#------------------------------------------------------------------------------
#$Date: 2023-12-08 16:16:31 +0200 (Fri, 08 Dec 2023) $
#$Revision: 288183 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/31/09/4310971.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4310971
loop_
_publ_author_name
'Éric Fournier'
'Frédéric Lebrun'
'Marc Drouin'
'Andreas Decken'
'Pierre D. Harvey'
_publ_section_title
;
 Preparation and Solid-State Characterization of Mixed-Ligand
 Coordination/Organometallic Oligomers and Polymers of Copper(I) and
 Silver(I) Using Diphosphine and Mono- and Diisocyanide Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              3127
_journal_page_last               3135
_journal_paper_doi               10.1021/ic034806m
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C74 H80 Ag2 Cl2 N4 O8 P4'
_chemical_formula_weight         1563.94
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.780(12)
_cell_angle_beta                 107.349(11)
_cell_angle_gamma                115.764(11)
_cell_formula_units_Z            1
_cell_length_a                   13.1321(19)
_cell_length_b                   13.3093(18)
_cell_length_c                   13.4611(16)
_cell_measurement_temperature    293(2)
_cell_volume                     1828.0(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_wavelength     1.54060
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0178
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            6931
_diffrn_reflns_theta_full        69.93
_diffrn_reflns_theta_max         69.93
_diffrn_reflns_theta_min         3.80
_exptl_absorpt_coefficient_mu    6.249
_exptl_crystal_density_diffrn    1.421
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             804
_refine_diff_density_max         1.017
_refine_diff_density_min         -1.210
_refine_diff_density_rms         0.144
_refine_ls_extinction_coef       0.0010(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     425
_refine_ls_number_reflns         6931
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0625
_refine_ls_R_factor_gt           0.0484
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1478P)²+1.9468P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1542
_refine_ls_wR_factor_ref         0.2051
_reflns_number_gt                5990
_reflns_number_total             6931
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic034806mrom20030711_100942.cif
_cod_data_source_block           fl135b
_cod_depositor_comments
;
The following automatic conversions were performed:

data name '_atom_site_symmetry_multiplicit' was replaced with
'_atom_site_symmetry_multiplicity' as specified in the replacement
file 'data/replacement-values/replacement_tags.lst'.

Automatic conversion script
Id: cif_correct_tags 9268 2022-04-12 08:56:07Z antanas 
;
_cod_original_cell_volume        1828.0(4)
_cod_database_code               4310971
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.63423(3) 0.02378(3) 0.44795(3) 0.05185(19) Uani 1 1 d . . .
P1 P 0.72301(12) 0.23854(11) 0.57754(10) 0.0446(3) Uani 1 1 d . . .
P2 P 0.42269(12) -0.15454(12) 0.29009(10) 0.0461(3) Uani 1 1 d . . .
Cl Cl 0.27153(19) 0.3618(2) 0.1607(2) 0.0899(6) Uani 1 1 d . . .
O1 O 0.2188(14) 0.2442(10) 0.1511(11) 0.186(5) Uani 1 1 d . . .
O2 O 0.2095(11) 0.4076(10) 0.1959(13) 0.215(6) Uani 1 1 d . . .
O3 O 0.2482(10) 0.3545(16) 0.0496(10) 0.239(8) Uani 1 1 d . . .
O4 O 0.4034(8) 0.4326(10) 0.2195(9) 0.164(4) Uani 1 1 d . . .
N1 N 1.2132(5) -0.0810(6) 0.7209(5) 0.0676(13) Uani 1 1 d . . .
N2 N 0.7385(6) -0.1490(6) 0.5265(5) 0.0697(13) Uani 1 1 d . . .
C1 C 1.2575(7) -0.0680(7) 0.6608(6) 0.0694(16) Uani 1 1 d . . .
C2 C 1.1547(6) -0.0934(7) 0.7988(6) 0.0725(17) Uani 1 1 d . . .
C3 C 1.0503(7) -0.2269(8) 0.7516(7) 0.079(2) Uani 1 1 d . . .
H3A H 1.0169 -0.2381 0.8061 0.094 Uiso 1 1 calc . . .
H3B H 1.0857 -0.2771 0.7432 0.094 Uiso 1 1 calc . . .
C4 C 0.9406(7) -0.2719(7) 0.6345(7) 0.0710(16) Uani 1 1 d . . .
H4A H 0.9707 -0.2723 0.5768 0.085 Uiso 1 1 calc . . .
H4B H 0.8728 -0.3558 0.6114 0.085 Uiso 1 1 calc . . .
C5 C 0.8886(6) -0.1883(6) 0.6408(5) 0.0593(13) Uani 1 1 d . . .
H5 H 0.8564 -0.1924 0.6976 0.071 Uiso 1 1 calc . . .
C6 C 0.9962(7) -0.0541(6) 0.6850(7) 0.0711(16) Uani 1 1 d . . .
H6A H 1.0294 -0.0463 0.6299 0.085 Uiso 1 1 calc . . .
H6B H 0.9633 -0.0017 0.6926 0.085 Uiso 1 1 calc . . .
C7 C 1.1036(7) -0.0119(8) 0.8016(6) 0.081(2) Uani 1 1 d . . .
H7A H 1.1723 0.0718 0.8255 0.097 Uiso 1 1 calc . . .
H7B H 1.0722 -0.0110 0.8584 0.097 Uiso 1 1 calc . . .
C8 C 0.7738(7) -0.2392(6) 0.5231(6) 0.0664(15) Uani 1 1 d . . .
C9 C 0.7064(7) -0.0832(6) 0.5170(5) 0.0678(15) Uani 1 1 d . . .
C10 C 1.2605(9) -0.0527(12) 0.9159(8) 0.115(4) Uani 1 1 d . . .
H10A H 1.3257 0.0327 0.9448 0.173 Uiso 1 1 calc . . .
H10B H 1.2962 -0.1017 0.9075 0.173 Uiso 1 1 calc . . .
H10C H 1.2259 -0.0636 0.9689 0.173 Uiso 1 1 calc . . .
C11 C 0.8019(10) -0.2602(9) 0.4203(7) 0.093(2) Uani 1 1 d . . .
H11A H 0.8749 -0.1853 0.4342 0.140 Uiso 1 1 calc . . .
H11B H 0.7297 -0.2843 0.3521 0.140 Uiso 1 1 calc . . .
H11C H 0.8188 -0.3243 0.4101 0.140 Uiso 1 1 calc . . .
C12 C 0.6560(8) -0.3557(7) 0.5051(8) 0.093(2) Uani 1 1 d . . .
H12A H 0.6416 -0.3389 0.5713 0.140 Uiso 1 1 calc . . .
H12B H 0.6699 -0.4217 0.4947 0.140 Uiso 1 1 calc . . .
H12C H 0.5830 -0.3790 0.4380 0.140 Uiso 1 1 calc . . .
C13 C 0.6494(5) 0.2761(5) 0.6651(4) 0.0508(11) Uani 1 1 d . . .
H13A H 0.7136 0.3534 0.7328 0.061 Uiso 1 1 calc . . .
H13B H 0.5846 0.2867 0.6208 0.061 Uiso 1 1 calc . . .
C14 C 0.8909(5) 0.3259(5) 0.6813(4) 0.0506(11) Uani 1 1 d . . .
C15 C 0.9526(6) 0.2656(6) 0.6936(5) 0.0617(13) Uani 1 1 d . . .
H15 H 0.9102 0.1825 0.6449 0.074 Uiso 1 1 calc . . .
C16 C 1.0780(7) 0.3271(8) 0.7778(6) 0.0757(18) Uani 1 1 d . . .
H16 H 1.1194 0.2856 0.7850 0.091 Uiso 1 1 calc . . .
C17 C 1.1401(6) 0.4498(7) 0.8503(5) 0.0746(18) Uani 1 1 d . . .
H17 H 1.2229 0.4908 0.9083 0.089 Uiso 1 1 calc . . .
C18 C 1.0801(6) 0.5122(7) 0.8372(6) 0.0734(17) Uani 1 1 d . . .
H18 H 1.1229 0.5956 0.8850 0.088 Uiso 1 1 calc . . .
C19 C 0.9556(6) 0.4501(6) 0.7525(5) 0.0603(13) Uani 1 1 d . . .
H19 H 0.9152 0.4923 0.7434 0.072 Uiso 1 1 calc . . .
C20 C 0.7156(5) 0.3169(5) 0.4846(4) 0.0501(11) Uani 1 1 d . . .
C21 C 0.6026(7) 0.3043(6) 0.4216(5) 0.0666(15) Uani 1 1 d . . .
H21 H 0.5344 0.2669 0.4370 0.080 Uiso 1 1 calc . . .
C22 C 0.5878(8) 0.3457(7) 0.3365(6) 0.0810(19) Uani 1 1 d . . .
H22 H 0.5108 0.3357 0.2945 0.097 Uiso 1 1 calc . . .
C23 C 0.6906(9) 0.4024(7) 0.3157(6) 0.082(2) Uani 1 1 d . . .
H23 H 0.6830 0.4322 0.2598 0.098 Uiso 1 1 calc . . .
C24 C 0.8020(8) 0.4154(7) 0.3752(6) 0.082(2) Uani 1 1 d . . .
H24 H 0.8694 0.4524 0.3588 0.099 Uiso 1 1 calc . . .
C25 C 0.8168(6) 0.3736(6) 0.4614(5) 0.0643(14) Uani 1 1 d . . .
H25 H 0.8941 0.3839 0.5028 0.077 Uiso 1 1 calc . . .
C26 C 0.4500(5) -0.2277(5) 0.1764(4) 0.0547(12) Uani 1 1 d . . .
C27 C 0.4903(8) -0.3060(7) 0.1849(6) 0.0786(19) Uani 1 1 d . . .
H27 H 0.4955 -0.3298 0.2449 0.094 Uiso 1 1 calc . . .
C28 C 0.5235(9) -0.3498(9) 0.1032(8) 0.096(3) Uani 1 1 d . . .
H28 H 0.5536 -0.4006 0.1107 0.115 Uiso 1 1 calc . . .
C29 C 0.5124(8) -0.3189(8) 0.0107(6) 0.092(3) Uani 1 1 d . . .
H29 H 0.5361 -0.3474 -0.0427 0.110 Uiso 1 1 calc . . .
C30 C 0.4658(9) -0.2455(8) -0.0003(6) 0.088(2) Uani 1 1 d . . .
H30 H 0.4553 -0.2262 -0.0630 0.105 Uiso 1 1 calc . . .
C31 C 0.4338(7) -0.1996(6) 0.0823(5) 0.0711(16) Uani 1 1 d . . .
H31 H 0.4019 -0.1504 0.0740 0.085 Uiso 1 1 calc . . .
C32 C 0.2934(6) -0.1418(6) 0.2123(5) 0.0568(12) Uani 1 1 d . . .
C33 C 0.1760(7) -0.2471(8) 0.1225(5) 0.0731(18) Uani 1 1 d . . .
H33 H 0.1644 -0.3246 0.1023 0.088 Uiso 1 1 calc . . .
C34 C 0.0794(7) -0.2350(11) 0.0654(7) 0.092(3) Uani 1 1 d . . .
H34 H 0.0019 -0.3040 0.0068 0.110 Uiso 1 1 calc . . .
C35 C 0.0984(10) -0.1213(14) 0.0954(8) 0.106(3) Uani 1 1 d . . .
H35 H 0.0317 -0.1143 0.0571 0.127 Uiso 1 1 calc . . .
C36 C 0.2093(12) -0.0178(11) 0.1783(8) 0.103(3) Uani 1 1 d . . .
H36 H 0.2187 0.0586 0.1954 0.124 Uiso 1 1 calc . . .
C37 C 0.3124(8) -0.0265(8) 0.2395(6) 0.079(2) Uani 1 1 d . . .
H37 H 0.3902 0.0437 0.2961 0.095 Uiso 1 1 calc . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C9 Ag C1 99.0(2) . 2_756 ?
C9 Ag P1 118.58(17) . . ?
C1 Ag P1 97.57(18) 2_756 . ?
C9 Ag P2 98.14(18) . . ?
C1 Ag P2 98.90(18) 2_756 . ?
P1 Ag P2 136.48(4) . . ?
C20 P1 C14 104.6(2) . . ?
C20 P1 C13 105.1(2) . . ?
C14 P1 C13 103.1(2) . . ?
C20 P1 Ag 105.28(16) . . ?
C14 P1 Ag 115.49(18) . . ?
C13 P1 Ag 121.71(18) . . ?
C32 P2 C26 103.3(3) . . ?
C32 P2 C13 104.7(3) . 2_656 ?
C26 P2 C13 103.5(2) . 2_656 ?
C32 P2 Ag 124.3(2) . . ?
C26 P2 Ag 107.42(18) . . ?
C13 P2 Ag 111.60(17) 2_656 . ?
O2 Cl O1 107.9(8) . . ?
O2 Cl O4 117.7(7) . . ?
O1 Cl O4 113.7(7) . . ?
O2 Cl O3 107.5(9) . . ?
O1 Cl O3 107.1(9) . . ?
O4 Cl O3 102.1(6) . . ?
C1 N1 C2 177.4(7) . . ?
C9 N2 C8 172.9(6) . . ?
N1 C1 Ag 174.5(6) . 2_756 ?
N1 C2 C7 106.8(6) . . ?
N1 C2 C3 108.1(6) . . ?
C7 C2 C3 111.7(6) . . ?
N1 C2 C10 106.2(6) . . ?
C7 C2 C10 112.9(8) . . ?
C3 C2 C10 110.8(7) . . ?
C2 C3 C4 112.8(6) . . ?
C2 C3 H3A 109.0 . . ?
C4 C3 H3A 109.0 . . ?
C2 C3 H3B 109.0 . . ?
C4 C3 H3B 109.0 . . ?
H3A C3 H3B 107.8 . . ?
C5 C4 C3 111.0(6) . . ?
C5 C4 H4A 109.4 . . ?
C3 C4 H4A 109.4 . . ?
C5 C4 H4B 109.4 . . ?
C3 C4 H4B 109.4 . . ?
H4A C4 H4B 108.0 . . ?
C6 C5 C4 110.2(5) . . ?
C6 C5 C8 114.7(5) . . ?
C4 C5 C8 110.0(5) . . ?
C6 C5 H5 107.2 . . ?
C4 C5 H5 107.2 . . ?
C8 C5 H5 107.2 . . ?
C7 C6 C5 110.8(6) . . ?
C7 C6 H6A 109.5 . . ?
C5 C6 H6A 109.5 . . ?
C7 C6 H6B 109.5 . . ?
C5 C6 H6B 109.5 . . ?
H6A C6 H6B 108.1 . . ?
C2 C7 C6 112.8(6) . . ?
C2 C7 H7A 109.0 . . ?
C6 C7 H7A 109.0 . . ?
C2 C7 H7B 109.0 . . ?
C6 C7 H7B 109.0 . . ?
H7A C7 H7B 107.8 . . ?
N2 C8 C11 106.0(6) . . ?
N2 C8 C12 105.1(5) . . ?
C11 C8 C12 112.0(7) . . ?
N2 C8 C5 108.7(5) . . ?
C11 C8 C5 114.1(6) . . ?
C12 C8 C5 110.4(6) . . ?
N2 C9 Ag 164.1(6) . . ?
C2 C10 H10A 109.5 . . ?
C2 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C2 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C8 C11 H11A 109.5 . . ?
C8 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C8 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C8 C12 H12A 109.5 . . ?
C8 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C8 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
P2 C13 P1 111.4(3) 2_656 . ?
P2 C13 H13A 109.3 2_656 . ?
P1 C13 H13A 109.3 . . ?
P2 C13 H13B 109.3 2_656 . ?
P1 C13 H13B 109.3 . . ?
H13A C13 H13B 108.0 . . ?
C15 C14 C19 119.1(5) . . ?
C15 C14 P1 119.2(4) . . ?
C19 C14 P1 121.6(4) . . ?
C14 C15 C16 120.9(6) . . ?
C14 C15 H15 119.5 . . ?
C16 C15 H15 119.5 . . ?
C17 C16 C15 119.4(6) . . ?
C17 C16 H16 120.3 . . ?
C15 C16 H16 120.3 . . ?
C16 C17 C18 120.2(6) . . ?
C16 C17 H17 119.9 . . ?
C18 C17 H17 119.9 . . ?
C17 C18 C19 119.8(6) . . ?
C17 C18 H18 120.1 . . ?
C19 C18 H18 120.1 . . ?
C14 C19 C18 120.5(6) . . ?
C14 C19 H19 119.7 . . ?
C18 C19 H19 119.7 . . ?
C21 C20 C25 118.4(5) . . ?
C21 C20 P1 120.5(4) . . ?
C25 C20 P1 120.3(4) . . ?
C22 C21 C20 122.1(7) . . ?
C22 C21 H21 119.0 . . ?
C20 C21 H21 119.0 . . ?
C23 C22 C21 118.1(7) . . ?
C23 C22 H22 120.9 . . ?
C21 C22 H22 120.9 . . ?
C24 C23 C22 121.2(6) . . ?
C24 C23 H23 119.4 . . ?
C22 C23 H23 119.4 . . ?
C23 C24 C25 120.6(7) . . ?
C23 C24 H24 119.7 . . ?
C25 C24 H24 119.7 . . ?
C20 C25 C24 119.6(6) . . ?
C20 C25 H25 120.2 . . ?
C24 C25 H25 120.2 . . ?
C27 C26 C31 119.8(5) . . ?
C27 C26 P2 121.1(5) . . ?
C31 C26 P2 119.1(5) . . ?
C26 C27 C28 119.7(7) . . ?
C26 C27 H27 120.2 . . ?
C28 C27 H27 120.2 . . ?
C29 C28 C27 121.1(8) . . ?
C29 C28 H28 119.4 . . ?
C27 C28 H28 119.4 . . ?
C30 C29 C28 118.8(6) . . ?
C30 C29 H29 120.6 . . ?
C28 C29 H29 120.6 . . ?
C29 C30 C31 120.5(7) . . ?
C29 C30 H30 119.7 . . ?
C31 C30 H30 119.7 . . ?
C26 C31 C30 119.9(7) . . ?
C26 C31 H31 120.0 . . ?
C30 C31 H31 120.0 . . ?
C37 C32 C33 120.1(6) . . ?
C37 C32 P2 118.7(5) . . ?
C33 C32 P2 121.2(5) . . ?
C34 C33 C32 120.0(8) . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C35 C34 C33 119.2(9) . . ?
C35 C34 H34 120.4 . . ?
C33 C34 H34 120.4 . . ?
C36 C35 C34 123.1(8) . . ?
C36 C35 H35 118.5 . . ?
C34 C35 H35 118.5 . . ?
C35 C36 C37 119.5(9) . . ?
C35 C36 H36 120.3 . . ?
C37 C36 H36 120.3 . . ?
C32 C37 C36 118.1(8) . . ?
C32 C37 H37 120.9 . . ?
C36 C37 H37 120.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag C9 2.251(6) . ?
Ag C1 2.331(6) 2_756 ?
Ag P1 2.4672(14) . ?
Ag P2 2.4921(15) . ?
P1 C20 1.816(5) . ?
P1 C14 1.824(5) . ?
P1 C13 1.842(5) . ?
P2 C32 1.812(6) . ?
P2 C26 1.827(5) . ?
P2 C13 1.831(6) 2_656 ?
Cl O2 1.334(9) . ?
Cl O1 1.362(10) . ?
Cl O4 1.387(8) . ?
Cl O3 1.404(10) . ?
N1 C1 1.133(7) . ?
N1 C2 1.474(7) . ?
N2 C9 1.142(8) . ?
N2 C8 1.459(7) . ?
C1 Ag 2.331(6) 2_756 ?
C2 C7 1.502(11) . ?
C2 C3 1.505(12) . ?
C2 C10 1.530(11) . ?
C3 C4 1.537(11) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 C5 1.537(8) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.529(9) . ?
C5 C8 1.555(9) . ?
C5 H5 0.9800 . ?
C6 C7 1.529(11) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 H7A 0.9700 . ?
C7 H7B 0.9700 . ?
C8 C11 1.530(10) . ?
C8 C12 1.538(11) . ?
C10 H10A 0.9600 . ?
C10 H10B 0.9600 . ?
C10 H10C 0.9600 . ?
C11 H11A 0.9600 . ?
C11 H11B 0.9600 . ?
C11 H11C 0.9600 . ?
C12 H12A 0.9600 . ?
C12 H12B 0.9600 . ?
C12 H12C 0.9600 . ?
C13 P2 1.831(6) 2_656 ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C14 C15 1.370(8) . ?
C14 C19 1.382(8) . ?
C15 C16 1.393(9) . ?
C15 H15 0.9300 . ?
C16 C17 1.376(11) . ?
C16 H16 0.9300 . ?
C17 C18 1.377(11) . ?
C17 H17 0.9300 . ?
C18 C19 1.386(9) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C20 C21 1.385(8) . ?
C20 C25 1.386(8) . ?
C21 C22 1.384(10) . ?
C21 H21 0.9300 . ?
C22 C23 1.383(12) . ?
C22 H22 0.9300 . ?
C23 C24 1.353(12) . ?
C23 H23 0.9300 . ?
C24 C25 1.399(9) . ?
C24 H24 0.9300 . ?
C25 H25 0.9300 . ?
C26 C27 1.372(9) . ?
C26 C31 1.387(8) . ?
C27 C28 1.393(10) . ?
C27 H27 0.9300 . ?
C28 C29 1.388(14) . ?
C28 H28 0.9300 . ?
C29 C30 1.373(14) . ?
C29 H29 0.9300 . ?
C30 C31 1.400(9) . ?
C30 H30 0.9300 . ?
C31 H31 0.9300 . ?
C32 C37 1.376(9) . ?
C32 C33 1.416(9) . ?
C33 C34 1.372(11) . ?
C33 H33 0.9300 . ?
C34 C35 1.356(15) . ?
C34 H34 0.9300 . ?
C35 C36 1.348(16) . ?
C35 H35 0.9300 . ?
C36 C37 1.429(12) . ?
C36 H36 0.9300 . ?
C37 H37 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C9 Ag P1 C20 149.6(3) . . . . ?
C1 Ag P1 C20 45.0(3) 2_756 . . . ?
P2 Ag P1 C20 -66.49(19) . . . . ?
C9 Ag P1 C14 34.8(3) . . . . ?
C1 Ag P1 C14 -69.8(2) 2_756 . . . ?
P2 Ag P1 C14 178.68(18) . . . . ?
C9 Ag P1 C13 -91.3(3) . . . . ?
C1 Ag P1 C13 164.1(3) 2_756 . . . ?
P2 Ag P1 C13 52.6(2) . . . . ?
C9 Ag P2 C32 166.6(3) . . . . ?
C1 Ag P2 C32 -92.9(3) 2_756 . . . ?
P1 Ag P2 C32 18.1(2) . . . . ?
C9 Ag P2 C26 -73.1(3) . . . . ?
C1 Ag P2 C26 27.4(3) 2_756 . . . ?
P1 Ag P2 C26 138.4(2) . . . . ?
C9 Ag P2 C13 39.7(2) . . . 2_656 ?
C1 Ag P2 C13 140.2(2) 2_756 . . 2_656 ?
P1 Ag P2 C13 -108.77(17) . . . 2_656 ?
C2 N1 C1 Ag 72(18) . . . 2_756 ?
C1 N1 C2 C7 9(16) . . . . ?
C1 N1 C2 C3 129(16) . . . . ?
C1 N1 C2 C10 -112(16) . . . . ?
N1 C2 C3 C4 -64.8(7) . . . . ?
C7 C2 C3 C4 52.4(8) . . . . ?
C10 C2 C3 C4 179.2(6) . . . . ?
C2 C3 C4 C5 -53.9(8) . . . . ?
C3 C4 C5 C6 55.3(7) . . . . ?
C3 C4 C5 C8 -177.3(5) . . . . ?
C4 C5 C6 C7 -56.1(7) . . . . ?
C8 C5 C6 C7 179.1(5) . . . . ?
N1 C2 C7 C6 64.6(8) . . . . ?
C3 C2 C7 C6 -53.3(8) . . . . ?
C10 C2 C7 C6 -179.0(6) . . . . ?
C5 C6 C7 C2 55.7(7) . . . . ?
C9 N2 C8 C11 29(6) . . . . ?
C9 N2 C8 C12 -90(6) . . . . ?
C9 N2 C8 C5 152(6) . . . . ?
C6 C5 C8 N2 -47.0(7) . . . . ?
C4 C5 C8 N2 -171.9(5) . . . . ?
C6 C5 C8 C11 71.1(7) . . . . ?
C4 C5 C8 C11 -53.8(7) . . . . ?
C6 C5 C8 C12 -161.8(5) . . . . ?
C4 C5 C8 C12 73.3(6) . . . . ?
C8 N2 C9 Ag -8(8) . . . . ?
C1 Ag C9 N2 -42(2) 2_756 . . . ?
P1 Ag C9 N2 -145(2) . . . . ?
P2 Ag C9 N2 59(2) . . . . ?
C20 P1 C13 P2 152.1(3) . . . 2_656 ?
C14 P1 C13 P2 -98.6(3) . . . 2_656 ?
Ag P1 C13 P2 32.9(3) . . . 2_656 ?
C20 P1 C14 C15 -124.5(5) . . . . ?
C13 P1 C14 C15 125.8(5) . . . . ?
Ag P1 C14 C15 -9.3(5) . . . . ?
C20 P1 C14 C19 59.3(5) . . . . ?
C13 P1 C14 C19 -50.4(5) . . . . ?
Ag P1 C14 C19 174.5(4) . . . . ?
C19 C14 C15 C16 1.2(9) . . . . ?
P1 C14 C15 C16 -175.1(5) . . . . ?
C14 C15 C16 C17 0.6(10) . . . . ?
C15 C16 C17 C18 -2.0(11) . . . . ?
C16 C17 C18 C19 1.6(11) . . . . ?
C15 C14 C19 C18 -1.7(9) . . . . ?
P1 C14 C19 C18 174.6(5) . . . . ?
C17 C18 C19 C14 0.3(10) . . . . ?
C14 P1 C20 C21 -158.0(5) . . . . ?
C13 P1 C20 C21 -49.8(5) . . . . ?
Ag P1 C20 C21 79.8(5) . . . . ?
C14 P1 C20 C25 32.3(5) . . . . ?
C13 P1 C20 C25 140.5(5) . . . . ?
Ag P1 C20 C25 -89.8(4) . . . . ?
C25 C20 C21 C22 0.4(9) . . . . ?
P1 C20 C21 C22 -169.4(5) . . . . ?
C20 C21 C22 C23 -0.7(11) . . . . ?
C21 C22 C23 C24 1.1(11) . . . . ?
C22 C23 C24 C25 -1.3(12) . . . . ?
C21 C20 C25 C24 -0.5(9) . . . . ?
P1 C20 C25 C24 169.3(5) . . . . ?
C23 C24 C25 C20 0.9(11) . . . . ?
C32 P2 C26 C27 -147.7(6) . . . . ?
C13 P2 C26 C27 -38.8(6) 2_656 . . . ?
Ag P2 C26 C27 79.4(6) . . . . ?
C32 P2 C26 C31 34.6(6) . . . . ?
C13 P2 C26 C31 143.6(5) 2_656 . . . ?
Ag P2 C26 C31 -98.2(5) . . . . ?
C31 C26 C27 C28 4.6(11) . . . . ?
P2 C26 C27 C28 -173.1(6) . . . . ?
C26 C27 C28 C29 -2.2(13) . . . . ?
C27 C28 C29 C30 -1.1(14) . . . . ?
C28 C29 C30 C31 2.0(13) . . . . ?
C27 C26 C31 C30 -3.7(10) . . . . ?
P2 C26 C31 C30 174.0(6) . . . . ?
C29 C30 C31 C26 0.4(12) . . . . ?
C26 P2 C32 C37 -120.9(5) . . . . ?
C13 P2 C32 C37 131.1(5) 2_656 . . . ?
Ag P2 C32 C37 1.3(6) . . . . ?
C26 P2 C32 C33 57.1(5) . . . . ?
C13 P2 C32 C33 -50.9(5) 2_656 . . . ?
Ag P2 C32 C33 179.3(4) . . . . ?
C37 C32 C33 C34 -2.4(9) . . . . ?
P2 C32 C33 C34 179.6(5) . . . . ?
C32 C33 C34 C35 0.5(10) . . . . ?
C33 C34 C35 C36 1.2(12) . . . . ?
C34 C35 C36 C37 -0.9(13) . . . . ?
C33 C32 C37 C36 2.6(10) . . . . ?
P2 C32 C37 C36 -179.4(5) . . . . ?
C35 C36 C37 C32 -1.0(12) . . . . ?
