#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:36:30 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179148 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/09/4310957.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4310957
loop_
_publ_author_name
'Evgeny V. Dikarev'
'Kristian W. Andreini'
'Marina A. Petrukhina'
_publ_section_title
;
 On the Road to a Termolecular Complex with Acetone: A Heterometallic
 Supramolecular Network {[Rh2(O2CCF3)4].μ2-OCMe2.[Cu4(O2CCF3)4]}
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3219
_journal_page_last               3224
_journal_paper_doi               10.1021/ic030340w
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety
;
  [Rh2 (O2 C C F3)4] [Cu4 (O2 C C F3)4] (O C (C H3)2)
;
_chemical_formula_sum            'C19 H6 Cu4 F24 O17 Rh2'
_chemical_formula_weight         1422.22
_chemical_melting_point          ?
_chemical_name_systematic
;
  Catena[tetrakis(mu2-trifluoroacetato-O,O')-di-rhodium(II)-
  (mu2-O-acetone)-tetrakis(mu2-trifluoroacetato-O,O')-tetra-copper(I)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.3950(10)
_cell_angle_beta                 94.6990(10)
_cell_angle_gamma                107.5290(10)
_cell_formula_units_Z            2
_cell_length_a                   8.5009(5)
_cell_length_b                   11.1068(6)
_cell_length_c                   20.8409(12)
_cell_measurement_reflns_used    6895
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.27
_cell_measurement_theta_min      2.22
_cell_volume                     1865.49(18)
_computing_cell_refinement       'SMART, SAINT'
_computing_data_collection       SMART
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXP-93 (Sheldrick, 1993)'
_computing_publication_material  'SHELXCIF-93 (Sheldrick, 1993)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.902
_diffrn_measured_fraction_theta_max 0.902
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       '0.3 deg wide ω exposures'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0159
_diffrn_reflns_av_sigmaI/netI    0.0219
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            16227
_diffrn_reflns_theta_full        28.27
_diffrn_reflns_theta_max         28.27
_diffrn_reflns_theta_min         1.93
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count na
_diffrn_standards_interval_time  na
_diffrn_standards_number         'none (area detector data)'
_exptl_absorpt_coefficient_mu    3.293
_exptl_absorpt_correction_T_max  0.7786
_exptl_absorpt_correction_T_min  0.3318
_exptl_absorpt_correction_type   'multi-scan (SADABS)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.532
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
_exptl_crystal_description       needle
_exptl_crystal_F_000             1356
_exptl_crystal_size_max          0.43
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.623
_refine_diff_density_min         -0.820
_refine_diff_density_rms         0.093
_refine_ls_extinction_coef       noref
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     606
_refine_ls_number_reflns         8347
_refine_ls_number_restraints     18
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0264
_refine_ls_R_factor_gt           0.0246
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0353P)²+1.5258P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0634
_refine_ls_wR_factor_ref         0.0645
_reflns_number_gt                7773
_reflns_number_total             8347
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic030340w_1.cif
_cod_data_source_block           '[Rh2(O2CCF3)4(Me2CO)Cu4(O2CCF3)4]_(5)'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

Automatic conversion script
Id: cif_fix_values 1569 2011-02-09 13:29:24Z adriana 
;
_cod_database_code               4310957
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.35582(2) 0.252979(15) 0.361204(8) 0.02024(5) Uani 1 1 d . . .
Rh2 Rh 0.49568(2) 0.450447(15) 0.421508(8) 0.02103(5) Uani 1 1 d . . .
Cu1 Cu 0.45873(4) 0.16249(3) 0.071492(14) 0.03033(7) Uani 1 1 d . . .
Cu2 Cu 0.32419(4) 0.17187(3) 0.188857(15) 0.03562(8) Uani 1 1 d . . .
Cu3 Cu 0.11854(4) 0.01392(3) 0.091870(15) 0.03138(7) Uani 1 1 d . . .
Cu4 Cu 0.25533(4) -0.01105(3) -0.021159(14) 0.03160(7) Uani 1 1 d . . .
O1 O 0.16447(19) 0.32233(15) 0.33892(8) 0.0260(3) Uani 1 1 d . . .
O2 O 0.45773(19) 0.33064(15) 0.28189(7) 0.0250(3) Uani 1 1 d . A .
O3 O 0.5587(2) 0.19757(15) 0.38624(8) 0.0274(3) Uani 1 1 d . . .
O4 O 0.2614(2) 0.18666(15) 0.44434(7) 0.0258(3) Uani 1 1 d . . .
O5 O 0.2971(2) 0.50892(15) 0.39607(8) 0.0274(3) Uani 1 1 d . . .
O6 O 0.5886(2) 0.51654(15) 0.33910(8) 0.0280(3) Uani 1 1 d . A .
O7 O 0.6891(2) 0.38358(16) 0.44412(8) 0.0279(3) Uani 1 1 d . . .
O9 O 0.0125(2) 0.14237(15) 0.08820(8) 0.0302(3) Uani 1 1 d . . .
O10 O 0.1779(2) 0.26446(18) 0.17059(9) 0.0385(4) Uani 1 1 d . . .
O11 O 0.3645(2) 0.27030(16) 0.02566(8) 0.0316(4) Uani 1 1 d . . .
O12 O 0.1886(2) 0.12774(15) -0.04775(8) 0.0295(3) Uani 1 1 d . . .
O13 O 0.5860(2) 0.07579(17) 0.11921(8) 0.0306(4) Uani 1 1 d . . .
O14 O 0.4762(2) 0.08641(19) 0.21302(8) 0.0379(4) Uani 1 1 d . . .
O15 O 0.1988(2) -0.12383(16) 0.10703(9) 0.0339(4) Uani 1 1 d . . .
O16 O 0.3296(2) -0.13629(16) 0.01890(8) 0.0328(4) Uani 1 1 d . . .
O17 O 0.21583(19) 0.07801(15) 0.30121(8) 0.0262(3) Uani 1 1 d . . .
C1 C 0.1809(3) 0.4333(2) 0.35996(11) 0.0248(4) Uani 1 1 d . . .
C2 C 0.0425(3) 0.4878(2) 0.33555(13) 0.0346(5) Uani 1 1 d . . .
C3 C 0.5461(3) 0.4449(2) 0.28888(10) 0.0242(4) Uani 1 1 d . . .
C4 C 0.6058(3) 0.5063(2) 0.22681(12) 0.0323(5) Uani 1 1 d D A 1
F4 F 0.5977(6) 0.4152(4) 0.17939(19) 0.0308(9) Uiso 0.50 1 d PD A 1
F5 F 0.7640(5) 0.5823(4) 0.23843(18) 0.0317(8) Uiso 0.50 1 d PD A 1
F6 F 0.5105(5) 0.5727(5) 0.20742(19) 0.0352(8) Uiso 0.50 1 d PD A 1
F4X F 0.6512(10) 0.4324(8) 0.1880(4) 0.042(2) Uiso 0.25 1 d PD A 2
F5X F 0.7243(10) 0.6134(7) 0.2388(4) 0.048(2) Uiso 0.25 1 d PD A 2
F6X F 0.4725(9) 0.5288(8) 0.1943(4) 0.0425(19) Uiso 0.25 1 d PD A 2
F4Y F 0.5558(10) 0.4331(7) 0.1738(4) 0.042(2) Uiso 0.25 1 d PD A 3
F5Y F 0.7721(7) 0.5446(7) 0.2293(3) 0.0321(16) Uiso 0.25 1 d PD A 3
F6Y F 0.5633(10) 0.6123(7) 0.2182(4) 0.0407(18) Uiso 0.25 1 d PD A 3
C5 C 0.6750(3) 0.2738(2) 0.42216(10) 0.0257(4) Uani 1 1 d . . .
C6 C 0.8173(3) 0.2213(3) 0.44406(12) 0.0350(5) Uani 1 1 d . . .
C9 C 0.5746(3) 0.0602(2) 0.17793(11) 0.0278(5) Uani 1 1 d . . .
C10 C 0.6967(3) 0.0025(3) 0.21409(12) 0.0385(6) Uani 1 1 d . . .
C11 C 0.2593(3) 0.2368(2) -0.02194(11) 0.0258(4) Uani 1 1 d . . .
C12 C 0.2050(3) 0.3436(2) -0.05248(12) 0.0333(5) Uani 1 1 d . . .
C13 C 0.0591(3) 0.2365(2) 0.12835(11) 0.0271(4) Uani 1 1 d . . .
C14 C -0.0437(3) 0.3288(2) 0.12868(13) 0.0325(5) Uani 1 1 d . . .
C15 C 0.2820(3) -0.1687(2) 0.07226(12) 0.0276(5) Uani 1 1 d . . .
C16 C 0.3375(3) -0.2776(2) 0.09939(13) 0.0322(5) Uani 1 1 d . . .
C17 C 0.1987(3) -0.0347(2) 0.30746(11) 0.0281(5) Uani 1 1 d . . .
C18 C 0.0881(4) -0.1322(3) 0.25943(15) 0.0450(7) Uani 1 1 d . . .
H18A H 0.0440 -0.0908 0.2248 0.067 Uiso 1 1 calc R . .
H18B H -0.0038 -0.1863 0.2805 0.067 Uiso 1 1 calc R . .
H18C H 0.1510 -0.1840 0.2412 0.067 Uiso 1 1 calc R . .
C19 C 0.2868(5) -0.0782(3) 0.36180(16) 0.0597(10) Uani 1 1 d . . .
H19A H 0.3954 -0.0799 0.3499 0.089 Uiso 1 1 calc R . .
H19B H 0.2214 -0.1634 0.3713 0.089 Uiso 1 1 calc R . .
H19C H 0.3019 -0.0201 0.4001 0.089 Uiso 1 1 calc R . .
F1 F 0.0837(2) 0.5466(2) 0.28242(10) 0.0604(5) Uani 1 1 d . . .
F2 F 0.0199(2) 0.56951(19) 0.37862(11) 0.0639(6) Uani 1 1 d . . .
F3 F -0.10161(18) 0.39798(15) 0.32097(8) 0.0400(3) Uani 1 1 d . . .
F7 F 0.7759(3) 0.1536(2) 0.49447(10) 0.0670(6) Uani 1 1 d . . .
F8 F 0.9582(2) 0.31369(18) 0.46169(9) 0.0508(4) Uani 1 1 d . . .
F9 F 0.8476(2) 0.14823(17) 0.39844(9) 0.0462(4) Uani 1 1 d . . .
F13 F 0.6172(3) -0.0954(2) 0.24429(11) 0.0725(7) Uani 1 1 d . . .
F14 F 0.7948(3) 0.0864(2) 0.25770(11) 0.0778(7) Uani 1 1 d . . .
F15 F 0.7895(2) -0.0348(2) 0.17546(8) 0.0623(6) Uani 1 1 d . . .
F16 F 0.0826(2) 0.36337(19) -0.02193(10) 0.0566(5) Uani 1 1 d . . .
F17 F 0.3277(2) 0.45062(15) -0.04851(9) 0.0517(4) Uani 1 1 d . . .
F18 F 0.1494(2) 0.31474(17) -0.11396(8) 0.0507(4) Uani 1 1 d . . .
F19 F -0.1509(2) 0.31255(16) 0.07708(8) 0.0451(4) Uani 1 1 d . . .
F20 F -0.1322(2) 0.30946(19) 0.17944(9) 0.0538(5) Uani 1 1 d . . .
F21 F 0.0510(2) 0.44668(16) 0.13440(12) 0.0658(6) Uani 1 1 d . . .
F22 F 0.2749(2) -0.31241(15) 0.15415(8) 0.0446(4) Uani 1 1 d . . .
F23 F 0.5026(2) -0.23966(18) 0.11175(9) 0.0511(4) Uani 1 1 d . . .
F24 F 0.2963(3) -0.37660(16) 0.05770(10) 0.0596(5) Uani 1 1 d . . .
O8 O 0.39028(19) 0.37238(14) 0.50147(7) 0.0244(3) Uani 1 1 d . . .
C7 C 0.2998(3) 0.2582(2) 0.49438(10) 0.0226(4) Uani 1 1 d . . .
C8 C 0.2334(3) 0.2006(2) 0.55654(11) 0.0295(5) Uani 1 1 d . . .
F10 F 0.1669(2) 0.27546(16) 0.58821(8) 0.0493(4) Uani 1 1 d . . .
F11 F 0.1170(3) 0.09126(15) 0.54407(8) 0.0544(5) Uani 1 1 d . . .
F12 F 0.3556(3) 0.1855(3) 0.59448(10) 0.0719(7) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Rh1 O2 88.23(6) . . y
O1 Rh1 O3 175.45(6) . . y
O2 Rh1 O3 90.71(6) . . y
O1 Rh1 O4 91.52(7) . . y
O2 Rh1 O4 176.05(6) . . y
O3 Rh1 O4 89.23(7) . . y
O1 Rh1 O17 88.29(6) . . y
O2 Rh1 O17 89.82(6) . . y
O3 Rh1 O17 96.14(6) . . y
O4 Rh1 O17 94.11(6) . . y
O1 Rh1 Rh2 87.82(4) . . n
O2 Rh1 Rh2 88.34(4) . . n
O3 Rh1 Rh2 87.72(5) . . n
O4 Rh1 Rh2 87.71(4) . . n
O17 Rh1 Rh2 175.75(4) . . y
O6 Rh2 O5 88.14(7) . . y
O6 Rh2 O7 91.54(7) . . y
O5 Rh2 O7 177.07(6) . . y
O6 Rh2 O8 175.98(6) . . y
O5 Rh2 O8 91.00(7) . . y
O7 Rh2 O8 89.12(6) . . y
O6 Rh2 O8 103.20(6) . 2_666 y
O5 Rh2 O8 91.60(6) . 2_666 y
O7 Rh2 O8 91.32(6) . 2_666 y
O8 Rh2 O8 80.74(6) . 2_666 y
O6 Rh2 Rh1 87.76(5) . . n
O5 Rh2 Rh1 88.51(5) . . n
O7 Rh2 Rh1 88.57(5) . . n
O8 Rh2 Rh1 88.29(4) . . n
O8 Rh2 Rh1 169.03(4) 2_666 . y
O11 Cu1 O13 170.77(8) . . y
O11 Cu1 Cu4 80.68(5) . . n
O13 Cu1 Cu4 106.59(5) . . n
O11 Cu1 O16 96.71(7) . 2_655 y
O13 Cu1 O16 79.88(6) . 2_655 y
Cu4 Cu1 O16 76.19(4) . 2_655 n
O11 Cu1 Cu2 99.92(6) . . n
O13 Cu1 Cu2 82.44(5) . . n
Cu4 Cu1 Cu2 114.474(14) . . y
O16 Cu1 Cu2 161.48(4) 2_655 . n
O11 Cu1 Cu3 86.95(5) . . n
O13 Cu1 Cu3 101.70(5) . . n
Cu4 Cu1 Cu3 57.677(11) . . y
O16 Cu1 Cu3 132.54(4) 2_655 . n
Cu2 Cu1 Cu3 56.954(11) . . y
O10 Cu2 O14 175.71(8) . . y
O10 Cu2 O2 88.16(7) . . y
O14 Cu2 O2 87.62(7) . . y
O10 Cu2 O17 99.43(7) . . y
O14 Cu2 O17 78.37(7) . . y
O2 Cu2 O17 69.94(5) . . y
O10 Cu2 Cu3 80.72(6) . . n
O14 Cu2 Cu3 103.40(6) . . n
O2 Cu2 Cu3 167.49(4) . . n
O17 Cu2 Cu3 106.08(4) . . n
O10 Cu2 Cu1 102.21(6) . . n
O14 Cu2 Cu1 80.86(6) . . n
O2 Cu2 Cu1 124.41(4) . . n
O17 Cu2 Cu1 154.19(4) . . n
Cu3 Cu2 Cu1 64.222(12) . . y
O15 Cu3 O9 169.83(8) . . y
O15 Cu3 O12 95.28(7) . 2 y
O9 Cu3 O12 80.51(6) . 2 y
O15 Cu3 Cu2 95.12(6) . . n
O9 Cu3 Cu2 84.03(5) . . n
O12 Cu3 Cu2 148.04(4) 2 . n
O15 Cu3 Cu4 78.62(6) . . n
O9 Cu3 Cu4 110.87(5) . . n
O12 Cu3 Cu4 95.32(4) 2 . n
Cu2 Cu3 Cu4 116.346(15) . . y
O15 Cu3 Cu1 87.85(5) . . n
O9 Cu3 Cu1 100.26(5) . . n
O12 Cu3 Cu1 151.72(4) 2 . n
Cu2 Cu3 Cu1 58.824(11) . . y
Cu4 Cu3 Cu1 57.684(11) . . y
O12 Cu4 O16 170.72(7) . . y
O12 Cu4 O9 83.90(6) . 2 y
O16 Cu4 O9 102.56(7) . 2 y
O12 Cu4 O13 105.93(6) . 2_655 y
O16 Cu4 O13 81.43(6) . 2_655 y
O9 Cu4 O13 85.57(5) 2 2_655 y
O12 Cu4 Cu3 86.89(5) . . n
O16 Cu4 Cu3 85.67(5) . . n
O9 Cu4 Cu3 97.36(4) 2 . n
O13 Cu4 Cu3 167.11(4) 2_655 . n
O12 Cu4 Cu1 84.07(5) . . n
O16 Cu4 Cu1 87.72(5) . . n
O9 Cu4 Cu1 158.84(4) 2 . n
O13 Cu4 Cu1 114.51(4) 2_655 . n
Cu3 Cu4 Cu1 64.638(12) . . y
C1 O1 Rh1 117.24(14) . . n
C3 O2 Rh1 116.73(14) . . n
C3 O2 Cu2 136.45(14) . . n
Rh1 O2 Cu2 105.78(6) . . y
C5 O3 Rh1 117.25(15) . . n
C7 O4 Rh1 118.78(14) . . n
C1 O5 Rh2 116.76(14) . . n
C3 O6 Rh2 118.13(14) . . n
C5 O7 Rh2 116.85(14) . . n
C13 O9 Cu3 120.20(15) . . n
C13 O10 Cu2 126.71(17) . . n
C11 O11 Cu1 125.29(16) . . n
C11 O12 Cu4 120.57(15) . . n
C9 O13 Cu1 122.06(16) . . n
C9 O14 Cu2 125.80(16) . . n
C15 O15 Cu3 127.68(17) . . n
C15 O16 Cu4 118.45(16) . . n
C17 O17 Rh1 132.79(15) . . y
C17 O17 Cu2 116.98(14) . . y
Rh1 O17 Cu2 94.27(5) . . y
O1 C1 O5 129.6(2) . . n
O1 C1 C2 115.6(2) . . n
O5 C1 C2 114.7(2) . . n
F2 C2 F1 108.4(2) . . n
F2 C2 F3 107.7(2) . . n
F1 C2 F3 107.8(2) . . n
F2 C2 C1 111.8(2) . . n
F1 C2 C1 109.0(2) . . n
F3 C2 C1 112.1(2) . . n
O6 C3 O2 128.9(2) . . n
O6 C3 C4 115.1(2) . . n
O2 C3 C4 115.9(2) . . n
F6 C4 F5 109.6(4) . . n
F6 C4 F4 108.9(3) . . n
F5 C4 F4 109.0(3) . . n
F6 C4 C3 109.0(2) . . n
F5 C4 C3 110.0(2) . . n
F4 C4 C3 110.3(2) . . n
O7 C5 O3 129.6(2) . . n
O7 C5 C6 116.0(2) . . n
O3 C5 C6 114.4(2) . . n
F9 C6 F7 108.4(2) . . n
F9 C6 F8 107.3(2) . . n
F7 C6 F8 108.2(2) . . n
F9 C6 C5 112.3(2) . . n
F7 C6 C5 108.7(2) . . n
F8 C6 C5 111.8(2) . . n
O14 C9 O13 128.6(2) . . n
O14 C9 C10 113.3(2) . . n
O13 C9 C10 118.1(2) . . n
F15 C10 F13 107.9(3) . . n
F15 C10 F14 108.1(2) . . n
F13 C10 F14 107.5(2) . . n
F15 C10 C9 112.5(2) . . n
F13 C10 C9 110.8(2) . . n
F14 C10 C9 109.9(2) . . n
O11 C11 O12 129.0(2) . . n
O11 C11 C12 115.5(2) . . n
O12 C11 C12 115.4(2) . . n
F17 C12 F18 107.8(2) . . n
F17 C12 F16 108.2(2) . . n
F18 C12 F16 107.5(2) . . n
F17 C12 C11 111.8(2) . . n
F18 C12 C11 111.9(2) . . n
F16 C12 C11 109.5(2) . . n
O10 C13 O9 128.1(2) . . n
O10 C13 C14 113.7(2) . . n
O9 C13 C14 118.1(2) . . n
F21 C14 F19 108.7(2) . . n
F21 C14 F20 107.7(2) . . n
F19 C14 F20 106.5(2) . . n
F21 C14 C13 111.6(2) . . n
F19 C14 C13 113.5(2) . . n
F20 C14 C13 108.5(2) . . n
O15 C15 O16 129.0(2) . . n
O15 C15 C16 115.7(2) . . n
O16 C15 C16 115.3(2) . . n
F24 C16 F22 108.9(2) . . n
F24 C16 F23 107.7(2) . . n
F22 C16 F23 107.1(2) . . n
F24 C16 C15 111.3(2) . . n
F22 C16 C15 112.3(2) . . n
F23 C16 C15 109.26(19) . . n
O17 C17 C18 120.0(2) . . n
O17 C17 C19 122.2(2) . . n
C18 C17 C19 117.8(2) . . n
C7 O8 Rh2 116.89(14) . . n
C7 O8 Rh2 143.83(14) . 2_666 n
Rh2 O8 Rh2 99.26(6) . 2_666 n
O4 C7 O8 128.3(2) . . n
O4 C7 C8 116.51(19) . . n
O8 C7 C8 115.17(19) . . n
F12 C8 F11 109.6(2) . . n
F12 C8 F10 108.0(2) . . n
F11 C8 F10 106.6(2) . . n
F12 C8 C7 109.5(2) . . n
F11 C8 C7 111.80(19) . . n
F10 C8 C7 111.21(19) . . n
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 O1 2.0288(15) . y
Rh1 O2 2.0323(15) . y
Rh1 O3 2.0360(16) . y
Rh1 O4 2.0415(16) . y
Rh1 O17 2.2173(15) . y
Rh1 Rh2 2.3995(2) . y
Rh2 O6 2.0225(16) . y
Rh2 O5 2.0237(16) . y
Rh2 O7 2.0282(16) . y
Rh2 O8 2.0565(16) . y
Rh2 O8 2.3918(15) 2_666 y
Cu1 O11 1.8803(17) . y
Cu1 O13 1.9021(17) . y
Cu1 Cu4 2.7510(4) . y
Cu1 O16 2.7744(18) 2_655 y
Cu1 Cu2 2.7947(5) . y
Cu1 Cu3 2.9414(5) . y
Cu2 O10 1.8642(18) . y
Cu2 O14 1.8701(18) . y
Cu2 O2 2.5111(16) . y
Cu2 O17 2.7197(17) . y
Cu2 Cu3 2.7380(4) . y
Cu3 O15 1.8814(17) . y
Cu3 O9 1.9044(16) . y
Cu3 O12 2.6737(17) 2 y
Cu3 Cu4 2.7507(4) . y
Cu4 O12 1.8847(16) . y
Cu4 O16 1.8894(17) . y
Cu4 O9 2.5633(17) 2 y
Cu4 O13 2.7249(17) 2_655 y
O1 C1 1.254(3) . n
O2 C3 1.260(3) . n
O3 C5 1.256(3) . n
O4 C7 1.242(3) . n
O5 C1 1.254(3) . n
O6 C3 1.247(3) . n
O7 C5 1.252(3) . n
O9 C13 1.255(3) . n
O10 C13 1.238(3) . n
O11 C11 1.243(3) . n
O12 C11 1.253(3) . n
O13 C9 1.251(3) . n
O14 C9 1.244(3) . n
O15 C15 1.241(3) . n
O16 C15 1.245(3) . n
O17 C17 1.229(3) . y
C1 C2 1.538(3) . n
C2 F2 1.316(3) . n
C2 F1 1.327(3) . n
C2 F3 1.329(3) . n
C3 C4 1.539(3) . n
C4 F6 1.303(4) . n
C4 F5 1.352(4) . n
C4 F4 1.366(4) . n
C5 C6 1.539(3) . n
C6 F9 1.315(3) . n
C6 F7 1.327(3) . n
C6 F8 1.333(3) . n
C9 C10 1.539(3) . n
C10 F15 1.309(3) . n
C10 F13 1.311(3) . n
C10 F14 1.314(4) . n
C11 C12 1.539(3) . n
C12 F17 1.319(3) . n
C12 F18 1.320(3) . n
C12 F16 1.331(3) . n
C13 C14 1.534(3) . n
C14 F21 1.309(3) . n
C14 F19 1.321(3) . n
C14 F20 1.336(3) . n
C15 C16 1.536(3) . n
C16 F24 1.314(3) . n
C16 F22 1.322(3) . n
C16 F23 1.338(3) . n
C17 C18 1.484(3) . n
C17 C19 1.484(4) . n
O8 C7 1.265(3) . n
O8 Rh2 2.3918(15) 2_666 n
C7 C8 1.542(3) . n
C8 F12 1.308(3) . n
C8 F11 1.315(3) . n
C8 F10 1.321(3) . n
