#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/31/14/4311465.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4311465
loop_
_publ_author_name
'Karl M. Kadish'
'Tuan D. Phan'
'Li-Lun Wang'
'Lingamallu Giribabu'
'Antoine Thuriere'
'Julien Wellhoff'
'Shurong Huang'
'Eric Van Caemelbecke'
'John L. Bear'
_publ_section_title
;
 Synthesis, Structural, Spectroscopic, and Electrochemical
 Characterization of High Oxidation State Diruthenium Complexes Containing
 Four Identical Unsymmetrical Bridging Ligands
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              4825
_journal_page_last               4832
_journal_paper_doi               10.1021/ic0499594
_journal_volume                  43
_journal_year                    2004
_chemical_formula_sum            'C60 H34 F12 N8 Ru2'
_chemical_formula_weight         1297.09
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 101.145(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.0146(5)
_cell_length_b                   19.7799(9)
_cell_length_c                   24.1941(11)
_cell_measurement_reflns_used    6241
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      25.01
_cell_measurement_theta_min      1.88
_cell_volume                     5171.7(4)
_computing_cell_refinement       'Bruker SAINT software (Bruker, 1999)'
_computing_data_collection       'Siemens SMART software (Siemens, 1996)'
_computing_data_reduction        'Bruker SAINT software (Bruker, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      223(2)
_diffrn_detector_area_resol_mean 1K
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Siemens SMART CCD'
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0235
_diffrn_reflns_av_sigmaI/netI    0.0126
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            27194
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.88
_diffrn_standards_decay_%        0.0
_exptl_absorpt_coefficient_mu    0.678
_exptl_absorpt_correction_T_max  0.8585
_exptl_absorpt_correction_T_min  0.7691
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            'Extremely dark blue'
_exptl_crystal_density_diffrn    1.666
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2584
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.327
_refine_diff_density_min         -0.316
_refine_diff_density_rms         0.046
_refine_ls_extinction_coef       0.00030(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     740
_refine_ls_number_reflns         9084
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0276
_refine_ls_R_factor_gt           0.0204
_refine_ls_shift/su_max          0.015
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0274P)²+3.4079P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0523
_refine_ls_wR_factor_ref         0.0571
_reflns_number_gt                7637
_reflns_number_total             9372
_reflns_threshold_expression     >4sigma(I)
_cod_data_source_file            ic0499594si20040106_022128.cif
_cod_data_source_block           k636
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Empirical' changed to
'empirical' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_formula_sum        'C60 H34 N8 F12 Ru2'
_cod_database_code               4311465
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.879380(14) 0.351529(8) 0.650937(7) 0.02594(5) Uani 1 1 d . . .
Ru2 Ru 0.697571(14) 0.298824(8) 0.591121(6) 0.02343(5) Uani 1 1 d . . .
F1 F 0.86229(14) 0.32473(9) 0.45616(6) 0.0565(4) Uani 1 1 d . . .
F2 F 0.5250(2) 0.36442(11) 0.30975(6) 0.0838(6) Uani 1 1 d . . .
F3 F 0.50727(14) 0.43116(7) 0.49333(6) 0.0531(4) Uani 1 1 d . . .
F4 F 0.87056(13) 0.11691(7) 0.62255(5) 0.0472(3) Uani 1 1 d . . .
F5 F 0.6517(2) -0.02049(8) 0.48015(8) 0.0825(6) Uani 1 1 d . . .
F6 F 0.67890(14) 0.21147(7) 0.45035(5) 0.0480(3) Uani 1 1 d . . .
F7 F 0.53912(13) 0.28170(7) 0.73242(6) 0.0521(4) Uani 1 1 d . . .
F8 F 0.19151(14) 0.14905(9) 0.66372(9) 0.0760(6) Uani 1 1 d . . .
F9 F 0.53803(11) 0.13540(6) 0.58014(5) 0.0373(3) Uani 1 1 d . . .
F10 F 0.77423(16) 0.31040(8) 0.79193(6) 0.0577(4) Uani 1 1 d . . .
F11 F 0.9530(2) 0.47688(14) 0.91843(8) 0.1138(9) Uani 1 1 d . . .
F12 F 0.86021(18) 0.52350(8) 0.72507(8) 0.0738(5) Uani 1 1 d . . .
N1 N 0.88489(16) 0.43511(9) 0.60464(7) 0.0329(4) Uani 1 1 d . . .
N2 N 0.74238(16) 0.37758(9) 0.53707(7) 0.0308(4) Uani 1 1 d . . .
N3 N 0.97853(15) 0.30212(9) 0.59762(7) 0.0285(4) Uani 1 1 d . . .
N4 N 0.80840(15) 0.23355(8) 0.56180(7) 0.0264(4) Uani 1 1 d . . .
N5 N 0.87031(15) 0.25432(8) 0.69117(7) 0.0262(3) Uani 1 1 d . . .
N6 N 0.66396(14) 0.23602(8) 0.65039(7) 0.0247(3) Uani 1 1 d . . .
N7 N 0.59688(15) 0.37319(8) 0.62854(7) 0.0273(4) Uani 1 1 d . . .
N8 N 0.77035(15) 0.39370(9) 0.69868(7) 0.0295(4) Uani 1 1 d . . .
C1 C 0.9606(2) 0.48942(12) 0.62068(11) 0.0435(6) Uani 1 1 d . . .
H1 H 1.0097 0.4895 0.6571 0.052 Uiso 1 1 calc R . .
C2 C 0.9681(3) 0.54277(13) 0.58678(11) 0.0506(6) Uani 1 1 d . . .
H2 H 1.0220 0.5789 0.5990 0.061 Uiso 1 1 calc R . .
C3 C 0.8937(3) 0.54302(13) 0.53305(11) 0.0510(6) Uani 1 1 d . . .
H3 H 0.8962 0.5800 0.5089 0.061 Uiso 1 1 calc R . .
C4 C 0.8177(2) 0.48985(12) 0.51549(10) 0.0433(6) Uani 1 1 d . . .
H4 H 0.7678 0.4904 0.4793 0.052 Uiso 1 1 calc R . .
C5 C 0.8130(2) 0.43304(11) 0.55163(9) 0.0320(5) Uani 1 1 d . . .
C6 C 0.6858(2) 0.37579(11) 0.47843(9) 0.0343(5) Uani 1 1 d . . .
C7 C 0.7468(2) 0.34797(12) 0.43890(10) 0.0435(6) Uani 1 1 d . . .
C8 C 0.6952(3) 0.34270(14) 0.38216(10) 0.0546(7) Uani 1 1 d . . .
H8 H 0.7383 0.3226 0.3565 0.065 Uiso 1 1 calc R . .
C9 C 0.5785(3) 0.36816(15) 0.36537(10) 0.0565(7) Uani 1 1 d . . .
C10 C 0.5126(3) 0.39829(14) 0.40106(11) 0.0518(7) Uani 1 1 d . . .
H10 H 0.4332 0.4162 0.3880 0.062 Uiso 1 1 calc R . .
C11 C 0.5684(2) 0.40104(12) 0.45718(10) 0.0403(5) Uani 1 1 d . . .
C12 C 1.0981(2) 0.32014(12) 0.59762(9) 0.0365(5) Uani 1 1 d . . .
H12 H 1.1312 0.3574 0.6196 0.044 Uiso 1 1 calc R . .
C13 C 1.1720(2) 0.28708(13) 0.56753(11) 0.0449(6) Uani 1 1 d . . .
H13 H 1.2535 0.3018 0.5683 0.054 Uiso 1 1 calc R . .
C14 C 1.1249(2) 0.23105(13) 0.53552(10) 0.0448(6) Uani 1 1 d . . .
H14 H 1.1749 0.2068 0.5151 0.054 Uiso 1 1 calc R . .
C15 C 1.0059(2) 0.21184(12) 0.53420(9) 0.0357(5) Uani 1 1 d . . .
H15 H 0.9735 0.1739 0.5130 0.043 Uiso 1 1 calc R . .
C16 C 0.93050(18) 0.24882(10) 0.56476(8) 0.0277(4) Uani 1 1 d . . .
C17 C 0.77009(18) 0.16876(10) 0.53926(8) 0.0279(4) Uani 1 1 d . . .
C18 C 0.8002(2) 0.11041(11) 0.57068(9) 0.0346(5) Uani 1 1 d . . .
C19 C 0.7634(2) 0.04651(12) 0.55223(11) 0.0466(6) Uani 1 1 d . . .
H19 H 0.7861 0.0081 0.5748 0.056 Uiso 1 1 calc R . .
C20 C 0.6922(3) 0.04167(13) 0.49934(12) 0.0512(6) Uani 1 1 d . . .
C21 C 0.6607(2) 0.09618(13) 0.46516(10) 0.0470(6) Uani 1 1 d . . .
H21 H 0.6121 0.0912 0.4289 0.056 Uiso 1 1 calc R . .
C22 C 0.7023(2) 0.15857(11) 0.48537(9) 0.0349(5) Uani 1 1 d . . .
C23 C 0.9761(2) 0.22779(11) 0.72202(9) 0.0342(5) Uani 1 1 d . . .
H23 H 1.0516 0.2487 0.7197 0.041 Uiso 1 1 calc R . .
C24 C 0.9791(2) 0.17265(12) 0.75614(9) 0.0394(5) Uani 1 1 d . . .
H24 H 1.0548 0.1550 0.7754 0.047 Uiso 1 1 calc R . .
C25 C 0.8678(2) 0.14326(11) 0.76175(9) 0.0392(5) Uani 1 1 d . . .
H25 H 0.8665 0.1077 0.7874 0.047 Uiso 1 1 calc R . .
C26 C 0.7602(2) 0.16632(11) 0.72977(9) 0.0329(5) Uani 1 1 d . . .
H26 H 0.6843 0.1470 0.7336 0.039 Uiso 1 1 calc R . .
C27 C 0.76303(18) 0.21935(10) 0.69084(8) 0.0249(4) Uani 1 1 d . . .
C28 C 0.54450(18) 0.21198(10) 0.65480(8) 0.0267(4) Uani 1 1 d . . .
C29 C 0.4813(2) 0.23585(11) 0.69510(10) 0.0361(5) Uani 1 1 d . . .
C30 C 0.3642(2) 0.21532(13) 0.69940(12) 0.0487(6) Uani 1 1 d . . .
H30 H 0.3244 0.2327 0.7274 0.058 Uiso 1 1 calc R . .
C31 C 0.3084(2) 0.16863(13) 0.66132(12) 0.0473(6) Uani 1 1 d . . .
C32 C 0.3633(2) 0.14140(11) 0.62060(10) 0.0389(5) Uani 1 1 d . . .
H32 H 0.3229 0.1090 0.5951 0.047 Uiso 1 1 calc R . .
C33 C 0.48115(19) 0.16373(10) 0.61860(9) 0.0300(4) Uani 1 1 d . . .
C34 C 0.47567(19) 0.38594(11) 0.60727(9) 0.0343(5) Uani 1 1 d . . .
H34 H 0.4397 0.3644 0.5734 0.041 Uiso 1 1 calc R . .
C35 C 0.4025(2) 0.42765(12) 0.63143(10) 0.0384(5) Uani 1 1 d . . .
H35 H 0.3191 0.4345 0.6146 0.046 Uiso 1 1 calc R . .
C36 C 0.4541(2) 0.45991(12) 0.68164(10) 0.0386(5) Uani 1 1 d . . .
H36 H 0.4058 0.4886 0.6996 0.046 Uiso 1 1 calc R . .
C37 C 0.5756(2) 0.44927(11) 0.70423(9) 0.0352(5) Uani 1 1 d . . .
H37 H 0.6117 0.4711 0.7379 0.042 Uiso 1 1 calc R . .
C38 C 0.64830(18) 0.40564(10) 0.67743(8) 0.0278(4) Uani 1 1 d . . .
C39 C 0.81570(19) 0.41556(12) 0.75518(9) 0.0357(5) Uani 1 1 d . . .
C40 C 0.8184(2) 0.37367(13) 0.80091(10) 0.0434(6) Uani 1 1 d . . .
C41 C 0.8634(3) 0.39257(18) 0.85608(11) 0.0618(8) Uani 1 1 d . . .
H41 H 0.8633 0.3626 0.8862 0.074 Uiso 1 1 calc R . .
C42 C 0.9079(3) 0.4569(2) 0.86463(14) 0.0719(10) Uani 1 1 d . . .
C43 C 0.9103(3) 0.50159(18) 0.82229(15) 0.0683(9) Uani 1 1 d . . .
H43 H 0.9428 0.5454 0.8296 0.082 Uiso 1 1 calc R . .
C44 C 0.8631(2) 0.48013(14) 0.76801(12) 0.0506(6) Uani 1 1 d . . .
C45 C 1.03191(19) 0.36927(11) 0.70842(9) 0.0321(5) Uani 1 1 d . . .
C46 C 1.1247(2) 0.38800(11) 0.73904(9) 0.0356(5) Uani 1 1 d . . .
C47 C 1.23611(19) 0.41472(11) 0.77361(8) 0.0317(5) Uani 1 1 d . . .
C48 C 1.2397(2) 0.48054(12) 0.79366(10) 0.0404(5) Uani 1 1 d . . .
H48 H 1.1681 0.5074 0.7858 0.048 Uiso 1 1 calc R . .
C49 C 1.3473(2) 0.50696(13) 0.82494(11) 0.0490(6) Uani 1 1 d . . .
H49 H 1.3482 0.5517 0.8382 0.059 Uiso 1 1 calc R . .
C50 C 1.4529(2) 0.46866(13) 0.83684(10) 0.0469(6) Uani 1 1 d . . .
H50 H 1.5262 0.4872 0.8577 0.056 Uiso 1 1 calc R . .
C51 C 1.4508(2) 0.40289(14) 0.81814(11) 0.0475(6) Uani 1 1 d . . .
H51 H 1.5226 0.3762 0.8266 0.057 Uiso 1 1 calc R . .
C52 C 1.3435(2) 0.37618(13) 0.78706(10) 0.0433(6) Uani 1 1 d . . .
H52 H 1.3428 0.3311 0.7747 0.052 Uiso 1 1 calc R . .
C53 C 0.54821(19) 0.28163(10) 0.53327(8) 0.0289(4) Uani 1 1 d . . .
C54 C 0.45798(19) 0.26566(11) 0.49866(9) 0.0323(5) Uani 1 1 d . . .
C55 C 0.35216(19) 0.24743(11) 0.45731(8) 0.0321(5) Uani 1 1 d . . .
C56 C 0.3284(2) 0.18003(12) 0.44125(10) 0.0403(5) Uani 1 1 d . . .
H56 H 0.3837 0.1460 0.4573 0.048 Uiso 1 1 calc R . .
C57 C 0.2244(3) 0.16302(15) 0.40205(11) 0.0545(7) Uani 1 1 d . . .
H57 H 0.2090 0.1175 0.3920 0.065 Uiso 1 1 calc R . .
C58 C 0.1432(3) 0.21214(18) 0.37764(11) 0.0627(8) Uani 1 1 d . . .
H58 H 0.0737 0.2004 0.3502 0.075 Uiso 1 1 calc R . .
C59 C 0.1641(3) 0.27866(17) 0.39362(11) 0.0590(8) Uani 1 1 d . . .
H59 H 0.1073 0.3121 0.3777 0.071 Uiso 1 1 calc R . .
C60 C 0.2679(2) 0.29674(13) 0.43276(10) 0.0438(6) Uani 1 1 d . . .
H60 H 0.2817 0.3424 0.4429 0.053 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C45 Ru1 N8 92.45(8) . . ?
C45 Ru1 N1 97.59(8) . . ?
N8 Ru1 N1 93.73(7) . . ?
C45 Ru1 N3 92.43(8) . . ?
N8 Ru1 N3 174.56(7) . . ?
N1 Ru1 N3 87.99(7) . . ?
C45 Ru1 N5 87.05(7) . . ?
N8 Ru1 N5 91.47(7) . . ?
N1 Ru1 N5 172.86(6) . . ?
N3 Ru1 N5 86.40(6) . . ?
C45 Ru1 Ru2 164.49(6) . . ?
N8 Ru1 Ru2 90.29(5) . . ?
N1 Ru1 Ru2 97.45(5) . . ?
N3 Ru1 Ru2 84.37(5) . . ?
N5 Ru1 Ru2 77.62(4) . . ?
C53 Ru2 N6 99.10(7) . . ?
C53 Ru2 N4 96.87(8) . . ?
N6 Ru2 N4 93.67(7) . . ?
C53 Ru2 N7 89.39(7) . . ?
N6 Ru2 N7 86.59(6) . . ?
N4 Ru2 N7 173.61(6) . . ?
C53 Ru2 N2 87.21(7) . . ?
N6 Ru2 N2 171.36(7) . . ?
N4 Ru2 N2 91.40(7) . . ?
N7 Ru2 N2 87.60(7) . . ?
C53 Ru2 Ru1 164.03(6) . . ?
N6 Ru2 Ru1 94.84(5) . . ?
N4 Ru2 Ru1 89.94(5) . . ?
N7 Ru2 Ru1 83.67(4) . . ?
N2 Ru2 Ru1 78.16(5) . . ?
C5 N1 C1 119.90(19) . . ?
C5 N1 Ru1 115.06(13) . . ?
C1 N1 Ru1 124.83(15) . . ?
C5 N2 C6 113.32(17) . . ?
C5 N2 Ru2 128.11(14) . . ?
C6 N2 Ru2 118.42(13) . . ?
C16 N3 C12 117.87(18) . . ?
C16 N3 Ru1 122.12(13) . . ?
C12 N3 Ru1 119.87(14) . . ?
C16 N4 C17 115.76(16) . . ?
C16 N4 Ru2 120.06(13) . . ?
C17 N4 Ru2 124.13(13) . . ?
C23 N5 C27 117.07(18) . . ?
C23 N5 Ru1 118.65(14) . . ?
C27 N5 Ru1 124.13(13) . . ?
C27 N6 C28 119.39(16) . . ?
C27 N6 Ru2 115.87(13) . . ?
C28 N6 Ru2 124.60(12) . . ?
C34 N7 C38 116.92(18) . . ?
C34 N7 Ru2 121.18(14) . . ?
C38 N7 Ru2 121.67(13) . . ?
C38 N8 C39 116.43(17) . . ?
C38 N8 Ru1 120.80(13) . . ?
C39 N8 Ru1 122.71(13) . . ?
C2 C1 N1 123.2(2) . . ?
C1 C2 C3 118.4(2) . . ?
C4 C3 C2 120.2(2) . . ?
C3 C4 C5 120.6(2) . . ?
N2 C5 N1 117.86(18) . . ?
N2 C5 C4 124.4(2) . . ?
N1 C5 C4 117.75(19) . . ?
C7 C6 C11 115.4(2) . . ?
C7 C6 N2 121.1(2) . . ?
C11 C6 N2 123.5(2) . . ?
F1 C7 C8 117.8(2) . . ?
F1 C7 C6 118.6(2) . . ?
C8 C7 C6 123.6(2) . . ?
C9 C8 C7 116.7(3) . . ?
F2 C9 C8 118.4(3) . . ?
F2 C9 C10 117.8(3) . . ?
C8 C9 C10 123.8(2) . . ?
C9 C10 C11 116.6(3) . . ?
F3 C11 C10 118.3(2) . . ?
F3 C11 C6 117.8(2) . . ?
C10 C11 C6 123.8(2) . . ?
C13 C12 N3 123.5(2) . . ?
C12 C13 C14 118.8(2) . . ?
C15 C14 C13 119.3(2) . . ?
C14 C15 C16 120.2(2) . . ?
N3 C16 N4 117.92(18) . . ?
N3 C16 C15 120.17(18) . . ?
N4 C16 C15 121.90(18) . . ?
C18 C17 C22 115.02(19) . . ?
C18 C17 N4 121.14(18) . . ?
C22 C17 N4 123.84(19) . . ?
F4 C18 C19 118.0(2) . . ?
F4 C18 C17 117.70(18) . . ?
C19 C18 C17 124.3(2) . . ?
C20 C19 C18 116.6(2) . . ?
F5 C20 C21 118.7(2) . . ?
F5 C20 C19 118.3(2) . . ?
C21 C20 C19 123.0(2) . . ?
C20 C21 C22 117.8(2) . . ?
F6 C22 C21 117.8(2) . . ?
F6 C22 C17 118.96(19) . . ?
C21 C22 C17 123.2(2) . . ?
N5 C23 C24 123.9(2) . . ?
C23 C24 C25 118.4(2) . . ?
C26 C25 C24 119.5(2) . . ?
C25 C26 C27 119.9(2) . . ?
N6 C27 N5 117.02(17) . . ?
N6 C27 C26 122.83(18) . . ?
N5 C27 C26 120.08(18) . . ?
C29 C28 C33 114.73(18) . . ?
C29 C28 N6 122.46(18) . . ?
C33 C28 N6 122.80(18) . . ?
F7 C29 C30 118.4(2) . . ?
F7 C29 C28 117.61(18) . . ?
C30 C29 C28 124.0(2) . . ?
C31 C30 C29 117.1(2) . . ?
F8 C31 C32 118.4(2) . . ?
F8 C31 C30 118.2(2) . . ?
C32 C31 C30 123.4(2) . . ?
C31 C32 C33 116.8(2) . . ?
F9 C33 C32 117.33(19) . . ?
F9 C33 C28 118.67(18) . . ?
C32 C33 C28 124.0(2) . . ?
N7 C34 C35 124.7(2) . . ?
C34 C35 C36 118.5(2) . . ?
C37 C36 C35 118.9(2) . . ?
C36 C37 C38 120.6(2) . . ?
N8 C38 N7 117.24(18) . . ?
N8 C38 C37 122.40(19) . . ?
N7 C38 C37 120.35(18) . . ?
C40 C39 C44 115.1(2) . . ?
C40 C39 N8 122.4(2) . . ?
C44 C39 N8 122.5(2) . . ?
F10 C40 C39 118.6(2) . . ?
F10 C40 C41 117.3(3) . . ?
C39 C40 C41 124.1(3) . . ?
C42 C41 C40 116.7(3) . . ?
C43 C42 F11 118.5(3) . . ?
C43 C42 C41 123.5(3) . . ?
F11 C42 C41 118.0(4) . . ?
C42 C43 C44 117.3(3) . . ?
F12 C44 C43 119.1(3) . . ?
F12 C44 C39 117.5(2) . . ?
C43 C44 C39 123.3(3) . . ?
C46 C45 Ru1 171.0(2) . . ?
C45 C46 C47 176.1(3) . . ?
C48 C47 C52 117.8(2) . . ?
C48 C47 C46 120.6(2) . . ?
C52 C47 C46 121.5(2) . . ?
C49 C48 C47 120.7(2) . . ?
C50 C49 C48 120.6(2) . . ?
C49 C50 C51 119.6(2) . . ?
C50 C51 C52 120.0(2) . . ?
C51 C52 C47 121.2(2) . . ?
C54 C53 Ru2 174.79(18) . . ?
C53 C54 C55 179.2(3) . . ?
C60 C55 C56 118.3(2) . . ?
C60 C55 C54 120.5(2) . . ?
C56 C55 C54 121.3(2) . . ?
C57 C56 C55 120.6(2) . . ?
C58 C57 C56 120.5(3) . . ?
C57 C58 C59 119.6(2) . . ?
C58 C59 C60 120.7(3) . . ?
C59 C60 C55 120.3(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C45 1.994(2) . ?
Ru1 N8 2.0021(17) . ?
Ru1 N1 2.0046(17) . ?
Ru1 N3 2.0872(17) . ?
Ru1 N5 2.1661(17) . ?
Ru1 Ru2 2.4640(2) . ?
Ru2 C53 1.973(2) . ?
Ru2 N6 1.9853(16) . ?
Ru2 N4 1.9987(16) . ?
Ru2 N7 2.1452(17) . ?
Ru2 N2 2.1517(17) . ?
F1 C7 1.341(3) . ?
F2 C9 1.363(3) . ?
F3 C11 1.342(3) . ?
F4 C18 1.348(2) . ?
F5 C20 1.359(3) . ?
F6 C22 1.340(3) . ?
F7 C29 1.349(2) . ?
F8 C31 1.357(3) . ?
F9 C33 1.341(2) . ?
F10 C40 1.345(3) . ?
F11 C42 1.359(3) . ?
F12 C44 1.343(3) . ?
N1 C5 1.371(3) . ?
N1 C1 1.369(3) . ?
N2 C5 1.352(3) . ?
N2 C6 1.436(3) . ?
N3 C16 1.364(3) . ?
N3 C12 1.365(3) . ?
N4 C16 1.367(3) . ?
N4 C17 1.424(3) . ?
N5 C23 1.362(3) . ?
N5 C27 1.368(3) . ?
N6 C27 1.358(2) . ?
N6 C28 1.422(2) . ?
N7 C34 1.358(3) . ?
N7 C38 1.368(3) . ?
N8 C38 1.364(3) . ?
N8 C39 1.429(3) . ?
C1 C2 1.349(3) . ?
C2 C3 1.396(4) . ?
C3 C4 1.360(3) . ?
C4 C5 1.431(3) . ?
C6 C7 1.385(3) . ?
C6 C11 1.388(3) . ?
C7 C8 1.384(3) . ?
C8 C9 1.367(4) . ?
C9 C10 1.368(4) . ?
C10 C11 1.379(3) . ?
C12 C13 1.360(3) . ?
C13 C14 1.394(3) . ?
C14 C15 1.359(3) . ?
C15 C16 1.417(3) . ?
C17 C18 1.387(3) . ?
C17 C22 1.386(3) . ?
C18 C19 1.375(3) . ?
C19 C20 1.369(4) . ?
C20 C21 1.362(4) . ?
C21 C22 1.373(3) . ?
C23 C24 1.364(3) . ?
C24 C25 1.387(3) . ?
C25 C26 1.362(3) . ?
C26 C27 1.414(3) . ?
C28 C29 1.386(3) . ?
C28 C33 1.389(3) . ?
C29 C30 1.375(3) . ?
C30 C31 1.364(4) . ?
C31 C32 1.363(3) . ?
C32 C33 1.381(3) . ?
C34 C35 1.362(3) . ?
C35 C36 1.393(3) . ?
C36 C37 1.361(3) . ?
C37 C38 1.416(3) . ?
C39 C40 1.378(3) . ?
C39 C44 1.392(3) . ?
C40 C41 1.383(3) . ?
C41 C42 1.366(5) . ?
C42 C43 1.357(5) . ?
C43 C44 1.382(4) . ?
C45 C46 1.200(3) . ?
C46 C47 1.445(3) . ?
C47 C48 1.387(3) . ?
C47 C52 1.392(3) . ?
C48 C49 1.380(3) . ?
C49 C50 1.371(4) . ?
C50 C51 1.376(4) . ?
C51 C52 1.378(3) . ?
C53 C54 1.211(3) . ?
C54 C55 1.428(3) . ?
C55 C60 1.398(3) . ?
C55 C56 1.399(3) . ?
C56 C57 1.380(3) . ?
C57 C58 1.374(4) . ?
C58 C59 1.378(4) . ?
C59 C60 1.382(3) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C45 Ru1 Ru2 C53 -177.0(3) . . . . ?
N8 Ru1 Ru2 C53 82.7(2) . . . . ?
N1 Ru1 Ru2 C53 -11.1(2) . . . . ?
N3 Ru1 Ru2 C53 -98.3(2) . . . . ?
N5 Ru1 Ru2 C53 174.2(2) . . . . ?
C45 Ru1 Ru2 N6 32.3(2) . . . . ?
N8 Ru1 Ru2 N6 -68.03(7) . . . . ?
N1 Ru1 Ru2 N6 -161.83(7) . . . . ?
N3 Ru1 Ru2 N6 110.95(7) . . . . ?
N5 Ru1 Ru2 N6 23.41(6) . . . . ?
C45 Ru1 Ru2 N4 -61.4(2) . . . . ?
N8 Ru1 Ru2 N4 -161.71(7) . . . . ?
N1 Ru1 Ru2 N4 104.49(7) . . . . ?
N3 Ru1 Ru2 N4 17.27(7) . . . . ?
N5 Ru1 Ru2 N4 -70.27(6) . . . . ?
C45 Ru1 Ru2 N7 118.3(2) . . . . ?
N8 Ru1 Ru2 N7 17.98(7) . . . . ?
N1 Ru1 Ru2 N7 -75.82(7) . . . . ?
N3 Ru1 Ru2 N7 -163.04(6) . . . . ?
N5 Ru1 Ru2 N7 109.43(6) . . . . ?
C45 Ru1 Ru2 N2 -152.9(2) . . . . ?
N8 Ru1 Ru2 N2 106.85(7) . . . . ?
N1 Ru1 Ru2 N2 13.05(7) . . . . ?
N3 Ru1 Ru2 N2 -74.17(7) . . . . ?
N5 Ru1 Ru2 N2 -161.71(7) . . . . ?
C45 Ru1 N1 C5 162.79(15) . . . . ?
N8 Ru1 N1 C5 -104.23(15) . . . . ?
N3 Ru1 N1 C5 70.60(15) . . . . ?
N5 Ru1 N1 C5 32.5(6) . . . . ?
Ru2 Ru1 N1 C5 -13.45(15) . . . . ?
C45 Ru1 N1 C1 -11.9(2) . . . . ?
N8 Ru1 N1 C1 81.05(19) . . . . ?
N3 Ru1 N1 C1 -104.11(19) . . . . ?
N5 Ru1 N1 C1 -142.3(5) . . . . ?
Ru2 Ru1 N1 C1 171.84(18) . . . . ?
C53 Ru2 N2 C5 155.31(19) . . . . ?
N6 Ru2 N2 C5 18.1(5) . . . . ?
N4 Ru2 N2 C5 -107.88(18) . . . . ?
N7 Ru2 N2 C5 65.80(18) . . . . ?
Ru1 Ru2 N2 C5 -18.23(17) . . . . ?
C53 Ru2 N2 C6 -19.94(16) . . . . ?
N6 Ru2 N2 C6 -157.2(4) . . . . ?
N4 Ru2 N2 C6 76.87(16) . . . . ?
N7 Ru2 N2 C6 -109.45(16) . . . . ?
Ru1 Ru2 N2 C6 166.52(16) . . . . ?
C45 Ru1 N3 C16 145.76(16) . . . . ?
N8 Ru1 N3 C16 -8.2(8) . . . . ?
N1 Ru1 N3 C16 -116.72(16) . . . . ?
N5 Ru1 N3 C16 58.86(15) . . . . ?
Ru2 Ru1 N3 C16 -19.03(14) . . . . ?
C45 Ru1 N3 C12 -30.01(17) . . . . ?
N8 Ru1 N3 C12 176.1(7) . . . . ?
N1 Ru1 N3 C12 67.51(16) . . . . ?
N5 Ru1 N3 C12 -116.90(16) . . . . ?
Ru2 Ru1 N3 C12 165.21(16) . . . . ?
C53 Ru2 N4 C16 143.72(15) . . . . ?
N6 Ru2 N4 C16 -116.65(15) . . . . ?
N7 Ru2 N4 C16 -24.5(7) . . . . ?
N2 Ru2 N4 C16 56.35(15) . . . . ?
Ru1 Ru2 N4 C16 -21.80(14) . . . . ?
C53 Ru2 N4 C17 -39.00(16) . . . . ?
N6 Ru2 N4 C17 60.64(15) . . . . ?
N7 Ru2 N4 C17 152.8(5) . . . . ?
N2 Ru2 N4 C17 -126.36(15) . . . . ?
Ru1 Ru2 N4 C17 155.48(15) . . . . ?
C45 Ru1 N5 C23 -23.09(16) . . . . ?
N8 Ru1 N5 C23 -115.47(15) . . . . ?
N1 Ru1 N5 C23 107.7(5) . . . . ?
N3 Ru1 N5 C23 69.53(15) . . . . ?
Ru2 Ru1 N5 C23 154.55(15) . . . . ?
C45 Ru1 N5 C27 152.35(16) . . . . ?
N8 Ru1 N5 C27 59.97(15) . . . . ?
N1 Ru1 N5 C27 -76.8(6) . . . . ?
N3 Ru1 N5 C27 -115.02(15) . . . . ?
Ru2 Ru1 N5 C27 -30.00(14) . . . . ?
C53 Ru2 N6 C27 161.84(14) . . . . ?
N4 Ru2 N6 C27 64.27(14) . . . . ?
N7 Ru2 N6 C27 -109.33(14) . . . . ?
N2 Ru2 N6 C27 -61.5(5) . . . . ?
Ru1 Ru2 N6 C27 -25.98(13) . . . . ?
C53 Ru2 N6 C28 -22.50(17) . . . . ?
N4 Ru2 N6 C28 -120.07(15) . . . . ?
N7 Ru2 N6 C28 66.33(15) . . . . ?
N2 Ru2 N6 C28 114.1(4) . . . . ?
Ru1 Ru2 N6 C28 149.68(15) . . . . ?
C53 Ru2 N7 C34 1.50(16) . . . . ?
N6 Ru2 N7 C34 -97.65(16) . . . . ?
N4 Ru2 N7 C34 169.8(5) . . . . ?
N2 Ru2 N7 C34 88.74(16) . . . . ?
Ru1 Ru2 N7 C34 167.09(16) . . . . ?
C53 Ru2 N7 C38 175.84(15) . . . . ?
N6 Ru2 N7 C38 76.68(15) . . . . ?
N4 Ru2 N7 C38 -15.8(7) . . . . ?
N2 Ru2 N7 C38 -96.92(15) . . . . ?
Ru1 Ru2 N7 C38 -18.58(14) . . . . ?
C45 Ru1 N8 C38 170.63(16) . . . . ?
N1 Ru1 N8 C38 72.85(16) . . . . ?
N3 Ru1 N8 C38 -35.4(8) . . . . ?
N5 Ru1 N8 C38 -102.25(15) . . . . ?
Ru2 Ru1 N8 C38 -24.63(15) . . . . ?
C45 Ru1 N8 C39 -6.51(17) . . . . ?
N1 Ru1 N8 C39 -104.29(17) . . . . ?
N3 Ru1 N8 C39 147.4(7) . . . . ?
N5 Ru1 N8 C39 80.60(17) . . . . ?
Ru2 Ru1 N8 C39 158.22(16) . . . . ?
C5 N1 C1 C2 0.7(4) . . . . ?
Ru1 N1 C1 C2 175.2(2) . . . . ?
N1 C1 C2 C3 1.0(4) . . . . ?
C1 C2 C3 C4 -1.2(4) . . . . ?
C2 C3 C4 C5 -0.1(4) . . . . ?
C6 N2 C5 N1 -171.02(19) . . . . ?
Ru2 N2 C5 N1 13.5(3) . . . . ?
C6 N2 C5 C4 9.1(3) . . . . ?
Ru2 N2 C5 C4 -166.34(18) . . . . ?
C1 N1 C5 N2 178.1(2) . . . . ?
Ru1 N1 C5 N2 3.2(2) . . . . ?
C1 N1 C5 C4 -2.0(3) . . . . ?
Ru1 N1 C5 C4 -176.97(17) . . . . ?
C3 C4 C5 N2 -178.4(2) . . . . ?
C3 C4 C5 N1 1.7(4) . . . . ?
C5 N2 C6 C7 87.6(3) . . . . ?
Ru2 N2 C6 C7 -96.5(2) . . . . ?
C5 N2 C6 C11 -92.5(3) . . . . ?
Ru2 N2 C6 C11 83.4(2) . . . . ?
C11 C6 C7 F1 177.7(2) . . . . ?
N2 C6 C7 F1 -2.4(3) . . . . ?
C11 C6 C7 C8 -2.3(3) . . . . ?
N2 C6 C7 C8 177.6(2) . . . . ?
F1 C7 C8 C9 -178.5(2) . . . . ?
C6 C7 C8 C9 1.5(4) . . . . ?
C7 C8 C9 F2 179.4(2) . . . . ?
C7 C8 C9 C10 0.6(4) . . . . ?
F2 C9 C10 C11 179.6(2) . . . . ?
C8 C9 C10 C11 -1.5(4) . . . . ?
C9 C10 C11 F3 179.0(2) . . . . ?
C9 C10 C11 C6 0.5(4) . . . . ?
C7 C6 C11 F3 -177.2(2) . . . . ?
N2 C6 C11 F3 2.9(3) . . . . ?
C7 C6 C11 C10 1.2(3) . . . . ?
N2 C6 C11 C10 -178.7(2) . . . . ?
C16 N3 C12 C13 -1.3(3) . . . . ?
Ru1 N3 C12 C13 174.68(19) . . . . ?
N3 C12 C13 C14 -1.1(4) . . . . ?
C12 C13 C14 C15 1.4(4) . . . . ?
C13 C14 C15 C16 0.5(4) . . . . ?
C12 N3 C16 N4 -175.73(18) . . . . ?
Ru1 N3 C16 N4 8.4(2) . . . . ?
C12 N3 C16 C15 3.2(3) . . . . ?
Ru1 N3 C16 C15 -172.66(15) . . . . ?
C17 N4 C16 N3 -164.77(17) . . . . ?
Ru2 N4 C16 N3 12.7(2) . . . . ?
C17 N4 C16 C15 16.3(3) . . . . ?
Ru2 N4 C16 C15 -166.16(16) . . . . ?
C14 C15 C16 N3 -2.9(3) . . . . ?
C14 C15 C16 N4 176.0(2) . . . . ?
C16 N4 C17 C18 75.1(2) . . . . ?
Ru2 N4 C17 C18 -102.3(2) . . . . ?
C16 N4 C17 C22 -104.3(2) . . . . ?
Ru2 N4 C17 C22 78.3(2) . . . . ?
C22 C17 C18 F4 177.21(19) . . . . ?
N4 C17 C18 F4 -2.3(3) . . . . ?
C22 C17 C18 C19 -2.4(3) . . . . ?
N4 C17 C18 C19 178.1(2) . . . . ?
F4 C18 C19 C20 -179.9(2) . . . . ?
C17 C18 C19 C20 -0.3(4) . . . . ?
C18 C19 C20 F5 -178.5(2) . . . . ?
C18 C19 C20 C21 1.8(4) . . . . ?
F5 C20 C21 C22 179.8(2) . . . . ?
C19 C20 C21 C22 -0.4(4) . . . . ?
C20 C21 C22 F6 175.3(2) . . . . ?
C20 C21 C22 C17 -2.6(4) . . . . ?
C18 C17 C22 F6 -174.02(19) . . . . ?
N4 C17 C22 F6 5.4(3) . . . . ?
C18 C17 C22 C21 3.9(3) . . . . ?
N4 C17 C22 C21 -176.6(2) . . . . ?
C27 N5 C23 C24 -6.3(3) . . . . ?
Ru1 N5 C23 C24 169.50(17) . . . . ?
N5 C23 C24 C25 -2.7(3) . . . . ?
C23 C24 C25 C26 5.5(3) . . . . ?
C24 C25 C26 C27 0.7(3) . . . . ?
C28 N6 C27 N5 -166.98(17) . . . . ?
Ru2 N6 C27 N5 8.9(2) . . . . ?
C28 N6 C27 C26 16.0(3) . . . . ?
Ru2 N6 C27 C26 -168.09(15) . . . . ?
C23 N5 C27 N6 -164.69(17) . . . . ?
Ru1 N5 C27 N6 19.8(2) . . . . ?
C23 N5 C27 C26 12.4(3) . . . . ?
Ru1 N5 C27 C26 -163.10(14) . . . . ?
C25 C26 C27 N6 167.0(2) . . . . ?
C25 C26 C27 N5 -9.9(3) . . . . ?
C27 N6 C28 C29 70.6(3) . . . . ?
Ru2 N6 C28 C29 -105.0(2) . . . . ?
C27 N6 C28 C33 -110.6(2) . . . . ?
Ru2 N6 C28 C33 73.9(2) . . . . ?
C33 C28 C29 F7 178.49(19) . . . . ?
N6 C28 C29 F7 -2.6(3) . . . . ?
C33 C28 C29 C30 -1.1(3) . . . . ?
N6 C28 C29 C30 177.8(2) . . . . ?
F7 C29 C30 C31 -179.6(2) . . . . ?
C28 C29 C30 C31 0.0(4) . . . . ?
C29 C30 C31 F8 -178.1(2) . . . . ?
C29 C30 C31 C32 0.9(4) . . . . ?
F8 C31 C32 C33 178.5(2) . . . . ?
C30 C31 C32 C33 -0.6(4) . . . . ?
C31 C32 C33 F9 177.5(2) . . . . ?
C31 C32 C33 C28 -0.7(3) . . . . ?
C29 C28 C33 F9 -176.66(18) . . . . ?
N6 C28 C33 F9 4.4(3) . . . . ?
C29 C28 C33 C32 1.5(3) . . . . ?
N6 C28 C33 C32 -177.4(2) . . . . ?
C38 N7 C34 C35 -0.9(3) . . . . ?
Ru2 N7 C34 C35 173.74(18) . . . . ?
N7 C34 C35 C36 -0.1(4) . . . . ?
C34 C35 C36 C37 0.8(3) . . . . ?
C35 C36 C37 C38 -0.6(3) . . . . ?
C39 N8 C38 N7 -166.73(18) . . . . ?
Ru1 N8 C38 N7 16.0(2) . . . . ?
C39 N8 C38 C37 12.9(3) . . . . ?
Ru1 N8 C38 C37 -164.42(16) . . . . ?
C34 N7 C38 N8 -179.25(18) . . . . ?
Ru2 N7 C38 N8 6.2(2) . . . . ?
C34 N7 C38 C37 1.1(3) . . . . ?
Ru2 N7 C38 C37 -173.46(15) . . . . ?
C36 C37 C38 N8 179.9(2) . . . . ?
C36 C37 C38 N7 -0.4(3) . . . . ?
C38 N8 C39 C40 92.7(3) . . . . ?
Ru1 N8 C39 C40 -90.1(2) . . . . ?
C38 N8 C39 C44 -88.9(3) . . . . ?
Ru1 N8 C39 C44 88.4(2) . . . . ?
C44 C39 C40 F10 -180.0(2) . . . . ?
N8 C39 C40 F10 -1.4(3) . . . . ?
C44 C39 C40 C41 0.4(4) . . . . ?
N8 C39 C40 C41 178.9(2) . . . . ?
F10 C40 C41 C42 180.0(2) . . . . ?
C39 C40 C41 C42 -0.3(4) . . . . ?
C40 C41 C42 C43 -0.4(5) . . . . ?
C40 C41 C42 F11 -179.9(3) . . . . ?
F11 C42 C43 C44 -179.6(3) . . . . ?
C41 C42 C43 C44 1.0(5) . . . . ?
C42 C43 C44 F12 178.0(3) . . . . ?
C42 C43 C44 C39 -0.9(4) . . . . ?
C40 C39 C44 F12 -178.6(2) . . . . ?
N8 C39 C44 F12 2.9(3) . . . . ?
C40 C39 C44 C43 0.3(4) . . . . ?
N8 C39 C44 C43 -178.3(2) . . . . ?
N8 Ru1 C45 C46 -92.7(13) . . . . ?
N1 Ru1 C45 C46 1.4(13) . . . . ?
N3 Ru1 C45 C46 89.6(13) . . . . ?
N5 Ru1 C45 C46 175.9(13) . . . . ?
Ru2 Ru1 C45 C46 167.3(11) . . . . ?
Ru1 C45 C46 C47 2(5) . . . . ?
C45 C46 C47 C48 48(4) . . . . ?
C45 C46 C47 C52 -130(4) . . . . ?
C52 C47 C48 C49 1.2(4) . . . . ?
C46 C47 C48 C49 -177.6(2) . . . . ?
C47 C48 C49 C50 0.0(4) . . . . ?
C48 C49 C50 C51 -1.0(4) . . . . ?
C49 C50 C51 C52 0.8(4) . . . . ?
C50 C51 C52 C47 0.5(4) . . . . ?
C48 C47 C52 C51 -1.5(4) . . . . ?
C46 C47 C52 C51 177.3(2) . . . . ?
N6 Ru2 C53 C54 -44(2) . . . . ?
N4 Ru2 C53 C54 50(2) . . . . ?
N7 Ru2 C53 C54 -131(2) . . . . ?
N2 Ru2 C53 C54 142(2) . . . . ?
Ru1 Ru2 C53 C54 165.1(19) . . . . ?
Ru2 C53 C54 C55 -133(21) . . . . ?
C53 C54 C55 C60 -58(22) . . . . ?
C53 C54 C55 C56 123(22) . . . . ?
C60 C55 C56 C57 0.2(3) . . . . ?
C54 C55 C56 C57 178.7(2) . . . . ?
C55 C56 C57 C58 0.8(4) . . . . ?
C56 C57 C58 C59 -1.8(4) . . . . ?
C57 C58 C59 C60 1.9(5) . . . . ?
C58 C59 C60 C55 -0.9(4) . . . . ?
C56 C55 C60 C59 -0.1(4) . . . . ?
C54 C55 C60 C59 -178.6(2) . . . . ?
