#------------------------------------------------------------------------------
#$Date: 2016-03-23 00:53:07 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179133 $
#$URL: svn://www.crystallography.net/cod/cif/4/30/95/4309598.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4309598
loop_
_publ_author_name
'Catelijne H. M. Amijs'
'Alexsandro Berger'
'Fouad Soulimani'
'Tom Visser'
'Gerard P. M. van Klink'
'Martin Lutz'
'Anthony L. Spek'
'Gerard van Koten'
_publ_contact_author_address
; Bijvoet Center for Biomolecular Research
  Dep. Crystal and Structural Chemistry
  Utrecht University
  Padualaan 8
  3584 CH Utrecht
  The Netherlands
;
_publ_contact_author_email       m.lutz@chem.uu.nl
_publ_contact_author_fax         '[+31] 30 2533940'
_publ_contact_author_name        'Martin Lutz'
_publ_contact_author_phone       '[+31] 30 2533902'
_publ_section_title
;
Neutral Pyridyl-Functionalized C,N-ortho-Chelated Aminoaryl Platinum(II)
Corner Building Blocks for Application in Coordination Reactions
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              6567
_journal_page_last               6578
_journal_paper_doi               10.1021/ic050697v
_journal_volume                  44
_journal_year                    2005
_chemical_formula_moiety         'C52 H68 N8 Pt3, 2(N O3)'
_chemical_formula_sum            'C52 H68 N10 O6 Pt3'
_chemical_formula_weight         1514.43
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 128.2015(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   18.1883(3)
_cell_length_b                   21.1087(4)
_cell_length_c                   23.0192(4)
_cell_measurement_reflns_used    193230
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      23.53
_cell_measurement_theta_min      1.02
_cell_volume                     6945.1(2)
_computing_cell_refinement       HKL2000
_computing_data_collection       'Nonius COLLECT'
_computing_data_reduction        'HKL2000, ABST, SortAV, SQUEEZE'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF-99 (Beurskens et al., 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0739
_diffrn_reflns_av_sigmaI/netI    0.0472
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            70031
_diffrn_reflns_theta_full        23.50
_diffrn_reflns_theta_max         23.50
_diffrn_reflns_theta_min         1.42
_exptl_absorpt_coefficient_mu    6.072
_exptl_absorpt_correction_T_max  0.80785
_exptl_absorpt_correction_T_min  0.20668
_exptl_absorpt_correction_type   analytical
_exptl_crystal_colour            yellowish
_exptl_crystal_density_diffrn    1.448
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2928
_exptl_crystal_size_max          0.42
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.458
_refine_diff_density_min         -0.731
_refine_diff_density_rms         0.128
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     612
_refine_ls_number_reflns         10269
_refine_ls_number_restraints     32
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0567
_refine_ls_R_factor_gt           0.0405
_refine_ls_shift/su_max          0.020
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0637P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1074
_refine_ls_wR_factor_ref         0.1138
_reflns_number_gt                7459
_reflns_number_total             10269
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic050697vsi20050504_091400_1.cif
_cod_data_source_block           s3090a
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4309598
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.36682(2) 0.926111(16) 0.364254(19) 0.04872(12) Uani 1 1 d . . .
Pt2 Pt -0.11940(2) 0.597586(15) 0.358071(17) 0.04258(11) Uani 1 1 d . . .
Pt3 Pt 0.05476(3) 0.079182(15) 0.42711(2) 0.05106(12) Uani 1 1 d . . .
N11 N 0.4340(5) 0.8707(4) 0.3355(4) 0.069(2) Uani 1 1 d . . .
N12 N 0.3176(5) 1.0007(3) 0.3901(4) 0.0524(18) Uani 1 1 d . . .
C11 C 0.4445(6) 0.9926(4) 0.3694(5) 0.053(2) Uani 1 1 d . . .
C12 C 0.4924(6) 0.9808(5) 0.3418(5) 0.064(3) Uani 1 1 d . . .
C13 C 0.5423(7) 1.0302(7) 0.3415(6) 0.081(3) Uani 1 1 d . . .
H13 H 0.5755 1.0232 0.3225 0.097 Uiso 1 1 calc R . .
C14 C 0.5447(8) 1.0888(6) 0.3679(6) 0.085(4) Uani 1 1 d . . .
H14 H 0.5803 1.1218 0.3679 0.101 Uiso 1 1 calc R . .
C15 C 0.4945(7) 1.1005(4) 0.3952(6) 0.070(3) Uani 1 1 d . . .
H15 H 0.4946 1.1413 0.4125 0.085 Uiso 1 1 calc R . .
C16 C 0.4446(6) 1.0504(5) 0.3960(5) 0.057(2) Uani 1 1 d . . .
C17 C 0.4746(7) 0.9163(5) 0.3073(6) 0.076(3) Uani 1 1 d . . .
H17A H 0.5337 0.8986 0.3206 0.091 Uiso 1 1 calc R . .
H17B H 0.4295 0.9199 0.2528 0.091 Uiso 1 1 calc R . .
C18 C 0.5178(7) 0.8389(5) 0.4045(6) 0.085(3) Uani 1 1 d . . .
H18A H 0.4970 0.8133 0.4274 0.128 Uiso 1 1 calc R . .
H18B H 0.5619 0.8712 0.4395 0.128 Uiso 1 1 calc R . .
H18C H 0.5487 0.8114 0.3911 0.128 Uiso 1 1 calc R . .
C19 C 0.3746(8) 0.8225(5) 0.2789(6) 0.089(3) Uani 1 1 d . . .
H19A H 0.4120 0.7979 0.2695 0.133 Uiso 1 1 calc R . .
H19B H 0.3231 0.8433 0.2331 0.133 Uiso 1 1 calc R . .
H19C H 0.3492 0.7942 0.2963 0.133 Uiso 1 1 calc R . .
C110 C 0.3932(6) 1.0538(4) 0.4270(5) 0.057(2) Uani 1 1 d . . .
H11A H 0.3632 1.0959 0.4166 0.069 Uiso 1 1 calc R . .
H11B H 0.4370 1.0477 0.4812 0.069 Uiso 1 1 calc R . .
C111 C 0.2333(6) 1.0270(4) 0.3205(4) 0.055(2) Uani 1 1 d . . .
H11C H 0.2091 1.0624 0.3317 0.083 Uiso 1 1 calc R . .
H11D H 0.1854 0.9940 0.2941 0.083 Uiso 1 1 calc R . .
H11E H 0.2496 1.0421 0.2894 0.083 Uiso 1 1 calc R . .
C112 C 0.2928(7) 0.9855(5) 0.4390(5) 0.073(3) Uani 1 1 d . . .
H11F H 0.2841 1.0249 0.4566 0.109 Uiso 1 1 calc R . .
H11G H 0.3432 0.9607 0.4813 0.109 Uiso 1 1 calc R . .
H11H H 0.2346 0.9609 0.4113 0.109 Uiso 1 1 calc R . .
N21 N -0.1880(5) 0.6896(3) 0.3113(4) 0.0501(18) Uani 1 1 d . . .
N22 N 0.2795(5) 0.8533(3) 0.3570(4) 0.0541(18) Uani 1 1 d . . .
C21 C -0.0242(6) 0.6383(4) 0.3532(4) 0.043(2) Uani 1 1 d . . .
C22 C -0.0582(6) 0.6922(3) 0.3057(4) 0.043(2) Uani 1 1 d . . .
C23 C 0.0014(6) 0.7284(4) 0.3030(4) 0.048(2) Uani 1 1 d . . .
H23 H -0.0233 0.7631 0.2694 0.058 Uiso 1 1 calc R . .
C24 C 0.0972(6) 0.7168(4) 0.3473(5) 0.051(2) Uani 1 1 d . . .
C25 C 0.1296(6) 0.6651(4) 0.3939(4) 0.050(2) Uani 1 1 d . . .
H25 H 0.1947 0.6559 0.4254 0.060 Uiso 1 1 calc R . .
C26 C 0.0706(6) 0.6266(4) 0.3960(4) 0.043(2) Uani 1 1 d . . .
H26 H 0.0957 0.5909 0.4279 0.052 Uiso 1 1 calc R . .
C27 C -0.1596(6) 0.7074(4) 0.2640(5) 0.054(2) Uani 1 1 d . . .
H27A H -0.1976 0.6834 0.2170 0.065 Uiso 1 1 calc R . .
H27B H -0.1704 0.7532 0.2522 0.065 Uiso 1 1 calc R . .
C28 C -0.2913(6) 0.6910(4) 0.2609(6) 0.074(3) Uani 1 1 d . . .
H28A H -0.3130 0.7315 0.2346 0.111 Uiso 1 1 calc R . .
H28B H -0.3143 0.6861 0.2896 0.111 Uiso 1 1 calc R . .
H28C H -0.3153 0.6563 0.2252 0.111 Uiso 1 1 calc R . .
C29 C -0.1499(7) 0.7400(4) 0.3687(5) 0.068(3) Uani 1 1 d . . .
H29A H -0.1781 0.7808 0.3446 0.101 Uiso 1 1 calc R . .
H29B H -0.0819 0.7426 0.3971 0.101 Uiso 1 1 calc R . .
H29C H -0.1647 0.7299 0.4020 0.101 Uiso 1 1 calc R . .
C210 C 0.1611(6) 0.7630(4) 0.3468(5) 0.055(2) Uani 1 1 d . . .
C211 C 0.1342(6) 0.7972(5) 0.2899(5) 0.062(3) Uani 1 1 d . . .
H211 H 0.0738 0.7905 0.2443 0.074 Uiso 1 1 calc R . .
C212 C 0.1920(7) 0.8432(4) 0.2942(5) 0.061(2) Uani 1 1 d . . .
H212 H 0.1694 0.8682 0.2518 0.073 Uiso 1 1 calc R . .
C213 C 0.3077(6) 0.8178(4) 0.4165(5) 0.058(2) Uani 1 1 d . . .
H213 H 0.3683 0.8250 0.4617 0.070 Uiso 1 1 calc R . .
C214 C 0.2528(7) 0.7721(5) 0.4145(5) 0.067(3) Uani 1 1 d . . .
H214 H 0.2752 0.7471 0.4568 0.081 Uiso 1 1 calc R . .
N31 N -0.2081(4) 0.5540(3) 0.3820(3) 0.0424(16) Uani 1 1 d . . .
N32 N 0.0302(6) 0.1789(3) 0.4229(4) 0.062(2) Uani 1 1 d . . .
C31 C -0.0660(5) 0.5114(3) 0.3830(4) 0.0401(19) Uani 1 1 d . . .
C32 C -0.0969(5) 0.4709(3) 0.4122(4) 0.0391(19) Uani 1 1 d . . .
C33 C -0.0738(6) 0.4066(4) 0.4255(4) 0.044(2) Uani 1 1 d . . .
H33 H -0.0929 0.3814 0.4483 0.053 Uiso 1 1 calc R . .
C34 C -0.0219(6) 0.3788(4) 0.4051(4) 0.045(2) Uani 1 1 d . . .
C35 C 0.0052(5) 0.4188(4) 0.3726(4) 0.041(2) Uani 1 1 d . . .
H35 H 0.0391 0.4016 0.3573 0.050 Uiso 1 1 calc R . .
C36 C -0.0161(5) 0.4823(3) 0.3623(4) 0.0415(19) Uani 1 1 d . . .
H36 H 0.0039 0.5075 0.3401 0.050 Uiso 1 1 calc R . .
C37 C -0.1492(6) 0.5027(4) 0.4357(4) 0.046(2) Uani 1 1 d . . .
H37A H -0.1890 0.4715 0.4366 0.055 Uiso 1 1 calc R . .
H37B H -0.1044 0.5207 0.4859 0.055 Uiso 1 1 calc R . .
C38 C -0.2944(6) 0.5271(4) 0.3170(5) 0.060(2) Uani 1 1 d . . .
H38A H -0.2797 0.4899 0.3004 0.089 Uiso 1 1 calc R . .
H38B H -0.3265 0.5588 0.2775 0.089 Uiso 1 1 calc R . .
H38C H -0.3349 0.5145 0.3295 0.089 Uiso 1 1 calc R . .
C39 C -0.2317(6) 0.5983(4) 0.4186(5) 0.060(2) Uani 1 1 d . . .
H39A H -0.2589 0.5744 0.4377 0.090 Uiso 1 1 calc R . .
H39B H -0.2770 0.6297 0.3826 0.090 Uiso 1 1 calc R . .
H39C H -0.1748 0.6199 0.4595 0.090 Uiso 1 1 calc R . .
C310 C -0.0002(5) 0.3079(4) 0.4151(4) 0.0382(19) Uani 1 1 d . . .
C311 C -0.0546(7) 0.2676(4) 0.4181(5) 0.059(2) Uani 1 1 d . . .
H311 H -0.1043 0.2829 0.4173 0.071 Uiso 1 1 calc R . .
C312 C -0.0374(7) 0.2028(4) 0.4223(5) 0.058(2) Uani 1 1 d . . .
H312 H -0.0760 0.1745 0.4248 0.069 Uiso 1 1 calc R . .
C313 C 0.0855(6) 0.2221(4) 0.4206(5) 0.055(2) Uani 1 1 d . . .
H313 H 0.1355 0.2070 0.4216 0.066 Uiso 1 1 calc R . .
C314 C 0.0706(6) 0.2856(4) 0.4170(4) 0.050(2) Uani 1 1 d . . .
H314 H 0.1100 0.3142 0.4157 0.060 Uiso 1 1 calc R . .
N41 N 0.1594(5) 0.0701(3) 0.5401(4) 0.0536(19) Uani 1 1 d . . .
N42 N -0.0425(6) 0.0622(3) 0.3146(4) 0.060(2) Uani 1 1 d . . .
C41 C 0.0695(5) -0.0061(4) 0.4272(4) 0.042(2) Uani 1 1 d . . .
C42 C 0.1405(7) -0.0392(4) 0.4951(5) 0.060(2) Uani 1 1 d . . .
C43 C 0.1499(7) -0.1054(4) 0.4978(6) 0.066(3) Uani 1 1 d . . .
H43 H 0.1960 -0.1266 0.5428 0.079 Uiso 1 1 calc R . .
C44 C 0.0896(8) -0.1387(5) 0.4327(7) 0.073(3) Uani 1 1 d . . .
H44 H 0.0977 -0.1831 0.4327 0.088 Uiso 1 1 calc R . .
C45 C 0.0205(9) -0.1105(5) 0.3698(7) 0.087(4) Uani 1 1 d . . .
H45 H -0.0216 -0.1353 0.3268 0.105 Uiso 1 1 calc R . .
C46 C 0.0092(7) -0.0429(4) 0.3666(5) 0.065(3) Uani 1 1 d . . .
C47 C 0.2081(8) 0.0071(5) 0.5553(6) 0.091(3) Uani 1 1 d . . .
H47A H 0.2632 0.0127 0.5567 0.109 Uiso 1 1 calc R . .
H47B H 0.2300 -0.0094 0.6039 0.109 Uiso 1 1 calc R . .
C48 C 0.2367(8) 0.1191(6) 0.5754(7) 0.108(4) Uani 1 1 d . . .
H48A H 0.2107 0.1611 0.5709 0.162 Uiso 1 1 calc R . .
H48B H 0.2649 0.1190 0.5504 0.162 Uiso 1 1 calc R . .
H48C H 0.2846 0.1089 0.6278 0.162 Uiso 1 1 calc R . .
C49 C 0.1197(8) 0.0758(6) 0.5779(6) 0.104(4) Uani 1 1 d . . .
H49A H 0.1695 0.0729 0.6314 0.156 Uiso 1 1 calc R . .
H49B H 0.0745 0.0415 0.5620 0.156 Uiso 1 1 calc R . .
H49C H 0.0879 0.1167 0.5660 0.156 Uiso 1 1 calc R . .
C410 C -0.0686(9) -0.0049(5) 0.3036(6) 0.096(4) Uani 1 1 d . . .
H41A H -0.0826 -0.0200 0.2569 0.115 Uiso 1 1 calc R . .
H41B H -0.1256 -0.0103 0.2997 0.115 Uiso 1 1 calc R . .
C411 C 0.0063(10) 0.0762(6) 0.2833(7) 0.104(4) Uani 1 1 d . . .
H41C H 0.0576 0.0459 0.3030 0.156 Uiso 1 1 calc R . .
H41D H 0.0315 0.1193 0.2970 0.156 Uiso 1 1 calc R . .
H41E H -0.0379 0.0725 0.2294 0.156 Uiso 1 1 calc R . .
C412 C -0.1271(8) 0.1029(5) 0.2739(6) 0.099(4) Uani 1 1 d . . .
H41F H -0.1704 0.0889 0.2223 0.148 Uiso 1 1 calc R . .
H41G H -0.1089 0.1470 0.2755 0.148 Uiso 1 1 calc R . .
H41H H -0.1577 0.0998 0.2969 0.148 Uiso 1 1 calc R . .
O51 O 0.3579(6) 0.2157(4) 0.4207(5) 0.129(3) Uiso 1 1 d D . .
O52 O 0.2602(6) 0.1680(4) 0.4287(5) 0.118(3) Uiso 1 1 d D . .
O53 O 0.2908(8) 0.2661(5) 0.4579(6) 0.192(5) Uiso 1 1 d D . .
N51 N 0.3030(4) 0.2167(3) 0.4357(3) 0.100(3) Uiso 1 1 d D . .
O61 O 0.2765(13) 0.7777(7) 0.6319(10) 0.296(9) Uiso 1 1 d D . .
O62 O 0.2538(13) 0.6861(7) 0.5822(11) 0.313(10) Uiso 1 1 d D . .
O63 O 0.3756(14) 0.7402(11) 0.6188(16) 0.51(2) Uiso 1 1 d D . .
N61 N 0.3019(9) 0.7348(6) 0.6110(6) 0.77(5) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C11 Pt1 N12 81.9(3) . . ?
C11 Pt1 N11 83.0(4) . . ?
N12 Pt1 N11 164.7(3) . . ?
C11 Pt1 N22 179.1(3) . . ?
N12 Pt1 N22 97.9(3) . . ?
N11 Pt1 N22 97.2(3) . . ?
C31 Pt2 C21 97.2(3) . . ?
C31 Pt2 N21 170.4(3) . . ?
C21 Pt2 N21 80.9(3) . . ?
C31 Pt2 N31 81.2(3) . . ?
C21 Pt2 N31 171.2(3) . . ?
N21 Pt2 N31 102.1(2) . . ?
C41 Pt3 N42 80.9(3) . . ?
C41 Pt3 N41 83.5(3) . . ?
N42 Pt3 N41 164.3(3) . . ?
C41 Pt3 N32 177.2(3) . . ?
N42 Pt3 N32 96.9(3) . . ?
N41 Pt3 N32 98.7(3) . . ?
C19 N11 C18 109.5(8) . . ?
C19 N11 C17 109.3(8) . . ?
C18 N11 C17 106.1(8) . . ?
C19 N11 Pt1 114.8(6) . . ?
C18 N11 Pt1 109.0(5) . . ?
C17 N11 Pt1 107.8(5) . . ?
C111 N12 C112 107.7(7) . . ?
C111 N12 C110 107.2(6) . . ?
C112 N12 C110 108.8(7) . . ?
C111 N12 Pt1 108.5(5) . . ?
C112 N12 Pt1 116.2(5) . . ?
C110 N12 Pt1 108.1(5) . . ?
C16 C11 C12 122.8(9) . . ?
C16 C11 Pt1 118.2(7) . . ?
C12 C11 Pt1 118.9(8) . . ?
C11 C12 C13 117.9(10) . . ?
C11 C12 C17 114.5(9) . . ?
C13 C12 C17 127.3(9) . . ?
C14 C13 C12 121.4(10) . . ?
C14 C13 H13 119.3 . . ?
C12 C13 H13 119.3 . . ?
C13 C14 C15 120.2(10) . . ?
C13 C14 H14 119.9 . . ?
C15 C14 H14 119.9 . . ?
C16 C15 C14 118.5(10) . . ?
C16 C15 H15 120.8 . . ?
C14 C15 H15 120.8 . . ?
C11 C16 C15 119.3(9) . . ?
C11 C16 C110 115.6(8) . . ?
C15 C16 C110 125.0(9) . . ?
C12 C17 N11 109.7(7) . . ?
C12 C17 H17A 109.7 . . ?
N11 C17 H17A 109.7 . . ?
C12 C17 H17B 109.7 . . ?
N11 C17 H17B 109.7 . . ?
H17A C17 H17B 108.2 . . ?
N11 C18 H18A 109.5 . . ?
N11 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
N11 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N11 C19 H19A 109.5 . . ?
N11 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
N11 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C16 C110 N12 107.9(7) . . ?
C16 C110 H11A 110.1 . . ?
N12 C110 H11A 110.1 . . ?
C16 C110 H11B 110.1 . . ?
N12 C110 H11B 110.1 . . ?
H11A C110 H11B 108.4 . . ?
N12 C111 H11C 109.5 . . ?
N12 C111 H11D 109.5 . . ?
H11C C111 H11D 109.5 . . ?
N12 C111 H11E 109.5 . . ?
H11C C111 H11E 109.5 . . ?
H11D C111 H11E 109.5 . . ?
N12 C112 H11F 109.5 . . ?
N12 C112 H11G 109.5 . . ?
H11F C112 H11G 109.5 . . ?
N12 C112 H11H 109.5 . . ?
H11F C112 H11H 109.5 . . ?
H11G C112 H11H 109.5 . . ?
C28 N21 C29 110.5(7) . . ?
C28 N21 C27 105.3(7) . . ?
C29 N21 C27 106.3(7) . . ?
C28 N21 Pt2 117.7(5) . . ?
C29 N21 Pt2 112.7(5) . . ?
C27 N21 Pt2 103.2(4) . . ?
C212 N22 C213 117.0(7) . . ?
C212 N22 Pt1 121.5(6) . . ?
C213 N22 Pt1 121.3(6) . . ?
C26 C21 C22 116.7(7) . . ?
C26 C21 Pt2 128.8(6) . . ?
C22 C21 Pt2 113.9(6) . . ?
C23 C22 C21 120.2(8) . . ?
C23 C22 C27 123.5(7) . . ?
C21 C22 C27 116.2(7) . . ?
C22 C23 C24 122.6(8) . . ?
C22 C23 H23 118.7 . . ?
C24 C23 H23 118.7 . . ?
C25 C24 C23 116.7(8) . . ?
C25 C24 C210 123.4(8) . . ?
C23 C24 C210 119.7(7) . . ?
C26 C25 C24 121.9(8) . . ?
C26 C25 H25 119.1 . . ?
C24 C25 H25 119.1 . . ?
C25 C26 C21 121.9(8) . . ?
C25 C26 H26 119.0 . . ?
C21 C26 H26 119.0 . . ?
C22 C27 N21 108.6(7) . . ?
C22 C27 H27A 110.0 . . ?
N21 C27 H27A 110.0 . . ?
C22 C27 H27B 110.0 . . ?
N21 C27 H27B 110.0 . . ?
H27A C27 H27B 108.4 . . ?
N21 C28 H28A 109.5 . . ?
N21 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
N21 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
N21 C29 H29A 109.5 . . ?
N21 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
N21 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C211 C210 C214 118.9(8) . . ?
C211 C210 C24 123.5(8) . . ?
C214 C210 C24 117.4(8) . . ?
C210 C211 C212 121.4(9) . . ?
C210 C211 H211 119.3 . . ?
C212 C211 H211 119.3 . . ?
N22 C212 C211 121.7(8) . . ?
N22 C212 H212 119.2 . . ?
C211 C212 H212 119.2 . . ?
N22 C213 C214 123.0(9) . . ?
N22 C213 H213 118.5 . . ?
C214 C213 H213 118.5 . . ?
C213 C214 C210 117.9(9) . . ?
C213 C214 H214 121.1 . . ?
C210 C214 H214 121.1 . . ?
C38 N31 C37 109.6(6) . . ?
C38 N31 C39 108.8(6) . . ?
C37 N31 C39 107.4(6) . . ?
C38 N31 Pt2 113.4(5) . . ?
C37 N31 Pt2 104.4(4) . . ?
C39 N31 Pt2 113.0(5) . . ?
C312 N32 C313 116.2(7) . . ?
C312 N32 Pt3 122.9(6) . . ?
C313 N32 Pt3 120.9(6) . . ?
C32 C31 C36 115.6(7) . . ?
C32 C31 Pt2 115.5(5) . . ?
C36 C31 Pt2 127.7(6) . . ?
C33 C32 C31 122.7(7) . . ?
C33 C32 C37 121.6(7) . . ?
C31 C32 C37 115.4(6) . . ?
C32 C33 C34 120.1(7) . . ?
C32 C33 H33 119.9 . . ?
C34 C33 H33 119.9 . . ?
C35 C34 C33 117.0(7) . . ?
C35 C34 C310 121.8(7) . . ?
C33 C34 C310 121.1(7) . . ?
C36 C35 C34 121.6(7) . . ?
C36 C35 H35 119.2 . . ?
C34 C35 H35 119.2 . . ?
C35 C36 C31 122.8(7) . . ?
C35 C36 H36 118.6 . . ?
C31 C36 H36 118.6 . . ?
N31 C37 C32 108.4(6) . . ?
N31 C37 H37A 110.0 . . ?
C32 C37 H37A 110.0 . . ?
N31 C37 H37B 110.0 . . ?
C32 C37 H37B 110.0 . . ?
H37A C37 H37B 108.4 . . ?
N31 C38 H38A 109.5 . . ?
N31 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
N31 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
N31 C39 H39A 109.5 . . ?
N31 C39 H39B 109.5 . . ?
H39A C39 H39B 109.5 . . ?
N31 C39 H39C 109.5 . . ?
H39A C39 H39C 109.5 . . ?
H39B C39 H39C 109.5 . . ?
C311 C310 C314 120.0(8) . . ?
C311 C310 C34 120.0(7) . . ?
C314 C310 C34 119.9(7) . . ?
C310 C311 C312 119.1(8) . . ?
C310 C311 H311 120.5 . . ?
C312 C311 H311 120.5 . . ?
N32 C312 C311 122.9(8) . . ?
N32 C312 H312 118.5 . . ?
C311 C312 H312 118.5 . . ?
C314 C313 N32 122.0(8) . . ?
C314 C313 H313 119.0 . . ?
N32 C313 H313 119.0 . . ?
C310 C314 C313 119.8(8) . . ?
C310 C314 H314 120.1 . . ?
C313 C314 H314 120.1 . . ?
C49 N41 C48 105.5(8) . . ?
C49 N41 C47 112.0(8) . . ?
C48 N41 C47 105.0(8) . . ?
C49 N41 Pt3 109.6(6) . . ?
C48 N41 Pt3 116.0(6) . . ?
C47 N41 Pt3 108.8(5) . . ?
C410 N42 C411 109.7(8) . . ?
C410 N42 C412 110.7(9) . . ?
C411 N42 C412 106.1(8) . . ?
C410 N42 Pt3 108.6(5) . . ?
C411 N42 Pt3 105.6(7) . . ?
C412 N42 Pt3 116.0(6) . . ?
C46 C41 C42 116.5(8) . . ?
C46 C41 Pt3 122.5(7) . . ?
C42 C41 Pt3 120.7(6) . . ?
C43 C42 C41 122.0(9) . . ?
C43 C42 C47 126.5(9) . . ?
C41 C42 C47 110.8(8) . . ?
C44 C43 C42 117.6(9) . . ?
C44 C43 H43 121.2 . . ?
C42 C43 H43 121.2 . . ?
C45 C44 C43 122.3(9) . . ?
C45 C44 H44 118.9 . . ?
C43 C44 H44 118.9 . . ?
C44 C45 C46 120.5(10) . . ?
C44 C45 H45 119.8 . . ?
C46 C45 H45 119.8 . . ?
C41 C46 C45 120.9(9) . . ?
C41 C46 C410 111.7(8) . . ?
C45 C46 C410 127.2(10) . . ?
C42 C47 N41 109.2(8) . . ?
C42 C47 H47A 109.8 . . ?
N41 C47 H47A 109.8 . . ?
C42 C47 H47B 109.8 . . ?
N41 C47 H47B 109.8 . . ?
H47A C47 H47B 108.3 . . ?
N41 C48 H48A 109.5 . . ?
N41 C48 H48B 109.5 . . ?
H48A C48 H48B 109.5 . . ?
N41 C48 H48C 109.5 . . ?
H48A C48 H48C 109.5 . . ?
H48B C48 H48C 109.5 . . ?
N41 C49 H49A 109.5 . . ?
N41 C49 H49B 109.5 . . ?
H49A C49 H49B 109.5 . . ?
N41 C49 H49C 109.5 . . ?
H49A C49 H49C 109.5 . . ?
H49B C49 H49C 109.5 . . ?
N42 C410 C46 109.9(9) . . ?
N42 C410 H41A 109.7 . . ?
C46 C410 H41A 109.7 . . ?
N42 C410 H41B 109.7 . . ?
C46 C410 H41B 109.7 . . ?
H41A C410 H41B 108.2 . . ?
N42 C411 H41C 109.5 . . ?
N42 C411 H41D 109.5 . . ?
H41C C411 H41D 109.5 . . ?
N42 C411 H41E 109.5 . . ?
H41C C411 H41E 109.5 . . ?
H41D C411 H41E 109.5 . . ?
N42 C412 H41F 109.5 . . ?
N42 C412 H41G 109.5 . . ?
H41F C412 H41G 109.5 . . ?
N42 C412 H41H 109.5 . . ?
H41F C412 H41H 109.5 . . ?
H41G C412 H41H 109.5 . . ?
O52 N51 O53 119.5(6) . . ?
O52 N51 O51 119.9(6) . . ?
O53 N51 O51 120.6(6) . . ?
O61 N61 O63 120.3(7) . . ?
O61 N61 O62 120.1(7) . . ?
O63 N61 O62 119.6(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C11 1.943(9) . ?
Pt1 N12 2.072(7) . ?
Pt1 N11 2.073(7) . ?
Pt1 N22 2.141(6) . ?
Pt2 C31 1.972(7) . ?
Pt2 C21 1.998(8) . ?
Pt2 N21 2.196(6) . ?
Pt2 N31 2.203(6) . ?
Pt3 C41 1.820(8) . ?
Pt3 N42 2.074(8) . ?
Pt3 N41 2.075(7) . ?
Pt3 N32 2.141(6) . ?
N11 C19 1.469(12) . ?
N11 C18 1.517(11) . ?
N11 C17 1.578(12) . ?
N12 C111 1.479(10) . ?
N12 C112 1.484(10) . ?
N12 C110 1.557(10) . ?
C11 C16 1.364(12) . ?
C11 C12 1.383(11) . ?
C12 C13 1.384(13) . ?
C12 C17 1.507(13) . ?
C13 C14 1.368(14) . ?
C13 H13 0.9500 . ?
C14 C15 1.413(15) . ?
C14 H14 0.9500 . ?
C15 C16 1.401(12) . ?
C15 H15 0.9500 . ?
C16 C110 1.488(12) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9800 . ?
C19 H19B 0.9800 . ?
C19 H19C 0.9800 . ?
C110 H11A 0.9900 . ?
C110 H11B 0.9900 . ?
C111 H11C 0.9800 . ?
C111 H11D 0.9800 . ?
C111 H11E 0.9800 . ?
C112 H11F 0.9800 . ?
C112 H11G 0.9800 . ?
C112 H11H 0.9800 . ?
N21 C28 1.477(11) . ?
N21 C29 1.492(10) . ?
N21 C27 1.515(10) . ?
N22 C212 1.350(10) . ?
N22 C213 1.353(10) . ?
C21 C26 1.379(10) . ?
C21 C22 1.427(10) . ?
C22 C23 1.360(11) . ?
C22 C27 1.495(11) . ?
C23 C24 1.392(11) . ?
C23 H23 0.9500 . ?
C24 C25 1.380(11) . ?
C24 C210 1.523(11) . ?
C25 C26 1.370(10) . ?
C25 H25 0.9500 . ?
C26 H26 0.9500 . ?
C27 H27A 0.9900 . ?
C27 H27B 0.9900 . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C210 C211 1.298(11) . ?
C210 C214 1.426(12) . ?
C211 C212 1.389(12) . ?
C211 H211 0.9500 . ?
C212 H212 0.9500 . ?
C213 C214 1.369(12) . ?
C213 H213 0.9500 . ?
C214 H214 0.9500 . ?
N31 C38 1.455(10) . ?
N31 C37 1.487(9) . ?
N31 C39 1.487(9) . ?
N32 C312 1.320(10) . ?
N32 C313 1.385(10) . ?
C31 C32 1.403(10) . ?
C31 C36 1.403(10) . ?
C32 C33 1.399(10) . ?
C32 C37 1.510(10) . ?
C33 C34 1.415(11) . ?
C33 H33 0.9500 . ?
C34 C35 1.404(10) . ?
C34 C310 1.530(11) . ?
C35 C36 1.373(10) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 H39A 0.9800 . ?
C39 H39B 0.9800 . ?
C39 H39C 0.9800 . ?
C310 C311 1.339(11) . ?
C310 C314 1.346(11) . ?
C311 C312 1.393(11) . ?
C311 H311 0.9500 . ?
C312 H312 0.9500 . ?
C313 C314 1.360(11) . ?
C313 H313 0.9500 . ?
C314 H314 0.9500 . ?
N41 C49 1.439(11) . ?
N41 C48 1.513(13) . ?
N41 C47 1.514(12) . ?
N42 C410 1.464(12) . ?
N42 C411 1.477(12) . ?
N42 C412 1.483(12) . ?
C41 C46 1.363(12) . ?
C41 C42 1.449(11) . ?
C42 C43 1.406(12) . ?
C42 C47 1.510(13) . ?
C43 C44 1.382(13) . ?
C43 H43 0.9500 . ?
C44 C45 1.334(14) . ?
C44 H44 0.9500 . ?
C45 C46 1.437(13) . ?
C45 H45 0.9500 . ?
C46 C410 1.487(13) . ?
C47 H47A 0.9900 . ?
C47 H47B 0.9900 . ?
C48 H48A 0.9800 . ?
C48 H48B 0.9800 . ?
C48 H48C 0.9800 . ?
C49 H49A 0.9800 . ?
C49 H49B 0.9800 . ?
C49 H49C 0.9800 . ?
C410 H41A 0.9900 . ?
C410 H41B 0.9900 . ?
C411 H41C 0.9800 . ?
C411 H41D 0.9800 . ?
C411 H41E 0.9800 . ?
C412 H41F 0.9800 . ?
C412 H41G 0.9800 . ?
C412 H41H 0.9800 . ?
O51 N51 1.242(7) . ?
O52 N51 1.239(7) . ?
O53 N51 1.240(8) . ?
O61 N61 1.241(8) . ?
O62 N61 1.242(8) . ?
O63 N61 1.242(8) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C11 Pt1 N11 C19 -142.3(7) . . . . ?
N12 Pt1 N11 C19 -134.0(11) . . . . ?
N22 Pt1 N11 C19 36.9(7) . . . . ?
C11 Pt1 N11 C18 94.5(7) . . . . ?
N12 Pt1 N11 C18 102.9(12) . . . . ?
N22 Pt1 N11 C18 -86.3(7) . . . . ?
C11 Pt1 N11 C17 -20.2(6) . . . . ?
N12 Pt1 N11 C17 -11.9(14) . . . . ?
N22 Pt1 N11 C17 158.9(6) . . . . ?
C11 Pt1 N12 C111 94.1(5) . . . . ?
N11 Pt1 N12 C111 85.7(12) . . . . ?
N22 Pt1 N12 C111 -85.1(5) . . . . ?
C11 Pt1 N12 C112 -144.5(7) . . . . ?
N11 Pt1 N12 C112 -152.8(10) . . . . ?
N22 Pt1 N12 C112 36.4(7) . . . . ?
C11 Pt1 N12 C110 -21.8(5) . . . . ?
N11 Pt1 N12 C110 -30.2(13) . . . . ?
N22 Pt1 N12 C110 159.0(5) . . . . ?
N12 Pt1 C11 C16 9.3(7) . . . . ?
N11 Pt1 C11 C16 -172.9(7) . . . . ?
N12 Pt1 C11 C12 -166.7(7) . . . . ?
N11 Pt1 C11 C12 11.1(7) . . . . ?
C16 C11 C12 C13 -0.1(13) . . . . ?
Pt1 C11 C12 C13 175.8(7) . . . . ?
C16 C11 C12 C17 -173.4(8) . . . . ?
Pt1 C11 C12 C17 2.4(11) . . . . ?
C11 C12 C13 C14 0.3(14) . . . . ?
C17 C12 C13 C14 172.7(10) . . . . ?
C12 C13 C14 C15 -1.1(16) . . . . ?
C13 C14 C15 C16 1.5(15) . . . . ?
C12 C11 C16 C15 0.5(13) . . . . ?
Pt1 C11 C16 C15 -175.3(7) . . . . ?
C12 C11 C16 C110 -177.0(8) . . . . ?
Pt1 C11 C16 C110 7.1(10) . . . . ?
C14 C15 C16 C11 -1.2(14) . . . . ?
C14 C15 C16 C110 176.1(9) . . . . ?
C11 C12 C17 N11 -19.5(11) . . . . ?
C13 C12 C17 N11 167.8(9) . . . . ?
C19 N11 C17 C12 151.7(8) . . . . ?
C18 N11 C17 C12 -90.4(9) . . . . ?
Pt1 N11 C17 C12 26.3(9) . . . . ?
C11 C16 C110 N12 -25.0(10) . . . . ?
C15 C16 C110 N12 157.5(8) . . . . ?
C111 N12 C110 C16 -86.6(8) . . . . ?
C112 N12 C110 C16 157.2(7) . . . . ?
Pt1 N12 C110 C16 30.2(7) . . . . ?
C21 Pt2 N21 C28 148.5(6) . . . . ?
N31 Pt2 N21 C28 -39.9(6) . . . . ?
C21 Pt2 N21 C29 -81.1(6) . . . . ?
N31 Pt2 N21 C29 90.5(6) . . . . ?
C21 Pt2 N21 C27 33.2(5) . . . . ?
N31 Pt2 N21 C27 -155.3(5) . . . . ?
N12 Pt1 N22 C212 84.8(7) . . . . ?
N11 Pt1 N22 C212 -92.7(7) . . . . ?
N12 Pt1 N22 C213 -91.4(7) . . . . ?
N11 Pt1 N22 C213 91.1(7) . . . . ?
C31 Pt2 C21 C26 -36.2(7) . . . . ?
N21 Pt2 C21 C26 153.3(7) . . . . ?
C31 Pt2 C21 C22 153.3(5) . . . . ?
N21 Pt2 C21 C22 -17.2(5) . . . . ?
C26 C21 C22 C23 1.4(10) . . . . ?
Pt2 C21 C22 C23 173.2(6) . . . . ?
C26 C21 C22 C27 -175.4(7) . . . . ?
Pt2 C21 C22 C27 -3.6(8) . . . . ?
C21 C22 C23 C24 -2.6(11) . . . . ?
C27 C22 C23 C24 174.0(7) . . . . ?
C22 C23 C24 C25 1.5(12) . . . . ?
C22 C23 C24 C210 -174.0(7) . . . . ?
C23 C24 C25 C26 0.7(12) . . . . ?
C210 C24 C25 C26 176.0(7) . . . . ?
C24 C25 C26 C21 -1.8(12) . . . . ?
C22 C21 C26 C25 0.7(11) . . . . ?
Pt2 C21 C26 C25 -169.7(6) . . . . ?
C23 C22 C27 N21 -143.4(7) . . . . ?
C21 C22 C27 N21 33.3(9) . . . . ?
C28 N21 C27 C22 -166.6(6) . . . . ?
C29 N21 C27 C22 76.1(8) . . . . ?
Pt2 N21 C27 C22 -42.7(7) . . . . ?
C25 C24 C210 C211 155.3(9) . . . . ?
C23 C24 C210 C211 -29.4(13) . . . . ?
C25 C24 C210 C214 -29.4(12) . . . . ?
C23 C24 C210 C214 145.8(8) . . . . ?
C214 C210 C211 C212 -1.7(14) . . . . ?
C24 C210 C211 C212 173.5(8) . . . . ?
C213 N22 C212 C211 -1.9(13) . . . . ?
Pt1 N22 C212 C211 -178.2(7) . . . . ?
C210 C211 C212 N22 1.9(15) . . . . ?
C212 N22 C213 C214 1.8(13) . . . . ?
Pt1 N22 C213 C214 178.2(7) . . . . ?
N22 C213 C214 C210 -1.6(14) . . . . ?
C211 C210 C214 C213 1.5(14) . . . . ?
C24 C210 C214 C213 -173.9(8) . . . . ?
C31 Pt2 N31 C38 -91.5(6) . . . . ?
N21 Pt2 N31 C38 79.4(6) . . . . ?
C31 Pt2 N31 C37 27.7(5) . . . . ?
N21 Pt2 N31 C37 -161.5(4) . . . . ?
C31 Pt2 N31 C39 144.1(6) . . . . ?
N21 Pt2 N31 C39 -45.1(6) . . . . ?
N42 Pt3 N32 C312 84.3(8) . . . . ?
N41 Pt3 N32 C312 -96.4(8) . . . . ?
N42 Pt3 N32 C313 -95.6(7) . . . . ?
N41 Pt3 N32 C313 83.6(7) . . . . ?
C21 Pt2 C31 C32 162.4(6) . . . . ?
N31 Pt2 C31 C32 -8.8(5) . . . . ?
C21 Pt2 C31 C36 -31.0(7) . . . . ?
N31 Pt2 C31 C36 157.8(7) . . . . ?
C36 C31 C32 C33 4.8(11) . . . . ?
Pt2 C31 C32 C33 173.1(6) . . . . ?
C36 C31 C32 C37 179.0(7) . . . . ?
Pt2 C31 C32 C37 -12.8(9) . . . . ?
C31 C32 C33 C34 -4.0(12) . . . . ?
C37 C32 C33 C34 -177.8(7) . . . . ?
C32 C33 C34 C35 0.8(11) . . . . ?
C32 C33 C34 C310 -176.7(7) . . . . ?
C33 C34 C35 C36 1.2(12) . . . . ?
C310 C34 C35 C36 178.7(7) . . . . ?
C34 C35 C36 C31 -0.2(12) . . . . ?
C32 C31 C36 C35 -2.8(11) . . . . ?
Pt2 C31 C36 C35 -169.3(6) . . . . ?
C38 N31 C37 C32 81.6(7) . . . . ?
C39 N31 C37 C32 -160.4(6) . . . . ?
Pt2 N31 C37 C32 -40.1(7) . . . . ?
C33 C32 C37 N31 -148.4(7) . . . . ?
C31 C32 C37 N31 37.4(9) . . . . ?
C35 C34 C310 C311 -153.7(8) . . . . ?
C33 C34 C310 C311 23.7(12) . . . . ?
C35 C34 C310 C314 22.6(11) . . . . ?
C33 C34 C310 C314 -160.0(8) . . . . ?
C314 C310 C311 C312 -0.6(13) . . . . ?
C34 C310 C311 C312 175.7(7) . . . . ?
C313 N32 C312 C311 1.3(13) . . . . ?
Pt3 N32 C312 C311 -178.7(7) . . . . ?
C310 C311 C312 N32 -0.6(14) . . . . ?
C312 N32 C313 C314 -0.8(13) . . . . ?
Pt3 N32 C313 C314 179.2(6) . . . . ?
C311 C310 C314 C313 1.1(13) . . . . ?
C34 C310 C314 C313 -175.3(7) . . . . ?
N32 C313 C314 C310 -0.3(13) . . . . ?
C41 Pt3 N41 C49 -105.3(7) . . . . ?
N42 Pt3 N41 C49 -109.8(11) . . . . ?
N32 Pt3 N41 C49 72.9(7) . . . . ?
C41 Pt3 N41 C48 135.5(7) . . . . ?
N42 Pt3 N41 C48 131.0(11) . . . . ?
N32 Pt3 N41 C48 -46.3(7) . . . . ?
C41 Pt3 N41 C47 17.4(6) . . . . ?
N42 Pt3 N41 C47 12.9(14) . . . . ?
N32 Pt3 N41 C47 -164.4(6) . . . . ?
C41 Pt3 N42 C410 21.0(7) . . . . ?
N41 Pt3 N42 C410 25.5(14) . . . . ?
N32 Pt3 N42 C410 -157.2(7) . . . . ?
C41 Pt3 N42 C411 -96.6(6) . . . . ?
N41 Pt3 N42 C411 -92.0(12) . . . . ?
N32 Pt3 N42 C411 85.2(6) . . . . ?
C41 Pt3 N42 C412 146.3(8) . . . . ?
N41 Pt3 N42 C412 150.9(10) . . . . ?
N32 Pt3 N42 C412 -31.9(8) . . . . ?
N42 Pt3 C41 C46 -11.3(7) . . . . ?
N41 Pt3 C41 C46 169.9(7) . . . . ?
N42 Pt3 C41 C42 176.0(7) . . . . ?
N41 Pt3 C41 C42 -2.8(6) . . . . ?
C46 C41 C42 C43 3.0(12) . . . . ?
Pt3 C41 C42 C43 176.1(6) . . . . ?
C46 C41 C42 C47 174.1(8) . . . . ?
Pt3 C41 C42 C47 -12.7(10) . . . . ?
C41 C42 C43 C44 1.1(13) . . . . ?
C47 C42 C43 C44 -168.6(10) . . . . ?
C42 C43 C44 C45 -4.4(15) . . . . ?
C43 C44 C45 C46 3.5(17) . . . . ?
C42 C41 C46 C45 -4.0(13) . . . . ?
Pt3 C41 C46 C45 -177.0(7) . . . . ?
C42 C41 C46 C410 171.6(8) . . . . ?
Pt3 C41 C46 C410 -1.4(11) . . . . ?
C44 C45 C46 C41 1.0(16) . . . . ?
C44 C45 C46 C410 -173.8(11) . . . . ?
C43 C42 C47 N41 -163.2(8) . . . . ?
C41 C42 C47 N41 26.2(11) . . . . ?
C49 N41 C47 C42 93.7(10) . . . . ?
C48 N41 C47 C42 -152.4(9) . . . . ?
Pt3 N41 C47 C42 -27.6(10) . . . . ?
C411 N42 C410 C46 88.3(11) . . . . ?
C412 N42 C410 C46 -155.1(9) . . . . ?
Pt3 N42 C410 C46 -26.6(10) . . . . ?
C41 C46 C410 N42 19.5(12) . . . . ?
C45 C46 C410 N42 -165.2(9) . . . . ?
