#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/07/4310754.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4310754
loop_
_publ_author_name
'E. Effendy'
'Fabio Marchetti'
'Claudio Pettinari'
'Riccardo Pettinari'
'Massimo Ricciutelli'
'Brian W. Skelton'
'Allan H. White'
_publ_contact_author_address
;
   Department of Chemistry
   University of Western Australia
   35 Stirling Hwy
   Crawley
   Western Australia 6009
   Australia
;
_publ_contact_author_email       bws@crystal.uwa.edu.au
_publ_contact_author_fax         (+61)_08_9380_1118
_publ_contact_author_name        'B. W. Skelton'
_publ_contact_author_phone       (+61)_08-9380_3481
_publ_section_title
;
 (Bis(1,2,4-triazol-1-yl)methane)silver(I) Phosphino Complexes: Structures
 and Spectroscopic Properties of Mixed-Ligand Coordination Polymers
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2157
_journal_page_last               2165
_journal_paper_doi               10.1021/ic0353413
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety         'C31 H33 Ag2 N13 O3 P1, N O3'
_chemical_formula_sum            'C31 H33 Ag2 N14 O6 P'
_chemical_formula_weight         944.41
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_cell_angle_alpha                76.802(2)
_cell_angle_beta                 77.954(2)
_cell_angle_gamma                62.5980(10)
_cell_formula_units_Z            2
_cell_length_a                   10.5051(7)
_cell_length_b                   11.3410(8)
_cell_length_c                   17.5390(10)
_cell_measurement_reflns_used    8192
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      32.2
_cell_measurement_theta_min      2.3
_cell_volume                     1793.1(2)
_computing_cell_refinement       'Siemens SAINT (Siemens, 1995)'
_computing_data_collection       'Siemens SMART (Siemens, 1995)'
_computing_data_reduction        xtal
_computing_molecular_graphics    xtal
_computing_publication_material  'xtal BONDLA CIFIO'
_computing_structure_refinement  'xtal CRYLSQ'
_computing_structure_solution    xtal
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 1.0
_diffrn_measured_fraction_theta_max .98
_diffrn_measurement_device_type
;
Bruker SMART CCD diffractometer
;
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_detector       'CCD area detector'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .024
_diffrn_reflns_av_sigmaI/netI    .098
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            31385
_diffrn_reflns_theta_full        36.5
_diffrn_reflns_theta_max         37.0
_diffrn_reflns_theta_min         2.05
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.202
_exptl_absorpt_correction_T_max  .863
_exptl_absorpt_correction_T_min  .722
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
 SADABS; Sheldrick, 1996
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.749
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       pyramid
_exptl_crystal_F_000             948
_exptl_crystal_size_max          .25
_exptl_crystal_size_mid          .2
_exptl_crystal_size_min          .16
_refine_diff_density_max         2.436
_refine_diff_density_min         -1.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_all   .938
_refine_ls_goodness_of_fit_ref   1.004
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     619
_refine_ls_number_reflns         11922
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          .07
_refine_ls_R_factor_gt           .038
_refine_ls_shift/su_max          .001
_refine_ls_shift/su_mean         .00007
_refine_ls_structure_factor_coef F
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         .047
_refine_ls_wR_factor_ref         .041
_reflns_d_resolution_high        .583
_reflns_d_resolution_low         9.931
_reflns_Friedel_coverage         0
_reflns_limit_h_max              17
_reflns_limit_h_min              0
_reflns_limit_k_max              19
_reflns_limit_k_min              -16
_reflns_limit_l_max              30
_reflns_limit_l_min              -28
_reflns_number_gt                11922
_reflns_number_total             17806
_reflns_threshold_expression     'F    > 4.00 sig(F   )'
_cod_data_source_file            ic0353413si20031119_095931_5.cif
_cod_data_source_block           nootz
_cod_original_sg_symbol_Hall     -p_1
_cod_original_formula_sum        'C31 H33 Ag2 N14 O6 P1'
_cod_database_code               4310754
loop_
_symmetry_equiv_pos_as_xyz
+x,+y,+z
-x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_calc_attached_atom
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 .743578(18) .365842(16) .222694(9) .02510(14) Uani ? ? 1.00000 ? ?
Ag2 -.308575(18) .959224(18) .401136(11) .03053(15) Uani ? ? 1.00000 ? ?
C1 .2887(2) .6895(2) .42358(12) .0222(16) Uani ? ? 1.00000 ? ?
N111 .39297(18) .65646(16) .35462(10) .0201(13) Uani ? ? 1.00000 ? ?
N112 .3993(2) .75060(17) .29201(11) .0241(15) Uani ? ? 1.00000 ? ?
C113 .5070(2) .6770(2) .24404(13) .0234(17) Uani ? ? 1.00000 ? ?
N114 .56850(19) .54352(17) .27199(10) .0222(14) Uani ? ? 1.00000 ? ?
C115 .4933(2) .5347(2) .34219(12) .0217(16) Uani ? ? 1.00000 ? ?
N121 .14533(18) .72702(17) .40474(10) .0211(14) Uani ? ? 1.00000 ? ?
N122 .1209(2) .64686(19) .36823(12) .0275(16) Uani ? ? 1.00000 ? ?
C123 -.0195(2) .7088(2) .36732(13) .0261(18) Uani ? ? 1.00000 ? ?
N124 -.0857(2) .82189(19) .40114(11) .0262(16) Uani ? ? 1.00000 ? ?
C125 .0219(2) .8301(2) .42419(13) .0252(17) Uani ? ? 1.00000 ? ?
C2 1.1270(3) .3575(2) .39336(15) .032(2) Uani ? ? 1.00000 ? ?
N211 1.0719(2) .39176(18) .31801(11) .0236(14) Uani ? ? 1.00000 ? ?
N212 1.1614(2) .3688(2) .24901(12) .035(2) Uani ? ? 1.00000 ? ?
C213 1.0694(3) .4054(3) .19820(14) .031(2) Uani ? ? 1.00000 ? ?
N214 .9287(2) .4509(2) .22848(12) .0304(18) Uani ? ? 1.00000 ? ?
C215 .9356(2) .4414(2) .30401(14) .0267(19) Uani ? ? 1.00000 ? ?
N221 1.2463(2) .22511(18) .39893(11) .0244(15) Uani ? ? 1.00000 ? ?
N222 1.2314(2) .1126(2) .39689(13) .0314(18) Uani ? ? 1.00000 ? ?
C223 1.3649(3) .0184(2) .39892(14) .0279(19) Uani ? ? 1.00000 ? ?
N224 1.4627(2) .06371(19) .40198(11) .0254(15) Uani ? ? 1.00000 ? ?
C225 1.3834(3) .1945(2) .40187(13) .0259(18) Uani ? ? 1.00000 ? ?
P .84116(5) .21081(5) .13041(3) .0170(4) Uani ? ? 1.00000 ? ?
C11 1.0366(2) .15340(19) .10975(11) .0190(15) Uani ? ? 1.00000 ? ?
C12 1.1226(2) .0960(2) .17226(13) .0227(16) Uani ? ? 1.00000 ? ?
C121 1.0622(3) .0699(3) .25658(14) .031(2) Uani ? ? 1.00000 ? ?
C13 1.2702(2) .0620(2) .15525(15) .029(2) Uani ? ? 1.00000 ? ?
C14 1.3325(3) .0836(2) .07845(16) .033(2) Uani ? ? 1.00000 ? ?
C15 1.2491(3) .1382(2) .01689(15) .031(2) Uani ? ? 1.00000 ? ?
C16 1.1017(2) .1729(2) .03259(13) .0234(17) Uani ? ? 1.00000 ? ?
C21 .8160(2) .05639(19) .15917(11) .0185(15) Uani ? ? 1.00000 ? ?
C22 .6787(2) .0622(2) .19065(11) .0213(16) Uani ? ? 1.00000 ? ?
C221 .5464(2) .1934(2) .19795(15) .028(2) Uani ? ? 1.00000 ? ?
C23 .6663(3) -.0585(2) .21427(13) .0256(19) Uani ? ? 1.00000 ? ?
C24 .7841(3) -.1820(2) .20624(13) .028(2) Uani ? ? 1.00000 ? ?
C25 .9184(3) -.1870(2) .17371(13) .0260(18) Uani ? ? 1.00000 ? ?
C26 .9335(2) -.0679(2) .15105(12) .0220(16) Uani ? ? 1.00000 ? ?
C31 .7723(2) .2824(2) .03443(11) .0194(15) Uani ? ? 1.00000 ? ?
C32 .7478(2) .4149(2) -.00046(12) .0236(17) Uani ? ? 1.00000 ? ?
C321 .7844(4) .5027(3) .03571(17) .037(3) Uani ? ? 1.00000 ? ?
C33 .6894(3) .4657(2) -.07172(14) .031(2) Uani ? ? 1.00000 ? ?
C34 .6556(3) .3908(3) -.10863(15) .036(2) Uani ? ? 1.00000 ? ?
C35 .6800(3) .2602(3) -.07489(14) .034(2) Uani ? ? 1.00000 ? ?
C36 .7383(2) .2068(2) -.00352(13) .0256(18) Uani ? ? 1.00000 ? ?
N1 .7602(2) .20139(18) .40165(11) .0256(15) Uani ? ? 1.00000 ? ?
O11 .6935(2) .20459(19) .35007(10) .0365(17) Uani ? ? 1.00000 ? ?
O12 .7940(2) .10314(16) .45733(10) .0325(15) Uani ? ? 1.00000 ? ?
O13 .7920(2) .2943(2) .40051(13) .047(2) Uani ? ? 1.00000 ? ?
N2 .6588(2) .64323(19) .44872(10) .0240(16) Uani ? ? 1.00000 ? ?
O21 .6567(2) .70826(19) .38089(10) .0349(17) Uani ? ? 1.00000 ? ?
O22 .5420(2) .6602(2) .49227(10) .0366(18) Uani ? ? 1.00000 ? ?
O23 .7762(2) .56157(18) .47360(10) .0345(16) Uani ? ? 1.00000 ? ?
H1a .288(3) .765(3) .4410(16) .029(7) Uiso ? ? 1.00000 ? ?
H1b .314(3) .621(3) .4611(16) .025(7) Uiso ? ? 1.00000 ? ?
H113 .537(3) .712(3) .2004(17) .033(7) Uiso ? ? 1.00000 ? ?
H115 .507(3) .455(3) .3812(15) .023(6) Uiso ? ? 1.00000 ? ?
H123 -.070(3) .677(3) .3471(17) .033(7) Uiso ? ? 1.00000 ? ?
H125 .020(3) .895(3) .4446(17) .035(8) Uiso ? ? 1.00000 ? ?
H2a 1.048(4) .362(3) .4291(19) .044(9) Uiso ? ? 1.00000 ? ?
H2b 1.167(3) .417(3) .4008(17) .038(8) Uiso ? ? 1.00000 ? ?
H213 1.096(3) .403(3) .1457(17) .030(7) Uiso ? ? 1.00000 ? ?
H215 .864(4) .464(3) .339(2) .052(10) Uiso ? ? 1.00000 ? ?
H223 1.394(3) -.075(3) .3966(19) .049(9) Uiso ? ? 1.00000 ? ?
H225 1.413(3) .260(3) .4002(17) .035(8) Uiso ? ? 1.00000 ? ?
H121a .997(5) .047(4) .261(2) .072(13) Uiso ? ? 1.00000 ? ?
H121b 1.125(4) .028(4) .290(2) .069(12) Uiso ? ? 1.00000 ? ?
H121c 1.013(5) .144(4) .279(2) .075(13) Uiso ? ? 1.00000 ? ?
H13 1.326(3) .027(3) .1973(16) .028(7) Uiso ? ? 1.00000 ? ?
H14 1.429(4) .070(4) .067(2) .067(11) Uiso ? ? 1.00000 ? ?
H15 1.276(3) .155(3) -.0359(18) .040(8) Uiso ? ? 1.00000 ? ?
H16 1.047(3) .211(2) -.0072(15) .020(6) Uiso ? ? 1.00000 ? ?
H221a .469(3) .176(3) .2172(18) .043(8) Uiso ? ? 1.00000 ? ?
H221b .552(4) .246(3) .228(2) .048(9) Uiso ? ? 1.00000 ? ?
H221c .528(3) .252(3) .1494(19) .042(8) Uiso ? ? 1.00000 ? ?
H23 .572(3) -.054(3) .2386(15) .026(7) Uiso ? ? 1.00000 ? ?
H24 .773(3) -.263(2) .2231(13) .015(5) Uiso ? ? 1.00000 ? ?
H25 1.001(3) -.273(3) .1688(16) .029(7) Uiso ? ? 1.00000 ? ?
H26 1.019(3) -.071(2) .1313(14) .018(6) Uiso ? ? 1.00000 ? ?
H321a .734(4) .522(4) .081(2) .065(12) Uiso ? ? 1.00000 ? ?
H321b .877(5) .459(4) .049(2) .078(13) Uiso ? ? 1.00000 ? ?
H321c .761(3) .589(3) .0030(18) .040(8) Uiso ? ? 1.00000 ? ?
H33 .671(3) .551(3) -.0920(18) .039(8) Uiso ? ? 1.00000 ? ?
H34 .618(4) .424(4) -.156(2) .061(11) Uiso ? ? 1.00000 ? ?
H35 .659(3) .205(3) -.0996(17) .036(8) Uiso ? ? 1.00000 ? ?
H36 .758(3) .115(3) .0175(15) .025(6) Uiso ? ? 1.00000 ? ?
loop_
_atom_sites_solution_primary
?
loop_
_atom_type_symbol
_atom_type_description
_atom_type_oxidation_number
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C ? 0 62 .002 .002 'Int Tables Vol IV Tables 2.2B and 2.3.1'
H ? 0 66 0 0 'Int Tables Vol IV Tables 2.2B and 2.3.1'
Ag ? 0 4 -1.085 1.101 'Int Tables Vol IV Tables 2.2B and 2.3.1'
N ? 0 28 .004 .003 'Int Tables Vol IV Tables 2.2B and 2.3.1'
O ? 0 12 .008 .006 'Int Tables Vol IV Tables 2.2B and 2.3.1'
P ? 0 2 .09 .095 'Int Tables Vol IV Tables 2.2B and 2.3.1'
loop_
_diffrn_attenuator_code
_diffrn_attenuator_scale
? ?
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
? ? ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N114 Ag1 N214 . . . 90.09(8) ?
N114 Ag1 P . . . 151.97(6) ?
N114 Ag1 O11 . . . 90.11(6) ?
N214 Ag1 P . . . 109.23(5) ?
N214 Ag1 O11 . . . 116.75(7) ?
P Ag1 O11 . . . 98.49(5) ?
N124 Ag2 N224 . . '1 365' 169.21(9) ?
N124 Ag2 O11 . . '1 465' 104.08(8) ?
N124 Ag2 O12 . . '1 465' 79.23(8) ?
N224 Ag2 O11 '1 365' . '1 465' 86.25(7) ?
N224 Ag2 O12 '1 365' . '1 465' 110.69(7) ?
O11 Ag2 O12 '1 465' . '1 465' 46.54(5) ?
N111 C1 N121 . . . 110.10(19) ?
N111 C1 H1a . . . 109.1(16) ?
N111 C1 H1b . . . 108.9(16) ?
N121 C1 H1a . . . 108.6(16) ?
N121 C1 H1b . . . 111(2) ?
H1a C1 H1b . . . 109(3) ?
C1 N111 N112 . . . 122.70(15) ?
C1 N111 C115 . . . 126.55(17) ?
N112 N111 C115 . . . 110.74(16) ?
N111 N112 C113 . . . 101.97(15) ?
N112 C113 N114 . . . 114.60(18) ?
N112 C113 H113 . . . 121.7(18) ?
N114 C113 H113 . . . 123.6(17) ?
Ag1 N114 C113 . . . 133.72(14) ?
Ag1 N114 C115 . . . 122.97(13) ?
C113 N114 C115 . . . 103.27(16) ?
N111 C115 N114 . . . 109.42(17) ?
N111 C115 H115 . . . 122.5(14) ?
N114 C115 H115 . . . 128.1(14) ?
C1 N121 N122 . . . 120.92(16) ?
C1 N121 C125 . . . 128.5(2) ?
N122 N121 C125 . . . 110.4(2) ?
N121 N122 C123 . . . 102.39(19) ?
N122 C123 N124 . . . 114.3(3) ?
N122 C123 H123 . . . 123.4(15) ?
N124 C123 H123 . . . 122.3(15) ?
Ag2 N124 C123 . . . 125.2(2) ?
Ag2 N124 C125 . . . 130.79(16) ?
C123 N124 C125 . . . 103.64(19) ?
N121 C125 N124 . . . 109.3(2) ?
N121 C125 H125 . . . 121.4(19) ?
N124 C125 H125 . . . 129.0(18) ?
N211 C2 N221 . . . 109.8(2) ?
N211 C2 H2a . . . 103(2) ?
N211 C2 H2b . . . 114.0(16) ?
N221 C2 H2a . . . 113.2(18) ?
N221 C2 H2b . . . 104.5(15) ?
H2a C2 H2b . . . 113(3) ?
C2 N211 N212 . . . 122.0(2) ?
C2 N211 C215 . . . 128.4(2) ?
N212 N211 C215 . . . 109.6(2) ?
N211 N212 C213 . . . 101.7(2) ?
N212 C213 N214 . . . 115.8(2) ?
N212 C213 H213 . . . 124(2) ?
N214 C213 H213 . . . 121(2) ?
Ag1 N214 C213 . . . 129.4(2) ?
Ag1 N214 C215 . . . 106.05(18) ?
C213 N214 C215 . . . 102.1(2) ?
N211 C215 N214 . . . 110.8(2) ?
N211 C215 H215 . . . 124(3) ?
N214 C215 H215 . . . 125(3) ?
C2 N221 N222 . . . 122.5(2) ?
C2 N221 C225 . . . 127.0(3) ?
N222 N221 C225 . . . 110.36(18) ?
N221 N222 C223 . . . 102.3(2) ?
N222 C223 N224 . . . 114.3(2) ?
N222 C223 H223 . . . 125(2) ?
N224 C223 H223 . . . 121(2) ?
C223 N224 C225 . . . 103.5(2) ?
C223 N224 Ag2 . . '1 745' 130.33(14) ?
C225 N224 Ag2 . . '1 745' 126.1(2) ?
N221 C225 N224 . . . 109.6(3) ?
N221 C225 H225 . . . 121.7(16) ?
N224 C225 H225 . . . 128.6(16) ?
Ag1 P C11 . . . 109.85(8) ?
Ag1 P C21 . . . 117.49(6) ?
Ag1 P C31 . . . 114.02(6) ?
C11 P C21 . . . 104.79(9) ?
C11 P C31 . . . 105.66(9) ?
C21 P C31 . . . 104.01(11) ?
P C11 C12 . . . 120.01(14) ?
P C11 C16 . . . 120.64(16) ?
C12 C11 C16 . . . 119.2(2) ?
C11 C12 C121 . . . 122.7(2) ?
C11 C12 C13 . . . 118.7(2) ?
C121 C12 C13 . . . 118.5(2) ?
C12 C121 H121a . . . 113(3) ?
C12 C121 H121b . . . 116(3) ?
C12 C121 H121c . . . 114(3) ?
H121a C121 H121b . . . 118(4) ?
H121a C121 H121c . . . 98(4) ?
H121b C121 H121c . . . 95(4) ?
C12 C13 C14 . . . 121.2(2) ?
C12 C13 H13 . . . 118.5(17) ?
C14 C13 H13 . . . 120.3(17) ?
C13 C14 C15 . . . 120.3(2) ?
C13 C14 H14 . . . 122(2) ?
C15 C14 H14 . . . 118(2) ?
C14 C15 C16 . . . 119.4(2) ?
C14 C15 H15 . . . 129(2) ?
C16 C15 H15 . . . 111(2) ?
C11 C16 C15 . . . 121.1(2) ?
C11 C16 H16 . . . 119.7(16) ?
C15 C16 H16 . . . 119.2(17) ?
P C21 C22 . . . 120.30(14) ?
P C21 C26 . . . 120.03(18) ?
C22 C21 C26 . . . 119.7(2) ?
C21 C22 C221 . . . 122.3(2) ?
C21 C22 C23 . . . 118.10(17) ?
C221 C22 C23 . . . 119.6(2) ?
C22 C221 H221a . . . 108.9(18) ?
C22 C221 H221b . . . 115.3(19) ?
C22 C221 H221c . . . 113.1(17) ?
H221a C221 H221b . . . 110(3) ?
H221a C221 H221c . . . 108(3) ?
H221b C221 H221c . . . 101(3) ?
C22 C23 C24 . . . 121.8(2) ?
C22 C23 H23 . . . 117.8(16) ?
C24 C23 H23 . . . 120.3(16) ?
C23 C24 C25 . . . 119.9(3) ?
C23 C24 H24 . . . 120.3(13) ?
C25 C24 H24 . . . 119.9(13) ?
C24 C25 C26 . . . 119.17(18) ?
C24 C25 H25 . . . 120(2) ?
C26 C25 H25 . . . 121(2) ?
C21 C26 C25 . . . 121.4(2) ?
C21 C26 H26 . . . 119.1(17) ?
C25 C26 H26 . . . 119.5(16) ?
P C31 C32 . . . 121.0(2) ?
P C31 C36 . . . 119.67(15) ?
C32 C31 C36 . . . 119.3(2) ?
C31 C32 C321 . . . 122.7(2) ?
C31 C32 C33 . . . 118.4(3) ?
C321 C32 C33 . . . 118.9(2) ?
C32 C321 H321a . . . 113(4) ?
C32 C321 H321b . . . 112(3) ?
C32 C321 H321c . . . 111(2) ?
H321a C321 H321b . . . 101(4) ?
H321a C321 H321c . . . 104(3) ?
H321b C321 H321c . . . 115(4) ?
C32 C33 C34 . . . 122.1(2) ?
C32 C33 H33 . . . 117(2) ?
C34 C33 H33 . . . 121(2) ?
C33 C34 C35 . . . 119.9(3) ?
C33 C34 H34 . . . 122(3) ?
C35 C34 H34 . . . 118(3) ?
C34 C35 C36 . . . 119.3(3) ?
C34 C35 H35 . . . 122.0(16) ?
C36 C35 H35 . . . 118.8(16) ?
C31 C36 C35 . . . 121.2(2) ?
C31 C36 H36 . . . 121(2) ?
C35 C36 H36 . . . 117(2) ?
O11 N1 O12 . . . 119.8(2) ?
O11 N1 O13 . . . 121.0(2) ?
O12 N1 O13 . . . 119.3(2) ?
Ag1 O11 N1 . . . 107.04(17) ?
Ag1 O11 Ag2 . . '1 645' 143.84(8) ?
N1 O11 Ag2 . . '1 645' 97.74(13) ?
N1 O12 Ag2 . . '1 645' 95.81(16) ?
O21 N2 O22 . . . 119.79(18) ?
O21 N2 O23 . . . 120.31(19) ?
O22 N2 O23 . . . 119.90(17) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N114 . . 2.2161(16) ?
Ag1 N214 . . 2.565(3) ?
Ag1 P . . 2.3896(6) ?
Ag1 O11 . . 2.6722(19) ?
Ag2 N124 . . 2.1337(17) ?
Ag2 N224 . '1 365' 2.1335(18) ?
Ag2 O11 . '1 465' 2.731(2) ?
Ag2 O12 . '1 465' 2.755(2) ?
C1 N111 . . 1.442(2) ?
C1 N121 . . 1.453(3) ?
C1 H1a . . .96(4) ?
C1 H1b . . .87(2) ?
N111 N112 . . 1.360(2) ?
N111 C115 . . 1.329(2) ?
N112 C113 . . 1.318(3) ?
C113 N114 . . 1.358(3) ?
C113 H113 . . .85(3) ?
N114 C115 . . 1.327(3) ?
C115 H115 . . .98(3) ?
N121 N122 . . 1.361(4) ?
N121 C125 . . 1.329(2) ?
N122 C123 . . 1.312(3) ?
C123 N124 . . 1.355(3) ?
C123 H123 . . .92(4) ?
N124 C125 . . 1.324(4) ?
C125 H125 . . .88(4) ?
C2 N211 . . 1.453(3) ?
C2 N221 . . 1.445(3) ?
C2 H2a . . .92(3) ?
C2 H2b . . .99(4) ?
N211 N212 . . 1.364(3) ?
N211 C215 . . 1.329(3) ?
N212 C213 . . 1.312(4) ?
C213 N214 . . 1.352(3) ?
C213 H213 . . .91(3) ?
N214 C215 . . 1.319(3) ?
C215 H215 . . .84(3) ?
N221 N222 . . 1.365(4) ?
N221 C225 . . 1.327(3) ?
N222 C223 . . 1.316(3) ?
C223 N224 . . 1.358(4) ?
C223 H223 . . .97(4) ?
N224 C225 . . 1.325(3) ?
C225 H225 . . .92(4) ?
P C11 . . 1.827(2) ?
P C21 . . 1.832(2) ?
P C31 . . 1.833(2) ?
C11 C12 . . 1.410(3) ?
C11 C16 . . 1.401(3) ?
C12 C121 . . 1.503(3) ?
C12 C13 . . 1.396(3) ?
C121 H121a . . .82(6) ?
C121 H121b . . .87(4) ?
C121 H121c . . .89(4) ?
C13 C14 . . 1.390(4) ?
C13 H13 . . .94(3) ?
C14 C15 . . 1.381(4) ?
C14 H14 . . .94(4) ?
C15 C16 . . 1.393(4) ?
C15 H15 . . .91(3) ?
C16 H16 . . .89(3) ?
C21 C22 . . 1.409(3) ?
C21 C26 . . 1.395(2) ?
C22 C221 . . 1.507(3) ?
C22 C23 . . 1.395(4) ?
C221 H221a . . .90(4) ?
C221 H221b . . .91(4) ?
C221 H221c . . .94(3) ?
C23 C24 . . 1.391(3) ?
C23 H23 . . .97(3) ?
C24 C25 . . 1.386(4) ?
C24 H24 . . .95(3) ?
C25 C26 . . 1.391(4) ?
C25 H25 . . .97(2) ?
C26 H26 . . .88(3) ?
C31 C32 . . 1.410(3) ?
C31 C36 . . 1.396(4) ?
C32 C321 . . 1.511(5) ?
C32 C33 . . 1.391(3) ?
C321 H321a . . .87(4) ?
C321 H321b . . .92(5) ?
C321 H321c . . .97(3) ?
C33 C34 . . 1.376(5) ?
C33 H33 . . .89(3) ?
C34 C35 . . 1.386(4) ?
C34 H34 . . .92(4) ?
C35 C36 . . 1.393(3) ?
C35 H35 . . .96(4) ?
C36 H36 . . .96(3) ?
N1 O11 . . 1.239(3) ?
N1 O12 . . 1.267(2) ?
N1 O13 . . 1.239(4) ?
N2 O21 . . 1.247(2) ?
N2 O22 . . 1.259(3) ?
N2 O23 . . 1.248(2) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
? ? ? ? ? ? ? ? ? ? ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
? ? ? ? ? ? ? ? ? ?
