#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:43:47 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179125 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/87/4308763.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308763
loop_
_publ_author_name
'Yong-Yue Lin'
'Siu-Wai Lai'
'Chi-Ming Che'
'Wen-Fu Fu'
'Zhong-Yuan Zhou'
'Nianyong Zhu'
_publ_section_title
;
Structural Variations and Spectroscopic Properties of Luminescent Mono- and
Multinuclear Silver(I) and Copper(I) Complexes Bearing Phosphine and
Cyanide Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1511
_journal_page_last               1524
_journal_paper_doi               10.1021/ic048876k
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C54 H92 Ag4 N4 P4'
_chemical_formula_weight         1352.68
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                96.118(6)
_cell_angle_beta                 113.275(5)
_cell_angle_gamma                109.545(5)
_cell_formula_units_Z            1
_cell_length_a                   10.939(3)
_cell_length_b                   12.686(3)
_cell_length_c                   12.851(4)
_cell_measurement_reflns_used    7213
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1
_cell_volume                     1483.9(7)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0300
_diffrn_reflns_av_sigmaI/netI    0.0602
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            10068
_diffrn_reflns_theta_full        27.56
_diffrn_reflns_theta_max         27.56
_diffrn_reflns_theta_min         2.12
_exptl_absorpt_coefficient_mu    1.445
_exptl_absorpt_correction_T_max  0.7610
_exptl_absorpt_correction_T_min  0.6711
_exptl_absorpt_correction_type   'multi scans'
_exptl_absorpt_process_details   'SADABS; Sheldrick 1996'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.514
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             692
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.847
_refine_diff_density_min         -0.620
_refine_diff_density_rms         0.095
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     301
_refine_ls_number_reflns         6734
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.027
_refine_ls_R_factor_all          0.0703
_refine_ls_R_factor_gt           0.0438
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0300P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0837
_refine_ls_wR_factor_ref         0.0907
_reflns_number_gt                4416
_reflns_number_total             6734
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic048876ksi20040816_075836_4.cif
_cod_data_source_block           p61_Cpd3b
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_database_code               4308763
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.49164(2) 1.026294(17) 0.888882(17) 0.04499(6) Uani 1 1 d . . .
Ag2 Ag 1.0000 1.0000 1.0000 0.05808(10) Uani 1 2 d S . .
Ag3 Ag 0.5000 0.5000 0.5000 0.07547(13) Uani 1 2 d S . .
P1 P 0.41473(6) 0.82130(5) 0.80961(5) 0.03368(16) Uani 1 1 d . . .
P2 P 0.52698(6) 0.79213(5) 1.06463(5) 0.03333(16) Uani 1 1 d . . .
C26 C 0.8559(3) 1.0726(3) 0.9923(3) 0.0568(9) Uani 1 1 d . . .
N2 N 0.5899(3) 0.5172(3) 0.2929(3) 0.0917(11) Uani 1 1 d . . .
C1 C 0.4520(2) 0.7880(2) 0.6843(2) 0.0381(7) Uani 1 1 d . . .
H1A H 0.4230 0.7038 0.6607 0.046 Uiso 1 1 calc R . .
C2 C 0.3645(3) 0.8214(3) 0.5788(2) 0.0605(9) Uani 1 1 d . . .
H2A H 0.3850 0.9032 0.6024 0.073 Uiso 1 1 calc R . .
H2B H 0.2611 0.7767 0.5520 0.073 Uiso 1 1 calc R . .
C3 C 0.4004(3) 0.7998(3) 0.4780(3) 0.0806(12) Uani 1 1 d . . .
H3A H 0.3709 0.7170 0.4491 0.097 Uiso 1 1 calc R . .
H3B H 0.3457 0.8255 0.4138 0.097 Uiso 1 1 calc R . .
C4 C 0.5608(3) 0.8631(3) 0.5159(3) 0.0808(12) Uani 1 1 d . . .
H4A H 0.5889 0.9464 0.5383 0.097 Uiso 1 1 calc R . .
H4B H 0.5807 0.8449 0.4507 0.097 Uiso 1 1 calc R . .
C5 C 0.6490(3) 0.8284(3) 0.6188(3) 0.0653(9) Uani 1 1 d . . .
H5A H 0.7522 0.8735 0.6452 0.078 Uiso 1 1 calc R . .
H5B H 0.6283 0.7468 0.5939 0.078 Uiso 1 1 calc R . .
C6 C 0.6139(3) 0.8485(3) 0.7201(2) 0.0543(8) Uani 1 1 d . . .
H6A H 0.6466 0.9314 0.7514 0.065 Uiso 1 1 calc R . .
H6B H 0.6676 0.8205 0.7825 0.065 Uiso 1 1 calc R . .
C7 C 0.2222(2) 0.7315(2) 0.7657(2) 0.0404(7) Uani 1 1 d . . .
H7A H 0.2168 0.7286 0.8398 0.049 Uiso 1 1 calc R . .
C8 C 0.1153(3) 0.7834(2) 0.7011(2) 0.0547(8) Uani 1 1 d . . .
H8A H 0.1488 0.8626 0.7464 0.066 Uiso 1 1 calc R . .
H8B H 0.1121 0.7857 0.6249 0.066 Uiso 1 1 calc R . .
C9 C -0.0368(3) 0.7108(3) 0.6843(3) 0.0767(11) Uani 1 1 d . . .
H9A H -0.0351 0.7164 0.7608 0.092 Uiso 1 1 calc R . .
H9B H -0.1038 0.7423 0.6393 0.092 Uiso 1 1 calc R . .
C10 C -0.0921(3) 0.5846(3) 0.6215(3) 0.0803(13) Uani 1 1 d . . .
H10A H -0.1074 0.5777 0.5409 0.096 Uiso 1 1 calc R . .
H10B H -0.1854 0.5410 0.6190 0.096 Uiso 1 1 calc R . .
C11 C 0.0141(3) 0.5330(3) 0.6821(3) 0.0742(12) Uani 1 1 d . . .
H11A H -0.0205 0.4542 0.6353 0.089 Uiso 1 1 calc R . .
H11B H 0.0182 0.5291 0.7583 0.089 Uiso 1 1 calc R . .
C12 C 0.1668(3) 0.6045(2) 0.6990(3) 0.0529(9) Uani 1 1 d . . .
H12A H 0.1651 0.6010 0.6226 0.064 Uiso 1 1 calc R . .
H12B H 0.2331 0.5718 0.7425 0.064 Uiso 1 1 calc R . .
C13 C 0.3693(2) 0.6715(2) 1.0571(2) 0.0397(7) Uani 1 1 d . . .
H13A H 0.2836 0.6700 0.9906 0.048 Uiso 1 1 calc R . .
C14 C 0.3445(3) 0.6940(3) 1.1651(2) 0.0561(9) Uani 1 1 d . . .
H14A H 0.4237 0.6924 1.2339 0.067 Uiso 1 1 calc R . .
H14B H 0.3441 0.7704 1.1796 0.067 Uiso 1 1 calc R . .
C15 C 0.1996(3) 0.6018(3) 1.1455(3) 0.0719(11) Uani 1 1 d . . .
H15A H 0.1199 0.6082 1.0813 0.086 Uiso 1 1 calc R . .
H15B H 0.1876 0.6151 1.2160 0.086 Uiso 1 1 calc R . .
C16 C 0.1936(3) 0.4798(3) 1.1166(3) 0.0778(12) Uani 1 1 d . . .
H16A H 0.2667 0.4709 1.1843 0.093 Uiso 1 1 calc R . .
H16B H 0.0985 0.4228 1.1002 0.093 Uiso 1 1 calc R . .
C17 C 0.2205(3) 0.4572(3) 1.0117(3) 0.0731(12) Uani 1 1 d . . .
H17A H 0.1409 0.4569 0.9420 0.088 Uiso 1 1 calc R . .
H17B H 0.2222 0.3811 0.9992 0.088 Uiso 1 1 calc R . .
C18 C 0.3653(3) 0.5497(2) 1.0294(3) 0.0558(9) Uani 1 1 d . . .
H18A H 0.4459 0.5444 1.0938 0.067 Uiso 1 1 calc R . .
H18B H 0.3762 0.5356 0.9586 0.067 Uiso 1 1 calc R . .
C19 C 0.6947(2) 0.7787(2) 1.1650(2) 0.0389(7) Uani 1 1 d . . .
H19A H 0.6778 0.6965 1.1466 0.047 Uiso 1 1 calc R . .
C20 C 0.8268(3) 0.8485(3) 1.1502(2) 0.0577(9) Uani 1 1 d . . .
H20A H 0.8396 0.9290 1.1611 0.069 Uiso 1 1 calc R . .
H20B H 0.8094 0.8188 1.0706 0.069 Uiso 1 1 calc R . .
C21 C 0.9664(3) 0.8431(3) 1.2375(3) 0.0802(12) Uani 1 1 d . . .
H21A H 0.9582 0.7640 1.2202 0.096 Uiso 1 1 calc R . .
H21B H 1.0483 0.8927 1.2278 0.096 Uiso 1 1 calc R . .
C22 C 0.9958(3) 0.8810(3) 1.3629(3) 0.0849(14) Uani 1 1 d . . .
H22A H 1.0809 0.8704 1.4148 0.102 Uiso 1 1 calc R . .
H22B H 1.0166 0.9631 1.3837 0.102 Uiso 1 1 calc R . .
C23 C 0.8669(3) 0.8120(3) 1.3794(3) 0.0843(13) Uani 1 1 d . . .
H23A H 0.8854 0.8421 1.4593 0.101 Uiso 1 1 calc R . .
H23B H 0.8541 0.7315 1.3685 0.101 Uiso 1 1 calc R . .
C24 C 0.7279(3) 0.8178(3) 1.2932(2) 0.0666(10) Uani 1 1 d . . .
H24A H 0.7369 0.8971 1.3107 0.080 Uiso 1 1 calc R . .
H24B H 0.6466 0.7689 1.3040 0.080 Uiso 1 1 calc R . .
C25 C 0.5179(2) 0.7600(2) 0.91754(19) 0.0356(6) Uani 1 1 d . . .
H25A H 0.6169 0.7888 0.9272 0.043 Uiso 1 1 calc R . .
H25B H 0.4744 0.6762 0.8852 0.043 Uiso 1 1 calc R . .
N1 N 0.7664(2) 1.1032(2) 0.9836(2) 0.0751(9) Uani 1 1 d . . .
C27 C 0.5574(3) 0.5128(3) 0.3673(3) 0.0765(13) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 P2 158.95(2) . 2_677 ?
P1 Ag1 N1 102.91(7) . . ?
P2 Ag1 N1 98.14(7) 2_677 . ?
P1 Ag1 Ag1 86.89(2) . 2_677 ?
P2 Ag1 Ag1 94.24(2) 2_677 2_677 ?
N1 Ag1 Ag1 87.71(7) . 2_677 ?
C26 Ag2 C26 180.000(2) 2_777 . ?
C27 Ag3 C27 180.000(1) . 2_666 ?
C7 P1 C25 104.81(12) . . ?
C7 P1 C1 108.56(11) . . ?
C25 P1 C1 102.80(12) . . ?
C7 P1 Ag1 114.61(9) . . ?
C25 P1 Ag1 111.71(7) . . ?
C1 P1 Ag1 113.38(9) . . ?
C13 P2 C25 105.56(11) . . ?
C13 P2 C19 107.52(12) . . ?
C25 P2 C19 104.59(12) . . ?
C13 P2 Ag1 109.51(9) . 2_677 ?
C25 P2 Ag1 111.58(9) . 2_677 ?
C19 P2 Ag1 117.34(8) . 2_677 ?
N1 C26 Ag2 174.0(2) . . ?
C2 C1 C6 109.9(2) . . ?
C2 C1 P1 111.7(2) . . ?
C6 C1 P1 111.00(16) . . ?
C2 C1 H1A 108.0 . . ?
C6 C1 H1A 108.0 . . ?
P1 C1 H1A 108.0 . . ?
C1 C2 C3 111.9(3) . . ?
C1 C2 H2A 109.2 . . ?
C3 C2 H2A 109.2 . . ?
C1 C2 H2B 109.2 . . ?
C3 C2 H2B 109.2 . . ?
H2A C2 H2B 107.9 . . ?
C4 C3 C2 111.6(2) . . ?
C4 C3 H3A 109.3 . . ?
C2 C3 H3A 109.3 . . ?
C4 C3 H3B 109.3 . . ?
C2 C3 H3B 109.3 . . ?
H3A C3 H3B 108.0 . . ?
C3 C4 C5 110.5(3) . . ?
C3 C4 H4A 109.6 . . ?
C5 C4 H4A 109.6 . . ?
C3 C4 H4B 109.6 . . ?
C5 C4 H4B 109.6 . . ?
H4A C4 H4B 108.1 . . ?
C4 C5 C6 111.3(3) . . ?
C4 C5 H5A 109.4 . . ?
C6 C5 H5A 109.4 . . ?
C4 C5 H5B 109.4 . . ?
C6 C5 H5B 109.4 . . ?
H5A C5 H5B 108.0 . . ?
C5 C6 C1 113.0(2) . . ?
C5 C6 H6A 109.0 . . ?
C1 C6 H6A 109.0 . . ?
C5 C6 H6B 109.0 . . ?
C1 C6 H6B 109.0 . . ?
H6A C6 H6B 107.8 . . ?
C12 C7 C8 110.31(19) . . ?
C12 C7 P1 114.84(19) . . ?
C8 C7 P1 114.89(19) . . ?
C12 C7 H7A 105.2 . . ?
C8 C7 H7A 105.2 . . ?
P1 C7 H7A 105.2 . . ?
C9 C8 C7 110.4(3) . . ?
C9 C8 H8A 109.6 . . ?
C7 C8 H8A 109.6 . . ?
C9 C8 H8B 109.6 . . ?
C7 C8 H8B 109.6 . . ?
H8A C8 H8B 108.1 . . ?
C10 C9 C8 112.5(3) . . ?
C10 C9 H9A 109.1 . . ?
C8 C9 H9A 109.1 . . ?
C10 C9 H9B 109.1 . . ?
C8 C9 H9B 109.1 . . ?
H9A C9 H9B 107.8 . . ?
C9 C10 C11 111.6(2) . . ?
C9 C10 H10A 109.3 . . ?
C11 C10 H10A 109.3 . . ?
C9 C10 H10B 109.3 . . ?
C11 C10 H10B 109.3 . . ?
H10A C10 H10B 108.0 . . ?
C10 C11 C12 111.8(3) . . ?
C10 C11 H11A 109.3 . . ?
C12 C11 H11A 109.3 . . ?
C10 C11 H11B 109.3 . . ?
C12 C11 H11B 109.3 . . ?
H11A C11 H11B 107.9 . . ?
C11 C12 C7 111.1(3) . . ?
C11 C12 H12A 109.4 . . ?
C7 C12 H12A 109.4 . . ?
C11 C12 H12B 109.4 . . ?
C7 C12 H12B 109.4 . . ?
H12A C12 H12B 108.0 . . ?
C18 C13 C14 110.8(2) . . ?
C18 C13 P2 116.13(19) . . ?
C14 C13 P2 112.67(16) . . ?
C18 C13 H13A 105.4 . . ?
C14 C13 H13A 105.4 . . ?
P2 C13 H13A 105.4 . . ?
C15 C14 C13 110.4(2) . . ?
C15 C14 H14A 109.6 . . ?
C13 C14 H14A 109.6 . . ?
C15 C14 H14B 109.6 . . ?
C13 C14 H14B 109.6 . . ?
H14A C14 H14B 108.1 . . ?
C14 C15 C16 111.0(3) . . ?
C14 C15 H15A 109.4 . . ?
C16 C15 H15A 109.4 . . ?
C14 C15 H15B 109.4 . . ?
C16 C15 H15B 109.4 . . ?
H15A C15 H15B 108.0 . . ?
C17 C16 C15 111.6(3) . . ?
C17 C16 H16A 109.3 . . ?
C15 C16 H16A 109.3 . . ?
C17 C16 H16B 109.3 . . ?
C15 C16 H16B 109.3 . . ?
H16A C16 H16B 108.0 . . ?
C16 C17 C18 111.6(2) . . ?
C16 C17 H17A 109.3 . . ?
C18 C17 H17A 109.3 . . ?
C16 C17 H17B 109.3 . . ?
C18 C17 H17B 109.3 . . ?
H17A C17 H17B 108.0 . . ?
C13 C18 C17 110.4(3) . . ?
C13 C18 H18A 109.6 . . ?
C17 C18 H18A 109.6 . . ?
C13 C18 H18B 109.6 . . ?
C17 C18 H18B 109.6 . . ?
H18A C18 H18B 108.1 . . ?
C20 C19 C24 109.1(2) . . ?
C20 C19 P2 112.31(19) . . ?
C24 C19 P2 110.8(2) . . ?
C20 C19 H19A 108.2 . . ?
C24 C19 H19A 108.2 . . ?
P2 C19 H19A 108.2 . . ?
C19 C20 C21 112.3(3) . . ?
C19 C20 H20A 109.1 . . ?
C21 C20 H20A 109.1 . . ?
C19 C20 H20B 109.1 . . ?
C21 C20 H20B 109.1 . . ?
H20A C20 H20B 107.9 . . ?
C22 C21 C20 112.3(3) . . ?
C22 C21 H21A 109.2 . . ?
C20 C21 H21A 109.2 . . ?
C22 C21 H21B 109.2 . . ?
C20 C21 H21B 109.2 . . ?
H21A C21 H21B 107.9 . . ?
C23 C22 C21 110.8(3) . . ?
C23 C22 H22A 109.5 . . ?
C21 C22 H22A 109.5 . . ?
C23 C22 H22B 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 108.1 . . ?
C22 C23 C24 111.6(3) . . ?
C22 C23 H23A 109.3 . . ?
C24 C23 H23A 109.3 . . ?
C22 C23 H23B 109.3 . . ?
C24 C23 H23B 109.3 . . ?
H23A C23 H23B 108.0 . . ?
C23 C24 C19 113.0(3) . . ?
C23 C24 H24A 109.0 . . ?
C19 C24 H24A 109.0 . . ?
C23 C24 H24B 109.0 . . ?
C19 C24 H24B 109.0 . . ?
H24A C24 H24B 107.8 . . ?
P1 C25 P2 115.98(14) . . ?
P1 C25 H25A 108.3 . . ?
P2 C25 H25A 108.3 . . ?
P1 C25 H25B 108.3 . . ?
P2 C25 H25B 108.3 . . ?
H25A C25 H25B 107.4 . . ?
C26 N1 Ag1 140.1(2) . . ?
N2 C27 Ag3 178.1(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4087(9) . ?
Ag1 P2 2.4125(9) 2_677 ?
Ag1 N1 2.522(2) . ?
Ag1 Ag1 2.9512(9) 2_677 ?
Ag2 C26 2.052(3) 2_777 ?
Ag2 C26 2.052(3) . ?
Ag3 C27 2.040(5) . ?
Ag3 C27 2.040(5) 2_666 ?
P1 C7 1.836(2) . ?
P1 C25 1.839(3) . ?
P1 C1 1.851(3) . ?
P2 C13 1.843(3) . ?
P2 C25 1.846(3) . ?
P2 C19 1.856(2) . ?
P2 Ag1 2.4125(9) 2_677 ?
C26 N1 1.139(4) . ?
N2 C27 1.145(5) . ?
C1 C2 1.518(4) . ?
C1 C6 1.519(3) . ?
C1 H1A 0.9800 . ?
C2 C3 1.520(4) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.502(4) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.507(5) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.516(4) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C12 1.529(4) . ?
C7 C8 1.535(4) . ?
C7 H7A 0.9800 . ?
C8 C9 1.520(4) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.508(5) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.513(5) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.522(4) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C18 1.531(4) . ?
C13 C14 1.531(4) . ?
C13 H13A 0.9800 . ?
C14 C15 1.525(4) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.525(5) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 C17 1.507(5) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.534(4) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C20 1.519(4) . ?
C19 C24 1.525(4) . ?
C19 H19A 0.9800 . ?
C20 C21 1.526(4) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.501(5) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.501(5) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.518(4) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Ag1 P1 C7 -15.05(13) 2_677 . . . ?
N1 Ag1 P1 C7 165.61(12) . . . . ?
Ag1 Ag1 P1 C7 78.68(9) 2_677 . . . ?
P2 Ag1 P1 C25 -134.06(10) 2_677 . . . ?
N1 Ag1 P1 C25 46.60(12) . . . . ?
Ag1 Ag1 P1 C25 -40.33(9) 2_677 . . . ?
P2 Ag1 P1 C1 110.36(10) 2_677 . . . ?
N1 Ag1 P1 C1 -68.99(11) . . . . ?
Ag1 Ag1 P1 C1 -155.92(8) 2_677 . . . ?
C26 Ag2 C26 N1 118(100) 2_777 . . . ?
C7 P1 C1 C2 63.9(2) . . . . ?
C25 P1 C1 C2 174.57(17) . . . . ?
Ag1 P1 C1 C2 -64.67(18) . . . . ?
C7 P1 C1 C6 -173.0(2) . . . . ?
C25 P1 C1 C6 -62.3(2) . . . . ?
Ag1 P1 C1 C6 58.4(2) . . . . ?
C6 C1 C2 C3 53.4(3) . . . . ?
P1 C1 C2 C3 177.1(2) . . . . ?
C1 C2 C3 C4 -56.5(4) . . . . ?
C2 C3 C4 C5 56.7(4) . . . . ?
C3 C4 C5 C6 -55.6(4) . . . . ?
C4 C5 C6 C1 54.9(3) . . . . ?
C2 C1 C6 C5 -53.2(3) . . . . ?
P1 C1 C6 C5 -177.3(2) . . . . ?
C25 P1 C7 C12 -65.8(2) . . . . ?
C1 P1 C7 C12 43.5(2) . . . . ?
Ag1 P1 C7 C12 171.43(17) . . . . ?
C25 P1 C7 C8 164.72(19) . . . . ?
C1 P1 C7 C8 -86.0(2) . . . . ?
Ag1 P1 C7 C8 41.9(2) . . . . ?
C12 C7 C8 C9 56.2(3) . . . . ?
P1 C7 C8 C9 -172.1(2) . . . . ?
C7 C8 C9 C10 -55.4(4) . . . . ?
C8 C9 C10 C11 54.1(4) . . . . ?
C9 C10 C11 C12 -53.6(4) . . . . ?
C10 C11 C12 C7 55.4(4) . . . . ?
C8 C7 C12 C11 -56.6(3) . . . . ?
P1 C7 C12 C11 171.7(2) . . . . ?
C25 P2 C13 C18 60.3(2) . . . . ?
C19 P2 C13 C18 -50.9(2) . . . . ?
Ag1 P2 C13 C18 -179.42(17) 2_677 . . . ?
C25 P2 C13 C14 -170.36(19) . . . . ?
C19 P2 C13 C14 78.4(2) . . . . ?
Ag1 P2 C13 C14 -50.1(2) 2_677 . . . ?
C18 C13 C14 C15 -57.3(3) . . . . ?
P2 C13 C14 C15 170.7(2) . . . . ?
C13 C14 C15 C16 56.5(3) . . . . ?
C14 C15 C16 C17 -55.8(3) . . . . ?
C15 C16 C17 C18 55.2(4) . . . . ?
C14 C13 C18 C17 56.4(3) . . . . ?
P2 C13 C18 C17 -173.4(2) . . . . ?
C16 C17 C18 C13 -55.5(4) . . . . ?
C13 P2 C19 C20 162.55(19) . . . . ?
C25 P2 C19 C20 50.7(2) . . . . ?
Ag1 P2 C19 C20 -73.6(2) 2_677 . . . ?
C13 P2 C19 C24 -75.2(2) . . . . ?
C25 P2 C19 C24 172.9(2) . . . . ?
Ag1 P2 C19 C24 48.7(2) 2_677 . . . ?
C24 C19 C20 C21 53.5(3) . . . . ?
P2 C19 C20 C21 176.7(2) . . . . ?
C19 C20 C21 C22 -55.3(4) . . . . ?
C20 C21 C22 C23 54.7(4) . . . . ?
C21 C22 C23 C24 -54.6(5) . . . . ?
C22 C23 C24 C19 55.7(4) . . . . ?
C20 C19 C24 C23 -54.1(4) . . . . ?
P2 C19 C24 C23 -178.2(2) . . . . ?
C7 P1 C25 P2 -73.96(15) . . . . ?
C1 P1 C25 P2 172.61(12) . . . . ?
Ag1 P1 C25 P2 50.71(14) . . . . ?
C13 P2 C25 P1 90.91(15) . . . . ?
C19 P2 C25 P1 -155.80(12) . . . . ?
Ag1 P2 C25 P1 -27.97(14) 2_677 . . . ?
Ag2 C26 N1 Ag1 -10(3) . . . . ?
P1 Ag1 N1 C26 6.2(4) . . . . ?
P2 Ag1 N1 C26 -173.6(4) 2_677 . . . ?
Ag1 Ag1 N1 C26 92.4(4) 2_677 . . . ?
C27 Ag3 C27 N2 151(100) 2_666 . . . ?
