eu2 N3 147.4(4) . . ?
O9 Eu2 N3 75.9(3) . . ?
O11 Eu2 N3 133.2(4) . . ?
O10 Eu2 N3 115.5(4) . . ?
O12 Eu2 N3 73.9(3) . . ?
N4 Eu2 N3 63.6(4) . . ?
C71 O7 Eu2 138.6(9) . . ?
C73 O8 Eu2 132.3(8) . . ?
C87 O9 Eu2 136.6(9) . . ?
C89 O10 Eu2 133.0(10) . . ?
C103 O11 Eu2 139.6(10) . . ?
C105 O12 Eu2 133.4(10) . . ?
C109 N3 C113 121.1(14) . . ?
C109 N3 Eu2 120.3(11) . . ?
C113 N3 Eu2 117.6(11) . . ?
C118 N4 C114 116.9(14) . . ?
C118 N4 Eu2 122.3(11) . . ?
C114 N4 Eu2 120.6(10) . . ?
C62 C61 C70 121.0(14) . . ?
C62 C61 C71 119.4(13) . . ?
C70 C61 C71 119.5(14) . . ?
C61 C62 C63 121.4(14) . . ?
C64 C63 C62 124.2(17) . . ?
C64 C63 C68 116.1(16) . . ?
C62 C63 C68 119.6(16) . . ?
C63 C64 C65 124.2(18) . . ?
C66 C65 C64 121(2) . . ?
C65 C66 C67 117(2) . . ?
C66 C67 C68 123.6(18) . . ?
C69 C68 C67 124.4(18) . . ?
C69 C68 C63 118.2(16) . . ?
C67 C68 C63 117.3(18) . . ?
C68 C69 C70 122.8(16) . . ?
C61 C70 C69 116.9(15) . . ?
O7 C71 C72 123.6(14) . . ?
O7 C71 C61 117.3(13) . . ?
C72 C71 C61 119.0(14) . . ?
C73 C72 C71 119.9(13) . . ?
O8 C73 C72 130.6(12) . . ?
O8 C73 C74 113.7(11) . . ?
C72 C73 C74 115.6(13) . . ?
F23 C74 F22 107.2(12) . . ?
F23 C74 C75 107.6(10) . . ?
F22 C74 C75 104.3(10) . . ?
F23 C74 C73 110.1(10) . . ?
F22 C74 C73 113.7(11) . . ?
C75 C74 C73 113.6(11) . . ?
F25 C75 F24 104.4(10) . . ?
F25 C75 C74 109.9(10) . . ?
F24 C75 C74 106.6(9) . . ?
F25 C75 C76 108.5(10) . . ?
F24 C75 C76 106.5(10) . . ?
C74 C75 C76 119.8(11) . . ?
F28 C76 F27 113.7(14) . . ?
F28 C76 F26 111.6(14) . . ?
F27 C76 F26 107.6(13) . . ?
F28 C76 C75 110.9(13) . . ?
F27 C76 C75 106.6(12) . . ?
F26 C76 C75 105.9(12) . . ?
C78 C77 C86 118.7(13) . . ?
C78 C77 C87 118.3(14) . . ?
C86 C77 C87 122.9(14) . . ?
C77 C78 C79 122.8(14) . . ?
C84 C79 C80 121.1(15) . . ?
C84 C79 C78 115.5(16) . . ?
C80 C79 C78 123.1(17) . . ?
C81 C80 C79 121.0(18) . . ?
C80 C81 C82 120(2) . . ?
C83 C82 C81 121(2) . . ?
C82 C83 C84 122.1(19) . . ?
C85 C84 C83 124.9(18) . . ?
C85 C84 C79 119.6(16) . . ?
C83 C84 C79 114.3(17) . . ?
C84 C85 C86 121.3(15) . . ?
C77 C86 C85 121.2(14) . . ?
O9 C87 C88 119.0(13) . . ?
O9 C87 C77 116.7(13) . . ?
C88 C87 C77 124.3(13) . . ?
C89 C88 C87 125.9(14) . . ?
O10 C89 C88 126.4(14) . . ?
O10 C89 C90 110.4(13) . . ?
C88 C89 C90 122.2(14) . . ?
F29 C90 F30 108.7(14) . . ?
F29 C90 C91 102.1(11) . . ?
F30 C90 C91 105.9(12) . . ?
F29 C90 C89 112.1(13) . . ?
F30 C90 C89 115.6(13) . . ?
C91 C90 C89 111.4(13) . . ?
F32 C91 F31 101.9(15) . . ?
F32 C91 C90 114.6(13) . . ?
F31 C91 C90 97.7(12) . . ?
F32 C91 C92 113.9(13) . . ?
F31 C91 C92 108.1(14) . . ?
C90 C91 C92 117.6(12) . . ?
F33 C92 F35 112.0(18) . . ?
F33 C92 F34 106.6(16) . . ?
F35 C92 F34 111.6(17) . . ?
F33 C92 C91 108.1(15) . . ?
F35 C92 C91 112.6(14) . . ?
F34 C92 C91 105.6(15) . . ?
C94 C93 C102 117.1(14) . . ?
C94 C93 C103 118.5(14) . . ?
C102 C93 C103 124.4(16) . . ?
C93 C94 C95 120.5(14) . . ?
C100 C95 C96 120.9(16) . . ?
C100 C95 C94 121.6(17) . . ?
C96 C95 C94 117.5(17) . . ?
C97 C96 C95 119.9(19) . . ?
C96 C97 C98 116(2) . . ?
C99 C98 C97 126(2) . . ?
C98 C99 C100 117(2) . . ?
C101 C100 C95 119.1(16) . . ?
C101 C100 C99 121.5(18) . . ?
C95 C100 C99 119.3(19) . . ?
C100 C101 C102 119.5(15) . . ?
C101 C102 C93 121.9(15) . . ?
O11 C103 C104 123.8(14) . . ?
O11 C103 C93 114.1(15) . . ?
C104 C103 C93 122.1(15) . . ?
C105 C104 C103 119.1(15) . . ?
O12 C105 C104 132.8(15) . . ?
O12 C105 C106 113.5(15) . . ?
C104 C105 C106 113.5(14) . . ?
F36 C106 F37 111.7(14) . . ?
F36 C106 C107 105.5(11) . . ?
F37 C106 C107 106.5(11) . . ?
F36 C106 C105 111.4(12) . . ?
F37 C106 C105 107.6(12) . . ?
C107 C106 C105 114.1(13) . . ?
F39 C107 F38 106.5(11) . . ?
F39 C107 C106 112.4(12) . . ?
F38 C107 C106 106.1(11) . . ?
F39 C107 C108 106.1(11) . . ?
F38 C107 C108 105.6(11) . . ?
C106 C107 C108 119.3(12) . . ?
F40 C108 F42 118.3(16) . . ?
F40 C108 F41 106.4(13) . . ?
F42 C108 F41 107.4(14) . . ?
F40 C108 C107 108.4(13) . . ?
F42 C108 C107 109.3(13) . . ?
F41 C108 C107 106.4(13) . . ?
N3 C109 C110 119.2(16) . . ?
C111 C110 C109 120.0(18) . . ?
C110 C111 C112 120(2) . . ?
C113 C112 C111 116.7(19) . . ?
C113 C112 C119 121(2) . . ?
C111 C112 C119 122(2) . . ?
N3 C113 C112 122.4(17) . . ?
N3 C113 C114 120.4(15) . . ?
C112 C113 C114 117.2(18) . . ?
N4 C114 C115 121.6(18) . . ?
N4 C114 C113 116.3(15) . . ?
C115 C114 C113 122.1(18) . . ?
C116 C115 C114 121(2) . . ?
C116 C115 C120 123(2) . . ?
C114 C115 C120 116(2) . . ?
C117 C116 C115 117.5(19) . . ?
C116 C117 C118 119.6(19) . . ?
N4 C118 C117 123.1(18) . . ?
C120 C119 C112 123(2) . . ?
C119 C120 C115 120(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O3 2.346(9) . ?
Eu1 O1 2.348(8) . ?
Eu1 O4 2.345(10) . ?
Eu1 O6 2.354(9) . ?
Eu1 O5 2.365(9) . ?
Eu1 O2 2.398(9) . ?
Eu1 N2 2.612(11) . ?
Eu1 N1 2.587(11) . ?
O1 C11 1.278(15) . ?
O2 C13 1.222(13) . ?
O3 C27 1.295(14) . ?
O4 C29 1.242(14) . ?
O5 C43 1.290(16) . ?
O6 C45 1.281(19) . ?
N1 C49 1.284(15) . ?
N1 C53 1.352(16) . ?
N2 C58 1.295(14) . ?
N2 C54 1.372(16) . ?
C1 C2 1.399(18) . ?
C1 C10 1.370(17) . ?
C1 C11 1.474(13) . ?
C2 C3 1.332(18) . ?
C3 C8 1.37(2) . ?
C3 C4 1.40(2) . ?
C4 C5 1.40(2) . ?
C5 C6 1.42(2) . ?
C6 C7 1.30(2) . ?
C7 C8 1.362(19) . ?
C8 C9 1.43(2) . ?
C9 C10 1.37(2) . ?
C11 C12 1.430(18) . ?
C12 C13 1.347(17) . ?
C13 C14 1.552(14) . ?
C14 F1 1.311(12) . ?
C14 F2 1.342(11) . ?
C14 C15 1.530(12) . ?
C15 F4 1.318(11) . ?
C15 F3 1.372(11) . ?
C15 C16 1.561(12) . ?
C16 F5 1.290(11) . ?
C16 F7 1.291(12) . ?
C16 F6 1.329(12) . ?
C17 C18 1.294(16) . ?
C17 C26 1.409(17) . ?
C17 C27 1.509(17) . ?
C18 C19 1.434(17) . ?
C19 C20 1.396(18) . ?
C19 C24 1.401(18) . ?
C20 C21 1.341(19) . ?
C21 C22 1.40(2) . ?
C22 C23 1.33(2) . ?
C23 C24 1.45(2) . ?
C24 C25 1.369(18) . ?
C25 C26 1.335(17) . ?
C27 C28 1.369(16) . ?
C28 C29 1.405(17) . ?
C29 C30 1.549(13) . ?
C30 F8 1.325(11) . ?
C30 F9 1.371(12) . ?
C30 C31 1.492(14) . ?
C31 F11 1.337(13) . ?
C31 F10 1.375(14) . ?
C31 C32 1.567(16) . ?
C32 F14 1.278(15) . ?
C32 F12 1.287(13) . ?
C32 F13 1.338(14) . ?
C33 C34 1.401(16) . ?
C33 C42 1.388(16) . ?
C33 C43 1.501(18) . ?
C34 C35 1.416(16) . ?
C35 C36 1.386(17) . ?
C35 C40 1.416(17) . ?
C36 C37 1.408(18) . ?
C37 C38 1.368(19) . ?
C38 C39 1.339(17) . ?
C39 C40 1.422(17) . ?
C40 C41 1.404(17) . ?
C41 C42 1.399(16) . ?
C43 C44 1.315(18) . ?
C44 C45 1.41(2) . ?
C45 C46 1.532(16) . ?
C46 F15 1.320(15) . ?
C46 F16 1.375(15) . ?
C46 C47 1.502(16) . ?
C47 F18 1.286(14) . ?
C47 F17 1.341(14) . ?
C47 C48 1.566(16) . ?
C48 F19 1.259(15) . ?
C48 F21 1.278(15) . ?
C48 F20 1.289(15) . ?
C49 C50 1.409(18) . ?
C50 C51 1.379(18) . ?
C51 C52 1.328(18) . ?
C52 C59 1.47(2) . ?
C52 C53 1.425(19) . ?
C53 C54 1.432(18) . ?
C54 C55 1.384(18) . ?
C55 C56 1.382(19) . ?
C55 C60 1.42(2) . ?
C56 C57 1.399(19) . ?
C57 C58 1.401(17) . ?
C59 C60 1.277(19) . ?
Eu2 O8 2.322(9) . ?
Eu2 O7 2.325(9) . ?
Eu2 O9 2.355(9) . ?
Eu2 O11 2.360(9) . ?
Eu2 O10 2.390(9) . ?
Eu2 O12 2.388(9) . ?
Eu2 N4 2.584(12) . ?
Eu2 N3 2.606(11) . ?
O7 C71 1.256(15) . ?
O8 C73 1.291(15) . ?
O9 C87 1.269(13) . ?
O10 C89 1.245(15) . ?
O11 C103 1.261(15) . ?
O12 C105 1.251(15) . ?
N3 C109 1.323(15) . ?
N3 C113 1.338(16) . ?
N4 C118 1.351(16) . ?
N4 C114 1.343(16) . ?
C61 C62 1.345(16) . ?
C61 C70 1.430(16) . ?
C61 C71 1.569(18) . ?
C62 C63 1.399(17) . ?
C63 C64 1.374(18) . ?
C63 C68 1.414(19) . ?
C64 C65 1.312(19) . ?
C65 C66 1.35(2) . ?
C66 C67 1.35(2) . ?
C67 C68 1.387(19) . ?
C68 C69 1.379(19) . ?
C69 C70 1.403(18) . ?
C71 C72 1.440(16) . ?
C72 C73 1.351(16) . ?
C73 C74 1.548(13) . ?
C74 F23 1.344(11) . ?
C74 F22 1.339(11) . ?
C74 C75 1.511(13) . ?
C75 F25 1.327(11) . ?
C75 F24 1.386(10) . ?
C75 C76 1.543(14) . ?
C76 F28 1.280(14) . ?
C76 F27 1.307(13) . ?
C76 F26 1.323(14) . ?
C77 C78 1.372(16) . ?
C77 C86 1.376(17) . ?
C77 C87 1.480(17) . ?
C78 C79 1.437(17) . ?
C79 C84 1.426(19) . ?
C79 C80 1.382(18) . ?
C80 C81 1.316(19) . ?
C81 C82 1.39(2) . ?
C82 C83 1.34(2) . ?
C83 C84 1.41(2) . ?
C84 C85 1.388(19) . ?
C85 C86 1.362(18) . ?
C87 C88 1.413(17) . ?
C88 C89 1.359(18) . ?
C89 C90 1.553(14) . ?
C90 F29 1.313(12) . ?
C90 F30 1.366(12) . ?
C90 C91 1.502(14) . ?
C91 F32 1.241(13) . ?
C91 F31 1.394(15) . ?
C91 C92 1.561(15) . ?
C92 F33 1.268(16) . ?
C92 F35 1.230(14) . ?
C92 F34 1.287(15) . ?
C93 C94 1.421(17) . ?
C93 C102 1.404(17) . ?
C93 C103 1.450(18) . ?
C94 C95 1.406(17) . ?
C95 C100 1.384(19) . ?
C95 C96 1.49(2) . ?
C96 C97 1.36(2) . ?
C97 C98 1.42(3) . ?
C98 C99 1.39(3) . ?
C99 C100 1.43(2) . ?
C100 C101 1.40(2) . ?
C101 C102 1.422(17) . ?
C103 C104 1.440(18) . ?
C104 C105 1.325(18) . ?
C105 C106 1.568(14) . ?
C106 F36 1.318(12) . ?
C106 F37 1.329(12) . ?
C106 C107 1.514(14) . ?
C107 F39 1.361(12) . ?
C107 F38 1.380(11) . ?
C107 C108 1.549(15) . ?
C108 F40 1.287(13) . ?
C108 F42 1.283(13) . ?
C108 F41 1.317(13) . ?
C109 C110 1.394(19) . ?
C110 C111 1.35(2) . ?
C111 C112 1.40(2) . ?
C112 C113 1.36(2) . ?
C112 C119 1.42(2) . ?
C113 C114 1.461(19) . ?
C114 C115 1.39(2) . ?
C115 C116 1.37(2) . ?
C115 C120 1.50(2) . ?
C116 C117 1.36(2) . ?
C117 C118 1.39(2) . ?
C119 C120 1.30(2) . ?
