#------------------------------------------------------------------------------
#$Date: 2016-03-23 01:43:06 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179152 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/13/4311353.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4311353
loop_
_publ_author_name
'Cristina Tejel'
'Miguel A. Ciriano'
'Gustavo Ríos-Moreno'
'Isabel T. Dobrinovitch'
'Fernando J. Lahoz'
'Luis A. Oro'
'Miguel Parra-Hake'
_publ_contact_author_address
;
  Dr. Fernando J. Lahoz
  Departamento de Química Inorgánica - I.C.M.A.
  Facultad de Ciencias
  Universidad de Zaragoza - C.S.I.C.
  50009 Zaragoza, Spain
;
_publ_contact_author_email       lahoz@posta.unizar.es
_publ_contact_author_fax         '+34 976 761187'
_publ_contact_author_name        'Dr. Fernando J. Lahoz'
_publ_contact_author_phone       '+34 976 761147'
_publ_section_title
;
 Crescent-Shaped Rhodium(I) Complexes with
 Bis(o-carboxymethylphenyl)triazenide
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4719
_journal_page_last               4726
_journal_paper_doi               10.1021/ic049691g
_journal_volume                  43
_journal_year                    2004
_chemical_formula_moiety         'C21 H14 Cl2 N3 O9 Rh3'
_chemical_formula_sum            'C21 H14 Cl2 N3 O9 Rh3'
_chemical_formula_weight         831.98
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.9420(10)
_cell_angle_beta                 92.9820(10)
_cell_angle_gamma                108.7770(10)
_cell_formula_units_Z            2
_cell_length_a                   9.5760(6)
_cell_length_b                   9.7734(6)
_cell_length_c                   14.6622(9)
_cell_measurement_reflns_used    4971
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.97
_cell_measurement_theta_min      2.25
_cell_volume                     1289.74(14)
_computing_cell_refinement       'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_data_collection       'SMART v. 5.611 (Bruker AXS, 2000)'
_computing_data_reduction        'SAINT+ v. 6.01 (Bruker AXS, 2000)'
_computing_molecular_graphics    'XP program, SHELXTL v6.10, Bruker2000'
_computing_publication_material  'XCIF program, SHELXTLv6.10, BrukerAXS'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.26
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.909
_diffrn_measurement_device_type  'Bruker SMART APEX CCD system'
_diffrn_measurement_method       'ω rotations with narrow frames'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0301
_diffrn_reflns_av_sigmaI/netI    0.0552
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            15845
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.59
_diffrn_reflns_theta_min         1.40
_diffrn_standards_decay_%        'no decay'
_exptl_absorpt_coefficient_mu    2.160
_exptl_absorpt_correction_T_max  0.7893
_exptl_absorpt_correction_T_min  0.7077
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
; 
 SADABS: Area-Detector Absorption Correction. (1996)  Bruker-AXS 
 within SAINT+ package, v. 6.01.           
;
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    2.142
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'irregular block'
_exptl_crystal_F_000             804
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.022
_refine_diff_density_min         -0.681
_refine_diff_density_rms         0.117
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.973
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     357
_refine_ls_number_reflns         5997
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.973
_refine_ls_R_factor_all          0.0383
_refine_ls_R_factor_gt           0.0303
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0150P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0548
_refine_ls_wR_factor_ref         0.0561
_reflns_number_gt                4941
_reflns_number_total             5997
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic049691gsi20040310_075146_2.cif
_cod_data_source_block           compound5
_cod_database_code               4311353
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.27580(3) 0.24760(3) 0.178570(18) 0.01583(7) Uani 1 1 d . . .
Rh2 Rh 0.34789(3) 0.25651(3) 0.349720(18) 0.01510(7) Uani 1 1 d . . .
Rh3 Rh 0.31553(3) 0.55386(3) 0.26564(2) 0.01963(8) Uani 1 1 d . . .
Cl1 Cl 0.35296(9) 0.50589(9) 0.41960(6) 0.01714(19) Uani 1 1 d . . .
Cl2 Cl 0.57211(10) 0.63577(10) 0.25617(7) 0.0268(2) Uani 1 1 d . . .
O1 O 0.1911(3) 0.2789(3) 0.04914(15) 0.0207(6) Uani 1 1 d . . .
O2 O 0.0291(3) 0.2714(3) -0.06540(16) 0.0272(6) Uani 1 1 d . . .
O3 O 0.3682(2) 0.1746(2) 0.48116(15) 0.0175(5) Uani 1 1 d . . .
O4 O 0.2837(3) 0.0681(3) 0.60367(15) 0.0198(6) Uani 1 1 d . . .
O5 O 0.3270(3) -0.0170(3) 0.23361(16) 0.0232(6) Uani 1 1 d . . .
O6 O 0.5838(3) 0.3328(3) 0.12018(18) 0.0306(7) Uani 1 1 d . . .
O7 O 0.6797(3) 0.3591(3) 0.34625(17) 0.0298(7) Uani 1 1 d . . .
O8 O 0.2896(3) 0.6485(3) 0.07988(19) 0.0431(8) Uani 1 1 d . . .
O9 O -0.0114(3) 0.4632(3) 0.27248(18) 0.0317(7) Uani 1 1 d . . .
N1 N 0.0614(3) 0.1667(3) 0.21135(18) 0.0146(6) Uani 1 1 d . . .
N2 N 0.0206(3) 0.1596(3) 0.29544(19) 0.0158(6) Uani 1 1 d . . .
N3 N 0.1254(3) 0.1958(3) 0.36130(19) 0.0157(6) Uani 1 1 d . . .
C1 C 0.0622(4) 0.2341(4) 0.0160(2) 0.0202(8) Uani 1 1 d . . .
C2 C 0.1528(4) 0.3613(5) -0.1105(3) 0.0353(11) Uani 1 1 d . . .
H2A H 0.1879 0.4523 -0.0711 0.012(10) Uiso 1 1 d R . .
H2B H 0.1168 0.3719 -0.1715 0.068(15) Uiso 1 1 d R . .
H2C H 0.2208 0.3032 -0.1133 0.054(15) Uiso 1 1 d R . .
C3 C -0.0658(4) 0.1379(4) 0.0550(2) 0.0182(8) Uani 1 1 d . . .
C4 C -0.1960(4) 0.0760(4) -0.0039(2) 0.0203(8) Uani 1 1 d . . .
H4 H -0.1952 0.1011 -0.0708 0.022(10) Uiso 1 1 d R . .
C5 C -0.3218(4) -0.0160(4) 0.0265(2) 0.0219(8) Uani 1 1 d . . .
H5 H -0.4065 -0.0512 -0.0156 0.026(10) Uiso 1 1 d R . .
C6 C -0.3213(4) -0.0498(4) 0.1157(2) 0.0247(9) Uani 1 1 d . . .
H6 H -0.4082 -0.1145 0.1448 0.019(9) Uiso 1 1 d R . .
C7 C -0.1948(4) 0.0089(4) 0.1751(2) 0.0205(8) Uani 1 1 d . . .
H7 H -0.2207 -0.0317 0.2377 0.043(12) Uiso 1 1 d R . .
C8 C -0.0651(4) 0.1052(4) 0.1474(2) 0.0163(8) Uani 1 1 d . . .
C9 C 0.0660(4) 0.2059(4) 0.4486(2) 0.0157(8) Uani 1 1 d . . .
C10 C -0.0605(4) 0.2449(4) 0.4533(2) 0.0214(8) Uani 1 1 d . . .
H10 H -0.0996 0.2739 0.4016 0.014(9) Uiso 1 1 d R . .
C11 C -0.1279(4) 0.2462(4) 0.5341(2) 0.0224(9) Uani 1 1 d . . .
H11 H -0.2157 0.2717 0.5347 0.014(9) Uiso 1 1 d R . .
C12 C -0.0681(4) 0.2104(4) 0.6126(2) 0.0215(8) Uani 1 1 d . . .
H12 H -0.1161 0.2006 0.6681 0.019(10) Uiso 1 1 d R . .
C13 C 0.0606(4) 0.1779(4) 0.6101(2) 0.0194(8) Uani 1 1 d . . .
H13 H 0.0993 0.1443 0.6600 0.015(9) Uiso 1 1 d R . .
C14 C 0.1311(4) 0.1751(4) 0.5291(2) 0.0154(8) Uani 1 1 d . . .
C15 C 0.2697(4) 0.1396(4) 0.5337(2) 0.0180(8) Uani 1 1 d . . .
C16 C 0.4206(4) 0.0390(4) 0.6172(2) 0.0257(9) Uani 1 1 d . . .
H16A H 0.4230 -0.0398 0.5740 0.025(11) Uiso 1 1 d R . .
H16B H 0.4170 -0.0076 0.6748 0.030(11) Uiso 1 1 d R . .
H16C H 0.4965 0.1266 0.6225 0.025(11) Uiso 1 1 d R . .
C17 C 0.3219(4) 0.0998(4) 0.2516(2) 0.0191(8) Uani 1 1 d . . .
C18 C 0.4686(4) 0.3076(4) 0.1442(2) 0.0203(8) Uani 1 1 d . . .
C19 C 0.5550(4) 0.3204(4) 0.3456(2) 0.0201(8) Uani 1 1 d . . .
C20 C 0.2976(4) 0.6112(4) 0.1509(3) 0.0277(9) Uani 1 1 d . . .
C21 C 0.1148(4) 0.4976(4) 0.2711(2) 0.0239(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C18 Rh1 C17 90.06(14) . . ?
C18 Rh1 N1 175.75(14) . . ?
C17 Rh1 N1 88.00(12) . . ?
C18 Rh1 O1 91.76(12) . . ?
C17 Rh1 O1 143.80(12) . . ?
N1 Rh1 O1 87.58(10) . . ?
C18 Rh1 Rh2 95.64(11) . . ?
C17 Rh1 Rh2 48.88(10) . . ?
N1 Rh1 Rh2 85.93(7) . . ?
O1 Rh1 Rh2 165.51(7) . . ?
C18 Rh1 Rh3 90.85(11) . . ?
C17 Rh1 Rh3 121.46(10) . . ?
N1 Rh1 Rh3 93.39(8) . . ?
O1 Rh1 Rh3 94.67(7) . . ?
Rh2 Rh1 Rh3 72.829(11) . . ?
C19 Rh2 C17 91.83(15) . . ?
C19 Rh2 N3 176.52(14) . . ?
C17 Rh2 N3 91.61(13) . . ?
C19 Rh2 O3 90.92(12) . . ?
C17 Rh2 O3 108.80(12) . . ?
N3 Rh2 O3 87.44(10) . . ?
C19 Rh2 Cl1 91.88(11) . . ?
C17 Rh2 Cl1 156.10(10) . . ?
N3 Rh2 Cl1 85.19(8) . . ?
O3 Rh2 Cl1 94.74(6) . . ?
C19 Rh2 Rh1 98.18(10) . . ?
C17 Rh2 Rh1 50.98(10) . . ?
N3 Rh2 Rh1 84.43(8) . . ?
O3 Rh2 Rh1 157.78(6) . . ?
Cl1 Rh2 Rh1 105.12(2) . . ?
C21 Rh3 C20 90.83(16) . . ?
C21 Rh3 Cl2 177.39(11) . . ?
C20 Rh3 Cl2 87.36(12) . . ?
C21 Rh3 Cl1 91.86(11) . . ?
C20 Rh3 Cl1 173.92(12) . . ?
Cl2 Rh3 Cl1 89.76(3) . . ?
C21 Rh3 Rh1 88.06(12) . . ?
C20 Rh3 Rh1 89.77(12) . . ?
Cl2 Rh3 Rh1 93.82(3) . . ?
Cl1 Rh3 Rh1 95.76(2) . . ?
Rh3 Cl1 Rh2 85.67(3) . . ?
C1 O1 Rh1 128.0(2) . . ?
C1 O2 C2 116.3(3) . . ?
C15 O3 Rh2 125.4(2) . . ?
C15 O4 C16 116.8(3) . . ?
N2 N1 C8 109.6(3) . . ?
N2 N1 Rh1 124.7(2) . . ?
C8 N1 Rh1 125.6(2) . . ?
N3 N2 N1 116.7(3) . . ?
N2 N3 C9 110.4(3) . . ?
N2 N3 Rh2 127.5(2) . . ?
C9 N3 Rh2 121.7(2) . . ?
O1 C1 O2 119.3(3) . . ?
O1 C1 C3 127.4(3) . . ?
O2 C1 C3 113.4(3) . . ?
O2 C2 H2A 104.2 . . ?
O2 C2 H2B 108.5 . . ?
H2A C2 H2B 112.9 . . ?
O2 C2 H2C 103.1 . . ?
H2A C2 H2C 116.1 . . ?
H2B C2 H2C 111.1 . . ?
C4 C3 C8 119.3(3) . . ?
C4 C3 C1 116.8(3) . . ?
C8 C3 C1 123.9(3) . . ?
C5 C4 C3 121.1(3) . . ?
C5 C4 H4 120.4 . . ?
C3 C4 H4 118.5 . . ?
C4 C5 C6 119.9(3) . . ?
C4 C5 H5 117.1 . . ?
C6 C5 H5 123.0 . . ?
C5 C6 C7 120.3(3) . . ?
C5 C6 H6 125.9 . . ?
C7 C6 H6 113.8 . . ?
C6 C7 C8 121.6(3) . . ?
C6 C7 H7 106.5 . . ?
C8 C7 H7 131.9 . . ?
C7 C8 C3 117.8(3) . . ?
C7 C8 N1 119.9(3) . . ?
C3 C8 N1 122.3(3) . . ?
C10 C9 C14 119.1(3) . . ?
C10 C9 N3 119.0(3) . . ?
C14 C9 N3 121.9(3) . . ?
C11 C10 C9 121.2(3) . . ?
C11 C10 H10 119.0 . . ?
C9 C10 H10 119.8 . . ?
C12 C11 C10 120.1(3) . . ?
C12 C11 H11 120.9 . . ?
C10 C11 H11 119.0 . . ?
C13 C12 C11 119.5(3) . . ?
C13 C12 H12 117.7 . . ?
C11 C12 H12 122.7 . . ?
C12 C13 C14 121.8(3) . . ?
C12 C13 H13 121.9 . . ?
C14 C13 H13 115.8 . . ?
C13 C14 C9 118.3(3) . . ?
C13 C14 C15 117.6(3) . . ?
C9 C14 C15 124.1(3) . . ?
O3 C15 O4 120.7(3) . . ?
O3 C15 C14 126.0(3) . . ?
O4 C15 C14 113.3(3) . . ?
O4 C16 H16A 110.8 . . ?
O4 C16 H16B 106.9 . . ?
H16A C16 H16B 99.8 . . ?
O4 C16 H16C 107.8 . . ?
H16A C16 H16C 119.9 . . ?
H16B C16 H16C 110.8 . . ?
O5 C17 Rh2 145.3(3) . . ?
O5 C17 Rh1 134.5(3) . . ?
Rh2 C17 Rh1 80.14(14) . . ?
O6 C18 Rh1 174.4(3) . . ?
O7 C19 Rh2 177.6(3) . . ?
O8 C20 Rh3 178.5(4) . . ?
O9 C21 Rh3 178.3(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C18 1.860(4) . ?
Rh1 C17 2.014(4) . ?
Rh1 N1 2.048(3) . ?
Rh1 O1 2.110(2) . ?
Rh1 Rh2 2.5544(4) . ?
Rh1 Rh3 3.0482(4) . ?
Rh2 C19 1.883(4) . ?
Rh2 C17 1.953(4) . ?
Rh2 N3 2.040(3) . ?
Rh2 O3 2.173(2) . ?
Rh2 Cl1 2.5458(9) . ?
Rh3 C21 1.829(4) . ?
Rh3 C20 1.836(4) . ?
Rh3 Cl2 2.3421(10) . ?
Rh3 Cl1 2.3772(9) . ?
O1 C1 1.226(4) . ?
O2 C1 1.330(4) . ?
O2 C2 1.457(4) . ?
O3 C15 1.231(4) . ?
O4 C15 1.315(4) . ?
O4 C16 1.436(4) . ?
O5 C17 1.166(4) . ?
O6 C18 1.132(4) . ?
O7 C19 1.131(4) . ?
O8 C20 1.139(4) . ?
O9 C21 1.147(4) . ?
N1 N2 1.313(3) . ?
N1 C8 1.423(4) . ?
N2 N3 1.294(4) . ?
N3 C9 1.435(4) . ?
C1 C3 1.462(5) . ?
C2 H2A 0.9676 . ?
C2 H2B 0.9682 . ?
C2 H2C 0.9921 . ?
C3 C4 1.407(5) . ?
C3 C8 1.418(4) . ?
C4 C5 1.373(5) . ?
C4 H4 1.0315 . ?
C5 C6 1.377(5) . ?
C5 H5 0.9428 . ?
C6 C7 1.382(5) . ?
C6 H6 1.0094 . ?
C7 C8 1.399(5) . ?
C7 H7 1.0421 . ?
C9 C10 1.385(5) . ?
C9 C14 1.407(4) . ?
C10 C11 1.380(5) . ?
C10 H10 0.9327 . ?
C11 C12 1.380(5) . ?
C11 H11 0.9511 . ?
C12 C13 1.370(5) . ?
C12 H12 0.9515 . ?
C13 C14 1.399(4) . ?
C13 H13 0.9331 . ?
C14 C15 1.475(5) . ?
C16 H16A 0.9610 . ?
C16 H16B 0.9906 . ?
C16 H16C 0.9219 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C18 Rh1 Rh2 C19 0.57(15) . . . . ?
C17 Rh1 Rh2 C19 85.70(17) . . . . ?
N1 Rh1 Rh2 C19 176.60(13) . . . . ?
O1 Rh1 Rh2 C19 -119.8(3) . . . . ?
Rh3 Rh1 Rh2 C19 -88.58(11) . . . . ?
C18 Rh1 Rh2 C17 -85.13(17) . . . . ?
N1 Rh1 Rh2 C17 90.90(15) . . . . ?
O1 Rh1 Rh2 C17 154.5(3) . . . . ?
Rh3 Rh1 Rh2 C17 -174.28(13) . . . . ?
C18 Rh1 Rh2 N3 178.24(14) . . . . ?
C17 Rh1 Rh2 N3 -96.62(15) . . . . ?
N1 Rh1 Rh2 N3 -5.72(11) . . . . ?
O1 Rh1 Rh2 N3 57.9(3) . . . . ?
Rh3 Rh1 Rh2 N3 89.09(8) . . . . ?
C18 Rh1 Rh2 O3 -112.7(2) . . . . ?
C17 Rh1 Rh2 O3 -27.5(2) . . . . ?
N1 Rh1 Rh2 O3 63.35(18) . . . . ?
O1 Rh1 Rh2 O3 127.0(3) . . . . ?
Rh3 Rh1 Rh2 O3 158.17(16) . . . . ?
C18 Rh1 Rh2 Cl1 94.76(11) . . . . ?
C17 Rh1 Rh2 Cl1 179.90(13) . . . . ?
N1 Rh1 Rh2 Cl1 -89.20(8) . . . . ?
O1 Rh1 Rh2 Cl1 -25.6(3) . . . . ?
Rh3 Rh1 Rh2 Cl1 5.61(2) . . . . ?
C18 Rh1 Rh3 C21 166.86(15) . . . . ?
C17 Rh1 Rh3 C21 -102.55(16) . . . . ?
N1 Rh1 Rh3 C21 -12.83(13) . . . . ?
O1 Rh1 Rh3 C21 75.01(13) . . . . ?
Rh2 Rh1 Rh3 C21 -97.51(11) . . . . ?
C18 Rh1 Rh3 C20 76.02(16) . . . . ?
C17 Rh1 Rh3 C20 166.61(17) . . . . ?
N1 Rh1 Rh3 C20 -103.67(14) . . . . ?
O1 Rh1 Rh3 C20 -15.83(14) . . . . ?
Rh2 Rh1 Rh3 C20 171.65(12) . . . . ?
C18 Rh1 Rh3 Cl2 -11.33(11) . . . . ?
C17 Rh1 Rh3 Cl2 79.26(12) . . . . ?
N1 Rh1 Rh3 Cl2 168.99(8) . . . . ?
O1 Rh1 Rh3 Cl2 -103.17(7) . . . . ?
Rh2 Rh1 Rh3 Cl2 84.31(3) . . . . ?
C18 Rh1 Rh3 Cl1 -101.47(11) . . . . ?
C17 Rh1 Rh3 Cl1 -10.88(12) . . . . ?
N1 Rh1 Rh3 Cl1 78.85(8) . . . . ?
O1 Rh1 Rh3 Cl1 166.69(7) . . . . ?
Rh2 Rh1 Rh3 Cl1 -5.83(2) . . . . ?
C21 Rh3 Cl1 Rh2 93.84(12) . . . . ?
Cl2 Rh3 Cl1 Rh2 -88.21(3) . . . . ?
Rh1 Rh3 Cl1 Rh2 5.61(2) . . . . ?
C19 Rh2 Cl1 Rh3 92.09(10) . . . . ?
C17 Rh2 Cl1 Rh3 -6.7(3) . . . . ?
N3 Rh2 Cl1 Rh3 -89.80(8) . . . . ?
O3 Rh2 Cl1 Rh3 -176.83(6) . . . . ?
Rh1 Rh2 Cl1 Rh3 -6.90(3) . . . . ?
C18 Rh1 O1 C1 165.1(3) . . . . ?
C17 Rh1 O1 C1 72.6(4) . . . . ?
N1 Rh1 O1 C1 -10.7(3) . . . . ?
Rh2 Rh1 O1 C1 -74.1(4) . . . . ?
Rh3 Rh1 O1 C1 -103.9(3) . . . . ?
C19 Rh2 O3 C15 165.4(3) . . . . ?
C17 Rh2 O3 C15 -102.3(3) . . . . ?
N3 Rh2 O3 C15 -11.5(3) . . . . ?
Cl1 Rh2 O3 C15 73.5(3) . . . . ?
Rh1 Rh2 O3 C15 -80.0(3) . . . . ?
C17 Rh1 N1 N2 57.2(3) . . . . ?
O1 Rh1 N1 N2 -158.8(3) . . . . ?
Rh2 Rh1 N1 N2 8.3(2) . . . . ?
Rh3 Rh1 N1 N2 -64.2(2) . . . . ?
C17 Rh1 N1 C8 -120.4(3) . . . . ?
O1 Rh1 N1 C8 23.6(3) . . . . ?
Rh2 Rh1 N1 C8 -169.3(3) . . . . ?
Rh3 Rh1 N1 C8 118.2(3) . . . . ?
C8 N1 N2 N3 172.1(3) . . . . ?
Rh1 N1 N2 N3 -5.8(4) . . . . ?
N1 N2 N3 C9 170.5(3) . . . . ?
N1 N2 N3 Rh2 -2.3(4) . . . . ?
C17 Rh2 N3 N2 -44.0(3) . . . . ?
O3 Rh2 N3 N2 -152.8(3) . . . . ?
Cl1 Rh2 N3 N2 112.2(3) . . . . ?
Rh1 Rh2 N3 N2 6.5(3) . . . . ?
C17 Rh2 N3 C9 143.9(3) . . . . ?
O3 Rh2 N3 C9 35.2(2) . . . . ?
Cl1 Rh2 N3 C9 -59.8(2) . . . . ?
Rh1 Rh2 N3 C9 -165.5(2) . . . . ?
Rh1 O1 C1 O2 176.7(2) . . . . ?
Rh1 O1 C1 C3 -4.8(5) . . . . ?
C2 O2 C1 O1 1.7(5) . . . . ?
C2 O2 C1 C3 -177.0(3) . . . . ?
O1 C1 C3 C4 -166.5(4) . . . . ?
O2 C1 C3 C4 12.0(5) . . . . ?
O1 C1 C3 C8 13.8(6) . . . . ?
O2 C1 C3 C8 -167.7(3) . . . . ?
C8 C3 C4 C5 -0.5(5) . . . . ?
C1 C3 C4 C5 179.8(3) . . . . ?
C3 C4 C5 C6 -0.4(6) . . . . ?
C4 C5 C6 C7 0.2(6) . . . . ?
C5 C6 C7 C8 1.0(6) . . . . ?
C6 C7 C8 C3 -1.9(5) . . . . ?
C6 C7 C8 N1 178.1(3) . . . . ?
C4 C3 C8 C7 1.6(5) . . . . ?
C1 C3 C8 C7 -178.8(3) . . . . ?
C4 C3 C8 N1 -178.4(3) . . . . ?
C1 C3 C8 N1 1.3(5) . . . . ?
N2 N1 C8 C7 -20.9(4) . . . . ?
Rh1 N1 C8 C7 157.0(3) . . . . ?
N2 N1 C8 C3 159.1(3) . . . . ?
Rh1 N1 C8 C3 -23.0(5) . . . . ?
N2 N3 C9 C10 -29.6(4) . . . . ?
Rh2 N3 C9 C10 143.6(3) . . . . ?
N2 N3 C9 C14 149.3(3) . . . . ?
Rh2 N3 C9 C14 -37.4(4) . . . . ?
C14 C9 C10 C11 -3.6(5) . . . . ?
N3 C9 C10 C11 175.4(3) . . . . ?
C9 C10 C11 C12 1.0(6) . . . . ?
C10 C11 C12 C13 1.9(5) . . . . ?
C11 C12 C13 C14 -2.2(5) . . . . ?
C12 C13 C14 C9 -0.4(5) . . . . ?
C12 C13 C14 C15 179.7(3) . . . . ?
C10 C9 C14 C13 3.3(5) . . . . ?
N3 C9 C14 C13 -175.7(3) . . . . ?
C10 C9 C14 C15 -176.8(3) . . . . ?
N3 C9 C14 C15 4.2(5) . . . . ?
Rh2 O3 C15 O4 168.1(2) . . . . ?
Rh2 O3 C15 C14 -14.3(5) . . . . ?
C16 O4 C15 O3 2.5(5) . . . . ?
C16 O4 C15 C14 -175.4(3) . . . . ?
C13 C14 C15 O3 -155.9(3) . . . . ?
C9 C14 C15 O3 24.2(6) . . . . ?
C13 C14 C15 O4 21.9(4) . . . . ?
C9 C14 C15 O4 -158.0(3) . . . . ?
C19 Rh2 C17 O5 80.2(5) . . . . ?
N3 Rh2 C17 O5 -99.2(5) . . . . ?
O3 Rh2 C17 O5 -11.4(5) . . . . ?
Cl1 Rh2 C17 O5 179.0(3) . . . . ?
Rh1 Rh2 C17 O5 179.3(6) . . . . ?
C19 Rh2 C17 Rh1 -99.05(13) . . . . ?
N3 Rh2 C17 Rh1 81.50(11) . . . . ?
O3 Rh2 C17 Rh1 169.35(8) . . . . ?
Cl1 Rh2 C17 Rh1 -0.2(3) . . . . ?
C18 Rh1 C17 O5 -82.0(4) . . . . ?
N1 Rh1 C17 O5 94.2(4) . . . . ?
O1 Rh1 C17 O5 11.1(5) . . . . ?
Rh2 Rh1 C17 O5 -179.4(5) . . . . ?
Rh3 Rh1 C17 O5 -173.0(3) . . . . ?
C18 Rh1 C17 Rh2 97.44(14) . . . . ?
N1 Rh1 C17 Rh2 -86.34(12) . . . . ?
O1 Rh1 C17 Rh2 -169.49(12) . . . . ?
Rh3 Rh1 C17 Rh2 6.40(14) . . . . ?
