#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:43:47 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179125 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/87/4308761.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308761
loop_
_publ_author_name
'Yong-Yue Lin'
'Siu-Wai Lai'
'Chi-Ming Che'
'Wen-Fu Fu'
'Zhong-Yuan Zhou'
'Nianyong Zhu'
_publ_section_title
;
Structural Variations and Spectroscopic Properties of Luminescent Mono- and
Multinuclear Silver(I) and Copper(I) Complexes Bearing Phosphine and
Cyanide Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1511
_journal_page_last               1524
_journal_paper_doi               10.1021/ic048876k
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C38 H66 Ag2 N2 P2'
_chemical_formula_weight         828.61
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 107.169(7)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.291(3)
_cell_length_b                   29.554(8)
_cell_length_c                   13.731(4)
_cell_measurement_reflns_used    4306
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1
_cell_volume                     3990(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD Area Detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1077
_diffrn_reflns_av_sigmaI/netI    0.2282
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       38
_diffrn_reflns_limit_k_min       -32
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            25747
_diffrn_reflns_theta_full        27.57
_diffrn_reflns_theta_max         27.57
_diffrn_reflns_theta_min         2.08
_exptl_absorpt_coefficient_mu    1.088
_exptl_absorpt_correction_T_max  0.8805
_exptl_absorpt_correction_T_min  0.8117
_exptl_absorpt_correction_type   'multi scans'
_exptl_absorpt_process_details   'SADABS; Sheldrick 1996'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.379
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       PRISM
_exptl_crystal_F_000             1728
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.550
_refine_diff_density_min         -0.757
_refine_diff_density_rms         0.087
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.968
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         9198
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.968
_refine_ls_R_factor_all          0.1772
_refine_ls_R_factor_gt           0.0469
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0050P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0644
_refine_ls_wR_factor_ref         0.0768
_reflns_number_gt                2876
_reflns_number_total             9198
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic048876ksi20040816_075836_2.cif
_cod_data_source_block           chep53_Cpd2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        3990.3(19)
_cod_database_code               4308761
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.63845(2) -0.149368(7) 1.277967(15) 0.06148(8) Uani 1 1 d . . .
Ag2 Ag 1.96770(2) -0.248978(8) 1.076301(15) 0.05923(7) Uani 1 1 d . . .
P1 P 1.79370(6) -0.09416(2) 1.38166(5) 0.0380(2) Uani 1 1 d . . .
P2 P 1.43475(7) -0.16975(2) 1.14432(5) 0.0429(2) Uani 1 1 d . . .
N1 N 1.8064(2) -0.19150(8) 1.19719(15) 0.0826(9) Uani 1 1 d . . .
N2 N 2.1379(2) -0.30159(7) 0.95020(15) 0.0713(9) Uani 1 1 d . . .
C1 C 1.7764(2) -0.08656(8) 1.50935(15) 0.0406(8) Uani 1 1 d . . .
H1A H 1.8147 -0.1141 1.5467 0.049 Uiso 1 1 calc R . .
C2 C 1.6278(2) -0.08562(9) 1.50975(15) 0.0578(10) Uani 1 1 d . . .
H2A H 1.5854 -0.0579 1.4779 0.069 Uiso 1 1 calc R . .
H2B H 1.5795 -0.1109 1.4700 0.069 Uiso 1 1 calc R . .
C3 C 1.6163(2) -0.08843(9) 1.61790(16) 0.0695(11) Uani 1 1 d . . .
H3A H 1.5212 -0.0873 1.6155 0.083 Uiso 1 1 calc R . .
H3B H 1.6533 -0.1170 1.6483 0.083 Uiso 1 1 calc R . .
C4 C 1.6916(3) -0.05015(9) 1.68275(18) 0.0858(12) Uani 1 1 d . . .
H4A H 1.6879 -0.0538 1.7521 0.103 Uiso 1 1 calc R . .
H4B H 1.6484 -0.0217 1.6567 0.103 Uiso 1 1 calc R . .
C5 C 1.8382(3) -0.04935(10) 1.68228(17) 0.0871(12) Uani 1 1 d . . .
H5A H 1.8843 -0.0761 1.7170 0.105 Uiso 1 1 calc R . .
H5B H 1.8829 -0.0230 1.7195 0.105 Uiso 1 1 calc R . .
C6 C 1.8507(2) -0.04801(8) 1.57417(16) 0.0675(10) Uani 1 1 d . . .
H6A H 1.8143 -0.0196 1.5424 0.081 Uiso 1 1 calc R . .
H6B H 1.9461 -0.0493 1.5775 0.081 Uiso 1 1 calc R . .
C7 C 1.7872(2) -0.03897(7) 1.32014(15) 0.0439(9) Uani 1 1 d . . .
H7A H 1.8643 -0.0210 1.3609 0.053 Uiso 1 1 calc R . .
C8 C 1.6580(2) -0.01264(8) 1.31301(18) 0.0682(10) Uani 1 1 d . . .
H8A H 1.6541 -0.0061 1.3813 0.082 Uiso 1 1 calc R . .
H8B H 1.5801 -0.0313 1.2798 0.082 Uiso 1 1 calc R . .
C9 C 1.6481(3) 0.03186(9) 1.25414(18) 0.0876(12) Uani 1 1 d . . .
H9A H 1.5615 0.0462 1.2485 0.105 Uiso 1 1 calc R . .
H9B H 1.7198 0.0522 1.2911 0.105 Uiso 1 1 calc R . .
C10 C 1.6609(3) 0.02366(10) 1.14992(18) 0.0998(13) Uani 1 1 d . . .
H10A H 1.5837 0.0060 1.1105 0.120 Uiso 1 1 calc R . .
H10B H 1.6598 0.0524 1.1156 0.120 Uiso 1 1 calc R . .
C11 C 1.7874(3) -0.00060(9) 1.15477(18) 0.0928(12) Uani 1 1 d . . .
H11A H 1.8643 0.0189 1.1859 0.111 Uiso 1 1 calc R . .
H11B H 1.7891 -0.0074 1.0860 0.111 Uiso 1 1 calc R . .
C12 C 1.8029(2) -0.04427(8) 1.21487(15) 0.0670(10) Uani 1 1 d . . .
H12A H 1.7355 -0.0657 1.1769 0.080 Uiso 1 1 calc R . .
H12B H 1.8919 -0.0569 1.2211 0.080 Uiso 1 1 calc R . .
C13 C 1.9683(2) -0.11369(7) 1.39912(16) 0.0415(9) Uani 1 1 d . . .
H13A H 1.9709 -0.1213 1.3303 0.050 Uiso 1 1 calc R . .
C14 C 2.0857(2) -0.08172(8) 1.4392(2) 0.0733(11) Uani 1 1 d . . .
H14A H 2.0907 -0.0731 1.5083 0.088 Uiso 1 1 calc R . .
H14B H 2.0697 -0.0545 1.3978 0.088 Uiso 1 1 calc R . .
C15 C 2.2205(2) -0.10242(9) 1.4385(2) 0.0845(12) Uani 1 1 d . . .
H15A H 2.2193 -0.1077 1.3685 0.101 Uiso 1 1 calc R . .
H15B H 2.2931 -0.0812 1.4683 0.101 Uiso 1 1 calc R . .
C16 C 2.2494(3) -0.14627(9) 1.49641(19) 0.0818(12) Uani 1 1 d . . .
H16A H 2.2629 -0.1406 1.5683 0.098 Uiso 1 1 calc R . .
H16B H 2.3321 -0.1595 1.4889 0.098 Uiso 1 1 calc R . .
C17 C 2.1327(3) -0.17883(9) 1.4571(2) 0.0828(12) Uani 1 1 d . . .
H17A H 2.1497 -0.2059 1.4990 0.099 Uiso 1 1 calc R . .
H17B H 2.1278 -0.1877 1.3881 0.099 Uiso 1 1 calc R . .
C18 C 1.9968(2) -0.15849(8) 1.45753(17) 0.0570(10) Uani 1 1 d . . .
H18A H 1.9971 -0.1534 1.5274 0.068 Uiso 1 1 calc R . .
H18B H 1.9245 -0.1798 1.4268 0.068 Uiso 1 1 calc R . .
C19 C 1.2872(2) -0.13182(7) 1.12915(18) 0.0556(10) Uani 1 1 d . . .
H19A H 1.2701 -0.1348 1.1954 0.067 Uiso 1 1 calc R . .
C20 C 1.1518(2) -0.14404(8) 1.05662(18) 0.0665(10) Uani 1 1 d . . .
H20A H 1.1587 -0.1437 0.9877 0.080 Uiso 1 1 calc R . .
H20B H 1.1287 -0.1746 1.0712 0.080 Uiso 1 1 calc R . .
C21 C 1.0405(3) -0.11305(9) 1.0622(2) 0.1169(16) Uani 1 1 d . . .
H21A H 0.9604 -0.1198 1.0059 0.140 Uiso 1 1 calc R . .
H21B H 1.0182 -0.1192 1.1249 0.140 Uiso 1 1 calc R . .
C22 C 1.0715(3) -0.06488(10) 1.0591(2) 0.1085(14) Uani 1 1 d . . .
H22A H 1.0003 -0.0475 1.0747 0.130 Uiso 1 1 calc R . .
H22B H 1.0717 -0.0570 0.9906 0.130 Uiso 1 1 calc R . .
C23 C 1.2036(3) -0.05217(9) 1.1311(2) 0.0932(13) Uani 1 1 d . . .
H23A H 1.1956 -0.0524 1.1998 0.112 Uiso 1 1 calc R . .
H23B H 1.2257 -0.0215 1.1162 0.112 Uiso 1 1 calc R . .
C24 C 1.3193(3) -0.08344(9) 1.1269(2) 0.1051(14) Uani 1 1 d . . .
H24A H 1.3433 -0.0772 1.0651 0.126 Uiso 1 1 calc R . .
H24B H 1.3981 -0.0767 1.1843 0.126 Uiso 1 1 calc R . .
C25 C 1.3757(2) -0.22579(7) 1.16652(15) 0.0405(9) Uani 1 1 d . . .
H25A H 1.3031 -0.2350 1.1058 0.049 Uiso 1 1 calc R . .
C26 C 1.4904(2) -0.26076(7) 1.18627(16) 0.0534(9) Uani 1 1 d . . .
H26A H 1.5205 -0.2632 1.1259 0.064 Uiso 1 1 calc R . .
H26B H 1.5668 -0.2501 1.2416 0.064 Uiso 1 1 calc R . .
C27 C 1.4493(3) -0.30709(8) 1.21317(16) 0.0636(10) Uani 1 1 d . . .
H27A H 1.5266 -0.3274 1.2259 0.076 Uiso 1 1 calc R . .
H27B H 1.3776 -0.3190 1.1561 0.076 Uiso 1 1 calc R . .
C28 C 1.3995(3) -0.30521(9) 1.30737(16) 0.0695(11) Uani 1 1 d . . .
H28A H 1.3694 -0.3350 1.3212 0.083 Uiso 1 1 calc R . .
H28B H 1.4730 -0.2958 1.3661 0.083 Uiso 1 1 calc R . .
C29 C 1.2829(3) -0.27194(8) 1.28874(17) 0.0708(11) Uani 1 1 d . . .
H29A H 1.2553 -0.2695 1.3502 0.085 Uiso 1 1 calc R . .
H29B H 1.2061 -0.2837 1.2352 0.085 Uiso 1 1 calc R . .
C30 C 1.3179(2) -0.22478(8) 1.25819(15) 0.0525(10) Uani 1 1 d . . .
H30A H 1.3842 -0.2109 1.3159 0.063 Uiso 1 1 calc R . .
H30B H 1.2367 -0.2062 1.2411 0.063 Uiso 1 1 calc R . .
C31 C 1.4732(2) -0.17590(8) 1.02285(15) 0.0524(9) Uani 1 1 d . . .
H31A H 1.5405 -0.2003 1.0356 0.063 Uiso 1 1 calc R . .
C32 C 1.5471(3) -0.13580(9) 0.99643(17) 0.0830(12) Uani 1 1 d . . .
H32A H 1.6273 -0.1297 1.0532 0.100 Uiso 1 1 calc R . .
H32B H 1.4885 -0.1095 0.9872 0.100 Uiso 1 1 calc R . .
C33 C 1.5904(3) -0.14263(9) 0.90044(16) 0.0901(11) Uani 1 1 d . . .
H33A H 1.6229 -0.1140 0.8819 0.108 Uiso 1 1 calc R . .
H33B H 1.6656 -0.1639 0.9153 0.108 Uiso 1 1 calc R . .
C34 C 1.4809(3) -0.15957(10) 0.81287(17) 0.0963(13) Uani 1 1 d . . .
H34A H 1.5190 -0.1675 0.7584 0.116 Uiso 1 1 calc R . .
H34B H 1.4151 -0.1356 0.7881 0.116 Uiso 1 1 calc R . .
C35 C 1.4098(3) -0.19984(10) 0.83816(17) 0.0928(13) Uani 1 1 d . . .
H35A H 1.4715 -0.2255 0.8510 0.111 Uiso 1 1 calc R . .
H35B H 1.3327 -0.2072 0.7800 0.111 Uiso 1 1 calc R . .
C36 C 1.3600(3) -0.19221(9) 0.93101(15) 0.0714(11) Uani 1 1 d . . .
H36A H 1.2874 -0.1700 0.9144 0.086 Uiso 1 1 calc R . .
H36B H 1.3231 -0.2203 0.9482 0.086 Uiso 1 1 calc R . .
C37 C 1.8632(3) -0.21113(10) 1.15355(17) 0.0671(11) Uani 1 1 d . . .
C38 C 2.0786(3) -0.28405(9) 0.99879(18) 0.0639(11) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Ag1 P1 152.21(2) . . ?
P2 Ag1 N1 95.31(5) . . ?
P1 Ag1 N1 99.50(5) . . ?
C37 Ag2 C38 177.05(11) . . ?
C1 P1 C7 109.44(11) . . ?
C1 P1 C13 106.41(10) . . ?
C7 P1 C13 103.98(11) . . ?
C1 P1 Ag1 114.29(8) . . ?
C7 P1 Ag1 113.60(7) . . ?
C13 P1 Ag1 108.35(7) . . ?
C25 P2 C31 103.56(11) . . ?
C25 P2 C19 105.49(11) . . ?
C31 P2 C19 110.38(11) . . ?
C25 P2 Ag1 110.89(7) . . ?
C31 P2 Ag1 110.08(8) . . ?
C19 P2 Ag1 115.68(8) . . ?
C37 N1 Ag1 171.06(19) . . ?
C6 C1 C2 108.52(19) . . ?
C6 C1 P1 118.87(17) . . ?
C2 C1 P1 112.70(13) . . ?
C6 C1 H1A 105.2 . . ?
C2 C1 H1A 105.2 . . ?
P1 C1 H1A 105.2 . . ?
C3 C2 C1 111.53(17) . . ?
C3 C2 H2A 109.3 . . ?
C1 C2 H2A 109.3 . . ?
C3 C2 H2B 109.3 . . ?
C1 C2 H2B 109.3 . . ?
H2A C2 H2B 108.0 . . ?
C4 C3 C2 111.1(2) . . ?
C4 C3 H3A 109.4 . . ?
C2 C3 H3A 109.4 . . ?
C4 C3 H3B 109.4 . . ?
C2 C3 H3B 109.4 . . ?
H3A C3 H3B 108.0 . . ?
C3 C4 C5 110.5(2) . . ?
C3 C4 H4A 109.6 . . ?
C5 C4 H4A 109.6 . . ?
C3 C4 H4B 109.6 . . ?
C5 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C4 C5 C6 112.02(19) . . ?
C4 C5 H5A 109.2 . . ?
C6 C5 H5A 109.2 . . ?
C4 C5 H5B 109.2 . . ?
C6 C5 H5B 109.2 . . ?
H5A C5 H5B 107.9 . . ?
C1 C6 C5 112.4(2) . . ?
C1 C6 H6A 109.1 . . ?
C5 C6 H6A 109.1 . . ?
C1 C6 H6B 109.1 . . ?
C5 C6 H6B 109.1 . . ?
H6A C6 H6B 107.9 . . ?
C12 C7 C8 109.29(18) . . ?
C12 C7 P1 110.49(16) . . ?
C8 C7 P1 113.47(17) . . ?
C12 C7 H7A 107.8 . . ?
C8 C7 H7A 107.8 . . ?
P1 C7 H7A 107.8 . . ?
C7 C8 C9 113.2(2) . . ?
C7 C8 H8A 108.9 . . ?
C9 C8 H8A 108.9 . . ?
C7 C8 H8B 108.9 . . ?
C9 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
C10 C9 C8 110.8(2) . . ?
C10 C9 H9A 109.5 . . ?
C8 C9 H9A 109.5 . . ?
C10 C9 H9B 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 108.1 . . ?
C11 C10 C9 111.3(2) . . ?
C11 C10 H10A 109.4 . . ?
C9 C10 H10A 109.4 . . ?
C11 C10 H10B 109.4 . . ?
C9 C10 H10B 109.4 . . ?
H10A C10 H10B 108.0 . . ?
C10 C11 C12 112.9(2) . . ?
C10 C11 H11A 109.0 . . ?
C12 C11 H11A 109.0 . . ?
C10 C11 H11B 109.0 . . ?
C12 C11 H11B 109.0 . . ?
H11A C11 H11B 107.8 . . ?
C7 C12 C11 114.2(2) . . ?
C7 C12 H12A 108.7 . . ?
C11 C12 H12A 108.7 . . ?
C7 C12 H12B 108.7 . . ?
C11 C12 H12B 108.7 . . ?
H12A C12 H12B 107.6 . . ?
C14 C13 C18 110.07(17) . . ?
C14 C13 P1 120.01(17) . . ?
C18 C13 P1 111.66(16) . . ?
C14 C13 H13A 104.5 . . ?
C18 C13 H13A 104.5 . . ?
P1 C13 H13A 104.5 . . ?
C13 C14 C15 112.4(2) . . ?
C13 C14 H14A 109.1 . . ?
C15 C14 H14A 109.1 . . ?
C13 C14 H14B 109.1 . . ?
C15 C14 H14B 109.1 . . ?
H14A C14 H14B 107.9 . . ?
C16 C15 C14 112.5(2) . . ?
C16 C15 H15A 109.1 . . ?
C14 C15 H15A 109.1 . . ?
C16 C15 H15B 109.1 . . ?
C14 C15 H15B 109.1 . . ?
H15A C15 H15B 107.8 . . ?
C15 C16 C17 110.4(2) . . ?
C15 C16 H16A 109.6 . . ?
C17 C16 H16A 109.6 . . ?
C15 C16 H16B 109.6 . . ?
C17 C16 H16B 109.6 . . ?
H16A C16 H16B 108.1 . . ?
C16 C17 C18 112.4(2) . . ?
C16 C17 H17A 109.1 . . ?
C18 C17 H17A 109.1 . . ?
C16 C17 H17B 109.1 . . ?
C18 C17 H17B 109.1 . . ?
H17A C17 H17B 107.9 . . ?
C17 C18 C13 111.9(2) . . ?
C17 C18 H18A 109.2 . . ?
C13 C18 H18A 109.2 . . ?
C17 C18 H18B 109.2 . . ?
C13 C18 H18B 109.2 . . ?
H18A C18 H18B 107.9 . . ?
C24 C19 C20 113.0(2) . . ?
C24 C19 P2 114.24(19) . . ?
C20 C19 P2 120.05(17) . . ?
C24 C19 H19A 102.0 . . ?
C20 C19 H19A 102.0 . . ?
P2 C19 H19A 102.0 . . ?
C21 C20 C19 113.4(2) . . ?
C21 C20 H20A 108.9 . . ?
C19 C20 H20A 108.9 . . ?
C21 C20 H20B 108.9 . . ?
C19 C20 H20B 108.9 . . ?
H20A C20 H20B 107.7 . . ?
C22 C21 C20 114.8(3) . . ?
C22 C21 H21A 108.6 . . ?
C20 C21 H21A 108.6 . . ?
C22 C21 H21B 108.6 . . ?
C20 C21 H21B 108.6 . . ?
H21A C21 H21B 107.5 . . ?
C21 C22 C23 113.3(2) . . ?
C21 C22 H22A 108.9 . . ?
C23 C22 H22A 108.9 . . ?
C21 C22 H22B 108.9 . . ?
C23 C22 H22B 108.9 . . ?
H22A C22 H22B 107.7 . . ?
C22 C23 C24 113.4(2) . . ?
C22 C23 H23A 108.9 . . ?
C24 C23 H23A 108.9 . . ?
C22 C23 H23B 108.9 . . ?
C24 C23 H23B 108.9 . . ?
H23A C23 H23B 107.7 . . ?
C19 C24 C23 114.0(2) . . ?
C19 C24 H24A 108.7 . . ?
C23 C24 H24A 108.7 . . ?
C19 C24 H24B 108.7 . . ?
C23 C24 H24B 108.7 . . ?
H24A C24 H24B 107.6 . . ?
C26 C25 C30 109.33(17) . . ?
C26 C25 P2 111.47(16) . . ?
C30 C25 P2 110.30(15) . . ?
C26 C25 H25A 108.6 . . ?
C30 C25 H25A 108.6 . . ?
P2 C25 H25A 108.6 . . ?
C27 C26 C25 113.5(2) . . ?
C27 C26 H26A 108.9 . . ?
C25 C26 H26A 108.9 . . ?
C27 C26 H26B 108.9 . . ?
C25 C26 H26B 108.9 . . ?
H26A C26 H26B 107.7 . . ?
C26 C27 C28 111.2(2) . . ?
C26 C27 H27A 109.4 . . ?
C28 C27 H27A 109.4 . . ?
C26 C27 H27B 109.4 . . ?
C28 C27 H27B 109.4 . . ?
H27A C27 H27B 108.0 . . ?
C29 C28 C27 109.17(19) . . ?
C29 C28 H28A 109.8 . . ?
C27 C28 H28A 109.8 . . ?
C29 C28 H28B 109.8 . . ?
C27 C28 H28B 109.8 . . ?
H28A C28 H28B 108.3 . . ?
C28 C29 C30 113.5(2) . . ?
C28 C29 H29A 108.9 . . ?
C30 C29 H29A 108.9 . . ?
C28 C29 H29B 108.9 . . ?
C30 C29 H29B 108.9 . . ?
H29A C29 H29B 107.7 . . ?
C29 C30 C25 112.65(19) . . ?
C29 C30 H30A 109.1 . . ?
C25 C30 H30A 109.1 . . ?
C29 C30 H30B 109.1 . . ?
C25 C30 H30B 109.1 . . ?
H30A C30 H30B 107.8 . . ?
C32 C31 C36 111.52(18) . . ?
C32 C31 P2 113.60(16) . . ?
C36 C31 P2 117.87(18) . . ?
C32 C31 H31A 104.0 . . ?
C36 C31 H31A 104.0 . . ?
P2 C31 H31A 104.0 . . ?
C31 C32 C33 113.6(2) . . ?
C31 C32 H32A 108.8 . . ?
C33 C32 H32A 108.8 . . ?
C31 C32 H32B 108.8 . . ?
C33 C32 H32B 108.8 . . ?
H32A C32 H32B 107.7 . . ?
C34 C33 C32 113.8(2) . . ?
C34 C33 H33A 108.8 . . ?
C32 C33 H33A 108.8 . . ?
C34 C33 H33B 108.8 . . ?
C32 C33 H33B 108.8 . . ?
H33A C33 H33B 107.7 . . ?
C33 C34 C35 113.0(2) . . ?
C33 C34 H34A 109.0 . . ?
C35 C34 H34A 109.0 . . ?
C33 C34 H34B 109.0 . . ?
C35 C34 H34B 109.0 . . ?
H34A C34 H34B 107.8 . . ?
C34 C35 C36 112.7(2) . . ?
C34 C35 H35A 109.1 . . ?
C36 C35 H35A 109.1 . . ?
C34 C35 H35B 109.0 . . ?
C36 C35 H35B 109.1 . . ?
H35A C35 H35B 107.8 . . ?
C31 C36 C35 112.1(2) . . ?
C31 C36 H36A 109.2 . . ?
C35 C36 H36A 109.2 . . ?
C31 C36 H36B 109.2 . . ?
C35 C36 H36B 109.2 . . ?
H36A C36 H36B 107.9 . . ?
N1 C37 Ag2 178.2(3) . . ?
N2 C38 Ag2 175.4(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P2 2.4196(8) . ?
Ag1 P1 2.4288(8) . ?
Ag1 N1 2.627(2) . ?
Ag2 C37 2.051(3) . ?
Ag2 C38 2.056(3) . ?
P1 C1 1.828(2) . ?
P1 C7 1.829(2) . ?
P1 C13 1.835(2) . ?
P2 C25 1.820(2) . ?
P2 C31 1.833(2) . ?
P2 C19 1.849(3) . ?
N1 C37 1.115(3) . ?
N2 C38 1.152(3) . ?
C1 C6 1.508(3) . ?
C1 C2 1.531(3) . ?
C1 H1A 0.9800 . ?
C2 C3 1.527(3) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.505(3) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.511(4) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.528(3) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C12 1.509(3) . ?
C7 C8 1.519(3) . ?
C7 H7A 0.9800 . ?
C8 C9 1.531(3) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.495(3) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.471(4) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.515(3) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C14 1.504(3) . ?
C13 C18 1.531(3) . ?
C13 H13A 0.9800 . ?
C14 C15 1.519(4) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.504(4) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 C17 1.509(3) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.524(3) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C24 1.470(3) . ?
C19 C20 1.499(3) . ?
C19 H19A 0.9800 . ?
C20 C21 1.486(4) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.462(4) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.474(4) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.522(4) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C26 1.531(3) . ?
C25 C30 1.543(3) . ?
C25 H25A 0.9800 . ?
C26 C27 1.511(3) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.527(3) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 C29 1.513(3) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 C30 1.529(3) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 C32 1.509(3) . ?
C31 C36 1.521(3) . ?
C31 H31A 0.9800 . ?
C32 C33 1.524(3) . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C33 C34 1.472(3) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C34 C35 1.491(4) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C35 C36 1.525(3) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Ag1 P1 C1 101.71(9) . . . . ?
N1 Ag1 P1 C1 -137.06(9) . . . . ?
P2 Ag1 P1 C7 -24.85(11) . . . . ?
N1 Ag1 P1 C7 96.38(10) . . . . ?
P2 Ag1 P1 C13 -139.86(9) . . . . ?
N1 Ag1 P1 C13 -18.63(9) . . . . ?
P1 Ag1 P2 C25 -154.05(9) . . . . ?
N1 Ag1 P2 C25 83.84(10) . . . . ?
P1 Ag1 P2 C31 91.95(10) . . . . ?
N1 Ag1 P2 C31 -30.16(10) . . . . ?
P1 Ag1 P2 C19 -34.01(12) . . . . ?
N1 Ag1 P2 C19 -156.12(11) . . . . ?
P2 Ag1 N1 C37 -2.8(15) . . . . ?
P1 Ag1 N1 C37 -159.2(15) . . . . ?
C7 P1 C1 C6 -41.4(2) . . . . ?
C13 P1 C1 C6 70.33(19) . . . . ?
Ag1 P1 C1 C6 -170.14(15) . . . . ?
C7 P1 C1 C2 87.15(18) . . . . ?
C13 P1 C1 C2 -161.07(16) . . . . ?
Ag1 P1 C1 C2 -41.54(18) . . . . ?
C6 C1 C2 C3 -57.2(3) . . . . ?
P1 C1 C2 C3 169.01(17) . . . . ?
C1 C2 C3 C4 58.2(3) . . . . ?
C2 C3 C4 C5 -55.5(3) . . . . ?
C3 C4 C5 C6 54.0(3) . . . . ?
C2 C1 C6 C5 55.7(2) . . . . ?
P1 C1 C6 C5 -173.80(16) . . . . ?
C4 C5 C6 C1 -55.5(3) . . . . ?
C1 P1 C7 C12 179.39(15) . . . . ?
C13 P1 C7 C12 66.03(17) . . . . ?
Ag1 P1 C7 C12 -51.54(17) . . . . ?
C1 P1 C7 C8 -57.46(17) . . . . ?
C13 P1 C7 C8 -170.82(15) . . . . ?
Ag1 P1 C7 C8 71.61(16) . . . . ?
C12 C7 C8 C9 -51.7(2) . . . . ?
P1 C7 C8 C9 -175.52(15) . . . . ?
C7 C8 C9 C10 55.7(3) . . . . ?
C8 C9 C10 C11 -55.7(3) . . . . ?
C9 C10 C11 C12 54.4(3) . . . . ?
C8 C7 C12 C11 49.8(3) . . . . ?
P1 C7 C12 C11 175.34(17) . . . . ?
C10 C11 C12 C7 -52.6(3) . . . . ?
C1 P1 C13 C14 -70.7(2) . . . . ?
C7 P1 C13 C14 44.8(2) . . . . ?
Ag1 P1 C13 C14 165.92(17) . . . . ?
C1 P1 C13 C18 60.23(17) . . . . ?
C7 P1 C13 C18 175.75(15) . . . . ?
Ag1 P1 C13 C18 -63.10(16) . . . . ?
C18 C13 C14 C15 54.1(3) . . . . ?
P1 C13 C14 C15 -174.28(18) . . . . ?
C13 C14 C15 C16 -55.7(3) . . . . ?
C14 C15 C16 C17 54.3(3) . . . . ?
C15 C16 C17 C18 -54.0(3) . . . . ?
C16 C17 C18 C13 54.6(3) . . . . ?
C14 C13 C18 C17 -53.6(3) . . . . ?
P1 C13 C18 C17 170.54(16) . . . . ?
C25 P2 C19 C24 170.59(19) . . . . ?
C31 P2 C19 C24 -78.2(2) . . . . ?
Ag1 P2 C19 C24 47.6(2) . . . . ?
C25 P2 C19 C20 -50.3(2) . . . . ?
C31 P2 C19 C20 60.9(2) . . . . ?
Ag1 P2 C19 C20 -173.29(17) . . . . ?
C24 C19 C20 C21 -47.3(3) . . . . ?
P2 C19 C20 C21 173.1(2) . . . . ?
C19 C20 C21 C22 48.7(3) . . . . ?
C20 C21 C22 C23 -49.1(4) . . . . ?
C21 C22 C23 C24 47.8(4) . . . . ?
C20 C19 C24 C23 47.1(3) . . . . ?
P2 C19 C24 C23 -170.94(18) . . . . ?
C22 C23 C24 C19 -47.8(3) . . . . ?
C31 P2 C25 C26 66.99(16) . . . . ?
C19 P2 C25 C26 -177.00(15) . . . . ?
Ag1 P2 C25 C26 -51.04(16) . . . . ?
C31 P2 C25 C30 -171.35(14) . . . . ?
C19 P2 C25 C30 -55.34(16) . . . . ?
Ag1 P2 C25 C30 70.61(15) . . . . ?
C30 C25 C26 C27 53.3(2) . . . . ?
P2 C25 C26 C27 175.55(14) . . . . ?
C25 C26 C27 C28 -58.0(2) . . . . ?
C26 C27 C28 C29 56.6(3) . . . . ?
C27 C28 C29 C30 -55.1(2) . . . . ?
C28 C29 C30 C25 53.3(2) . . . . ?
C26 C25 C30 C29 -50.0(2) . . . . ?
P2 C25 C30 C29 -172.94(14) . . . . ?
C25 P2 C31 C32 -170.08(17) . . . . ?
C19 P2 C31 C32 77.42(19) . . . . ?
Ag1 P2 C31 C32 -51.48(18) . . . . ?
C25 P2 C31 C36 56.8(2) . . . . ?
C19 P2 C31 C36 -55.7(2) . . . . ?
Ag1 P2 C31 C36 175.38(16) . . . . ?
C36 C31 C32 C33 -49.1(3) . . . . ?
P2 C31 C32 C33 174.80(16) . . . . ?
C31 C32 C33 C34 48.9(3) . . . . ?
C32 C33 C34 C35 -49.9(3) . . . . ?
C33 C34 C35 C36 52.3(3) . . . . ?
C32 C31 C36 C35 51.2(3) . . . . ?
P2 C31 C36 C35 -174.77(18) . . . . ?
C34 C35 C36 C31 -53.1(3) . . . . ?
Ag1 N1 C37 Ag2 -95(7) . . . . ?
C38 Ag2 C37 N1 -137(7) . . . . ?
C37 Ag2 C38 N2 -60(4) . . . . ?
