#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:43:47 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179125 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/87/4308764.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4308764
loop_
_publ_author_name
'Yong-Yue Lin'
'Siu-Wai Lai'
'Chi-Ming Che'
'Wen-Fu Fu'
'Zhong-Yuan Zhou'
'Nianyong Zhu'
_publ_section_title
;
Structural Variations and Spectroscopic Properties of Luminescent Mono- and
Multinuclear Silver(I) and Copper(I) Complexes Bearing Phosphine and
Cyanide Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              1511
_journal_page_last               1524
_journal_paper_doi               10.1021/ic048876k
_journal_volume                  44
_journal_year                    2005
_chemical_formula_sum            'C57 H99 Cu3 N3 P3'
_chemical_formula_weight         1109.92
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.674(6)
_cell_angle_beta                 104.391(6)
_cell_angle_gamma                101.276(5)
_cell_formula_units_Z            2
_cell_length_a                   11.456(3)
_cell_length_b                   15.090(4)
_cell_length_c                   18.440(4)
_cell_measurement_reflns_used    4713
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      1
_cell_volume                     2999.6(13)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0484
_diffrn_reflns_av_sigmaI/netI    0.1619
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            20436
_diffrn_reflns_theta_full        27.60
_diffrn_reflns_theta_max         27.60
_diffrn_reflns_theta_min         1.88
_exptl_absorpt_coefficient_mu    1.170
_exptl_absorpt_correction_T_max  0.7997
_exptl_absorpt_correction_T_min  0.7353
_exptl_absorpt_correction_type   'multi scans'
_exptl_absorpt_process_details   'SADABS; Sheldrick 1996'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.229
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1188
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.637
_refine_diff_density_min         -0.353
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         13660
_refine_ls_number_restraints     130
_refine_ls_restrained_S_all      1.061
_refine_ls_R_factor_all          0.1730
_refine_ls_R_factor_gt           0.0636
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0200P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1066
_refine_ls_wR_factor_ref         0.1193
_reflns_number_gt                4801
_reflns_number_total             13660
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic048876ksi20040816_075836_5.cif
_cod_data_source_block           58_Cpd4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        2999.8(12)
_cod_database_code               4308764
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.58802(4) 0.87443(3) 0.36266(2) 0.06080(14) Uani 1 1 d . . .
Cu2 Cu 0.13444(4) 0.83617(3) 0.27062(3) 0.06857(15) Uani 1 1 d . . .
Cu3 Cu -0.15402(4) 1.04063(3) 0.21604(2) 0.06780(15) Uani 1 1 d . . .
P1 P 0.67512(8) 0.79655(6) 0.45170(5) 0.0504(3) Uani 1 1 d . . .
P2 P 0.04010(9) 0.68811(7) 0.22804(6) 0.0640(3) Uani 1 1 d . . .
P3 P -0.16046(8) 1.14440(6) 0.13817(5) 0.0527(3) Uani 1 1 d . . .
N1 N 0.3100(3) 0.85379(19) 0.32113(19) 0.0972(12) Uani 1 1 d . . .
N2 N -0.0156(3) 0.9807(2) 0.23932(18) 0.0901(11) Uani 1 1 d . . .
N3 N -0.3275(3) 0.9453(2) 0.29978(18) 0.1026(13) Uani 1 1 d . . .
C1 C 0.8445(3) 0.8325(2) 0.48762(16) 0.0564(11) Uani 1 1 d D . .
H1A H 0.8592 0.8963 0.5097 0.068 Uiso 1 1 calc R . .
C2 C 0.9087(2) 0.8368(2) 0.42522(18) 0.0738(13) Uani 1 1 d D . .
H2A H 0.8701 0.8717 0.3881 0.089 Uiso 1 1 calc R . .
H2B H 0.8978 0.7754 0.4002 0.089 Uiso 1 1 calc R . .
C3 C 1.0463(3) 0.8800(2) 0.4539(2) 0.0905(15) Uani 1 1 d D . .
H3A H 1.0841 0.8729 0.4128 0.109 Uiso 1 1 calc R . .
H3B H 1.0568 0.9448 0.4688 0.109 Uiso 1 1 calc R . .
C4 C 1.1127(3) 0.8397(3) 0.51966(19) 0.0978(17) Uani 1 1 d D . .
H4A H 1.1188 0.7788 0.5023 0.117 Uiso 1 1 calc R . .
H4B H 1.1959 0.8766 0.5403 0.117 Uiso 1 1 calc R . .
C5 C 1.0469(3) 0.8352(3) 0.5800(2) 0.1160(19) Uani 1 1 d D . .
H5A H 1.0537 0.8967 0.6032 0.139 Uiso 1 1 calc R . .
H5B H 1.0870 0.8028 0.6187 0.139 Uiso 1 1 calc R . .
C6 C 0.9108(3) 0.7880(3) 0.5505(2) 0.0809(14) Uani 1 1 d D . .
H6A H 0.9036 0.7245 0.5323 0.097 Uiso 1 1 calc R . .
H6B H 0.8719 0.7899 0.5916 0.097 Uiso 1 1 calc R . .
C7 C 0.6202(3) 0.80069(19) 0.53667(16) 0.0540(11) Uani 1 1 d D . .
H7A H 0.6554 0.7586 0.5688 0.065 Uiso 1 1 calc R . .
C8 C 0.4788(2) 0.7714(2) 0.51728(17) 0.0687(12) Uani 1 1 d D . .
H8A H 0.4426 0.8105 0.4832 0.082 Uiso 1 1 calc R . .
H8B H 0.4523 0.7093 0.4914 0.082 Uiso 1 1 calc R . .
C9 C 0.4322(3) 0.7766(2) 0.58714(18) 0.0798(13) Uani 1 1 d D . .
H9A H 0.4642 0.7348 0.6200 0.096 Uiso 1 1 calc R . .
H9B H 0.3426 0.7580 0.5725 0.096 Uiso 1 1 calc R . .
C10 C 0.4720(3) 0.8726(2) 0.6298(2) 0.0989(14) Uani 1 1 d D . .
H10A H 0.4357 0.9140 0.5983 0.119 Uiso 1 1 calc R . .
H10B H 0.4431 0.8739 0.6750 0.119 Uiso 1 1 calc R . .
C11 C 0.6112(3) 0.9027(2) 0.65130(18) 0.0830(14) Uani 1 1 d D . .
H11A H 0.6468 0.8646 0.6865 0.100 Uiso 1 1 calc R . .
H11B H 0.6359 0.9652 0.6763 0.100 Uiso 1 1 calc R . .
C12 C 0.6602(3) 0.8964(2) 0.58203(18) 0.0743(13) Uani 1 1 d D . .
H12A H 0.7498 0.9139 0.5980 0.089 Uiso 1 1 calc R . .
H12B H 0.6310 0.9394 0.5495 0.089 Uiso 1 1 calc R . .
C13 C 0.6437(3) 0.67499(19) 0.41366(15) 0.0532(11) Uani 1 1 d D . .
H13A H 0.7132 0.6699 0.3927 0.064 Uiso 1 1 calc R . .
C14 C 0.6435(3) 0.60487(17) 0.46806(17) 0.0651(12) Uani 1 1 d D . .
H14A H 0.7227 0.6191 0.5060 0.078 Uiso 1 1 calc R . .
H14B H 0.5801 0.6091 0.4938 0.078 Uiso 1 1 calc R . .
C15 C 0.6205(3) 0.5084(2) 0.42990(19) 0.0832(14) Uani 1 1 d D . .
H15A H 0.6920 0.5011 0.4128 0.100 Uiso 1 1 calc R . .
H15B H 0.6114 0.4668 0.4666 0.100 Uiso 1 1 calc R . .
C16 C 0.5093(4) 0.4832(2) 0.36461(19) 0.1022(17) Uani 1 1 d D . .
H16A H 0.4360 0.4802 0.3825 0.123 Uiso 1 1 calc R . .
H16B H 0.5049 0.4232 0.3393 0.123 Uiso 1 1 calc R . .
C17 C 0.5117(4) 0.55056(19) 0.30967(19) 0.0953(16) Uani 1 1 d D . .
H17A H 0.4340 0.5355 0.2705 0.114 Uiso 1 1 calc R . .
H17B H 0.5773 0.5463 0.2858 0.114 Uiso 1 1 calc R . .
C18 C 0.5321(3) 0.64714(19) 0.34696(17) 0.0750(14) Uani 1 1 d D . .
H18A H 0.5406 0.6883 0.3099 0.090 Uiso 1 1 calc R . .
H18B H 0.4596 0.6536 0.3633 0.090 Uiso 1 1 calc R . .
C19 C 0.0270(3) 0.6216(2) 0.30602(18) 0.0634(12) Uani 1 1 d D . .
H19A H -0.0217 0.6516 0.3328 0.076 Uiso 1 1 calc R . .
C20 C 0.1484(3) 0.6302(2) 0.36378(18) 0.0995(16) Uani 1 1 d D . .
H20A H 0.1874 0.6944 0.3791 0.119 Uiso 1 1 calc R . .
H20B H 0.2020 0.6022 0.3407 0.119 Uiso 1 1 calc R . .
C21 C 0.1362(4) 0.5863(2) 0.4337(2) 0.1059(17) Uani 1 1 d D . .
H21A H 0.2180 0.5894 0.4664 0.127 Uiso 1 1 calc R . .
H21B H 0.0933 0.6200 0.4613 0.127 Uiso 1 1 calc R . .
C22 C 0.0666(3) 0.4880(2) 0.4135(2) 0.0978(15) Uani 1 1 d D . .
H22A H 0.1153 0.4522 0.3928 0.117 Uiso 1 1 calc R . .
H22B H 0.0533 0.4641 0.4588 0.117 Uiso 1 1 calc R . .
C23 C -0.0556(4) 0.4795(3) 0.35696(19) 0.1065(18) Uani 1 1 d D . .
H23A H -0.1080 0.5084 0.3805 0.128 Uiso 1 1 calc R . .
H23B H -0.0955 0.4154 0.3422 0.128 Uiso 1 1 calc R . .
C24 C -0.0437(4) 0.5227(2) 0.28634(18) 0.0864(15) Uani 1 1 d D . .
H24A H -0.0012 0.4884 0.2588 0.104 Uiso 1 1 calc R . .
H24B H -0.1255 0.5196 0.2537 0.104 Uiso 1 1 calc R . .
C25 C 0.1220(3) 0.6306(2) 0.1713(2) 0.1054(17) Uani 1 1 d D . .
H25A H 0.1703 0.6062 0.2136 0.126 Uiso 1 1 calc R . .
C26 C 0.2253(3) 0.6856(3) 0.1555(3) 0.177(2) Uani 1 1 d D . .
H26A H 0.2790 0.7188 0.2031 0.213 Uiso 1 1 calc R . .
H26B H 0.1954 0.7304 0.1253 0.213 Uiso 1 1 calc R . .
C27 C 0.3031(3) 0.6425(3) 0.1161(2) 0.1128(17) Uani 1 1 d D . .
H27A H 0.3359 0.6853 0.0857 0.135 Uiso 1 1 calc R . .
H27B H 0.3727 0.6317 0.1539 0.135 Uiso 1 1 calc R . .
C28 C 0.2400(4) 0.5568(3) 0.0674(3) 0.192(3) Uani 1 1 d D . .
H28A H 0.2070 0.5716 0.0173 0.230 Uiso 1 1 calc R . .
H28B H 0.3023 0.5227 0.0639 0.230 Uiso 1 1 calc R . .
C29 C 0.1421(4) 0.4966(3) 0.0859(2) 0.154(2) Uani 1 1 d D . .
H29A H 0.1775 0.4555 0.1181 0.184 Uiso 1 1 calc R . .
H29B H 0.0885 0.4599 0.0396 0.184 Uiso 1 1 calc R . .
C30 C 0.0652(3) 0.5417(2) 0.12454(19) 0.0902(15) Uani 1 1 d D . .
H30A H -0.0059 0.5493 0.0861 0.108 Uiso 1 1 calc R . .
H30B H 0.0342 0.5001 0.1564 0.108 Uiso 1 1 calc R . .
C31 C -0.1195(3) 0.6703(2) 0.16755(16) 0.0680(12) Uani 1 1 d D . .
H31A H -0.1513 0.6050 0.1496 0.082 Uiso 1 1 calc R . .
C32 C -0.1233(3) 0.7217(3) 0.09916(18) 0.0866(14) Uani 1 1 d D . .
H32A H -0.0829 0.7853 0.1163 0.104 Uiso 1 1 calc R . .
H32B H -0.0780 0.6966 0.0676 0.104 Uiso 1 1 calc R . .
C33 C -0.2559(3) 0.7150(3) 0.0523(2) 0.1188(19) Uani 1 1 d D . .
H33A H -0.2552 0.7507 0.0110 0.143 Uiso 1 1 calc R . .
H33B H -0.2941 0.6520 0.0310 0.143 Uiso 1 1 calc R . .
C34 C -0.3309(3) 0.7498(3) 0.10104(19) 0.1149(18) Uani 1 1 d D . .
H34A H -0.2959 0.8140 0.1192 0.138 Uiso 1 1 calc R . .
H34B H -0.4150 0.7437 0.0706 0.138 Uiso 1 1 calc R . .
C35 C -0.3325(3) 0.6982(3) 0.1676(2) 0.1095(17) Uani 1 1 d D . .
H35A H -0.3752 0.6351 0.1498 0.131 Uiso 1 1 calc R . .
H35B H -0.3766 0.7246 0.1992 0.131 Uiso 1 1 calc R . .
C36 C -0.2008(3) 0.7023(3) 0.21382(18) 0.0810(14) Uani 1 1 d D . .
H36A H -0.2038 0.6647 0.2539 0.097 Uiso 1 1 calc R . .
H36B H -0.1630 0.7646 0.2373 0.097 Uiso 1 1 calc R . .
C37 C -0.1949(3) 1.0867(2) 0.04352(18) 0.0858(15) Uani 1 1 d D . .
H37A H -0.1285 1.0540 0.0449 0.103 Uiso 1 1 calc R . .
C38 C -0.3109(4) 1.0129(3) 0.0237(2) 0.145(2) Uani 1 1 d D . .
H38A H -0.3816 1.0406 0.0193 0.174 Uiso 1 1 calc R . .
H38B H -0.3085 0.9754 0.0641 0.174 Uiso 1 1 calc R . .
C39 C -0.3272(5) 0.9519(3) -0.0513(2) 0.175(3) Uani 1 1 d D . .
H39A H -0.2567 0.9241 -0.0471 0.210 Uiso 1 1 calc R . .
H39B H -0.4007 0.9034 -0.0607 0.210 Uiso 1 1 calc R . .
C40 C -0.3383(5) 1.0056(3) -0.1157(2) 0.183(3) Uani 1 1 d D . .
H40A H -0.4054 1.0371 -0.1195 0.219 Uiso 1 1 calc R . .
H40B H -0.3518 0.9670 -0.1631 0.219 Uiso 1 1 calc R . .
C41 C -0.2142(5) 1.0725(3) -0.0952(2) 0.178(3) Uani 1 1 d D . .
H41A H -0.2090 1.1084 -0.1361 0.213 Uiso 1 1 calc R . .
H41B H -0.1487 1.0393 -0.0884 0.213 Uiso 1 1 calc R . .
C42 C -0.1969(4) 1.1369(3) -0.02137(19) 0.123(2) Uani 1 1 d D . .
H42A H -0.1200 1.1822 -0.0114 0.148 Uiso 1 1 calc R . .
H42B H -0.2639 1.1687 -0.0280 0.148 Uiso 1 1 calc R . .
C43 C -0.2717(3) 1.21762(19) 0.13811(16) 0.0617(11) Uani 1 1 d D . .
H43A H -0.3448 1.1826 0.0993 0.074 Uiso 1 1 calc R . .
C44 C -0.2518(3) 1.30777(19) 0.10954(19) 0.0770(12) Uani 1 1 d D . .
H44A H -0.1756 1.3465 0.1416 0.092 Uiso 1 1 calc R . .
H44B H -0.2415 1.2983 0.0590 0.092 Uiso 1 1 calc R . .
C45 C -0.3543(3) 1.3565(2) 0.10697(19) 0.1017(15) Uani 1 1 d D . .
H45A H -0.3255 1.4190 0.0994 0.122 Uiso 1 1 calc R . .
H45B H -0.4225 1.3281 0.0634 0.122 Uiso 1 1 calc R . .
C46 C -0.4006(3) 1.3576(2) 0.1738(2) 0.1021(15) Uani 1 1 d D . .
H46A H -0.4778 1.3777 0.1621 0.123 Uiso 1 1 calc R . .
H46B H -0.3419 1.4019 0.2139 0.123 Uiso 1 1 calc R . .
C47 C -0.4216(3) 1.2682(2) 0.2020(2) 0.0912(14) Uani 1 1 d D . .
H47A H -0.4970 1.2293 0.1691 0.109 Uiso 1 1 calc R . .
H47B H -0.4336 1.2774 0.2520 0.109 Uiso 1 1 calc R . .
C48 C -0.3180(3) 1.2202(2) 0.20573(18) 0.0952(13) Uani 1 1 d D . .
H48A H -0.2499 1.2500 0.2489 0.114 Uiso 1 1 calc R . .
H48B H -0.3457 1.1581 0.2145 0.114 Uiso 1 1 calc R . .
C49 C -0.0098(2) 1.2239(2) 0.15419(15) 0.0499(10) Uani 1 1 d D . .
H49A H -0.0208 1.2732 0.1235 0.060 Uiso 1 1 calc R . .
C50 C 0.0372(3) 1.2649(2) 0.23677(17) 0.0715(13) Uani 1 1 d D . .
H50A H 0.0463 1.2164 0.2677 0.086 Uiso 1 1 calc R . .
H50B H -0.0232 1.2952 0.2502 0.086 Uiso 1 1 calc R . .
C51 C 0.1623(3) 1.3340(2) 0.2540(2) 0.0926(16) Uani 1 1 d D . .
H51A H 0.1518 1.3857 0.2270 0.111 Uiso 1 1 calc R . .
H51B H 0.1906 1.3563 0.3076 0.111 Uiso 1 1 calc R . .
C52 C 0.2565(3) 1.2913(3) 0.23115(19) 0.1035(17) Uani 1 1 d D . .
H52A H 0.2745 1.2446 0.2626 0.124 Uiso 1 1 calc R . .
H52B H 0.3324 1.3372 0.2389 0.124 Uiso 1 1 calc R . .
C53 C 0.2115(3) 1.2493(3) 0.1490(2) 0.1081(17) Uani 1 1 d D . .
H53A H 0.2728 1.2195 0.1362 0.130 Uiso 1 1 calc R . .
H53B H 0.2007 1.2968 0.1173 0.130 Uiso 1 1 calc R . .
C54 C 0.0881(3) 1.1792(2) 0.1341(2) 0.0918(15) Uani 1 1 d D . .
H54A H 0.0605 1.1534 0.0811 0.110 Uiso 1 1 calc R . .
H54B H 0.0998 1.1301 0.1639 0.110 Uiso 1 1 calc R . .
C55 C 0.4165(3) 0.8633(2) 0.3409(2) 0.0631(12) Uani 1 1 d . . .
C56 C 0.0492(3) 0.9293(2) 0.2522(2) 0.0692(12) Uani 1 1 d . . .
C57 C -0.2689(3) 0.9864(2) 0.26446(19) 0.0640(11) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C55 Cu1 N3 116.43(14) . 1_655 ?
C55 Cu1 P1 117.71(11) . . ?
N3 Cu1 P1 125.66(9) 1_655 . ?
C56 Cu2 N1 125.43(13) . . ?
C56 Cu2 P2 121.33(11) . . ?
N1 Cu2 P2 113.14(9) . . ?
C57 Cu3 N2 106.92(14) . . ?
C57 Cu3 P3 131.65(11) . . ?
N2 Cu3 P3 121.27(10) . . ?
C7 P1 C1 104.29(13) . . ?
C7 P1 C13 106.22(14) . . ?
C1 P1 C13 105.29(15) . . ?
C7 P1 Cu1 114.86(10) . . ?
C1 P1 Cu1 115.25(11) . . ?
C13 P1 Cu1 110.10(9) . . ?
C25 P2 C19 106.70(17) . . ?
C25 P2 C31 105.26(16) . . ?
C19 P2 C31 104.96(14) . . ?
C25 P2 Cu2 113.03(11) . . ?
C19 P2 Cu2 111.89(10) . . ?
C31 P2 Cu2 114.30(12) . . ?
C37 P3 C49 105.50(14) . . ?
C37 P3 C43 107.31(16) . . ?
C49 P3 C43 105.08(14) . . ?
C37 P3 Cu3 107.99(12) . . ?
C49 P3 Cu3 112.26(10) . . ?
C43 P3 Cu3 117.93(10) . . ?
C55 N1 Cu2 170.3(3) . . ?
C56 N2 Cu3 166.4(3) . . ?
C57 N3 Cu1 175.2(3) . 1_455 ?
C6 C1 C2 110.5(3) . . ?
C6 C1 P1 119.2(2) . . ?
C2 C1 P1 112.81(19) . . ?
C6 C1 H1A 104.2 . . ?
C2 C1 H1A 104.2 . . ?
P1 C1 H1A 104.2 . . ?
C1 C2 C3 112.8(3) . . ?
C1 C2 H2A 109.0 . . ?
C3 C2 H2A 109.0 . . ?
C1 C2 H2B 109.0 . . ?
C3 C2 H2B 109.0 . . ?
H2A C2 H2B 107.8 . . ?
C4 C3 C2 113.7(3) . . ?
C4 C3 H3A 108.8 . . ?
C2 C3 H3A 108.8 . . ?
C4 C3 H3B 108.8 . . ?
C2 C3 H3B 108.8 . . ?
H3A C3 H3B 107.7 . . ?
C5 C4 C3 111.4(3) . . ?
C5 C4 H4A 109.4 . . ?
C3 C4 H4A 109.4 . . ?
C5 C4 H4B 109.4 . . ?
C3 C4 H4B 109.3 . . ?
H4A C4 H4B 108.0 . . ?
C4 C5 C6 113.0(3) . . ?
C4 C5 H5A 109.0 . . ?
C6 C5 H5A 109.0 . . ?
C4 C5 H5B 109.0 . . ?
C6 C5 H5B 109.0 . . ?
H5A C5 H5B 107.8 . . ?
C1 C6 C5 111.6(3) . . ?
C1 C6 H6A 109.3 . . ?
C5 C6 H6A 109.3 . . ?
C1 C6 H6B 109.3 . . ?
C5 C6 H6B 109.3 . . ?
H6A C6 H6B 108.0 . . ?
C8 C7 C12 108.1(3) . . ?
C8 C7 P1 111.5(2) . . ?
C12 C7 P1 112.0(2) . . ?
C8 C7 H7A 108.4 . . ?
C12 C7 H7A 108.4 . . ?
P1 C7 H7A 108.4 . . ?
C9 C8 C7 111.9(2) . . ?
C9 C8 H8A 109.2 . . ?
C7 C8 H8A 109.2 . . ?
C9 C8 H8B 109.2 . . ?
C7 C8 H8B 109.2 . . ?
H8A C8 H8B 107.9 . . ?
C8 C9 C10 111.1(3) . . ?
C8 C9 H9A 109.4 . . ?
C10 C9 H9A 109.4 . . ?
C8 C9 H9B 109.4 . . ?
C10 C9 H9B 109.4 . . ?
H9A C9 H9B 108.0 . . ?
C11 C10 C9 109.7(3) . . ?
C11 C10 H10A 109.7 . . ?
C9 C10 H10A 109.7 . . ?
C11 C10 H10B 109.7 . . ?
C9 C10 H10B 109.7 . . ?
H10A C10 H10B 108.2 . . ?
C10 C11 C12 111.1(3) . . ?
C10 C11 H11A 109.4 . . ?
C12 C11 H11A 109.4 . . ?
C10 C11 H11B 109.4 . . ?
C12 C11 H11B 109.4 . . ?
H11A C11 H11B 108.0 . . ?
C11 C12 C7 113.1(3) . . ?
C11 C12 H12A 109.0 . . ?
C7 C12 H12A 109.0 . . ?
C11 C12 H12B 109.0 . . ?
C7 C12 H12B 109.0 . . ?
H12A C12 H12B 107.8 . . ?
C18 C13 C14 110.7(2) . . ?
C18 C13 P1 112.7(2) . . ?
C14 C13 P1 118.7(2) . . ?
C18 C13 H13A 104.4 . . ?
C14 C13 H13A 104.4 . . ?
P1 C13 H13A 104.4 . . ?
C15 C14 C13 113.3(3) . . ?
C15 C14 H14A 108.9 . . ?
C13 C14 H14A 108.9 . . ?
C15 C14 H14B 108.9 . . ?
C13 C14 H14B 108.9 . . ?
H14A C14 H14B 107.7 . . ?
C16 C15 C14 113.5(3) . . ?
C16 C15 H15A 108.9 . . ?
C14 C15 H15A 108.9 . . ?
C16 C15 H15B 108.9 . . ?
C14 C15 H15B 108.9 . . ?
H15A C15 H15B 107.7 . . ?
C15 C16 C17 111.4(3) . . ?
C15 C16 H16A 109.3 . . ?
C17 C16 H16A 109.3 . . ?
C15 C16 H16B 109.3 . . ?
C17 C16 H16B 109.3 . . ?
H16A C16 H16B 108.0 . . ?
C16 C17 C18 112.3(3) . . ?
C16 C17 H17A 109.1 . . ?
C18 C17 H17A 109.1 . . ?
C16 C17 H17B 109.1 . . ?
C18 C17 H17B 109.1 . . ?
H17A C17 H17B 107.9 . . ?
C13 C18 C17 113.8(3) . . ?
C13 C18 H18A 108.8 . . ?
C17 C18 H18A 108.8 . . ?
C13 C18 H18B 108.8 . . ?
C17 C18 H18B 108.8 . . ?
H18A C18 H18B 107.7 . . ?
C20 C19 C24 110.7(3) . . ?
C20 C19 P2 113.1(2) . . ?
C24 C19 P2 118.1(2) . . ?
C20 C19 H19A 104.4 . . ?
C24 C19 H19A 104.4 . . ?
P2 C19 H19A 104.4 . . ?
C19 C20 C21 113.6(3) . . ?
C19 C20 H20A 108.8 . . ?
C21 C20 H20A 108.9 . . ?
C19 C20 H20B 108.9 . . ?
C21 C20 H20B 108.9 . . ?
H20A C20 H20B 107.7 . . ?
C22 C21 C20 111.8(3) . . ?
C22 C21 H21A 109.3 . . ?
C20 C21 H21A 109.3 . . ?
C22 C21 H21B 109.3 . . ?
C20 C21 H21B 109.3 . . ?
H21A C21 H21B 107.9 . . ?
C23 C22 C21 110.8(3) . . ?
C23 C22 H22A 109.5 . . ?
C21 C22 H22A 109.5 . . ?
C23 C22 H22B 109.5 . . ?
C21 C22 H22B 109.5 . . ?
H22A C22 H22B 108.1 . . ?
C22 C23 C24 112.9(3) . . ?
C22 C23 H23A 109.0 . . ?
C24 C23 H23A 109.0 . . ?
C22 C23 H23B 109.0 . . ?
C24 C23 H23B 109.0 . . ?
H23A C23 H23B 107.8 . . ?
C19 C24 C23 111.7(3) . . ?
C19 C24 H24A 109.3 . . ?
C23 C24 H24A 109.3 . . ?
C19 C24 H24B 109.3 . . ?
C23 C24 H24B 109.3 . . ?
H24A C24 H24B 107.9 . . ?
C26 C25 C30 118.2(4) . . ?
C26 C25 P2 116.7(3) . . ?
C30 C25 P2 122.4(3) . . ?
C26 C25 H25A 95.5 . . ?
C30 C25 H25A 95.5 . . ?
P2 C25 H25A 95.5 . . ?
C25 C26 C27 119.8(4) . . ?
C25 C26 H26A 107.4 . . ?
C27 C26 H26A 107.4 . . ?
C25 C26 H26B 107.4 . . ?
C27 C26 H26B 107.4 . . ?
H26A C26 H26B 106.9 . . ?
C28 C27 C26 115.3(3) . . ?
C28 C27 H27A 108.5 . . ?
C26 C27 H27A 108.5 . . ?
C28 C27 H27B 108.5 . . ?
C26 C27 H27B 108.5 . . ?
H27A C27 H27B 107.5 . . ?
C29 C28 C27 120.3(4) . . ?
C29 C28 H28A 107.2 . . ?
C27 C28 H28A 107.3 . . ?
C29 C28 H28B 107.3 . . ?
C27 C28 H28B 107.3 . . ?
H28A C28 H28B 106.9 . . ?
C28 C29 C30 115.4(4) . . ?
C28 C29 H29A 108.4 . . ?
C30 C29 H29A 108.4 . . ?
C28 C29 H29B 108.4 . . ?
C30 C29 H29B 108.4 . . ?
H29A C29 H29B 107.5 . . ?
C25 C30 C29 118.6(3) . . ?
C25 C30 H30A 107.6 . . ?
C29 C30 H30A 107.6 . . ?
C25 C30 H30B 107.7 . . ?
C29 C30 H30B 107.7 . . ?
H30A C30 H30B 107.1 . . ?
C36 C31 C32 110.1(3) . . ?
C36 C31 P2 109.44(19) . . ?
C32 C31 P2 111.0(2) . . ?
C36 C31 H31A 108.7 . . ?
C32 C31 H31A 108.7 . . ?
P2 C31 H31A 108.7 . . ?
C33 C32 C31 111.7(3) . . ?
C33 C32 H32A 109.3 . . ?
C31 C32 H32A 109.3 . . ?
C33 C32 H32B 109.3 . . ?
C31 C32 H32B 109.3 . . ?
H32A C32 H32B 107.9 . . ?
C34 C33 C32 110.6(3) . . ?
C34 C33 H33A 109.5 . . ?
C32 C33 H33A 109.5 . . ?
C34 C33 H33B 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 108.1 . . ?
C35 C34 C33 111.8(3) . . ?
C35 C34 H34A 109.3 . . ?
C33 C34 H34A 109.3 . . ?
C35 C34 H34B 109.3 . . ?
C33 C34 H34B 109.2 . . ?
H34A C34 H34B 107.9 . . ?
C34 C35 C36 110.1(3) . . ?
C34 C35 H35A 109.6 . . ?
C36 C35 H35A 109.6 . . ?
C34 C35 H35B 109.6 . . ?
C36 C35 H35B 109.6 . . ?
H35A C35 H35B 108.1 . . ?
C35 C36 C31 113.8(3) . . ?
C35 C36 H36A 108.8 . . ?
C31 C36 H36A 108.8 . . ?
C35 C36 H36B 108.8 . . ?
C31 C36 H36B 108.8 . . ?
H36A C36 H36B 107.7 . . ?
C42 C37 C38 107.6(3) . . ?
C42 C37 P3 121.7(3) . . ?
C38 C37 P3 112.3(3) . . ?
C42 C37 H37A 104.5 . . ?
C38 C37 H37A 104.5 . . ?
P3 C37 H37A 104.5 . . ?
C37 C38 C39 112.1(4) . . ?
C37 C38 H38A 109.2 . . ?
C39 C38 H38A 109.2 . . ?
C37 C38 H38B 109.2 . . ?
C39 C38 H38B 109.2 . . ?
H38A C38 H38B 107.9 . . ?
C40 C39 C38 111.1(4) . . ?
C40 C39 H39A 109.4 . . ?
C38 C39 H39A 109.4 . . ?
C40 C39 H39B 109.4 . . ?
C38 C39 H39B 109.4 . . ?
H39A C39 H39B 108.0 . . ?
C39 C40 C41 102.7(4) . . ?
C39 C40 H40A 111.3 . . ?
C41 C40 H40A 111.3 . . ?
C39 C40 H40B 111.2 . . ?
C41 C40 H40B 111.2 . . ?
H40A C40 H40B 109.1 . . ?
C40 C41 C42 110.6(4) . . ?
C40 C41 H41A 109.5 . . ?
C42 C41 H41A 109.5 . . ?
C40 C41 H41B 109.6 . . ?
C42 C41 H41B 109.5 . . ?
H41A C41 H41B 108.1 . . ?
C37 C42 C41 111.8(3) . . ?
C37 C42 H42A 109.2 . . ?
C41 C42 H42A 109.3 . . ?
C37 C42 H42B 109.3 . . ?
C41 C42 H42B 109.3 . . ?
H42A C42 H42B 107.9 . . ?
C48 C43 C44 113.0(3) . . ?
C48 C43 P3 114.5(2) . . ?
C44 C43 P3 120.1(2) . . ?
C48 C43 H43A 101.8 . . ?
C44 C43 H43A 101.8 . . ?
P3 C43 H43A 101.8 . . ?
C45 C44 C43 114.4(3) . . ?
C45 C44 H44A 108.7 . . ?
C43 C44 H44A 108.7 . . ?
C45 C44 H44B 108.7 . . ?
C43 C44 H44B 108.7 . . ?
H44A C44 H44B 107.6 . . ?
C46 C45 C44 115.5(3) . . ?
C46 C45 H45A 108.4 . . ?
C44 C45 H45A 108.4 . . ?
C46 C45 H45B 108.4 . . ?
C44 C45 H45B 108.4 . . ?
H45A C45 H45B 107.5 . . ?
C45 C46 C47 114.0(3) . . ?
C45 C46 H46A 108.7 . . ?
C47 C46 H46A 108.7 . . ?
C45 C46 H46B 108.7 . . ?
C47 C46 H46B 108.7 . . ?
H46A C46 H46B 107.6 . . ?
C46 C47 C48 113.8(3) . . ?
C46 C47 H47A 108.8 . . ?
C48 C47 H47A 108.8 . . ?
C46 C47 H47B 108.8 . . ?
C48 C47 H47B 108.8 . . ?
H47A C47 H47B 107.7 . . ?
C43 C48 C47 115.3(3) . . ?
C43 C48 H48A 108.4 . . ?
C47 C48 H48A 108.5 . . ?
C43 C48 H48B 108.5 . . ?
C47 C48 H48B 108.4 . . ?
H48A C48 H48B 107.5 . . ?
C50 C49 C54 108.1(3) . . ?
C50 C49 P3 109.5(2) . . ?
C54 C49 P3 113.4(2) . . ?
C50 C49 H49A 108.6 . . ?
C54 C49 H49A 108.6 . . ?
P3 C49 H49A 108.6 . . ?
C49 C50 C51 112.3(3) . . ?
C49 C50 H50A 109.1 . . ?
C51 C50 H50A 109.1 . . ?
C49 C50 H50B 109.1 . . ?
C51 C50 H50B 109.1 . . ?
H50A C50 H50B 107.9 . . ?
C52 C51 C50 110.9(3) . . ?
C52 C51 H51A 109.5 . . ?
C50 C51 H51A 109.5 . . ?
C52 C51 H51B 109.4 . . ?
C50 C51 H51B 109.5 . . ?
H51A C51 H51B 108.0 . . ?
C51 C52 C53 111.1(3) . . ?
C51 C52 H52A 109.4 . . ?
C53 C52 H52A 109.4 . . ?
C51 C52 H52B 109.4 . . ?
C53 C52 H52B 109.4 . . ?
H52A C52 H52B 108.0 . . ?
C52 C53 C54 110.8(3) . . ?
C52 C53 H53A 109.5 . . ?
C54 C53 H53A 109.5 . . ?
C52 C53 H53B 109.5 . . ?
C54 C53 H53B 109.5 . . ?
H53A C53 H53B 108.1 . . ?
C49 C54 C53 110.7(3) . . ?
C49 C54 H54A 109.5 . . ?
C53 C54 H54A 109.5 . . ?
C49 C54 H54B 109.5 . . ?
C53 C54 H54B 109.5 . . ?
H54A C54 H54B 108.1 . . ?
N1 C55 Cu1 174.2(4) . . ?
N2 C56 Cu2 172.9(3) . . ?
N3 C57 Cu3 169.7(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 C55 1.876(3) . ?
Cu1 N3 1.945(4) 1_655 ?
Cu1 P1 2.2431(10) . ?
Cu2 C56 1.870(4) . ?
Cu2 N1 1.950(3) . ?
Cu2 P2 2.2638(11) . ?
Cu3 C57 1.866(3) . ?
Cu3 N2 1.950(3) . ?
Cu3 P3 2.2086(11) . ?
P1 C7 1.829(3) . ?
P1 C1 1.841(3) . ?
P1 C13 1.842(3) . ?
P2 C25 1.840(4) . ?
P2 C19 1.839(3) . ?
P2 C31 1.845(3) . ?
P3 C37 1.799(3) . ?
P3 C49 1.840(3) . ?
P3 C43 1.843(3) . ?
N1 C55 1.159(4) . ?
N2 C56 1.173(4) . ?
N3 C57 1.174(4) . ?
N3 Cu1 1.945(4) 1_455 ?
C1 C6 1.504(4) . ?
C1 C2 1.511(4) . ?
C1 H1A 0.9800 . ?
C2 C3 1.522(4) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C4 1.504(4) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.489(4) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.522(4) . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C8 1.535(3) . ?
C7 C12 1.533(4) . ?
C7 H7A 0.9800 . ?
C8 C9 1.514(4) . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C10 1.517(4) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.510(4) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.521(4) . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C13 C18 1.500(3) . ?
C13 C14 1.516(4) . ?
C13 H13A 0.9800 . ?
C14 C15 1.508(4) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C15 C16 1.480(4) . ?
C15 H15A 0.9700 . ?
C15 H15B 0.9700 . ?
C16 C17 1.494(4) . ?
C16 H16A 0.9700 . ?
C16 H16B 0.9700 . ?
C17 C18 1.508(4) . ?
C17 H17A 0.9700 . ?
C17 H17B 0.9700 . ?
C18 H18A 0.9700 . ?
C18 H18B 0.9700 . ?
C19 C20 1.502(4) . ?
C19 C24 1.519(4) . ?
C19 H19A 0.9800 . ?
C20 C21 1.520(4) . ?
C20 H20A 0.9700 . ?
C20 H20B 0.9700 . ?
C21 C22 1.508(4) . ?
C21 H21A 0.9700 . ?
C21 H21B 0.9700 . ?
C22 C23 1.499(4) . ?
C22 H22A 0.9700 . ?
C22 H22B 0.9700 . ?
C23 C24 1.527(4) . ?
C23 H23A 0.9700 . ?
C23 H23B 0.9700 . ?
C24 H24A 0.9700 . ?
C24 H24B 0.9700 . ?
C25 C26 1.415(4) . ?
C25 C30 1.468(4) . ?
C25 H25A 0.9800 . ?
C26 C27 1.489(4) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.457(4) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 C29 1.428(5) . ?
C28 H28A 0.9700 . ?
C28 H28B 0.9700 . ?
C29 C30 1.489(4) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C31 C36 1.527(4) . ?
C31 C32 1.529(4) . ?
C31 H31A 0.9800 . ?
C32 C33 1.529(4) . ?
C32 H32A 0.9700 . ?
C32 H32B 0.9700 . ?
C33 C34 1.517(4) . ?
C33 H33A 0.9700 . ?
C33 H33B 0.9700 . ?
C34 C35 1.508(4) . ?
C34 H34A 0.9700 . ?
C34 H34B 0.9700 . ?
C35 C36 1.524(4) . ?
C35 H35A 0.9700 . ?
C35 H35B 0.9700 . ?
C36 H36A 0.9700 . ?
C36 H36B 0.9700 . ?
C37 C42 1.466(4) . ?
C37 C38 1.501(4) . ?
C37 H37A 0.9800 . ?
C38 C39 1.547(4) . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C39 C40 1.486(5) . ?
C39 H39A 0.9700 . ?
C39 H39B 0.9700 . ?
C40 C41 1.514(5) . ?
C40 H40A 0.9700 . ?
C40 H40B 0.9700 . ?
C41 C42 1.553(4) . ?
C41 H41A 0.9700 . ?
C41 H41B 0.9700 . ?
C42 H42A 0.9700 . ?
C42 H42B 0.9700 . ?
C43 C48 1.472(4) . ?
C43 C44 1.495(4) . ?
C43 H43A 0.9800 . ?
C44 C45 1.496(4) . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C45 C46 1.459(4) . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C46 C47 1.483(4) . ?
C46 H46A 0.9700 . ?
C46 H46B 0.9700 . ?
C47 C48 1.496(4) . ?
C47 H47A 0.9700 . ?
C47 H47B 0.9700 . ?
C48 H48A 0.9700 . ?
C48 H48B 0.9700 . ?
C49 C50 1.517(3) . ?
C49 C54 1.520(4) . ?
C49 H49A 0.9800 . ?
C50 C51 1.541(4) . ?
C50 H50A 0.9700 . ?
C50 H50B 0.9700 . ?
C51 C52 1.487(4) . ?
C51 H51A 0.9700 . ?
C51 H51B 0.9700 . ?
C52 C53 1.513(4) . ?
C52 H52A 0.9700 . ?
C52 H52B 0.9700 . ?
C53 C54 1.538(4) . ?
C53 H53A 0.9700 . ?
C53 H53B 0.9700 . ?
C54 H54A 0.9700 . ?
C54 H54B 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C55 Cu1 P1 C7 -43.59(16) . . . . ?
N3 Cu1 P1 C7 141.67(15) 1_655 . . . ?
C55 Cu1 P1 C1 -164.88(17) . . . . ?
N3 Cu1 P1 C1 20.39(17) 1_655 . . . ?
C55 Cu1 P1 C13 76.23(17) . . . . ?
N3 Cu1 P1 C13 -98.50(16) 1_655 . . . ?
C56 Cu2 P2 C25 125.8(2) . . . . ?
N1 Cu2 P2 C25 -50.76(19) . . . . ?
C56 Cu2 P2 C19 -113.66(18) . . . . ?
N1 Cu2 P2 C19 69.73(17) . . . . ?
C56 Cu2 P2 C31 5.46(18) . . . . ?
N1 Cu2 P2 C31 -171.15(16) . . . . ?
C57 Cu3 P3 C37 -101.14(19) . . . . ?
N2 Cu3 P3 C37 73.54(16) . . . . ?
C57 Cu3 P3 C49 142.97(17) . . . . ?
N2 Cu3 P3 C49 -42.35(15) . . . . ?
C57 Cu3 P3 C43 20.61(18) . . . . ?
N2 Cu3 P3 C43 -164.71(14) . . . . ?
C56 Cu2 N1 C55 -95.7(17) . . . . ?
P2 Cu2 N1 C55 80.7(17) . . . . ?
C57 Cu3 N2 C56 36.7(14) . . . . ?
P3 Cu3 N2 C56 -139.1(13) . . . . ?
C7 P1 C1 C6 49.7(3) . . . . ?
C13 P1 C1 C6 -61.9(3) . . . . ?
Cu1 P1 C1 C6 176.6(2) . . . . ?
C7 P1 C1 C2 -178.1(2) . . . . ?
C13 P1 C1 C2 70.3(3) . . . . ?
Cu1 P1 C1 C2 -51.2(3) . . . . ?
C6 C1 C2 C3 -52.4(4) . . . . ?
P1 C1 C2 C3 171.3(2) . . . . ?
C1 C2 C3 C4 50.5(4) . . . . ?
C2 C3 C4 C5 -49.6(4) . . . . ?
C3 C4 C5 C6 52.3(5) . . . . ?
C2 C1 C6 C5 54.8(4) . . . . ?
P1 C1 C6 C5 -172.0(3) . . . . ?
C4 C5 C6 C1 -56.0(5) . . . . ?
C1 P1 C7 C8 -179.4(2) . . . . ?
C13 P1 C7 C8 -68.4(2) . . . . ?
Cu1 P1 C7 C8 53.5(2) . . . . ?
C1 P1 C7 C12 59.3(2) . . . . ?
C13 P1 C7 C12 170.2(2) . . . . ?
Cu1 P1 C7 C12 -67.8(2) . . . . ?
C12 C7 C8 C9 -55.2(4) . . . . ?
P1 C7 C8 C9 -178.7(2) . . . . ?
C7 C8 C9 C10 58.6(4) . . . . ?
C8 C9 C10 C11 -57.8(4) . . . . ?
C9 C10 C11 C12 56.3(4) . . . . ?
C10 C11 C12 C7 -56.4(4) . . . . ?
C8 C7 C12 C11 54.3(3) . . . . ?
P1 C7 C12 C11 177.6(2) . . . . ?
C7 P1 C13 C18 102.4(3) . . . . ?
C1 P1 C13 C18 -147.3(2) . . . . ?
Cu1 P1 C13 C18 -22.5(3) . . . . ?
C7 P1 C13 C14 -29.3(3) . . . . ?
C1 P1 C13 C14 81.0(3) . . . . ?
Cu1 P1 C13 C14 -154.2(2) . . . . ?
C18 C13 C14 C15 49.2(4) . . . . ?
P1 C13 C14 C15 -178.3(2) . . . . ?
C13 C14 C15 C16 -51.6(4) . . . . ?
C14 C15 C16 C17 52.7(5) . . . . ?
C15 C16 C17 C18 -53.0(5) . . . . ?
C14 C13 C18 C17 -50.4(4) . . . . ?
P1 C13 C18 C17 174.0(3) . . . . ?
C16 C17 C18 C13 53.2(5) . . . . ?
C25 P2 C19 C20 70.8(3) . . . . ?
C31 P2 C19 C20 -177.8(3) . . . . ?
Cu2 P2 C19 C20 -53.3(3) . . . . ?
C25 P2 C19 C24 -60.8(3) . . . . ?
C31 P2 C19 C24 50.5(3) . . . . ?
Cu2 P2 C19 C24 175.0(2) . . . . ?
C24 C19 C20 C21 -52.7(4) . . . . ?
P2 C19 C20 C21 172.1(3) . . . . ?
C19 C20 C21 C22 53.8(5) . . . . ?
C20 C21 C22 C23 -53.3(5) . . . . ?
C21 C22 C23 C24 54.4(5) . . . . ?
C20 C19 C24 C23 52.2(4) . . . . ?
P2 C19 C24 C23 -175.1(3) . . . . ?
C22 C23 C24 C19 -54.4(5) . . . . ?
C19 P2 C25 C26 -128.7(3) . . . . ?
C31 P2 C25 C26 120.1(3) . . . . ?
Cu2 P2 C25 C26 -5.3(4) . . . . ?
C19 P2 C25 C30 70.2(4) . . . . ?
C31 P2 C25 C30 -40.9(4) . . . . ?
Cu2 P2 C25 C30 -166.3(3) . . . . ?
C30 C25 C26 C27 -23.8(6) . . . . ?
P2 C25 C26 C27 174.3(3) . . . . ?
C25 C26 C27 C28 26.8(6) . . . . ?
C26 C27 C28 C29 -31.8(7) . . . . ?
C27 C28 C29 C30 32.8(6) . . . . ?
C26 C25 C30 C29 24.5(6) . . . . ?
P2 C25 C30 C29 -174.7(3) . . . . ?
C28 C29 C30 C25 -28.4(6) . . . . ?
C25 P2 C31 C36 171.0(2) . . . . ?
C19 P2 C31 C36 58.6(3) . . . . ?
Cu2 P2 C31 C36 -64.4(3) . . . . ?
C25 P2 C31 C32 -67.2(3) . . . . ?
C19 P2 C31 C32 -179.6(2) . . . . ?
Cu2 P2 C31 C32 57.4(3) . . . . ?
C36 C31 C32 C33 -53.4(4) . . . . ?
P2 C31 C32 C33 -174.7(3) . . . . ?
C31 C32 C33 C34 56.4(4) . . . . ?
C32 C33 C34 C35 -57.7(4) . . . . ?
C33 C34 C35 C36 55.7(4) . . . . ?
C34 C35 C36 C31 -54.0(4) . . . . ?
C32 C31 C36 C35 52.8(4) . . . . ?
P2 C31 C36 C35 175.1(3) . . . . ?
C49 P3 C37 C42 -55.3(4) . . . . ?
C43 P3 C37 C42 56.4(4) . . . . ?
Cu3 P3 C37 C42 -175.5(3) . . . . ?
C49 P3 C37 C38 175.1(3) . . . . ?
C43 P3 C37 C38 -73.3(3) . . . . ?
Cu3 P3 C37 C38 54.8(3) . . . . ?
C42 C37 C38 C39 54.1(5) . . . . ?
P3 C37 C38 C39 -169.3(3) . . . . ?
C37 C38 C39 C40 -62.0(6) . . . . ?
C38 C39 C40 C41 63.2(6) . . . . ?
C39 C40 C41 C42 -63.7(5) . . . . ?
C38 C37 C42 C41 -54.8(5) . . . . ?
P3 C37 C42 C41 173.6(3) . . . . ?
C40 C41 C42 C37 63.4(5) . . . . ?
C37 P3 C43 C48 140.5(2) . . . . ?
C49 P3 C43 C48 -107.5(2) . . . . ?
Cu3 P3 C43 C48 18.4(3) . . . . ?
C37 P3 C43 C44 -79.8(3) . . . . ?
C49 P3 C43 C44 32.2(3) . . . . ?
Cu3 P3 C43 C44 158.1(2) . . . . ?
C48 C43 C44 C45 -44.5(4) . . . . ?
P3 C43 C44 C45 175.3(2) . . . . ?
C43 C44 C45 C46 45.0(4) . . . . ?
C44 C45 C46 C47 -45.3(4) . . . . ?
C45 C46 C47 C48 45.6(4) . . . . ?
C44 C43 C48 C47 45.9(4) . . . . ?
P3 C43 C48 C47 -171.5(2) . . . . ?
C46 C47 C48 C43 -46.7(4) . . . . ?
C37 P3 C49 C50 -170.9(2) . . . . ?
C43 P3 C49 C50 75.9(2) . . . . ?
Cu3 P3 C49 C50 -53.5(2) . . . . ?
C37 P3 C49 C54 -50.1(3) . . . . ?
C43 P3 C49 C54 -163.3(2) . . . . ?
Cu3 P3 C49 C54 67.3(2) . . . . ?
C54 C49 C50 C51 57.3(4) . . . . ?
P3 C49 C50 C51 -178.7(2) . . . . ?
C49 C50 C51 C52 -56.4(4) . . . . ?
C50 C51 C52 C53 54.8(4) . . . . ?
C51 C52 C53 C54 -56.6(5) . . . . ?
C50 C49 C54 C53 -58.2(4) . . . . ?
P3 C49 C54 C53 -179.8(2) . . . . ?
C52 C53 C54 C49 58.8(4) . . . . ?
Cu2 N1 C55 Cu1 -14(5) . . . . ?
N3 Cu1 C55 N1 53(3) 1_655 . . . ?
P1 Cu1 C55 N1 -122(3) . . . . ?
Cu3 N2 C56 Cu2 3(4) . . . . ?
N1 Cu2 C56 N2 -163(3) . . . . ?
P2 Cu2 C56 N2 21(3) . . . . ?
Cu1 N3 C57 Cu3 11(5) 1_455 . . . ?
N2 Cu3 C57 N3 6.6(18) . . . . ?
P3 Cu3 C57 N3 -178.2(17) . . . . ?
